| Common Name: | SPECTRACIDE WEED STOP FOR LAWNS PLUS CRABGRASS KILLER(3) |
| Manufacturer: | SPECTRUM GROUP |
| SDS Revision Date: | 4/13/2018 |
| SDS Format: | GHS-US |
| Item Number(s): | 36WG56, 56EC11 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
SPECTRACIDE(R*) WEED STOP(R*) FOR LAWNS PLUS CRABGRASS KILLER(3)
CONFORMS TO HAZARD COMMUNICATION STANDARD 29 CFR 1910.1200
MAY 23, 2018
| SECTION 1 - IDENTIFICATION |  |
PRODUCT IDENTIFIER:
SPECTRACIDE(R*) WEED STOP(R*) FOR LAWNS PLUS CRABGRASS KILLER(3)
OTHER MEANS OF IDENTIFICATION:
EPA REGISTRATION NUMBER: 9688-337-8845
PRODUCT CODE: HG-96587; HG-96588; HG-96590
FORMULA NUMBER: HG-21-0971
RECOMMENDED USE: SELECTIVE HERBICIDE
RECOMMENDED RESTRICTIONS: USE IN ACCORDANCE WITH LABEL DIRECTIONS
MANUFACTURER/IMPORTER/SUPPLIER/DISTRIBUTER INFORMATION:
COMPANY NAME: SPECTRUM GROUP, DIVISION OF UNITED INDUSTRIES CORPORATION
ADDRESS: PO BOX 142642
TELEPHONE NUMBER: 1-800-917-5438
WEBSITE: WWW.SPECTRACIDE.COM
EMERGENCY TELEPHONE NUMBER:
CHEMTREC: (800)424-9300
MEDICAL: 1-800-917-5438
| SECTION 2 - HAZARD(S) IDENTIFICATION | |
CLASSIFICATION OF SUBSTANCE OR MIXTURE:
PHYSICAL HAZARD(S): NOT CLASSIFIED AS A PHYSICAL HAZARD
HEALTH HAZARD(S):
SKIN SENSITIZER: CATEGORY 1
ENVIRONMENTAL HAZARD: NOT CLASSIFIED AS AN ENVIRONMENTAL HAZARD
LABEL ELEMENTS:
HAZARD PICTOGRAM(S): EXCLAMATION MARK
SIGNAL WORD: WARNING
HAZARD STATEMENTS: MAY CAUSE AN ALLERGIC SKIN REACTION
PRECAUTIONARY STATEMENTS:
AVOID BREATHING SPRAY. CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT
OF THE WORKPLACE. WEAR PROTECTIVE GLOVES.
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF SKIN IRRITATION OR RASH OCCURS:
GET MEDICAL ADVICE. WASH CONTAMINATED CLOTHING BEFORE REUSE. DISPOSE OF
CONTENTS AND CONTAINER IN ACCORDANCE WITH LOCAL, REGIONAL, NATIONAL AND
INTERNATIONAL REGULATIONS.
HAZARD(S) NOT OTHERWISE CLASSIFIES (HNOC):
NO ADDITIONAL INFORMATION AVAILABLE
SUPPLEMENTAL INFORMATION: NONE
| SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL NAME SYNONYMS CAS NUMBER %
2,4-DIMETHYLAMINE SALT 2008-39-1 0.253
QUINCLORAC 84087-01-4 0.121
DICAMBA, DIMETHYLAMINE SALT 2300-66-5 0.029
SULFENTRAZONE 122836-35-5 0.0150
| SECTION 4 - FIRST-AID MEASURES | |
INHALATION:
IF BREATHING IS DIFFICULT, REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A
POSITION COMFORTABLE FOR BREATHING. GET MEDICAL ADVICE/ATTENTION IF YOU
FEEL UNWELL.
SKIN CONTACT:
IN CASE OF CONTACT, WASH SKIN WITH PLENTY OF WATER FOR 15 MINUTES. IF SKIN
IRRITATION OR REDNESS DEVELOPS, SEEK MEDICAL ATTENTION.
