| Common Name: | ECO-SURE INDUSTRIAL ENAMEL AEROSOL PAINT, A-A-2787 TYPE I, FLAT BLACK 37038 |
| Manufacturer: | LHB INDUSTRIES |
| SDS Revision Date: | 7/5/2018 |
| SDS Format: | GHS-US |
| Item Number(s): | 5MN11 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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LIGHTHOUSE FOR THE BLIND ST. LOUIS. MO.
SAFETY DATA SHEET
ECO-SURE INDUSTRIAL ENAMEL AEROSOL PAINT
SDS REVISION DATE: 07/05/2018
| 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE |  |
AND OF THE COMPANY/UNDERTAKING
1.1. PRODUCT IDENTIFIER:
PRODUCT IDENTITY: ECO-SURE INDUSTRIAL ENAMEL AEROSOL PAINT
ALTERNATE NAMES:
SPECIFICATION: A-A-2787 TYPE I, FLAT BLACK 37038
LHB PART NUMBER: 0674-390
NATIONAL STOCK NUMBER: 8010-01-331-6108
CAGE CODE: 0FTT5
CONTRACT NUMBER: SPE8EG-16-D-0015
1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
INTENDED USE: SEE PRODUCT LABEL.
APPLICATION METHOD: SEE PRODUCT LABEL.
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
COMPANY NAME:
LHB INDUSTRIES
8833 FLEISCHER PLACE
BERKELEY, MO 63134
EMERGENCY:
24 HOUR EMERGENCY TELEPHONE NO.: (800) 633-8253 (PERS)
CUSTOMER SERVICE:
LHB INDUSTRIES: (314) 423-4333
| 2. HAZARD IDENTIFICATION OF THE PRODUCT | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
FLAM. AEROSOL 1; H222: EXTREMELY FLAMMABLE AEROSOL.
PRESS. GAS; H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
EYE IRRIT. 2; H319: CAUSES SERIOUS EYE IRRITATION.
STOT SE 3; H336:
MAY CAUSE DROWSINESS OR DIZZINESS. SPECIFIC TARGET ORGANS:
(NOT AVAILABLE)
STOT RE 2; H373:
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
SPECIFIC TARGET ORGANS: (CENTRAL NERVOUS SYSTEM)
2.2. LABEL ELEMENTS:
USING THE TOXICITY DATA LISTED IN SECTION 11 AND 12 THE PRODUCT IS LABELED
AS FOLLOWS.
FLAME
GAS CYLINDER
EXCLAMATION MARK
HEALTH HAZARD
DANGER
H222: EXTREMELY FLAMMABLE AEROSOL.
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
H319: CAUSES SERIOUS EYE IRRITATION.
H373: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
[PREVENTION]:
P210:
KEEP AWAY FROM HEAT / SPARKS / OPEN FLAMES / HOT SURFACES - NO SMOKING.
P211: DO NOT SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE.
P251:
PRESSURIZED CONTAINER: DO NOT PIERCE OR BURN, EVEN AFTER USE.
P260: DO NOT BREATHE MIST / VAPORS / SPRAY.
P262: DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING.
P264: WASH THOROUGHLY AFTER HANDLING.
P280: WEAR PROTECTIVE GLOVES / EYE PROTECTION / FACE PROTECTION.
[RESPONSE]:
P301+310:
IF SWALLOWED: IMMEDIATELY CALL A POISON CENTER OR DOCTOR / PHYSICIAN.
P305+351+338:
IF IN EYES:
RINSE CONTINUOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES IF
PRESENT AND EASY TO DO - CONTINUE RINSING.
P314: GET MEDICAL ADVICE / ATTENTION IF YOU FEEL UNWELL.
P331: DO NOT INDUCE VOMITING.
P337+313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE / ATTENTION.
[STORAGE]:
P410+412:
PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING
50 DEG. C / 122 DEG. F.
[DISPOSAL]: NO GHS DISPOSAL STATEMENTS
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES THAT PRESENT A HAZARD WITHIN
THE MEANING OF THE RELEVANT STATE AND FEDERAL HAZARDOUS SUBSTANCES
REGULATIONS.
INGREDIENT/CHEMICAL DESIGNATIONS WEIGHT % GHS CLASSIFICATION NOTES
ACETONE 25 - 50 FLAM. LIQ. 2;H225 [1][2]
CAS NUMBER: 0000067-64-1 EYE IRRIT. 2;H319
STOT SE 3;H336
PROPANE 10 - 25 FLAM. GAS 1;H220 [1][2]
CAS NUMBER: 0000074-98-6 PRESS. GAS;H280
SOLVENT NAPHTHA (PETROLEUM), 1.0 - 10 ASP. TOX. 1;H304 [1]
LIGHT ALIPHATIC
CAS NUMBER: 0064742-89-8
BUTANE 1.0 - 10 FLAM. GAS 1;H220 [1][2]
CAS NUMBER: 0000106-97-8 PRESS. GAS;H280
N-BUTYL ACETATE 1.0 - 10 FLAM. LIQ. 3;H226 [1][2]
CAS NUMBER: 0000123-86-4 STOT SE 3;H336
PROPANE, 2-METHYL- 1.0 - 10 FLAM. GAS 1;H220 [1][2]
CAS NUMBER: 0000075-28-5 PRESS. GAS;H280
CARBON BLACK 1.0 - 10 [1][2]
CAS NUMBER: 0001333-86-4
STODDARD SOLVENT 1.0 - 10 STOT RE 1;H372 [1][2]
CAS NUMBER: 0008052-41-3 ASP. TOX. 1;H304
SOLVENT NAPHTHA (PETROLEUM), 1.0 - 10 ASP. TOX. 1;H304 [1]
LIGHT AROMATIC
CAS NUMBER: 0064742-95-6
[1]: SUBSTANCE CLASSIFIED WITH A HEALTH OR ENVIRONMENTAL HAZARD.
