| Common Name: | PLASTIC AND EMBLEM ADHESIVE - CLEAR, PN 08061 |
| Manufacturer: | 3M |
| SDS Revision Date: | 3/3/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 5LTL2 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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3M(TM) PLASTIC AND EMBLEM ADHESIVE - CLEAR, PN 08061
03/03/15
3M
SAFETY DATA SHEET
COPYRIGHT, 2015, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR THE
PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 10-4794-3
ISSUE DATE: 03/03/15
VERSION NUMBER: 47.00
SUPERCEDES DATE: 09/21/12
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER:
3M(TM) PLASTIC AND EMBLEM ADHESIVE - CLEAR, PN 08061
PRODUCT IDENTIFICATION NUMBERS:
41-0003-7952-3, 41-3701-2181-0, 60-4550-3003-5, 60-4550-5499-3
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE:
ADHESIVE, CLEAR ADHESIVE FOR PLASTIC REPAIR AND EMBLEM APPLICATION
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: AUTOMOTIVE AFTERMARKET
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER: 1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
THE LABEL ELEMENTS BELOW WERE PREPARED IN ACCORDANCE WITH OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200. THIS INFORMATION MAY BE DIFFERENT
FROM THE ACTUAL PRODUCT LABEL INFORMATION FOR LABELS REGULATED BY OTHER
AGENCIES.
2.1. HAZARD CLASSIFICATION:
FLAMMABLE LIQUID: CATEGORY 2.
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 2A.
SKIN SENSITIZER: CATEGORY 1.
SPECIFIC TARGET ORGAN TOXICITY (CENTRAL NERVOUS SYSTEM): CATEGORY 3.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS:
FLAME
EXCLAMATION MARK
PICTOGRAMS:
FLAME
EXCLAMATION MARK
HAZARD STATEMENTS:
HIGHLY FLAMMABLE LIQUID AND VAPOR.
CAUSES SERIOUS EYE IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
MAY CAUSE DROWSINESS OR DIZZINESS.
PRECAUTIONARY STATEMENTS:
GENERAL: KEEP OUT OF REACH OF CHILDREN.
PREVENTION:
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING.
GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT.
USE ONLY NON-SPARKING TOOLS.
TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
KEEP CONTAINER TIGHTLY CLOSED.
USE EXPLOSION-PROOF ELECTRICAL/VENTILATING/LIGHTING EQUIPMENT.
AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY.
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
WEAR PROTECTIVE GLOVES AND EYE/FACE PROTECTION.
WASH THOROUGHLY AFTER HANDLING.
CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
RESPONSE:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF SKIN IRRITATION OR RASH OCCURS:
GET MEDICAL ADVICE/ATTENTION.
WASH CONTAMINATED CLOTHING BEFORE REUSE.
CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
IN CASE OF FIRE:
USE A FIRE FIGHTING AGENT SUITABLE FOR FLAMMABLE LIQUIDS SUCH AS DRY
CHEMICAL OR CARBON DIOXIDE TO EXTINGUISH.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP COOL.
KEEP CONTAINER TIGHTLY CLOSED.
STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
2.3. HAZARDS NOT OTHERWISE CLASSIFIED: NONE.
41% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE ORAL TOXICITY.
41% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE INHALATION
TOXICITY.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
METHYL ETHYL KETONE 78-93-3 30 - 60 TRADE SECRET *
VINYL CHLORIDE, VINYL ACETATE, 32650-26-3 15 - 40 TRADE SECRET *
MALEIC ACID POLYMER
THERMOPLASTIC POLYESTER TRADE SECRET* 15 - 40 TRADE SECRET *
4,4'-ISOPROPYLIDENEDIPHENOL- 25068-38-6 <0.5 TRADE SECRET *
EPICHLOROHYDRIN POLYMER
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND WASH
BEFORE REUSE. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER. REMOVE CONTACT LENSES IF EASY
TO DO. CONTINUE RINSING. GET MEDICAL ATTENTION.
IF SWALLOWED: RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
IN CASE OF FIRE:
USE A FIRE FIGHTING AGENT SUITABLE FOR FLAMMABLE LIQUIDS SUCH AS DRY
CHEMICAL OR CARBON DIOXIDE TO EXTINGUISH.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
CLOSED CONTAINERS EXPOSED TO HEAT FROM FIRE MAY BUILD PRESSURE AND EXPLODE.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
WATER MAY NOT EFFECTIVELY EXTINGUISH FIRE; HOWEVER, IT SHOULD BE USED TO
KEEP FIRE-EXPOSED CONTAINERS AND SURFACES COOL AND PREVENT EXPLOSIVE
RUPTURE.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO
SMOKING. USE ONLY NON-SPARKING TOOLS. VENTILATE THE AREA WITH FRESH AIR.
