| Common Name: | KILLS BEDBUGS, FLEAS, BROWN DOG TICKS AND OTHER INSECTS LISTED ON THIS LABEL |
| Manufacturer: | J.T. EATON |
| SDS Revision Date: | 12/15/2014 |
| SDS Format: | GHS-US |
| Item Number(s): | 5PTR4 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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CONFORMS TO HAZCOM 2012/UNITED STATES
JT EATON(TM)
FAMILY OWNED AND OPERATED
SAFETY DATA SHEET
JT EATON(TM) KILLS BEDBUGS, FLEAS, BROWN DOG TICKS AND OTHER INSECTS LISTED
ON THIS LABEL
| SECTION 1. IDENTIFICATION |  |
GHS PRODUCT IDENTIFIER:
JT EATON(TM) KILLS BEDBUGS, FLEAS, BROWN DOG TICKS AND OTHER INSECTS
LISTED ON THIS LABEL
EPA REGISTRATION NO.: 45385-28-56
EPA LABEL CONTENT:
SEE ATTACHED EPA LABEL CONTENT IN THIS PDF (CLICK ICON ON LEFT END SIDE OF
THIS PAGE).
PRODUCT CODE: 204-O, 204-O1G, 204-O1GP, 204-05G
OTHER MEANS OF IDENTIFICATION: PYRETHRINS
PRODUCT TYPE: LIQUID.
IDENTIFIED USES: INSECTICIDE SPRAY.
SUPPLIER'S DETAILS:
J.T. EATON & CO., INC.
1393 EAST HIGHLAND ROAD
TWINSBURG, OH 44087
U.S.A.
TEL: 330-425-7801
TOLL FREE: 800-321-3421
WEB SITE: WWW.JTEATON.COM
EMERGENCY TELEPHONE NUMBER (WITH HOURS OF OPERATION):
1-800-664-9042 OR N.P.I.C. 1-800-858-7378 8:30 AM TO 5:00 PM EST
| SECTION 2. HAZARDS IDENTIFICATION | |
OSHA/HCS STATUS:
THIS MATERIAL IS CONSIDERED HAZARDOUS BY THE OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200).
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
ASPIRATION HAZARD: CATEGORY 1
AQUATIC HAZARD (ACUTE): CATEGORY 1
AQUATIC HAZARD (LONG-TERM): CATEGORY 3
GHS LABEL ELEMENTS:
HAZARD PICTOGRAMS:
HEALTH HAZARD
ENVIRONMENT
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
VERY TOXIC TO AQUATIC LIFE.
HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
PRECAUTIONARY STATEMENTS:
PREVENTION: AVOID RELEASE TO THE ENVIRONMENT.
RESPONSE: COLLECT SPILLAGE.
IF SWALLOWED:
IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN. DO NOT INDUCE VOMITING.
STORAGE: STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS AND CONTAINER IN ACCORDANCE WITH ALL LOCAL, REGIONAL,
NATIONAL AND INTERNATIONAL REGULATIONS.
HAZARDS NOT OTHERWISE CLASSIFIED: NONE KNOWN.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE/MIXTURE: MIXTURE
OTHER MEANS OF IDENTIFICATION: PYRETHRINS
CAS NUMBER/OTHER IDENTIFIERS:
CAS NUMBER: NOT APPLICABLE.
PRODUCT CODE: 204-O, 204-O1G, 204-O1GP, 204-05G
INGREDIENT NAME % CAS NUMBER
DISTILLATES (PETROLEUM), HYDROTREATED LIGHT 60 - 100 64742-47-8
2-(2-BUTOXYETHOXY)ETHYL 6-PROPYLPIPERONYL ETHER 1 - 5 51-03-6
PYRETHRINS AND PYRETHROIDS 0.1 - 1 8003-34-7
ANY CONCENTRATION SHOWN AS A RANGE IS TO PROTECT CONFIDENTIALITY OR IS DUE
TO BATCH VARIATION.
