| Common Name: | ECO-SURE INDUSTRIAL ENAMEL AEROSOL PAINT |
| Manufacturer: | LHB INDUSTRIES |
| SDS Revision Date: | 8/28/2018 |
| SDS Format: | GHS-US |
| Item Number(s): | 5MN13 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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LIGHTHOUSE FOR THE BLIND ST. LOUIS, MO.
SAFETY DATA SHEET
ECO-SURE INDUSTRIAL ENAMEL AEROSOL PAINT
SDS REVISION DATE: 08/28/2018
| 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE |  |
AND OF THE COMPANY/UNDERTAKING
1.1. PRODUCT IDENTIFIER:
PRODUCT IDENTITY: ECO-SURE INDUSTRIAL ENAMEL AEROSOL PAINT
ALTERNATE NAMES:
SPECIFICATION: A-A-2787 TYPE I, GLOSS RED 11105
LHB PART NUMBER: 0674-110
NATIONAL STOCK NUMBER: 8010-01-331-6110
CAGE CODE: 0FTT5
CONTRACT NUMBER: SPE8EG-16-D-0015
1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
INTENDED USE: SEE PRODUCT LABEL.
APPLICATION METHOD: SEE PRODUCT LABEL.
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
COMPANY NAME:
LHB INDUSTRIES
8833 FLEISCHER PLACE
BERKELEY, MO 63134
EMERGENCY:
24 HOUR EMERGENCY TELEPHONE NO.: (800)633-8253 (PERS)
CUSTOMER SERVICE:
LHB INDUSTRIES: (314)423-4333
| 2. HAZARD IDENTIFICATION OF THE PRODUCT | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
FLAM. AEROSOL 1;
H222: EXTREMELY FLAMMABLE AEROSOL.
PRESS. GAS;
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
ACUTE TOX. 5;
H303: MAY BE HARMFUL IF SWALLOWED. (NOT ADOPTED BY US OSHA)
SKIN IRRIT. 3;
H316: CAUSES MILD SKIN IRRITATION. (NOT ADOPTED BY US OSHA)
EYE IRRIT. 2;
H319: CAUSES SERIOUS EYE IRRITATION.
STOT SE 3;
H336: MAY CAUSE DROWSINESS OR DIZZINESS.
2.2. LABEL ELEMENTS:
USING THE TOXICITY DATA LISTED IN SECTION 11 AND 12 THE PRODUCT IS LABELED
AS FOLLOWS.
FLAME
GAS CYLINDER
EXCLAMATION MARK
DANGER
H222: EXTREMELY FLAMMABLE AEROSOL.
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
H303: MAY BE HARMFUL IF SWALLOWED.
H316: CAUSES MILD SKIN IRRITATION.
H319: CAUSES SERIOUS EYE IRRITATION.
H336: MAY CAUSE DROWSINESS AND DIZZINESS.
[PREVENTION]:
P210:
KEEP AWAY FROM HEAT / SPARKS / OPEN FLAMES / HOT SURFACES - NO SMOKING.
P211: DO NOT SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE.
P251:
PRESSURIZED CONTAINER: DO NOT PIERCE OR BURN, EVEN AFTER USE.
P261: AVOID BREATHING DUST / FUME / GAS / MIST / VAPORS / SPRAY.
P264: WASH THOROUGHLY AFTER HANDLING.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P280: WEAR PROTECTIVE GLOVES / EYE PROTECTION / FACE PROTECTION.
[RESPONSE]:
P304+312:
IF INHALED: CALL A POISON CENTER OR DOCTOR / PHYSICIAN IF YOU FEEL UNWELL.
P305+351+338:
IF IN EYES:
RINSE CONTINUOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES IF
PRESENT AND EASY TO DO - CONTINUE RINSING.
P332+313:
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE / ATTENTION.
P337+313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE / ATTENTION.
P340:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING.
[STORAGE]:
P403+233: STORE IN A WELL VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
P405: STORE LOCKED UP.
P410+412:
PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING 50 DEG. C /
122 DEG. F.
[DISPOSAL]:
P501:
DISPOSE OF CONTENTS / CONTAINER IN ACCORDANCE WITH LOCAL / NATIONAL
REGULATIONS.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES THAT PRESENT A HAZARD WITHIN
THE MEANING OF THE RELEVANT STATE AND FEDERAL HAZARDOUS SUBSTANCES
REGULATIONS.
