| Common Name: | TOUGH GUY LAUNDRY DETERGENT (5GUU1) |
| Manufacturer: | W.W. GRAINGER |
| SDS Revision Date: | 3/8/2013 |
| SDS Format: | GHS-US |
| Item Number(s): | 5GUU1 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
SAFETY DATA SHEET
ISSUING DATE: 08-MAR-2013
REVISION DATE: 08-MAR-2013
REVISION NUMBER: 1
| 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION |  |
AND OF THE COMPANY/UNDERTAKING
PRODUCT IDENTIFIER:
PRODUCT NAME: GRAINGER TOUGH GUY LAUNDRY DETERGENT (5GUU1)
OTHER MEANS OF IDENTIFICATION:
SYNONYMS: NONE
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE: LAUNDRY DETERGENT
USES ADVISED AGAINST: NO INFORMATION AVAILABLE
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
SUPPLIER NAME: W.W GRAINGER
SUPPLIER ADDRESS:
100 GRAINGER PARKWAY
LAKE FOREST, IL 60045
SUPPLIER PHONE NUMBER: 800-472-4643
EMERGENCY TELEPHONE NUMBER: 800-228-5635
| 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION:
THIS CHEMICAL IS CONSIDERED HAZARDOUS BY THE 2012 OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200)
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2
GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENTS:
EMERGENCY OVERVIEW:
SIGNAL WORD: WARNING
HAZARD STATEMENTS:
MAY CAUSE SKIN IRRITATION
MAY CAUSE EYE IRRITATION
EXCLAMATION MARK
APPEARANCE: CLEAR
PHYSICAL STATE: VISCOUS LIQUID
ODOR: NONE
PRECAUTIONARY STATEMENTS - PREVENTION:
WASH FACE, HANDS AND ANY EXPOSED SKIN THOROUGHLY AFTER HANDLING
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION
AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY
REMOVE THE CONTAMINATED CLOTHING AND WASH.
PRECAUTIONARY STATEMENTS - RESPONSE:
SPECIFIC TREATMENT (SEE SUPPLEMENTAL FIRST AID INSTRUCTIONS ON THIS LABEL)
SKIN:
IF ON SKIN: NO ADVERSE REACTION EXPECTED. WASH WITH SOAP AND WATER
TAKE OFF CONTAMINATED CLOTHING AND WASH BEFORE REUSE
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION
PRECAUTIONARY STATEMENTS - STORAGE: NONE
PRECAUTIONARY STATEMENTS - DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC): NOT APPLICABLE
UNKNOWN TOXICITY:
6.502% OF THE MIXTURE CONSISTS OF INGREDIENT(S) OF UNKNOWN TOXICITY
OTHER INFORMATION:
TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS:
REPEATED OR PROLONGED SKIN CONTACT MAY CAUSE ALLERGIC REACTIONS WITH
SUSCEPTIBLE PERSONS
INTERACTIONS WITH OTHER CHEMICALS: NO INFORMATION AVAILABLE.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL NAME CAS NO. WEIGHT-% TRADE SECRET
COCAMIDOPROPYL BETAINE 61789-40-0 7 - 13 *
COCAMIDOPROPYLAMINE OXIDE 68155-09-9 1 - 5 *
METHYLISOTHIAZOLINONE 2682-20-4 0.1 - 1 *
*THE EXACT PERCENTAGE (CONCENTRATION) OF COMPOSITION HAS BEEN WITHHELD AS A
TRADE SECRET
| 4. FIRST AID MEASURES | |
FIRST AID MEASURES:
GENERAL ADVICE: SHOW THIS SAFETY DATA SHEET TO THE DOCTOR IN ATTENDANCE.
EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS, FOR AT
LEAST 15 MINUTES. KEEP EYE WIDE OPEN WHILE RINSING. REMOVE CONTACT LENSES,
IF PRESENT AND IF IRRITATION PERSISTS CONSULT A DOCTOR/PHYSICIAN.
