| Common Name: | ENAMEL 1-GL 2PK HIGH GLOSS BLACK, 634402 |
| Manufacturer: | RUST-OLEUM |
| SDS Revision Date: | 4/29/2021 |
| SDS Format: | GHS-US |
| Item Number(s): | 5A264 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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DATE PRINTED: 4/29/2021
SAFETY DATA SHEET
RUST-OLEUM CORPORATION
TRUSTED QUALITY SINCE 1921
WWW.RUSTOLEUM.COM
| 1. IDENTIFICATION |  |
PRODUCT NAME: ENAMEL 1-GL 2PK HIGH GLOSS BLACK
PRODUCT IDENTIFIER: 634402
RECOMMENDED USE: TOPCOAT/ALKYD
REVISION DATE: 4/29/2021
SUPERCEDES DATE: 11 /13/2020
SUPPLIER:
RUST-OLEUM CORPORATION
11 HAWTHORN PARKWAY
VERNON HILLS, IL 60061
USA
RUST-OLEUM CANADA (ROCA)
200 CONFEDERATION PARKWAY
CONCORD, ON L4K4T8
CANADA
EMERGENCY PHONE: 800-387-3625
MANUFACTURER:
RUST-OLEUM CORPORATION
11 HAWTHORN PARKWAY
VERNON HILLS, IL 60061
USA
PREPARER: REGULATORY DEPARTMENT
EMERGENCY TELEPHONE:
24 HOUR HOTLINE: 847-367-7700
| 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION:
SYMBOL(S) OF PRODUCT:
FLAME
EXCLAMATION MARK
HEALTH HAZARD
SIGNAL WORD: DANGER
POSSIBLE HAZARDS:
2% OF THE MIXTURE CONSISTS OF INGREDIENT(S) OF UNKNOWN ACUTE TOXICITY.
GHS HAZARD STATEMENTS:
FLAMMABLE LIQUID, CATEGORY 3:
H226: FLAMMABLE LIQUID AND VAPOR.
SKIN SENSITIZER, CATEGORY 1:
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
GERM CELL MUTAGENICITY, CATEGORY 1B:
H340: MAY CAUSE GENETIC DEFECTS.
CARCINOGENICITY, CATEGORY 1B:
H350: MAY CAUSE CANCER.
GHS LABEL PRECAUTIONARY STATEMENTS:
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
P210:
KEEP AWAY FROM HEAT, HOT SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION
SOURCES. NO SMOKING.
P233: KEEP CONTAINER TIGHTLY CLOSED.
P261: AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY.
P272:
CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE.
P280:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
P321: FOR SPECIFIC TREATMENT SEE LABEL.
P405: STORE LOCKED UP.
P501:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL, REGIONAL AND
NATIONAL REGULATIONS.
P302+P352:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
P303+P361+P353:
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
P308+P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
P333+P313:
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
P370+P378:
IN CASE OF FIRE:
USE ALCOHOL FILM FORMING FOAM, CARBON DIOXIDE, DRY CHEMICAL, DRY SAND TO
EXTINGUISH.
P403+P235: STORE IN A WELL-VENTILATED PLACE. KEEP COOL.
GHS SDS PRECAUTIONARY STATEMENTS:
P240: GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT.
P241: USE EXPLOSION-PROOF ELECTRICAL/VENTILATING/LIGHTING/EQUIPMENT.
P242: USE ONLY NON-SPARKING TOOLS.
P243: TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
P363: WASH CONTAMINATED CLOTHING BEFORE REUSE.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS SUBSTANCES:
CHEMICAL NAME CAS-NO. WT.% GHS SYMBOLS GHS STATEMENTS
HYDROTREATED LIGHT 64742-47-8 47 GHS08 H304
DISTILLATE
CARBON BLACK 1333-86-4 2.3 NOT AVAILABLE NOT AVAILABLE
METHYL ETHYL KETOXIME 96-29-7 0.4 GHS05-GHS06- H302-312-317-
GHS07 318-331
NAPHTHA, HYDROTREATED 64742-48-9 0.3 GHS08 H304-340-350
HEAVY
ETHYLBENZENE 100-41-4 0.2 GHS02-GHS07- H225-304-332-
GHS08 373
COBALT 2-ETHYLHEXANOATE 136-52-7 0.2 NOT AVAILABLE NOT AVAILABLE
NAPHTHA, HYDROTREATED 64742-48-9 0.1 GHS08 H304
HEAVY
| 4. FIRST-AID MEASURES | |
FIRST AID - EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES
HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION. DO NOT ALLOW RUBBING OF
EYES OR KEEPING EYES CLOSED.