INGREDIENT/CHEMICAL DESIGNATIONS WEIGHT % GHS CLASSIFICATION NOTES
2-PROPANONE 10 - 25 FLAM. LIQ. 2; H225 [1][2]
CAS NUMBER: 0000067-64-1 EYE IRRIT. 2; H319
STOT SE 3; H336
PROPANE 10 - 25 FLAM. GAS 1; H220 [1][2]
CAS NUMBER: 0000074-98-6 PRESS. GAS; H280
N-BUTYL ACETATE 10 - 25 FLAM. LIQ. 3; H226 [1][2]
CAS NUMBER: 0000123-86-4 STOT SE 3; H336
BUTANE 1.0 - 10 FLAM. GAS 1; H220 [1][2]
CAS NUMBER: 0000106-97-8 PRESS. GAS; H280
PROPANE, 2-METHYL- 1.0 - 10 FLAM. GAS 1; H220 [1][2]
CAS NUMBER: 0000075-28-5 PRESS. GAS; H280
5-METHYL-2-HEXANONE 1.0 - 10 FLAM. LIQ. 3; H226 [1][2]
CAS NUMBER: 0000110-12-3 ACUTE TOX. 4; H332
BUTAN-1-OL 1.0 - 10 FLAM. LIQ. 3; H226 [1][2]
CAS NUMBER: 0000071-36-3 ACUTE TOX. 4; H302
STOT SE 3; H335
SKIN IRRIT. 2; H315
EYE DAM. 1; H318
STOT SE 3; H336
PENTAN-2-ONE 1.0 - 10 FLAM. LIQ. 2; H225 [1][2]
CAS NUMBER: 0000107-87-9 ACUTE TOX. 4; H302
EYE IRRIT. 2; H319
STOT SE 3; H335
SKIN IRRIT. 2; H315
ISO-BUTYL ACETATE . 1.0 - 10 FLAM. LIQ. 2; H225 [1][2]
CAS NUMBER: 0000110-19-0
HEPTAN-2-ONE 1.0 - 10 FLAM. LIQ. 3; H226 [1][2]
CAS NUMBER: 0000110-43-0 ACUTE TOX. 4; H332
ACUTE TOX. 4; H302
4-HYDROXY-4-METHLYPENTAN-2-ONE 1.0 - 10 EYE IRRIT. 2; H319 [1][2]
CAS NUMBER: 0000123-42-2
[1]SUBSTANCE CLASSIFIED WITH A HEALTH OR ENVIRONMENTAL HAZARD.
[2]SUBSTANCE WITH A WORKPLACE EXPOSURE LIMIT.
[3]PBT-SUBSTANCE OR VPVB-SUBSTANCE.
*THE FULL TEXTS OF THE PHRASES ARE SHOWN IN SECTION 16.
| 4. FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
GENERAL:
MOVE VICTIM TO FRESH AIR.
CALL 911 OR EMERGENCY MEDICAL SERVICE IF DEEMED NECESSARY.
GIVE ARTIFICIAL RESPIRATION IF VICTIM IS NOT BREATHING.
ADMINISTER OXYGEN IF BREATHING IS DIFFICULT.
REMOVE AND ISOLATE CONTAMINATED CLOTHING AND SHOES.
IN CASE OF CONTACT WITH LIQUEFIED GAS, THAW FROSTED PARTS WITH LUKEWARM
WATER.
KEEP VICTIM WARM AND QUIET.
ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE MATERIAL(S) INVOLVED AND
TAKE PRECAUTIONS TO PROTECT THEMSELVES.
INHALATION:
REMOVE TO FRESH AIR, KEEP PATIENT WARM AND AT REST. IF BREATHING IS
IRREGULAR OR STOPPED, GIVE ARTIFICIAL RESPIRATION. IF UNCONSCIOUS PLACE IN
THE RECOVERY POSITION AND OBTAIN IMMEDIATE MEDICAL ATTENTION. GIVE NOTHING
BY MOUTH.
EYES:
IRRIGATE COPIOUSLY WITH CLEAN FRESH WATER FOR AT LEAST 15 MINUTES, HOLDING
THE EYELIDS APART AND SEEK MEDICAL ATTENTION.
SKIN:
REMOVE AND ISOLATE CONTAMINATED CLOTHING AND SHOES. CLOTHING FROZEN TO THE
SKIN SHOULD BE THAWED BEFORE BEING REMOVED. IN CASE OF CONTACT WITH
LIQUEFIED GAS, THAW FROSTED PARTS WITH LUKEWARM WATER.
INGESTION:
IF ACCIDENTALLY SWALLOWED OBTAIN IMMEDIATE MEDICAL ATTENTION. KEEP AT REST.
DO NOT INDUCE VOMITING.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
OVERVIEW:
EXPOSURE TO SOLVENT VAPOR CONCENTRATIONS FROM THE COMPONENT SOLVENTS IN
EXCESS OF THE STATED OCCUPATIONAL EXPOSURE LIMITS MAY RESULT IN ADVERSE
HEALTH EFFECTS SUCH AS MUCOUS MEMBRANE AND RESPIRATORY SYSTEM IRRITATION
AND ADVERSE EFFECTS ON THE KIDNEYS, LIVER AND CENTRAL NERVOUS SYSTEM.
SYMPTOMS INCLUDE HEADACHE, NAUSEA, DIZZINESS, FATIGUE, MUSCULAR WEAKNESS,
DROWSINESS AND IN EXTREME CASES, LOSS OF CONSCIOUSNESS.
REPEATED OR PROLONGED CONTACT WITH THE PREPARATION MAY CAUSE REMOVAL OF
NATURAL FAT FROM THE SKIN RESULTING IN DRYNESS, IRRITATION AND POSSIBLE
NON-ALLERGIC CONTACT DERMATITIS. SOLVENTS MAY ALSO BE ABSORBED THROUGH THE
SKIN. SPLASHES OF LIQUID IN THE EYES MAY CAUSE IRRITATION AND SORENESS
WITH POSSIBLE REVERSIBLE DAMAGE. SEE SECTION 2 FOR FURTHER DETAILS.