REFER TO OTHER SECTIONS OF THIS SDS FOR INFORMATION REGARDING PHYSICAL AND
HEALTH HAZARDS, RESPIRATORY PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE
EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. FOR LARGER SPILLS, COVER DRAINS AND BUILD
DIKES TO PREVENT ENTRY INTO SEWER SYSTEMS OR BODIES OF WATER.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
CONTAIN SPILL. WORKING FROM AROUND THE EDGES OF THE SPILL INWARD, COVER WITH
BENTONITE, VERMICULITE, OR COMMERCIALLY AVAILABLE INORGANIC ABSORBENT
MATERIAL. MIX IN SUFFICIENT ABSORBENT UNTIL IT APPEARS DRY. REMEMBER, ADDING
AN ABSORBENT MATERIAL DOES NOT REMOVE A PHYSICAL, HEALTH, OR ENVIRONMENTAL
HAZARD. COLLECT AS MUCH OF THE SPILLED MATERIAL AS POSSIBLE USING
NON-SPARKING TOOLS. PLACE IN A METAL CONTAINER APPROVED FOR TRANSPORTATION
BY APPROPRIATE AUTHORITIES. SEAL THE CONTAINER. DISPOSE OF COLLECTED
MATERIAL AS SOON AS POSSIBLE.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
DO NOT USE IN A CONFINED AREA WITH MINIMAL AIR EXCHANGE. KEEP OUT OF REACH
OF CHILDREN. KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO
SMOKING. USE ONLY NON-SPARKING TOOLS. TAKE PRECAUTIONARY MEASURES AGAINST
STATIC DISCHARGE. AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT
GET IN EYES, ON SKIN, OR ON CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING
THIS PRODUCT. WASH THOROUGHLY AFTER HANDLING. CONTAMINATED WORK CLOTHING
SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE. WASH CONTAMINATED CLOTHING
BEFORE REUSE. AVOID CONTACT WITH OXIDIZING AGENTS (EG. CHLORINE, CHROMIC
ACID ETC.) WEAR LOW STATIC OR PROPERLY GROUNDED SHOES. TO MINIMIZE THE RISK
OF IGNITION, DETERMINE APPLICABLE ELECTRICAL CLASSIFICATIONS FOR THE PROCESS
USING THIS PRODUCT AND SELECT SPECIFIC LOCAL EXHAUST VENTILATION EQUIPMENT
TO AVOID FLAMMABLE VAPOR ACCUMULATION. GROUND/BOND CONTAINER AND RECEIVING
EQUIPMENT IF THERE IS POTENTIAL FOR STATIC ELECTRICITY ACCUMULATION DURING
TRANSFER.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
STORE IN A WELL-VENTILATED PLACE. KEEP COOL. KEEP CONTAINER TIGHTLY CLOSED.
STORE AWAY FROM HEAT. STORE AWAY FROM ACIDS. STORE AWAY FROM OXIDIZING
AGENTS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL
COMMENTS
METHYL ETHYL KETONE 78-93-3 ACGIH TWA: 200 PPM
STEL: 300 PPM
METHYL ETHYL KETONE 78-93-3 OSHA TWA:
590 MG/M3(200 PPM)
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
USE GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO CONTROL
AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR CONTROL
DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE, USE
RESPIRATORY PROTECTION EQUIPMENT. USE EXPLOSION-PROOF VENTILATION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING EYE/FACE PROTECTION(S) ARE RECOMMENDED: INDIRECT VENTED
GOGGLES
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT LOCAL
STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
NOTE:
NITRILE GLOVES MAY BE WORN OVER POLYMER LAMINATE GLOVES TO IMPROVE
DEXTERITY.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED:
BUTYL RUBBER
POLYMER LAMINATE
IF THIS PRODUCT IS USED IN A MANNER THAT PRESENTS A HIGHER POTENTIAL FOR
EXPOSURE (EG. SPRAYING, HIGH SPLASH POTENTIAL ETC.), THEN USE OF PROTECTIVE
COVERALLS MAY BE NECESSARY. SELECT AND USE BODY PROTECTION TO PREVENT
