| Common Name: | AIR BRAKE ANTI-FREEZE & CONDITIONER NO. 05532 (ITEM 1003822) |
| Manufacturer: | CRC INDUSTRIES |
| SDS Revision Date: | 4/9/2018 |
| SDS Format: | GHS-US |
| Item Number(s): | 5EVZ6 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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CRC(R*)
SAFETY DATA SHEET
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER: AIR BRAKE ANTI-FREEZE & CONDITIONER
OTHER MEANS OF IDENTIFICATION:
PRODUCT CODE: NO. 05532 (ITEM# 1003822)
RECOMMENDED USE: AIR BRAKE ANTI-FREEZE
RECOMMENDED RESTRICTIONS: NONE KNOWN.
MANUFACTURER/IMPORTER/SUPPLIER/DISTRIBUTOR INFORMATION:
MANUFACTURED OR SOLD BY:
COMPANY NAME: CRC INDUSTRIES, INC.
ADDRESS:
885 LOUIS DR.
WARMINSTER, PA 18974
US
TELEPHONE:
GENERAL INFORMATION: 215-674-4300
TECHNICAL ASSISTANCE: 800-521-3168
CUSTOMER SERVICE: 800-272-4620
24-HOUR EMERGENCY (CEEMTREC):
800-424-9300 (US)
703-527-3887 (INTERNATIONAL)
WEBSITE: WWW.CRCINDUSTRIES.COM
| 2. HAZARD(S) IDENTIFICATION | |
PHYSICAL HAZARDS:
FLAMMABLE LIQUIDS: CATEGORY 2
HEALTH HAZARDS:
ACUTE TOXICITY, ORAL: CATEGORY 3
ACUTE TOXICITY, DERMAL: CATEGORY 3
ACUTE TOXICITY, INHALATION: CATEGORY 3
REPRODUCTIVE TOXICITY (FERTILITY): CATEGORY 2
SPECIFIC TARGET ORGAN TOXICITY, SINGLE EXPOSURE:
CATEGORY 1 (CENTRAL NERVOUS SYSTEM, EYES)
ENVIRONMENTAL HAZARDS: NOT CLASSIFIED.
OSHA DEFINED HAZARDS: NOT CLASSIFIED.
LABEL ELEMENTS:
FLAME
SKULLS AND CROSSBONES
HEALTH HAZARD
SIGNAL WORD: DANGER
HAZARD STATEMENT:
HIGHLY FLAMMABLE LIQUID AND VAPOR. TOXIC IF SWALLOWED. TOXIC IN CONTACT
WITH SKIN. TOXIC IF INHALED. SUSPECTED OF DAMAGING FERTILITY. CAUSES
DAMAGE TO ORGANS (CENTRAL NERVOUS SYSTEM, EYES).
PRECAUTIONARY STATEMENT:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. KEEP AWAY FROM HEAT/SPARKS/OPEN
FLAMES/HOT SURFACES. - NO SMOKING. KEEP CONTAINER TIGHTLY CLOSED. USE
EXPLOSION-PROOF ELECTRICAL/VENTILATING/LIGHTING EQUIPMENT. USE ONLY
NON-SPARKING TOOLS. TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
DO NOT BREATHE VAPORS. USE ONLY WITH ADEQUATE VENTILATION; MAINTAIN
VENTILATION DURING USE AND UNTIL ALL VAPORS ARE GONE. OPEN DOORS AND
WINDOWS OR USE OTHER MEANS TO ENSURE A FRESH AIR SUPPLY DURING USE AND
WHILE PRODUCT IS DRYING. IF YOU EXPERIENCE ANY SYMPTOMS LISTED ON THIS
LABEL, INCREASE VENTILATION OR LEAVE THE AREA. WASH THOROUGHLY AFTER
HANDLING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WEAR
PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
RESPONSE:
IF SWALLOWED: IMMEDIATELY CALL A POISON CENTER/DOCTOR. RINSE MOUTH.
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER. CALL A POISON CENTER/DOCTOR IF YOU FEEL UNWELL. WASH
CONTAMINATED CLOTHING BEFORE REUSE.
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER/DOCTOR.
IF EXPOSED: CALL A POISON CENTER/DOCTOR.
IN CASE OF FIRE:
DO NOT USE WATER JET AS AN EXTINGUISHER, AS THIS WILL SPREAD THE FIRE.
STORAGE:
KEEP COOL. STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL/REGIONAL/NATIONAL
REGULATIONS.
HAZARD(S) NOT OTHERWISE CLASSIFIED (HNOC):
STATIC ACCUMULATING FLAMMABLE LIQUID CAN BECOME ELECTROSTATICALLY CHARGED
EVEN IN BONDED AND GROUNDED EQUIPMENT. SPARKS MAY IGNITE LIQUID AND VAPOR.