FIRST AID - SKIN CONTACT:
WASH SKIN WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. GET MEDICAL
ATTENTION IF IRRITATION DEVELOPS OR PERSISTS.
FIRST AID - INHALATION:
REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. GET IMMEDIATE MEDICAL ATTENTION. DO
NOT USE MOUTH-TO-MOUTH RESUSCITATION. IF YOU EXPERIENCE DIFFICULTY IN
BREATHING, LEAVE THE AREA TO OBTAIN FRESH AIR. IF CONTINUED DIFFICULTY IS
EXPERIENCED, GET MEDICAL ASSISTANCE IMMEDIATELY.
FIRST AID - INGESTION: IF SWALLOWED, GET MEDICAL ATTENTION.
| 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
ALCOHOL FILM FORMING FOAM, CARBON DIOXIDE, DRY CHEMICAL, DRY SAND, WATER
FOG
UNUSUAL FIRE AND EXPLOSION HAZARDS:
CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT DUE TO BUILDUP
OF STEAM. KEEP CONTAINERS TIGHTLY CLOSED. COMBUSTIBLE LIQUID AND VAPOR. NO
UNUSUAL FIRE OR EXPLOSION HAZARDS NOTED.
SPECIAL FIREFIGHTING PROCEDURES:
EVACUATE AREA AND FIGHT FIRE FROM A SAFE DISTANCE. USE WATER SPRAY TO KEEP
FIRE-EXPOSED CONTAINERS COOL. CONTAINERS MAY EXPLODE WHEN HEATED.
SPECIAL FIRE AND EXPLOSION HAZARD (COMBUSTIBLE DUST): NO INFORMATION
| 6. ACCIDENTAL RELEASE MEASURES | |
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
REMOVE ALL SOURCES OF IGNITION, VENTILATE AREA AND REMOVE WITH INERT
ABSORBENT AND NON-SPARKING TOOLS. DISPOSE OF ACCORDING TO LOCAL, STATE
(PROVINCIAL) AND FEDERAL REGULATIONS. DO NOT INCINERATE CLOSED CONTAINERS.
| 7. HANDLING AND STORAGE | |
HANDLING:
WASH THOROUGHLY AFTER HANDLING. WASH HANDS BEFORE EATING. REMOVE
CONTAMINATED CLOTHING AND LAUNDER BEFORE REUSE. USE ONLY WITH ADEQUATE
VENTILATION. FOLLOW ALL SDS AND LABEL PRECAUTIONS EVEN AFTER CONTAINER IS
EMPTIED BECAUSE IT MAY RETAIN PRODUCT RESIDUES. AVOID BREATHING FUMES,
VAPORS, OR MIST. AVOID CONTACT WITH EYES, SKIN AND CLOTHING.
STORAGE:
KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT,
SPARKS AND OPEN FLAME. AVOID EXCESS HEAT. STORE IN A DRY, WELL VENTILATED
PLACE. KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE.
ADVICE ON SAFE HANDLING OF COMBUSTIBLE DUST: NO INFORMATION
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
CHEMICAL NAME CAS-NO. WEIGHT % LESS THAN
HYDROTREATED LIGHT DISTILLATE 64742-47-8 50.0
CARBON BLACK 1333-86-4 5.0
METHYL ETHYL KETOXIME 96-29-7 1.0
NAPHTHA, HYDROTREATED HEAVY 64742-48-9 1.0
ETHYLBENZENE 100-41-4 1.0
COBALT 2-ETHYLHEXANOATE 136-52-7 1.0
NAPHTHA, HYDROTREATED HEAVY 64742-48-9 1.0
CHEMICAL NAME ACGIH ACGIH OSHA OSHA
TLV-TWA TLV-STEL PEL-TWA PEL-CEILING
HYDROTREATED LIGHT DISTILLATE N.E. N.E. N.E. N.E.
CARBON BLACK 3 MG/M3 N.E. 3.5 MG/M3 N.E.
