| Common Name: | DEVCON FLEXANE 80 PUTTY, FLEXA NE 80 PUTTY RESIN |
| Manufacturer: | ITW POLYMERS ADHESIVES, NORTH AMERICA |
| SDS Revision Date: | 7/30/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 5A459, 65KU70 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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DEVCON(R*)
KIT - SAFETY DATA SHEET
PRODUCT IDENTIFIER USED ON THE LABEL:
KIT NAME: DEVCON(R*) FLEXANE(R*) 80 PUTTY
STOCK NO.: 15820
OTHER MEANS OF IDENTIFICATION:
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
CHEMICAL MANUFACTURER ADDRESS AND TELEPHONE NUMBER:
MANUFACTURER NAME: ITW POLYMERS ADHESIVES, NORTH AMERICA
ADDRESS:
30 ENDICOTT STREET
DANVERS, MA 01923
GENERAL PHONE NUMBER: (978) 777-1100
EMERGENCY PHONE NUMBER:
EMERGENCY PHONE NUMBER: (800) 424-9300
CHEMTREC:
FOR EMERGENCIES IN THE US, CALL CHEMTREC: 800-424-9300
COMPONENT LIST:
COMPONENT A: FLEXANE 80 PUTTY CURING AGENT
COMPONENT B: FLEXANE 80 PUTTY RESIN
KIT SDS REVISION DATE: 07/30/2015
COMPONENT A - SDS
| SECTION 1: IDENTIFICATION |  |
PRODUCT IDENTIFIER USED ON THE LABEL:
PRODUCT NAME: FLEXANE 80 PUTTY CURING AGENT
OTHER MEANS OF IDENTIFICATION:
SYNONYMS: NONE.
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
PRODUCT USE/RESTRICTION: NOT APPLICABLE.
CHEMICAL MANUFACTURER ADDRESS AND TELEPHONE NUMBER:
MANUFACTURER NAME: ITW
ADDRESS:
30 ENDICOTT STREET
DANVERS, MA 01923
GENERAL PHONE NUMBER: (978) 777-1100
EMERGENCY PHONE NUMBER:
EMERGENCY PHONE NUMBER: (800) 424-9300
CHEMTREC:
FOR EMERGENCIES IN THE US, CALL CHEMTREC: 800-424-9300
| SECTION 2: HAZARD(S) IDENTIFICATION | |
CLASSIFICATION OF THE CHEMICAL IN ACCORDANCE WITH CFR 1910.1200(D)(F):
GHS PICTOGRAMS:
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: WARNING.
GHS CLASS:
SPECIFIC TARGET ORGAN TOXICITY - STOT REPEATED EXPOSURE RE. CATEGORY 2
(ORAL, LIVER, KIDNEY, AND PANCREAS).
EYE IRRITATION. CATEGORY 2.
ACUTE ORAL TOXICITY. CATEGORY 4.
HAZARD STATEMENTS:
H373: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
H319: CAUSES SERIOUS EYE IRRITATION.
H302: HARMFUL IF SWALLOWED.
PRECAUTIONARY STATEMENTS:
P260: DO NOT BREATHE DUST/FUME/GAS/MIST/VAPOURS/SPRAY.
P264: WASH HANDS THOROUGHLY AFTER HANDLING.
P270: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
P280:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
P301+P312:
IF SWALLOWED: CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
P314: GET MEDICAL ADVICE/ATTENTION IF YOU FEEL UNWELL.
P330: RINSE MOUTH.
P337+P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
P501:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL, STATE, FEDERAL AND
PROVINCIAL REGULATIONS.
HAZARDS NOT OTHERWISE CLASSIFIED THAT HAVE BEEN IDENTIFIED DURING THE
CLASSIFICATION PROCESS:
DIETHYLTOLUENEDIAMINE:
SIGNS/SYMPTOMS:
SYMPTOMS OF INGESTION MAY INCLUDE ABDOMINAL PAIN, NAUSEA, VOMITING, AND
DIARRHEA. CAUSES SERIOUS EYE IRRITATION WITH SYMPTOMS OF REDDENING, TEARING,
SWELLING, AND BURNING. INHALATION, SKIN ABSORPTION, OR INGESTION MAY CAUSE
METHEMOGLOBIN FORMATION RESULTING IN A REDUCED ABILITY OF THE BLOOD TO CARRY
OXYGEN; A SYMPTOM OF THIS MAY BE CYANOSIS (PURPLISH-BLUE COLORING OF SKIN,
FINGERNAILS, AND LIPS).
ROUTE OF EXPOSURE: EYES. SKIN. INHALATION. INGESTION.
POTENTIAL HEALTH EFFECTS:
EYE:
CAN CAUSE SEVERE EYE IRRITATION AND BURNS. EYE CONTACT MAY CAUSE PERMANENT
DAMAGE OR BLINDNESS.
SKIN: CAUSES SEVERE SKIN IRRITATION. MAY CAUSE PERMANENT SKIN DAMAGE.
INHALATION: VAPOR OR MIST MAY CAUSE SEVERE RESPIRATORY SYSTEM IRRITATION.
INGESTION:
CAUSES IRRITATION, A BURNING SENSATION OF THE MOUTH, THROAT AND
GASTROINTESTINAL TRACT AND ABDOMINAL PAIN.
CHRONIC HEALTH EFFECTS:
PROLONGED SKIN CONTACT MAY LEAD TO BURNING ASSOCIATED WITH SEVERE REDDENING,
SWELLING, AND POSSIBLE TISSUE DESTRUCTION.
SIGNS/SYMPTOMS:
OVEREXPOSURE MAY CAUSE EYE WATERING OR DISCOMFORT, REDNESS AND SWELLING.
TARGET ORGANS: EYES. SKIN. RESPIRATORY SYSTEM. DIGESTIVE SYSTEM.
AGGRAVATION OF PRE-EXISTING CONDITIONS:
MAY AGGRAVATE PRE-EXISTING RESPIRATORY DISORDERS, ALLERGY, ECZEMA, OR SKIN
CONDITIONS.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
MIXTURES:
CHEMICAL NAME CAS# INGREDIENT PERCENT EC NUM.
DIPROPYLENE GLYCOL DIBENZOATE 27138-31-4 40 - 50 BY WEIGHT
EPOXIDIZED SOYBEAN OIL 8013-07-8 1 - 10 BY WEIGHT
DIETHYLTOLUENEDIAMINE 68479-98-1 30 - 40 BY WEIGHT
DIPROPYLENE GLYCOL MONOBENZOATE 32686-95-6 1 - 10 BY WEIGHT
CARBON BLACK 1333-86-4 1 - 10 BY WEIGHT
PROPENYL PROPYL BENZOATE 197178-94-2 1 - 10 BY WEIGHT
PROPYLENE GLYCOL DIBENZOATE 19224-26-1 1 - 10 BY WEIGHT
| SECTION 4: FIRST AID MEASURES | |
DESCRIPTION OF NECESSARY MEASURES:
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 TO 20 MINUTES.
