| Common Name: | KWIK SEAL TUB & TILE ADHESIVE CAULK - ALL COLORS |
| Manufacturer: | DAP |
| SDS Revision Date: | 6/19/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 5E080 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SDS NUMBER: 00010009001
REVISION DATE: 6/19/2015
DAP(R*)
SAFETY DATA SHEET
24 HOUR EMERGENCY PHONE NUMBERS:
MEDICAL/POISON CONTROL:
IN U.S.:
CALL: 1-800-222-1222
OUTSIDE U.S.: CALL YOUR LOCAL POISON CONTROL CENTER
TRANSPORTATION/NATIONAL RESPONSE CENTER:
1-800-535-5053
1-352-323-3500
NOTE:
THE NATIONAL RESPONSE CENTER EMERGENCY NUMBERS TO BE USED ONLY IN THE EVENT
OF CHEMICAL EMERGENCIES INVOLVING A SPILL, LEAK, FIRE, EXPOSURE OR ACCIDENT
INVOLVING CHEMICALS.
IMPORTANT:
PROVIDE THIS INFORMATION TO EMPLOYEES, CUSTOMERS, AND USERS OF THIS
PRODUCT. READ THIS SDS BEFORE HANDLING OR DISPOSING OF THIS PRODUCT.
THIS PRODUCT IS COVERED BY THE OSHA HAZARD COMMUNICATION STANDARD AND
THIS DOCUMENT HAS BEEN PREPARED IN ACCORDANCE WITH REQUIREMENTS OF THIS
STANDARD. ALL ABBREVIATED TERMS USED IN THIS MSDS ARE FURTHER DESCRIBED
IN SECTION 16.
| 1. IDENTIFICATION |  |
THIS SAFETY DATA SHEET IS AVAILABLE IN AMERICAN SPANISH UPON REQUEST.
PRODUCT NAME: KWIK SEAL TUB & TILE ADHESIVE CAULK - ALL COLORS
PRODUCT UPC NUMBER: 18001 18013 18002
PRODUCT USE/CLASS: CAULKING COMPOUND
REVISION DATE: 6/19/2015
SUPERCEDES DATE: NEW SDS
SDS NO: 00010009001
MANUFACTURER:
DAP PRODUCTS INC.
2400 BOSTON STREET
SUITE 200
BALTIMORE, MD 21224-4723
888-327-8477 (NON - EMERGENCY MATTERS)
PREPARER: REGULATORY DEPARTMENT
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
UNDER NORMAL USE CONDITIONS, THIS PRODUCT IS NOT EXPECTED TO CAUSE ADVERSE
HEALTH EFFECTS.
GHS CLASSIFICATION: NOT A HAZARDOUS SUBSTANCE OR MIXTURE.
SYMBOL(S) OF PRODUCT: NONE
SIGNAL WORD: NOT A HAZARDOUS SUBSTANCE OR MIXTURE.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL NAME CAS-NO. WT. % GHS SYMBOLS GHS STATEMENTS
LIMESTONE 1317-65-3 50-75 GHS03 H270
DIETHYLENE GLYCOL 120-55-8 2.5-10 GHS03-GHS07 H270-312
DIBENZOATE
TITANIUM DIOXIDE 13463-67-7 0.1-1.0 NO INFORMATION NO INFORMATION
QUARTZ 14808-60-7 0.1-1.0 GHS03-GHS07 H270-302
THE TEXT FOR GHS HAZARD STATEMENTS SHOWN ABOVE (IF ANY) IS GIVEN IN
THE "OTHER INFORMATION" SECTION.
| 4. FIRST-AID MEASURES | |
FIRST AID - INHALATION:
MATERIAL IS NOT LIKELY TO PRESENT AN INHALATION HAZARD AT AMBIENT
CONDITIONS. IF YOU EXPERIENCE DIFFICULTY IN BREATHING, LEAVE THE AREA TO
OBTAIN FRESH AIR. IF CONTINUED DIFFICULTY IS EXPERIENCED, GET MEDICAL
ATTENTION IMMEDIATELY.
FIRST AID - SKIN CONTACT:
NO HEALTH HAZARDS ARE KNOWN TO EXIST. IN CASE OF CONTACT, WASH SKIN
IMMEDIATELY WITH SOAP AND WATER.
