| Common Name: | TITEBOND PROVANTAGE DRYWALL ADHESIVE, 5342 |
| Manufacturer: | FRANKLIN INTERNATIONAL |
| SDS Revision Date: | 6/2/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 5EAW2 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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FRANKLIN INTERNATIONAL
SAFETY DATA SHEET
TITEBOND PROVANTAGE DRYWALL ADHESIVE
| SECTION 1. IDENTIFICATION |  |
GHS PRODUCT IDENTIFIER: TITEBOND PROVANTAGE DRYWALL ADHESIVE
PRODUCT TYPE: LIQUID.
ADDRESS:
FRANKLIN INTERNATIONAL
2020 BRUCK STREET
COLUMBUS, OH 43207
CONTACT PERSON: FRANKLIN TECHNICAL SERVICES
TELEPHONE: (800) 877-4583
IN CASE OF EMERGENCY:
FRANKLIN SECURITY: (614) 445-1300
PRODUCT CODE: 5342
DATE OF REVISION: 6/2/2015.
PRINT DATE: 6/3/2015.
CHEMTREC (24 HOUR): (800) 424 - 9300
CHEMTREC INTERNATIONAL: (703) 527 - 3887
RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST: NOT APPLICABLE.
| SECTION 2. HAZARDS IDENTIFICATION | |
OSHA/HCS STATUS:
THIS MATERIAL IS CONSIDERED HAZARDOUS BY THE OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200).
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
FLAMMABLE LIQUIDS: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2
CARCINOGENICITY (INHALATION): CATEGORY 2
TOXIC TO REPRODUCTION (FERTILITY) (INHALATION): CATEGORY 2
TOXIC TO REPRODUCTION (UNBORN CHILD) (INHALATION): CATEGORY 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (RESPIRATORY TRACT
IRRITATION): CATEGORY 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (CENTRAL NERVOUS SYSTEM
(CNS), KIDNEYS AND LIVER) (INHALATION): CATEGORY 1
GHS LABEL ELEMENTS:
HAZARD PICTOGRAMS:
FLAME
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
HIGHLY FLAMMABLE LIQUID AND VAPOR.
CAUSES SERIOUS EYE IRRITATION.
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD IF INHALED.
SUSPECTED OF CAUSING CANCER IF INHALED.
MAY CAUSE RESPIRATORY IRRITATION.
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE IF INHALED.
(CENTRAL NERVOUS SYSTEM (CNS), KIDNEYS, LIVER)
PRECAUTIONARY STATEMENTS:
GENERAL:
READ LABEL BEFORE USE. KEEP OUT OF REACH OF CHILDREN. IF MEDICAL ADVICE IS
NEEDED, HAVE PRODUCT CONTAINER OR LABEL AT HAND.
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. USE PERSONAL PROTECTIVE
EQUIPMENT AS REQUIRED. WEAR PROTECTIVE GLOVES. WEAR EYE OR FACE PROTECTION.
KEEP AWAY FROM HEAT, HOT SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION
SOURCES. NO SMOKING. USE EXPLOSION-PROOF ELECTRICAL, VENTILATING, LIGHTING
AND ALL MATERIAL-HANDLING EQUIPMENT. USE ONLY NON-SPARKING TOOLS. TAKE
PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE. KEEP CONTAINER TIGHTLY
CLOSED. USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA. DO NOT BREATHE
VAPOR. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH HANDS
THOROUGHLY AFTER HANDLING.
RESPONSE: GET MEDICAL ATTENTION IF YOU FEEL UNWELL.
IF EXPOSED OR CONCERNED: GET MEDICAL ATTENTION.
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. CALL A POISON CENTER OR PHYSICIAN IF YOU FEEL UNWELL.
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH WATER OR
SHOWER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION.
STORAGE: STORE LOCKED UP. STORE IN A WELL-VENTILATED PLACE. KEEP COOL.
DISPOSAL:
DISPOSE OF CONTENTS AND CONTAINER IN ACCORDANCE WITH ALL LOCAL, REGIONAL,
NATIONAL AND INTERNATIONAL REGULATIONS.
SUPPLEMENTAL LABEL ELEMENTS:
AVOID CONTACT WITH SKIN AND CLOTHING. WASH THOROUGHLY AFTER HANDLING.
HAZARDS NOT OTHERWISE CLASSIFIED:
PROLONGED OR REPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
HAZARDOUS INGREDIENTS:
UNITED STATES:
NAME CAS NUMBER %
METHYL ACETATE 79-20-9 25 - 50
N-HEXANE 110-54-3 1 - 5
METHANOL 67-56-1 0.1 - 0.5
VINYL ACETATE 108-05-4 0.1 - 0.5
CANADA:
NAME CAS NUMBER %
METHYL ACETATE 79-20-9 25 - 50
N-HEXANE 110-54-3 1 - 5
METHANOL 67-56-1 0.1 - 0.5
VINYL ACETATE 108-05-4 0.1 - 0.5
MEXICO:
NAME CAS UN NUMBER % IDLH CLASSIFICATION
NUMBER H F R SPECIAL
METHYL ACETATE 79-20-9 UN1993 25 - 50 3100 PPM 2 3 0
N-HEXANE 110-54-3 UN1993 1 - 5 1100 PPM 1 3 1
ANY CONCENTRATION SHOWN AS A RANGE IS TO PROTECT CONFIDENTIALITY OR IS DUE
TO BATCH VARIATION.
THERE ARE NO ADDITIONAL INGREDIENTS PRESENT WHICH, WITHIN THE CURRENT
KNOWLEDGE OF THE SUPPLIER AND IN THE CONCENTRATIONS APPLICABLE, ARE
CLASSIFIED AS HAZARDOUS TO HEALTH OR THE ENVIRONMENT AND HENCE REQUIRE
REPORTING IN THIS SECTION.
OCCUPATIONAL EXPOSURE LIMITS, IF AVAILABLE, ARE LISTED IN SECTION 8.
| SECTION 4. FIRST AID MEASURES | |
DESCRIPTION OF NECESSARY FIRST AID MEASURES:
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER, OCCASIONALLY LIFTING THE UPPER
AND LOWER EYELIDS. CHECK FOR AND REMOVE ANY CONTACT LENSES. CONTINUE TO
RINSE FOR AT LEAST 10 MINUTES. GET MEDICAL ATTENTION.
INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. IF IT IS SUSPECTED THAT FUMES ARE STILL PRESENT, THE RESCUER
SHOULD WEAR AN APPROPRIATE MASK OR SELF-CONTAINED BREATHING APPARATUS. IF
NOT BREATHING, IF BREATHING IS IRREGULAR OR IF RESPIRATORY ARREST OCCURS,
PROVIDE ARTIFICIAL RESPIRATION OR OXYGEN BY TRAINED PERSONNEL. IT MAY BE
DANGEROUS TO THE PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH RESUSCITATION.