ENSURE ADEQUATE FLUSHING OF THE EYES BY SEPARATING THE EYELIDS WITH FINGERS.
GET IMMEDIATE MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY WASH SKIN WITH PLENTY OF SOAP AND WATER FOR 15 TO 20 MINUTES,
WHILE REMOVING CONTAMINATED CLOTHING AND SHOES.
GET MEDICAL ATTENTION IF IRRITATION DEVELOPS OR PERSISTS.
INHALATION:
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
RESPIRATION OR GIVE OXYGEN BY TRAINED PERSONNEL. SEEK IMMEDIATE MEDICAL
ATTENTION.
INGESTION:
IF SWALLOWED, DO NOT INDUCE VOMITING. CALL A PHYSICIAN OR POISON CONTROL
CENTER IMMEDIATELY. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
OTHER FIRST AID:
SYMPTOMS OF INGESTION MAY INCLUDE ABDOMINAL PAIN, NAUSEA, VOMITING, AND
DIARRHEA. CAUSES SERIOUS EYE IRRITATION WITH SYMPTOMS OF REDDENING, TEARING,
SWELLING, AND BURNING. INHALATION, SKIN ABSORPTION, OR INGESTION MAY CAUSE
METHEMOGLOBIN FORMATION RESULTING IN A REDUCED ABILITY OF THE BLOOD TO CARRY
OXYGEN; A SYMPTOM OF THIS MAY BE CYANOSIS (PURPLISH-BLUE COLORING OF SKIN,
FINGERNAILS, AND LIPS).
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
NOTE TO PHYSICIANS:
IMMEDIATELY GIVE OXYGEN IF VICTIM TURNS BLUE (LIPS, EARS, FINGERNAILS).
SINCE REVERSION OF METHAEMOGLOBIN TO HAEMOGLOBIN OCCURS SPONTANEOUSLY AFTER
TERMINATION OF EXPOSURE, MODERATE DEGREES OF CYANOSIS NEED TO BE TREATED
ONLY BY SUPPORTIVE MEASURES.
| SECTION 5: FIRE FIGHTING MEASURES | |
SUITABLE AND UNSUITABLE EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE CARBON DIOXIDE (CO2) OR DRY CHEMICAL WHEN FIGHTING FIRES INVOLVING THIS
MATERIAL.
UNSUITABLE EXTINGUISHING MEDIA: WATER OR FOAM MAY CAUSE FROTHING.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE-FIGHTERS:
PROTECTIVE EQUIPMENT:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS (SCBA), MSHA/NIOSH
(APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR.
FIRE FIGHTING INSTRUCTIONS:
EVACUATE AREA OF UNPROTECTED PERSONNEL. USE COLD WATER SPRAY TO COOL FIRE
EXPOSED CONTAINERS TO MINIMIZE RISK OF RUPTURE. DO NOT ENTER CONFINED FIRE
SPACE WITHOUT FULL PROTECTIVE GEAR. IF POSSIBLE, CONTAIN FIRE RUN-OFF WATER.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
EVACUATE AREA AND KEEP UNNECESSARY AND UNPROTECTED PERSONNEL FROM ENTERING
THE SPILL AREA.
ENVIRONMENTAL PRECAUTIONS:
ENVIRONMENTAL PRECAUTIONS:
AVOID RUNOFF INTO STORM SEWERS, DITCHES, AND WATERWAYS.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SPILL CLEANUP MEASURES:
ABSORB SPILL WITH INERT MATERIAL (E,G., DRY SAND OR EARTH), THEN PLACE IN
A CHEMICAL WASTE CONTAINER. PROVIDE VENTILATION. CLEAN UP SPILLS IMMEDIATELY
OBSERVING PRECAUTIONS IN THE PROTECTIVE EQUIPMENT SECTION. AFTER REMOVAL,
FLUSH SPILL AREA WITH SOAP AND WATER TO REMOVE TRACE RESIDUE.
AVOID PERSONAL CONTACT AND BREATHING VAPORS OR MISTS. VENTILATE AREA. USE
PROPER PERSONAL PROTECTIVE EQUIPMENT AS LISTED IN SECTION 8.
REFERENCE TO OTHER SECTIONS:
OTHER PRECAUTIONS: PUMP OR SHOVEL TO STORAGE/SALVAGE VESSELS.
| SECTION 7: HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
HANDLING:
USE WITH ADEQUATE VENTILATION. AVOID BREATHING VAPOR, AEROSOL OR MIST.
HYGIENE PRACTICES: WASH THOROUGHLY AFTER HANDLING.
SPECIAL HANDLING PROCEDURES:
PROVIDE APPROPRIATE VENTILATION/RESPIRATORY PROTECTION AGAINST DECOMPOSITION
PRODUCTS (SEE SECTION 10) DURING WELDING/FLAME CUTTING OPERATIONS AND TO
PROTECT AGAINST DUST DURING SANDING/GRINDING OF CURED PRODUCT.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE:
STORE IN A COOL, DRY, WELL VENTILATED AREA AWAY FROM SOURCES OF HEAT AND
INCOMPATIBLE MATERIALS. KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE. DO
NOT STORE IN REACTIVE METAL CONTAINERS. KEEP AWAY FROM ACIDS, OXIDIZERS.
| SECTION 8: EXPOSURE CONTROLS, PERSONAL PROTECTION | |
EXPOSURE GUIDELINES:
DIETHYLTOLUENEDIAMINE:
GUIDELINE TYPE: MANUFACTURER RECOMMENDED OCCUPATIONAL EXPOSURE LIMIT
GUIDELINE INFO:
OEL-TWA: 2 PPM
CARBON BLACK:
GUIDELINE ACGIH:
TLV-TWA: 3 MG/M3 INHALABLE FRACTION (I)
APPROPRIATE ENGINEERING CONTROLS:
ENGINEERING CONTROLS:
USE APPROPRIATE ENGINEERING CONTROL SUCH AS PROCESS ENCLOSURES, LOCAL
EXHAUST VENTILATION, OR OTHER ENGINEERING CONTROLS TO CONTROL AIRBORNE
LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. GOOD GENERAL VENTILATION SHOULD BE
SUFFICIENT TO CONTROL AIRBORNE LEVELS. WHERE SUCH SYSTEMS ARE NOT EFFECTIVE
WEAR SUITABLE PERSONAL PROTECTIVE EQUIPMENT, WHICH PERFORMS SATISFACTORILY
AND MEETS OSHA OR OTHER RECOGNIZED STANDARDS. CONSULT WITH LOCAL PROCEDURES
FOR SELECTION, TRAINING, INSPECTION AND MAINTENANCE OF THE PERSONAL
PROTECTIVE EQUIPMENT.