[2]: SUBSTANCE WITH A WORKPLACE EXPOSURE LIMIT.
[3]: PBT-SUBSTANCE OR VPVB-SUBSTANCE.
*THE FULL TEXTS OF THE PHRASES ARE SHOWN IN SECTION 16.
| 4. FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
GENERAL:
MOVE VICTIM TO FRESH AIR.
CALL 911 OR EMERGENCY MEDICAL SERVICE IF DEEMED NECESSARY.
GIVE ARTIFICIAL RESPIRATION IF VICTIM IS NOT BREATHING.
ADMINISTER OXYGEN IF BREATHING IS DIFFICULT.
REMOVE AND ISOLATE CONTAMINATED CLOTHING AND SHOES.
IN CASE OF CONTACT WITH LIQUEFIED GAS, THAW FROSTED PARTS WITH LUKEWARM
WATER.
KEEP VICTIM WARM AND QUIET.
ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE MATERIAL(S) INVOLVED AND
TAKE PRECAUTIONS TO PROTECT THEMSELVES.
INHALATION:
REMOVE TO FRESH AIR, KEEP PATIENT WARM AND AT REST. IF BREATHING IS
IRREGULAR OR STOPPED, GIVE ARTIFICIAL RESPIRATION. IF UNCONSCIOUS PLACE
IN THE RECOVERY POSITION AND OBTAIN IMMEDIATE MEDICAL ATTENTION. GIVE
NOTHING BY MOUTH.
EYES:
IRRIGATE COPIOUSLY WITH CLEAN WATER FOR AT LEAST 15 MINUTES, HOLDING THE
EYELIDS APART AND SEEK MEDICAL ATTENTION.
SKIN:
REMOVE AND ISOLATE CONTAMINATED CLOTHING AND SHOES. CLOTHING FROZEN TO THE
SKIN SHOULD BE THAWED BEFORE BEING REMOVED. IN CASE OF CONTACT WITH
LIQUEFIED GAS, THAW FROSTED PARTS WITH LUKEWARM WATER.
INGESTION:
IF SWALLOWED OBTAIN IMMEDIATE MEDICAL ATTENTION. KEEP AT REST. DO NOT
INDUCE VOMITING.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
OVERVIEW:
POTENTIAL HEALTH EFFECTS:
EYE CONTACT: MAY CAUSE TEARING, STINGING, REDNESS, IRRITATION, AND BURNS.
INHALATION:
IRRITATING TO RESPIRATORY TRACT. PROLONGED OR REPEATED BREATHING OF VERY
HIGH VAPOR CONCENTRATIONS CAUSE EUPHORIA, EXCITATION, AND DIZZINESS,
HEADACHES, NAUSEA, AND VOMITING, ABDOMINAL PAIN, FATIGUE, MUSCULAR
WEAKNESS. ASPIRATION INTO THE LUNGS CAN CAUSE CNS (CENTRAL NERVOUS SYSTEM)
AND SUBSEQUENT ASPIRATION INTO THE LUNGS CAN CAUSE PULMONARY EDEMA AND
CHEMICAL PNEUMONIA DEPRESSION. CHRONIC OVEREXPOSURE IN HIGH CONCENTRATIONS
MAY PRODUCE CNS DEPRESSION.
INGESTION:
IRRITATION OF THE MOUTH, ESOPHAGUS, AND STOMACH CAN DEVELOP FOLLOWING
INGESTION. SYMPTOMS INCLUDE BURNING OF THE MOUTH, SORE THROAT, VOMITING,
NAUSEA, DIZZINESS, LOSS OF CONSCIOUSNESS. DUE TO ITS LIGHT VISCOSITY,
THERE IS DANGER OF ASPIRATION INTO THE LUNGS DURING VOMITING. ASPIRATION
CAN RESULT IN SEVERE LUNG DAMAGE OR DEATH.
SKIN CONTACT:
PROLONGED OR REPEATED SKIN CONTACT MAY CAUSE MODERATE TO SEVERE IRRITATION
INCLUDING ITCHING AND REDNESS OF THE SKIN, DEFATTING, AND/OR DERMATITIS.
THIS PRODUCT CAN ALSO BE ABSORBED THROUGH THE SKIN AND PRODUCE CNS
SYMPTOMS. SINGLE PROLONGED EXPOSURE IS NOT LIKELY TO RESULT IN THE PRODUCT
BEING ABSORBED THROUGH THE SKIN IN HARMFUL AMOUNTS.
SIGNS AND SYMPTOMS OF EXPOSURE:
EYE IRRITATION, RESPIRATORY IRRITATION, DRYING AND CRACKING OF SKIN,
DIZZINESS, FATIGUE, HEADACHE, UNCONSCIOUSNESS OR ASPHYXIATION. CHRONIC
EFFECTS OF INGESTION AND SUBSEQUENT ASPIRATION INTO THE LUNGS CAN CAUSE
PNEUMATOCELE (LUNG CAVITY) FORMATION AND CHRONIC LUNG DYSFUNCTION.
REPEATED BREATHING OF VAPORS CAN CAUSE EFFECTS TO LIVER AND KIDNEYS.