FIRST AID - EYE CONTACT:
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH LARGE QUANTITIES OF WATER
FOR AT LEAST 15 MINUTES UNTIL IRRITATION SUBSIDES. GET MEDICAL ATTENTION
IMMEDIATELY.
FIRST AID - INGESTION:
IF SWALLOWED, DO NOT INDUCE VOMITING. GET MEDICAL ATTENTION IMMEDIATELY.
| 5. FIRE-FIGHTING MEASURES | |
UNUSUAL FIRE AND EXPLOSION HAZARDS: 465 <UNDEFINED>
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND (NIOSH APPROVED OR
EQUIVALENT) AND FULL PROTECTIVE GEAR. USE WATER SPRAY TO COOL EXPOSED
SURFACES.
EXTINGUISHING MEDIA: CARBON DIOXIDE, DRY CHEMICAL, FOAM, WATER FOG
| 6. ACCIDENTAL RELEASE MEASURES | |
ENVIRONMENTAL MEASURES: NO INFORMATION
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
CONTAIN SPILLED MATERIAL AND REMOVE WITH INERT ABSORBENT. DISPOSE OF
CONTAMINATED ABSORBENT, CONTAINER AND UNUSED CONTENTS IN ACCORDANCE WITH
LOCAL, STATE AND FEDERAL REGULATIONS. SCRAPE UP DRIED MATERIAL AND PLACE
INTO CONTAINERS. USE PERSONAL PROTECTIVE EQUIPMENT AS NECESSARY. IN CASE
OF SPILLAGE, ABSORB WITH INERT MATERIAL AND DISPOSE OF IN ACCORDANCE WITH
APPLICABLE REGULATIONS.
| 7. HANDLING AND STORAGE | |
HANDLING:
KEEP OUT OF REACH OF CHILDREN!
DO NOT TAKE INTERNALLY. USE ONLY WITH ADEQUATE VENTILATION. ENSURE FRESH
AIR ENTRY DURING APPLICATION AND DRYING. WASH THOROUGHLY AFTER HANDLING.
STORAGE:
AVOID EXCESSIVE HEAT AND FREEZING. DO NOT STORE AT TEMPERATURES ABOVE
120 DEGREES F. STORE AWAY FROM CAUSTICS AND OXIDIZERS.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
INGREDIENTS WITH OCCUPATIONAL EXPOSURE LIMITS:
CHEMICAL NAME ACGIH TLV-TWA ACGIH-TLV STEL OSHA PEL-TWA OSHA
PEL-CEILING
LIMESTONE N.E. N.E. 15 MG/M3TWA N.E.
TOTAL DUST,
5 MG/M3 TWA
RESPIRABLE
FRACTION
DIETHYLENE N.E. N.E. N.E. N.E.
GLYCOL
DIBENZOATE
TITANIUM 10 MG/M3 N.E. 15 MG/M3 N.E.
DIOXIDE TWA TWA TOTAL
DUST
QUARTZ 0.025 MG/M3 N.E. N.E. N.E.
TWA
RESPIRABLE
FRACTION
FURTHER ADVICE:
MEL = MAXIMUM EXPOSURE LIMIT
OES = OCCUPATIONAL EXPOSURE STANDARD
SUP = SUPPLIER'S RECOMMENDATION
SK = SKIN SENSITIZER
N.E. = NOT ESTABLISHED
PERSONAL PROTECTION:
RESPIRATORY PROTECTION:
NO PERSONAL RESPIRATORY PROTECTIVE EQUIPMENT NORMALLY REQUIRED. NATIONAL
INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH (NIOSH) HAS RECOMMENDED
THAT THE PERMISSIBLE EXPOSURE LIMIT BE CHANGED TO 50 MICROGRAMS RESPIRABLE
FREE SILICA PER CUBIC METER OF AIR (0.05 MG/M3) AS DETERMINED BY A FULL
SHIFT SAMPLE UP TO 10-HOUR WORK SHIFT.
SKIN PROTECTION: RUBBER GLOVES.
EYE PROTECTION: GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS.
OTHER PROTECTIVE EQUIPMENT: NOT REQUIRED UNDER NORMAL USE.
