| Common Name: | HERCULES FOR HANDS |
| Manufacturer: | HCC HOLDINGS |
| SDS Revision Date: | 1/1/2014 |
| SDS Format: | GHS-US |
| Item Number(s): | 5NRX3 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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HERCULES(R*)
MATERIAL NAME: HERCULES FOR HANDS
| SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION |  |
MSDS #: 304
PART NUMBERS: 45333, 45333T, 453339T, 45337
INTENDED USE: HAND WIPE
MANUFACTURER INFORMATION:
HCC HOLDINGS
AN OATEY AFFILIATE
4700 WEST 160TH STREET
CLEVELAND, OH 44135
PHONE: 216-267-7100
FOR EMERGENCY FIRST AID CALL: 1-877-740-5015.
FOR CHEMICAL TRANSPORTATION EMERGENCIES ONLY, CALL CHEMTREC AT:
1-800-424-9300.
OUTSIDE THE U.S.: 1-703-527-3887.
| SECTION 2 - HAZARDS IDENTIFICATION | |
GHS CLASSIFICATION:
SPECIFIC TARGET ORGAN TOXICITY SINGLE EXPOSURE - CATEGORY 3
GHS LABEL ELEMENTS:
SYMBOL(S): EXCLAMATION MARK
SIGNAL WORD: WARNING
HAZARD STATEMENTS: MAY CAUSE RESPIRATORY IRRITATION.
PRECAUTIONARY STATEMENTS:
PREVENTION: AVOID BREATHING FUME/GAS/MIST/VAPORS.
RESPONSE:
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
| SECTION 3 - COMPOSITION / INFORMATION ON INGREDIENTS | |
CAS # COMPONENT PERCENT
7732-18-5 WATER 50-80
1119-40-0 DIMETHYL GLUTARATE 7-13
627-93-0 DIMETHYL ADIPATE
106-65-0 DIMETHYL SUCCINATE
57-55-6 1,2-PROPYLENE GLYCOL 1-5
5989-27-5 D-LIMONENE 1-5
| SECTION 4 - FIRST AID MEASURES | |
FIRST AID: EYES
FLUSH VICTIM'S EYES WITH LARGE QUANTITIES OF WATER, HOLDING THE EYELIDS
APART. GET MEDICAL ATTENTION IF IRRITATION PERSISTS.
FIRST AID: SKIN
NO FIRST AID IS REQUIRED. IF IRRITATION DEVELOPS AFTER USE, DISCONTINUE USE
AND CONSULT A PHYSICIAN.
FIRST AID: INGESTION
DO NOT INDUCE VOMITING. GET IMMEDIATE MEDICAL ATTENTION.
FIRST AID: INHALATION
NO ADVERSE EFFECTS ARE EXPECTED, HOWEVER, IF IRRITATION OR OTHER SYMPTOMS
DEVELOP, REMOVE TO FRESH AIR. SEEK MEDICAL ATTENTION IF SYMPTOMS PERSIST.
| SECTION 5 - FIRE FIGHTING MEASURES | |
GENERAL FIRE HAZARDS:
SEE SECTION 9 FOR FLAMMABILITY PROPERTIES.
NOT CLASSIFIED AS FLAMMABLE OR COMBUSTIBLE BUT WILL BURN UNDER FIRE
CONDITIONS.
HAZARDOUS COMBUSTION PRODUCTS:
BURNING MAY PRODUCE CARBON MONOXIDE, CARBON DIOXIDE AND UNIDENTIFIED
HYDROCARBONS.
EXTINGUISHING MEDIA:
USE WATER FOG OR SPRAY, CARBON DIOXIDE, DRY CHEMICAL OR FOAM.
UNSUITABLE EXTINGUISHING MEDIA: NONE.
FIRE FIGHTING EQUIPMENT/INSTRUCTIONS:
FIREFIGHTERS SHOULD WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING
APPARATUS AND FULL PROTECTIVE CLOTHING FOR FIRES IN AREAS WHERE CHEMICALS
ARE USED OR STORED.
| SECTION 6 - ACCIDENTAL RELEASE MEASURES | |
RECOVERY AND NEUTRALIZATION: STOP LEAK IF IT CAN BE DONE WITHOUT RISK.
MATERIALS AND METHODS FOR CLEAN-UP:
PICK UP FOR RE-USE OR DISPOSAL. FLUSH SPILL AREA WITH WATER.