EXPOSURE TO SOLVENT VAPOR CONCENTRATIONS FROM THE COMPONENT SOLVENTS IN
EXCESS OF THE STATED OCCUPATIONAL EXPOSURE LIMITS MAY RESULT IN ADVERSE
HEALTH EFFECTS SUCH AS MUCOUS MEMBRANE AND RESPIRATORY SYSTEM IRRITATION
AND ADVERSE EFFECTS ON THE KIDNEYS, LIVER AND CENTRAL NERVOUS SYSTEM.
SYMPTOMS INCLUDE HEADACHE, NAUSEA, DIZZINESS, FATIGUE, MUSCULAR WEAKNESS,
DROWSINESS AND IN EXTREME CASES, LOSS OF CONSCIOUSNESS.
REPEATED OR PROLONGED CONTACT WITH THE PREPARATION MAY CAUSE REMOVAL OF
NATURAL FAT FROM THE SKIN RESULTING IN DRYNESS, IRRITATION AND POSSIBLE
NON-ALLERGIC CONTACT DERMATITIS. SOLVENTS MAY ALSO BE ABSORBED THROUGH THE
SKIN. SPLASHES OF LIQUID IN THE EYES MAY CAUSE IRRITATION AND SORENESS
WITH POSSIBLE REVERSIBLE DAMAGE. SEE SECTION 2 FOR FURTHER DETAILS.
INHALATION: MAY CAUSE DROWSINESS OR DIZZINESS.
EYES: CAUSES SERIOUS EYE IRRITATION.
| 5. FIRE-FIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
USE DRY CHEMICALS, CARBON DIOXIDE FOAM, WATER FOG, OR INERT GAS (NITROGEN)
FOR SMALL FIRES. FOR LARGE FIRES USE FOAM, WATER FOG, OR WATER SPRAY. WATER
FOG AND SPRAY ARE EFFECTIVE IN COOLING CONTAINERS AND ADJACENT STRUCTURES
BUT MIGHT CAUSE FROTHING AND/OR NOT ACHIEVE EXTINGUISHMENT. A WATER JET MAY
BE USED TO COOL THE CONTAINER'S EXTERNAL WALLS TO PREVENT PRESSURE
BUILD-UP, AUTO IGNITION, OR EXPLOSION. NEVER USE A WATER JET DIRECTLY ON
THE FIRE. PRODUCT WILL FLOAT AND CAN BE RE-IGNITED ON SURFACE OF WATER.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
HAZARDOUS DECOMPOSITION:
HIGH TEMPERATURES AND FIRES MAY PRODUCE SUCH TOXIC SUBSTANCES AS CARBON
MONOXIDE AND CARBON DIOXIDE.
KEEP AWAY FROM HEAT / SPARKS / OPEN FLAMES / HOT SURFACES - NO SMOKING.
DO NOT SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE.
PRESSURIZED CONTAINER: DO NOT PIERCE OR BURN, EVEN AFTER USE.
DO NOT BREATHE MIST / VAPORS / SPRAY.
DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING.
5.3. ADVICE FOR FIRE-FIGHTERS:
WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS (SCBA).
WEAR CHEMICAL PROTECTIVE CLOTHING THAT IS SPECIFICALLY RECOMMENDED BY THE
MANUFACTURER. IT MAY PROVIDE LITTLE OR NO THERMAL PROTECTION.
STRUCTURAL FIREFIGHTERS' PROTECTIVE CLOTHING WILL ONLY PROVIDE LIMITED
PROTECTION.
SOME MAY BURN BUT NONE IGNITE READILY.
CONTAINERS MAY EXPLODE WHEN HEATED.
RUPTURED CYLINDERS MAY ROCKET.
VAPORS MAY CAUSE DIZZINESS OR ASPHYXIATION WITHOUT WARNING.
VAPORS FROM LIQUEFIED GAS ARE INITIALLY HEAVIER THAN AIR AND SPREAD ALONG
GROUND.
CONTACT WITH GAS OR LIQUEFIED GAS MAY CAUSE BURNS, SEVERE INJURY AND/OR
FROSTBITE.
FIRE MAY PRODUCE IRRITATING, CORROSIVE AND/OR TOXIC GASES.
ERG GUIDE NO.: 126
| 6. ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
DO NOT TOUCH OR WALK THROUGH SPILLED MATERIAL.
STOP LEAK IF YOU CAN DO IT WITHOUT RISK.
DO NOT DIRECT WATER AT SPILL OR SOURCE OF LEAK.
USE WATER SPRAY TO REDUCE VAPORS OR DIVERT VAPOR CLOUD DRIFT. AVOID
ALLOWING WATER RUNOFF TO CONTACT SPILLED MATERIAL.
IF POSSIBLE, TURN LEAKING CONTAINERS SO THAT GAS ESCAPES RATHER THAN
LIQUID.
PREVENT ENTRY INTO WATERWAYS, SEWERS, BASEMENTS OR CONFINED AREAS.
ALLOW SUBSTANCE TO EVAPORATE.
VENTILATE THE AREA.
6.2. ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW SPILLS TO ENTER DRAINS OR WATERWAYS.
USE GOOD PERSONAL HYGIENE PRACTICES. WASH HANDS BEFORE EATING, DRINKING,
SMOKING OR USING TOILET. PROMPTLY REMOVE SOILED CLOTHING AND WASH
THOROUGHLY BEFORE REUSE.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
STAY UPWIND.
