SDS Table of Contents Click the desired link below to jump directly to that section in the SDS. SUPERCOOL(TM) TRUSTED BY PROFESSIONALS 24278 R-134A REFRIGERANT PLUS SAFETY DATA SHEET ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26, 2012 / RULES AND REGULATIONS DATE OF ISSUE: 05/05/2016 REVISION DATE: 05/05/2016 SUPERSEDES: 11/12/2014 VERSION: 4.2
1.1. IDENTIFICATION: PRODUCT FORM: MIXTURE TRADE NAME: 24278 R-134A REFRIGERANT PLUS CAS NO: 811-97-2 PRODUCT CODE: 24278 1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED AGAINST: USE OF THE SUBSTANCE/MIXTURE: REFRIGERANT PLUS IS USED AS AN R-134A REFRIGERANT CHARGE AND LEAK STOP IN R-134A REFRIGERATION SYSTEMS. USE OF THE SUBSTANCE/MIXTURE: REFRIGERANT GAS 1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET: TIRE SEAL, INC. 3574 CORONA STREET LAKE WORTH, FLORIDA 33461 USA T: 561-582-2245 F: 561-582-1499 WWW.SUPERCOOL.AC 1.4. EMERGENCY TELEPHONE NUMBER: EMERGENCY NUMBER: USA PHONE: 1-800-373-7542 INT'L: 1-484-951-2432 DGA/AAG ENVIRONMENTAL CONTRACT: DGA4000-048
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE: GHS-US CLASSIFICATION: NOT CLASSIFIED 2.2. LABEL ELEMENTS: GHS-US LABELING: HAZARD PICTOGRAMS (GHS-US): GHS04: GAS CYLINDER GHS08: HEALTH HAZARD SIGNAL WORD (GHS-US): WARNING HAZARD STATEMENTS (GHS-US): H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED H281: CONTAINS REFRIGERATED GAS; MAY CAUSE CRYOGENIC BURNS OR INJURY H302: HARMFUL IF SWALLOWED H312: HARMFUL IN CONTACT WITH SKIN PRECAUTIONARY STATEMENTS (GHS-US): P412: DO NOT EXPOSE TO TEMPERATURES EXCEEDING 50 DEG. C / 122 DEG. F 2.3. OTHER HAZARDS: OTHER HAZARDS NOT CONTRIBUTING TO THE CLASSIFICATION: CONTAINS GAS UNDER PRESSURE; MAY BURST IF HEATED. 2.4. UNKNOWN ACUTE TOXICITY (GHS US): NOT APPLICABLE
3.1. SUBSTANCE: NOT APPLICABLE 3.2. MIXTURE: NAME PRODUCT IDENTIFIER % GHS-US CLASSIFICATION 1,1,1,2- (CAS NO): 811-97-2 80 - 90 NOT CLASSIFIED TETRAFLUOROETHANE (MAIN CONSTITUENT) 1,2-BENZENE- (CAS NO): 68515-49-1 10 - 13 ACUTE TOX. 4 (ORAL), DICARBOXYLIC ACID H302 DIC9-11 BRANCHED ALKYLESTERS, ACUTE TOX. 4 C10 RICH (DERMAL), H312 FULL TEXT OF HAZARD CLASSES AND H-STATEMENTS: SEE SECTION 16
4.1. DESCRIPTION OF FIRST AID MEASURES: FIRST-AID MEASURES GENERAL: CONTENT UNDER PRESSURE. "FROSTBITE-LIKE" EFFECTS MAY OCCUR IF THE LIQUID OR ESCAPING VAPORS CONTACT THE EYES OR SKIN. GROSS INHALATION OVER EXPOSURE MAY CAUSE: CENTRAL NERVOUS SYSTEM DEPRESSION WITH DIZZINESS, CONFUSION, INCOORDINATION, DROWSINESS OR UNCONSCIOUSNESS OR DEATH. VOMITING: PREVENT ASPHYXIA/ASPIRATION PNEUMONIA. FIRST-AID MEASURES AFTER INHALATION: IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL RESPIRATION, PREFERABLY MOUTH-TO-MOUTH. IF BREATHING