INDIVIDUAL PROTECTION MEASURES:
EYE/FACE PROTECTION:
WEAR APPROPRIATE PROTECTIVE GLASSES OR SPLASH GOGGLES AS DESCRIBED BY
29 CFR 1910.133, OSHA EYE AND FACE PROTECTION REGULATION, OR THE EUROPEAN
STANDARD EN 166.
SKIN PROTECTION DESCRIPTION:
WEAR APPROPRIATE PROTECTIVE GLOVES AND OTHER PROTECTIVE APPAREL TO PREVENT
SKIN CONTACT. CONSULT MANUFACTURER'S DATA FOR PERMEABILITY DATA.
RESPIRATORY PROTECTION:
A NIOSH APPROVED AIR-PURIFYING RESPIRATOR WITH AN ORGANIC VAPOR CARTRIDGE
OR CANISTER MAY BE PERMISSIBLE UNDER CERTAIN CIRCUMSTANCES WHERE AIRBORNE
CONCENTRATIONS ARE EXPECTED TO EXCEED EXPOSURE LIMITS. PROTECTION PROVIDED
BY AIR PURIFYING RESPIRATORS IS LIMITED. USE A POSITIVE PRESSURE AIR
SUPPLIED RESPIRATOR IF THERE IS ANY POTENTIAL FOR AN UNCONTROLLED RELEASE,
EXPOSURE LEVELS ARE NOT KNOWN, OR ANY OTHER CIRCUMSTANCES WHERE AIR
PURIFYING RESPIRATORS MAY NOT PROVIDE ADEQUATE PROTECTION.
OTHER PROTECTIVE:
FACILITIES STORING OR UTILIZING THIS MATERIAL SHOULD BE EQUIPPED WITH AN
EYEWASH AND A DELUGE SHOWER SAFETY STATION.
NOTES: ONLY ESTABLISHED PEL AND TLV VALUES FOR THE INGREDIENTS ARE LISTED.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE APPEARANCE: LIQUID.
COLOR: MOBILE BLACK..
ODOR: MILD AMMONIA LIKE.
BOILING POINT: >450 DEG. F (232.2 DEG. C)
MELTING POINT: NOT DETERMINED.
SPECIFIC GRAVITY: 1.08
SOLUBILITY: NEGLIGIBLE.
VAPOR DENSITY: >1 (AIR = 1)
VAPOR PRESSURE: <1 MMHg @ 70 DEG. F
PERCENT VOLATILE: 0
EVAPORATION RATE: <<1 (BUTYL ACETATE = 1)
PH: 7-8 @ 5 PERCENT SOLUTION
MOLECULAR FORMULA: MIXTURE
MOLECULAR WEIGHT: MIXTURE
FLASH POINT: >275 DEG. F (135 DEG. C)
FLASH POINT METHOD: TAG CLOSED CUP. (TCC)
LOWER FLAMMABLE/EXPLOSIVE LIMIT: NOT DETERMINED.
UPPER FLAMMABLE/EXPLOSIVE LIMIT: NOT DETERMINED.
AUTO IGNITION TEMPERATURE: NOT DETERMINED.
VOC CONTENT: 0 G/L
9.2. OTHER INFORMATION:
PERCENT SOLIDS BY WEIGHT: 100
| SECTION 10: STABILITY AND REACTIVITY | |
CHEMICAL STABILITY:
CHEMICAL STABILITY: STABLE UNDER NORMAL TEMPERATURES AND PRESSURES.
POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION: NOT REPORTED.
CONDITIONS TO AVOID:
CONDITIONS TO AVOID:
EXTREME HEAT, SPARKS, AND OPEN FLAME. INCOMPATIBLE MATERIALS, OXIDIZERS AND
OXIDIZING CONDITIONS.
INCOMPATIBLE MATERIALS:
INCOMPATIBLE MATERIALS:
OXIDIZERS, ACIDS, AND CHLORINATED ORGANIC COMPOUNDS. REACTIVE METALS
(E.G. SODIUM, CALCIUM, ZINC). SODIUM/CALCIUM HYPOCHLORITE. NITROUS
ACID/OXIDE, NITRITES. PEROXIDES. MATERIALS REACTIVE WITH HYDROXYL COMPOUNDS.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
TOXICOLOGICAL INFORMATION:
DIOROPYLENE GLYCOL DIBENZOATE:
SKIN:
ADMINISTRATION ONTO THE SKIN - RAT LD50 - LETHAL DOSE, 50 PERCENT KILL:
>2000 MG/KG [DETAILS OF TOXIC EFFECTS NOT REPORTED OTHER THAN LETHAL DOSE
VALUE] (RTECS)
INGESTION:
ORAL - RAT LD50 - LETHAL DOSE, 50 PERCENT KILL:
3295 MG/KG [BRAIN AND COVERINGS - OTHER DEGENERATIVE CHANGES
CARDIAC - CARDIOMYOPATHY INCLUDING INFARCTION LIVER - OTHER CHANGES] (RTECS)
EPOXIDIZED SOYBEAN OIL:
SKIN:
ADMINISTRATION ONTO THE SKIN - RABBIT LD50 - LETHAL DOSE, 50 PERCENT KILL:
>20 ML/KG [DETAILS OF TOXIC EFFECTS NOT REPORTED OTHER THAN LETHAL DOSE
VALUE] (RTECS)
INGESTION:
ORAL - RAT LD50 - LETHAL DOSE, 50 PERCENT KILL:
40 GM/KG [DETAILS OF TOXIC EFFECTS NOT REPORTED OTHER THAN LETHAL DOSE
VALUE]
ORAL - RAT LD50 - LETHAL DOSE, 50 PERCENT KILL:
22500 UL/KG [DETAILS OF TOXIC EFFECTS NOT REPORTED OTHER THAN LETHAL DOSE
VALUE] (RTECS)
DIETHYLTOLUENEDIAMINE:
INGESTION:
ORAL - RAT LD50 - LETHAL DOSE, 50 PERCENT KILL:
472 MG/KG [SENSE ORGANS AND SPECIAL SENSES (EYE) - LACRIMATION
BEHAVIORAL - SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) MUSCULOSKELETAL - OTHER
CHANGES] (RTECS)
CARBON BLACK:
SKIN:
ADMINISTRATION ONTO THE SKIN - RABBIT LD50 - LETHAL DOSE, 50 PERCENT KILL:
>3 GM/KG [DETAILS OF TOXIC EFFECTS NOT REPORTED OTHER THAN LETHAL DOSE
VALUE] (RTECS)
INGESTION:
ORAL - RAT LD50 - LETHAL DOSE, 50 PERCENT KILL:
>15400 MG/KG [BEHAVIORAL - SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)] (RTECS)
CHRONIC EFFECTS:
THIS PRODUCT CONTAINS CARBON BLACK, WHICH IS CLASSIFIED AS A POSSIBLE
CARCINOGEN BY THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC).
