| Common Name: | NEOPRENE HIGH PERFORMANCE CONTACT ADHESIVE 1357 |
| Manufacturer: | 3M |
| SDS Revision Date: | 4/24/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 2RUF3, 5E0130, 5E127, 5E130 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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3M(TM) NEOPRENE HIGH PERFORMANCE CONTACT ADHESIVE 1357
04/24/15
3M
SAFETY DATA SHEET
COPYRIGHT, 2015, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR THE
PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 10-2789-5
VERSION NUMBER: 41.01
ISSUE DATE: 04/24/15
SUPERCEDES DATE: 01/12/15
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER:
3M(TM) NEOPRENE HIGH PERFORMANCE CONTACT ADHESIVE 1357
PRODUCT IDENTIFICATION NUMBERS:
62-1357-2630-5, 62-1357-2631-3, 62-1357-5530-4, 62-1357-5535-3,
62-1357-6530-3, 62-1357-7530-2, 62-1357-8540-0, 62-1357-9530-0,
62-1357-9531-8
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE: ADHESIVE, INDUSTRIAL USE
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: INDUSTRIAL ADHESIVES AND TAPES DIVISION
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
2.1. HAZARD CLASSIFICATION:
FLAMMABLE LIQUID: CATEGORY 2.
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 2A.
SKIN CORROSION/IRRITATION: CATEGORY 2.
SKIN SENSITIZER: CATEGORY 1.
REPRODUCTIVE TOXICITY: CATEGORY 1B.
SPECIFIC TARGET ORGAN TOXICITY (CENTRAL NERVOUS SYSTEM): CATEGORY 3.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 1.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS:
FLAME
EXCLAMATION MARK
HEALTH HAZARD
PICTOGRAMS:
FLAME
EXCLAMATION MARK
HEALTH HAZARD
HAZARD STATEMENTS:
HIGHLY FLAMMABLE LIQUID AND VAPOR.
CAUSES SERIOUS EYE IRRITATION.
CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
MAY CAUSE DROWSINESS OR DIZZINESS.
MAY DAMAGE FERTILITY OR THE UNBORN CHILD.
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE:
NERVOUS SYSTEM
SENSORY ORGANS
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING.
GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT.
USE ONLY NON-SPARKING TOOLS.
TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
KEEP CONTAINER TIGHTLY CLOSED.
USE EXPLOSION-PROOF ELECTRICAL/VENTILATING/LIGHTING EQUIPMENT.
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
WEAR PROTECTIVE GLOVES AND EYE/FACE PROTECTION.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH THOROUGHLY AFTER HANDLING.
CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
RESPONSE:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO.
CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
WASH CONTAMINATED CLOTHING BEFORE REUSE.
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
IN CASE OF FIRE:
USE A FIRE FIGHTING AGENT SUITABLE FOR FLAMMABLE LIQUIDS SUCH AS DRY
CHEMICAL OR CARBON DIOXIDE TO EXTINGUISH.
STORAGE:
KEEP COOL.
KEEP CONTAINER TIGHTLY CLOSED.
STORE LOCKED UP IN A WELL-VENTILATED PLACE.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE LOCAL/
REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
2.3. HAZARDS NOT OTHERWISE CLASSIFIED: NONE.
21% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE INHALATION
TOXICITY.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
MAGNESIUM RESINATE 68037-42-3 5 - 10 TRADE SECRET *
PETROLEUM DISTILLATE 64741-84-0 20 - 50 TRADE SECRET *
N-HEXANE 110-54-3 5 - 20 TRADE SECRET *
ACETONE 67-64-1 10 - 30 TRADE SECRET *
POLYCHLOROPRENE 9010-98-4 7 - 13 TRADE SECRET *
METHYL ETHYL KETONE 78-93-3 7 - 13 TRADE SECRET *
TOLUENE 108-88-3 1 - 10 TRADE SECRET *
ROSIN 8050-09-7 0.1 - 1 TRADE SECRET *
ZINC OXIDE 1314-13-2 0.1 - 1 TRADE SECRET *
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND WASH
BEFORE REUSE. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER. REMOVE CONTACT LENSES IF
EASY TO DO. CONTINUE RINSING. GET MEDICAL ATTENTION.
IF SWALLOWED: RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
IN CASE OF FIRE:
USE A FIRE FIGHTING AGENT SUITABLE FOR FLAMMABLE LIQUIDS SUCH AS DRY
CHEMICAL OR CARBON DIOXIDE TO EXTINGUISH.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
CLOSED CONTAINERS EXPOSED TO HEAT FROM FIRE MAY BUILD PRESSURE AND EXPLODE.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
ALDEHYDES DURING COMBUSTION
HYDROCARBONS DURING COMBUSTION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
WATER MAY NOT EFFECTIVELY EXTINGUISH FIRE; HOWEVER, IT SHOULD BE USED TO
KEEP FIRE-EXPOSED CONTAINERS AND SURFACES COOL AND PREVENT EXPLOSIVE
RUPTURE.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO
SMOKING. USE ONLY NON-SPARKING TOOLS. VENTILATE THE AREA WITH FRESH AIR.