GET MEDICAL ATTENTION. IF NECESSARY, CALL A POISON CENTER OR PHYSICIAN. IF
UNCONSCIOUS, PLACE IN RECOVERY POSITION AND GET MEDICAL ATTENTION
IMMEDIATELY. MAINTAIN AN OPEN AIRWAY. LOOSEN TIGHT CLOTHING SUCH AS A
COLLAR, TIE, BELT OR WAISTBAND.
SKIN CONTACT:
WASH SKIN THOROUGHLY WITH SOAP AND WATER OR USE RECOGNIZED SKIN CLEANSER.
REMOVE CONTAMINATED CLOTHING AND SHOES. CONTINUE TO RINSE FOR AT LEAST 10
MINUTES. GET MEDICAL ATTENTION. WASH CLOTHING BEFORE REUSE. CLEAN SHOES
THOROUGHLY BEFORE REUSE.
INGESTION:
WASH OUT MOUTH WITH WATER. REMOVE DENTURES IF ANY. REMOVE VICTIM TO FRESH
AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR BREATHING. IF MATERIAL
HAS BEEN SWALLOWED AND THE EXPOSED PERSON IS CONSCIOUS, GIVE SMALL
QUANTITIES OF WATER TO DRINK. STOP IF THE EXPOSED PERSON FEELS SICK AS
VOMITING MAY BE DANGEROUS. DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO
BY MEDICAL PERSONNEL. IF VOMITING OCCURS, THE HEAD SHOULD BE KEPT LOW SO
THAT VOMIT DOES NOT ENTER THE LUNGS. GET MEDICAL ATTENTION. NEVER GIVE
ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF UNCONSCIOUS, PLACE IN
RECOVERY POSITION AND GET MEDICAL ATTENTION IMMEDIATELY. MAINTAIN AN OPEN
AIRWAY. LOOSEN TIGHT CLOTHING SUCH AS A COLLAR, TIE, BELT OR WAISTBAND.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INHALATION: MAY CAUSE RESPIRATORY IRRITATION.
SKIN CONTACT: DEFATTING TO THE SKIN. MAY CAUSE SKIN DRYNESS AND IRRITATION.
INGESTION: IRRITATING TO MOUTH, THROAT AND STOMACH.
OVER-EXPOSURE SIGNS/SYMPTOMS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN OR IRRITATION
WATERING
REDNESS
INHALATION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
RESPIRATORY TRACT IRRITATION
COUGHING
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
IRRITATION
DRYNESS
CRACKING
INGESTION: NO SPECIFIC DATA.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED, IF
NECESSARY:
NOTES TO PHYSICIAN:
TREAT SYMPTOMATICALLY. CONTACT POISON TREATMENT SPECIALIST IMMEDIATELY IF
LARGE QUANTITIES HAVE BEEN INGESTED OR INHALED.
SPECIFIC TREATMENTS: NO SPECIFIC TREATMENT.
PROTECTION OF FIRST-AIDERS:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. IF IT IS SUSPECTED THAT FUMES ARE STILL PRESENT, THE RESCUER
SHOULD WEAR AN APPROPRIATE MASK OR SELF-CONTAINED BREATHING APPARATUS. IT
MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH
RESUSCITATION.
SEE TOXICOLOGICAL INFORMATION (SECTION 11)
| SECTION 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE DRY CHEMICAL, CO2, WATER SPRAY (FOG) OR FOAM.
UNSUITABLE EXTINGUISHING MEDIA: DO NOT USE WATER JET.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
HIGHLY FLAMMABLE LIQUID AND VAPOR. IN A FIRE OR IF HEATED, A PRESSURE
INCREASE WILL OCCUR AND THE CONTAINER MAY BURST, WITH THE RISK OF A
SUBSEQUENT EXPLOSION. RUNOFF TO SEWER MAY CREATE FIRE OR EXPLOSION HAZARD.
HAZARDOUS THERMAL DECOMPOSITION PRODUCTS:
DECOMPOSITION PRODUCTS MAY INCLUDE THE FOLLOWING MATERIALS:
CARBON DIOXIDE
CARBON MONOXIDE
SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
PROMPTLY ISOLATE THE SCENE BY REMOVING ALL PERSONS FROM THE VICINITY OF THE
INCIDENT IF THERE IS A FIRE. NO ACTION SHALL BE TAKEN INVOLVING ANY
PERSONAL RISK OR WITHOUT SUITABLE TRAINING. MOVE CONTAINERS FROM FIRE AREA
IF THIS CAN BE DONE WITHOUT RISK. USE WATER SPRAY TO KEEP FIRE-EXPOSED
CONTAINERS COOL.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
FIRE-FIGHTERS SHOULD WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND
SELF-CONTAINED BREATHING APPARATUS (SCBA) WITH A FULL FACE-PIECE OPERATED
IN POSITIVE PRESSURE MODE.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
FOR NON-EMERGENCY PERSONNEL:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. EVACUATE SURROUNDING AREAS. KEEP UNNECESSARY AND UNPROTECTED
PERSONNEL FROM ENTERING. DO NOT TOUCH OR WALK THROUGH SPILLED MATERIAL.
SHUT OFF ALL IGNITION SOURCES. NO FLARES, SMOKING OR FLAMES IN HAZARD AREA.
AVOID BREATHING VAPOR OR MIST. PROVIDE ADEQUATE VENTILATION. WEAR
APPROPRIATE RESPIRATOR WHEN VENTILATION IS INADEQUATE. PUT ON APPROPRIATE
PERSONAL PROTECTIVE EQUIPMENT.
FOR EMERGENCY RESPONDERS:
IF SPECIALISED CLOTHING IS REQUIRED TO DEAL WITH THE SPILLAGE, TAKE NOTE OF
ANY INFORMATION IN SECTION 8 ON SUITABLE AND UNSUITABLE MATERIALS. SEE ALSO
THE INFORMATION IN "FOR NON-EMERGENCY PERSONNEL".
ENVIRONMENTAL PRECAUTIONS:
AVOID DISPERSAL OF SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL,
WATERWAYS, DRAINS AND SEWERS. INFORM THE RELEVANT AUTHORITIES IF THE
PRODUCT HAS CAUSED ENVIRONMENTAL POLLUTION (SEWERS, WATERWAYS, SOIL OR
AIR).
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SMALL SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. USE SPARK-PROOF
TOOLS AND EXPLOSION-PROOF EQUIPMENT. DILUTE WITH WATER AND MOP UP IF
WATER-SOLUBLE. ALTERNATIVELY, OR IF WATER-INSOLUBLE, ABSORB WITH AN INERT
DRY MATERIAL AND PLACE IN AN APPROPRIATE WASTE DISPOSAL CONTAINER. DISPOSE
OF VIA A LICENSED WASTE DISPOSAL CONTRACTOR.