MANY GASES ARE HEAVIER THAN AIR AND WILL SPREAD ALONG GROUND AND COLLECT IN
LOW OR CONFINED AREAS (SEWERS, BASEMENTS, TANKS).
KEEP OUT OF LOW AREAS.
VENTILATE CLOSED SPACES BEFORE ENTERING.
ELIMINATE IGNITION SOURCES. SOAK UP WITH NONCOMBUSTIBLE ABSORBENT MATERIAL.
REMOVE ABSORBENT MATERIAL FOR PROPER DISPOSAL.
| 7. HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
STORE IN ACCORDANCE WITH THE NATIONAL FIRE PROTECTION ASSOCIATION'S
PUBLICATION NFPA 30, FLAMMABLE AND COMBUSTIBLE LIQUIDS CODE.
29 CFR 1910.106 APPLIES TO THE HANDLING, STORAGE, AND USE OF FLAMMABLE AND
COMBUSTIBLE LIQUIDS.
SEE SECTION 2 FOR FURTHER DETAILS. - [PREVENTION]:
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
HANDLE CONTAINERS CAREFULLY TO PREVENT DAMAGE AND SPILLAGE.
STORE THIS PRODUCT BELOW 120 DEG. F, IN A COOL, DRY, WELL VENTILATED AREA
AWAY FROM HEAT, SPARKS, FLAME, OXIDIZERS AND OUT OF DIRECT SUNLIGHT.
INCOMPATIBLE MATERIALS:
STRONG ACIDS, ALKALIS, AND OXIDIZERS SUCH AS LIQUID CHLORINE, HALOGENS,
HYDROGEN PEROXIDE, OXYGEN.
OTHER PRECAUTIONS:
ALL LABELED PRECAUTIONS MUST BE OBSERVED WHEN HANDLING, STORING AND
TRANSPORTING EMPTY CONTAINERS DUE TO PRODUCT RESIDUES. DO NOT REUSE
CONTAINERS. EMPTY CONTAINERS MAY CONTAIN MATERIAL RESIDUES WHICH CAN IGNITE
WITH EXPLOSIVE FORCE. CUTTING OR WELDING OF EMPTY CONTAINERS CAN CAUSE
FIRE, EXPLOSION, OR RELEASE FUMES FROM RESIDUES. KEEP CONTAINERS CLOSED AND
DRUM BUNGS IN PLACE. DISPOSE OF IN A LICENSED FACILITY.
SEE SECTION 2 FOR FURTHER DETAILS. - [STORAGE]:
7.3. SPECIFIC END USE(S): NO DATA AVAILABLE.
| 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
EXPOSURE:
CAS NO. INGREDIENT SOURCE VALUE
0000067-64-1 ACETONE OSHA TWA: 1000 PPM (2400 MG/M3)
STEL: 2400 MG/M3
ACGIH TWA: 250 PPM
STEL: 500 PPM SKIN
NIOSH 250 PPM (590 MG/M3) TWA
SUPPLIER NO ESTABLISHED LIMIT
0000074-98-6 PROPANE OSHA TWA: 1000 PPM (1800 MG/M3)
ACGIH ENSURE MINIMAL OXYGEN CONTENT
(ACGIH APPENDIX F)
NIOSH TWA: 1000 PPM (1800 MG/M3)
SUPPLIER NO ESTABLISHED LIMIT
0000075-28-5 PROPANE, 2-METHYL- OSHA NO ESTABLISHED LIMIT
ACGIH STEL: 1000 PPM
NIOSH TWA: 800 PPM (1900 MG/M3)
SUPPLIER NO ESTABLISHED LIMIT
0000106-97-8 BUTANE OSHA NO ESTABLISHED LIMIT
ACGIH TWA: 600 PPM
STEL: 750 PPM
NIOSH TWA: 800 PPM (1900 MG/M3)
SUPPLIER NO ESTABLISHED LIMIT
0000123-86-4 N-BUTYL ACETATE OSHA TWA: 150 PPM (710 MG/M3
ACGIH TWA: 20 PPMS
NIOSH TWA: 150 PPM (710 MG/M3)
ST: 200 PPM (950 MG/M3)
SUPPLIER NO ESTABLISHED LIMIT
0001333-86-4 CARBON BLACK OSHA TWA: 3.5 MG/M3
ACGIH TWA: 3 MG/M32B, REVISED 2011
NIOSH TWA: 3.5 MG/M3
CA TWA 0.1 MG PAHS/M3
[IN PRESENCE OF POLYCYCLIC
AROMATIC HYDROCARBONS (PAHS)]
SUPPLIER NO ESTABLISHED LIMIT
0008052-41-3 STODDARD SOLVENT OSHA TWA: 500 PPM (2900 MG/M3)
ACGIH TWA: 290 MG/M3
STEL: 580 MG/M3
NIOSH TWA: 350 MG/M3
C: 1800 MG/M3 [15-MINUTE]
SUPPLIER NO ESTABLISHED LIMIT
0064742-89-8 SOLVENT NAPHTHA OSHA NO ESTABLISHED LIMIT