SKIN CONTACT:
WASH OFF IMMEDIATELY WITH SOAP AND PLENTY OF WATER FOR AT LEAST 15 MINUTES.
MAY CAUSE AN ALLERGIC SKIN REACTION. IN THE CASE OF SKIN IRRITATION OR
ALLERGIC REACTIONS SEE A PHYSICIAN.
INHALATION:
REMOVE TO FRESH AIR. GET MEDICAL ATTENTION IMMEDIATELY IF SYMPTOMS OCCUR.
INGESTION:
RINSE MOUTH IMMEDIATELY AND DRINK PLENTY OF WATER. NEVER GIVE ANYTHING BY
MOUTH TO AN UNCONSCIOUS PERSON. DO NOT INDUCE VOMITING. CALL A PHYSICIAN.
SELF-PROTECTION OF THE FIRST AIDER:
AVOID CONTACT WITH SKIN, EYES OR CLOTHING. WEAR PERSONAL PROTECTIVE
CLOTHING (SEE SECTION 8).
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
MOST IMPORTANT SYMPTOMS AND EFFECTS:
BURNING SENSATION. ITCHING. RASHES. HIVES.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
NOTES TO PHYSICIAN:
TREAT SYMPTOMATICALLY. MAY CAUSE SENSITIZATION OF SUSCEPTIBLE PERSONS.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
USE EXTINGUISHING MEASURES THAT ARE APPROPRIATE TO LOCAL CIRCUMSTANCES AND
THE SURROUNDING ENVIRONMENT.
UNSUITABLE EXTINGUISHING MEDIA:
CAUTION: USE OF WATER SPRAY WHEN FIGHTING FIRE MAY BE INEFFICIENT.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
PRODUCT IS OR CONTAINS A SENSITIZER. MAY CAUSE SENSITIZATION BY SKIN
CONTACT.
UNIFORM FIRE CODE:
SENSITIZER: LIQUID
HAZARDOUS COMBUSTION PRODUCTS: CARBON OXIDES.
EXPLOSION DATA:
SENSITIVITY TO MECHANICAL IMPACT: NO.
SENSITIVITY TO STATIC DISCHARGE: NO.
PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND,
MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
AVOID CONTACT WITH SKIN, EYES OR CLOTHING. ENSURE ADEQUATE VENTILATION. USE
PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED.
OTHER INFORMATION: REFER TO PROTECTIVE MEASURES LISTED IN SECTIONS 7 AND 8.
ENVIRONMENTAL PRECAUTIONS:
ENVIRONMENTAL PRECAUTIONS:
REFER TO PROTECTIVE MEASURES LISTED IN SECTIONS 7 AND 8. PREVENT FURTHER
LEAKAGE OR SPILLAGE IF SAFE TO DO SO.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CONTAINMENT:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO.
METHODS FOR CLEANING UP:
SOAK UP WITH INERT ABSORBENT MATERIAL. PICK UP AND TRANSFER TO PROPERLY
LABELED CONTAINERS.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
HANDLING:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
AVOID CONTACT WITH SKIN, EYES OR CLOTHING. DO NOT EAT, DRINK OR SMOKE
WHEN USING THIS PRODUCT.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE:
KEEP CONTAINERS TIGHTLY CLOSED IN A DRY, COOL AND WELL-VENTILATED PLACE.
INCOMPATIBLE PRODUCTS: STRONG ACIDS. STRONG OXIDIZING AGENTS. STRONG BASES.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
EXPOSURE GUIDELINES:
THIS PRODUCT, AS SUPPLIED, DOES NOT CONTAIN ANY HAZARDOUS MATERIALS WITH
OCCUPATIONAL EXPOSURE LIMITS ESTABLISHED BY THE REGION SPECIFIC REGULATORY
BODIES
APPROPRIATE ENGINEERING CONTROLS:
ENGINEERING MEASURES:
SHOWERS
EYEWASH STATIONS
VENTILATION SYSTEMS
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION:
WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES). NONE REQUIRED FOR
CONSUMER USE.