IS DIFFICULT GIVE OXYGEN. GET MEDICAL ATTENTION. FIRST-AID MEASURES AFTER SKIN CONTACT: IN CASE OF CONTACT, IMMEDIATELY FLUSH SKIN WITH PLENTY OF SOAP AND WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. REMOVE CONTAMINATED CLOTHING AND SHOES, AND LAUNDER BEFORE REUSE. USE APPROVED SKIN LOTIONS OR CREAMS TO REPLACE LOST SKIN OILS. TREAT FOR FROSTBITE IF NECESSARY BY GENTLY WARMING AFFECTED AREA. FIRST-AID MEASURES AFTER EYE CONTACT: IN CASE OF CONTACT, OR SUSPECTED CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES AND GET MEDICAL ATTENTION IMMEDIATELY AFTER FLUSHING. FIRST-AID MEASURES AFTER INGESTION: DO NOT INDUCE VOMITING. GIVE NOTHING BY MOUTH. GET MEDICAL ATTENTION! IF VOMITING OCCURS, KEEP HEAD LOWER THAN HIPS TO PREVENT ASPIRATION. 4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED: SYMPTOMS/INJURIES AFTER INHALATION: CENTRAL NERVOUS SYSTEM DEPRESSION. DIZZINESS. MENTAL CONFUSION. 4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED: NO ADDITIONAL INFORMATION AVAILABLE
5.1. EXTINGUISHING MEDIA: SUITABLE EXTINGUISHING MEDIA: WATER FOG, CARBON DIOXIDE, FOAM, DRY CHEMICAL. USE WATER SPRAY TO KEEP CONTAINERS COOL THAT ARE EXPOSED TO HEAT OR FLAMES. 5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE: NO ADDITIONAL INFORMATION AVAILABLE 5.3. ADVICE FOR FIREFIGHTERS: NO ADDITIONAL INFORMATION AVAILABLE
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES: GENERAL MEASURES: WARNING! CONTENTS UNDER PRESSURE. CONTAINER MAY RUPTURE UNDER FIRE CONDITIONS. DECOMPOSITION MAY OCCUR. WEAR APPROVED POSITIVE-PRESSURE SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. 6.1.1. FOR NON-EMERGENCY PERSONNEL: PROTECTIVE EQUIPMENT: WEAR APPROPRIATE PROTECTIVE CLOTHING AND EQUIPMENT TO PREVENT SKIN AND EYE CONTACT. 6.1.2. FOR EMERGENCY RESPONDERS: NO ADDITIONAL INFORMATION AVAILABLE 6.2. ENVIRONMENTAL PRECAUTIONS: NO ADDITIONAL INFORMATION AVAILABLE 6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP: FOR CONTAINMENT: INCREASE AREA VENTILATION. DO NOT PUNCTURE OR INCINERATE CONTAINER. CONTENTS UNDER PRESSURE. 6.4. REFERENCE TO OTHER SECTIONS: NO ADDITIONAL INFORMATION AVAILABLE
7.1. PRECAUTIONS FOR SAFE HANDLING: PRECAUTIONS FOR SAFE HANDLING: CAUTION: COMPRESSED GAS. DO NOT PUNCTURE, INCINERATE OR STORE ABOVE 120 DEG. F. DO NOT STORE IN PASSENGER COMPARTMENT OF AUTOMOBILE. AVOID BREATHING VAPORS, IF EXPOSED TO HIGH VAPOR CONCENTRATION, LEAVE AREA AT ONCE. AVOID CONTACT WITH SKIN AND EYES. 7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES: STORAGE CONDITIONS: DO NOT STORE ABOVE 120 F. STORAGE TEMPERATURE: <49 DEG. C DO NOT STORE IN PASSENGER COMPARTMENT OF AUTOMOBILES. STORAGE AREA: STORE IN A DRY AREA. STORE IN A COOL AREA.