FOR LARGE SPILL, OR SPILLS IN CONFINED SPACES, PROVIDE MECHANICAL
VENTILATION TO DISPERSE OR EXHAUST VAPORS, IN ACCORDANCE WITH GOOD
INDUSTRIAL HYGIENE PRACTICE. WARNING! A MOTOR COULD BE AN IGNITION SOURCE
AND COULD CAUSE FLAMMABLE GASES OR VAPORS IN THE SPILL AREA TO BURN OR
EXPLODE. REFER TO OTHER SECTIONS OF THIS SDS FOR INFORMATION REGARDING
PHYSICAL AND HEALTH HAZARDS, RESPIRATORY PROTECTION, VENTILATION, AND
PERSONAL PROTECTIVE EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. FOR LARGER SPILLS, COVER DRAINS AND BUILD
DIKES TO PREVENT ENTRY INTO SEWER SYSTEMS OR BODIES OF WATER.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
CONTAIN SPILL. COVER SPILL AREA WITH A FIRE-EXTINGUISHING FOAM. AN
APPROPRIATE AQUEOUS FILM FORMING FOAM (AFFF) IS RECOMMENDED. WORKING FROM
AROUND THE EDGES OF THE SPILL INWARD, COVER WITH BENTONITE, VERMICULITE,
OR COMMERCIALLY AVAILABLE INORGANIC ABSORBENT MATERIAL. MIX IN SUFFICIENT
ABSORBENT UNTIL IT APPEARS DRY. REMEMBER, ADDING AN ABSORBENT MATERIAL DOES
NOT REMOVE A PHYSICAL, HEALTH, OR ENVIRONMENTAL HAZARD. COLLECT AS MUCH OF
THE SPILLED MATERIAL AS POSSIBLE USING NON-SPARKING TOOLS. PLACE IN A METAL
CONTAINER APPROVED FOR TRANSPORTATION BY APPROPRIATE AUTHORITIES. CLEAN UP
RESIDUE WITH AN APPROPRIATE SOLVENT SELECTED BY A QUALIFIED AND AUTHORIZED
PERSON. VENTILATE THE AREA WITH FRESH AIR. READ AND FOLLOW SAFETY
PRECAUTIONS ON THE SOLVENT LABEL AND SDS. SEAL THE CONTAINER. DISPOSE OF
COLLECTED MATERIAL AS SOON AS POSSIBLE.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
FOR INDUSTRIAL OR PROFESSIONAL USE ONLY. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. KEEP AWAY FROM HEAT/SPARKS/OPEN
FLAMES/HOT SURFACES. - NO SMOKING. USE ONLY NON-SPARKING TOOLS. TAKE
PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE. DO NOT BREATHE DUST/FUME/
GAS/MIST/VAPORS/SPRAY. DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING. DO
NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH THOROUGHLY AFTER
HANDLING. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE
WORKPLACE. AVOID RELEASE TO THE ENVIRONMENT. WASH CONTAMINATED CLOTHING
BEFORE REUSE. AVOID CONTACT WITH OXIDIZING AGENTS (EG. CHLORINE, CHROMIC
ACID ETC.) WEAR LOW STATIC OR PROPERLY GROUNDED SHOES. USE PERSONAL
PROTECTIVE EQUIPMENT (GLOVES, RESPIRATORS, ETC.) AS REQUIRED. TO MINIMIZE
THE RISK OF IGNITION, DETERMINE APPLICABLE ELECTRICAL CLASSIFICATIONS FOR
THE PROCESS USING THIS PRODUCT AND SELECT SPECIFIC LOCAL EXHAUST
VENTILATION EQUIPMENT TO AVOID FLAMMABLE VAPOR ACCUMULATION. GROUND/BOND
CONTAINER AND RECEIVING EQUIPMENT IF THERE IS POTENTIAL FOR STATIC
ELECTRICITY ACCUMULATION DURING TRANSFER.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
STORE IN A WELL-VENTILATED PLACE. KEEP COOL. KEEP CONTAINER TIGHTLY CLOSED.