(PETROLEUM), LIGHT
ALIPHATIC ACGIH NO ESTABLISHED LIMIT
NIOSH NO ESTABLISHED LIMIT
SUPPLIER NO ESTABLISHED LIMIT
0064742-95-6 SOLVENT NAPHTHA OSHA NO ESTABLISHED LIMIT
(PETROLEUM), LIGHT
AROMATLC ACGIH NO ESTABLISHED LIMIT
NIOSH NO ESTABLISHED LIMIT
SUPPLIER NO ESTABLISHED LIMIT
CARCINOGEN DATA:
CAS NO. INGREDIENT SOURCE VALUE
0000067-64-1 ACETONE OSHA SELECT CARCINOGEN: NO
NTP KNOWN: NO
SUSPECTED: NO
IARC GROUP 1: NO
GROUP 2A: NO
GROUP 2B: NO
GROUP 3: NO
GROUP 4: NO
0000074-98-6 PROPANE OSHA SELECT CARCINOGEN: NO
NTP KNOWN: NO
SUSPECTED: NO
IARC GROUP 1: NO
GROUP 2A: NO
GROUP 2B: NO
GROUP 3: NO
GROUP 4: NO
0000075-28-5 PROPANE, 2-METHYL- OSHA SELECT CARCINOGEN: NO
NTP KNOWN: NO
SUSPECTED: NO
IARC GROUP 1: NO
GROUP 2A: NO
GROUP 2B: NO
GROUP 3: NO
GROUP 4: NO
0000106-97-8 BUTANE OSHA SELECT CARCINOGEN: NO
NTP KNOWN: NO
SUSPECTED: NO
IARC GROUP 1: NO
GROUP 2A: NO
GROUP 2B: NO
GROUP 3: NO
GROUP 4: NO
0000123-86-4 N-BUTYL ACETATE OSHA SELECT CARCINOGEN: NO
NTP KNOWN: NO
SUSPECTED: NO
IARC GROUP 1: NO
GROUP 2A: NO
GROUP 2B: NO
GROUP 3: NO
GROUP 4: NO
0001333-86-4 CARBON BLACK OSHA SELECT CARCINOGEN: NO
NTP KNOWN: NO
SUSPECTED: NO
IARC GROUP 1: NO
GROUP 2A: NO
GROUP 2B: YES
GROUP 3: NO
GROUP 4: NO
0008052-41-3 STODDARD SOLVENT OSHA SELECT CARCINOGEN: NO
NTP KNOWN: NO
SUSPECTED: NO
IARC GROUP 1: NO
GROUP 2A: NO
GROUP 2B: NO
GROUP 3: NO
GROUP 4: NO
0064742-89-8 SOLVENT NAPHTHA OSHA SELECT CARCINOGEN: NO
(PETROLEUM), LIGHT
ALIPHATIC NTP KNOWN: NO
SUSPECTED: NO
IARC GROUP 1: NO
GROUP 2A: NO
GROUP 2B: NO
GROUP 3: NO
GROUP 4: NO
0064742-95-6 SOLVENT NAPHTHA OSHA SELECT CARCINOGEN: NO
(PETROLEUM), LIGHT
AROMATIC NTP KNOWN: NO
SUSPECTED: NO
IARC GROUP 1: NO
GROUP 2A: NO
GROUP 2B: NO
GROUP 3: NO
GROUP 4: NO
8.2. EXPOSURE CONTROLS:
RESPIRATORY:
IF WORKERS ARE EXPOSED TO CONCENTRATIONS ABOVE THE EXPOSURE LIMIT THEY MUST
USE THE APPROPRIATE, CERTIFIED RESPIRATORS.
EYES:
WEAR SAFETY EYEWEAR, E.G. SAFETY SPECTACLES, GOGGLES OR VISORS TO PROTECT
AGAINST THE SPLASH OF LIQUIDS.
SKIN:
OVERALLS WHICH COVER THE BODY, ARMS AND LEGS SHOULD BE WORN. SKIN SHOULD
NOT BE EXPOSED. ALL PARTS OF THE BODY SHOULD BE WASHED AFTER CONTACT. WEAR
NITRILE OR SIMILAR CHEMICAL RESISTANT GLOVES TO KEEP SKIN CONTACT TO A
MINIMUM.
REFER TO THE MANUFACTURER'S RECOMMENDATIONS REGARDING THE SUITABILITY OF
ANY GLOVES USED.
ENGINEERING CONTROLS:
PROVIDE ADEQUATE VENTILATION. WHERE REASONABLY PRACTICABLE THIS SHOULD
BE ACHIEVED BY THE USE OF LOCAL EXHAUST VENTILATION AND GOOD GENERAL
EXTRACTION. IF THESE ARE NOT SUFFICIENT TO MAINTAIN CONCENTRATIONS OF
PARTICULATES AND ANY VAPOR BELOW OCCUPATIONAL EXPOSURE LIMITS SUITABLE
RESPIRATORY PROTECTION MUST BE WORN.
OTHER WORK PRACTICES:
USE GOOD PERSONAL HYGIENE PRACTICES. WASH HANDS BEFORE EATING, DRINKING,
SMOKING OR USING TOILET. PROMPTLY REMOVE SOILED CLOTHING AND WASH
THOROUGHLY BEFORE REUSE.