INHALATION: MAY CAUSE DROWSINESS OR DIZZINESS.
EYES: CAUSES SERIOUS EYE IRRITATION.
SKIN: CAUSES MILD SKIN IRRITATION. (NOT ADOPTED BY US OSHA)
INGESTION: MAY BE HARMFUL IF SWALLOWED. (NOT ADOPTED BY US OSHA)
| 5. FIRE-FIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
FIRE INVOLVING TANKS:
SOME OF THESE MATERIALS, IF SPILLED, MAY EVAPORATE LEAVING A FLAMMABLE
RESIDUE. SOME OF THESE MATERIALS, IF SPILLED, MAY EVAPORATE LEAVING A
FLAMMABLE RESIDUE.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
CARBON MONOXIDE AND CARBON DIOXIDE
KEEP AWAY FROM HEAT / SPARKS / OPEN FLAMES / HOT SURFACES - NO SMOKING.
DO NOT SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE.
PRESSURIZED CONTAINER: DO NOT PIERCE OR BURN, EVEN AFTER USE.
AVOID BREATHING DUST / FUME / GAS / MIST / VAPORS / SPRAY.
5.3. ADVICE FOR FIRE-FIGHTERS:
WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS (SCBA).
WEAR CHEMICAL PROTECTIVE CLOTHING THAT IS SPECIFICALLY RECOMMENDED BY THE
MANUFACTURER. IT MAY PROVIDE LITTLE OR NO THERMAL PROTECTION.
STRUCTURAL FIREFIGHTERS' PROTECTIVE CLOTHING WILL ONLY PROVIDE LIMITED
PROTECTION.
SOME MAY BURN BUT NONE IGNITE READILY.
CONTAINERS MAY EXPLODE WHEN HEATED.
RUPTURED CYLINDERS MAY ROCKET.
VAPORS MAY CAUSE DIZZINESS OR ASPHYXIATION WITHOUT WARNING.
VAPORS FROM LIQUEFIED GAS ARE INITIALLY HEAVIER THAN AIR AND SPREAD ALONG
GROUND.
CONTACT WITH GAS OR LIQUEFIED GAS MAY CAUSE BURNS, SEVERE INJURY AND/OR
FROSTBITE.
FIRE MAY PRODUCE IRRITATING, CORROSIVE AND/OR TOXIC GASES.
ERG GUIDE NO.: 126
| 6. ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
DO NOT TOUCH OR WALK THROUGH SPILLED MATERIAL.
STOP LEAK IF YOU CAN DO IT WITHOUT RISK.
DO NOT DIRECT WATER AT SPILL OR SOURCE OF LEAK.
USE WATER SPRAY TO REDUCE VAPORS OR DIVERT VAPOR CLOUD DRIFT. AVOID
ALLOWING WATER RUNOFF TO CONTACT SPILLED MATERIAL.
IF POSSIBLE, TURN LEAKING CONTAINERS SO THAT GAS ESCAPES RATHER THAN
LIQUID.
PREVENT ENTRY INTO WATERWAYS, SEWERS, BASEMENTS OR CONFINED AREAS.
ALLOW SUBSTANCE TO EVAPORATE.
VENTILATE THE AREA.
6.2. ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW SPILLS TO ENTER DRAINS OR WATERCOURSES.
USE GOOD PERSONAL HYGIENE PRACTICES. WASH HANDS BEFORE EATING, DRINKING,
SMOKING OR USING TOILET. PROMPTLY REMOVE SOILED CLOTHING AND WASH
THOROUGHLY BEFORE REUSE.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
AS AN IMMEDIATE PRECAUTIONARY MEASURE, ISOLATE SPILL OR LEAK AREA FOR AT
LEAST 100 METERS (330 FEET) IN ALL DIRECTIONS.
KEEP UNAUTHORIZED PERSONNEL AWAY.
STAY UPWIND.
MANY GASES ARE HEAVIER THAN AIR AND WILL SPREAD ALONG GROUND AND COLLECT IN
LOW OR CONFINED AREAS (SEWERS, BASEMENTS, TANKS).
KEEP OUT OF LOW AREAS.
VENTILATE CLOSED SPACES BEFORE ENTERING.
| 7. HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
STORE IN ACCORDANCE WITH THE NATIONAL FIRE PROTECTION ASSOCIATION'S
PUBLICATION NFPA 30, FLAMMABLE AND COMBUSTIBLE LIQUIDS CODE. 29 CFR
1910.106 APPLIES TO THE HANDLING, STORAGE, AND USE OF FLAMMABLE AND
COMBUSTIBLE LIQUIDS.
SEE SECTION 2 FOR FURTHER DETAILS. - [PREVENTION]:
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
HANDLE CONTAINERS CAREFULLY TO PREVENT DAMAGE AND SPILLAGE.
INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS
SEE SECTION 2 FOR FURTHER DETAILS. - [STORAGE]:
7.3. SPECIFIC END USE(S): NO DATA AVAILABLE.
| 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
EXPOSURE:
CAS NO. INGREDIENT SOURCE VALUE
0000067-64-1 2-PROPANONE OSHA TWA: 1000 PPM (2400 MG/M3)
STEL: 2400 MG/M3
ACGIH TWA: 250 PPM
STEL: 500 PPM SKIN
NIOSH 250 PPM (590 MG/M3) TWA
SUPPLIER NO ESTABLISHED LIMIT
0000071-36-3 BUTAN-1-OL OSHA TWA: 100 PPM (300 MG/M3)
ACGIH TWA: 15 PPM
CEILING: 30 PPM
NIOSH C 50 PPM (150 MG/M3) [SKIN]
SUPPLIER NO ESTABLISHED LIMIT
0000074-98-6 PROPANE OSHA TWA: 1000 PPM (1800 MG/M3)
ACGIH NO ESTABLISHED LIMIT
NIOSH TWA: 1000 PPM (1800 MG/M3)
SUPPLIER NO ESTABLISHED LIMIT
0000075-28-5 PROPANE, 2-METHYL- OSHA NO ESTABLISHED LIMIT
ACGIH NO ESTABLISHED LIMIT
NIOSH TWA: 800 PPM (1900 MG/M3)
SUPPLIER NO ESTABLISHED LIMIT
0000106-97-8 BUTANE OSHA NO ESTABLISHED LIMIT
ACGIH TWA: 600 PPM
STEL: 750 PPM
NIOSH TWA: 800 PPM (1900 MG/M3)
SUPPLIER NO ESTABLISHED LIMIT
0000107-87-9 PENTAN-2-ONE OSHA TWA: 200 PPM (700 MG/M3)
ACGIH TWA: 150 PPM
STEL: 250 PPM
NIOSH TWA: 150 PPM (530 MG/M3)
SUPPLIER NO ESTABLISHED LIMIT
0000110-12-3 5-METHYL-2-HEXANONE OSHA TWA: 100 PPM (475 MG/M3)
ACGIH TWA: 50 PPM
NIOSH TWA: 50 PPM (240 MG/M3)
SUPPLIER NO ESTABLISHED LIMIT
0000110-19-0 ISO-BUTYL ACETATE. OSHA TWA: 150 PPM (700 MG/M3)
ACGIH TWA: 150 PPM
NIOSH TWA: 150 PPM (700 MG/M3)
SUPPLIER NO ESTABLISHED LIMIT
0000110-43-0 HEPTAN-2-ONE OSHA TWA: 100 PPM (465 MG/M3)
ACGIH TWA: 50 PPM
NIOSH TWA: 100 PPM (465 MG/M3)
SUPPLIER NO ESTABLISHED LIMIT
0000123-42-2 4-HYDROXY-4- OSHA TWA: 50 PPM (240 MG/M3)
METHLYPENTAN-2-ONE ACGIH TWA: 50 PPM
NIOSH TWA: 50 PPM (240 MG/M3)
SUPPLIER NO ESTABLISHED LIMIT
0000123-86-4 N-BUTYL ACETATE OSHA TWA: 150 PPM (710 MG/M3
ACGIH TWA: 20 PPMS
NIOSH TWA: 150 PPM (710 MG/M3)
ST: 200 PPM (950 MG/M3)
SUPPLIER NO ESTABLISHED LIMIT
CARCINOGEN DATA:
CAS NO. INGREDIENT SOURCE VALUE
0000067-64-1 2-PROPANONE OSHA SELECT CARCINOGEN: NO
NTP KNOWN: NO
SUSPECTED: NO
IARC GROUP 1: NO
GROUP 2A: NO
GROUP 2B: NO
GROUP 3: NO
GROUP 4: NO
0000071-36-3 BUTAN-1-OL OSHA SELECT CARCINOGEN: NO
NTP KNOWN: NO
SUSPECTED: NO
IARC GROUP 1: NO
GROUP 2A: NO
GROUP 2B: NO
GROUP 3: NO
GROUP 4: NO
0000074-98-6 PROPANE OSHA SELECT CARCINOGEN: NO
NTP KNOWN: NO
SUSPECTED: NO
IARC GROUP 1: NO
GROUP 2A: NO
GROUP 2B: NO
GROUP 3: NO
GROUP 4: NO
0000075-28-5 PROPANE, 2-METHYL- OSHA SELECT CARCINOGEN: NO
NTP KNOWN: NO
SUSPECTED: NO
IARC GROUP 1: NO
GROUP 2A: NO
GROUP 2B: NO
GROUP 3: NO
GROUP 4: NO
0000106-97-8 BUTANE OSHA SELECT CARCINOGEN: NO
NTP KNOWN: NO
SUSPECTED: NO
IARC GROUP 1: NO
GROUP 2A: NO
GROUP 2B: NO
GROUP 3: NO
GROUP 4: NO
0000107-87-9 PENTAN-2-ONE OSHA SELECT CARCINOGEN: NO
NTP KNOWN: NO
SUSPECTED: NO
IARC GROUP 1: NO
GROUP 2A: NO
GROUP 2B: NO
GROUP 3: NO
GROUP 4: NO
0000110-12-3 5-METHYL-2-HEXANONE OSHA SELECT CARCINOGEN: NO
NTP KNOWN: NO
SUSPECTED: NO
IARC GROUP 1: NO
GROUP 2A: NO
GROUP 2B: NO
GROUP 3: NO
GROUP 4: NO