STORE AWAY FROM HEAT. STORE AWAY FROM ACIDS. STORE AWAY FROM OXIDIZING
AGENTS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL COMMENTS
TOLUENE 108-88-3 OSHA TWA: 200 PPM
CEIL: 300 PPM
TOLUENE 108-88-3 ACGIH TWA: 20 PPM A4:
NOT CLASS. AS HUMAN
CARCIN
TOLUENE 108-88-3 CMRG STEL: 75 PPM SKIN NOTATION
N-HEXANE 110-54-3 ACGIH TWA: 50 PPM SKIN NOTATION
N-HEXANE 110-54-3 OSHA TWA:
1800 MG/M3
(500 PPM)
ZINC OXIDE 1314-13-2 ACGIH TWA (RESPIRABLE
FRACTION):
2 MG/M3
STEL (RESPIRABLE
FRACTION):
10 MG/M3
ZINC OXIDE 1314-13-2 OSHA TWA (AS FUME):
5 MG/M3
TWA (AS TOTAL
DUST): 15 MG/M3
TWA (RESPIRABLE
FRACTION):
5 MG/M3
ACETONE 67-64-1 OSHA TWA:
2400 MG/M3
(1000 PPM)
ACETONE 67-64-1 ACGIH TWA: 500 PPM A4:
STEL: 750 PPM NOT CLASS. AS HUMAN
CARCIN
METHYL ETHYL 78-93-3 ACGIH TWA: 200 PPM
KETONE STEL: 300 PPM
METHYL ETHYL 78-93-3 OSHA TWA:
KETONE 590 MG/M3
(200 PPM)
ROSIN 8050-09-7 ACGIH LIMIT VALUE CNTRL ALL EXPOSR-
NOT LOW AS POSSIB,
ESTABLISHED: DERMAL/RESPIRATORY
SENSITIZER
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
USE GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR CONTROL
DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE, USE
RESPIRATORY PROTECTION EQUIPMENT. USE EXPLOSION-PROOF VENTILATION
EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING EYE/FACE PROTECTION(S) ARE RECOMMENDED:
INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT LOCAL
STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
NOTE:
NITRILE GLOVES MAY BE WORN OVER POLYMER LAMINATE GLOVES TO IMPROVE
DEXTERITY.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED:
POLYMER LAMINATE
IF THIS PRODUCT IS USED IN A MANNER THAT PRESENTS A HIGHER POTENTIAL FOR
EXPOSURE (EG. SPRAYING, HIGH SPLASH POTENTIAL ETC.), THEN USE OF PROTECTIVE
COVERALLS MAY BE NECESSARY. SELECT AND USE BODY PROTECTION TO PREVENT
CONTACT BASED ON THE RESULTS OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING PROTECTIVE CLOTHING MATERIAL(S) ARE RECOMMENDED:
APRON - POLYMER LAMINATE
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM.
BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT FROM THE FOLLOWING
RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
ORGANIC VAPORS AND PARTICULATES
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: LIQUID
ODOR, COLOR, GRADE: GREY/GREEN, STRONG PETROLEUM ODOR.
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NOT APPLICABLE
MELTING POINT: NOT APPLICABLE
BOILING POINT: >=56 DEG. C [DETAILS: ACETONE]
FLASH POINT: -7 DEG. F [TEST METHOD: CLOSED CUP] [DETAILS: N-HEXANE]
EVAPORATION RATE: >=2.0 [REF STD: WATER=1]
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLAMMABLE LIMITS (LEL): 1.0% VOLUME
FLAMMABLE LIMITS (UEL): 12.8% VOLUME
VAPOR PRESSURE: <=185 MMHg [@ 68 DEG. F]
VAPOR DENSITY: 2.0 [REF STD: AIR=1]
DENSITY: 0.815 G/ML
SPECIFIC GRAVITY: 0.815 [REF STD: WATER=1]
SOLUBILITY IN WATER: SLIGHT (LESS THAN 10%)
SOLUBILITY- NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/ WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: 200 - 450 CENTIPOISE [@ 27 DEG. C]
HAZARDOUS AIR POLLUTANTS: <=13.2% WEIGHT [TEST METHOD: CALCULATED]
VOC LESS H2O & EXEMPT SOLVENTS:
<=580 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
SOLIDS CONTENT: 12 - 25%
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN
CONDITIONS - SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID:
HEAT
SPARKS AND/OR FLAMES
10.5. INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
NONE KNOWN.
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING
COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY
PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
SKIN CONTACT:
SKIN IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, DRYNESS,
CRACKING, BLISTERING, AND PAIN.
ALLERGIC SKIN REACTION (NON-PHOTO INDUCED):
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, BLISTERING, AND ITCHING.
EYE CONTACT:
SEVERE EYE IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE SIGNIFICANT REDNESS, SWELLING, PAIN, TEARING,
CLOUDY APPEARANCE OF THE CORNEA, AND IMPAIRED VISION.
INGESTION:
GASTROINTESTINAL IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA, VOMITING
AND DIARRHEA.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
ADDITIONAL HEALTH EFFECTS:
SINGLE EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS:
CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION:
SIGNS/SYMPTOMS MAY INCLUDE HEADACHE, DIZZINESS, DROWSINESS, INCOORDINATION,
NAUSEA, SLOWED REACTION TIME, SLURRED SPEECH, GIDDINESS, AND
UNCONSCIOUSNESS.