EMERGENCY MEASURES: ISOLATE AREA. KEEP UNNECESSARY PERSONNEL AWAY.
PERSONAL PRECAUTIONS AND PROTECTIVE EQUIPMENT: NONE REQUIRED.
ENVIRONMENTAL PRECAUTIONS: NONE
PREVENTION OF SECONDARY HAZARDS: NONE
| SECTION 7 - HANDLING AND STORAGE | |
HANDLING PROCEDURES:
AVOID CONTACT WITH EYES. KEEP CONTAINERS CLOSED WHEN NOT IN USE.
STORAGE PROCEDURES: STORE IN A COOL, DRY AREA. KEEP FROM FREEZING.
INCOMPATIBILITIES: STRONG OXIDIZING AGENTS, ACIDS AND BASES.
| SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION | |
COMPONENT EXPOSURE LIMITS:
ACGIH, OSHA, AND NIOSH HAVE NOT DEVELOPED EXPOSURE LIMITS FOR ANY OF THIS
PRODUCT'S COMPONENTS.
ENGINEERING MEASURES: NONE REQUIRED FOR NORMAL PRODUCT USE CONDITIONS.
PERSONAL PROTECTIVE EQUIPMENT: RESPIRATORY
NONE REQUIRED FOR NORMAL PRODUCT USE CONDITIONS.
PERSONAL PROTECTIVE EQUIPMENT: HANDS
NONE REQUIRED FOR NORMAL PRODUCT USE CONDITIONS. THIS PRODUCT IS INTENDED
FOR USE ON THE SKIN.
PERSONAL PROTECTIVE EQUIPMENT: EYES
NONE REQUIRED FOR NORMAL PRODUCT USE CONDITIONS. SAFETY GLASSES RECOMMENDED
WHERE SPLASHING IF POSSIBLE.
PERSONAL PROTECTIVE EQUIPMENT: SKIN AND BODY
NO ADDITIONAL PROTECTIVE EQUIPMENT NEEDED.
| SECTION 9 - PHYSICAL & CHEMICAL PROPERTIES | |
APPEARANCE: TOWELETTES SATURATED WITH CLEAR, COLORLESS LIQUID.
ODOR: PLEASANT
PHYSICAL STATE: SOLID SATURATED WITH LIQUID
PH: ND
VAPOR PRESSURE: 1 MMHg @ 20 DEG. C
VAPOR DENSITY: ND
BOILING POINT: 100-230 DEG. C
MELTING POINT: ND
SOLUBILITY (H2O): 100%
SPECIFIC GRAVITY: 1.01
EVAPORATION RATE: 0.01 (BUAC=1)
VOC: ND
OCTANOL/H2O COEFF.: ND
FLASH POINT: 235 DEG. F (113 DEG. C)
FLASH POINT METHOD: ND
UPPER FLAMMABILITY LIMIT (UFL): 8.0
LOWER FLAMMABILITY LIMIT (LFL): 0.7
BURNING RATE: ND
AUTO IGNITION: ND
| SECTION 10 - CHEMICAL STABILITY & REACTIVITY INFORMATION | |
CHEMICAL STABILITY: THIS IS A STABLE MATERIAL.
HAZARDOUS REACTION POTENTIAL: WILL NOT OCCUR.
CONDITIONS TO AVOID: NONE.
INCOMPATIBLE PRODUCTS: STRONG OXIDIZING AGENTS, ACIDS AND BASES.
HAZARDOUS DECOMPOSITION PRODUCTS:
BURNING MAY PRODUCE CARBON MONOXIDE, CARBON DIOXIDE AND UNIDENTIFIED
HYDROCARBONS.
| SECTION 11 - TOXICOLOGICAL INFORMATION | |
ACUTE TOXICITY:
COMPONENT ANALYSIS - LD50/LC50:
DIMETHYL GLUTARATE (1119-40-0):
INHALATION LC50 RAT: >5.6 MG/L 4 H
ORAL LD50 RAT: 8191 MG/KG
DIMETHYL ADIPATE (627-93-0):
ORAL LD50 RAT: 1920 MG/KG
DIMETHYL SUCCINATE (106-65-0):
ORAL LD50 RAT: >5000 MG/KG
DERMAL LD50 RABBIT: >5000 MG/KG
1,2-PROPYLENE GLYCOL (57-55-6):
ORAL LD50 RAT: 20000 MG/KG
DERMAL LD50 RABBIT: 20800 MG/KG
D-LIMONENE (5989-27-5):
ORAL LD50 RAT: 4400 MG/KG
DERMAL LD50 RABBIT: >2000 MG/KG
POTENTIAL HEALTH EFFECTS: SKIN CORROSION PROPERTY/STIMULATIVENESS
NO SIGNIFICANT IRRITATION IS EXPECTED. NOT A SKIN IRRITANT IN ANIMAL TESTS.
