| Common Name: | RLI FOOD GRADE CLEANER |
| Manufacturer: | RENEWABLE LUBRICANTS |
| SDS Revision Date: | 5/15/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 21A574, 5JGG6, 5JGG7 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
ISSUE DATE: MAY 15, 2015
REVISION DATE: MAY 15, 2015
VERSION: 1
| 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION |  |
AND OF THE COMPANY/UNDERTAKING
PRODUCT IDENTIFIER:
PRODUCT NAME: -RLI FOOD GRADE CLEANER
OTHER MEANS OF IDENTIFICATION:
PRODUCT CODE: 87810, 87812, 87813, 87814, 87816
SYNONYMS: NONE
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE: CLEANING AGENT.
USES ADVISED AGAINST: CONSUMER USE
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
SUPPLIER AND MANUFACTURE:
RENEWABLE LUBRICANTS, INC.
476 GRIGGY RD NE
P.O. BOX 474
HARTVILLE, OH 44632
PHONE: (330) 877-9982
FAX: (330) 877-2266
WWW.RENEWABLELUBE.COM
WWW.RENEWABLELUBRICANTS.COM
EMERGENCY TELEPHONE NUMBER:
EMERGENCY TELEPHONE:
(CHEMTREC): 1-800-424-9300.
OUTSIDE THE U.S.: (703) 527-3887
| 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION:
OSHA REGULATORY STATUS:
THIS CHEMICAL IS CONSIDERED HAZARDOUS BY THE 2012 OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200)
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2A
LABEL ELEMENTS:
EMERGENCY OVERVIEW:
SIGNAL WORD: WARNING
HAZARD STATEMENTS:
CAUSES SKIN IRRITATION
CAUSES SERIOUS EYE IRRITATION
EXCLAMATION MARK
APPEARANCE: AQUEOUS SOLUTION
PHYSICAL STATE: LIQUID
ODOR: PLEASANT
PRECAUTIONARY STATEMENTS - PREVENTION:
WASH FACE, HANDS AND ANY EXPOSED SKIN THOROUGHLY AFTER HANDLING
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION
EYES:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION
SKIN IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION
TAKE OFF CONTAMINATED CLOTHING AND WASH BEFORE REUSE
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC):
OTHER INFORMATION: MAY BE HARMFUL IF SWALLOWED
UNKNOWN ACUTE TOXICITY:
4.32% OF THE MIXTURE CONSISTS OF INGREDIENT(S) OF UNKNOWN TOXICITY
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
THIS MATERIAL IS CONSIDERED HAZARDOUS BY THE OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200).
COMPONENTS CAS-NO WEIGHT % TRADE SECRET
ETHANOL, 2-BUTOXY- 111-76-2 5-15 *
DODECYLBENEZENESULFONIC ACID, 27323-41-7 1-10 *
TRIETHANOLAMINE SALT
SILICA ACID, DISODIUM SALT 6834-92-0 1-10 *
| 4. FIRST AID MEASURES | |
FIRST AID MEASURES:
EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS, FOR AT
LEAST 15 MINUTES. IF EYE IRRITATION PERSISTS, CONSULT A SPECIALIST.
SKIN CONTACT:
WASH OFF IMMEDIATELY WITH SOAP AND PLENTY OF WATER. REMOVE AND WASH
CONTAMINATED CLOTHING BEFORE RE-USE. IF SKIN IRRITATION PERSISTS, CALL A
PHYSICIAN.
INHALATION: MOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
INGESTION: DO NOT INDUCE VOMITING WITHOUT MEDICAL ADVICE.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS: NO INFORMATION AVAILABLE.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA: THE PRODUCT IS NOT FLAMMABLE.
UNSUITABLE EXTINGUISHING MEDIA: NO INFORMATION AVAILABLE
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL: NONE IN PARTICULAR.
EXPLOSION DATA:
SENSITIVITY TO MECHANICAL IMPACT: NONE.
SENSITIVITY TO STATIC DISCHARGE: NONE.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND,
MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
AVOID CONTACT WITH SKIN AND EYES. USE PERSONAL PROTECTIVE EQUIPMENT.
ENVIRONMENTAL PRECAUTIONS:
ENVIRONMENTAL PRECAUTIONS: DO NOT FLUSH INTO SURFACE WATER.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CONTAINMENT:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO.
METHODS FOR CLEANING UP:
WIPE UP WITH ABSORBENT MATERIAL (E.G. CLOTH, FLEECE).