MAY CAUSE FLASH FIRE OR EXPLOSION.
SUPPLEMENTAL INFORMATION: NONE.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
MIXTURES:
CHEMICAL NAME COMMON NAME AND SYNONYMS CAS NUMBER %
METHANOL 67-56-1 90 - 100
SPECIFIC CHEMICAL IDENTITY AND/OR PERCENTAGE OF COMPOSITION HAS BEEN
WITHHELD AS A TRADE SECRET.
| 4. FIRST-AID MEASURES | |
INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. OXYGEN OR ARTIFICIAL RESPIRATION IF NEEDED. DO NOT USE
MOUTH-TO-MOUTH METHOD IF VICTIM INHALED THE SUBSTANCE. INDUCE ARTIFICIAL
RESPIRATION WITH THE AID OF A POCKET MASK EQUIPPED WITH A ONE-WAY VALVE OR
OTHER PROPER RESPIRATORY MEDICAL DEVICE. CALL A POISON CENTER OR
DOCTOR/PHYSICIAN.
SKIN CONTACT:
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER. GET MEDICAL ADVICE/ATTENTION IF YOU FEEL UNWELL. GET MEDICAL
ATTENTION IF IRRITATION DEVELOPS AND PERSISTS. WASH CONTAMINATED CLOTHING
BEFORE REUSE.
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES.
REMOVE CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING. GET
MEDICAL ATTENTION IF IRRITATION DEVELOPS AND PERSISTS.
INGESTION:
CALL A PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. RINSE MOUTH. DO NOT
INDUCE VOMITING WITHOUT ADVICE FROM POISON CONTROL CENTER. IF VOMITING
OCCURS, KEEP HEAD LOW SO THAT STOMACH CONTENT DOESN'T GET INTO THE LUNGS.
DO NOT USE MOUTH-TO-MOUTH METHOD IF VICTIM INGESTED THE SUBSTANCE. INDUCE
ARTIFICIAL RESPIRATION WITH THE AID OF A POCKET MASK EQUIPPED WITH A
ONE-WAY VALVE OR OTHER PROPER RESPIRATORY MEDICAL DEVICE.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
NARCOSIS. HEADACHE. DIZZINESS. NAUSEA, VOMITING. BEHAVIORAL CHANGES.
DECREASE IN MOTOR FUNCTIONS. DIRECT CONTACT WITH EYES MAY CAUSE TEMPORARY
IRRITATION.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
METHANOL IS METABOLIZED TO FORMIC ACID AND FORMALDEHYDE. THESE METABOLITES
CAN CAUSE METABOLIC ACIDOSIS, VISUAL DISTURBANCES AND BLINDNESS. SINCE
METABOLISM IS REQUIRED FOR THESE TOXIC SYMPTOMS, THEIR ONSET MAY BE DELAYED
FROM 6 TO 30 HOURS FOLLOWING INGESTION. ETHANOL COMPETES FOR THE SAME
METABOLIC PATHWAY AND HAS BEEN USED TO PREVENT METHANOL METABOLISM. ETHANOL
ADMINISTRATION IS INDICATED IN SYMPTOMATIC PATIENTS OR AT BLOOD METHANOL
CONCENTRATIONS ABOVE 20 (MICRO)G/DL. METHANOL IS EFFECTIVELY REMOVED BY
HEMODIALYSIS. FOMEPIZOLE (4-METHYLPYRAZOLE) IS AN EFFECTIVE ANTAGONIST OF
ALCOHOL DEHYDROGENASE, AND MAY BE USED AS AN ANTIDOTE IN THE TREATMENT OF
METHANOL POISONING.
PROVIDE GENERAL SUPPORTIVE MEASURES AND TREAT SYMPTOMATICALLY. THERMAL
BURNS:
FLUSH WITH WATER IMMEDIATELY. WHILE FLUSHING, REMOVE CLOTHES WHICH DO NOT
ADHERE TO AFFECTED AREA. CALL AN AMBULANCE. CONTINUE FLUSHING DURING
TRANSPORT TO HOSPITAL. KEEP VICTIM WARM. KEEP VICTIM UNDER OBSERVATION.
SYMPTOMS MAY BE DELAYED.
GENERAL INFORMATION: TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING.
IF EXPOSED OR CONCERNED:
GET MEDICAL ADVICE/ATTENTION. ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF
THE MATERIAL(S) INVOLVED, AND TAKE PRECAUTIONS TO PROTECT THEMSELVES. SHOW
THIS SAFETY DATA SHEET TO THE DOCTOR IN ATTENDANCE. WASH CONTAMINATED
CLOTHING BEFORE REUSE.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
WATER FOG. ALCOHOL RESISTANT FOAM. CARBON DIOXIDE (CO2). DRY CHEMICAL
POWDER, CARBON DIOXIDE, SAND OR EARTH MAY BE USED FOR SMALL FIRES ONLY.