THERE ARE NO ADDITIONAL INGREDIENTS PRESENT WHICH, WITHIN THE CURRENT
KNOWLEDGE OF THE SUPPLIER AND IN THE CONCENTRATIONS APPLICABLE, ARE
CLASSIFIED AS HAZARDOUS TO HEALTH OR THE ENVIRONMENT AND HENCE REQUIRE
REPORTING IN THIS SECTION.
OCCUPATIONAL EXPOSURE LIMITS, IF AVAILABLE, ARE LISTED IN SECTION 8.
| SECTION 4. FIRST AID MEASURES | |
DESCRIPTION OF NECESSARY FIRST AID MEASURES:
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER, OCCASIONALLY LIFTING THE UPPER
AND LOWER EYELIDS. CHECK FOR AND REMOVE ANY CONTACT LENSES. CONTINUE TO
RINSE FOR AT LEAST 20 MINUTES. GET MEDICAL ATTENTION IF IRRITATION OCCURS.
INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. IF NOT BREATHING, IF BREATHING IS IRREGULAR OR IF RESPIRATORY
ARREST OCCURS, PROVIDE ARTIFICIAL RESPIRATION OR OXYGEN BY TRAINED
PERSONNEL. IT MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE
MOUTH-TO-MOUTH RESUSCITATION. GET MEDICAL ATTENTION IF ADVERSE HEALTH
EFFECTS PERSIST OR ARE SEVERE. IF UNCONSCIOUS, PLACE IN RECOVERY POSITION
AND GET MEDICAL ATTENTION IMMEDIATELY. MAINTAIN AN OPEN AIRWAY.
SKIN CONTACT:
FLUSH CONTAMINATED SKIN WITH PLENTY OF WATER. GET MEDICAL ATTENTION IF
SYMPTOMS OCCUR. WASH CLOTHING BEFORE REUSE. CLEAN SHOES THOROUGHLY BEFORE
REUSE.
INGESTION:
GET MEDICAL ATTENTION IMMEDIATELY. CALL A POISON CENTER OR PHYSICIAN. WASH
OUT MOUTH WITH WATER. REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A
POSITION COMFORTABLE FOR BREATHING. IF MATERIAL HAS BEEN SWALLOWED AND THE
EXPOSED PERSON IS CONSCIOUS, GIVE SMALL QUANTITIES OF WATER TO DRINK. STOP
IF THE EXPOSED PERSON FEELS SICK AS VOMITING MAY BE DANGEROUS. ASPIRATION
HAZARD IF SWALLOWED. CAN ENTER LUNGS AND CAUSE DAMAGE. DO NOT INDUCE
VOMITING. IF VOMITING OCCURS, THE HEAD SHOULD BE KEPT LOW SO THAT VOMIT
DOES NOT ENTER THE LUNGS. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON. IF UNCONSCIOUS, PLACE IN RECOVERY POSITION AND GET MEDICAL
ATTENTION IMMEDIATELY. MAINTAIN AN OPEN AIRWAY.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
INHALATION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SKIN CONTACT: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
INGESTION: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
OVER-EXPOSURE SIGNS/SYMPTOMS:
EYE CONTACT: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
INHALATION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SKIN CONTACT: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
INGESTION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING: NAUSEA OR VOMITING
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED,
IF NECESSARY:
NOTES TO PHYSICIAN:
TREAT SYMPTOMATICALLY. CONTACT POISON TREATMENT SPECIALIST IMMEDIATELY IF
LARGE QUANTITIES HAVE BEEN INGESTED OR INHALED.
SPECIFIC TREATMENTS: NO SPECIFIC TREATMENT.
PROTECTION OF FIRST-AIDERS:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. IT MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE
MOUTH-TO-MOUTH RESUSCITATION.
SEE TOXICOLOGICAL INFORMATION (SECTION 11)
| SECTION 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE AN EXTINGUISHING AGENT SUITABLE FOR THE SURROUNDING FIRE.