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
HANDLING:
PREPARE THE WORKING SOLUTION AS GIVEN ON THE LABEL(S) AND/OR THE USER
INSTRUCTIONS. HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY
PRACTICE.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE CONDITIONS:
FREEZING WILL AFFECT THE PHYSICAL CONDITION BUT WILL NOT DAMAGE THE
MATERIAL. THAW AND MIX BEFORE USING
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
EXPOSURE GUIDELINES:
COMPONENTS ACGIH TLV OSHA (TWA MG/M3) IDLH
ETHANOL, 2-BUTOXY- - 111-76-2 20 PPM 240 MG/M3
APPROPRIATE ENGINEERING CONTROLS:
ENGINEERING MEASURES TO REDUCE EXPOSURE:
ENSURE ADEQUATE VENTILATION, ESPECIALLY IN CONFINED AREAS.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
RESPIRATORY PROTECTION: NOT REQUIRED; EXCEPT IN CASE OF AEROSOL FORMATION.
HAND PROTECTION: NITRILE RUBBER
EYE PROTECTION: SAFETY GLASSES
SKIN AND BODY PROTECTION:
USUAL SAFETY PRECAUTIONS WHILE HANDLING THE PRODUCT WILL PROVIDE ADEQUATE
PROTECTION AGAINST THIS POTENTIAL EFFECT
GENERAL HYGIENE CONSIDERATIONS: AVOID CONTACT WITH SKIN, EYES AND CLOTHING
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
APPEARANCE: AQUEOUS SOLUTION
ODOR: PLEASANT
COLOR: CLEAR
ODOR THRESHOLD: NO INFORMATION AVAILABLE
PROPERTY VALUES REMARKS - METHOD
PH 11.2
MELTING POINT/FREEZING POINT <=0 DEG. C / 32 DEG. F
BOILING POINT / BOILING RANGE >=100 DEG. C /212 DEG. F
FLASH POINT NO FLASH POINT
EVAPORATION RATE NO INFORMATION AVAILABLE
FLAMMABILITY (SOLID, GAS) NO FLAMMABILITY
FLAMMABILITY LIMIT IN AIR:
UPPER FLAMMABILITY LIMIT NOT FLAMMABLE
LOWER FLAMMABILITY LIMIT NOT FLAMMABLE
VAPOR PRESSURE NO INFORMATION AVAILABLE
VAPOR DENSITY NO INFORMATION AVAILABLE
SPECIFIC GRAVITY >1.0
WATER SOLUBILITY COMPLETELY SOLUBLE
SOLUBILITY IN OTHER SOLVENTS NO INFORMATION AVAILABLE
PARTITION COEFFICIENT NO INFORMATION AVAILABLE
AUTOIGNITION TEMPERATURE NO INFORMATION AVAILABLE
DECOMPOSITION TEMPERATURE NO INFORMATION AVAILABLE
KINEMATIC VISCOSITY NO INFORMATION AVAILABLE
DYNAMIC VISCOSITY NO INFORMATION AVAILABLE
EXPLOSIVE PROPERTIES NO INFORMATION AVAILABLE
OXIDIZING PROPERTIES NO INFORMATION AVAILABLE
OTHER INFORMATION:
SOFTENING POINT NO INFORMATION AVAILABLE
MOLECULAR WEIGHT NO INFORMATION AVAILABLE
VOC CONTENT (%) NOT LISTED AS A
VOC (CARB)
DENSITY NO INFORMATION AVAILABLE
BULK DENSITY NO INFORMATION AVAILABLE
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: NOT APPLICABLE
CHEMICAL STABILITY:
STABILITY: STABLE UNDER NORMAL CONDITIONS
POSSIBILITY OF HAZARDOUS REACTIONS:
POSSIBILITY OF HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
HAZARDOUS POLYMERIZATION: HAZARDOUS POLYMERIZATION DOES NOT OCCUR.
CONDITIONS TO AVOID:
CONDITIONS TO AVOID: NO SPECIAL STORAGE CONDITIONS REQUIRED
HAZARDOUS DECOMPOSITION PRODUCTS:
HAZARDOUS DECOMPOSITION PRODUCTS: NONE REASONABLY FORESEEABLE
INCOMPATIBLE MATERIALS:
INCOMPATIBLE MATERIALS: ACIDS
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
PRODUCT INFORMATION: MAY BE HARMFUL IF SWALLOWED
EYE CONTACT: MODERATELY IRRITATING TO THE EYES.
SKIN CONTACT: MAY CAUSE IRRITATION.
INHALATION: AVOID BREATHING VAPORS OR MISTS.
INGESTION:
INGESTION MAY CAUSE GASTROINTESTINAL IRRITATION, NAUSEA, VOMITING AND
DIARRHOEA.