0000110-19-0 ISO-BUTYL ACETATE. OSHA SELECT CARCINOGEN: NO
NTP KNOWN: NO
SUSPECTED: NO
IARC GROUP 1: NO
GROUP 2A: NO
GROUP 2B: NO
GROUP 3: NO
GROUP 4: NO
0000110-43-0 HEPTAN-2-ONE OSHA SELECT CARCINOGEN: NO
NTP KNOWN: NO
SUSPECTED: NO
IARC GROUP 1: NO
GROUP 2A: NO
GROUP 2B: NO
GROUP 3: NO
GROUP 4: NO
0000123-42-2 4-HYDROXY-4- OSHA SELECT CARCINOGEN: NO
METHLYPENTAN-2-ONE
NTP KNOWN: NO
SUSPECTED: NO
IARC GROUP 1: NO
GROUP 2A: NO
GROUP 2B: NO
GROUP 3: NO
GROUP 4: NO
0000123-86-4 N-BUTYL ACETATE OSHA SELECT CARCINOGEN: NO
NTP KNOWN: NO
SUSPECTED: NO
IARC GROUP 1: NO
GROUP 2A: NO
GROUP 2B: NO
GROUP 3: NO
GROUP 4: NO
8.2. EXPOSURE CONTROLS:
RESPIRATORY:
IF WORKERS ARE EXPOSED TO CONCENTRATIONS ABOVE THE EXPOSURE LIMIT THEY MUST
USE THE APPROPRIATE, CERTIFIED RESPIRATORS.
EYES:
WEAR SAFETY EYEWEAR, E.G. SAFETY SPECTACLES, GOGGLES OR VISORS TO PROTECT
AGAINST THE SPLASH OF LIQUIDS.
SKIN:
OVERALLS WHICH COVER THE BODY, ARMS AND LEGS SHOULD BE WORN. SKIN SHOULD
NOT BE EXPOSED. ALL PARTS OF THE BODY SHOULD BE WASHED AFTER CONTACT.
ENGINEERING CONTROLS:
PROVIDE ADEQUATE VENTILATION. WHERE REASONABLY PRACTICABLE THIS SHOULD BE
ACHIEVED BY THE USE OF LOCAL EXHAUST VENTILATION AND GOOD GENERAL
EXTRACTION. IF THESE ARE NOT SUFFICIENT TO MAINTAIN CONCENTRATIONS OF
PARTICULATES AND ANY VAPOR BELOW OCCUPATIONAL EXPOSURE LIMITS SUITABLE
RESPIRATORY PROTECTION MUST BE WORN.
OTHER WORK PRACTICES:
USE GOOD PERSONAL HYGIENE PRACTICES. WASH HANDS BEFORE EATING, DRINKING,
SMOKING OR USING TOILET. PROMPTLY REMOVE SOILED CLOTHING AND WASH
THOROUGHLY BEFORE REUSE.
SEE SECTION 2 FOR FURTHER DETAILS. - [PREVENTION]:
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: RED LIQUID/GAS
ODOR: PAINT
ODOR THRESHOLD: NOT MEASURED
PH: NOT MEASURED
MELTING POINT / FREEZING POINT: NOT MEASURED
INITIAL BOILING POINT AND BOILING RANGE: NOT MEASURED
FLASH POINT: NOT MEASURED
EVAPORATION RATE (ETHER = 1): SLOWER THAN ETHER
FLAMMABILITY (SOLID, GAS):
FLAM. AEROSOL 1; H222 EXTREMELY FLAMMABLE AEROSOL.
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS:
LOWER EXPLOSIVE LIMIT: 1.1%
UPPER EXPLOSIVE LIMIT: 12.8%
VAPOR PRESSURE (PA): NOT MEASURED
VAPOR DENSITY: >1(HEAVIER THAN AIR)
SPECIFIC GRAVITY: 0.746 (6.56 LB/GAL)
SOLUBILITY IN WATER: INSOLUBLE
PARTITION COEFFICIENT N-OCTANOL/WATER (LOG KOW): NOT MEASURED
AUTO-IGNITION TEMPERATURE: NOT MEASURED
DECOMPOSITION TEMPERATURE: NOT MEASURED
VISCOSITY (CST): NOT MEASURED
VOC %: 54.8% BY WT, 4.52 LB/GAL
MAXIMUM INCREMENTAL REACTIVITY: 0.67
HAPS (LBS/GAL): 0.00 LBS/GAL
HAPS (LBS/GAL OF SOLIDS): 0.00 LBS/GAL
HAPS (LBS/LB OF SOLIDS): 0.00 LBS/LB
9.2. OTHER INFORMATION: NO OTHER RELEVANT INFORMATION.
| 10. STABILITY AND REACTIVITY | |
10.1. REACTIVITY: HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.2. CHEMICAL STABILITY: STABLE UNDER NORMAL CIRCUMSTANCES.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS: NO DATA AVAILABLE.
10.4. CONDITIONS TO AVOID:
AVOID CONTACT WITH OPEN FLAME, SPARKS OR HOT SURFACES.