UNSUITABLE EXTINGUISHING MEDIA: NONE KNOWN.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
COMBUSTIBLE LIQUID. THIS MATERIAL IS VERY TOXIC TO AQUATIC LIFE. THIS
MATERIAL IS HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS. FIRE WATER
CONTAMINATED WITH THIS MATERIAL MUST BE CONTAINED AND PREVENTED FROM BEING
DISCHARGED TO ANY WATERWAY, SEWER OR DRAIN.
HAZARDOUS THERMAL DECOMPOSITION PRODUCTS:
DECOMPOSITION PRODUCTS MAY INCLUDE THE FOLLOWING MATERIALS:
CARBON DIOXIDE
CARBON MONOXIDE
SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
NO SPECIAL MEASURES ARE REQUIRED.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
FIRE-FIGHTERS SHOULD WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND
SELF-CONTAINED BREATHING APPARATUS (SCBA) WITH A FULL FACE-PIECE OPERATED
IN POSITIVE PRESSURE MODE.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
FOR NON-EMERGENCY PERSONNEL:
SHUT OFF ALL IGNITION SOURCES. NO FLARES, SMOKING OR FLAMES IN HAZARD AREA.
AVOID BREATHING VAPOR OR MIST. PROVIDE ADEQUATE VENTILATION. WEAR
APPROPRIATE RESPIRATOR WHEN VENTILATION IS INADEQUATE. PUT ON APPROPRIATE
PERSONAL PROTECTIVE EQUIPMENT.
FOR EMERGENCY RESPONDERS:
IF SPECIALIZED CLOTHING IS REQUIRED TO DEAL WITH THE SPILLAGE, TAKE NOTE
OF ANY INFORMATION IN SECTION 8 ON SUITABLE AND UNSUITABLE MATERIALS.
SEE ALSO THE INFORMATION IN "FOR NON-EMERGENCY PERSONNEL".
ENVIRONMENTAL PRECAUTIONS:
AVOID DISPERSAL OF SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL,
WATERWAYS, DRAINS AND SEWERS. INFORM THE RELEVANT AUTHORITIES IF THE
PRODUCT HAS CAUSED ENVIRONMENTAL POLLUTION (SEWERS, WATERWAYS, SOIL OR
AIR). WATER POLLUTING MATERIAL. MAY BE HARMFUL TO THE ENVIRONMENT IF
RELEASED IN LARGE QUANTITIES. COLLECT SPILLAGE.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. APPROACH
RELEASE FROM UPWIND. PREVENT ENTRY INTO SEWERS, WATER COURSES, BASEMENTS OR
CONFINED AREAS. WASH SPILLAGES INTO AN EFFLUENT TREATMENT PLANT OR PROCEED
AS FOLLOWS. CONTAIN AND COLLECT SPILLAGE WITH NON-COMBUSTIBLE, ABSORBENT
MATERIAL E.G. SAND, EARTH, VERMICULITE OR DIATOMACEOUS EARTH AND PLACE IN
CONTAINER FOR DISPOSAL ACCORDING TO LOCAL REGULATIONS (SEE SECTION 13).
DISPOSE OF VIA A LICENSED WASTE DISPOSAL CONTRACTOR. CONTAMINATED ABSORBENT
MATERIAL MAY POSE THE SAME HAZARD AS THE SPILLED PRODUCT.
NOTE:
SEE SECTION 1 FOR EMERGENCY CONTACT INFORMATION AND SECTION 13 FOR WASTE
DISPOSAL.
| SECTION 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
PROTECTIVE MEASURES:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8). DO NOT
SWALLOW. AVOID CONTACT WITH EYES, SKIN AND CLOTHING. AVOID BREATHING VAPOR
OR MIST. AVOID RELEASE TO THE ENVIRONMENT. KEEP IN THE ORIGINAL CONTAINER
OR AN APPROVED ALTERNATIVE MADE FROM A COMPATIBLE MATERIAL, KEPT TIGHTLY
CLOSED WHEN NOT IN USE. EMPTY CONTAINERS RETAIN PRODUCT RESIDUE AND CAN BE
HAZARDOUS. DO NOT REUSE CONTAINER.