LARGE SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. USE SPARK-PROOF
TOOLS AND EXPLOSION-PROOF EQUIPMENT. APPROACH RELEASE FROM UPWIND. PREVENT
ENTRY INTO SEWERS, WATER COURSES, BASEMENTS OR CONFINED AREAS. WASH
SPILLAGES INTO AN EFFLUENT TREATMENT PLANT OR PROCEED AS FOLLOWS. CONTAIN
AND COLLECT SPILLAGE WITH NON-COMBUSTIBLE, ABSORBENT MATERIAL E.G. SAND,
EARTH, VERMICULITE OR DIATOMACEOUS EARTH AND PLACE IN CONTAINER FOR
DISPOSAL ACCORDING TO LOCAL REGULATIONS (SEE SECTION 13). DISPOSE OF VIA A
LICENSED WASTE DISPOSAL CONTRACTOR. CONTAMINATED ABSORBENT MATERIAL MAY
POSE THE SAME HAZARD AS THE SPILLED PRODUCT.
NOTE:
SEE SECTION 1 FOR EMERGENCY CONTACT INFORMATION AND SECTION 13 FOR WASTE
DISPOSAL.
| SECTION 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
PROTECTIVE MEASURES:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8). AVOID
EXPOSURE - OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. AVOID EXPOSURE DURING
PREGNANCY. DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND
UNDERSTOOD. DO NOT GET IN EYES OR ON SKIN OR CLOTHING. DO NOT BREATHE VAPOR
OR MIST. DO NOT INGEST. USE ONLY WITH ADEQUATE VENTILATION. WEAR
APPROPRIATE RESPIRATOR WHEN VENTILATION IS INADEQUATE. DO NOT ENTER STORAGE
AREAS AND CONFINED SPACES UNLESS ADEQUATELY VENTILATED. KEEP IN THE
ORIGINAL CONTAINER OR AN APPROVED ALTERNATIVE MADE FROM A COMPATIBLE
MATERIAL, KEPT TIGHTLY CLOSED WHEN NOT IN USE. STORE AND USE AWAY FROM
HEAT, SPARKS, OPEN FLAME OR ANY OTHER IGNITION SOURCE. USE EXPLOSION-PROOF
ELECTRICAL (VENTILATING, LIGHTING AND MATERIAL HANDLING) EQUIPMENT. USE
ONLY NON-SPARKING TOOLS. TAKE PRECAUTIONARY MEASURES AGAINST ELECTROSTATIC
DISCHARGES. EMPTY CONTAINERS RETAIN PRODUCT RESIDUE AND CAN BE HAZARDOUS.
DO NOT REUSE CONTAINER.
ADVICE ON GENERAL OCCUPATIONAL HYGIENE:
EATING, DRINKING AND SMOKING SHOULD BE PROHIBITED IN AREAS WHERE THIS
MATERIAL IS HANDLED, STORED AND PROCESSED. WORKERS SHOULD WASH HANDS AND
FACE BEFORE EATING, DRINKING AND SMOKING. REMOVE CONTAMINATED CLOTHING AND
PROTECTIVE EQUIPMENT BEFORE ENTERING EATING AREAS. SEE ALSO SECTION 8 FOR
ADDITIONAL INFORMATION ON HYGIENE MEASURES.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE BETWEEN THE FOLLOWING TEMPERATURES:
-17 TO 40 DEG. C (1.4 TO 104 DEG. F). STORE IN ACCORDANCE WITH LOCAL
REGULATIONS. STORE IN A SEGREGATED AND APPROVED AREA. STORE IN ORIGINAL
CONTAINER PROTECTED FROM DIRECT SUNLIGHT IN A DRY, COOL AND WELL-VENTILATED
AREA, AWAY FROM INCOMPATIBLE MATERIALS (SEE SECTION 10) AND FOOD AND DRINK.
STORE LOCKED UP. ELIMINATE ALL IGNITION SOURCES. SEPARATE FROM OXIDIZING
MATERIALS. KEEP CONTAINER TIGHTLY CLOSED AND SEALED UNTIL READY FOR USE.
CONTAINERS THAT HAVE BEEN OPENED MUST BE CAREFULLY RESEALED AND KEPT
UPRIGHT TO PREVENT LEAKAGE. DO NOT STORE IN UNLABELED CONTAINERS. USE
APPROPRIATE CONTAINMENT TO AVOID ENVIRONMENTAL CONTAMINATION.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
UNITED STATES:
OCCUPATIONAL EXPOSURE LIMITS:
INGREDIENT NAME EXPOSURE LIMITS
METHYL ACETATE ACGIH TLV (UNITED STATES, 4/2014).
TWA: 200 PPM 8 HOURS.
TWA: 606 MG/M3 8 HOURS.
STEL: 250 PPM 15 MINUTES.
STEL: 757 MG/M3 15 MINUTES.
OSHA PEL 1989 (UNITED STATES, 3/1989).
TWA: 200 PPM 8 HOURS.
TWA: 610 MG/M3 8 HOURS.
STEL: 250 PPM 15 MINUTES.
STEL: 760 MG/M3 15 MINUTES.
NIOSH REL (UNITED STATES, 10/2013).
TWA: 200 PPM 10 HOURS.
TWA: 610 MG/M3 10 HOURS.
STEL: 250 PPM 15 MINUTES.
STEL: 760 MG/M3 15 MINUTES.
OSHA PEL (UNITED STATES, 2/2013).
TWA: 200 PPM 8 HOURS.
TWA: 610 MG/M3 8 HOURS.
N-HEXANE OSHA PEL 1989 (UNITED STATES, 3/1989).
TWA: 50 PPM 8 HOURS.
TWA: 180 MG/M3 8 HOURS.
NIOSH REL (UNITED STATES, 10/2013).
TWA: 50 PPM 10 HOURS.
TWA: 180 MG/M3 10 HOURS.
ACGIH TLV (UNITED STATES, 4/2014).
ABSORBED THROUGH SKIN.
TWA: 50 PPM 8 HOURS.
OSHA PEL (UNITED STATES, 2/2013).
TWA: 500 PPM 8 HOURS.
TWA: 1800 MG/M3 8 HOURS.
METHANOL ACGIH TLV (UNITED STATES, 4/2014).
ABSORBED THROUGH SKIN.
TWA: 200 PPM 8 HOURS.
TWA: 262 MG/M3 8 HOURS.
STEL: 250 PPM 15 MINUTES.
STEL: 328 MG/M3 15 MINUTES.
OSHA PEL 1989 (UNITED STATES, 3/1989).
ABSORBED THROUGH SKIN.