PROLONGED OR REPEATED EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS:
OCULAR EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE BLURRED OR SIGNIFICANTLY IMPAIRED VISION.
AUDITORY EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE HEARING IMPAIRMENT, BALANCE DYSFUNCTION AND
RINGING IN THE EARS.
PERIPHERAL NEUROPATHY:
SIGNS/SYMPTOMS MAY INCLUDE TINGLING OR NUMBNESS OF THE EXTREMITIES,
INCOORDINATION, WEAKNESS OF THE HANDS AND FEET, TREMORS AND MUSCLE ATROPHY.
OLFACTORY EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE DECREASED ABILITY TO DETECT ODORS AND/OR
COMPLETE LOSS OF SMELL.
NEUROLOGICAL EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE PERSONALITY CHANGES, LACK OF COORDINATION,
SENSORY LOSS, TINGLING OR NUMBNESS OF THE EXTREMITIES, WEAKNESS, TREMORS,
AND/OR CHANGES IN BLOOD PRESSURE AND HEART RATE.
REPRODUCTIVE/DEVELOPMENTAL TOXICITY:
CONTAINS A CHEMICAL OR CHEMICALS WHICH CAN CAUSE BIRTH DEFECTS OR OTHER
REPRODUCTIVE HARM.
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT INHALATION- NO DATA AVAILABLE;
VAPOR (4 HR) CALCULATED ATE >50 MG/L
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE >5,000
MG/KG
PETROLEUM DISTILLATE DERMAL RABBIT LD50: >2,000 MG/KG
PETROLEUM DISTILLATE INHALATION- RAT LC50: 259 MG/L
VAPOR
(4 HOURS)
PETROLEUM DISTILLATE INGESTION RAT LD50: >5,000 MG/KG
N-HEXANE DERMAL RABBIT LD50: >2,000 MG/KG
N-HEXANE INHALATION- RAT LC50: 170 MG/L
VAPOR
(4 HOURS)
N-HEXANE INGESTION RAT LD50: >28,700 MG/KG
ACETONE DERMAL RABBIT LD50: >15,688 MG/KG
ACETONE INHALATION- RAT LC50: 76 MG/L
VAPOR
(4 HOURS)
ACETONE INGESTION RAT LD50: 5,800 MG/KG
METHYL ETHYL KETONE DERMAL RABBIT LD50: >8,050 MG/KG
METHYL ETHYL KETONE INHALATION- RAT LC50: 34.5 MG/L
VAPOR
(4 HOURS)
METHYL ETHYL KETONE INGESTION RAT LD50: 2,737 MG/KG
POLYCHLOROPRENE DERMAL LD50:
ESTIMATED TO BE
>5,000 MG/KG
POLYCHLOROPRENE INGESTION RAT LD50: >20,000 MG/KG
MAGNESIUM RESINATE INGESTION LD50:
ESTIMATED TO BE
2,000 - 5,000 MG/KG
TOLUENE DERMAL RAT LD50: 12,000 MG/KG
TOLUENE INHALATION- RAT LC50: 30 MG/L
VAPOR
(4 HOURS)
TOLUENE INGESTION RAT LD50: 5,550 MG/KG
ZINC OXIDE DERMAL LD50:
ESTIMATED TO BE
>5,000 MG/KG
ZINC OXIDE INHALATION- RAT LC50: >5.7 MG/L
DUST/MIST
(4 HOURS)
ZINC OXIDE INGESTION RAT LD50: >5,000 MG/KG
ROSIN DERMAL RABBIT LD50: >2,500 MG/KG
ROSIN INGESTION RAT LD50: 7,600 MG/KG
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
PETROLEUM DISTILLATE RABBIT IRRITANT
N-HEXANE HUMAN MILD IRRITANT
AND
ANIMAL
ACETONE MOUSE MINIMAL IRRITATION
METHYL ETHYL KETONE RABBIT MINIMAL IRRITATION
POLYCHLOROPRENE HUMAN NO SIGNIFICANT IRRITATION
TOLUENE RABBIT IRRITANT
ZINC OXIDE HUMAN NO SIGNIFICANT IRRITATION
AND
ANIMAL
ROSIN RABBIT NO SIGNIFICANT IRRITATION
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
PETROLEUM DISTILLATE RABBIT MILD IRRITANT
N-HEXANE RABBIT MILD IRRITANT
ACETONE RABBIT SEVERE IRRITANT
METHYL ETHYL KETONE RABBIT SEVERE IRRITANT
POLYCHLOROPRENE PROFESSIONAL NO SIGNIFICANT IRRITATION
JUDGEMENT
TOLUENE RABBIT MODERATE IRRITANT
ZINC OXIDE RABBIT MILD IRRITANT
ROSIN RABBIT MILD IRRITANT
SKIN SENSITIZATION:
NAME SPECIES VALUE
PETROLEUM DISTILLATE GUINEA NOT SENSITIZING
PIG
N-HEXANE HUMAN NOT SENSITIZING
TOLUENE GUINEA NOT SENSITIZING
PIG
ZINC OXIDE GUINEA SOME POSITIVE DATA EXIST,
PIG BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
ROSIN GUINEA SENSITIZING
PIG
RESPIRATORY SENSITIZATION:
NAME SPECIES VALUE
ROSIN HUMAN SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
PETROLEUM DISTILLATE IN VITRO NOT MUTAGENIC