METHYL ETHYL KETOXIME 10 PPM N.E. N.E. N.E.
NAPHTHA, HYDROTREATED HEAVY N.E. N.E. N.E. N.E.
ETHYLBENZENE 20 PPM N.E. 100 PPM N.E.
COBALT 2-ETHYLHEXANOATE N.E. N.E. N.E. N.E.
NAPHTHA, HYDROTREATED HEAVY N.E. N.E. N.E. N.E.
PERSONAL PROTECTION:
ENGINEERING CONTROLS:
USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO CONTROL AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS.
PREVENT BUILD-UP OF VAPORS BY OPENING ALL DOORS AND WINDOWS TO ACHIEVE
CROSS-VENTILATION.
RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA 1910.134 AND ANSI Z88.2
REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A
RESPIRATOR'S USE.
SKIN PROTECTION:
USE GLOVES TO PREVENT PROLONGED SKIN CONTACT. NITRILE OR NEOPRENE GLOVES
MAY AFFORD ADEQUATE SKIN PROTECTION.
EYE PROTECTION:
USE SAFETY EYEWEAR DESIGNED TO PROTECT AGAINST SPLASH OF LIQUIDS.
OTHER PROTECTIVE EQUIPMENT:
REFER TO SAFETY SUPERVISOR OR INDUSTRIAL HYGIENIST FOR FURTHER GUIDANCE
REGARDING TYPES OF PERSONAL PROTECTIVE EQUIPMENT AND THEIR APPLICATIONS.
HYGIENIC PRACTICES:
WASH THOROUGHLY WITH SOAP AND WATER BEFORE EATING, DRINKING OR SMOKING.
REMOVE CONTAMINATED CLOTHING IMMEDIATELY AND LAUNDER BEFORE REUSE.
ENGINEERING MEASURES FOR COMBUSTIBLE DUST: NO INFORMATION
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: LIQUID
PHYSICAL STATE: LIQUID
ODOR: SOLVENT LIKE
ODOR THRESHOLD: N.E.
SPECIFIC GRAVITY: 0.912
PH: N.A.
FREEZE POINT, DEG. C: N.D.
VISCOSITY: N.D.
SOLUBILITY IN WATER: NEGLIGIBLE
PARTITION COEFFICIENT, N-OCTANOL/WATER: N.D.
DECOMPOSITION TEMP., DEG. C: N.D.
BOILING RANGE, DEG. C: 136 - 3,000
EXPLOSIVE LIMITS, VOL%: 0.5 - 6.6
FLAMMABILITY: SUPPORTS COMBUSTION
FLASH POINT, DEG. C: 42
EVAPORATION RATE: SLOWER THAN ETHER
AUTO-IGNITION TEMP., DEG. C: N.D.
VAPOR DENSITY: HEAVIER THAN AIR
VAPOR PRESSURE: N.D.
(SEE "OTHER INFORMATION" SECTION FOR ABBREVIATION LEGEND)
| 10. STABILITY AND REACTIVITY | |
CONDITIONS TO AVOID: NO INFORMATION
INCOMPATIBILITY:
INCOMPATIBLE WITH STRONG OXIDIZING AGENTS, STRONG ACIDS AND STRONG
ALKALIES.
HAZARDOUS DECOMPOSITION:
WHEN HEATED TO DECOMPOSITION, IT EMITS ACRID SMOKE AND IRRITATING FUMES.
CONTAINS SOLVENTS WHICH MAY FORM CARBON MONOXIDE, CARBON DIOXIDE, AND
FORMALDEHYDE.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR UNDER NORMAL CONDITIONS.
STABILITY: THIS PRODUCT IS STABLE UNDER NORMAL STORAGE CONDITIONS.
| 11. TOXICOLOGICAL INFORMATION | |
EFFECTS OF OVEREXPOSURE - EYE CONTACT:
SUBSTANCE CAUSES MODERATE EYE IRRITATION.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT:
SUBSTANCE MAY CAUSE SLIGHT SKIN IRRITATION.
EFFECTS OF OVEREXPOSURE - INHALATION:
HIGH GAS, VAPOR, MIST OR DUST CONCENTRATIONS MAY BE HARMFUL IF INHALED.