CONTACT BASED ON THE RESULTS OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING PROTECTIVE CLOTHING MATERIAL(S) ARE RECOMMENDED:
APRON - POLYMER LAMINATE
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM. BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT
FROM THE FOLLOWING RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
ORGANIC VAPORS AND PARTICULATES
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: LIQUID
ODOR, COLOR, GRADE: CLEAR, KETONE ODOR
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
MELTING POINT: NO DATA AVAILABLE
BOILING POINT: 176 DEG. F [DETAILS: CONDITIONS: (MEK)]
FLASH POINT:
20 DEG. F [TEST METHOD: TAGLIABUE CLOSED CUP] [DETAILS: CONDITIONS:
(METHYL ETHYL KETONE)]
EVAPORATION RATE: 2.70 [REF STD: WATER=1]
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLAMMABLE LIMITS(LEL): 1.80% VOLUME
FLAMMABLE LIMITS(UEL): 10% VOLUME
VAPOR PRESSURE: 91 MMHg [DETAILS: CONDITIONS: @ 68F]
VAPOR DENSITY: 2.41 [REF STD: AIR=1]
DENSITY: 0.950 G/ML
SPECIFIC GRAVITY: 0.95 [REF STD: WATER=1]
SOLUBILITY IN WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: 404 DEG. C [DETAILS: MEK]
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: APPROXIMATELY 8,500 CENTIPOISE
HAZARDOUS AIR POLLUTANTS:
<0.0001 LB HAPS/LB SOLIDS [TEST METHOD: CALCULATED]
VOLATILE ORGANIC COMPOUNDS:
552 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
VOLATILE ORGANIC COMPOUNDS:
58.1% WEIGHT [TEST METHOD: CALCULATED PER CARB TITLE 2]
PERCENT VOLATILE: 58.1% WEIGHT
VOC LESS H2O & EXEMPT SOLVENTS:
552 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN CONDITIONS -
SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID:
SPARKS AND/OR FLAMES
HEAT
10.5. INCOMPATIBLE MATERIALS: NOT DETERMINED
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
NONE KNOWN.
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL CLASSIFICATION
IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE MANDATED BY A
COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON INGREDIENTS MAY NOT
BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE SIGNS AND SYMPTOMS OF
EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW THE THRESHOLD FOR
LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR EXPOSURE, OR THE DATA MAY
NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY
PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION: MAY BE HARMFUL IF INHALED.
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
SKIN CONTACT:
CONTACT WITH THE SKIN DURING PRODUCT USE IS NOT EXPECTED TO RESULT IN
SIGNIFICANT IRRITATION. ALLERGIC SKIN REACTION (NON-PHOTO INDUCED):
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, BLISTERING, AND ITCHING.
EYE CONTACT:
SEVERE EYE IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE SIGNIFICANT REDNESS, SWELLING, PAIN, TEARING,
CLOUDY APPEARANCE OF THE CORNEA, AND IMPAIRED VISION.
INGESTION: MAY BE HARMFUL IF SWALLOWED.
GASTROINTESTINAL IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA, VOMITING
AND DIARRHEA.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
ADDITIONAL HEALTH EFFECTS:
SINGLE EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS:
CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION:
SIGNS/SYMPTOMS MAY INCLUDE HEADACHE, DIZZINESS, DROWSINESS, INCOORDINATION,
NAUSEA, SLOWED REACTION TIME, SLURRED SPEECH, GIDDINESS, AND
UNCONSCIOUSNESS.