N-HEXANE IN VITRO NOT MUTAGENIC
N-HEXANE IN VIVO NOT MUTAGENIC
ACETONE IN VIVO NOT MUTAGENIC
ACETONE IN VITRO SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
METHYL ETHYL KETONE IN VITRO NOT MUTAGENIC
TOLUENE IN VITRO NOT MUTAGENIC
TOLUENE IN VIVO NOT MUTAGENIC
ZINC OXIDE IN VITRO SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
ZINC OXIDE IN VIVO SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
N-HEXANE DERMAL MOUSE NOT CARCINOGENIC
N-HEXANE INHALATION MOUSE SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
ACETONE NOT MULTIPLE NOT CARCINOGENIC
SPECIFIED ANIMAL
SPECIES
METHYL ETHYL INHALATION HUMAN NOT CARCINOGENIC
KETONE
TOLUENE DERMAL MOUSE SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
TOLUENE INGESTION RAT SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
TOLUENE INHALATION MOUSE SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE SPECIES TEST RESULT EXPOSURE
DURATION
N-HEXANE INGESTION NOT TOXIC TO MOUSE NOAEL: DURING
DEVELOPMENT 2,200 ORGANOGENESIS
MG/KG/DAY
N-HEXANE INHALATION SOME POSITIVE RAT NOAEL: DURING
DEVELOPMENTAL 0.7 MG/L GESTATION
DATA EXIST,
BUT THE DATA
ARE NOT
SUFFICIENT
FOR
CLASSIFICATION
N-HEXANE INGESTION TOXIC TO MALE RAT NOAEL: 90 DAYS
REPRODUCTION 1,140
MG/KG/DAY
N-HEXANE INHALATION TOXIC TO MALE RAT LOAEL: 28 DAYS
REPRODUCTION 3.52 MG/L
ACETONE INGESTION NOT TOXIC TO MOUSE NOAEL: 13 WEEKS
FEMALE 11,298
REPRODUCTION MG/KG/DAY
ACETONE INGESTION SOME POSITIVE RAT NOAEL: 13 WEEKS
MALE 1,700
REPRODUCTIVE MG/KG/DAY
DATA EXIST,
BUT THE DATA
ARE NOT
SUFFICIENT FOR
CLASSIFICATION
ACETONE INHALATION SOME POSITIVE RAT NOAEL: DURING
DEVELOPMENTAL 5.2 MG/L ORGANOGENESIS
DATA EXIST,
BUT THE DATA
ARE NOT
SUFFICIENT
FOR
CLASSIFICATION
METHYL INHALATION NOT TOXIC TO RAT NOAEL: 90 DAYS
ETHYL FEMALE 14.7 MG/L
KETONE REPRODUCTION
METHYL INHALATION NOT TOXIC TO RAT NOAEL: 90 DAYS
ETHYL MALE 14.7 MG/L
KETONE REPRODUCTION
METHYL INHALATION SOME POSITIVE RAT LOAEL: DURING
ETHYL DEVELOPMENTAL 8.8 MG/L GESTATION
KETONE DATA EXIST,
BUT THE DATA
ARE NOT
SUFFICIENT FOR
CLASSIFICATION
TOLUENE INHALATION SOME POSITIVE HUMAN NOAEL: OCCUPATIONAL
FEMALE NOT EXPOSURE
REPRODUCTIVE AVAILABLE
DATA EXIST,
BUT THE DATA
ARE NOT
SUFFICIENT FOR
CLASSIFICATION
TOLUENE INHALATION SOME POSITIVE RAT NOAEL: 1 GENERATION
MALE 2.3 MG/L
REPRODUCTIVE
DATA EXIST,
BUT THE DATA
ARE NOT
SUFFICIENT FOR
CLASSIFICATION
TOLUENE INGESTION TOXIC TO RAT LOAEL: DURING
DEVELOPMENT 520 GESTATION
MG/KG/DAY
TOLUENE INHALATION TOXIC TO HUMAN NOAEL: POISONING
DEVELOPMENT NOT AND/OR ABUSE
AVAILABLE
ZINC INGESTION SOME POSITIVE MULTIPLE NOAEL: PREMATING &
OXIDE REPRODUCTIVE/ ANIMAL 125 DURING
DEVELOPMENTAL SPECIES MG/KG/DAY GESTATION
DATA EXIST,
BUT THE DATA
ARE NOT
SUFFICIENT FOR
CLASSIFICATION
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
PETROLEUM INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS
DISTILLATE SYSTEM DEPRESSION OR HUMAN NOAEL NOT
DIZZINESS
PETROLEUM INHALATION RESPIRATORY IRRITATION SOME POSITIVE DATA EXIST,
DISTILLATE BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
N-HEXANE INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
N-HEXANE INHALATION RESPIRATORY IRRITATION SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
N-HEXANE INHALATION RESPIRATORY SYSTEM SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
ACETONE INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR
SYSTEM DEPRESSION DIZZINESS
ACETONE INHALATION RESPIRATORY IRRITATION SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