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE WATER JET AS AN EXTINGUISHER, AS THIS WILL SPREAD THE FIRE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
VAPORS MAY FORM EXPLOSIVE MIXTURES WITH AIR. VAPORS MAY TRAVEL CONSIDERABLE
DISTANCE TO A SOURCE OF IGNITION AND FLASH BACK. THIS PRODUCT IS A POOR
CONDUCTOR OF ELECTRICITY AND CAN BECOME ELECTROSTATICALLY CHARGED. IF
SUFFICIENT CHARGE IS ACCUMULATED, IGNITION OF FLAMMABLE MIXTURES CAN OCCUR.
THIS LIQUID MAY ACCUMULATE STATIC ELECTRICITY WHEN FILLING PROPERLY
GROUNDED CONTAINERS. STATIC ELECTRICITY ACCUMULATION MAY BE SIGNIFICANTLY
INCREASED BY THE PRESENCE OF SMALL QUANTITIES OF WATER OR OTHER
CONTAMINANTS. MATERIAL WILL FLOAT AND MAY IGNITE ON SURFACE OF WATER.
DURING FIRE, GASES HAZARDOUS TO HEALTH MAY BE FORMED.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING MUST BE
WORN IN CASE OF FIRE.
FIRE-FIGHTING EQUIPMENT/INSTRUCTIONS:
IN CASE OF FIRE AND/OR EXPLOSION DO NOT BREATHE FUMES. MOVE CONTAINERS
FROM FIRE AREA IF YOU CAN DO SO WITHOUT RISK. USE STANDARD FIREFIGHTING
PROCEDURES AND CONSIDER THE HAZARDS OF OTHER INVOLVED MATERIALS.
SPECIFIC METHODS:
USE STANDARD FIREFIGHTING PROCEDURES AND CONSIDER THE HAZARDS OF OTHER
INVOLVED MATERIALS.
GENERAL FIRE HAZARDS: HIGHLY FLAMMABLE LIQUID AND VAPOR.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
KEEP UNNECESSARY PERSONNEL AWAY. KEEP PEOPLE AWAY FROM AND UPWIND OF
SPILL/LEAK. ELIMINATE ALL IGNITION SOURCES (NO SMOKING, FLARES, SPARKS,
OR FLAMES IN IMMEDIATE AREA). WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND
CLOTHING DURING CLEAN-UP. DO NOT BREATHE VAPOR. DO NOT TOUCH DAMAGED
CONTAINERS OR SPILLED MATERIAL UNLESS WEARING APPROPRIATE PROTECTIVE
CLOTHING. VENTILATE CLOSED SPACES BEFORE ENTERING THEM. USE APPROPRIATE
CONTAINMENT TO AVOID ENVIRONMENTAL CONTAMINATION. LOCAL AUTHORITIES SHOULD
BE ADVISED IF SIGNIFICANT SPILLAGES CANNOT BE CONTAINED. FOR PERSONAL
PROTECTION, SEE SECTION 8 OF THE SDS.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
ELIMINATE ALL IGNITION SOURCES (NO SMOKING, FLARES, SPARKS, OR FLAMES IN
IMMEDIATE AREA). KEEP COMBUSTIBLES (WOOD, PAPER, OIL, ETC.) AWAY FROM
SPILLED MATERIAL. TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
USE ONLY NON-SPARKING TOOLS. THIS PRODUCT IS MISCIBLE IN WATER.
SMALL SPILLS:
ABSORB WITH EARTH, SAND OR OTHER NON-COMBUSTIBLE MATERIAL AND TRANSFER TO
CONTAINERS FOR LATER DISPOSAL. WIPE UP WITH ABSORBENT MATERIAL (E.G. CLOTH,
FLEECE). CLEAN SURFACE THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION.
NEVER RETURN SPILLS TO ORIGINAL CONTAINERS FOR RE-USE. FOR WASTE DISPOSAL,
SEE SECTION 13 OF THE SDS.