HYGIENIC PRACTICES:
WASH HANDS BEFORE BREAKS AND AT THE END OF WORKDAY. REMOVE AND WASH
CONTAMINATED CLOTHING BEFORE RE-USE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: COLORED
PHYSICAL STATE: PASTE
ODOR: VERY SLIGHT AMMONIA
ODOR THRESHOLD: NOT ESTABLISHED
DENSITY, G/CM3: 1.56 - 1.58
PH: BETWEEN 7.0 AND 12.0
FREEZE POINT, DEG. C: NOT ESTABLISHED
VISCOSITY (MPA.S): NOT ESTABLISHED
SOLUBILITY IN WATER: NOT ESTABLISHED
PARTITION COEFF., N-OCTANOL/WATER: NOT ESTABLISHED
DECOMPOSITION TEMPERATURE, DEG. C: NOT ESTABLISHED
EXPLOSIVE LIMITS, %: N.L. - N.L.
BOILING RANGE, DEG. C: N.L. - N.L.
AUTO-IGNITION TEMPERATURE, DEG. C: NOT ESTABLISHED
MINIMUM FLASH POINT, DEG. C: 93.3
VAPOR PRESSURE, MMHg: NO INFORMATION
EVAPORATION RATE: SLOWER THAN N-BUTYL ACETATE
FLASH METHOD: SETA CLOSED CUP
VAPOR DENSITY: HEAVIER THAN AIR
FLAMMABILITY: NO INFORMATION
COMBUSTIBILITY: DOES NOT SUPPORT COMBUSTION
(SEE "OTHER INFORMATION" SECTION FOR ABBREVIATION LEGEND)
(IF PRODUCT IS AN AEROSOL, THE FLASH POINT STATED ABOVE IS THAT OF THE
PROPELLANT.)
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
CONDITIONS TO AVOID: EXCESSIVE HEAT AND FREEZING.
INCOMPATIBILITY: INCOMPATIBLE WITH STRONG BASES AND OXIDIZING AGENTS.
HAZARDOUS DECOMPOSITION PRODUCTS:
NORMAL DECOMPOSITION PRODUCTS, I.E., COX, NOX.
| 11. TOXICOLOGICAL INFORMATION | |
EFFECT OF OVEREXPOSURE - INHALATION:
UNDER NORMAL USE CONDITIONS, THIS PRODUCT IS NOT EXPECTED TO CAUSE ADVERSE
HEALTH EFFECTS. INHALATION OF VAPORS IN HIGH CONCENTRATION MAY CAUSE MILD
IRRITATION OF RESPIRATORY SYSTEM (NOSE, MOUTH, MUCOUS MEMBRANES).
EFFECT OF OVEREXPOSURE - SKIN CONTACT:
UNDER NORMAL USE CONDITIONS, THIS PRODUCT IS NOT EXPECTED TO CAUSE ADVERSE
HEALTH EFFECTS. PROLONGED OR REPEATED CONTACT WITH SKIN MAY CAUSE MILD
IRRITATION.
EFFECT OF OVEREXPOSURE - EYE CONTACT:
UNDER NORMAL USE CONDITIONS, THIS PRODUCT IS NOT EXPECTED TO CAUSE ADVERSE
HEALTH EFFECTS. DIRECT EYE CONTACT MAY CAUSE IRRITATION.
EFFECT OF OVEREXPOSURE - INGESTION:
UNDER NORMAL USE CONDITIONS, THIS PRODUCT IS NOT EXPECTED TO CAUSE ADVERSE
HEALTH EFFECTS. SINGLE DOSE ORAL TOXICITY IS VERY LOW. AMOUNTS INGESTED
INCIDENTAL TO INDUSTRIAL HANDLING ARE NOT LIKELY TO CAUSE INJURY;
HOWEVER, INGESTION OF LARGE AMOUNTS MAY CAUSE INJURY.
CARCINOGENICITY: NO INFORMATION
EFFECT OF OVEREXPOSURE - CHRONIC HAZARDS:
REPEATED OR PROLONGED EXPOSURE MAY CAUSE IRRITATION OF EYES AND SKIN.
THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC) HAS DETERMINED THAT
CRYSTALLINE SILICA IN THE FORM OF QUARTZ OR CRISTOBALITE THAT IS INHALED
FROM OCCUPATIONAL SOURCES IS CARCINOGENIC TO HUMANS (GROUP 1- CARCINOGENIC
TO HUMANS). REFER TO IARC MONOGRAPH 68, SILICA, SOME SILICATES AND ORGANIC
FIBRES (PUBLISHED IN JUNE 1997) IN CONJUNCTION WITH THE USE OF THESE
MATERIALS. THE NATIONAL TOXICOLOGY PROGRAM (NTP) CLASSIFIES RESPIRABLE
CRYSTALLINE SILICA AS "KNOWN TO BE A HUMAN CARCINOGEN". REFER TO THE 9TH
REPORT ON CARCINOGENS (2000). THE AMERICAN CONFERENCE OF GOVERNMENTAL
INDUSTRIAL HYGIENISTS (ACGIH) CLASSIFIES CRYSTALLINE SILICA, QUARTZ, AS A
SUSPECTED HUMAN CARCINOGEN (GROUP A2). BREATHING DUST CONTAINING RESPIRABLE
CRYSTALLINE SILICA MAY NOT CAUSE NOTICEABLE INJURY OR ILLNESS EVEN THOUGH
PERMANENT LUNG DAMAGE MAY BE OCCURRING. INHALATION OF DUST MAY HAVE THE
FOLLOWING SERIOUS CHRONIC HEALTH EFFECTS: EXCESSIVE INHALATION OF
RESPIRABLE DUST CAN CAUSE PNEUMOCONIOSIS, A RESPIRATORY DISEASE, WHICH CAN
RESULT IN DELAYED, PROGRESSIVE, DISABLING AND SOMETIMES FATAL LUNG INJURY.
SYMPTOMS INCLUDE COUGH, SHORTNESS OF BREATH, WHEEZING, NON-SPECIFIC CHEST
ILLNESS AND REDUCED PULMONARY FUNCTION. SMOKING EXACERBATES THIS DISEASE.
INDIVIDUALS WITH PNEUMOCONIOSIS ARE PREDISPOSED TO DEVELOP TUBERCULOSIS.
THERE IS SOME EVIDENCE THAT BREATHING RESPIRABLE CRYSTALLINE SILICA OR THE
DISEASE SILICOSIS IS ASSOCIATED WITH AN INCREASED INCIDENCE OF SIGNIFICANT
DISEASE ENDPOINTS SUCH AS SCLERODERMA (AN IMMUNE SYSTEM DISORDER MANIFESTED
BY FIBROSIS OF THE LUNGS, SKIN AND OTHER INTERNAL ORGANS) AND KIDNEY
DISEASE.
PRIMARY ROUTE(S) OF ENTRY: INHALATION, SKIN CONTACT
ACUTE TOXICITY VALUES:
THE ACUTE EFFECTS OF THIS PRODUCT HAVE NOT BEEN TESTED. DATA ON INDIVIDUAL
COMPONENTS ARE TABULATED BELOW:
CAS-NO. CHEMICAL NAME ORAL LD50 DERMAL LD50 VAPOR LC50
1317-65-3 LIMESTONE 6450 MG/KG >2000 MG/KG >20 MG/L
RAT
120-55-8 DIETHYLENE GLYCOL 2830 MG/KG 2000 MG/KG >200 MG/L
DIBENZOATE RAT RABBIT RAT
13463-67-7 TITANIUM DIOXIDE >10000 MG/KG >5000 MG/KG >20 MG/L
RAT RABBIT
14808-60-7 QUARTZ 500 MG/KG >2000 MG/KG >20 MG/L
RAT
N.L. = NO INFORMATION
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION:
ECOLOGICAL INJURIES ARE NOT KNOWN OR EXPECTED UNDER NORMAL USE.
| 13. DISPOSAL INFORMATION | |
DISPOSAL INFORMATION:
THIS PRODUCT DOES NOT MEET THE DEFINITION OF A HAZARDOUS WASTE ACCORDING
TO U.S. EPA HAZARDOUS WASTE MANAGEMENT REGULATION, 40 CFR SECTION 261.
DISPOSE AS HAZARDOUS WASTE ACCORDING TO ALL LOCAL, STATE, FEDERAL AND
PROVINCIAL REGULATIONS. STATE AND LOCAL REGULATIONS/RESTRICTIONS ARE
COMPLEX AND MAY DIFFER FROM FEDERAL REGULATIONS. RESPONSIBILITY FOR
PROPER WASTE DISPOSAL IS WITH THE OWNER OF THE WASTE.
| 14. TRANSPORT INFORMATION | |
SPECIAL TRANSPORT PRECAUTIONS: NO INFORMATION
DOT UN/NA NUMBER: N.A.
DOT PROPER SHIPPING NAME: NOT REGULATED.