ACETONE INHALATION IMMUNE SYSTEM SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
ACETONE INHALATION LIVER SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
ACETONE INGESTION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR
SYSTEM DEPRESSION DIZZINESS
METHYL ETHYL INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR
KETONE SYSTEM DEPRESSION DIZZINESS
METHYL ETHYL INHALATION RESPIRATORY IRRITATION SOME POSITIVE DATA EXIST,
KETONE BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
METHYL ETHYL INGESTION LIVER SOME POSITIVE DATA EXIST,
KETONE BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
METHYL ETHYL INGESTION KIDNEY AND/OR SOME POSITIVE DATA EXIST,
KETONE BLADDER BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
TOLUENE INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR
SYSTEM DEPRESSION DIZZINESS
TOLUENE INHALATION RESPIRATORY IRRITATION SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
TOLUENE INHALATION IMMUNE SYSTEM SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
TOLUENE INGESTION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR
SYSTEM DEPRESSION DIZZINESS
NAME SPECIES TEST RESULT EXPOSURE DURATION
PETROLEUM HUMAN NOAEL: NOT AVAILABLE
DISTILLATE AND
ANIMAL
PETROLEUM NOAEL: NOT AVAILABLE
DISTILLATE
N-HEXANE HUMAN NOAEL: NOT AVAILABLE NOT AVAILABLE
N-HEXANE RABBIT NOAEL: NOT AVAILABLE 8 HOURS
N-HEXANE RAT NOAEL: 24.6 MG/L 8 HOURS
ACETONE HUMAN NOAEL: NOT AVAILABLE
ACETONE HUMAN NOAEL: NOT AVAILABLE
ACETONE HUMAN NOAEL: 1.19 MG/L 6 HOURS
ACETONE GUINEA NOAEL: NOT AVAILABLE
PIG
ACETONE HUMAN NOAEL: NOT AVAILABLE POISONING
AND/OR ABUSE
METHYL ETHYL OFFICIAL NOAEL: NOT AVAILABLE
KETONE CLASSIFICATION
METHYL ETHYL HUMAN NOAEL: NOT AVAILABLE
KETONE
METHYL ETHYL RAT NOAEL: NOT AVAILABLE NOT APPLICABLE
KETONE
METHYL ETHYL RAT LOAEL: 1,080 MG/KG NOT APPLICABLE
KETONE
TOLUENE HUMAN NOAEL: NOT AVAILABLE
TOLUENE HUMAN NOAEL: NOT AVAILABLE
TOLUENE MOUSE NOAEL: 0.004 MG/L 3 HOURS
TOLUENE HUMAN NOAEL: NOT AVAILABLE POISONING
AND/OR ABUSE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
N-HEXANE INHALATION PERIPHERAL NERVOUS CAUSES DAMAGE TO ORGANS
SYSTEM THROUGH PROLONGED OR
REPEATED EXPOSURE
N-HEXANE INHALATION RESPIRATORY SYSTEM SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
N-HEXANE INHALATION LIVER SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
N-HEXANE INHALATION KIDNEY AND/OR SOME POSITIVE DATA EXIST,
BLADDER BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
N-HEXANE INHALATION HEMATOPOIETIC SOME POSITIVE DATA EXIST,
SYSTEM BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
N-HEXANE INHALATION AUDITORY SYSTEM SOME POSITIVE DATA EXIST,
IMMUNE SYSTEM BUT THE DATA ARE NOT
EYES SUFFICIENT FOR
CLASSIFICATION
N-HEXANE INHALATION HEART ALL DATA ARE NEGATIVE
SKIN
ENDOCRINE SYSTEM
N-HEXANE INGESTION PERIPHERAL NERVOUS SOME POSITIVE DATA EXIST,
SYSTEM BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
N-HEXANE INGESTION ENDOCRINE SYSTEM SOME POSITIVE DATA EXIST,
HEMATOPOIETIC BUT THE DATA ARE NOT
SYSTEM SUFFICIENT FOR
LIVER CLASSIFICATION
IMMUNE SYSTEM
KIDNEY AND/OR BLADDER
ACETONE DERMAL EYES SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
ACETONE INHALATION HEMATOPOIETIC SOME POSITIVE DATA EXIST,
SYSTEM BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
ACETONE INHALATION IMMUNE SYSTEM SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
ACETONE INHALATION KIDNEY AND/OR SOME POSITIVE DATA EXIST,
BLADDER BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