ENVIRONMENTAL PRECAUTIONS:
AVOID DISCHARGE INTO DRAINS, WATER COURSES OR ONTO THE GROUND. USE
APPROPRIATE CONTAINMENT TO AVOID ENVIRONMENTAL CONTAMINATION.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. DO NOT HANDLE, STORE OR OPEN
NEAR AN OPEN FLAME, SOURCES OF HEAT OR SOURCES OF IGNITION. PROTECT
MATERIAL FROM DIRECT SUNLIGHT. EXPLOSION-PROOF GENERAL AND LOCAL EXHAUST
VENTILATION. MINIMIZE FIRE RISKS FROM FLAMMABLE AND COMBUSTIBLE MATERIALS
(INCLUDING COMBUSTIBLE DUST AND STATIC ACCUMULATING LIQUIDS) OR DANGEROUS
REACTIONS WITH INCOMPATIBLE MATERIALS. HANDLING OPERATIONS THAT CAN
PROMOTE ACCUMULATION OF STATIC CHARGES INCLUDE BUT ARE NOT LIMITED TO:
MIXING, FILTERING, PUMPING AT HIGH FLOW RATES, SPLASH FILLING, CREATING
MISTS OR SPRAYS, TANK AND CONTAINER FILLING, TANK CLEANING, SAMPLING,
GAUGING, SWITCH LOADING, VACUUM TRUCK OPERATIONS. TAKE PRECAUTIONARY
MEASURES AGAINST STATIC DISCHARGES. USE NON-SPARKING TOOLS AND
EXPLOSION-PROOF EQUIPMENT. DO NOT BREATHE VAPOR. DO NOT TASTE OR SWALLOW.
AVOID CONTACT WITH EYES, SKIN, AND CLOTHING. AVOID PROLONGED EXPOSURE.
WHEN USING, DO NOT EAT, DRINK OR SMOKE. PREGNANT OR BREASTFEEDING WOMEN
MUST NOT HANDLE THIS PRODUCT. SHOULD BE HANDLED IN CLOSED SYSTEMS, IF
POSSIBLE. USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA. WEAR APPROPRIATE
PERSONAL PROTECTIVE EQUIPMENT. WASH HANDS THOROUGHLY AFTER HANDLING. WASH
CONTAMINATED CLOTHING BEFORE REUSE. OBSERVE GOOD INDUSTRIAL HYGIENE
PRACTICES. FOR PRODUCT USAGE INSTRUCTIONS, SEE THE PRODUCT LABEL.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
KEEP AWAY FROM HEAT, SPARKS AND OPEN FLAME. ELIMINATE SOURCES OF IGNITION.
AVOID SPARK PROMOTERS. STORE IN A COOL, DRY PLACE OUT OF DIRECT SUNLIGHT.
KEEP CONTAINER TIGHTLY CLOSED. STORE IN A WELL-VENTILATED PLACE. KEEP IN
AN AREA EQUIPPED WITH SPRINKLERS. STORE AWAY FROM INCOMPATIBLE MATERIALS
(SEE SECTION 10 OF THE SDS).
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE LIMITS:
US. OSHA TABLE Z-1 LIMITS FOR AIR CONTAMINANTS (29 CFR 1910.1000):
COMPONENTS TYPE VALUE
METHANOL PEL 260 MG/M3
(CAS 67-56-1) 200 PPM
US. ACGIH THRESHOLD LIMIT VALUES:
COMPONENTS TYPE VALUE
METHANOL STEL 250 PPM
(CAS 67-56-1)
TWA 200 PPM
US. NIOSH: POCKET GUIDE TO CHEMICAL HAZARDS
COMPONENTS TYPE VALUE
METHANOL STEL 325 MG/M3
(CAS 67-56-1) 250 PPM
TWA 260 MG/M3
200 PPM
BIOLOGICAL LIMIT VALUES:
ACGH BIOLOGICAL EXPOSURE INDICES:
COMPONENTS VALUE DETERMINANT SPECIMEN SAMPLING TIME
METHANOL 15 MG/L METHANOL URINE *
(CAS 67-56-1)
* - FOR SAMPLING DETAILS, PLEASE SEE THE SOURCE DOCUMENT.
EXPOSURE GUIDELINES:
US - CALIFORNIA OELS SKIN DESIGNATION
METHANOL (CAS 67-56-1) CAN BE ABSORBED THROUGH THE SKIN.
US - MINNESOTA HAZ SUBS SKIN DESIGNATION APPLIES
METHANOL (CAS 67-56-1) SKIN DESIGNATION APPLIES.
US - TENNESSEE OELS SKIN DESIGNATION
METHANOL (CAS 67-56-1) CAN BE ABSORBED THROUGH THE SKIN.
US ACGIH THRESHOLD LIMIT VALUES SKIN DESIGNATION
METHANOL (CAS 67-56-1) CAN BE ABSORBED THROUGH THE SKIN.
US NIOSH POCKET GUIDE TO CHEMICAL SKIN DESIGNATION
HAZARDS
METHANOL (CAS 67-56-1) CAN BE ABSORBED THROUGH THE SKIN.