SKIN AND BODY PROTECTION:
WEAR PROTECTIVE GLOVES AND PROTECTIVE CLOTHING. LONG SLEEVED CLOTHING.
IMPERVIOUS GLOVES.
RESPIRATORY PROTECTION:
NO PROTECTIVE EQUIPMENT IS NEEDED UNDER NORMAL USE CONDITIONS. IF EXPOSURE
LIMITS ARE EXCEEDED OR IRRITATION IS EXPERIENCED, VENTILATION AND
EVACUATION MAY BE REQUIRED.
HYGIENE MEASURES:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE. TAKE
OFF CONTAMINATED CLOTHING AND WASH BEFORE REUSE. AVOID CONTACT WITH SKIN,
EYES OR CLOTHING. WEAR SUITABLE GLOVES AND EYE/FACE PROTECTION. DO NOT EAT,
DRINK OR SMOKE WHEN USING THIS PRODUCT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: VISCOUS LIQUID
APPEARANCE: CLEAR
ODOR: NEUTRAL
COLOR: PALE GOLD
ODOR THRESHOLD: NO INFORMATION AVAILABLE
PROPERTY VALUES REMARKS/ METHOD
PH 7.25 NONE KNOWN
MELTING / FREEZING POINT NO DATA AVAILABLE NONE KNOWN
BOILING POINT / BOILING RANGE 212 DEG. F NONE KNOWN
FLASH POINT 94 DEG. C / 201 DEG. F NONE KNOWN
EVAPORATION RATE NO DATA AVAILABLE NONE KNOWN
FLAMMABILITY (SOLID, GAS) NO DATA AVAILABLE NONE KNOWN
FLAMMABILITY LIMIT IN AIR:
UPPER FLAMMABILITY LIMIT NO DATA AVAILABLE
LOWER FLAMMABILITY LIMIT NO DATA AVAILABLE
VAPOR PRESSURE NO DATA AVAILABLE NONE KNOWN
VAPOR DENSITY NO DATA AVAILABLE NONE KNOWN
SPECIFIC GRAVITY 1.01 - 1.02 NONE KNOWN
WATER SOLUBILITY SOLUBLE IN WATER NONE KNOWN
SOLUBILITY IN OTHER SOLVENTS NO DATA AVAILABLE NONE KNOWN
PARTITION COEFFICIENT NO DATA AVAILABLE NONE KNOWN
N-OCTANOL/WATER
AUTOIGNITION TEMPERATURE NO DATA AVAILABLE NONE KNOWN
DECOMPOSITION TEMPERATURE NO DATA AVAILABLE NONE KNOWN
KINEMATIC VISCOSITY NO DATA AVAILABLE NONE KNOWN
DYNAMIC VISCOSITY NO DATA AVAILABLE NONE KNOWN
EXPLOSIVE PROPERTIES NO DATA AVAILABLE
OXIDIZING PROPERTIES NO DATA AVAILABLE
OTHER INFORMATION:
SOFTENING POINT NO DATA AVAILABLE
VOC CONTENT (%) NO DATA AVAILABLE
PARTICLE SIZE NO DATA AVAILABLE
PARTICLE SIZE DISTRIBUTION NO DATA AVAILABLE
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: NO DATA AVAILABLE.
CHEMICAL STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
HAZARDOUS POLYMERIZATION: HAZARDOUS POLYMERIZATION DOES NOT OCCUR.
CONDITIONS TO AVOID: NONE KNOWN BASED ON INFORMATION SUPPLIED.
INCOMPATIBLE MATERIALS:
STRONG ACIDS. STRONG OXIDIZING AGENTS. STRONG BASES.
HAZARDOUS DECOMPOSITION PRODUCTS: CARBON OXIDES.
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
PRODUCT INFORMATION:
PRODUCT DOES NOT PRESENT AN ACUTE TOXICITY HAZARD BASED ON KNOWN OR
SUPPLIED INFORMATION.
INHALATION:
SPECIFIC TEST DATA FOR THE SUBSTANCE OR MIXTURE IS NOT AVAILABLE. NO
IRRITATION EXPECTED.