SEE SECTION 2 FOR FURTHER DETAILS. - [PREVENTION]:
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: BLACK LIQUID/GAS
ODOR: PAINT
ODOR THRESHOLD: NOT MEASURED
PH: NOT MEASURED
MELTING POINT / FREEZING POINT: NOT MEASURED
INITIAL BOILING POINT AND BOILING RANGE: NOT MEASURED
FLASH POINT: PROPELLANT <0 F
EVAPORATION RATE (ETHER = 1): SLOWER THAN ETHER
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS:
LOWER EXPLOSIVE LIMIT: 1.1
UPPER EXPLOSIVE LIMIT: 12.8
VAPOR PRESSURE (PA): NOT MEASURED
VAPOR DENSITY: >1 (HEAVIER THAN AIR)
SPECIFIC GRAVITY: 0.754 (6.28 LB/GAL)
SOLUBILITY IN WATER: INSOLUBLE
PARTITION COEFFICIENT N-OCTANOL/WATER (LOG KOW): NOT MEASURED
AUTO-IGNITION TEMPERATURE: NOT MEASURED
DECOMPOSITION TEMPERATURE: NOT MEASURED
VISCOSITY (CST): NOT MEASURED
VOC %: 49.0% BY WT, 4.32 IB/GAL, 517 G/L (MINUS WATER AND EXEMPT SOLVENTS)
MAXIMUM INCREMENTAL REACTIVITY: 0.64
HAPS (LBS/GAL): 0.0
HAPS (LBS/GAL OF SOLIDS): 0.0
HAPS (LBS/LB OF SOLIDS): 0.0
% VOLATILE (BY VOLUME): 88.7
9.2. OTHER INFORMATION: NO OTHER RELEVANT INFORMATION.
| 10. STABILITY AND REACTIVITY | |
10.1. REACTIVITY: HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.2. CHEMICAL STABILITY: STABLE UNDER NORMAL CIRCUMSTANCES.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS: NO DATA AVAILABLE.
10.4. CONDITIONS TO AVOID:
AVOID CONTACT WITH OPEN FLAME, SPARKS OR HOT SURFACES.
10.5. INCOMPATIBLE MATERIALS:
STRONG ACIDS, ALKALIS, AND OXIDIZERS SUCH AS LIQUID CHLORINE, HALOGENS,
HYDROGEN PEROXIDE, OXYGEN.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
HIGH TEMPERATURES AND FIRES MAY PRODUCE SUCH TOXIC SUBSTANCES AS CARBON
MONOXIDE AND CARBON DIOXIDE.
| 11. TOXICOLOGICAL INFORMATION | |
ACUTE TOXICITY:
EXPOSURE TO SOLVENT VAPOR CONCENTRATIONS FROM THE COMPONENT SOLVENTS IN
EXCESS OF THE STATED OCCUPATIONAL EXPOSURE LIMITS MAY RESULT IN ADVERSE
HEALTH EFFECTS SUCH AS MUCOUS MEMBRANE AND RESPIRATORY SYSTEM IRRITATION
AND ADVERSE EFFECTS ON THE KIDNEYS, LIVER AND CENTRAL NERVOUS SYSTEM.
SYMPTOMS INCLUDE HEADACHE, NAUSEA, DIZZINESS, FATIGUE, MUSCULAR WEAKNESS,
DROWSINESS AND IN EXTREME CASES, LOSS OF CONSCIOUSNESS.
REPEATED OR PROLONGED CONTACT WITH THE PREPARATION MAY CAUSE REMOVAL OF
NATURAL FAT FROM THE SKIN RESULTING IN DRYNESS, IRRITATION AND POSSIBLE
NON-ALLERGIC CONTACT DERMATITIS. SOLVENTS MAY ALSO BE ABSORBED THROUGH THE
SKIN. SPLASHES OF LIQUID IN THE EYES MAY CAUSE IRRITATION AND SORENESS WITH
POSSIBLE REVERSIBLE DAMAGE.
BASED UPON ANIMAL TESTING, THE C9 AROMATIC HYDROCARBON COMPONENTS
(TRIMETHYLBENZENES AND ETHYLMETHYLBENZENES) ARE PRESUMED TO CAUSE FETAL
TOXICITY AND/OR DECREASED FETAL AND NEWBORN WEIGHTS IF OVEREXPOSURE OCCURS
DURING THE EARLY GESTATION PERIOD.
INGREDIENT ORAL LD50, MG/KG SKIN LD50, MG/KG
ACETONE - (67-64-1) 2,000.00, RAT - 2,000.00, RABBIT -
CATEGORY: 4 CATEGORY: 4
PROPANE - (74-98-6) NO DATA AVAILABLE NO DATA AVAILABLE
SOLVENT NAPHTHA (PETROLEUM), 5,000.00, MOUSE - 3,000.00, RABBIT -
LIGHT ALIPHATIC - (64742-89-8) CATEGORY: 5 CATEGORY: 5
BUTANE - (106-97-8) NO DATA AVAILABLE NO DATA AVAILABLE
N-BUTYL ACETATE - (123-86-4) 10,700.00, RAT - 17,600.00, RABBIT -
CATEGORY: NA CATEGORY: NA
PROPANE, 2-METHYL- - (75-28-5) NO DATA AVAILABLE NO DATA AVAILABLE
CARBON BLACK - (1333-86-4) 8,000.00, RAT - NO DATA AVAILABLE
CATEGORY: NA
STODDARD SOLVENT - (8052-41 -3) NO DATA AVAILABLE NO DATA AVAILABLE
SOLVENT NAPHTHA (PETROLEUM), 6,800.00, RAT - 3,400.00, RABBIT -
LIGHT AROMATIC - (64742-95-6) CATEGORY: NA CATEGORY: 5
INGREDIENT INHALATION INHALATION INHALATION
VAPOR LD50, DUST/MIST LD50, GAS LD50,
MG/L/4HR MG/L/4HR PPM
ACETONE 76.00, RAT - NO DATA NO DATA
CATEGORY: NA AVAILABLE AVAILABLE
PROPANE 658.00, RAT - NO DATA NO DATA
CATEGORY: NA AVAILABLE AVAILABLE
SOLVENT NAPHTHA NO DATA NO DATA NO DATA
(PETROLEUM), LIGHT AVAILABLE AVAILABLE AVAILABLE
ALIPHATIC
BUTANE 658.00, RAT - NO DATA NO DATA
CATEGORY: NA AVAILABLE AVAILABLE
N-BUTYL ACETATE NO DATA NO DATA NO DATA
AVAILABLE AVAILABLE AVAILABLE
PROPANE, 2-METHYL- 658.00, RAT - NO DATA NO DATA
CATEGORY: NA AVAILABLE AVAILABLE
CARBON BLACK NO DATA NO DATA NO DATA
AVAILABLE AVAILABLE AVAILABLE
STODDARD SOLVENT NO DATA NO DATA NO DATA
AVAILABLE AVAILABLE AVAILABLE
SOLVENT NAPHTHA NO DATA NO DATA NO DATA
(PETROLEUM), LIGHT AVAILABLE AVAILABLE AVAILABLE
AROMATIC
NOTE:
WHEN NO ROUTE SPECIFIC LD50 DATA IS AVAILABLE FOR AN ACUTE TOXIN, THE
CONVERTED ACUTE TOXICITY POINT ESTIMATE WAS USED IN THE CALCULATION OF
THE PRODUCT'S ATE (ACUTE TOXICITY ESTIMATE).