ACETONE INHALATION HEART ALL DATA ARE NEGATIVE
LIVER
ACETONE INGESTION KIDNEY AND/OR SOME POSITIVE DATA EXIST,
BLADDER BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
ACETONE INGESTION HEART SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
ACETONE INGESTION HEMATOPOIETIC SOME POSITIVE DATA EXIST,
SYSTEM BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
ACETONE INGESTION LIVER SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
ACETONE INGESTION EYES ALL DATA ARE NEGATIVE
ACETONE INGESTION RESPIRATORY SYSTEM ALL DATA ARE NEGATIVE
ACETONE INGESTION MUSCLES ALL DATA ARE NEGATIVE
ACETONE INGESTION SKIN ALL DATA ARE NEGATIVE
BONE, TEETH, NAILS,
AND/OR HAIR
METHYL ETHYL DERMAL NERVOUS SYSTEM ALL DATA ARE NEGATIVE
KETONE
METHYL ETHYL INHALATION LIVER SOME POSITIVE DATA EXIST,
KETONE KIDNEY AND/OR BUT THE DATA ARE NOT
BLADDER SUFFICIENT FOR
CLASSIFICATION
METHYL ETHYL INHALATION HEART ALL DATA ARE NEGATIVE
KETONE ENDOCRINE SYSTEM
BONE, TEETH, NAILS,
AND/OR HAIR
HEMATOPOIETIC SYSTEM
IMMUNE SYSTEM
MUSCLES
METHYL ETHYL INGESTION LIVER SOME POSITIVE DATA EXIST,
KETONE BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
METHYL ETHYL INGESTION NERVOUS SYSTEM ALL DATA ARE NEGATIVE
KETONE
TOLUENE INHALATION AUDITORY SYSTEM CAUSES DAMAGE TO ORGANS
NERVOUS SYSTEM THROUGH PROLONGED OR
EYES REPEATED EXPOSURE
OLFACTORY SYSTEM
TOLUENE INHALATION RESPIRATORY SYSTEM SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
TOLUENE INHALATION HEART SOME POSITIVE DATA EXIST,
LIVER BUT THE DATA ARE NOT
KIDNEY AND/OR BLADDER SUFFICIENT FOR
CLASSIFICATION
TOLUENE INHALATION ENDOCRINE SYSTEM SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
TOLUENE INHALATION IMMUNE SYSTEM SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
TOLUENE INHALATION BONE, TEETH, NAILS, SOME POSITIVE DATA EXIST,
AND/OR HAIR BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
TOLUENE INHALATION HEMATOPOIETIC SOME POSITIVE DATA EXIST,
SYSTEM BUT THE DATA ARE NOT
VASCULAR SYSTEM SUFFICIENT FOR
CLASSIFICATION
TOLUENE INGESTION NERVOUS SYSTEM SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
TOLUENE INGESTION HEART SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
TOLUENE INGESTION LIVER SOME POSITIVE DATA EXIST,
KIDNEY AND/OR BLADDER BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
TOLUENE INGESTION HEMATOPOIETIC SOME POSITIVE DATA EXIST,
SYSTEM BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
TOLUENE INGESTION ENDOCRINE SYSTEM SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
TOLUENE INGESTION IMMUNE SYSTEM SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
ZINC OXIDE INGESTION NERVOUS SYSTEM SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
ZINC OXIDE INGESTION ENDOCRINE SYSTEM SOME POSITIVE DATA EXIST,
HEMATOPOIETIC BUT THE DATA ARE NOT
SYSTEM SUFFICIENT FOR
KIDNEY AND/OR BLADDER CLASSIFICATION
NAME SPECIES TEST RESULT EXPOSURE DURATION
N-HEXANE HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL
EXPOSURE
N-HEXANE MOUSE LOAEL: 1.76 MG/L 13 WEEKS
N-HEXANE RAT NOAEL: NOT AVAILABLE 6 MONTHS
N-HEXANE RAT LOAEL: 1.76 MG/L 6 MONTHS
N-HEXANE MOUSE NOAEL: 35.2 MG/L 13 WEEKS
N-HEXANE HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL
EXPOSURE
N-HEXANE RAT NOAEL: 1.76 MG/L 6 MONTHS
N-HEXANE RAT NOAEL: 1,140 MG/KG/DAY 90 DAYS
N-HEXANE RAT NOAEL: NOT AVAILABLE 13 WEEKS
ACETONE GUINEA NOAEL: NOT AVAILABLE 3 WEEKS
PIG
ACETONE HUMAN NOAEL: 3 MG/L 6 WEEKS
ACETONE HUMAN NOAEL: 1.19 MG/L 6 DAYS