ALTHOUGH NORMAL APPLICATION PROCEDURES FOR THIS PRODUCT POSE MINIMAL HAZARD
AS TO THE RELEASE OF CARBON BLACK DUST, GRINDING OR SANDING CURED PRODUCT
MAY GENERATE RESPIRABLE CARBON BLACK.
CARCINOGENICITY:
CARBON BLACK AND ITS EXTRACTS HAVE BEEN TESTED FOR CARCINOGENICITY IN RATS
AND MICE BY INHALATION AND IT HAS SHOWN SUFFICIENT EVIDENCE IN LABORATORY
ANIMALS FOR THE CARCINOGENICITY OF CARBON BLACK.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICITY:
ECOTOXICITY: NO ECOTOXICITY DATA WAS FOUND FOR THE PRODUCT.
ENVIRONMENTAL FATE: NO ENVIRONMENTAL INFORMATION FOUND FOR THIS PRODUCT.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
DESCRIPTION OF WASTE:
WASTE DISPOSAL:
CONSULT WITH THE US EPA GUIDELINES LISTED IN 40 CFR PART 261.3 FOR THE
CLASSIFICATIONS OF HAZARDOUS WASTE PRIOR TO DISPOSAL. FURTHERMORE, CONSULT
WITH YOUR STATE AND LOCAL WASTE REQUIREMENTS OR GUIDELINES, IF APPLICABLE,
TO ENSURE COMPLIANCE. ARRANGE DISPOSAL IN ACCORDANCE TO THE EPA AND/OR STATE
AND LOCAL GUIDELINES.
RCRA NUMBER: NOT DETERMINED.
| SECTION 14: TRANSPORT INFORMATION | |
DOT SHIPPING NAME: REFER TO BILL OF LADING
DOT UN NUMBER: REFER TO BILL OF LADING
IATA SHIPPING NAME: REFER TO BILL OF LADING
IATA UN NUMBER: REFER TO BILL OF LADING
IMDG UN NUMBER: REFER TO BILL OF LADING
IMDG SHIPPING NAME: REFER TO BILL OF LADING
| SECTION 15: REGULATORY INFORMATION | |
SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS SPECIFIC FOR THE PRODUCT:
DIPROPYLENE GLYCOL DIBENZOATE:
TSCA INVENTORY STATUS: LISTED
CANADA DSL: LISTED
EPOXIDIZED SOYBEAN OIL:
TSCA INVENTORY STATUS: LISTED
CANADA DSL: LISTED
DIETHYLTOLUENEDIAMINE:
TSCA INVENTORY STATUS: LISTED
CANADA DSL: LISTED
CARBON BLACK:
TSCA INVENTORY STATUS: LISTED
CALIFORNIA PROP 65:
LISTED: CANCER.
CANADA DSL: LISTED
PROPYLENE GLYCOL DIBENZOATE:
TSCA INVENTORY STATUS: LISTED
CANADIAN REGULATIONS.:
WHMIS HAZARD CLASS(ES): D2B; D2A
ALL COMPONENTS OF THIS PRODUCT ARE ON THE CANADIAN DOMESTIC SUBSTANCES LIST.
WHMIS PICTOGRAMS: D2 - MATERIALS CAUSING OTHER TOXIC EFFECTS
| SECTION 16: ADDITIONAL INFORMATION | |
HMIS RATINGS:
HMIS HEALTH HAZARD 2*
HMIS FIRE HAZARD 1
HMIS REACTIVITY 0
HMIS PERSONAL PROTECTION X
HEALTH HAZARD 2*
FIRE HAZARD 1
REACTIVITY 0
PERSONAL PROTECTION X
* CHRONIC HEALTH EFFECTS
SDS REVISION DATE: MARCH 17, 2015
MSDS REVISION NOTES: GHS UPDATE
SDS FORMAT: IN ACCORDANCE TO OSHA GHS 1910.1200
MSDS AUTHOR: ACTIO CORPORATION
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. ITW POLYMERS ADHESIVES, NA, MAKES NO WARRANTIES,
EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF
PERFORMANCE OR USAGE OF TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER
THE ITW POLYMERS ADHESIVES, NA PRODUCT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION. GIVEN THE VARIETY OF
FACTORS THAT CAN AFFECT THE USE AND APPLICATION OF A ITW POLYMERS ADHESIVES,
NA PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S KNOWLEDGE AND
CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE ITW POLYMERS ADHESIVES,
NA PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION. ITW POLYMERS ADHESIVES,
NA PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED
IN ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, ITW POLYMERS
ADHESIVES, NA MAKES NO REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY.
IN ADDITION, INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS
THE INFORMATION IN THE MSDS AVAILABLE DIRECTLY FROM ITW POLYMERS ADHESIVES,
NA
COPYRIGHT(C) 1996-2015 ACTIO CORPORATION. ALL RIGHTS RESERVED.
COMPONENT B - SDS
| SECTION 1: IDENTIFICATION | |
PRODUCT IDENTIFIER USED ON THE LABEL:
PRODUCT NAME: FLEXANE 80 PUTTY RESIN
OTHER MEANS OF IDENTIFICATION:
SYNONYMS: NONE.
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
PRODUCT USE/RESTRICTION: NOT APPLICABLE.
CHEMICAL MANUFACTURER ADDRESS AND TELEPHONE NUMBER:
MANUFACTURER NAME: ITW
ADDRESS:
30 ENDICOTT STREET
DANVERS, MA 01923
GENERAL PHONE NUMBER: (978) 777-1100
EMERGENCY PHONE NUMBER:
EMERGENCY PHONE NUMBER: (800) 424-9300
CHEMTREC:
FOR EMERGENCIES IN THE US, CALL CHEMTREC: 800-424-9300
| SECTION 2: HAZARD(S) IDENTIFICATION | |
CLASSIFICATION OF THE CHEMICAL IN ACCORDANCE WITH CFR 1910.1200(D)(F):
GHS PICTOGRAMS:
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER.