CLASSIFICATION CATEGORY HAZARD DESCRIPTION
ACUTE TOXICITY (ORAL) NOT APPLICABLE
ACUTE TOXICITY (DERMAL) NOT APPLICABLE
ACUTE TOXICITY (INHALATION) NOT APPLICABLE
SKIN CORROSION/IRRITATION NOT APPLICABLE
SERIOUS EYE DAMAGE/IRRITATION 2 CAUSES SERIOUS EYE IRRITATION.
RESPIRATORY SENSITIZATION NOT APPLICABLE
SKIN SENSITIZATION NOT APPLICABLE
GERM CELL MUTAGENICITY NOT APPLICABLE
CARCINOGENICITY NOT APPLICABLE
REPRODUCTIVE TOXICITY NOT APPLICABLE
STOT-SINGLE EXPOSURE 3 MAY CAUSE DROWSINESS OR DIZZINESS.
STOT-REPEATED EXPOSURE 2 MAY CAUSE DAMAGE TO ORGANS THROUGH
PROLONGED OR REPEATED EXPOSURE.
ASPIRATION HAZARD NOT APPLICABLE
| 12. ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
AQUATIC ECOTOXICITY:
INGREDIENT 96 HR LC50 48 HR EC50 ERC50
FISH, MG/L CRUSTACEA, MG/L ALGAE, MG/L
ACETONE - (67-64-1) 100.00, PIMEPHALES 10.00, DAPHNIA 20.565 (72 HR),
PROMELAS MAGNA ULVA PERTUSA
PROPANE - (74-98-6) NOT AVAILABLE NOT AVAILABLE NOT AVAILABLE
SOLVENT NAPHTHA NOT AVAILABLE NOT AVAILABLE 4,700.00
(PETROLEUM), LIGHT (72 HR),
ALIPHATIC - SELENASTRUM
(64742-89-8) CAPRICORNUTUM
BUTANE - (106-97-8) 6.00, FISH NOT AVAILABLE NOT AVAILABLE
(PISCIS)
N-BUTYL ACETATE - 18.00, PIMEPHALES 32.00, ARTEMIA 674.70 (72 HR),
(123-86-4) PROMELAS SALINA SCENEDESMUS
SUBSPICATUS
PROPANE, 2-METHYL- NOT AVAILABLE NOT AVAILABLE NOT AVAILABLE
-(75-28-5)
CARBON BLACK - 1,000.00, DANIO 5,600.00, 10,000.00
(1333-86-4) RERIO DAPHNIA (72 HR),
MAGNA SCENEDESMUS
SUBSPICATUS
STODDARD SOLVENT - NOT AVAILABLE NOT AVAILABLE NOT AVAILABLE
(8052-41-3)
SOLVENT NAPHTHA 9.22, ONCORHYNCHUS 6.14, DAPHNIA 19.00 (72 HR),
(PETROLEUM), LIGHT MYKISS MAGNA SELENASTRUM
AROMATIC - CAPRICORNUTUM
(64742-95-6)
12.2. PERSISTENCE AND DEGRADABILITY:
THERE IS NO DATA AVAILABLE ON THE PREPARATION ITSELF.
12.3. BIOACCUMULATIVE POTENTIAL: NOT MEASURED
12.4. MOBILITY IN SOIL: NO DATA AVAILABLE.
12.5. RESULTS OF PBT AND VPVB ASSESSMENT:
THIS PRODUCT CONTAINS NO PBT/VPVB CHEMICALS.
12.6. OTHER ADVERSE EFFECTS: NO DATA AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
13.1. WASTE TREATMENT METHODS:
DO NOT ALLOW INTO DRAINS OR WATER COURSES. WASTES AND EMPTIED CONTAINERS
SHOULD BE DISPOSED OF IN ACCORDANCE WITH REGULATIONS MADE UNDER THE CONTROL
OF POLLUTION ACT AND THE ENVIRONMENTAL PROTECTION ACT.