ACETONE GUINEA NOAEL: 119 MG/L NOT AVAILABLE
PIG
ACETONE RAT NOAEL: 45 MG/L 8 WEEKS
ACETONE RAT NOAEL: 900 MG/KG/DAY 13 WEEKS
ACETONE RAT NOAEL: 2,500 MG/KG/DAY 13 WEEKS
ACETONE RAT NOAEL: 200 MG/KG/DAY 13 WEEKS
ACETONE MOUSE NOAEL: 3,896 MG/KG/DAY 14 DAYS
ACETONE RAT NOAEL: 3,400 MG/KG/DAY 13 WEEKS
ACETONE RAT NOAEL: 2,500 MG/KG/DAY 13 WEEKS
ACETONE RAT NOAEL: 2,500 MG/KG 13 WEEKS
ACETONE MOUSE NOAEL: 11,298 MG/KG/DAY 13 WEEKS
METHYL ETHYL GUINEA NOAEL: NOT AVAILABLE 31 WEEKS
KETONE PIG
METHYL ETHYL RAT NOAEL: 14.7 MG/L 90 DAYS
KETONE
METHYL ETHYL RAT NOAEL: 14.7 MG/L 90 DAYS
KETONE
METHYL ETHYL RAT NOAEL: NOT AVAILABLE 7 DAYS
KETONE
METHYL ETHYL RAT NOAEL: 173 MG/KG/DAY 90 DAYS
KETONE
TOLUENE HUMAN NOAEL: NOT AVAILABLE POISONING
AND/OR ABUSE
TOLUENE RAT LOAEL: 2.3 MG/L 15 MONTHS
TOLUENE RAT NOAEL: 11.3 MG/L 15 WEEKS
TOLUENE RAT NOAEL: 1.1 MG/L 4 WEEKS
TOLUENE MOUSE NOAEL: NOT AVAILABLE 20 DAYS
TOLUENE MOUSE NOAEL: 1.1 MG/L 8 WEEKS
TOLUENE HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL
EXPOSURE
TOLUENE RAT NOAEL: 625 MG/KG/DAY 13 WEEKS
TOLUENE RAT NOAEL: 2,500 MG/KG/DAY 13 WEEKS
TOLUENE MULTIPLE NOAEL: 2,500 MG/KG/DAY 13 WEEKS
ANIMAL
SPECIES
TOLUENE MOUSE NOAEL: 600 MG/KG/DAY 14 DAYS
TOLUENE MOUSE NOAEL: 105 MG/KG/DAY 28 DAYS
TOLUENE MOUSE NOAEL: 105 MG/KG/DAY 4 WEEKS
ZINC OXIDE RAT NOAEL: 600 MG/KG/DAY 10 DAYS
ZINC OXIDE OTHER NOAEL: 500 MG/KG/DAY 6 MONTHS
ASPIRATION HAZARD:
NAME VALUE
PETROLEUM DISTILLATE ASPIRATION HAZARD
N-HEXANE ASPIRATION HAZARD
TOLUENE ASPIRATION HAZARD
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/ CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
INCINERATE IN A PERMITTED WASTE INCINERATION FACILITY. AS A DISPOSAL
ALTERNATIVE, UTILIZE AN ACCEPTABLE PERMITTED WASTE DISPOSAL FACILITY.
EMPTY DRUMS/BARRELS/CONTAINERS USED FOR TRANSPORTING AND HANDLING
HAZARDOUS CHEMICALS (CHEMICAL SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED
AS HAZARDOUS AS PER APPLICABLE REGULATIONS) SHALL BE CONSIDERED, STORED,
TREATED & DISPOSED OF AS HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY
APPLICABLE WASTE REGULATIONS. CONSULT WITH THE RESPECTIVE REGULATING
AUTHORITIES TO DETERMINE THE AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
EPA HAZARDOUS WASTE NUMBER (RCRA):
D001 (IGNITABLE)
D035 (METHYL ETHYL KETONE)
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
311/312 HAZARD CATEGORIES:
FIRE HAZARD: YES
PRESSURE HAZARD: NO
REACTIVITY HAZARD: NO
IMMEDIATE HAZARD: YES
DELAYED HAZARD: YES
SECTION 313 TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF THAT
SECTION AND 40 CFR PART 372 (EPCRA):
INGREDIENT C.A.S. NO % BY WT
TOLUENE 108-88-3 1 - 10
N-HEXANE (HEXANE) 110-54-3 5 - 20
N-HEXANE 110-54-3 5 - 20
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 2
FLAMMABILITY 3
INSTABILITY 0
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED
FOR USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED ON
THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO INCLUDE
THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT ARE KNOWN
TO BE GENERATED IN SIGNIFICANT QUANTITIES.
DOCUMENT GROUP: 10-2789-5
VERSION NUMBER: 41.01
ISSUE DATE: 04/24/15
SUPERCEDES DATE: 01/12/15
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
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TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED IN
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INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
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