TWA: 200 PPM 8 HOURS.
TWA: 260 MG/M3 8 HOURS.
STEL: 250 PPM 15 MINUTES.
STEL: 325 MG/M3 15 MINUTES.
NIOSH REL (UNITED STATES, 10/2013).
ABSORBED THROUGH SKIN.
TWA: 200 PPM 10 HOURS.
TWA: 260 MG/M3 10 HOURS.
STEL: 250 PPM 15 MINUTES.
STEL: 325 MG/M3 15 MINUTES.
OSHA PEL (UNITED STATES, 2/2013).
TWA: 200 PPM 8 HOURS.
TWA: 260 MG/M3 8 HOURS.
VINYL ACETATE ACGIH TLV (UNITED STATES, 4/2014).
TWA: 10 PPM 8 HOURS.
TWA: 35 MG/M3 8 HOURS.
STEL: 15 PPM 15 MINUTES.
STEL: 53 MG/M3 15 MINUTES.
OSHA PEL 1989 (UNITED STATES, 3/1989).
TWA: 10 PPM 8 HOURS.
TWA: 30 MG/M3 8 HOURS.
STEL: 20 PPM 15 MINUTES.
STEL: 60 MG/M3 15 MINUTES.
NIOSH REL (UNITED STATES, 10/2013).
CEIL: 4 PPM 15 MINUTES.
CEIL: 15 MG/M3 15 MINUTES.
CANADA:
OCCUPATIONAL EXPOSURE LIMITS:
INGREDIENT LIST NAME TWA (8 HOURS) STEL (15 MINS)
PPM MG/M3 OTHER PPM MG/M3 OTHER
METHYL ACETATE US ACGIH 4/2014 200 606 250 757
AB 4/2009 200 606 250 757
BC 4/2014 200 250
ON 1/2013 200 606 250 757
QC 1/2014 200 606 250 757
N-HEXANE US ACGIH 4/2014 50
AB 4/2009 50 176
BC 4/2014 20
ON 1/2013 50
QC 1/2014 50 176
METHANOL US ACGIH 4/2014 200 262 250 328
AB 4/2009 200 262 250 328
BC 4/2014 200 250
ON 1/2013 200 262 250 328
QC 1/2014 200 262 250 328
VINYL ACETATE US ACGIH 4/2014 10 35 15 53
AB 4/2009 10 35 15 53
BC 4/2014 10 15
ON 1/2013 10 35 15 53
QC 1/2014 10 35 15 53
INGREDIENT LIST NAME CEILING NOTATIONS
PPM MG/M3 OTHER
METHYL ACETATE US ACGIH 4/2014
AB 4/2009
BC 4/2014
ON 1/2013
QC 1/2014
N-HEXANE US ACGIH 4/2014 [1]
AB 4/2009 [1]
BC 4/2014 [1]
ON 1/2013 [1]
QC 1/2014 [1]
METHANOL US ACGIH 4/2014 [1]
AB 4/2009 [1]
BC 4/2014 [1]
ON 1/2013 [1]
QC 1/2014 [1]
VINYL ACETATE US ACGIH 4/2014
AB 4/2009
BC 4/2014
ON 1/2013
QC 1/2014
[1]ABSORBED THROUGH SKIN.
MEXICO:
OCCUPATIONAL EXPOSURE LIMITS:
INGREDIENT EXPOSURE LIMITS
METHYL ACETATE NOM-010-STPS (MEXICO, 9/2000).
LMPE-PPT: 200 PPM 8 HOURS.
LMPE-PPT: 610 MG/M3 8 HOURS.
LMPE-CT: 760 MG/M3 15 MINUTES.
LMPE-CT: 250 PPM 15 MINUTES.
N-HEXANE NOM-010-STPS (MEXICO, 9/2000).
LMPE-PPT: 50 PPM 8 HOURS.
LMPE-PPT: 176 MG/M3 8 HOURS.
CONSULT LOCAL AUTHORITIES FOR ACCEPTABLE EXPOSURE LIMITS.
APPROPRIATE ENGINEERING CONTROLS:
USE ONLY WITH ADEQUATE VENTILATION. USE PROCESS ENCLOSURES, LOCAL EXHAUST
VENTILATION OR OTHER ENGINEERING CONTROLS TO KEEP WORKER EXPOSURE TO
AIRBORNE CONTAMINANTS BELOW ANY RECOMMENDED OR STATUTORY LIMITS. THE
ENGINEERING CONTROLS ALSO NEED TO KEEP GAS, VAPOR OR DUST CONCENTRATIONS
BELOW ANY LOWER EXPLOSIVE LIMITS. USE EXPLOSION-PROOF VENTILATION
EQUIPMENT.
ENVIRONMENTAL EXPOSURE CONTROLS:
EMISSIONS FROM VENTILATION OR WORK PROCESS EQUIPMENT SHOULD BE CHECKED TO
ENSURE THEY COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION
LEGISLATION. IN SOME CASES, FUME SCRUBBERS, FILTERS OR ENGINEERING
MODIFICATIONS TO THE PROCESS EQUIPMENT WILL BE NECESSARY TO REDUCE
EMISSIONS TO ACCEPTABLE LEVELS.
INDIVIDUAL PROTECTION MEASURES:
HYGIENE MEASURES:
WASH HANDS, FOREARMS AND FACE THOROUGHLY AFTER HANDLING CHEMICAL PRODUCTS,
BEFORE EATING, SMOKING AND USING THE LAVATORY AND AT THE END OF THE WORKING
PERIOD. APPROPRIATE TECHNIQUES SHOULD BE USED TO REMOVE POTENTIALLY
CONTAMINATED CLOTHING. WASH CONTAMINATED CLOTHING BEFORE REUSING. ENSURE
THAT EYEWASH STATIONS AND SAFETY SHOWERS ARE CLOSE TO THE WORKSTATION
LOCATION.
EYE/FACE PROTECTION:
SAFETY EYEWEAR COMPLYING WITH AN APPROVED STANDARD SHOULD BE USED WHEN A
RISK ASSESSMENT INDICATES THIS IS NECESSARY TO AVOID EXPOSURE TO LIQUID
SPLASHES, MISTS, GASES OR DUSTS. IF CONTACT IS POSSIBLE, THE FOLLOWING
PROTECTION SHOULD BE WORN, UNLESS THE ASSESSMENT INDICATES A HIGHER DEGREE
OF PROTECTION: CHEMICAL SPLASH GOGGLES.