APPROPRIATE ENGINEERING CONTROLS:
EXPLOSION-PROOF GENERAL AND LOCAL EXHAUST VENTILATION. GOOD GENERAL
VENTILATION (TYPICALLY 10 AIR CHANGES PER HOUR) SHOULD BE USED.
VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS. IF APPLICABLE, USE
PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO MAINTAIN AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS.
IF EXPOSURE LIMITS HAVE NOT BEEN ESTABLISHED, MAINTAIN AIRBORNE LEVELS TO
AN ACCEPTABLE LEVEL.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION: WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES).
SKIN PROTECTION:
HAND PROTECTION:
WEAR PROTECTIVE GLOVES SUCH AS: NITRILE. RUBBER.
OTHER:
WEAR APPROPRIATE CHEMICAL RESISTANT CLOTHING. USE OF AN IMPERVIOUS APRON
IS RECOMMENDED.
RESPIRATORY PROTECTION:
IF ENGINEERING CONTROLS ARE NOT FEASIBLE OR IF EXPOSURE EXCEEDS THE
APPLICABLE EXPOSURE LIMITS, USE A NIOSH-APPROVED CARTRIDGE RESPIRATOR WITH
AN ORGANIC VAPOR CARTRIDGE. USE A SELF-CONTAINED BREATHING APPARATUS IN
CONFINED SPACES AND FOR EMERGENCIES. AIR MONITORING IS NEEDED TO DETERMINE
ACTUAL EMPLOYEE EXPOSURE LEVELS.
THERMAL HAZARDS:
WEAR APPROPRIATE THERMAL PROTECTIVE CLOTHING, WHEN NECESSARY.
GENERAL HYGIENE CONSIDERATIONS:
WHEN USING, DO NOT EAT, DRINK OR SMOKE. ALWAYS OBSERVE GOOD PERSONAL
HYGIENE MEASURES, SUCH AS WASHING AFTER HANDLING THE MATERIAL AND BEFORE
EATING, DRINKING, AND/OR SMOKING. ROUTINELY WASH WORK CLOTHING AND
PROTECTIVE EQUIPMENT TO REMOVE CONTAMINANTS.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: LIQUID.
FORM: LIQUID.
COLOR: COLORLESS.
ODOR: PUNGENT. ALCOHOLIC.
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
MELTING POINT/FREEZING POINT: -144 DEG. F (-97.8 DEG. C) ESTIMATED
INITIAL BOILING POINT AND BOILING RANGE:
148.5 DEG. F (64.7 DEG. C) ESTIMATED
FLASH POINT: 54 DEG. F (12.2 DEG. C) SETAFLASH
EVAPORATION RATE: FAST.
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE.
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS:
FLAMMABILITY LIMIT - LOWER (%): 2.6% ESTIMATED
FLAMMABILITY LIMIT - UPPER (%): 36% ESTIMATED
VAPOR PRESSURE: 133.2 HPA ESTIMATED
VAPOR DENSITY: 1.1 (AIR = 1)
RELATIVE DENSITY: 0.79
SOLUBILITY(IES):
SOLUBILITY (WATER): COMPLETELY SOLUBLE.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: 725 DEG. F (385 DEG. C) ESTIMATED
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
PERCENT VOLATILE: 99.9% ESTIMATED
| 10. STABILITY AND REACTIVITY | |
REACTIVITY:
THE PRODUCT IS STABLE AND NON-REACTIVE UNDER NORMAL CONDITIONS OF USE,
STORAGE AND TRANSPORT.
CHEMICAL STABILITY: MATERIAL IS STABLE UNDER NORMAL CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS:
NO DANGEROUS REACTION KNOWN UNDER CONDITIONS OF NORMAL USE.
CONDITIONS TO AVOID:
AVOID HEAT, SPARKS, OPEN FLAMES AND OTHER IGNITION SOURCES. CONTACT WITH
INCOMPATIBLE MATERIALS.
INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS.
HAZARDOUS DECOMPOSITION PRODUCTS: CARBON OXIDES. FORMALDEHYDE.
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INHALATION: TOXIC IF INHALED. MAY CAUSE DAMAGE TO ORGANS BY INHALATION.
SKIN CONTACT: TOXIC IN CONTACT WITH SKIN.
EYE CONTACT: DIRECT CONTACT WITH EYES MAY CAUSE TEMPORARY IRRITATION.
INGESTION:
TOXIC IF SWALLOWED. EVEN SMALL AMOUNTS (30-250 ML METHANOL) MAY BE FATAL.
SYMPTOMS ARE STOMACH ACHE, NAUSEA, VOMITING, DULLNESS, VISUAL DISORDER AND
BLINDNESS.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
NARCOSIS. HEADACHE. DIZZINESS. NAUSEA, VOMITING. BEHAVIORAL CHANGES.