GHS CLASS:
RESPIRATORY SENSITISATION. CATEGORY 1.
SPECIFIC TARGET ORGAN TOXICITY - STOT REPEATED EXPOSURE RE. CATEGORY 2
(INHALATION, RESPIRATORY SYSTEM).
EYE IRRITATION. CATEGORY 2.
SKIN IRRITATION. CATEGORY 2.
SKIN SENSITIZATION. CATEGORY 1.
ACUTE INHALATION TOXICITY. CATEGORY 4.
SPECIFIC TARGET ORGAN TOXICITY - STOT, SINGLE EXPOSURE SE. CATEGORY 3.
HAZARD STATEMENTS:
H334:
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
H373: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
H319: CAUSES SERIOUS EYE IRRITATION.
H315: CAUSES SKIN IRRITATION.
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
H332: HARMFUL IF INHALED.
H335: MAY CAUSE RESPIRATORY IRRITATION.
PRECAUTIONARY STATEMENTS:
P260: DO NOT BREATHE DUST/FUME/GAS/MIST/VAPOURS/SPRAY.
P261: AVOID BREATHING DUST/FUME/GAS/MIST/VAPOURS/SPRAY.
P264: WASH HANDS THOROUGHLY AFTER HANDLING.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P272: CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE.
P280:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
P284: IN CASE OF INADEQUATE VENTILATION WEAR RESPIRATORY PROTECTION.
P302+P352:
IF ON SKIN: WASH WITH PLENTY OF WATER.
P304+P340:
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING.
P305+P351 + P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
P312: CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
P314: GET MEDICAL ADVICE/ATTENTION IF YOU FEEL UNWELL.
P321: SPECIFIC TREATMENT (SEE... ON THIS LABEL).
P332+P313:
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
P333+P313:
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
P337+P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
P342+P311:
IF EXPERIENCING RESPIRATORY SYMPTOMS:
CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
P362+P364: TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
P403+P233: STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
P405: STORE LOCKED UP.
P501:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL, STATE, FEDERAL AND
PROVINCIAL REGULATIONS.
HAZARDS NOT OTHERWISE CLASSIFIED THAT HAVE BEEN IDENTIFIED DURING THE
CLASSIFICATION PROCESS:
ROUTE OF EXPOSURE: EYES. SKIN. INHALATION. INGESTION.
POTENTIAL HEALTH EFFECTS:
EYE:
CAN CAUSE MODERATE IRRITATION, BURNING SENSATION, TEARING, REDNESS, AND
SWELLING. OVEREXPOSURE MAY CAUSE LACRIMATION, CONJUNCTIVITIS, CORNEAL DAMAGE
AND PERMANENT INJURY.
SKIN:
CAN CAUSE SKIN IRRITATION; ITCHING, REDNESS, RASHES, HIVES, BURNING, AND
SWELLING. ALLERGIC REACTIONS ARE POSSIBLE. MAY CAUSE SKIN SENSITIZATION, AN
ALLERGIC REACTION, WHICH BECOMES EVIDENT ON REEXPOSURE TO THIS MATERIAL.
INHALATION:
RESPIRATORY TRACT IRRITANT. HIGH CONCENTRATION MAY CAUSE DIZZINESS,
HEADACHE, AND ANESTHETIC EFFECTS. MAY CAUSE RESPIRATORY SENSITIZATION WITH
ASTHMA-LIKE SYMPTOMS IN SUSCEPTIBLE INDIVIDUALS.
INGESTION:
CAUSES IRRITATION, A BURNING SENSATION OF THE MOUTH, THROAT AND
GASTROINTESTINAL TRACT AND ABDOMINAL PAIN.
CHRONIC HEALTH EFFECTS:
PROLONGED SKIN CONTACT MAY LEAD TO BURNING ASSOCIATED WITH SEVERE REDDENING,
SWELLING, AND POSSIBLE TISSUE DESTRUCTION.
SIGNS/SYMPTOMS:
OVEREXPOSURE CAN CAUSE HEADACHES, DIZZINESS, NAUSEA, AND VOMITING.
TARGET ORGANS: EYES. SKIN. RESPIRATORY SYSTEM. DIGESTIVE SYSTEM.
AGGRAVATION OF PRE-EXISTING CONDITIONS:
INDIVIDUALS WITH PRE-EXISTING SKIN DISORDERS, ASTHMA, ALLERGIES OR KNOWN
SENSITIZATION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THIS PRODUCT.
ISOCYANATE EXPOSURE LEVELS MUST BE MONITORED. MEDICAL SUPERVISION OF ALL
EMPLOYEES WHO HANDLE OR COME IN CONTACT WITH ISOCYANATES IS RECOMMENDED
(I.E. FEV, FVC). THIS SHOULD INCLUDE PRE-EMPLOYMENT AND PERIODIC MEDICAL
EXAMINATIONS.
PERSONS WITH ASTHMATIC-TYPE CONDITIONS, CHRONIC BRONCHITIS, OTHER CHRONIC
RESPIRATORY DISEASES, RECURRENT SKIN ECZEMA OR SENSITIZATION SHOULD BE
EXCLUDED FROM WORKING WITH THIS PRODUCT. ONCE SENSITIZED NO FURTHER EXPOSURE
CAN BE PERMITTED.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
MIXTURES:
CHEMICAL NAME CAS# INGREDIENT PERCENT EC NUM.
POLYETHER POLYOL 25791-96-2 60 - 70 BY WEIGHT
DIPHENYLMETHANE DIISOCYANATE 26447-40-5 1 - 10 BY WEIGHT
DICYCLOHEXYLMETHANE- 5124-30-1 20 - 30 BY WEIGHT
4,4'-DIISOCYANATE
HIGHER OLIGIMERS OF METHANE 9016-87-9 1 - 10 BY WEIGHT
DIISOCYANATE (MDI)
4,4'-DIPHENYLMETHANE 101-68-8 1 - 10 BY WEIGHT
DIISOCYANATE
PROPRIETARY INGREDIENT(S) TRADE SECRET 0.1 - 1.0 BY WEIGHT
| SECTION 4: FIRST AID MEASURES | |
DESCRIPTION OF NECESSARY MEASURES:
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 TO 20 MINUTES.
ENSURE ADEQUATE FLUSHING OF THE EYES BY SEPARATING THE EYELIDS WITH FINGERS.
GET IMMEDIATE MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY WASH SKIN WITH PLENTY OF SOAP AND WATER FOR 15 TO 20 MINUTES,
WHILE REMOVING CONTAMINATED CLOTHING AND SHOES.
