| Common Name: | LOCTITE 242, 24221 |
| Manufacturer: | HENKEL |
| SDS Revision Date: | 6/14/2021 |
| SDS Format: | No Format Specified |
| Item Number(s): | 5A228 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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HENKEL
SAFETY DATA SHEET
REVISION NUMBER: 010.0
ISSUE DATE: 06/14/2021
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: LOCTITE 242
PRODUCT TYPE/USE: ADHESIVE
RESTRICTION OF USE: NONE IDENTIFIED
IDH NUMBER: 135354
ITEM NUMBER: 24221
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: +1 (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
WARNING
CAUSES SKIN AND EYE IRRITATION.
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
HAZARD CLASS HAZARD CATEGORY
SKIN IRRITATION 2
EYE IRRITATION 2B
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE 2
PICTOGRAM(S):
HEALTH HAZARD
EXCLAMATION MARK
PRECAUTIONARY STATEMENTS:
PREVENTION:
DO NOT BREATHE VAPORS, MIST, OR SPRAY. WASH AFFECTED AREA THOROUGHLY AFTER
HANDLING. WEAR PROTECTIVE GLOVES.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING. GET MEDICAL ATTENTION IF
YOU FEEL UNWELL.
IF SKIN IRRITATION OCCURS: GET MEDICAL ATTENTION.
IF EYE IRRITATION PERSISTS:
GET MEDICAL ATTENTION. TAKE OFF CONTAMINATED CLOTHING.
STORAGE: NOT PRESCRIBED
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/
PROVINCIAL AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD
(29 CFR 1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE
UNITED NATIONS GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND
LABELING OF CHEMICALS (GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
OLEIC ACID 5.5EO 9004-96-0 20 - 30
SACCHARIN 81-07-2 1 - 5
SILICA, AMORPHOUS, FUMED, CRYSTAL-FREE 112945-52-5 1 - 5
CUMENE HYDROPEROXIDE 80-15-9 1 - 5
PROPANE-1,2-DIOL 57-55-6 1 - 5
CUMENE 98-82-8 0.1 - 1
TITANIUM DIOXIDE 13463-67-7 0.1 - 1
* EXACT PERCENTAGES MAY VARY OR ARE TRADE SECRET. CONCENTRATION RANGE IS
PROVIDED TO ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION. GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER (USING SOAP, IF AVAILABLE).
REMOVE CONTAMINATED CLOTHING AND FOOTWEAR. WASH CLOTHING BEFORE REUSE.
GET MEDICAL ATTENTION.
EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS, FOR AT
LEAST 15 MINUTES. GET MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL
ATTENTION.
SYMPTOMS: SEE SECTION 11.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
WATER SPRAY (FOG), FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING, SUCH
AS TURN-OUT GEAR. IN CASE OF FIRE, KEEP CONTAINERS COOL WITH WATER SPRAY.
UNUSUAL FIRE OR EXPLOSION HAZARDS:
UNCONTROLLED POLYMERIZATION MAY OCCUR AT HIGH TEMPERATURES RESULTING IN
EXPLOSIONS OR RUPTURE OF STORAGE CONTAINERS.
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF CARBON. OXIDES OF SULFUR. OXIDES OF NITROGEN. IRRITATING ORGANIC
VAPOURS.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS.
CLEAN-UP METHODS:
REMOVE ALL SOURCES OF IGNITION. EVACUATE AND VENTILATE SPILL AREA; DIKE
SPILL TO PREVENT ENTRY INTO WATER SYSTEM; WEAR FULL PROTECTIVE EQUIPMENT
DURING CLEAN-UP. SOAK UP WITH INERT ABSORBENT MATERIAL (E.G. SAND, SILICA
GEL, ACID BINDER, UNIVERSAL BINDER, SAWDUST). SCRAPE UP AS MUCH MATERIAL
AS POSSIBLE. STORE IN A PARTLY FILLED, CLOSED CONTAINER UNTIL DISPOSAL.