8.1. CONTROL PARAMETERS: 1,2-BENZENEDICARBOXYLIC ACID DIC9-11 BRANCHED ALKYLESTERS, C10 RICH (68515-49-1): NOT APPLICABLE 1,1,1,2-TETRAFLUOROETHANE (811-97-2): NOT APPLICABLE 8.2. EXPOSURE CONTROLS: APPROPRIATE ENGINEERING CONTROLS: LOCAL EXHAUST VENTILATION AS NECESSARY TO MAINTAIN EXPOSURES TO WITHIN APPLICABLE LIMITS. SHOWERS. EYEWASH STATIONS. HAND PROTECTION: INSULATED GLOVES. EYE PROTECTION: WEAR SAFETY GLASSES OR GOGGLES TO PROTECT AGAINST EXPOSURE. SKIN AND BODY PROTECTION: AVOID SKIN CONTACT. WEAR PROTECTIVE CLOTHING AND GLOVES. RESPIRATORY PROTECTION: USE IN A WELL VENTILATED AREA.
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES: PHYSICAL STATE: LIQUID APPEARANCE: CLEAR, COLORLESS LIQUID OR GAS AT AMBIENT TEMPERATURES. COLOR: YELLOW GREEN ODOR: ETHER-LIKE ODOUR ODOR THRESHOLD: NO DATA AVAILABLE PH: NO DATA AVAILABLE MELTING POINT: NO DATA AVAILABLE FREEZING POINT: NO DATA AVAILABLE BOILING POINT: -26.5 DEG. C FLASH POINT: NO DATA AVAILABLE RELATIVE EVAPORATION RATE (BUTYL ACETATE=1): NO DATA AVAILABLE FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE VAPOR PRESSURE: NO DATA AVAILABLE RELATIVE VAPOR DENSITY AT 20 DEG. C: NO DATA AVAILABLE RELATIVE DENSITY: NO DATA AVAILABLE SOLUBILITY: NO DATA AVAILABLE LOG POW: NO DATA AVAILABLE AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE VISCOSITY, KINEMATIC: NO DATA AVAILABLE VISCOSITY, DYNAMIC: NO DATA AVAILABLE EXPLOSION LIMITS: NO DATA AVAILABLE EXPLOSIVE PROPERTIES: NO DATA AVAILABLE OXIDIZING PROPERTIES: NO DATA AVAILABLE 9.2. OTHER INFORMATION: GAS GROUP: LIQUEFIED GAS
10.1. REACTIVITY: NO ADDITIONAL INFORMATION AVAILABLE 10.2. CHEMICAL STABILITY: STABLE UNDER NORMAL CONDITIONS. STABLE UNDER NORMAL TEMPERATURES AND PRESSURES. 10.3. POSSIBILITY OF HAZARDOUS REACTIONS: HAZARDOUS POLYMERIZATION: WILL NOT OCCUR. 10.4. CONDITIONS TO AVOID: DO NOT EXPOSE TO HEAT OR STORE AT TEMPERATURES ABOVE 120 F. 10.5. INCOMPATIBLE MATERIALS: NO ADDITIONAL INFORMATION AVAILABLE 10.6. HAZARDOUS DECOMPOSITION PRODUCTS: CARBON MONOXIDE. CARBON DIOXIDE. THIS MATERIAL CAN BE DECOMPOSED BY HIGH TEMPERATURES FORMING HYDROFLUORIC ACID AND POSSIBLY CARBONYL FLUORIDE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS: ACUTE TOXICITY: NOT CLASSIFIED 1,2-BENZENEDICARBOXYLIC ACID DIC9-11 BRANCHED ALKYLESTERS, C10 RICH (68515-49-1): LD50 ORAL RAT: 2000 MG/KG (RAT) LD50 DERMAL RABBIT: 2000 MG/KG (RABBIT) ATE US (ORAL): 2000.000 MG/KG BODY WEIGHT ATE US (DERMAL): 2000.000 MG/KG BODY WEIGHT ADDITIONAL INFORMATION: DI-ISODECYL PHTHALATE (DIDP) HAS BEEN TESTED IN REPRODUCTIVE TOXICOLOGY STUDIES IN LABORATORY RATS (TWO-GENERATION STUDIES). THERE WERE NO EFFECTS ON