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT INHALATION- NO DATA AVAILABLE;
VAPOR(4 HR) CALCULATED ATE:
20 - 50 MG/L
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE:
2,000 - 5,000 MG/KG
METHYL ETHYL KETONE DERMAL RABBIT LD50: >8,050 MG/KG
METHYL ETHYL KETONE INHALATION- RAT LC50: 34.5 MG/L
VAPOR (4 HOURS)
METHYL ETHYL KETONE INGESTION RAT LD50: 2,737 MG/KG
4,4'-ISOPROPYLIDENEDIPHENOL- DERMAL RAT LD50: >1,600 MG/KG
EPICHLOROHYDRIN POLYMER
4,4'-ISOPROPYLIDENEDIPHENOL- INGESTION RAT LD50: >1,000 MG/KG
EPICHLOROHYDRIN POLYMER
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
METHYL ETHYL KETONE RABBIT MINIMAL IRRITATION
4,4'-ISOPROPYLIDENEDIPHENOL- RABBIT MILD IRRITANT
EPICHLOROHYDRIN POLYMER
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
METHYL ETHYL KETONE RABBIT SEVERE IRRITANT
4,4'-ISOPROPYLIDENEDIPHENOL- RABBIT MODERATE IRRITANT
EPICHLOROHYDRIN POLYMER
SKIN SENSITIZATION:
NAME SPECIES VALUE
4,4'-ISOPROPYLIDENEDIPHENOL- HUMAN AND ANIMAL SENSITIZING
EPICHLOROHYDRIN POLYMER
RESPIRATORY SENSITIZATION:
NAME SPECIES VALUE
4,4'-ISOPROPYLIDENEDIPHENOL- HUMAN SOME POSITIVE DATA EXIST, BUT
EPICHLOROHYDRIN POLYMER THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
METHYL ETHYL KETONE IN VITRO NOT MUTAGENIC
4,4'-ISOPROPYLIDENEDIPHENOL- IN VIVO NOT MUTAGENIC
EPICHLOROHYDRIN POLYMER
4,4'-ISOPROPYLIDENEDIPHENOL- IN VITRO SOME POSITIVE DATA EXIST, BUT
EPICHLOROHYDRIN POLYMER THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
METHYL ETHYL KETONE INHALATION HUMAN NOT CARCINOGENIC
4,4'-ISOPROPYLIDENEDIPHENOL- DERMAL MOUSE SOME POSITIVE DATA
EPICHLOROHYDRIN POLYMER EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE
METHYL ETHYL KETONE INHALATION NOT TOXIC TO FEMALE REPRODUCTION
METHYL ETHYL KETONE INHALATION NOT TOXIC TO MALE REPRODUCTION
METHYL ETHYL KETONE INHALATION SOME POSITIVE DEVELOPMENTAL DATA
EXIST, BUT THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION
4,4'-ISOPROPYLIDENEDIPHENOL- INGESTION NOT TOXIC TO FEMALE REPRODUCTION
EPICHLOROHYDRIN POLYMER
4,4'-ISOPROPYLIDENEDIPHENOL- INGESTION NOT TOXIC TO MALE REPRODUCTION
EPICHLOROHYDRIN POLYMER
4,4'-ISOPROPYLIDENEDIPHENOL- DERMAL NOT TOXIC TO DEVELOPMENT
EPICHLOROHYDRIN POLYMER
4,4'-ISOPROPYLIDENEDIPHENOL- INGESTION NOT TOXIC TO DEVELOPMENT
EPICHLOROHYDRIN POLYMER
NAME SPECIES TEST RESULT EXPOSURE DURATION
METHYL ETHYL KETONE RAT NOAEL: 90 DAYS
14.7 MG/L
METHYL ETHYL KETONE RAT NOAEL: 90 DAYS
14.7 MG/L
METHYL ETHYL KETONE RAT LOAEL: DURING
8.8 MG/L GESTATION
4,4'-ISOPROPYLIDENEDIPHENOL- RAT NOAEL: 2 GENERATION
EPICHLOROHYDRIN POLYMER 750 MG/KG/DAY
4,4'-ISOPROPYLIDENEDIPHENOL- RAT NOAEL: 2 GENERATION
EPICHLOROHYDRIN POLYMER 750 MG/KG/DAY
4,4'-ISOPROPYLIDENEDIPHENOL- RABBIT NOAEL: DURING
EPICHLOROHYDRIN POLYMER 300 MG/KG/DAY ORGANOGENESIS
4,4'-ISOPROPYLIDENEDIPHENOL- RAT NOAEL: 2 GENERATION
EPICHLOROHYDRIN POLYMER 750 MG/KG/DAY
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
METHYL ETHYL KETONE INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
METHYL ETHYL KETONE INHALATION RESPIRATORY SOME POSITIVE DATA
IRRITATION EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
METHYL ETHYL KETONE INGESTION LIVER SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
METHYL ETHYL KETONE INGESTION KIDNEY AND/OR SOME POSITIVE DATA
BLADDER EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
NAME SPECIES TEST RESULT EXPOSURE DURATION
METHYL ETHYL KETONE OFFICIAL NOAEL:
CLASSIFICATION NOT AVAILABLE
METHYL ETHYL KETONE HUMAN NOAEL:
NOT AVAILABLE
METHYL ETHYL KETONE RAT NOAEL: NOT APPLICABLE
NOT AVAILABLE
METHYL ETHYL KETONE RAT LOAEL: NOT APPLICABLE