GET MEDICAL ATTENTION IF IRRITATION DEVELOPS OR PERSISTS.
INHALATION:
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
RESPIRATION OR GIVE OXYGEN BY TRAINED PERSONNEL. SEEK IMMEDIATE MEDICAL
ATTENTION.
INGESTION:
IF SWALLOWED, DO NOT INDUCE VOMITING. CALL A PHYSICIAN OR POISON CONTROL
CENTER IMMEDIATELY. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
NOTE TO PHYSICIANS:
ASTHMATIC TYPE SYMPTOMS MAY DEVELOP, WHICH MAY BE IMMEDIATE OR DELAYED FOR
SEVERAL HOURS.
| SECTION 5: FIRE FIGHTING MEASURES | |
SUITABLE AND UNSUITABLE EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE CARBON DIOXIDE (CO2) OR DRY CHEMICAL WHEN FIGHTING FIRES INVOLVING THIS
MATERIAL.
UNSUITABLE EXTINGUISHING MEDIA: WATER MAY CAUSE FROTHING.
UNUSUAL FIRE HAZARDS:
DO NOT RESEAL CONTAINERS IF CONTAMINATED WITH WATER, RESIN WILL REACT WITH
WATER TO RELEASE CARBON DIOXIDE. AS A RESULT OF THE WATER CONTAMINATION,
PRESSURE WILL BUILD UP IN THE SEALED CONTAINER CAUSING IT TO RUPTURE.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE-FIGHTERS:
PROTECTIVE EQUIPMENT:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS (SCBA), MSHA/NIOSH
(APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR.
FIRE FIGHTING INSTRUCTIONS:
EVACUATE AREA OF UNPROTECTED PERSONNEL. USE COLD WATER SPRAY TO COOL FIRE
EXPOSED CONTAINERS TO MINIMIZE RISK OF RUPTURE. DO NOT ENTER CONFINED FIRE
SPACE WITHOUT FULL PROTECTIVE GEAR. IF POSSIBLE, CONTAIN FIRE RUN-OFF WATER.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
EVACUATE AREA AND KEEP UNNECESSARY AND UNPROTECTED PERSONNEL FROM ENTERING
THE SPILL AREA.
ENVIRONMENTAL PRECAUTIONS:
ENVIRONMENTAL PRECAUTIONS:
AVOID RUNOFF INTO STORM SEWERS, DITCHES, AND WATERWAYS.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SPILL CLEANUP MEASURES:
ABSORB SPILL WITH INERT MATERIAL (E,G., DRY SAND OR EARTH), THEN PLACE IN
A CHEMICAL WASTE CONTAINER. PROVIDE VENTILATION. CLEAN UP SPILLS IMMEDIATELY
OBSERVING PRECAUTIONS IN THE PROTECTIVE EQUIPMENT SECTION. NEUTRALIZE
RESIDUE WITH APPROPRIATE NEUTRALIZER. DO NOT ATTEMPT TO NEUTRALIZE LARGE
QUANTITIES OF MATERIAL UNLESS MEASURES TO CONTROL REACTIVITY AND HEAT
GENERATION HAVE BEEN TAKEN. AFTER REMOVAL, FLUSH SPILL AREA WITH SOAP AND
WATER TO REMOVE TRACE RESIDUE.
AVOID PERSONAL CONTACT AND BREATHING VAPORS OR MISTS. VENTILATE AREA. USE
PROPER PERSONAL PROTECTIVE EQUIPMENT AS LISTED IN SECTION 8.
A BLANKET OF PROTEIN FOAM MAY BE PLACED OVER SPILL FOR TEMPORARY CONTROL OF
ISOCYANATE VAPOR.
REFERENCE TO OTHER SECTIONS:
OTHER PRECAUTIONS:
PUMP LARGE QUANTITIES INTO CLOSED BUT NOT SEALED METAL CONTAINERS.
ISOCYANATES WILL REACT WITH WATER AND GENERATE CARBON DIOXIDE, THIS COULD
RESULT IN THE RUPTURE OF ANY CLOSED CONTAINERS.
NEUTRALIZE USING 10 PARTS NEUTRALIZER TO 1 PART ISOCYANATE SOLUTION. MIX
AND ALLOW TO STAND FOR 48 HRS IN CONTAINERS, LETTING EVOLVED CARBON DIOXIDE
TO VENT. NEUTRALIZER CONSIST OF 90% WATER, 3-8% CONCENTRATED AMMONIA
(OR SODIUM CARBONATE), 2% DETERGENT.
| SECTION 7: HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
HANDLING:
USE WITH ADEQUATE VENTILATION. AVOID BREATHING VAPOR, AEROSOL OR MIST.
HYGIENE PRACTICES: WASH THOROUGHLY AFTER HANDLING.
SPECIAL HANDLING PROCEDURES:
PROVIDE APPROPRIATE VENTILATION/RESPIRATORY PROTECTION AGAINST DECOMPOSITION
PRODUCTS (SEE SECTION 10) DURING WELDING/FLAME CUTTING OPERATIONS AND TO
PROTECT AGAINST DUST DURING SANDING/GRINDING OF CURED PRODUCT.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE:
STORE IN A COOL, DRY, WELL VENTILATED AREA AWAY FROM SOURCES OF HEAT AND
INCOMPATIBLE MATERIALS. KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE. DO
NOT RESEAL CONTAINER IF MOISTURE OR WATER CONTAMINATION IS SUSPECTED. WATER
CONTAMINATED MATERIAL IN A SEALED CONTAINER MAY RUPTURE DUE TO PRESSURE
BUILDUP.
| SECTION 8: EXPOSURE CONTROLS, PERSONAL PROTECTION | |
EXPOSURE GUIDELINES:
DICYCLOHEXYLMETHANE-4,4'-DIISOCYANATE:
GUIDELINE ACGIH:
TLV-TWA: 0.005 PPM
4,4'-DIPHENYLMETHANE DIISOCYANATE:
GUIDELINE ACGIH:
TLV-TWA: 0.005 PPM
GUIDELINE OSHA:
PEL-CEILING/PEAK: 0.02 PPM
APPROPRIATE ENGINEERING CONTROLS:
ENGINEERING CONTROLS:
USE APPROPRIATE ENGINEERING CONTROL SUCH AS PROCESS ENCLOSURES, LOCAL
EXHAUST VENTILATION, OR OTHER ENGINEERING CONTROLS TO CONTROL AIRBORNE
LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. GOOD GENERAL VENTILATION SHOULD BE
SUFFICIENT TO CONTROL AIRBORNE LEVELS. WHERE SUCH SYSTEMS ARE NOT EFFECTIVE
WEAR SUITABLE PERSONAL PROTECTIVE EQUIPMENT, WHICH PERFORMS SATISFACTORILY
AND MEETS OSHA OR OTHER RECOGNIZED STANDARDS. CONSULT WITH LOCAL PROCEDURES
FOR SELECTION, TRAINING, INSPECTION AND MAINTENANCE OF THE PERSONAL
PROTECTIVE EQUIPMENT.