FERTILITY, REPRODUCTIVE PERFORMANCE, OR EVIDENCE OF ALTERATION OF ENDOCRINE PROCESSES. A SMALL, STATISTICALLY SIGNIFICANT DECREASE IN OFFSPRING SURVIVAL WAS OBSERVED. IN EVALUATING THESE AND RELATED STUDIES, THE EU RISK ASSESSMENT FOR DIDP HAS CONCLUDED THAT CLASSIFICATION AND LABELING IS NOT REQUIRED FOR ANY EFFECT INCLUDING REPRODUCTIVE AND DEVELOPMENTAL EFFECTS. IN ADDITION THE NTP CENTER FOR EVALUATION OF RISKS TO HUMAN REPRODUCTION HAS CONCLUDED THAT THERE IS NEGLIGIBLE CONCERN FOR REPRODUCTIVE EFFECTS IN ADULTS AND MINIMAL CONCERN FOR DEVELOPMENTAL EFFECTS IN FETUSES AND CHILDREN DUE TO DIDP EXPOSURE 1,1,1,2-TETRAFLUOROETHANE (811-97-2): LC50 INHALATION RAT (MG/L): >2000 MG/L/4H (RAT; LITERATURE STUDY) LC50 INHALATION RAT (PPM): >359300 PPM/4H (RAT; LITERATURE STUDY) SKIN CORROSION/IRRITATION: NOT CLASSIFIED SERIOUS EYE DAMAGE/IRRITATION: NOT CLASSIFIED RESPIRATORY OR SKIN SENSITIZATION: NOT CLASSIFIED GERM CELL MUTAGENICITY: NOT CLASSIFIED CARCINOGENICITY: NOT CLASSIFIED (NOT EXPECTED TO CAUSE CANCER. THIS OIL MEETS THE IP-346 CRITERIA OF LESS THAN 3 PERCENT PAH'S AND IS NOT CONSIDERED A CARCINOGEN BY THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER) REPRODUCTIVE TOXICITY: NOT CLASSIFIED SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): NOT CLASSIFIED SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): NOT CLASSIFIED ASPIRATION HAZARD: NOT CLASSIFIED SYMPTOMS/INJURIES AFTER INHALATION: CENTRAL NERVOUS SYSTEM DEPRESSION. DIZZINESS. MENTAL CONFUSION.
12.1. TOXICITY: 1,1,1,2-TETRAFLUOROETHANE (811-97-2): LC50 FISH 1: 450 MG/L (LC50; 96 H) EC50 DAPHNIA 1: 980 MG/L (EC50; 48 H) 12.2. PERSISTENCE AND DEGRADABILITY: 1,2-BENZENEDICARBOXYLIC ACID DIC9-11 BRANCHED ALKYLESTERS, C10 RICH (68515-49-1): PERSISTENCE AND DEGRADABILITY: EXPECTED TO BE READILY BIODEGRADABLE. 1,1,1,2-TETRAFLUOROETHANE (811-97-2): PERSISTENCE AND DEGRADABILITY: NOT READILY BIODEGRADABLE IN WATER. 12.3. BIOACCUMULATIVE POTENTIAL: 1,2-BENZENEDICARBOXYLIC ACID DIC9-11 BRANCHED ALKYLESTERS, C10 RICH (68515-49-1): BIOACCUMULATIVE POTENTIAL: NO BIOACCUMULATION DATA AVAILABLE. 1,1,1,2-TETRAFLUOROETHANE (811-97-2): BCF OTHER AQUATIC ORGANISMS 1: 5 - 58 (BCF) LOG POW: 1.06 (OECD 107: PARTITION COEFFICIENT (N-OCTANOL/WATER): SHAKE FLASK METHOD) BIOACCUMULATIVE POTENTIAL: LOW POTENTIAL FOR BIOACCUMULATION (BCF <500). 12.4. MOBILITY IN SOIL: 1,2-BENZENEDICARBOXYLIC ACID DIC9-11 BRANCHED ALKYLESTERS, C10 RICH (68515-49-1): SURFACE TENSION: 0.033 N/M 12.5. OTHER ADVERSE EFFECTS: EFFECT ON THE GLOBAL WARMING: NO KNOWN EFFECTS FROM THIS PRODUCT. GWPMIX COMMENT: NO KNOWN EFFECTS FROM THIS PRODUCT. OTHER INFORMATION: AVOID RELEASE TO THE ENVIRONMENT.