EYE CONTACT:
IN CASE OF CONTACT, FLUSH EYES WITH PLENTY OF WATER. REMOVE CONTACT LENSES,
IF WORN. IF IRRITATION PERSISTS, GET MEDICAL ATTENTION.
INGESTION:
IF SWALLOWED, DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL
PERSONNEL. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET
MEDICAL ADVICE/ATTENTION.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
SYMPTOMS OF EXPOSURE MAY INCLUDE, IRRITATION OF EYES AND NOSE, COUCH AND/OR
SHORTNESS OF BREATH.
INDICATION OF IMMEDIATE MEDICAL ATTENTION & SPECIAL TREATMENT NEEDED:
IMMEDIATE MEDICAL ATTENTION SHOULD NOT BE REQUIRED.
| SECTION 5 - FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA: TREAT FOR SURROUNDING MATERIAL.
UNSUITABLE EXTINGUISHING MEDIA: NONE KNOWN.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
PRODUCTS OF COMBUSTION MAY INCLUDE, AND ARE NOT LIMITED TO: OXIDES OF
CARBON.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
KEEP UPWIND OF FIRE. WEAR FULL FIRE FIGHTING TURN-OUT GEAR (FULL BUNKER
GEAR) AND RESPIRATOR PROTECTION (SCBA).
| SECTION 6 - ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8. ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
CONTAIN AND/OR ABSORB SPILL WITH INERT MATERIAL. THEN PLACE IN A SUITABLE
CONTAINER. DO NOT FLUSH TO SEWER OR ALLOW TO ENTER WATERWAYS. USE
APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (PPE). SCOOP UP MATERIAL AND
PLACE IN A DISPOSABLE CONTAINER.
ENVIRONMENTAL PRECAUTIONS:
REPORT SPILLS AS REQUIRED BY LOCAL AND NATIONAL REGULATIONS. PREVENT ENTRY
INTO STORM SEWERS AND WATERWAYS.
| SECTION 7 - HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
AVOID BREATHING MIST. AVOID CONTACT WITH SKIN AND EYES. DO NOT SWALLOW.
HANDLE AND OPEN CONTAINER WITH CARE. WHEN USING DO NOT EAT, DRINK OR SMOKE.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
KEEP OUT OF REACH OF CHILDREN. KEEP CONTAINER TIGHTLY CLOSED. (SEE SECTION
10).
| SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION | |
CONTROL PARAMETERS:
EXPOSURE GUIDELINES:
CHEMICAL NAME ACGIH TLV OSHA PEL NIOSH IDLH
2,4-D DIMETHYLAMINE SALT TWA: 10 MG/M3 TWA: 10 MG/M3 IDLH: 10 MG/M3,
2008-39-1 INHALABLE TWA 10 MG/M3
FRACTION
APPROPRIATE ENGINEERING CONTROLS: LOCAL AND GENERAL VENTILATION
INDIVIDUAL PROTECTIVE MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION:
NONE REQUIRED FOR NORMAL USE. AVOID EYE CONTACT.
SKIN AND BODY PROTECTION:
WEAR PROTECTIVE CLOTHING TO AVOID SKIN CONTACT.
RESPIRATORY PROTECTION: NONE REQUIRED UNDER NORMAL USE CONDITIONS.
GENERAL HYGIENE CONSIDERATIONS:
DO NOT EAT, DRINK OR SMOKE WHERE MATERIAL IS HANDLED, PROCESSED OR STORED.