COMPONENTS ORAL LD50 DERMAL LD50 INHALATION LC50
ETHANOL, 2-BUTOXY- =470 MG/KG =220 MG/KG =450 PPM (RAT) 4 H
111-76-2 (RAT) (RABBIT)
DODECYLBENEZENE- =2320 MG/KG
SULFONIC ACID, (RAT)
TRIETHANOLAMINE
SALT
27323-41-7
SILICA ACID, =600 MG/KG
DISODIUM SALT (RAT)
6834-92-0
INFORMATION ON TOXICOLOGICAL EFFECTS:
DELAYED AND IMMEDIATE EFFECTS AS WELL AS CHRONIC EFFECTS FROM SHORT AND
LONG-TERM EXPOSURE:
SENSITIZATION: NO SENSITIZATION RESPONSES WERE OBSERVED.
MUTAGENIC EFFECTS:
DID NOT SHOW MUTAGENIC OR TERATOGENIC EFFECTS IN ANIMAL EXPERIMENTS.
CARCINOGENICITY:
THIS PRODUCT DOES NOT CONTAIN ANY CARCINOGENS OR POTENTIAL CARCINOGENS AS
LISTED BY OSHA, IARC OR NTP.
REPRODUCTIVE TOXICITY:
THIS PRODUCT DOES NOT CONTAIN ANY KNOWN OR SUSPECTED REPRODUCTIVE HAZARDS.
STOT - SINGLE EXPOSURE: NONE UNDER NORMAL USE CONDITIONS.
STOT - REPEATED EXPOSURE: NONE UNDER NORMAL USE CONDITIONS.
ASPIRATION HAZARD: NOT APPLICABLE.
NUMERICAL MEASURES OF TOXICITY - PRODUCT INFORMATION:
UNKNOWN ACUTE TOXICITY:
4.32% OF THE MIXTURE CONSISTS OF INGREDIENT(S) OF UNKNOWN TOXICITY
THE FOLLOWING VALUES ARE CALCULATED BASED ON CHAPTER 3.1 OF THE GHS
DOCUMENT.:
ATEMIX (ORAL): 3024 MG/KG
ATEMIX (DERMAL): 8130 MG/KG
ATEMIX (INHALATION-DUST/MIST): 13 MG/L
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY: NO KNOWN HAZARDS TO THE AQUATIC ENVIRONMENT.
4.319508% OF THE MIXTURE CONSISTS OF COMPONENTS(S) OF UNKNOWN HAZARDS TO
THE AQUATIC ENVIRONMENT:
ETHANOL, 2-BUTOXY- - 111-76-2:
ALGAE/AQUATIC PLANTS:
FISH:
1490: 96 H LEPOMIS MACROCHIRUS MG/L LC50 STATIC
2950: 96 H LEPOMIS MACROCHIRUS MG/L LC50
CRUSTACEA:
1000: 48 H DAPHNIA MAGNA MG/L EC50
SILICA ACID, DISODIUM SALT - 6834-92-0:
ALGAE/AQUATIC PLANTS:
FISH:
210: 96 H BRACHYDANIO RERIO MG/L LC50
210: 96 H BRACHYDANIO RERIO MG/L LC50 SEMI-STATIC
CRUSTACEA:
PERSISTENCE AND DEGRADABILITY:
READILY BIODEGRADABLE, ACCORDING TO APPROPRIATE OECD TEST. (BASED ON
COMPONENTS).
BIOACCUMULATION: NO INFORMATION AVAILABLE.
MOBILITY: SOLUBLE IN WATER.
COMPONENTS PARTITION COEFFICIENT
ETHANOL, 2-BUTOXY- - 111-76-2 0.81
| 13. DISPOSAL CONSIDERATIONS | |
WASTE TREATMENT METHODS:
DISPOSAL OF WASTES:
DISPOSAL SHOULD BE IN ACCORDANCE WITH APPLICABLE REGIONAL, NATIONAL AND
LOCAL LAWS AND REGULATIONS.
CONTAMINATED PACKAGING: DO NOT REUSE CONTAINER.
| 14. TRANSPORT INFORMATION | |
DOT: NOT REGULATED BY ANY MEANS OF TRANSPORTATION
| 15. REGULATORY INFORMATION | |
INTERNATIONAL INVENTORIES:
TSCA: LISTED IN TSCA
DSL: ALL OF THE COMPONENTS IN THIS PRODUCT ARE LISTED IN DSL
EINECS/ELINCS: THIS PRODUCT COMPLIES WITH EINECS/ELINCS
CHINA: THIS PRODUCT COMPLIES WITH CHINA IECSC.