USING INFORMATION PROVIDED IN THIS DATA SHEET ADVICE SHOULD BE OBTAINED
FROM THE WASTE REGULATION AUTHORITY, WHETHER THE SPECIAL WASTE REGULATIONS
APPLY.
| 14. TRANSPORT INFORMATION | |
DOT (DOMESTIC IMO / IMDG ICAO/IATA
SURFACE (OCEAN
TRANSPORTATION) TRANSPORTATION)
14.1. UN NUMBER UN1950 UN1950 UN1950
14.2. UN PROPER UN1950, AEROSOLS, AEROSOLS, LIMITED AEROSOLS, LIMITED
SHIPPING NAME LIMITED QUANTITY, QUANTITY QUANTITY
2.1,
14.3. TRANSPORT DOT HAZARD CLASS: IMDG: 2.1 AIR CLASS: 2.1
HAZARD CLASS(ES) 2.1
14.4. PACKING NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE
GROUP
14.5. ENVIRONMENTAL HAZARDS:
IMDG:
MARINE POLLUTANT: NO
14.6. SPECIAL PRECAUTIONS FOR USER: NO FURTHER INFORMATION
14.7. TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL73/78 AND THE IBC
CODE: NOT APPLICABLE
| 15. REGULATORY INFORMATION | |
REGULATORY OVERVIEW:
THE REGULATORY DATA IN SECTION 15 IS NOT INTENDED TO BE ALL-INCLUSIVE,
ONLY SELECTED REGULATIONS ARE REPRESENTED.
TOXIC SUBSTANCE CONTROL ACT (TSCA):
ALL COMPONENTS OF THIS MATERIAL ARE EITHER LISTED OR EXEMPT FROM LISTING ON
THE TSCA INVENTORY.
WHMIS CLASSIFICATION: D2B
US EPA TIER II HAZARDS:
FIRE: NO
SUDDEN RELEASE OF PRESSURE: YES
REACTIVE: NO
IMMEDIATE (ACUTE): YES
DELAYED (CHRONIC): YES
EPCRA 311/312 CHEMICALS AND RQS (LBS):
ACETONE (5,000.00)
N-BUTYL ACETATE (5,000.00)
EPCRA 302 EXTREMELY HAZARDOUS: (NO PRODUCT INGREDIENTS LISTED)
EPCRA 313 TOXIC CHEMICALS: (NO PRODUCT INGREDIENTS LISTED)
PROPOSITION 65 - CARCINOGENS (>0.0%): (NO PRODUCT INGREDIENTS LISTED)
PROPOSITION 65 - DEVELOPMENTAL TOXINS (>0.0%):
(NO PRODUCT INGREDIENTS LISTED)
PROPOSITION 65 - FEMALE REPRO TOXINS (>0.0%):
(NO PRODUCT INGREDIENTS LISTED)
PROPOSITION 65 - MALE REPRO TOXINS (>0.0%):
(NO PRODUCT INGREDIENTS LISTED)
N.J. RTK SUBSTANCES (>1%):
ACETONE
BUTANE
CARBON BLACK
N-BUTYL ACETATE
PROPANE
PROPANE, 2-METHYL-
STODDARD SOLVENT
PENN RTK SUBSTANCES (>1%):
ACETONE
BUTANE
CARBON BLACK
N-BUTYL ACETATE
PROPANE
PROPANE, 2-METHYL-
STODDARD SOLVENT
| 16. OTHER INFORMATION | |
THE INFORMATION AND RECOMMENDATIONS CONTAINED HEREIN ARE BASED UPON DATA
BELIEVED TO BE CORRECT. HOWEVER, NO GUARANTEE OR WARRANTY OF ANY KIND,
EXPRESSED OR IMPLIED, IS MADE WITH RESPECT TO THE INFORMATION CONTAINED
HEREIN. WE ACCEPT NO RESPONSIBILITY AND DISCLAIM ALL LIABILITY FOR ANY
HARMFUL EFFECTS WHICH MAY BE CAUSED BY EXPOSURE TO OUR PRODUCTS.
CUSTOMERS/USERS OF THIS PRODUCT MUST COMPLY WITH ALL APPLICABLE HEALTH
AND SAFETY LAWS, REGULATIONS, AND ORDERS.
THE FULL TEXT OF THE PHRASES APPEARING IN SECTION 3 IS:
H220: EXTREMELY FLAMMABLE GAS.
H225: HIGHLY FLAMMABLE LIQUID AND VAPOR.
H226: FLAMMABLE LIQUID AND VAPOR.
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
H304: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
H319: CAUSES SERIOUS EYE IRRITATION.
H336: MAY CAUSE DROWSINESS AND DIZZINESS.
H372: CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
THIS IS THE FIRST VERSION IN THE GHS SDS FORMAT. LISTINGS OF CHANGES FROM
PREVIOUS VERSIONS IN OTHER FORMATS ARE NOT APPLICABLE.
IMPORTANT NOTE:
THIS INFORMATION IS FURNISHED WITHOUT WARRANTY, EXPRESSED OR IMPLIED, AS TO
ACCURACY OR COMPLETENESS. THE INFORMATION IS OBTAINED FROM VARIOUS SOURCES
INCLUDING THE MANUFACTURER AND OTHER THIRD PARTY SOURCES. THE INFORMATION
MAY NOT BE VALID UNDER ALL CONDITIONS NOR IF THIS MATERIAL IS USED IN
COMBINATION WITH OTHER MATERIALS OR ANY PROCESS. FINAL DETERMINATION OF
SUITABILITY OF ANY MATERIAL IS THE SOLE RESPONSIBILITY OF THE USER.