EYE CONTACT:
SPECIFIC TEST DATA FOR THE SUBSTANCE OR MIXTURE IS NOT AVAILABLE. EXPECTED
TO BE AN IRRITANT BASED ON COMPONENTS. MAY CAUSE EYE IRRITATION. MAY CAUSE
BURNS.
SKIN CONTACT:
SPECIFIC TEST DATA FOR THE SUBSTANCE OR MIXTURE IS NOT AVAILABLE. NOT
EXPECTED TO BE A SKIN IRRITANT BASED ON COMPONENTS. PROLONGED CONTACT MAY
CAUSE REDNESS AND IRRITATION
INGESTION:
SPECIFIC TEST DATA FOR THE SUBSTANCE OR MIXTURE IS NOT AVAILABLE. INGESTION
MAY CAUSE IRRITATION TO MUCOUS MEMBRANES. INGESTION MAY CAUSE
GASTROINTESTINAL IRRITATION, NAUSEA, VOMITING AND DIARRHEA.
COMPONENT INFORMATION:
CHEMICAL NAME ORAL LD50 DERMAL LD50 INHALATION LC50
COCAMIDOPROPYL BETAINE = 4900 MG/KG
61789-40-0 (RAT)
INFORMATION ON TOXICOLOGICAL EFFECTS:
SYMPTOMS:
ERYTHEMA (SKIN REDNESS). MAY CAUSE REDNESS AND TEARING OF THE EYES.
ITCHING. RASHES. HIVES.
DELAYED AND IMMEDIATE EFFECTS AS WELL AS CHRONIC EFFECTS FROM SHORT AND
LONG-TERM EXPOSURE:
SENSITIZATION:
MAY CAUSE SENSITIZATION OF SUSCEPTIBLE PERSONS BY SKIN CONTACT.
MUTAGENIC EFFECTS: NO INFORMATION AVAILABLE.
CARCINOGENICITY: CONTAINS NO INGREDIENT LISTED AS A CARCINOGEN.
REPRODUCTIVE TOXICITY: NO INFORMATION AVAILABLE.
STOT - SINGLE EXPOSURE: NO INFORMATION AVAILABLE.
STOT - REPEATED EXPOSURE: NO INFORMATION AVAILABLE.
CHRONIC TOXICITY: NO KNOWN EFFECT BASED ON INFORMATION SUPPLIED.
TARGET ORGAN EFFECTS: EYES. SKIN.
ASPIRATION HAZARD: NO INFORMATION AVAILABLE.
NUMERICAL MEASURES OF TOXICITY PRODUCT INFORMATION:
THE FOLLOWING VALUES ARE CALCULATED BASED ON CHAPTER 3.1 OF THE GHS
DOCUMENT
ATEMIX (ORAL): 11,695.00 MG/KG
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY: TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
PERSISTENCE AND DEGRADABILITY: NO INFORMATION AVAILABLE.
BIOACCUMULATION: NO INFORMATION AVAILABLE
OTHER ADVERSE EFFECTS: NO INFORMATION AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
WASTE TREATMENT METHODS:
DISPOSAL METHODS:
THIS MATERIAL, AS SUPPLIED, IS NOT A HAZARDOUS WASTE ACCORDING TO FEDERAL
REGULATIONS (40 CFR 261). THIS MATERIAL COULD BECOME A HAZARDOUS WASTE IF
IT IS MIXED WITH OR OTHERWISE COMES IN CONTACT WITH A HAZARDOUS WASTE, IF
CHEMICAL ADDITIONS ARE MADE TO THIS MATERIAL, OR IF THE MATERIAL IS
PROCESSED OR OTHERWISE ALTERED. CONSULT 40 CFR 261 TO DETERMINE WHETHER
THE ALTERED MATERIAL IS A HAZARDOUS WASTE. CONSULT THE APPROPRIATE STATE,
REGIONAL, OR LOCAL REGULATIONS FOR ADDITIONAL REQUIREMENTS.