13.1. WASTE TREATMENT METHODS: WASTE DISPOSAL RECOMMENDATIONS: DISPOSAL SHOULD BE MADE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS.
DEPARTMENT OF TRANSPORTATION (DOT): IN ACCORDANCE WITH DOT: PROPER SHIPPING NAME (DOT): 1,1,1,2-TETRAFLUORETHANE CLASS (DOT): 2.2 - CLASS 2.2 - NON-FLAMMABLE COMPRESSED GAS 49 CFR 173.115 HAZARD LABELS (DOT): 2.2 - NON-FLAMMABLE GAS OTHER INFORMATION: NO SUPPLEMENTARY INFORMATION AVAILABLE. TDG: TRANSPORT DOCUMENT DESCRIPTION: 3159 1,1,1,2-TETRAFLUORETHANE, 2.2 UN-NO. (TDG): 3159 PROPER SHIPPING NAME (TDG): 1,1,1,2-TETRAFLUORETHANE TDG PRIMARY HAZARD CLASSES: 2.2 - CLASS 2.2 - NON-FLAMMABLE, NON-TOXIC GAS. TRANSPORT BY SEA: AIR TRANSPORT:
15.1. US FEDERAL REGULATIONS: 24278 R-134A REFRIGERANT PLUS (811-97-2): LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY 15.2. INTERNATIONAL REGULATIONS: CANADA: 24278 R-134A REFRIGERANT PLUS (811-97-2): LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST) WHMIS CLASSIFICATION: CLASS A - COMPRESSED GAS CLASS D DIVISION 2 SUBDIVISION B - TOXIC MATERIAL CAUSING OTHER TOXIC EFFECTS EU-REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE NATIONAL REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE 15.3. US STATE REGULATIONS: 24278 R-134A REFRIGERANT PLUS (811-97-2): U.S. - CALIFORNIA - PROPOSITION 65 - CARCINOGENS LIST: NO U.S. - CALIFORNIA - PROPOSITION 65 - DEVELOPMENTAL TOXICITY: YES U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - FEMALE: NO U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - MALE: NO 1,2-BENZENEDICARBOXYLIC ACID DIC9-11 BRANCHED ALKYLESTERS, C10 RICH (68515-49-1): U.S. - CALIFORNIA - PROPOSITION 65 - CARCINOGENS LIST: NO U.S. - CALIFORNIA - PROPOSITION 65 - DEVELOPMENTAL TOXICITY: YES U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - FEMALE: NO U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - MALE: NO NON-SIGNIFICANT RISK LEVEL (NSRL):
REVISION DATE: 05/05/2016 FULL TEXT OF H-PHRASES: SEE SECTION 16: H302: HARMFUL IF SWALLOWED H312: HARMFUL IN CONTACT WITH SKIN NFPA HEALTH HAZARD 1 - EXPOSURE COULD CAUSE IRRITATION BUT ONLY MINOR RESIDUAL INJURY EVEN IF NO TREATMENT IS GIVEN. NFPA FIRE HAZARD 0 - MATERIALS THAT WILL NOT BURN. NFPA REACTIVITY 1 - NORMALLY STABLE, BUT CAN BECOME UNSTABLE AT ELEVATED TEMPERATURES AND PRESSURES OR MAY REACT WITH WATER WITH SOME RELEASE OF ENERGY, BUT NOT VIOLENTLY. SDS US (GHS HAZCOM 2012) THIS INFORMATION IS FURNISHED WITHOUT WARRANTY, EXPRESSED OR IMPLIED, EXCEPT THAT IS ACCURATE TO THE BEST KNOWLEDGE OF TIRE SEAL, INC. THE DATA ON THIS SHEET RELATED ONLY TO THE SPECIFIC MATERIAL DESIGNED HEREIN. TIRE SEAL, INC. ASSUMES NO LEGAL RESPONSIBILITY FOR THE USE OR RELIANCE UPON THESE DATA. EN (ENGLISH US) |