10.5. INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS
10.6. HAZARDOUS DECOMPOSITION PRODUCTS: CARBON MONOXIDE AND CARBON DIOXIDE
| 11. TOXICOLOGICAL INFORMATION | |
ACUTE TOXICITY:
EXPOSURE TO SOLVENT VAPOR CONCENTRATIONS FROM THE COMPONENT SOLVENTS IN
EXCESS OF THE STATED OCCUPATIONAL EXPOSURE LIMITS MAY RESULT IN ADVERSE
HEALTH EFFECTS SUCH AS MUCOUS MEMBRANE AND RESPIRATORY SYSTEM IRRITATION
AND ADVERSE EFFECTS ON THE KIDNEYS, LIVER AND CENTRAL NERVOUS SYSTEM.
SYMPTOMS INCLUDE HEADACHE, NAUSEA, DIZZINESS, FATIGUE, MUSCULAR WEAKNESS,
DROWSINESS AND IN EXTREME CASES, LOSS OF CONSCIOUSNESS.
REPEATED OR PROLONGED CONTACT WITH THE PREPARATION MAY CAUSE REMOVAL OF
NATURAL FAT FROM THE SKIN RESULTING IN DRYNESS, IRRITATION AND POSSIBLE
NON-ALLERGIC CONTACT DERMATITIS. SOLVENTS MAY ALSO BE ABSORBED THROUGH THE
SKIN. SPLASHES OF LIQUID IN THE EYES MAY CAUSE IRRITATION AND SORENESS
WITH POSSIBLE REVERSIBLE DAMAGE.
INGREDIENT ORAL LD50, SKIN LD50, INHALATION INHALATION INHALATION
MG/KG MG/KG VAPOR LD50, DUST/MIST GAS LD50,
MG/L/4HR LD50, PPM
MG/L/4HR
2-PROPANONE - 2,000.00, 2,000.00, 76.00, RAT NO DATA NO DATA
(67-64-1) RAT - RABBIT - - CATEGORY: AVAILABLE AVAILABLE
CATEGORY: 4 CATEGORY: NA
4
PROPANE - NO DATA NO DATA 658.00, RAT NO DATA NO DATA
(74-98-6) AVAILABLE AVAILABLE - CATEGORY: AVAILABLE AVAILABLE
NA
N-BUTYL 10,700.00, 17,600.00, NO DATA NO DATA NO DATA
ACETATE - RAT - RABBIT - AVAILABLE AVAILABLE AVAILABLE
(123-86-4) CATEGORY: CATEGORY:
NA NA
BUTANE - NO DATA NO DATA 658.00, RAT NO DATA NO DATA
(106-97-8) AVAILABLE AVAILABLE - CATEGORY: AVAILABLE AVAILABLE
NA
PROPANE, NO DATA NO DATA 658.00, RAT NO DATA NO DATA
2-METHYL- - AVAILABLE AVAILABLE - CATEGORY: AVAILABLE AVAILABLE
(75-28-5) NA
5-METHYL-2- 3,200.00, 8,110.00, NO DATA NO DATA NO DATA
HEXANONE - RAT - RABBIT - AVAILABLE AVAILABLE AVAILABLE
(110-12-3) CATEGORY: 5 CATEGORY:
NA
BUTAN-1-OL - 2,292.00, 3,430.00, NO DATA NO DATA 8,000.00,
(71-36-3) RAT - RABBIT - AVAILABLE AVAILABLE RAT -
CATEGORY: 5 CATEGORY: CATEGORY:
5 4
PENTAN-2-ONE 1,600.00, 6,500.00, NO DATA NO DATA NO DATA
- (107-87-9) RAT - RABBIT - AVAILABLE AVAILABLE AVAILABLE
CATEGORY: 4 CATEGORY:
NA
ISO-BUTYL 13,400.00, 17,400.00, NO DATA NO DATA NO DATA
ACETATE. - RAT - RABBIT - AVAILABLE AVAILABLE AVAILABLE
(110-19-0) CATEGORY: CATEGORY:
NA NA
HEPTAN-2-ONE 1,670.00, 12,600.00, NO DATA NO DATA NO DATA
- (110-43-0) RAT - RABBIT - AVAILABLE AVAILABLE AVAILABLE
CATEGORY: 4 CATEGORY:
NA
4-HYDROXY-4- 2,520.00, 13,500.00, NO DATA NO DATA 1,500.00,
METHLYPENTAN- RAT - RABBIT - AVAILABLE AVAILABLE RAT -
2-ONE - CATEGORY: 5 CATEGORY: CATEGORY:
(123-42-2) NA NA
NOTE:
WHEN NO ROUTE SPECIFIC LD50 DATA IS AVAILABLE FOR AN ACUTE TOXIN, THE
CONVERTED ACUTE TOXICITY POINT ESTIMATE WAS USED IN THE CALCULATION OF THE
PRODUCT'S ATE (ACUTE TOXICITY ESTIMATE).