CONTAMINATED PACKAGING:
DISPOSE OF CONTENTS/CONTAINERS IN ACCORDANCE WITH LOCAL REGULATIONS.
CALIFORNIA HAZARDOUS WASTE CODES: 561
| 14. TRANSPORT INFORMATION | |
DOT: NOT REGULATED
TDG: NOT REGULATED
MEX: NOT REGULATED
ICAO: NOT REGULATED
IATA: NOT REGULATED
IMDG/IMO: NOT REGULATED
HAZARD CLASS: N/A
RID: NOT REGULATED
ADR: NOT REGULATED
ADN: NOT REGULATED
| 15. REGULATORY INFORMATION | |
INTERNATIONAL INVENTORIES:
TSCA: COMPLIES
DSL: ALL COMPONENTS ARE LISTED EITHER ON THE DSL OR NDSL.
TSCA: UNITED STATES TOXIC SUBSTANCES CONTROL ACT SECTION 8(B) INVENTORY
DSL/NDSL: CANADIAN DOMESTIC SUBSTANCES LIST/NON-DOMESTIC SUBSTANCES LIST
US FEDERAL REGULATIONS:
SARA 313:
SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION
ACT OF 1986 (SARA). THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS WHICH ARE
SUBJECT TO THE REPORTING REQUIREMENTS OF THE ACT AND TITLE 40 OF THE CODE
OF FEDERAL REGULATIONS, PART 372
SARA 311/312 HAZARD CATEGORIES:
ACUTE HEALTH HAZARD: YES
CHRONIC HEALTH HAZARD: NO
FIRE HAZARD: NO
SUDDEN RELEASE OF PRESSURE HAZARD: NO
REACTIVE HAZARD: NO
CWA (CLEAN WATER ACT):
THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES REGULATED AS POLLUTANTS
PURSUANT TO THE CLEAN WATER ACT (40 CFR 122.21 AND 40 CFR 122.42)
CERCLA:
THIS MATERIAL, AS SUPPLIED, DOES NOT CONTAIN ANY SUBSTANCES REGULATED AS
HAZARDOUS SUBSTANCES UNDER THE COMPREHENSIVE ENVIRONMENTAL RESPONSE
COMPENSATION AND LIABILITY ACT (CERCLA) (40 CFR 302) OR THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT (SARA) (40 CFR 355). THERE MAY BE
SPECIFIC REPORTING REQUIREMENTS AT THE LOCAL, REGIONAL, OR STATE LEVEL
PERTAINING TO RELEASES OF THIS MATERIAL
US STATE REGULATIONS:
CALIFORNIA PROPOSITION 65:
THIS PRODUCT DOES NOT CONTAIN ANY PROPOSITION 65 CHEMICALS.
U.S. STATE RIGHT-TO-KNOW REGULATIONS:
CHEMICAL NAME NEW JERSEY MASSACHUSETTS PENNSYLVANIA RHODE ILLINOIS
ISLAND
PHENOXYETHANOL X X X X
122-99-6
INTERNATIONAL REGULATIONS:
CANADA:
WHMIS HAZARD CLASS:
D2B - TOXIC MATERIALS
| 16. OTHER INFORMATION | |
NFPA:
HEALTH HAZARDS 1
FLAMMABILITY 0
INSTABILITY 0
PHYSICAL AND CHEMICAL HAZARDS
HMIS:
HEALTH HAZARDS 1
FLAMMABILITY 0
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
REVISION DATE: 08-MAR-2013
REVISION NOTE: NO INFORMATION AVAILABLE
DISCLAIMER:
THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT TO THE BEST
OF OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS PUBLICATION.
THE INFORMATION GIVEN IS DESIGNED ONLY AS A GUIDANCE FOR SAFE HANDLING,
USE, PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE AND IS NOT
TO BE CONSIDERED A WARRANTY OR QUALITY SPECIFICATION. THE INFORMATION
RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR
SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY
PROCESS, UNLESS SPECIFIED IN THE TEXT
1205822 - GRAINGER TOUGH GUY LAUNDRY DETERGENT (5GUU1)