DECREASE IN MOTOR FUNCTIONS.
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
TOXIC IF INHALED. TOXIC IN CONTACT WITH SKIN. TOXIC IF SWALLOWED.
SKIN CORROSION/IRRITATION:
PROLONGED SKIN CONTACT MAY CAUSE TEMPORARY IRRITATION.
SERIOUS EYE DAMAGE/EYE IRRITATION:
DIRECT CONTACT WITH EYES MAY CAUSE TEMPORARY IRRITATION.
RESPIRATORY OR SKIN SENSITIZATION:
RESPIRATORY SENSITIZATION: NOT A RESPIRATORY SENSITIZER.
SKIN SENSITIZATION:
THIS PRODUCT IS NOT EXPECTED TO CAUSE SKIN SENSITIZATION.
GERM CELL MUTAGENICITY:
NO DATA AVAILABLE TO INDICATE PRODUCT OR ANY COMPONENTS PRESENT AT GREATER
THAN 0.1% ARE MUTAGENIC OR GENOTOXIC.
CARCINOGENICITY: NOT CLASSIFIABLE AS TO CARCINOGENICITY TO HUMANS.
IARC MONOGRAPHS. OVERALL EVALUATION OF CARCINOGENICITY: NOT LISTED.
OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1052):
NOT REGULATED.
US. NATIONAL TOXICOLOGY PROGRAM (NTP) REPORT ON CARCINOGENS: NOT LISTED.
REPRODUCTIVE TOXICITY: SUSPECTED OF DAMAGING FERTILITY.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
CAUSES DAMAGE TO ORGANS (CENTRAL NERVOUS SYSTEM, EYES). EVEN SMALL AMOUNTS
(30-250 ML METHANOL) MAY BE FATAL. SYMPTOMS ARE STOMACH ACHE, NAUSEA,
VOMITING, DULLNESS, VISUAL DISORDER AND BLINDNESS.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NOT CLASSIFIED.
ASPIRATION HAZARD: NOT AN ASPIRATION HAZARD.
CHRONIC EFFECTS: PROLONGED INHALATION MAY BE HARMFUL.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
THE PRODUCT IS NOT CLASSIFIED AS ENVIRONMENTALLY HAZARDOUS. HOWEVER, THIS
DOES NOT EXCLUDE THE POSSIBILITY THAT LARGE OR FREQUENT SPILLS CAN HAVE A
HARMFUL OR DAMAGING EFFECT ON THE ENVIRONMENT.
COMPONENTS SPECIES TEST RESULTS
METHANOL (CAS 67-56-1):
AQUATIC:
FISH LC50 RAINBOW TROUT, DONALDSON 18000 - 20000 MG/L,
TROUT (ONCORHYNCHUS MYKISS) 96 HOURS
ACUTE:
CRUSTACEA EC50 WATER FLEA (DAPHNIA MAGNA) >10000 MG/L,
48 HOURS
FISH LC50 RAINBOW TROUT, DONALDSON 18000 - 20000 MG/L,
TROUT (ONCORHYNCHUS MYKISS) 96 HOURS
PERSISTENCE AND DEGRADABILITY:
NO DATA IS AVAILABLE ON THE DEGRADABILITY OF ANY INGREDIENTS IN THE
MIXTURE.
BIOACCUMULATIVE POTENTIAL:
PARTITION COEFFICIENT N-OCTANOL / WATER (LOG KOW):
METHANOL: -0.77
MOBILITY IN SOIL: NO DATA AVAILABLE.
OTHER ADVERSE EFFECTS:
NO OTHER ADVERSE ENVIRONMENTAL EFFECTS (E.G. OZONE DEPLETION, PHOTOCHEMICAL
OZONE CREATION POTENTIAL, ENDOCRINE DISRUPTION, GLOBAL WARMING POTENTIAL)
ARE EXPECTED FROM THIS COMPONENT.
| 13. DISPOSAL CONSIDERATIONS | |
HAZARDOUS WASTE CODE:
D001: WASTE FLAMMABLE MATERIAL WITH A FLASH POINT <140 F
F003: WASTE NON-HALOGENATED SOLVENT - SPENT NON-HALOGENATED SOLVENT
US RCRA HAZARDOUS WASTE U LIST REFERENCE
METHANOL (CAS 67-56-1) U154
CONTAMINATED PACKAGING:
EMPTY CONTAINERS SHOULD BE TAKEN TO AN APPROVED WASTE HANDLING SITE FOR
RECYCLING OR DISPOSAL. SINCE EMPTIED CONTAINERS MAY RETAIN PRODUCT RESIDUE,
FOLLOW LABEL WARNINGS EVEN AFTER CONTAINER IS EMPTIED.