REFER TO SECTION 8 "EXPOSURE CONTROLS / PERSONAL PROTECTION" PRIOR TO
CLEAN UP.
| 7. HANDLING AND STORAGE | |
HANDLING:
USE ONLY WITH ADEQUATE VENTILATION. PREVENT CONTACT WITH EYES, SKIN AND
CLOTHING. DO NOT BREATHE VAPOR AND MIST. WASH THOROUGHLY AFTER HANDLING.
KEEP CONTAINER CLOSED. REFER TO SECTION 8.
STORAGE:
FOR SAFE STORAGE, STORE BETWEEN -20 DEG. C (-4 DEG. F) AND 50 DEG. C
(122 DEG. F)
KEEP IN A COOL, WELL VENTILATED AREA AWAY FROM HEAT, SPARKS AND OPEN FLAME.
KEEP CONTAINER TIGHTLY CLOSED UNTIL READY FOR USE.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE
THE NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL AIHA WEEL OTHER
OLEIC ACID 5.5EO NONE NONE NONE NONE
SACCHARIN NONE NONE NONE NONE
SILICA, AMORPHOUS, 10 MG/M3 TWA 20 MPPCF NONE NONE
FUMED, CRYSTAL-FREE INHALABLE DUST. TWA
3 MG/M3 TWA 0.8 MG/M3
RESPIRABLE TWA
FRACTION.
50 MPPCF
3 MG/M3 TWA TWA TOTAL
RESPIRABLE DUST.
PARTICLES.
5 MG/M3
10 MG/M3 TWA TWA
INHALABLE RESPIRABLE
PARTICLES. FRACTION.
15 MG/M3
TWA TOTAL
DUST.
15 MPPCF
TWA
RESPIRABLE
FRACTION.
CUMENE HYDROPEROXIDE NONE NONE 1 PPM NONE
(6 MG/M3)
TWA (SKIN)
PROPANE-1,2-DIOL NONE NONE 10 MG/M3 NONE
TWA
AEROSOL.
CUMENE 5 PPM TWA 50 PPM NONE NONE
(245 MG/M3)
PEL (SKIN)
TITANIUM DIOXIDE 10 MG/M3 TWA 15 MG/M3 NONE NONE
PEL TOTAL
DUST.
15 MPPCF
TWA
RESPIRABLE
FRACTION.
15 MG/M3
TWA TOTAL
DUST.
50 MPPCF
TWA TOTAL
DUST.
5 MG/M3
TWA
RESPIRABLE
FRACTION.
ENGINEERING CONTROLS:
PROVIDE ADEQUATE LOCAL EXHAUST VENTILATION TO MAINTAIN WORKER EXPOSURE
BELOW EXPOSURE LIMITS.
RESPIRATORY PROTECTION:
USE NIOSH APPROVED RESPIRATOR IF THERE IS POTENTIAL TO EXCEED EXPOSURE
LIMIT(S).
EYE/FACE PROTECTION:
SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS. FULL FACE PROTECTION
SHOULD BE USED IF THE POTENTIAL FOR SPLASHING OR SPRAYING OF PRODUCT
EXISTS. SAFETY SHOWERS AND EYE WASH STATIONS SHOULD BE AVAILABLE.
SKIN PROTECTION:
USE CHEMICAL RESISTANT, IMPERMEABLE CLOTHING INCLUDING GLOVES AND EITHER
AN APRON OR BODY SUIT TO PREVENT SKIN CONTACT. NEOPRENE GLOVES. BUTYL
RUBBER GLOVES. NATURAL RUBBER GLOVES.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
COLOR: BLUE
ODOR: MILD
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT APPLICABLE
VAPOR PRESSURE: <5 MM Hg (27 DEG. C (80.6 DEG. F))
BOILING POINT/RANGE: >149 DEG. C (>300.2 DEG. F)
MELTING POINT/ RANGE: NOT AVAILABLE.