AVOID BREATHING FUMES, SPRAY, VAPORS, OR MIST. HIGH VAPOR CONCENTRATIONS
ARE IRRITATING TO THE EYES, NOSE, THROAT AND LUNGS. PROLONGED OR EXCESSIVE
INHALATION MAY CAUSE RESPIRATORY TRACT IRRITATION.
EFFECTS OF OVEREXPOSURE - INGESTION:
IRRITATING TO THE NOSE, THROAT AND RESPIRATORY TRACT. HARMFUL IF SWALLOWED.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS:
REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OCCUPATIONAL OVEREXPOSURE
TO SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. CONTAINS
CARBON BLACK. CHRONIC INFLAMMATION, LUNG FIBROSIS, AND LUNG TUMORS HAVE
BEEN OBSERVED IN SOME RATS EXPERIMENTALLY EXPOSED FOR LONG PERIODS OF TIME
TO EXCESSIVE CONCENTRATIONS OF CARBON BLACK AND SEVERAL INSOLUBLE FINE DUST
PARTICLES. TUMORS HAVE NOT BEEN OBSERVED IN OTHER ANIMAL SPECIES
(I.E., MOUSE AND HAMSTER) UNDER SIMILAR CIRCUMSTANCES AND STUDY CONDITIONS.
EPIDEMIOLOGICAL STUDIES OF NORTH AMERICAN WORKERS SHOW NO EVIDENCE OF
CLINICALLY SIGNIFICANT ADVERSE HEALTH EFFECTS DUE TO OCCUPATIONAL EXPOSURE
TO CARBON BLACK.
CARBON BLACK IS LISTED AS A GROUP 2B-"POSSIBLY CARCINOGENIC TO HUMANS" BY
IARC AND IS PROPOSED TO BE LISTED AS A4- "NOT CLASSIFIED AS A HUMAN
CARCINOGEN" BY THE AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL
HYGIENISTS. SIGNIFICANT EXPOSURE IS NOT ANTICIPATED DURING BRUSH
APPLICATION OR DRYING. RISK OF OVEREXPOSURE DEPENDS ON DURATION AND LEVEL
OF EXPOSURE TO DUST FROM REPEATED SANDING OF SURFACES OR SPRAY MIST AND
THE ACTUAL CONCENTRATION OF CARBON BLACK IN THE FORMULA. IARC LISTS
ETHYLBENZENE AS A POSSIBLE HUMAN CARCINOGEN (GROUP 2B).
PRIMARY ROUTE(S) OF ENTRY:
EYE CONTACT, INGESTION, INHALATION, SKIN ABSORPTION, SKIN CONTACT
ACUTE TOXICITY VALUES:
THE ACUTE EFFECTS OF THIS PRODUCT HAVE NOT BEEN TESTED. DATA ON INDIVIDUAL
COMPONENTS ARE TABULATED BELOW:
CAS-NO. CHEMICAL NAME ORAL LD50 DERMAL LD50 VAPOR LC50
64742-47-8 HYDROTREATED LIGHT >5000 MG/KG >2000 MG/KG >5000 MG/L
DISTILLATE RAT RABBIT RAT
1333-86-4 CARBON BLACK >15400 MG/KG N.E. N.E.
RAT
96-29-7 METHYL ETHYL 930 MG/KG 1100 MG/KG >4.83 MG/L
KETOXIME RAT RABBIT RAT
64742-48-9 NAPHTHA, >6000 MG/KG >5000 MG/KG N.E.
HYDROTREATED HEAVY RAT RABBIT
100-41-4 ETHYLBENZENE 3500 MG/KG 15400 MG/KG 17.4 MG/L
RAT RABBIT RAT
136-52-7 COBALT N.E. >5000 MG/KG N.E.
2-ETHYLHEXANOATE RABBIT
64742-48-9 NAPHTHA, >6000 MG/KG >5000 MG/KG N.E.
HYDROTREATED HEAVY RAT RABBIT
N.E. - NOT ESTABLISHED
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: PRODUCT IS A MIXTURE OF LISTED COMPONENTS.
| 13. DISPOSAL INFORMATION | |
DISPOSAL INFORMATION:
DISPOSE OF MATERIAL IN ACCORDANCE TO LOCAL, STATE, AND FEDERAL REGULATIONS
AND ORDINANCES. DO NOT INCINERATE CLOSED CONTAINERS.
| 14. TRANSPORT INFORMATION | |
DOMESTIC INTERNATIONAL AIR (IATA) TDG (CANADA)
(USDOT) (IMDG)
UN NUMBER N.A. 1263 1263 N.A.