DISPOSAL INSTRUCTIONS:
THIS MATERIAL AND ITS CONTAINER MUST BE DISPOSED OF AS HAZARDOUS WASTE.
COLLECT AND RECLAIM OR DISPOSE IN SEALED CONTAINERS AT LICENSED WASTE
DISPOSAL SITE. DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS.
| 14. TRANSPORT INFORMATION | |
DOT:
UN NUMBER: UN1230
UN PROPER SHIPPING NAME:
METHANOL, SOLUTION (METHANOL RQ = 5007 LBS), LIMITED QUANTITY
TRANSPORT HAZARD CLASS(ES):
CLASS: 3
SUBSIDIARY RISK:
LABEL(S): 3
PACKING GROUP: II
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
SPECIAL PROVISIONS: IB2, T7, TP2
PACKAGING EXCEPTIONS: 150
PACKAGING NON BULK: 202
PACKAGING BULK: 242
IATA:
UN NUMBER: UN1230
UN PROPER SHIPPING NAME: METHANOL, LIMITED QUANTITY
TRANSPORT HAZARD CLASS(ES):
CLASS: 3
SUBSIDIARY RISK: 6.1
PACKING GROUP: II
ERG CODE: 3L
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
OTHER INFORMATION:
PASSENGER AND CARGO AIRCRAFT: ALLOWED WITH RESTRICTIONS.
CARGO AIRCRAFT ONLY: ALLOWED WITH RESTRICTIONS.
IMDG:
UN NUMBER: UN1230
UN PROPER SHIPPING NAME: METHANOL, LIMITED QUANTITY
TRANSPORT HAZARD CLASS(ES):
CLASS: 3
SUBSIDIARY RISK: 6.1
PACKING GROUP: II
ENVIRONMENTAL HAZARDS:
MARINE POLLUTANT: NO.
EMS: F-E, S-D
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
| 15. REGULATORY INFORMATION | |
US FEDERAL REGULATIONS:
THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.
ALL COMPONENTS ARE ON THE U.S. EPA TSCA INVENTORY LIST.
TSCA SECTION 12(B) EXPORT NOTIFICATION (40 CFR 707, SUBPT. D):
NOT REGULATED.
SARA 304 EMERGENCY RELEASE NOTIFICATION: NOT REGULATED.
OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1052):
NOT REGULATED.
US EPCRA (SARA TITLE III) SECTION 313 - TOXIC CHEMICAL LISTED SUBSTANCE
METHANOL (CAS 67-56-1)
CERCLA HAZARDOUS SUBSTANCE LIST (40 CFR 302.4):
METHANOL (CAS 67-56-1): LISTED.
CERCLA HAZARDOUS SUBSTANCES REPORTABLE QUANTITY
METHANOL (CAS 67-56-1) 5000 LBS
SPILLS OR RELEASES RESULTING IN THE LOSS OF ANY INGREDIENT AT OR ABOVE ITS
RQ REQUIRE IMMEDIATE NOTIFICATION TO THE NATIONAL RESPONSE CENTER
(800-424-8802) AND TO YOUR LOCAL EMERGENCY PLANNING COMMITTEE.
OTHER FEDERAL REGULATIONS:
CLEAN AIR ACT (CAA) SECTION 112 HAZARDOUS AIR POLLUTANTS (HAPS) LIST:
METHANOL (CAS 67-56-1)
CLEAN AIR ACT (CAA) SECTION 112(R) ACCIDENTAL RELEASE PREVENTION
(40 CFR 68.130): NOT REGULATED.
SAFE DRINKING WATER ACT (SDWA): NOT REGULATED.
FOOD AND DRUG ADMINISTRATION (FDA): NOT REGULATED.
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA):
CLASSIFIED HAZARD CATEGORIES:
FLAMMABLE (GASES, AEROSOLS, LIQUIDS, OR SOLIDS)
ACUTE TOXICITY (ANY ROUTE OF EXPOSURE)
REPRODUCTIVE TOXICITY
SPECIFIC TARGET ORGAN TOXICITY (SINGLE OR REPEATED EXPOSURE)
HAZARD NOT OTHERWISE CLASSIFIED (HNOC)
SARA 302 EXTREMELY HAZARDOUS SUBSTANCE: NOT LISTED.
SARA 313 (TRI REPORTING):
CHEMICAL NAME CAS NUMBER % BY WT.