INDIVIDUAL PROTECTION MEASURES:
EYE/FACE PROTECTION:
WEAR APPROPRIATE PROTECTIVE GLASSES OR SPLASH GOGGLES AS DESCRIBED BY
29 CFR 1910.133, OSHA EYE AND FACE PROTECTION REGULATION, OR THE EUROPEAN
STANDARD EN 166.
SKIN PROTECTION DESCRIPTION:
WEAR APPROPRIATE PROTECTIVE GLOVES AND OTHER PROTECTIVE APPAREL TO PREVENT
SKIN CONTACT. CONSULT MANUFACTURER'S DATA FOR PERMEABILITY DATA.
RESPIRATORY PROTECTION:
A NIOSH APPROVED AIR-PURIFYING RESPIRATOR WITH AN ORGANIC VAPOR CARTRIDGE
OR CANISTER MAY BE PERMISSIBLE UNDER CERTAIN CIRCUMSTANCES WHERE AIRBORNE
CONCENTRATIONS ARE EXPECTED TO EXCEED EXPOSURE LIMITS. PROTECTION PROVIDED
BY AIR PURIFYING RESPIRATORS IS LIMITED. USE A POSITIVE PRESSURE AIR
SUPPLIED RESPIRATOR IF THERE IS ANY POTENTIAL FOR AN UNCONTROLLED RELEASE,
EXPOSURE LEVELS ARE NOT KNOWN, OR ANY OTHER CIRCUMSTANCES WHERE AIR
PURIFYING RESPIRATORS MAY NOT PROVIDE ADEQUATE PROTECTION.
OTHER PROTECTIVE:
FACILITIES STORING OR UTILIZING THIS MATERIAL SHOULD BE EQUIPPED WITH AN
EYEWASH AND A DELUGE SHOWER SAFETY STATION.
NOTES: ONLY ESTABLISHED PEL AND TLV VALUES FOR THE INGREDIENTS ARE LISTED.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE APPEARANCE: LIQUID
COLOR: CLEAR
ODOR: SLIGHTLY MUSTY.
BOILING POINT: >400 DEG. F (204.4 DEG. C)
MELTING POINT: NOT DETERMINED.
SPECIFIC GRAVITY: 1.1 @ 77 DEG. F
SOLUBILITY: INSOLUBLE.
VAPOR DENSITY: 8.5 MDI (AIR = 1)
VAPOR PRESSURE: <10 MMHg @ 77 DEG. F (MDI)
PERCENT VOLATILE: 0
EVAPORATION RATE: NOT DETERMINED.
PH: NOT DETERMINED.
MOLECULAR FORMULA: MIXTURE
MOLECULAR WEIGHT: MIXTURE
FLASH POINT: 453 DEG. F (233.8 DEG. C)
FLASH POINT METHOD: PENSKY-MARTENS CLOSED CUP
LOWER FLAMMABLE/EXPLOSIVE LIMIT: NOT DETERMINED.
UPPER FLAMMABLE/EXPLOSIVE LIMIT: NOT DETERMINED.
AUTO IGNITION TEMPERATURE: NOT DETERMINED.
VOC CONTENT: 0 G/L
9.2. OTHER INFORMATION:
PERCENT SOLIDS BY WEIGHT: 100
| SECTION 10: STABILITY AND REACTIVITY | |
CHEMICAL STABILITY:
CHEMICAL STABILITY: STABLE UNDER NORMAL TEMPERATURES AND PRESSURES.
POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION: POLYMERIZATION MAY OCCUR UNDER CERTAIN CONDITIONS.
CONDITIONS TO AVOID:
CONDITIONS TO AVOID:
EXTREME HEAT, SPARKS, AND OPEN FLAME. INCOMPATIBLE MATERIALS, OXIDIZERS AND
OXIDIZING CONDITIONS. MOISTURE AND EXTENDED EXPOSURE OVER 85 F.
INCOMPATIBLE MATERIALS:
INCOMPATIBLE MATERIALS:
ALCOHOLS, AMINES, STRONG BASES (ALKALI, AMMONIA), ACIDS, METAL COMPOUNDS,
MOISTURE OR WATER. RESIN REACTS WITH WATER TO GIVE OFF CARBON DIOXIDE.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
TOXICOLOGICAL INFORMATION:
POLYETHER POLYOL:
SKIN:
ADMINISTRATION ONTO THE SKIN - RABBIT LD50 - LETHAL DOSE, 50 PERCENT KILL:
>20 ML/KG [DETAILS OF TOXIC EFFECTS NOT REPORTED OTHER THAN LETHAL DOSE
VALUE]
ADMINISTRATION ONTO THE SKIN - RABBIT LD50 - LETHAL DOSE, 50 PERCENT KILL:
>16 ML/KG [DETAILS OF TOXIC EFFECTS NOT REPORTED OTHER THAN LETHAL DOSE
VALUE] (RTECS)
INGESTION:
ORAL - RAT LD50 - LETHAL DOSE, 50 PERCENT KILL:
>64 ML/KG [DETAILS OF TOXIC EFFECTS NOT REPORTED OTHER THAN LETHAL DOSE
VALUE]
ORAL - RAT LD50 - LETHAL DOSE, 50 PERCENT KILL:
2830 UL/KG [DETAILS OF TOXIC EFFECTS NOT REPORTED OTHER THAN LETHAL DOSE
VALUE] (RTECS)
DICYCLOHEXYLMETHANE-4,4'-DIISOCYANATE:
EYE:
ADMINISTRATION INTO THE EYE - RABBIT STANDARD DRAIZE TEST: 100 UL [MILD]
ADMINISTRATION INTO THE EYE - RABBIT STANDARD DRAIZE TEST:
100 UL/24H [SEVERE] (RTECS)
INGESTION:
ORAL - RAT LD50 - LETHAL DOSE, 50 PERCENT KILL:
9900 MG/KG [BEHAVIORAL - FOOD INTAKE (ANIMAL) GASTROINTESTINAL -
HYPERMOTILITY, DIARRHEA LIVER - OTHER CHANGES] (RTECS)
HIGHER OLIGIMERS OF METHANE DIISOCYANATE (MDI):
EYE:
ADMINISTRATION INTO THE EYE - RABBIT STANDARD DRAIZE TEST:
100 MG [MILD] (RTECS)
SKIN:
ADMINISTRATION ONTO THE SKIN - RABBIT LD50 - LETHAL DOSE, 50 PERCENT KILL:
>9400 MG/KG [DETAILS OF TOXIC EFFECTS NOT REPORTED OTHER THAN LETHAL DOSE
VALUE] (RTECS)
INHALATION:
INHALATION - RAT LC50 - LETHAL CONCENTRATION, 50 PERCENT KILL:
490 MG/M3/4H [SENSE ORGANS AND SPECIAL SENSES (EYE) - EFFECT, NOT OTHERWISE
SPECIFIED LUNGS, THORAX, OR RESPIRATION - RESPIRATORY DEPRESSION BLOOD -
HEMORRHAGE] (RTECS)
INGESTION:
ORAL - RAT LD50 - LETHAL DOSE, 50 PERCENT KILL:
49 GM/KG [BEHAVIORAL - SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)
GASTROINTESTINAL - HYPERMOTILITY, DIARRHEA NUTRITIONAL AND GROSS
METABOLIC - BODY TEMPERATURE DECREASE] (RTECS)
4,4-DIPHENYLMETHANE DIISOCYANATE:
EYE:
ADMINISTRATION INTO THE EYE - RABBIT STANDARD DRAIZE TEST:
100 MG [MODERATE] (RTECS)
INHALATION:
INHALATION - RAT LC50 - LETHAL CONCENTRATION, 50 PERCENT KILL:
178 MG/M3 [DETAILS OF TOXIC EFFECTS NOT REPORTED OTHER THAN LETHAL DOSE
VALUE] (RTECS)
INGESTION:
ORAL - RAT LD50 - LETHAL DOSE, 50 PERCENT KILL:
9200 MG/KG [BEHAVIORAL - SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)
BEHAVIORAL - ATAXIA NUTRITIONAL AND GROSS METABOLIC - BODY TEMPERATURE
DECREASE] (RTECS)
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICITY:
ECOTOXICITY: NO ECOTOXICITY DATA WAS FOUND FOR THE PRODUCT.
ENVIRONMENTAL FATE: NO ENVIRONMENTAL INFORMATION FOUND FOR THIS PRODUCT.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
DESCRIPTION OF WASTE:
WASTE DISPOSAL:
CONSULT WITH THE US EPA GUIDELINES LISTED IN 40 CFR PART 261.3 FOR THE
CLASSIFICATIONS OF HAZARDOUS WASTE PRIOR TO DISPOSAL. FURTHERMORE, CONSULT
WITH YOUR STATE AND LOCAL WASTE REQUIREMENTS OR GUIDELINES, IF APPLICABLE,
TO ENSURE COMPLIANCE. ARRANGE DISPOSAL IN ACCORDANCE TO THE EPA AND/OR STATE
AND LOCAL GUIDELINES.
RCRA NUMBER: NOT DETERMINED.
| SECTION 14: TRANSPORT INFORMATION | |
DOT SHIPPING NAME: REFER TO BILL OF LADING
DOT UN NUMBER: REFER TO BILL OF LADING
IATA SHIPPING NAME: REFER TO BILL OF LADING
IATA UN NUMBER: REFER TO BILL OF LADING
IMDG UN NUMBER: REFER TO BILL OF LADING
IMDG SHIPPING NAME: REFER TO BILL OF LADING
| SECTION 15: REGULATORY INFORMATION | |
SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS SPECIFIC FOR THE PRODUCT:
POLYETHER POLYOL:
TSCA INVENTORY STATUS: LISTED
CANADA DSL: LISTED
DIPHENYLMETHANE DIISOCYANATE:
TSCA INVENTORY STATUS: LISTED
CANADA DSL: LISTED
DICYCLOHEXYLMETHANE-4,4'-DIISOCYANATE:
TSCA INVENTORY STATUS: LISTED
SECTION 313:
EPCRA - 40 CFR PART 372 - (SARA TITLE III) SECTION 313 LISTED CHEMICAL.
CANADA DSL: LISTED
HIGHER OLIGIMERS OF METHANE DIISOCYANATE (MDI):
TSCA INVENTORY STATUS: LISTED
SECTION 313:
EPCRA - 40 CFR PART 372 - (SARA TITLE III) SECTION 313 LISTED CHEMICAL.
CANADA DSL: LISTED
4,4'-DIPHENYLMETHANE DIISOCTANATE:
TSCA INVENTORY STATUS: LISTED
SECTION 313:
EPCRA - 40 CFR PART 372 - (SARA TITLE III) SECTION 313 LISTED CHEMICAL.
CANADA DSL: LISTED
CANADIAN REGULATIONS:
WHMIS HAZARD CLASS(ES): D2A; D2B
ALL COMPONENTS OF THIS PRODUCT ARE ON THE CANADIAN DOMESTIC SUBSTANCES LIST.
WHMIS PICTOGRAMS: D2 - MATERIALS CAUSING OTHER TOXIC EFFECTS
| SECTION 16: ADDITIONAL INFORMATION | |
HMIS RATINGS:
HMIS HEALTH HAZARD 3*
HMIS FIRE HAZARD 1
HMIS REACTIVITY 1
HMIS PERSONAL PROTECTION X
HEALTH HAZARD 3*
FIRE HAZARD 1
REACTIVITY 1
PERSONAL PROTECTION X
* CHRONIC HEALTH EFFECTS
SDS REVISION DATE: MARCH 17, 2015
MSDS REVISION NOTES: GHS UPDATE
SDS FORMAT: IN ACCORDANCE TO OSHA GHS 1910.1200
MSDS AUTHOR: ACTIO CORPORATION
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. ITW POLYMERS ADHESIVES, NA, MAKES NO WARRANTIES,
EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF
PERFORMANCE OR USAGE OF TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER
THE ITW POLYMERS ADHESIVES, NA PRODUCT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION. GIVEN THE VARIETY OF
FACTORS THAT CAN AFFECT THE USE AND APPLICATION OF A ITW POLYMERS ADHESIVES,
NA PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S KNOWLEDGE AND
CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE ITW POLYMERS ADHESIVES,
NA PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION. ITW POLYMERS ADHESIVES,
NA PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED
IN ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, ITW POLYMERS
ADHESIVES, NA MAKES NO REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY.
IN ADDITION, INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS
THE INFORMATION IN THE MSDS AVAILABLE DIRECTLY FROM ITW POLYMERS ADHESIVES,
NA
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