SKIN PROTECTION:
HAND PROTECTION:
CHEMICAL-RESISTANT, IMPERVIOUS GLOVES COMPLYING WITH AN APPROVED STANDARD
SHOULD BE WORN AT ALL TIMES WHEN HANDLING CHEMICAL PRODUCTS IF A RISK
ASSESSMENT INDICATES THIS IS NECESSARY. CONSIDERING THE PARAMETERS
SPECIFIED BY THE GLOVE MANUFACTURER, CHECK DURING USE THAT THE GLOVES ARE
STILL RETAINING THEIR PROTECTIVE PROPERTIES. IT SHOULD BE NOTED THAT THE
TIME TO BREAKTHROUGH FOR ANY GLOVE MATERIAL MAY BE DIFFERENT FOR DIFFERENT
GLOVE MANUFACTURERS. IN THE CASE OF MIXTURES, CONSISTING OF SEVERAL
SUBSTANCES, THE PROTECTION TIME OF THE GLOVES CANNOT BE ACCURATELY
ESTIMATED.
BODY PROTECTION:
PERSONAL PROTECTIVE EQUIPMENT FOR THE BODY SHOULD BE SELECTED BASED ON THE
TASK BEING PERFORMED AND THE RISKS INVOLVED AND SHOULD BE APPROVED BY A
SPECIALIST BEFORE HANDLING THIS PRODUCT. WHEN THERE IS A RISK OF IGNITION
FROM STATIC ELECTRICITY, WEAR ANTISTATIC PROTECTIVE CLOTHING. FOR THE
GREATEST PROTECTION FROM STATIC DISCHARGES, CLOTHING SHOULD INCLUDE
ANTI-STATIC OVERALLS, BOOTS AND GLOVES.
OTHER SKIN PROTECTION:
APPROPRIATE FOOTWEAR AND ANY ADDITIONAL SKIN PROTECTION MEASURES SHOULD BE
SELECTED BASED ON THE TASK BEING PERFORMED AND THE RISKS INVOLVED AND
SHOULD BE APPROVED BY A SPECIALIST BEFORE HANDLING THIS PRODUCT.
RESPIRATORY PROTECTION:
USE A PROPERLY FITTED, AIR-PURIFYING OR AIR-FED RESPIRATOR COMPLYING WITH
AN APPROVED STANDARD IF A RISK ASSESSMENT INDICATES THIS IS NECESSARY.
RESPIRATOR SELECTION MUST BE BASED ON KNOWN OR ANTICIPATED EXPOSURE LEVELS,
THE HAZARDS OF THE PRODUCT AND THE SAFE WORKING LIMITS OF THE SELECTED
RESPIRATOR.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: LIQUID. [PASTE.]
COLOR: BEIGE. [LIGHT]
ODOR: SOLVENT(S) [STRONG]
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT APPLICABLE.
MELTING POINT: NOT AVAILABLE.
BOILING POINT: 54.444 DEG. C (130 DEG. F)
FLASH POINT:
CLOSED CUP: -18 DEG. C (-0.4 DEG. F) [SETAFLASH.]
EVAPORATION RATE: >1 (BUTYL ACETATE = 1)
FLAMMABILITY (SOLID, GAS):
HIGHLY FLAMMABLE IN THE PRESENCE OF THE FOLLOWING MATERIALS OR CONDITIONS:
OPEN FLAMES, SPARKS AND STATIC DISCHARGE AND HEAT.
VOC (LESS WATER, LESS EXEMPT SOLVENTS): 49 G/L
RELATIVE DENSITY: 1.2638
SOLUBILITY:
INSOLUBLE IN THE FOLLOWING MATERIALS: COLD WATER AND HOT WATER.
AUTO-IGNITION TEMPERATURE: 252 DEG. C (485.6 DEG. F)
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY:
NO SPECIFIC TEST DATA RELATED TO REACTIVITY AVAILABLE FOR THIS PRODUCT OR
ITS INGREDIENTS.
CHEMICAL STABILITY: THE PRODUCT IS STABLE.
POSSIBILITY OF HAZARDOUS REACTIONS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS REACTIONS WILL NOT
OCCUR.
CONDITIONS TO AVOID:
AVOID ALL POSSIBLE SOURCES OF IGNITION (SPARK OR FLAME). DO NOT PRESSURIZE,
CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE CONTAINERS TO HEAT OR
SOURCES OF IGNITION.
INCOMPATIBLE MATERIALS:
REACTIVE OR INCOMPATIBLE WITH THE FOLLOWING MATERIALS: OXIDIZING MATERIALS
HAZARDOUS DECOMPOSITION PRODUCTS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS DECOMPOSITION
PRODUCTS SHOULD NOT BE PRODUCED.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
PRODUCT/INGREDIENT RESULT SPECIES DOSE EXPOSURE
NAME
METHYL ACETATE LD50 DERMAL RABBIT >5 G/KG
LD50 ORAL RAT >5 G/KG
N-HEXANE LC50 INHALATION GAS. RAT 48000 PPM 4 HOURS
LD50 DERMAL RABBIT >3295 MG/KG
LD50 ORAL RAT 15840 MG/KG
METHANOL LC50 INHALATION GAS. RAT 145000 PPM 1 HOURS
LC50 INHALATION GAS. RAT 64000 PPM 4 HOURS
LD50 DERMAL RABBIT 15800 MG/KG
LD50 ORAL RAT 5600 MG/KG
VINYL ACETATE LC50 INHALATION VAPOR RAT 11400 MG/M3 4 HOURS
LD50 DERMAL RABBIT 2335 MG/KG
LD50 ORAL RAT 2900 MG/KG
CONCLUSION/SUMMARY: NOT AVAILABLE.
IRRITATION/CORROSION:
PRODUCT/INGREDIENT RESULT SPECIES SCORE EXPOSURE OBSERVATION
NAME
METHYL ACETATE EYES: RABBIT 24 HOURS
MODERATE 100 MILLIGRAMS
IRRITANT
SKIN: SKIN: RABBIT 24 HOURS
MILD MILD 500 MILLIGRAMS
IRRITANT IRRITANT
SKIN: SKIN: RABBIT 24 HOURS
MODERATE MODERATE 20 MILLIGRAMS
IRRITANT IRRITANT
N-HEXANE EYES: RABBIT 10 MILLIGRAMS
MILD
IRRITANT
METHANOL EYES: RABBIT 24 HOURS
MODERATE 100 MILLIGRAMS
IRRITANT
EYES: EYES: RABBIT 40 MILLIGRAMS
MODERATE MODERATE
IRRITANT IRRITANT
SKIN: SKIN: RABBIT 24 HOURS
MODERATE MODERATE 20 MILLIGRAMS
IRRITANT IRRITANT
CONCLUSION/SUMMARY:
SKIN:
PROLONGED OR REPEATED CONTACT CAN DEFAT THE SKIN AND LEAD TO IRRITATION,
CRACKING AND/OR DERMATITIS.
EYES: THIS PRODUCT MAY IRRITATE EYES UPON CONTACT.