POTENTIAL HEALTH EFFECTS: EYE CRITICAL DAMAGE/ STIMULATIVENESS
MAY CAUSE MILD IRRITATION OR DISCOMFORT. NOT AN EYE IRRITANT IN ANIMAL
TESTS.
POTENTIAL HEALTH EFFECTS: INGESTION
SWALLOWING MAY CAUSE NAUSEA, VOMITING AND DIARRHEA.
POTENTIAL HEALTH EFFECTS: INHALATION
INHALATION OF VAPORS MAY CAUSE IRRITATION OF THE NOSE, THROAT AND UPPER
RESPIRATORY TRACT. HIGH CONCENTRATIONS MAY CAUSE BLURRY VISION.
RESPIRATORY ORGANS SENSITIZATION/SKIN SENSITIZATION:
THIS PRODUCT IS NOT REPORTED TO HAVE ANY SKIN SENSITIZATION EFFECTS.
GENERATIVE CELL MUTAGENICITY:
THIS PRODUCT IS NOT REPORTED TO HAVE ANY MUTAGENIC EFFECTS
CARCINOGENICITY:
A: GENERAL PRODUCT INFORMATION
THIS PRODUCT IS NOT REPORTED TO HAVE ANY CARCINOGENIC EFFECTS
B: COMPONENT CARCINOGENICITY
D-LIMONENE (5989-27-5):
IARC:
MONOGRAPH 73 [1999] (OVERALL EVALUATION DOWNGRADED FROM 2B TO 3 WITH
SUPPORTING EVIDENCE FROM OTHER RELEVANT DATA) (GROUP 3 (NOT CLASSIFIABLE))
REPRODUCTIVE TOXICITY:
THIS PRODUCT IS NOT REPORTED TO HAVE ANY REPRODUCTIVE TOXICITY EFFECTS
SPECIFIED TARGET ORGAN GENERAL TOXICITY: SINGLE EXPOSURE
MAY CAUSE RESPIRATORY IRRITATION.
SPECIFIED TARGET ORGAN GENERAL TOXICITY: REPEATED EXPOSURE
THIS PRODUCT IS NOT REPORTED TO HAVE ANY SPECIFIC TARGET ORGAN TOXICITY
REPEAT EXPOSURE EFFECTS.
ASPIRATION RESPIRATORY ORGANS HAZARD: NOT AN ASPIRATION HAZARD.
| SECTION 12 - ECOLOGICAL INFORMATION | |
ECOTOXICITY:
A: GENERAL PRODUCT INFORMATION
THIS PRODUCT IS NOT EXPECTED TO BE TOXIC TO AQUATIC ORGANISMS.
B: COMPONENT ANALYSIS - ECOTOXICITY - AQUATIC TOXICITY
DIMETHYL GLUTARATE (1119-40-0):
TEST & SPECIES CONDITIONS
96 HR LC50 PIMEPHALES PROMELAS: 19.6-26.2 MG/L [STATIC]
48 HR EC50 DAPHNIA MAGNA: 122.1 - 163.5 MG/L
DIMETHYL SUCCINATE (106-65-0):
TEST & SPECIES CONDITIONS
96 HR LC50 BRACHYDANIO RERIO: 50-100 MG/L [STATIC]
1,2-PROPYLENE GLYCOL (57-55-6):
TEST & SPECIES CONDITIONS
96 HR LC50 ONCORHYNCHUS MYKISS: 51600 MG/L [STATIC]
96 HR LC50 ONCORHYNCHUS MYKISS: 41 - 47 ML/L [STATIC]
96 HR LC50 PIMEPHALES PROMELAS: 51400 MG/L [STATIC]
96 HR LC50 PIMEPHALES PROMELAS: 710 MG/L
96 HR EC50 PSEUDOKIRCHNERIELLA SUBCAPITATA: 19000 MG/L
24 HR EC50 DAPHNIA MAGNA: >10000 MG/L
48 HR EC50 DAPHNIA MAGNA: >1000 MG/L [STATIC]
D-LIMONENE (5989-27-5):
TEST & SPECIES CONDITIONS
96 HR LC50 PIMEPHALES PROMELAS: 0.619-0.796 MG/L [FLOW-THROUGH]
96 HR LC50 ONCORHYNCHUS MYKISS: 35 MG/L
PERSISTENCE/DEGRADABILITY: NO INFORMATION AVAILABLE FOR THE PRODUCT.