CLASSIFICATION CATEGORY HAZARD DESCRIPTION
ACUTE TOXICITY (ORAL) 5 MAY BE HARMFUL IF SWALLOWED. (NOT
ADOPTED BY US OSHA)
ACUTE TOXICITY (DERMAL) NOT APPLICABLE
ACUTE TOXICITY (INHALATION) NOT APPLICABLE
SKIN CORROSION/IRRITATION 3 CAUSES MILD SKIN IRRITATION. (NOT
ADOPTED BY US OSHA)
SERIOUS EYE DAMAGE/IRRITATION 2 CAUSES SERIOUS EYE IRRITATION.
RESPIRATORY SENSITIZATION NOT APPLICABLE
SKIN SENSITIZATION NOT APPLICABLE
GERM CELL MUTAGENICITY NOT APPLICABLE
CARCINOGENICITY NOT APPLICABLE
REPRODUCTIVE TOXICITY NOT APPLICABLE
STOT-SINGLE EXPOSURE 3 MAY CAUSE DROWSINESS OR DIZZINESS.
STOT-REPEATED EXPOSURE NOT APPLICABLE
ASPIRATION HAZARD NOT APPLICABLE
| 12. ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
AQUATIC ECOTOXICITY:
INGREDIENT 96 HR LC50 FISH, 48 HR EC50 CRUSTACEA, ERC50 ALGAE,
MG/L MG/L MG/L
2-PROPANONE - 100.00, PIMEPHALES 1 0.00, DAPHNIA MAGNA 20.565 (72 HR),
(67-64-1) PROMELAS ULVA PERTUSA
PROPANE - NOT AVAILABLE NOT AVAILABLE NOT AVAILABLE
(74-98-6)
N-BUTYL 18.00, PIMEPHALES 32.00, ARTEMIA SALINA 674.70 (72 HR),
ACETATE - PROMELAS SCENEDESMUS
(123-86-4) SUBSPICATUS
BUTANE - 6.00, FISH (PISCIS) NOT AVAILABLE NOT AVAILABLE
(106-97-8)
PROPANE, NOT AVAILABLE NOT AVAILABLE NOT AVAILABLE
2-METHYL- -
(75-28-5)
5-METHYL-2- 159.00, PIMEPHALES 560.00, DAPHNIA MAGNA 920.00 (72 HR),
HEXANONE - PROMELAS CHLOROCOCCALES
(110-12-3)
BUTAN-1-OL - 1,376.00, 1,328.00, DAPHNIA 500.00 (96 HR),
(71-36-3) PIMEPHALES PROMELAS MAGNA SCENEDESMUS
SUBSPICATUS
PENTAN-2-ONE 1,240.00, NOT AVAILABLE 0.00 (96 HR),
- (107-87-9) PIMEPHALES PROMELAS
ISO-BUTYL 101.00, LEUCISCUS 250.00, DAPHNIA MAGNA 600.00 (24 HR),
ACETATE. - IDUS CHLOROCOCCALES
(110-19-0)
HEPTAN-2-ONE 131.00, PIMEPHALES NOT AVAILABLE NOT AVAILABLE
- (110-43-0) PROMELAS
4-HYDROXY-4- 420.00, LEPOMIS 9,000.00, DAPHNIA NOT AVAILABLE
METHLYPENTAN- MACROCHIRUS MAGNA
2-ONE -
(123-42-2)
12.2. PERSISTENCE AND DEGRADABILITY:
THERE IS NO DATA AVAILABLE ON THE PREPARATION ITSELF.
12.3. BIOACCUMULATIVE POTENTIAL: NOT MEASURED
12.4. MOBILITY IN SOIL: NO DATA AVAILABLE.
12.5. RESULTS OF PBT AND VPVB ASSESSMENT:
THIS PRODUCT CONTAINS NO PBT/VPVB CHEMICALS.
12.6. OTHER ADVERSE EFFECTS: NO DATA AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
13.1. WASTE TREATMENT METHODS:
DO NOT ALLOW INTO DRAINS OR WATER COURSES. WASTES AND EMPTIED CONTAINERS
SHOULD BE DISPOSED OF IN ACCORDANCE WITH REGULATIONS MADE UNDER THE CONTROL
OF POLLUTION ACT AND THE ENVIRONMENTAL PROTECTION ACT. USING INFORMATION
PROVIDED IN THIS DATA SHEET ADVICE SHOULD BE OBTAINED FROM THE WASTE
REGULATION AUTHORITY, WHETHER THE SPECIAL WASTE REGULATIONS APPLY.
| 14. TRANSPORT INFORMATION | |
DOT (DOMESTIC IMO / IMDG (OCEAN ICAO/IATA
SURFACE TRANSPORTATION)
TRANSPORTATION)
14.1. UN NUMBER UN1950 UN1950 UN1950
14.2. UN PROPER UN1950, AEROSOLS, AEROSOLS, LIMITED AEROSOLS, LIMITED
SHIPPING NAME LIMITED QUANTITY, QUANTITY QUANTITY
2.1,
14.3. TRANSPORT DOT HAZARD CLASS: IMDG: 2.1 AIR CLASS: 2.1
HAZARD CLASS(ES) 2.1
14.4. PACKING NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE
GROUP
14.5. ENVIRONMENTAL HAZARDS:
IMDG:
MARINE POLLUTANT: NO
14.6. SPECIAL PRECAUTIONS FOR USER: NO FURTHER INFORMATION
14.7. TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL73/78 AND THE IBC
CODE: NOT APPLICABLE
| 15. REGULATORY INFORMATION | |
REGULATORY OVERVIEW:
THE REGULATORY DATA IN SECTION 15 IS NOT INTENDED TO BE ALL-INCLUSIVE, ONLY
SELECTED REGULATIONS ARE REPRESENTED. ALL INGREDIENTS OF THIS PRODUCT ARE
LISTED ON THE TSCA (TOXIC SUBSTANCE CONTROL ACT) INVENTORY OR ARE NOT
REQUIRED TO BE LISTED ON THE TSCA INVENTORY.