1,080 MG/KG
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
METHYL ETHYL KETONE DERMAL NERVOUS SYSTEM ALL DATA ARE NEGATIVE
METHYL ETHYL KETONE INHALATION LIVER SOME POSITIVE DATA
KIDNEY AND/OR EXIST, BUT THE DATA
BLADDER ARE NOT SUFFICIENT
FOR CLASSIFICATION
METHYL ETHYL KETONE INHALATION HEART ALL DATA ARE NEGATIVE
ENDOCRINE SYSTEM
BONE, TEETH,
NAILS, AND/OR
HAIR HEMATOPOIETIC
SYSTEM
IMMUNE SYSTEM
MUSCLES
METHYL ETHYL KETONE INGESTION LIVER SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
METHYL ETHYL KETONE INGESTION NERVOUS SYSTEM ALL DATA ARE NEGATIVE
4,4'- DERMAL LIVER SOME POSITIVE DATA
ISOPROPYLIDENEDI- EXIST, BUT THE DATA
PHENOL- ARE NOT SUFFICIENT
EPICHLOROHYDRIN FOR CLASSIFICATION
POLYMER
4,4'- DERMAL NERVOUS SYSTEM ALL DATA ARE NEGATIVE
ISOPROPYLIDENEDI-
PHENOL-
EPICHLOROHYDRIN
POLYMER
4,4'- INGESTION AUDITORY SYSTEM ALL DATA ARE NEGATIVE
ISOPROPYLIDENEDI- HEART
PHENOL- ENDOCRINE SYSTEM
EPICHLOROHYDRIN HEMATOPOIETIC
POLYMER SYSTEM
LIVER
EYES
KIDNEY AND/OR
BLADDER
NAME SPECIES TEST RESULT EXPOSURE DURATION
METHYL ETHYL KETONE GUINEA NOAEL: 31 WEEKS
PIG NOT AVAILABLE
METHYL ETHYL KETONE RAT NOAEL: 90 DAYS
14.7 MG/L
METHYL ETHYL KETONE RAT NOAEL: 90 DAYS
14.7 MG/L
METHYL ETHYL KETONE RAT NOAEL: 7 DAYS
NOT AVAILABLE
METHYL ETHYL KETONE RAT NOAEL: 90 DAYS
173 MG/KG/DAY
4,4'-ISOPROPYLIDENEDIPHENOL- RAT NOAEL: 2 YEARS
EPICHLOROHYDRIN POLYMER 1,000 MG/KG/DAY
4,4'-ISOPROPYLIDENEDIPHENOL- RAT NOAEL: 13 WEEKS
EPICHLOROHYDRIN POLYMER 1,000 MG/KG/DAY
4,4'-ISOPROPYLIDENEDIPHENOL- RAT NOAEL: 28 DAYS
EPICHLOROHYDRIN POLYMER 1,000 MG/KG/DAY
ASPIRATION HAZARD:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR
THE DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
INCINERATE IN A PERMITTED WASTE INCINERATION FACILITY. AS A DISPOSAL
ALTERNATIVE, UTILIZE AN ACCEPTABLE PERMITTED WASTE DISPOSAL FACILITY. EMPTY
DRUMS/BARRELS/CONTAINERS USED FOR TRANSPORTING AND HANDLING HAZARDOUS
CHEMICALS (CHEMICAL SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS HAZARDOUS
AS PER APPLICABLE REGULATIONS) SHALL BE CONSIDERED, STORED, TREATED &
DISPOSED OF AS HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY APPLICABLE WASTE
REGULATIONS. CONSULT WITH THE RESPECTIVE REGULATING AUTHORITIES TO DETERMINE
THE AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT HTTP://3M.COM/TRANSPORTINFO OR CALL
1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
311/312 HAZARD CATEGORIES:
FIRE HAZARD: YES
PRESSURE HAZARD: NO
REACTIVITY HAZARD: NO
IMMEDIATE HAZARD: YES
DELAYED HAZARD: NO
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 2
FLAMMABILITY 3
INSTABILITY 0
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED FOR
USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED ON
THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO INCLUDE
THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT ARE KNOWN
TO BE GENERATED IN SIGNIFICANT QUANTITIES.
DOCUMENT GROUP: 10-4794-3
ISSUE DATE: 03/03/15
VERSION NUMBER: 47.00
SUPERCEDES DATE: 09/21/12
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OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING,
BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A
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FIT FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
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3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED IN
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OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE INFORMATION IN THE SDS
AVAILABLE DIRECTLY FROM 3M
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