PROPER SHIPPING NOT REGULATED PAINT PAINT NOT REGULATED
NAME
HAZARD CLASS N.A. 3 3 N.A.
PACKING GROUP N.A. III III N.A.
LIMITED QUANTITY NO YES, >5L NO YES, >5L NO NO
| 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
CERCLA - SARA HAZARD CATEGORY:
THIS PRODUCT HAS BEEN REVIEWED ACCORDING TO THE EPA 'HAZARD CATEGORIES'
PROMULGATED UNDER SECTIONS 311 AND 312 OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 (SARA TITLE III) AND IS CONSIDERED, UNDER
APPLICABLE DEFINITIONS, TO MEET THE FOLLOWING CATEGORIES:
FLAMMABLE (GASES, AEROSOLS, LIQUIDS, OR SOLIDS), CARCINOGENICITY,
RESPIRATORY OR SKIN SENSITIZATION, GERM CELL MUTAGENICITY
SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372:
CHEMICAL NAME CAS-NO.
ETHYLBENZENE 100-41-4
COBALT 2-ETHYLHEXANOATE 136-52-7
TOXIC SUBSTANCES CONTROL ACT:
THIS PRODUCT CONTAINS THE FOLLOWING CHEMICAL SUBSTANCES SUBJECT TO THE
REPORTING REQUIREMENTS OF TSCA 12(B) IF EXPORTED FROM THE UNITED STATES:
NO TSCA 12(B) COMPONENTS EXIST IN THIS PRODUCT.
U.S. STATE REGULATIONS:
CALIFORNIA PROPOSITION 65:
WARNING: CANCER AND REPRODUCTIVE HARM - WWW.P65WARNINGS.CA.GOV.
| 16. OTHER INFORMATION | |
HMIS RATINGS:
HEALTH 2*
FLAMMABILITY 2
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA RATINGS:
HEALTH 2
FLAMMABILITY 2
INSTABILITY 0
VOLATILE ORGANIC COMPOUNDS: 448 G/L
SDS REVISION DATE: 4/29/2021
REASON FOR REVISION:
SUBSTANCE AND/OR PRODUCT PROPERTIES CHANGED IN SECTION(S):
03 - COMPOSITION / INFORMATION ON INGREDIENTS
11 - TOXICOLOGICAL INFORMATION
REVISION STATEMENT(S) CHANGED
LEGEND:
N.A. - NOT APPLICABLE
N.D. - NOT DETERMINED
N.E. - NOT ESTABLISHED
THE MANUFACTURER BELIEVES, TO THE BEST OF ITS KNOWLEDGE, INFORMATION AND
BELIEF, THE INFORMATION CONTAINED HEREIN TO BE ACCURATE AND RELIABLE AS
OF THE DATE OF THIS SAFETY DATA SHEET. HOWEVER, BECAUSE THE CONDITIONS OF
HANDLING, USE, AND STORAGE OF THESE MATERIALS ARE BEYOND OUR CONTROL, WE
ASSUME NO RESPONSIBILITY OR LIABILITY FOR PERSONAL INJURY OR PROPERTY
DAMAGE INCURRED BY THE USE OF THESE MATERIALS. THE MANUFACTURER MAKES NO
WAMANTY, EXPRESSED OR IMPLIED, REGARDING THE ACCURACY OR RELIABILITY OF
THE DATA OR RESULTS OBTAINED FROM THEIR USE. ALL MATERIALS MAY PRESENT
UNKNOWN HAZARDS AND SHOULD BE USED WITH CAUTION. THE INFORMATION AND
RECOMMENDATIONS IN THIS MATERIAL SAFETY DATA SHEET ARE OFFERED FOR THE
USERS' CONSIDERATION AND EXAMINATION. IT IS THE RESPONSIBILITY OF THE USER
TO DETERMINE THE FINAL SUITABILITY OF THIS INFORMATION AND TO COMPLY WITH
ALL APPLICABLE INTERNATIONAL, FEDERAL, STATE, AND LOCAL LAWS AND
REGULATIONS.
7400 SYSTEM DTM ALKYD ENAMEL