RESPIRATORY:
HIGH VAPOR CONCENTRATIONS CAN CAUSE HEADACHES, DIZZINESS, DROWSINESS AND
NAUSEA AND MAY LEAD TO UNCONSCIOUSNESS.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE):
NAME CATEGORY ROUTE OF EXPOSURE TARGET ORGANS
METHYL ACETATE CATEGORY 3 NOT APPLICABLE. RESPIRATORY TRACT
IRRITATION AND
NARCOTIC EFFECTS
N-HEXANE CATEGORY 3 NOT APPLICABLE. RESPIRATORY TRACT
IRRITATION AND
NARCOTIC EFFECTS
METHANOL CATEGORY 1 NOT DETERMINED NOT DETERMINED
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE):
NAME CATEGORY ROUTE OF EXPOSURE TARGET ORGANS
N-HEXANE CATEGORY 1 INHALATION PERIPHERAL NERVOUS SYSTEM
ASPIRATION HAZARD:
NAME RESULT
N-HEXANE ASPIRATION HAZARD: CATEGORY 1
INFORMATION ON THE LIKELY ROUTES OF EXPOSURE:
ROUTES OF ENTRY ANTICIPATED: ORAL, DERMAL, INHALATION.
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INHALATION: MAY CAUSE RESPIRATORY IRRITATION.
SKIN CONTACT: DEFATTING TO THE SKIN. MAY CAUSE SKIN DRYNESS AND IRRITATION.
INGESTION: IRRITATING TO MOUTH, THROAT AND STOMACH.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN OR IRRITATION
WATERING
REDNESS
INHALATION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
RESPIRATORY TRACT IRRITATION
COUGHING
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
IRRITATION
DRYNESS
CRACKING
INGESTION: NO SPECIFIC DATA.
DELAYED AND IMMEDIATE EFFECTS AND ALSO CHRONIC EFFECTS FROM SHORT AND LONG
TERM EXPOSURE:
SHORT TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE.
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE.
LONG TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE.
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE.
| SECTION 12. ECOLOGICAL INFORMATION | |
TOXICITY:
PRODUCT/INGREDIENT RESULT SPECIES EXPOSURE
NAME
METHYL ACETATE ACUTE LC50: FISH - PIMEPHALES 96 HOURS
408000 (MICRO)G/L PROMELAS - JUVENILE
FRESH WATER (FLEDGLING, HATCHLING,
WEANLING)
N-HEXANE ACUTE EC50: ALGAE 96 HOURS
0.89 MG/L
ACUTE EC50: CRUSTACEANS 48 HOURS
3.9 MG/L
ACUTE LC50: FISH - FATHEAD MINNOW 96 HOURS
2.5 MG/L
CHRONIC NOEC: CRUSTACEANS 21 DAYS
4.9 MG/L
CHRONIC NOEC: FISH - RAINBOW TROUT 28 DAYS
2.8 MG/L
METHANOL ACUTE EC50: ALGAE - ULVA PERTUSA 96 HOURS
16.912 MG/L
MARINE WATER
ACUTE LC50: CRUSTACEANS - CRANGON 48 HOURS
2500000 (MICRO)G/L CRANGON - ADULT
MARINE WATER
ACUTE LC50: DAPHNIA - DAPHNIA 48 HOURS
3289 TO 4395 MG/L MAGNA - NEONATE
FRESH WATER
ACUTE LC50: FISH - DANIO RERIO - 96 HOURS
290 MG/L EGG
FRESH WATER
CHRONIC NOEC: ALGAE - ULVA PERTUSA 96 HOURS
9.96 MG/L
MARINE WATER
VINYL ACETATE ACUTE EC50: ALGAE - 96 HOURS
8.81 MG/L PSEUDOKIRCHNERELLA
SUBCAPITATA
ACUTE EC50: DAPHNIA 48 HOURS
12.6 MG/L
ACUTE LC50: CRUSTACEANS - CRANGON 48 HOURS
10000 TO CRANGON - LARVAE
100000 (MICRO)G/L
MARINE WATER
ACUTE LC50: FISH - PIMEPHALES 96 HOURS
14000 (MICRO)G/L PROMELAS
FRESH WATER
CHRONIC NOEC: ALGAE - 96 HOURS
1.58 MG/L PSEUDOKIRCHNERELLA
SUBCAPITATA
CONCLUSION/SUMMARY: NOT AVAILABLE.
PERSISTENCE AND DEGRADABILITY:
PRODUCT/INGREDIENT NAME AQUATIC HALF-LIFE PHOTOLYSIS BIODEGRADABILITY
N-HEXANE READILY
METHANOL READILY
VINYL ACETATE READILY
BIOACCUMULATIVE POTENTIAL:
PRODUCT/INGREDIENT NAME LOGPOW BCF POTENTIAL
METHYL ACETATE 0.18 LOW
N-HEXANE 4 501.187 HIGH
METHANOL -0.77 <10 LOW
VINYL ACETATE 0.73 3.16 LOW
OTHER ADVERSE EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
THE GENERATION OF WASTE SHOULD BE AVOIDED OR MINIMIZED WHEREVER POSSIBLE.
DISPOSAL OF THIS PRODUCT, SOLUTIONS AND ANY BY-PRODUCTS SHOULD AT ALL TIMES
COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION AND WASTE DISPOSAL
LEGISLATION AND ANY REGIONAL LOCAL AUTHORITY REQUIREMENTS. DISPOSE OF
SURPLUS AND NON-RECYCLABLE PRODUCTS VIA A LICENSED WASTE DISPOSAL
CONTRACTOR. WASTE SHOULD NOT BE DISPOSED OF UNTREATED TO THE SEWER UNLESS
FULLY COMPLIANT WITH THE REQUIREMENTS OF ALL AUTHORITIES WITH JURISDICTION.
WASTE PACKAGING SHOULD BE RECYCLED. INCINERATION OR LANDFILL SHOULD ONLY BE
CONSIDERED WHEN RECYCLING IS NOT FEASIBLE. THIS MATERIAL AND ITS CONTAINER
MUST BE DISPOSED OF IN A SAFE WAY. CARE SHOULD BE TAKEN WHEN HANDLING
EMPTIED CONTAINERS THAT HAVE NOT BEEN CLEANED OR RINSED OUT. EMPTY
CONTAINERS OR LINERS MAY RETAIN SOME PRODUCT RESIDUES. VAPOR FROM PRODUCT
RESIDUES MAY CREATE A HIGHLY FLAMMABLE OR EXPLOSIVE ATMOSPHERE INSIDE THE
CONTAINER. DO NOT CUT, WELD OR GRIND USED CONTAINERS UNLESS THEY HAVE BEEN
CLEANED THOROUGHLY INTERNALLY. AVOID DISPERSAL OF SPILLED MATERIAL AND
RUNOFF AND CONTACT WITH SOIL, WATERWAYS, DRAINS AND SEWERS.
| SECTION 14. TRANSPORT INFORMATION | |
DOT TDG MEXICO
CLASSIFICATION CLASSIFICATION CLASSIFICATION
UN NUMBER 1133 1133 1133
UN PROPER SHIPPING FLAMMABLE FLAMMABLE FLAMMABLE
NAME LIQUID, N.O.S. LIQUID, N.O.S. LIQUID, N.O.S.