WASH HANDS AFTER HANDLING.
| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE (PHYSICAL STATE,): OPAQUE BROWN LIQUID
ODOR: AMINE TYPE ODOR
ODOR THRESHOLD: NO DATA AVAILABLE
PH: 6.0-10.0
MELTING / FREEZING POINT: NO DATA AVAILABLE
INITIAL BOILING POINT AND RANGE: NO DATA AVAILABLE
FLASHPOINT: NO DATA AVAILABLE
EVAPORATION RATE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS: NO DATA AVAILABLE
VAPOR PRESSURE: NO DATA AVAILABLE
VAPOR DENSITY: NO DATA AVAILABLE
RELATIVE DENSITY: 1.000
SOLUBILITY(IES): NO DATA AVAILABLE
PARTITION COEFFICIENT (N-OCTANOL/WATER): NO DATA AVAILABLE
AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: NO DATA AVAILABLE
| SECTION 10 - STABILITY AND REACTIVITY | |
REACTIVITY: NO DANGEROUS REACTION KNOWN UNDER CONDITIONS OF NORMAL USE.
CHEMICAL STABILITY: STABLE UNDER NORMAL STORAGE CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS:
NO DANGEROUS REACTION KNOWN UNDER CONDITIONS OF NORMAL USE.
CONDITIONS TO AVOID: HEAT. INCOMPATIBLE MATERIALS.
INCOMPATIBLE MATERIALS: NONE KNOWN.
HAZARDOUS DECOMPOSITION PRODUCTS:
MAY INCLUDE, AND ARE NOT LIMITED TO OXIDES OF CARBON.
| SECTION 11 - TOXICOLOGICAL INFORMATION | |
INFORMATION ON THE LIKELY ROUTES OF EXPOSURE:
INHALATION, INGESTION AND/OR SKIN OR EYE CONTACT
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
INHALATION: MAY CAUSE RESPIRATORY TRACT IRRITATION.
INGESTION:
MAY BE HARMFUL IF SWALLOWED. MAY CAUSE STOMACH DISTRESS, NAUSEA OR
VOMITING.
SKIN CONTACT:
MAY CAUSE SKIN IRRITATION. SYMPTOMS MAY INCLUDE REDNESS, DRYING, DEFATTING
AND CRACKING OF THE SKIN.
EYE CONTACT:
MAY CAUSE EYE IRRITATION. SYMPTOMS MAY INCLUDE DISCOMFORT OR PAIN, EXCESS
BLINKING AND TEAR PRODUCTION, WITH POSSIBLE REDNESS AND SWELLING.
ACUTE TOXICITY VALUES:
CALCULATED OVERALL CHEMICAL ACUTE TOXICITY VALUES (ATE):
LD50 (ORAL): >2000 MG/KG
LD50 (DERMAL): >2000 MG/KG
LC50 (INHALATION): >5 MG/L
EYE CONTACT:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
SKIN CONTACT:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
SENSITIZATION: SKIN SENSITIZER
CHRONIC EFFECTS-CARCINOGENICITY:
INGREDIENT CHEMICAL LISTED AS A CARCINOGEN OR POTENTIAL CARCINOGEN (NTP,
IARC, OSHA)
THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC) LISTS CHLOROPHENOXY
HERBICIDES IN ITS GROUP 2B (LIMITED EVIDENCE FOR CARCINOGENICITY IN
HUMANS.) THE US EPA HAS GIVEN THE CHLOROPHENOXY HERBICIDES 2,4-D, 2,4-DP,
MCPP, AND MCPA A CLASS D CLASSIFICATION (NOT CLASSIFIABLE AS TO HUMAN
CARCINOGENICITY.) MORE CURRENT 2,4-D LIFETIME FEEDING STUDIES IN RATS AND
MICE DID NOT SHOW CARCINOGENIC EFFECTS AND A RECENT WORLD HEALTH
ORGANIZATION (WHO) REVIEW OF 2,4-D TOXICOLOGY HAS CONCLUDED THAT 2,4-D IS
NOT A CARCINOGEN.