METHANOL 67-56-1 90 - 100
US STATE REGULATIONS:
US. NEW JERSEY WORKER AND COMMUNITY RIGHT-TO-KNOW ACT:
METHANOL (CAS 67-56-1)
US. MASSACHUSETTS RTK - SUBSTANCE LIST: METHANOL (CAS 67-56-1)
US. PENNSYLVANIA WORKER AND COMMUNITY RIGHT-TO-KNOW LAW:
METHANOL (CAS 67-56-1)
US. RHODE ISLAND RTK: METHANOL (CAS 67-56-1)
CALIFORNIA PROPOSITION 65:
WARNING: REPRODUCTIVE HARM - WWW.P65WARNINGS.CA.GOV
CALIFORNIA PROPOSITION 65 - CRT LISTED DATE/DEVELOPMENTAL TOXIN
METHANOL (CAS 67-56-1) LISTED: MARCH 16, 2012
US. CALIFORNIA. CANDIDATE CHEMICALS LIST. SAFER CONSUMER PRODUCTS
REGULATIONS (CAL. CODE REGS, TIT. 22, 69502.3, SUBD. (A)):
METHANOL (CAS 67-56-1)
VOLATILE ORGANIC COMPOUNDS (VOC) REGULATIONS:
EPA:
VOC CONTENT (40 CFR 51.100(S)): 100%
CONSUMER PRODUCTS (40 CFR 59, SUBPT. C): NOT REGULATED
STATE:
CONSUMER PRODUCTS: NOT REGULATED
VOC CONTENT (CA): 100%
VOC CONTENT (OTC): 100%
INTERNATIONAL INVENTORIES:
COUNTRY(S) OR REGION INVENTORY NAME ON INVENTORY
(YES/NO)*
AUSTRALIA AUSTRALIAN INVENTORY OF CHEMICAL YES
SUBSTANCES (AICS)
CANADA DOMESTIC SUBSTANCES LIST (DSL) YES
CANADA NON-DOMESTIC SUBSTANCES LIST (NDSL) NO
CHINA INVENTORY OF EXISTING CHEMICAL YES
SUBSTANCES IN CHINA (IECSC)
EUROPE EUROPEAN INVENTORY OF EXISTING YES
COMMERCIAL CHEMICAL SUBSTANCES
(EINECS)
EUROPE EUROPEAN LIST OF NOTIFIED CHEMICAL NO
SUBSTANCES (ELINCS)
JAPAN INVENTORY OF EXISTING AND NEW YES
CHEMICAL SUBSTANCES (ENCS)
KOREA EXISTING CHEMICALS LIST (ECL) YES
NEW ZEALAND NEW ZEALAND INVENTORY YES
PHILIPPINES PHILIPPINE INVENTORY OF CHEMICALS YES
AND CHEMICAL SUBSTANCES (PICCS)
TAIWAN TAIWAN TOXIC CHEMICAL SUBSTANCES YES
(TCS)
UNITED STATES & TOXIC SUBSTANCES CONTROL ACT (TSCA) YES
PUERTO RICO INVENTORY
*A "YES" INDICATES THAT ALL COMPONENTS OF THIS PRODUCT COMPLY WITH THE
INVENTORY REQUIREMENTS ADMINISTERED BY THE GOVERNING COUNTRY(S)
A "NO" INDICATES THAT ONE OR MORE COMPONENTS OF THE PRODUCT ARE NOT LISTED
OR EXEMPT FROM LISTING ON THE INVENTORY ADMINISTERED BY THE GOVERNING
COUNTRY(S).
| 16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION | |
OR LAST REVISION
ISSUE DATE: 03-24-2015
REVISION DATE: 04-09-2018
PREPARED BY: ALLISON YOON
VERSION #: 02
FURTHER INFORMATION: CRC # 620B/1002661
DISCLAIMER:
THE INFORMATION CONTAINED IN THIS DOCUMENT APPLIES TO THIS SPECIFIC
MATERIAL AS SUPPLIED. IT MAY NOT BE VALID FOR THIS MATERIAL IF IT IS USED
IN COMBINATION WITH ANY OTHER MATERIALS. THIS INFORMATION IS ACCURATE TO
THE BEST OF CRC'S KNOWLEDGE OR OBTAINED FROM SOURCES BELIEVED BY CRC TO
BE ACCURATE. BEFORE USING ANY PRODUCT, READ ALL WARNINGS AND DIRECTIONS ON
THE LABEL. FOR FURTHER CLARIFICATION OF ANY INFORMATION CONTAINED ON THIS
(M)SDS CONSULT YOUR SUPERVISOR, A HEALTH & SAFETY PROFESSIONAL, OR CRC
INDUSTRIES, INC..
REVISION INFORMATION:
THIS DOCUMENT HAS UNDERGONE SIGNIFICANT CHANGES AND SHOULD BE REVIEWED IN
ITS ENTIRETY.
MATERIAL NAME: AIR BRAKE ANTI-FREEZE & CONDITIONER
SDS US