(METHYL ACETATE, (METHYL ACETATE, (METHYL ACETATE,
N-HEXANE) N-HEXANE) N-HEXANE)
TRANSPORT HAZARD 3 3 3
CLASS(ES)
FLAMMABLE LIQUID, CLASS 3, CLASS 3,
CLASS/DIVISION FLAMMABLE LIQUIDS FLAMMABLE
3.1, 3.2, 3.3 LIQUIDS
PACKING GROUP III III III
ENVIRONMENTAL NO. NO. NO.
HAZARDS
ADDITIONAL REMARKS: REMARKS: REMARKS:
INFORMATION LIMITED QUANTITY LIMITED QUANTITY LIMITED QUANTITY
ADR/RID IMDG IATA
UN NUMBER 1133 1133 1133
UN PROPER SHIPPING ADHESIVES, FLAMMABLE ADHESIVES,
NAME CONTAINING LIQUID, N.O.S. CONTAINING
FLAMMABLE (METHYL ACETATE, FLAMMABLE
LIQUID N-HEXANE) LIQUID
TRANSPORT HAZARD 3 3 3
CLASS(ES)
CLASS 3, CLASS 3 - CLASS 3,
FLAMMABLE LIQUIDS FLAMMABLE LIQUIDS FLAMMABLE
LIQUIDS
PACKING GROUP III III III
ENVIRONMENTAL NO. NO. NO.
HAZARDS
ADDITIONAL SPECIAL REMARKS:
INFORMATION PROVISIONS: LIMITED QUANTITY
640 (E)
TUNNEL CODE:
(D/E)
REMARKS:
LIMITED QUANTITY
SPECIAL PRECAUTIONS FOR USER:
TRANSPORT WITHIN USER'S PREMISES:
ALWAYS TRANSPORT IN CLOSED CONTAINERS THAT ARE UPRIGHT AND SECURE. ENSURE
THAT PERSONS TRANSPORTING THE PRODUCT KNOW WHAT TO DO IN THE EVENT OF AN
ACCIDENT OR SPILLAGE.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE:
NOT AVAILABLE.
| SECTION 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
TSCA 8(A) PAIR: METHYL ACETATE
TSCA 8(A) CDR EXEMPT/PARTIAL EXEMPTION: NOT DETERMINED
UNITED STATES INVENTORY (TSCA 8B): ALL COMPONENTS ARE LISTED OR EXEMPTED.
CLEAN AIR ACT SECTION 112(B) HAZARDOUS AIR POLLUTANTS (HAPS): LISTED
CLEAN AIR ACT SECTION 602 CLASS I SUBSTANCES: NOT LISTED
CLEAN AIR ACT SECTION 602 CLASS II SUBSTANCES: NOT LISTED
SARA 302/304:
COMPOSITION/INFORMATION ON INGREDIENTS:
NAME % EHS SARA 302 TPQ SARA 304 RQ
(LBS) (GALLONS) (LBS) (GALLONS)
VINYL ACETATE 0.1 - 0.5 YES. 1000 129 5000 644.8
SARA 304 RQ: 2408027.8 LBS / 1093244.6 KG [228520.9 GAL / 865045.6 L]
SARA 311/312:
CLASSIFICATION:
FIRE HAZARD
IMMEDIATE (ACUTE) HEALTH HAZARD
DELAYED (CHRONIC) HEALTH HAZARD
COMPOSITION/INFORMATION ON INGREDIENTS:
NAME % FIRE SUDDEN REACTIVE IMMEDIATE DELAYED
HAZARD RELEASE (ACUTE) (CHRONIC)
OF HEALTH HEALTH
PRESSURE HAZARD HAZARD
METHYL ACETATE 25 - 50 YES. NO. NO. YES. NO.
N-HEXANE 1 - 5 YES. NO. NO. YES. YES.
METHANOL 0.1 - 0.5 YES. NO. NO. YES. YES.
VINYL ACETATE 0.1 - 0.5 YES. NO. NO. NO. YES.
SARA 313:
PRODUCT NAME CAS NUMBER %
FORM R - REPORTING REQUIREMENTS:
N-HEXANE 110-54-3 1 - 5
VINYL ACETATE 108-05-4 0.1 - 0.5
SUPPLIER NOTIFICATION:
N-HEXANE 110-54-3 1 - 5
VINYL ACETATE 108-05-4 0.1 - 0.5
SARA 313 NOTIFICATIONS MUST NOT BE DETACHED FROM THE SDS AND ANY COPYING
AND REDISTRIBUTION OF THE SDS SHALL INCLUDE COPYING AND REDISTRIBUTION OF
THE NOTICE ATTACHED TO COPIES OF THE SDS SUBSEQUENTLY REDISTRIBUTED.
STATE REGULATIONS:
MASSACHUSETTS:
THE FOLLOWING COMPONENTS ARE LISTED: METHYL ACETATE; HEXANE
NEW YORK:
THE FOLLOWING COMPONENTS ARE LISTED: VINYL ACETATE; HEXANE
NEW JERSEY:
THE FOLLOWING COMPONENTS ARE LISTED:
METHYL ACETATE; ACETIC ACID, METHYL ESTER; VINYL ACETATE;
ACETIC ACID ETHENYL ESTER; N-HEXANE; HEXANE
PENNSYLVANIA:
THE FOLLOWING COMPONENTS ARE LISTED:
ACETIC ACID, METHYL ESTER; ACETIC ACID ETHENYL ESTER; HEXANE
CALIFORNIA PROP. 65:
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
INGREDIENT CANCER REPRODUCTIVE NO SIGNIFICANT MAXIMUM ACCEPTABLE
NAME RISK LEVEL DOSAGE LEVEL
METHANOL NO. YES. 45000 (MICRO)G/DAY 23000 (MICRO)G/DAY
(INGESTION) (INGESTION)
47000 (MICRO)G/DAY 47000 (MICRO)G/DAY
(INHALATION) (INHALATION)
CANADA:
CANADIAN LISTS:
CANADIAN NPRI:
THE FOLLOWING COMPONENTS ARE LISTED: N-HEXANE
CEPA TOXIC SUBSTANCES: NONE OF THE COMPONENTS ARE LISTED.
CANADA INVENTORY: ALL COMPONENTS ARE LISTED OR EXEMPTED.
THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF
THE CONTROLLED PRODUCTS REGULATIONS AND THE MSDS CONTAINS ALL THE
INFORMATION REQUIRED BY THE CONTROLLED PRODUCTS REGULATIONS.
MEXICO:
CLASSIFICATION:
HEALTH 2
FLAMMABILITY 3
REACTIVITY 0
SPECIAL
INTERNATIONAL REGULATIONS:
INTERNATIONAL LISTS:
AUSTRALIA INVENTORY (AICS): ALL COMPONENTS ARE LISTED OR EXEMPTED.
CHINA INVENTORY (IECSC): ALL COMPONENTS ARE LISTED OR EXEMPTED.
JAPAN INVENTORY: NOT DETERMINED.
KOREA INVENTORY: ALL COMPONENTS ARE LISTED OR EXEMPTED.
MALAYSIA INVENTORY (EHS REGISTER): NOT DETERMINED.
NEW ZEALAND INVENTORY OF CHEMICALS (NZIOC):
ALL COMPONENTS ARE LISTED OR EXEMPTED.
PHILIPPINES INVENTORY (PICCS): ALL COMPONENTS ARE LISTED OR EXEMPTED.
TAIWAN INVENTORY (CSNN): ALL COMPONENTS ARE LISTED OR EXEMPTED.
EUROPE: ALL COMPONENTS ARE LISTED OR EXEMPTED.
CHEMICAL WEAPONS CONVENTION LIST SCHEDULE I CHEMICALS: NOT LISTED
CHEMICAL WEAPONS CONVENTION LIST SCHEDULE II CHEMICALS: NOT LISTED
CHEMICAL WEAPONS CONVENTION LIST SCHEDULE III CHEMICALS: NOT LISTED
| SECTION 16. OTHER INFORMATION | |
HAZARDOUS MATERIAL INFORMATION SYSTEM (U.S.A.):
HEALTH 2
FLAMMABILITY 3
PHYSICAL HAZARDS 0
CAUTION:
HMIS(R*) RATINGS ARE BASED ON A 0-4 RATING SCALE, WITH 0 REPRESENTING
MINIMAL HAZARDS OR RISKS, AND 4 REPRESENTING SIGNIFICANT HAZARDS OR RISKS
ALTHOUGH HMIS(R*) RATINGS ARE NOT REQUIRED ON SDSS UNDER 29 CFR 1910.1200,
THE PREPARER MAY CHOOSE TO PROVIDE THEM. HMIS(R*) RATINGS ARE TO BE USED
WITH A FULLY IMPLEMENTED HMIS(R*) PROGRAM. HMIS(R*) IS A REGISTERED MARK OF
THE NATIONAL PAINT & COATINGS ASSOCIATION (NPCA). HMIS(R*) MATERIALS MAY BE
PURCHASED EXCLUSIVELY FROM J. J. KELLER (800) 327-6868.
THE CUSTOMER IS RESPONSIBLE FOR DETERMINING THE PPE CODE FOR THIS MATERIAL.
NATIONAL FIRE PROTECTION ASSOCIATION (U.S.A.):
HEALTH 2
FLAMMABILITY 3
INSTABILITY/REACTIVITY 0
SPECIAL
REPRINTED WITH PERMISSION FROM NFPA 704-2001, IDENTIFICATION OF THE HAZARDS
OF MATERIALS FOR EMERGENCY RESPONSE COPYRIGHT (C)1997, NATIONAL FIRE
PROTECTION ASSOCIATION, QUINCY, MA 02269. THIS REPRINTED MATERIAL IS NOT
THE COMPLETE AND OFFICIAL POSITION OF THE NATIONAL FIRE PROTECTION
ASSOCIATION, ON THE REFERENCED SUBJECT WHICH IS REPRESENTED ONLY BY THE
STANDARD IN ITS ENTIRETY.
COPYRIGHT (C)2001, NATIONAL FIRE PROTECTION ASSOCIATION, QUINCY, MA 02269.
THIS WARNING SYSTEM IS INTENDED TO BE INTERPRETED AND APPLIED ONLY BY
PROPERLY TRAINED INDIVIDUALS TO IDENTIFY FIRE, HEALTH AND REACTIVITY
HAZARDS OF CHEMICALS. THE USER IS REFERRED TO CERTAIN LIMITED NUMBER OF
CHEMICALS WITH RECOMMENDED CLASSIFICATIONS IN NFPA 49 AND NFPA 325, WHICH
WOULD BE USED AS A GUIDELINE ONLY. WHETHER THE CHEMICALS ARE CLASSIFIED BY
NFPA OR NOT, ANYONE USING THE 704 SYSTEMS TO CLASSIFY CHEMICALS DOES SO AT
THEIR OWN RISK.
HISTORY:
DATE OF PRINTING: 6/3/2015.
DATE OF ISSUE/DATE OF REVISION: 6/2/2015.
DATE OF PREVIOUS ISSUE: 5/22/2015.
VERSION: 4.1
KEY TO ABBREVIATIONS:
ATE: ACUTE TOXICITY ESTIMATE
BCF: BIOCONCENTRATION FACTOR
GHS:
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELLING OF CHEMICALS
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
IBC: INTERMEDIATE BULK CONTAINER
IMDG: INTERNATIONAL MARITIME DANGEROUS GOODS
LOGPOW: LOGARITHM OF THE OCTANOL/WATER PARTITION COEFFICIENT
MARPOL 73/78:
INTERNATIONAL CONVENTION FOR THE PREVENTION OF POLLUTION FROM SHIPS, 1973
AS MODIFIED BY THE PROTOCOL OF 1978. ("MARPOL" = MARINE POLLUTION)
UN: UNITED NATIONS
REFERENCES: NOT AVAILABLE.
| INDICATES INFORMATION THAT HAS CHANGED FROM PREVIOUSLY ISSUED VERSION.
NOTICE TO READER:
TO THE BEST OF OUR KNOWLEDGE, THE INFORMATION CONTAINED HEREIN IS ACCURATE.
HOWEVER, NEITHER THE ABOVE-NAMED SUPPLIER, NOR ANY OF ITS SUBSIDIARIES,
ASSUMES ANY LIABILITY WHATSOEVER FOR THE ACCURACY OR COMPLETENESS OF THE
INFORMATION CONTAINED HEREIN.
FINAL DETERMINATION OF SUITABILITY OF ANY MATERIAL IS THE SOLE
RESPONSIBILITY OF THE USER. ALL MATERIALS MAY PRESENT UNKNOWN HAZARDS AND
SHOULD BE USED WITH CAUTION. ALTHOUGH CERTAIN HAZARDS ARE DESCRIBED HEREIN,
WE CANNOT GUARANTEE THAT THESE ARE THE ONLY HAZARDS THAT EXIST.