DOT TECHNICAL NAME: N.A.
DOT HAZARD CLASS: N.A.
HAZARD SUBCLASS: N.A.
PACKING GROUP: N.A.
| 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
CERCLA - SARA HAZARD CATEGORY:
THIS PRODUCT HAS BEEN REVIEWED ACCORDING TO THE EPA 'HAZARD CATEGORIES'
PROMULGATED UNDER SECTIONS 311 AND 312 OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 (SARA TITLE III) AND IS CONSIDERED, UNDER
APPLICABLE DEFINITIONS, TO MEET THE FOLLOWING CATEGORIES:
ACUTE HEALTH HAZARD, CHRONIC HEALTH HAZARD
SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372:
NO SARA 313 COMPONENTS EXIST IN THIS PRODUCT.
TOXIC SUBSTANCES CONTROL ACT:
ALL INGREDIENTS IN THIS PRODUCT ARE EITHER ON TSCA INVENTORY LIST, OR
OTHERWISE EXEMPT.
THIS PRODUCT CONTAINS THE FOLLOWING CHEMICAL SUBSTANCES SUBJECT TO THE
REPORTING REQUIREMENTS OF TSCA 12(B) IF EXPORTED FROM THE UNITED STATES:
NO TSCA 12(B) COMPONENTS EXIST IN THIS PRODUCT.
CALIFORNIA PROPOSITION 65 CARCINOGENS AND REPORODUCTIVE TOXINS:
CALIFORNIA PROPOSITION 65: NO INFORMATION
INTERNATIONAL REGULATIONS: AS FOLLOWS
CANADIAN WHMIS:
THIS SDS HAS BEEN PREPARED IN COMPLIANCE WITH CONTROLLED PRODUCT
REGULATIONS EXCEPT FOR THE USE OF THE 16 HEADINGS.
WHMIS CLASS: CONSUMER COMMODITY
| 16. OTHER INFORMATION | |
REVISION DATE: 6/19/2015
SUPERSEDES DATE: NEW MSDS
REASON FOR REVISION: HAZCOM2012/GHS CONVERSION
DATASHEET PRODUCED BY: REGULATORY DEPARTMENT
HMIS RATINGS:
HEALTH 1
FLAMMABILITY 0
REACTIVITY 0
PERSONAL PROTECTION X
VOC LESS WATER LESS EXEMPT SOLVENT, G/L: 34.5
VOC MATERIAL, G/L: 22
VOC AS DEFINED BY CALIFORNIA CONSUMER PRODUCT REGULATION, WT/WT%: 0.6
TEXT FOR GHS HAZARD STATEMENTS SHOWN IN SECTION 3 DESCRIBING EACH
INGREDIENT:
H270: MAY CAUSE OR INTENSIFY FIRE; OXIDISER.
H302: HARMFUL IF SWALLOWED.
H312: HARMFUL IN CONTACT WITH SKIN.
ICONS FOR GHS PICTOGRAMS SHOWN IN SECTION 3 DESCRIBING EACH INGREDIENT:
GHS03: FLAME OVER CIRCLE
GHS07: EXCLAMATION MARK
LEGEND:
N.A. - NOT APPLICABLE
N.E. - NOT ESTABLISHED
N.D. - NOT DETERMINED
DAP BELIEVES THE DATA AND STATEMENTS CONTAINED HEREIN ARE ACCURATE AS OF
THE DATE HEREOF. THEY ARE OFFERED IN GOOD FAITH AS TYPICAL VALUES AND NOT
AS A PRODUCT SPECIFICATION. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF
FITNESS FOR ANY PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR
IMPLIED, IS MADE WITH REGARD TO THE INFORMATION HEREIN PROVIDED OR THE
PRODUCT TO WHICH THE INFORMATION REFERS. SINCE THIS DOCUMENT IS INTENDED
ONLY AS A GUIDE TO THE APPROPRIATE USE AND PRECAUTIONARY HANDLING OF THE
REFERENCED PRODUCT BY A PROPERLY TRAINED PERSON, IT IS THEREFORE THE
RESPONSIBILITY OF THE USER TO (I) REVIEW THE RECOMMENDATIONS WITH DUE
CONSIDERATION FOR THE SPECIFIC CONTEXT OF THE INTENDED USE AND (II)
DETERMINE IF THEY ARE APPROPRIATE.