REPRODUCTIVE TOXICITY:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
GERM CELL MUTAGENICITY:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
STOT-SINGLE EXPOSURE:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
STOT-REPEATED EXPOSURE:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
ASPIRATION HAZARD:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
COMMENT:
ALL INFORMATION WAS GENERATED USING THE GHS CLASSIFICATION CRITERIA FOR
MIXTURES
| SECTION 12 - ECOLOGICAL INFORMATION | |
ECOTOXICITY:
THIS PRODUCT IS NOT EXPECTED TO BE HARMFUL TO AQUATIC ORGANISMS
PERSISTENCE AND DEGRADABILITY: NO DATA AVAILABLE
BIOACCUMULATIVE POTENTIAL: NO DATA AVAILABLE
MOBILITY IN SOIL: NO DATA AVAILABLE
OTHER ADVERSE EFFECTS: NO DATA AVAILABLE
| SECTION 13 - DISPOSAL CONSIDERATIONS | |
DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE,/PROVINCIAL AND FEDERAL
REGULATIONS. FOR MORE
| SECTION 14 - TRANSPORTATION INFORMATION | |
DOT: NOT REGULATED
IATA: NOT REGULATED
IMDG: NOT REGULATED
| SECTION 15 - REGULATORY INFORMATION | |
US EPA LABEL INFORMATION:
EPA PESTICIDE REGISTRATION NUMBER: 9688-337-8845
FEDERAL INSECTICIDE, FUNGICIDE, RODENTICIDE ACT REGULATIONS:
THIS CHEMICAL IS A PESTICIDE PRODUCT REGISTERED BY THE ENVIRONMENTAL
PROTECTION AGENCY AND IS SUBJECTED TO CERTAIN LABELING REQUIREMENTS
UNDER THE FEDERAL PESTICIDE LAW. THESE REQUIREMENTS DIFFER FROM THE
CLASSIFICATION CRITERIA AND HAZARD INFORMATION REQUIRED FOR SAFETY
DATA SHEETS, AND FOR WORKPLACE LABELS OF NON-PESTICIDE CHEMICALS.
FOLLOWING IS THE HAZARD INFORMATION AS REQUIRED ON THE PESTICIDE LABEL:
EPA PESTICIDE LABEL:
CAUTION: KEEP OUT OF REACH OF CHILDREN.
CAUTION:
CAUSES MODERATE EYE IRRITATION. AVOID CONTACT WITH EYES OR CLOTHING.
HARMFUL IF SWALLOWED. WEAR LONG-SLEEVED SHIRT AND LONG PANTS, SHOES PLUS
SOCKS AND GLOVES. WASH THOROUGHLY WITH SOAP AND WATER AFTER HANDLING AND
BEFORE EATING, DRINKING, CHEWING GUM, USING TOBACCO OR USING THE TOILET.
FIRST AID:
IF SWALLOWED:
CALL A POISON CONTROL CENTER OR DOCTOR IMMEDIATE FOR TREATMENT ADVICE. HAVE
A PERSON SIP A GLASS OF WATER IF ABLE TO SWALLOW. DO NOT INDUCE VOMITING
UNLESS TOLD TO BY A POISON CONTROL CENTER OR DOCTOR. DO NOT GIVE ANYTHING
TO AN UNCONSCIOUS PERSON.
IF IN EYES:
HOLD EYES OPEN AND RINSE SLOWLY AND GENTLY WITH WATER FOR 15-20 MINUTES.
REMOVE CONTACT LENSES, IF PRESENT, AFTER THE FIRST 5 MINUTES, THEN CONTINUE
RINSING EYE. CALL A POISON CONTROL CENTER FOR IMMEDIATE ADVICE.
HAVE THE PRODUCT AND CONTAINER OR LABEL WITH YOU WHEN CALLING A POISON
CONTROL CENTER OR DOCTOR, OR GOING FOR TREATMENT. YOU MAY ALSO CONTACT
1-800-917-5438 FOR EMERGENCY MEDICAL TREATMENT ADVICE.
ENVIRONMENTAL HAZARDS:
THIS PESTICIDE IS TOXIC TO FISH AND AQUATIC INVERTEBRATES. DRIFT AND RUNOFF
MAY BE HAZARDOUS TO AQUATIC ORGANISMS IN WATER ADJACENT TO TREATED AREAS.