SPECIFIC GRAVITY: 1.1 AT 23.9 DEG. C (75.02 DEG. F)
VAPOR DENSITY: NOT AVAILABLE.
FLASH POINT: >93.3 DEG. C (>199.94 DEG. F) TAGLIABUE CLOSED CUP
FLAME PROJECTION: NOT APPLICABLE
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: 2.6 % (PROPYLENE GLYCOL)
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: 12.5 % (PROPYLENE GLYCOL)
AUTOIGNITION TEMPERATURE: NOT DETERMINED
FLAMMABILITY: NOT APPLICABLE
EVAPORATION RATE: NOT AVAILABLE.
SOLUBILITY IN WATER: SLIGHT
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT:
0.56 %; 6.17 G/L (CALIFORNIA SCAQMD METHOD 316B) (ESTIMATED)
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER NORMAL CONDITIONS OF STORAGE AND USE.
HAZARDOUS REACTIONS:
NONE UNDER NORMAL PROCESSING. POLYMERIZATION MAY OCCUR AT ELEVATED
TEMPERATURE OR IN THE PRESENCE OF INCOMPATIBLE MATERIALS.
HAZARDOUS DECOMPOSITION PRODUCTS:
OXIDES OF CARBON. OXIDES OF SULFUR. OXIDES OF NITROGEN. IRRITATING ORGANIC
VAPOURS.
INCOMPATIBLE MATERIALS:
STRONG OXIDIZING AGENTS. FREE RADICAL INITIATORS. STRONG REDUCING AGENTS.
ALKALIS. OXYGEN SCAVENGERS. OTHER POLYMERIZATION INITIATORS. COPPER. IRON.
ZINC. ALUMINUM. RUST.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID:
ELEVATED TEMPERATURES. HEAT, FLAMES, SPARKS AND OTHER SOURCES OF IGNITION.
STORE AWAY FROM INCOMPATIBLE MATERIALS.
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES, INGESTION
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION:
INHALATION OF VAPORS OR MISTS OF THE PRODUCT MAY BE IRRITATING TO THE
RESPIRATORY SYSTEM.
SKIN CONTACT: CAUSES SKIN IRRITATION.
EYE CONTACT: CAUSES EYE IRRITATION.
INGESTION: MAY CAUSE GASTROINTESTINAL TRACT IRRITATION IF SWALLOWED.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED
HEALTH EFFECTS
OLEIC ACID 5.5EO NONE IRRITANT
SACCHARIN ORAL LD50 (MOUSE): NO TARGET ORGANS
17 G/KG
SILICA, AMORPHOUS, NONE NUISANCE DUST
FUMED, CRYSTAL-FREE
CUMENE HYDROPEROXIDE NONE ALLERGEN, CENTRAL NERVOUS
SYSTEM, CORROSIVE,
IRRITANT, MUTAGEN
PROPANE-1,2-DIOL ORAL LD50 (RABBIT): IRRITANT
18 G/KG
ORAL LD50 (MOUSE):
23.9 G/KG
ORAL LD50 (RAT):
30 G/KG
CUMENE ORAL LD50 (RAT): CENTRAL NERVOUS SYSTEM,
2.91 G/KG IRRITANT, LUNG
ORAL LD50 (RAT):
1,400 MG/KG
TITANIUM DIOXIDE INHALATION LC50 IRRITANT, RESPIRATORY,
(RAT, 4 H): SOME EVIDENCE OF
>6.82 MG/L CARCINOGENICITY
INHALATION LC50
(RAT, 4 H):
>2.28 MG/L
INHALATION LC50
(RAT, 4 H):
>3.56 MG/L
HAZARDOUS COMPONENT(S) NTP CARCINOGEN IARC CARCINOGEN OSHA CARCINOGEN
(SPECIFICALLY
REGULATED)
OLEIC ACID 5.5EO NO NO NO
SACCHARIN NO NO NO
SILICA, AMORPHOUS, NO NO NO
FUMED, CRYSTAL-FREE
CUMENE HYDROPEROXIDE NO NO NO
PROPANE-1,2-DIOL NO NO NO
CUMENE REASONABLY GROUP 2B NO
ANTICIPATED
TO BE A HUMAN
CARCINOGEN.