WHMIS CLASSIFICATION: D2B
US EPA TIER II HAZARDS:
FIRE: NO
REACTIVE: NO
SUDDEN RELEASE OF PRESSURE: YES
IMMEDIATE (ACUTE): YES
DELAYED (CHRONIC): NO
EPCRA 311/312 CHEMICALS AND RQS (LBS):
2-PROPANONE: (5,000.00)
BUTAN-1-OL: (5,000.00)
ISO-BUTYL ACETATE.: (5,000.00)
N-BUTYL ACETATE: (5,000.00)
EPCRA 302 EXTREMELY HAZARDOUS: (NO PRODUCT INGREDIENTS LISTED)
EPCRA 313 TOXIC CHEMICALS: BUTAN-1-OL
PROPOSITION 65 - CARCINOGENS (>0.0%): (NO PRODUCT INGREDIENTS LISTED)
PROPOSITION 65 - DEVELOPMENTAL TOXINS (>0.0%):
(NO PRODUCT INGREDIENTS LISTED)
PROPOSITION 65 - FEMALE REPRO TOXINS (>0.0%):
(NO PRODUCT INGREDIENTS LISTED)
PROPOSITION 65 - MALE REPRO TOXINS (>0.0%): (NO PRODUCT INGREDIENTS LISTED)
N.J. RTK SUBSTANCES (>1%):
4-HYDROXY-4-METHLYPENTAN-2-ONE
5-METHYL-2-HEXANONE
2-PROPANONE
BUTAN-1-OL
BUTANE
HEPTAN-2-ONE
ISO-BUTYL ACETATE.
N-BUTYL ACETATE
PENTAN-2-ONE
PROPANE
PROPANE, 2-METHYL-
PENN RTK SUBSTANCES (>1%):
4-HYDROXY-4-METHLYPENTAN-2-ONE
5-METHYL-2-HEXANONE
2-PROPANONE
BUTAN-1-OL
BUTANE
HEPTAN-2-ONE
ISO-BUTYL ACETATE.
N-BUTYL ACETATE
PENTAN-2-ONE
PROPANE
PROPANE, 2-METHYL-
| 16. OTHER INFORMATION | |
THE INFORMATION AND RECOMMENDATIONS CONTAINED HEREIN ARE BASED UPON DATA
BELIEVED TO BE CORRECT. HOWEVER, NO GUARANTEE OR WARRANTY OF ANY KIND,
EXPRESSED OR IMPLIED, IS MADE WITH RESPECT TO THE INFORMATION CONTAINED
HEREIN. WE ACCEPT NO RESPONSIBILITY AND DISCLAIM ALL LIABILITY FOR ANY
HARMFUL EFFECTS WHICH MAY BE CAUSED BY EXPOSURE TO OUR PRODUCTS.
CUSTOMERS/USERS OF THIS PRODUCT MUST COMPLY WITH ALL APPLICABLE HEALTH
AND SAFETY LAWS, REGULATIONS, AND ORDERS.
THE FULL TEXT OF THE PHRASES APPEARING IN SECTION 3 IS:
H220: EXTREMELY FLAMMABLE GAS.
H225: HIGHLY FLAMMABLE LIQUID AND VAPOR.
H226: FLAMMABLE LIQUID AND VAPOR.
H302: HARMFUL IF SWALLOWED.
H315: CAUSES SKIN IRRITATION.
H318: CAUSES SERIOUS EYE DAMAGE.
H319: CAUSES SERIOUS EYE IRRITATION.
H332: HARMFUL IF INHALED.
H335: MAY CAUSE RESPIRATORY IRRITATION.
H336: MAY CAUSE DROWSINESS AND DIZZINESS.
THIS IS THE FIRST VERSION IN THE GHS SDS FORMAT. LISTINGS OF CHANGES FROM
PREVIOUS VERSIONS IN OTHER FORMATS ARE NOT APPLICABLE.
IMPORTANT NOTE:
THIS INFORMATION IS FURNISHED WITHOUT WARRANTY, EXPRESSED OR IMPLIED, AS TO
ACCURACY OR COMPLETENESS. THE INFORMATION IS OBTAINED FROM VARIOUS SOURCES
INCLUDING THE MANUFACTURER AND OTHER THIRD PARTY SOURCES. THE INFORMATION
MAY NOT BE VALID UNDER ALL CONDITIONS NOR IF THIS MATERIAL IS USED IN
COMBINATION WITH OTHER MATERIALS OR ANY PROCESS. FINAL DETERMINATION OF
SUITABILITY OF ANY MATERIAL IS THE SOLE RESPONSIBILITY OF THE USER.