BIOACCUMULATION: NO INFORMATION AVAILABLE FOR THE PRODUCT.
MOBILITY IN SOIL: NO INFORMATION AVAILABLE FOR THE PRODUCT.
| SECTION 13 - DISPOSAL CONSIDERATIONS | |
WASTE DISPOSAL INSTRUCTIONS:
SEE SECTION 7 FOR HANDLING PROCEDURES. SEE SECTION 8 FOR PERSONAL
PROTECTIVE EQUIPMENT RECOMMENDATIONS.
DISPOSAL OF CONTAMINATED CONTAINERS OR PACKAGING:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
| SECTION 14 - TRANSPORTATION INFORMATION | |
DOT/IMDG INFORMATION:
SHIPPING NAME: NOT REGULATED
| SECTION 15 - REGULATORY INFORMATION | |
REGULATORY INFORMATION:
US FEDERAL REGULATIONS:
COMPONENT ANALYSIS:
NONE OF THIS PRODUCTS COMPONENTS ARE LISTED UNDER SARA SECTION 302 (40 CFR
355 APPENDIX A), SARA SECTION 313 (40 CFR 372.65), OR CERCLA (40 CFR
302.4).
STATE REGULATIONS:
COMPONENT ANALYSIS - STATE:
THE FOLLOWING COMPONENTS APPEAR ON ONE OR MORE OF THE FOLLOWING STATE
HAZARDOUS SUBSTANCES LISTS:
COMPONENT CAS CA MA MN NJ PA RI
1,2-PROPYLENE GLYCOL 57-55-6 NO NO YES YES YES NO
COMPONENT ANALYSIS - WHMIS IDL:
THE FOLLOWING COMPONENTS ARE IDENTIFIED UNDER THE CANADIAN HAZARDOUS
PRODUCTS ACT INGREDIENT DISCLOSURE LIST:
COMPONENT CAS # MINIMUM CONCENTRATION
1,2-PROPYLENE GLYCOL 57-55-6 1%
D-LIMONENE 5989-27-5 1%
ADDITIONAL REGULATORY INFORMATION:
COMPONENT ANALYSIS - INVENTORY:
COMPONENT CAS # TSCA CAN EEC
DIMETHYL GLUTARATE 1119-40-0 YES DSL EINECS
DIMETHYL ADIPATE 627-93-0 YES DSL EINECS
DIMETHYL SUCCINATE 106-65-0 YES DSL EINECS
1,2-PROPYLENE GLYCOL 57-55-6 YES DSL EINECS
D-LIMONENE 5989-27-5 YES DSL EINECS
| SECTION 16 - OTHER INFORMATION | |
KEY/LEGEND:
EPA = ENVIRONMENTAL PROTECTION AGENCY
TSCA = TOXIC SUBSTANCE CONTROL ACT
ACGIH = AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
IARC = INTERNATIONAL AGENCY FOR RESEARCH ON CANCER
NIOSH = NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH
NTP = NATIONAL TOXICOLOGY PROGRAM
OSHA = OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION.
NJTSR = NEW JERSEY TRADE SECRET REGISTRY
LITERATURE REFERENCES: NONE
OTHER INFORMATION:
NFPA RATING:
HEALTH 0
FIRE 1
REACTIVITY 0
HMIS RATING:
HEALTH 0
FIRE 1
REACTIVITY 0
DISCLAIMER:
THE INFORMATION HEREIN HAS BEEN COMPILED FROM SOURCES BELIEVED TO BE
RELIABLE, UP-TO-DATE, AND IS ACCURATE TO THE BEST OF OUR KNOWLEDGE.
HOWEVER, WE CANNOT GIVE ANY GUARANTEES REGARDING INFORMATION FROM OTHER
SOURCES, AND EXPRESSLY DO NOT MAKE WARRANTIES, NOR ASSUME ANY LIABILITY
FOR ITS USE.
ISSUE DATE: 01/01/2014
REVISION: 1.0000
PRINT DATE: 4/25/2014