TITANIUM DIOXIDE NO GROUP 2B NO
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE
MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY PACKAGE/
CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME:
RQ, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
HAZARD CLASS OR DIVISION: 9
IDENTIFICATION NUMBER: UN 3082
PACKING GROUP: III
DOT HAZARDOUS SUBSTANCE(S): ALPHA,ALPHA-DIMETHYLBENZYLHYDROPEROXIDE
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME:
RQ, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
HAZARD CLASS OR DIVISION: 9
IDENTIFICATION NUMBER: UN 3082
PACKING GROUP: III
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME:
RQ, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
HAZARD CLASS OR DIVISION: 9
IDENTIFICATION NUMBER: UN 3082
PACKING GROUP: III
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED AS ACTIVE OR ARE EXEMPT FROM LISTING ON THE
TOXIC SUBSTANCES CONTROL ACT (TSCA) INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS.
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH, DELAYED HEALTH
CERCLA/SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS SUBJECT TO THE
REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND
COMMUNITY RIGHT-TO-KNOW ACT OF 1986 (40 CFR 372). SACCHARIN
(CAS# 81-07-2). CUMENE HYDROPEROXIDE (CAS# 80-15-9). CUMENE
(CAS# 98-82-8).
CERCLA REPORTABLE QUANTITY:
CUMENE HYDROPEROXIDE (CAS# 80-15-9) 10 LBS. (4.54 KG)
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE
CANCER. THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA
TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
CONTAINS ONE OR MORE COMPONENTS LISTED ON THE NON-DOMESTIC SUBSTANCES
LIST. ALL OTHER COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON
THE DOMESTIC SUBSTANCES LIST. COMPONENTS LISTED ON THE NDSL MUST BE
TRACKED BY ALL CANADIAN IMPORTERS OF RECORD AS REQUIRED BY ENVIRONMENT
CANADA. THEY MAY BE IMPORTED INTO CANADA IN LIMITED QUANTITIES. PLEASE
CONTACT REGULATORY AFFAIRS FOR ADDITIONAL DETAILS.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: 7, 8, 11, 15
PREPARED BY: PRODUCT SAFETY AND REGULATORY AFFAIRS
ISSUE DATE: 06/14/2021
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS
AFFILIATES ("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS
OBTAINED BY PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS
THE USER'S RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S
PRODUCTS OR ANY PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR
PURPOSE, AND TO ADOPT SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE
PROTECTION OF PROPERTY AND PERSONS AGAINST ANY HAZARDS THAT MAY BE
INVOLVED IN THE HANDLING AND USE OF ANY HENKEL'S PRODUCTS. IN LIGHT
OF THE FOREGOING, HENKEL SPECIFICALLY DISCLAIMS ALL WARRANTIES,
EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY AND
FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE OR USE OF
HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST
PROFITS.
THIS SAFETY DATA SHEET HAS BEEN GENERATED BASED ON OSHA HAZARD
COMMUNICATION STANDARD (29 CFR 1910.1200) AND PROVIDES INFORMATION
IN ACCORDANCE WITH U.S. FEDERAL LAW ONLY. NO WARRANTY OR REPRESENTATION
OF ANY KIND IS GIVEN WITH RESPECT TO THE SUBSTANTIVE OR EXPORT LAWS OF
ANY OTHER JURISDICTION OR COUNTRY. PLEASE CONFIRM THAT THE INFORMATION
PROVIDED HEREIN CONFORMS TO THE SUBSTANTIVE EXPORT OR OTHER LAW OF ANY
OTHER JURISDICTION PRIOR TO EXPORT. PLEASE CONTACT HENKEL PRODUCT SAFETY
AND REGULATORY AFFAIRS FOR ADDITIONAL ASSISTANCE.