TO PROTECT THE ENVIRONMENT, DO NOT ALLOW PESTICIDE TO ENTER OR RUN OFF INTO
STORM DRAINS, DRAINAGE DITCHES, GUTTERS OR SURFACE WATERS. APPLYING THIS
PRODUCT IN CLAM WEATHER WHEN RAIN IS NOT PREDICTED FOR THE NEXT 24 HOURS
WILL HELP ENSURE THAT WIND OR RAIN DOES NOT BLOW OR WASH PESTICIDE OFF THE
TREATMENT AREA.
THIS CHEMICAL HAS PROPERTIES AND CHARACTERISTICS ASSOCIATED WITH CHEMICALS
DETECTED IN GROUNDWATER. THE USE OF THIS CHEMICAL IN AREAS WHERE SOILS ARE
PERMEABLE, PARTICULARLY WHERE THE WATER TABLE IS SHALLOW, MAY RESULT IN
GROUNDWATER CONTAMINATION. APPLICATION AROUND A CISTERN OR WELL MAY RESULT
IN CONTAMINATION. OF DRINKING OR GROUNDWATER.
EPA TSCA INVENTORY:
ALL OF THE COMPONENTS OF THIS PRODUCT ARE EITHER ON THE TOXIC SUBSTANCES
CONTROL ACT (TSCA) INVENTORY LIST OR EXEMPT.
CERCLA SECTION 103:
SPILLS OF THIS PRODUCT OVER THE RQ (REPORTABLE QUANTITY) MUST BE REPORTED
TO THE NATIONAL RESPONSE CENTER.
CHEMICAL NAME CHEMICAL RQ CONCENTRATION PRODUCT RQ
& CAS NUMBER (LBS.) IN PRODUCT (LBS.)
SODIUM HYDROXIDE 1,000 <0.01% 10,000,000
CAS # 1310-73-2
DIMETHYL DICAMBA 100 <0.1% 100,000
CAS # 2300-66-5
SARA HAZARD CATEGORY (311/312): SEE OSHA HAZARDS LISTED IN SECTION 2.
SARA 313:
SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION
ACT OF 1986 (SARA). THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS ABOVE THE
DE MINIMIS LEVELS, WHICH ARE SUBJECT TO THE REPORTING REQUIREMENTS OF THE
ACT AND TITLE 40 OF THE CODE OF FEDERAL REGULATIONS, PART 372.
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65):
THIS PRODUCT DOES NOT CONTAIN CHEMICALS REGULATED UNDER CALIFORNIA
PROPOSITION 65.
DISCLAIMER:
INFORMATION CONTAINED HEREIN WAS OBTAINED FROM SOURCES CONSIDERED
TECHNICALLY ACCURATE AND RELIABLE. WHILE EVERY EFFORT HAS BEEN MADE TO
ENSURE FULL DISCLOSURE OF PRODUCT HAZARDS, IN SOME CASES DATA IS NOT
AVAILABLE AND IS SO STATED. SINCE CONDITIONS OF ACTUAL PRODUCT USE ARE
BEYOND CONTROL OF THE SUPPLIER, IT IS ASSUMED THAT USERS OF THIS MATERIAL
HAVE BEEN FULLY TRAINED ACCORDING TO THE REQUIREMENTS OF ALL APPLICABLE
LEGISLATION AND REGULATORY INSTRUMENTS. NO WARRANTY, EXPRESSED OR IMPLIED,
IS MADE AND SUPPLIER WILL NOT BE LIABLE FOR ANY LOSSES, INJURIES OR
CONSEQUENTIAL DAMAGES WHICH MAY RESULT FROM THE USE OF OR RELIANCE ON ANY
INFORMATION CONTAINED IN THIS DOCUMENT.
| SECTION 16 - OTHER INFORMATION | |
ISSUE DATE: APRIL 13, 2018
REVISION DATE: APRIL 13, 2018
VERSION NUMBER: INITIAL