KECL: THIS PRODUCT COMPLIES WITH KOREA KECL.
PICCS: THIS PRODUCT COMPLIES WITH PHILIPPINES PICCS.
AICS:
ALL THE CONSTITUENTS OF THIS MATERIAL ARE LISTED ON THE AUSTRALIAN AICS
LEGEND:
TSCA: UNITED STATES TOXIC SUBSTANCES CONTROL ACT SECTION 8(B) INVENTORY
DSL/NDSL: CANADIAN DOMESTIC SUBSTANCES LIST/NON-DOMESTIC SUBSTANCES LIST
EINECS/ELINCS:
EUROPEAN INVENTORY OF EXISTING CHEMICAL SUBSTANCES/EUROPEAN LIST OF
NOTIFIED CHEMICAL SUBSTANCES
ENCS: JAPAN EXISTING AND NEW CHEMICAL SUBSTANCES
IECSC: CHINA INVENTORY OF EXISTING CHEMICAL SUBSTANCES
KECL: KOREAN EXISTING AND EVALUATED CHEMICAL SUBSTANCES
PICCS: PHILIPPINES INVENTORY OF CHEMICALS AND CHEMICAL SUBSTANCES
AICS: AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES
FEDERAL REGULATIONS:
SARA 313:
SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION
ACT OF 1986 (SARA). THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS WHICH ARE
SUBJECT TO THE REPORTING REQUIREMENTS OF THE ACT AND TITLE 40 OF THE CODE
OF FEDERAL REGULATIONS, PART 372
COMPONENTS SARA 313 THRESHOLD
ETHANOL, 2-BUTOXY- ETHANOL, 2-BUTOXY- (1%)
SARA 311/312 HAZARD CATEGORIES:
ACUTE HEALTH HAZARD: YES
CHRONIC HEALTH HAZARD: NO
FIRE HAZARD: NO
SUDDEN RELEASE OF PRESSURE HAZARD: NO
REACTIVE HAZARD: NO
CWA (CLEAN WATER ACT):
THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES REGULATED AS POLLUTANTS
PURSUANT TO THE CLEAN WATER ACT (40 CFR 122.21 AND 40 CFR 122.42)
CERCLA:
THIS MATERIAL, AS SUPPLIED, DOES NOT CONTAIN ANY SUBSTANCES REGULATED AS
HAZARDOUS SUBSTANCES UNDER THE COMPREHENSIVE ENVIRONMENTAL RESPONSE
COMPENSATION AND LIABILITY ACT (CERCLA) (40 CFR 302) OR THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT (SARA) (40 CFR 355). THERE MAY BE
SPECIFIC REPORTING REQUIREMENTS AT THE LOCAL, REGIONAL, OR STATE LEVEL
PERTAINING TO RELEASES OF THIS MATERIAL
STATE REGULATIONS (RTK):
CALIFORNIA PROPOSITION 65:
THIS PRODUCT DOES NOT CONTAIN ANY PROPOSITION 65 CHEMICALS
U.S. STATE RIGHT-TO-KNOW REGULATIONS:
COMPONENTS NJRTK MARTK PARTK
ETHANOL, 2-BUTOXY- SUBSTANCE NO. 0275 LISTED. LISTED. LISTED.
111-76-2
DODECYLBENEZENESULFONIC SUBSTANCE NO. 1905 LISTED. LISTED. LISTED.
ACID, TRIETHANOLAMINE
SALT
27323-41-7
U.S. EPA LABEL INFORMATION:
EPA PESTICIDE REGISTRATION NUMBER: NOT APPLICABLE
| 16. OTHER INFORMATION | |
NFPA:
HEALTH 1
FLAMMABILITY 0
INSTABILITY 0
NFPA/HMIS * FOR CARC, MUTA, TERA, SPECIFIC ORGAN *
HMIS HEALTH RATING:
HEALTH 1
FLAMMABILITY 0
PHYSICAL HAZARDS 0
PERSONAL PROTECTION B
DISCLAIMER:
THE INFORMATION PROVIDED IN THIS MATERIAL SAFETY DATA SHEET IS CORRECT TO
THE BEST OF OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS
PUBLICATION. THE INFORMATION GIVEN IS DESIGNED ONLY AS A GUIDANCE FOR SAFE
HANDLING, USE, PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE
AND IS NOT TO BE CONSIDERED A WARRANTY OR QUALITY SPECIFICATION. THE
INFORMATION RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE
VALID FOR SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN
ANY PROCESS, UNLESS SPECIFIED IN THE TEXT.
MATERIAL NAME: RLI FOOD GRADE CLEANER