ADVICE ON GENERAL OCCUPATIONAL HYGIENE:
EATING, DRINKING AND SMOKING SHOULD BE PROHIBITED IN AREAS WHERE THIS
MATERIAL IS HANDLED, STORED AND PROCESSED. WORKERS SHOULD WASH HANDS AND
FACE BEFORE EATING, DRINKING AND SMOKING. SEE ALSO SECTION 8 FOR ADDITIONAL
INFORMATION ON HYGIENE MEASURES.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE IN ACCORDANCE WITH LOCAL REGULATIONS. STORE IN ORIGINAL CONTAINER
PROTECTED FROM DIRECT SUNLIGHT IN A DRY, COOL AND WELL-VENTILATED AREA,
AWAY FROM INCOMPATIBLE MATERIALS (SEE SECTION 10) AND FOOD AND DRINK. STORE
LOCKED UP. KEEP CONTAINER TIGHTLY CLOSED AND SEALED UNTIL READY FOR USE.
CONTAINERS THAT HAVE BEEN OPENED MUST BE CAREFULLY RESEALED AND KEPT
UPRIGHT TO PREVENT LEAKAGE. DO NOT STORE IN UNLABELED CONTAINERS. USE
APPROPRIATE CONTAINMENT TO AVOID ENVIRONMENTAL CONTAMINATION.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
INGREDIENT NAME EXPOSURE LIMITS
DISTILLATES OSHA PEL (UNITED STATES).
(PETROLEUM), TWA: 213 PPM
HYDROTREATED LIGHT TWA: 1200 MG/M3
ACGIH TLV (UNITED STATES, 6/2013).
ABSORBED THROUGH SKIN.
TWA: 200 MG/M3, (AS TOTAL HYDROCARBON VAPOR) 8 HOURS.
PYRETHRINS AND ACGIH TLV (UNITED STATES, 6/2013).
PYRETHROIDS TWA: 5 MG/M3 8 HOURS.
NIOSH REL (UNITED STATES, 4/2013).
TWA: 5 MG/M3 10 HOURS.
OSHA PEL (UNITED STATES, 2/2013).
TWA: 5 MG/M3 8 HOURS.
APPROPRIATE ENGINEERING CONTROLS:
GOOD GENERAL VENTILATION SHOULD BE SUFFICIENT TO CONTROL WORKER EXPOSURE TO
AIRBORNE CONTAMINANTS.
ENVIRONMENTAL EXPOSURE CONTROLS:
EMISSIONS FROM VENTILATION OR WORK PROCESS EQUIPMENT SHOULD BE CHECKED TO
ENSURE THEY COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION
LEGISLATION.
INDIVIDUAL PROTECTION MEASURES:
HYGIENE MEASURES:
WASH HANDS, FOREARMS AND FACE THOROUGHLY AFTER HANDLING CHEMICAL PRODUCTS,
BEFORE EATING, SMOKING AND USING THE LAVATORY AND AT THE END OF THE WORKING
PERIOD. ENSURE THAT EYEWASH STATIONS AND SAFETY SHOWERS ARE CLOSE TO THE
WORKSTATION LOCATION.
EYE/FACE PROTECTION:
SAFETY EYEWEAR COMPLYING WITH AN APPROVED STANDARD SHOULD BE USED WHEN A
RISK ASSESSMENT INDICATES THIS IS NECESSARY TO AVOID EXPOSURE TO LIQUID
SPLASHES, MISTS, GASES OR DUSTS. IF CONTACT IS POSSIBLE, THE FOLLOWING
PROTECTION SHOULD BE WORN, UNLESS THE ASSESSMENT INDICATES A HIGHER DEGREE
OF PROTECTION: SAFETY GLASSES WITH SIDE-SHIELDS.
SKIN PROTECTION:
HAND PROTECTION:
CHEMICAL-RESISTANT, IMPERVIOUS GLOVES COMPLYING WITH AN APPROVED STANDARD
SHOULD BE WORN AT ALL TIMES WHEN HANDLING CHEMICAL PRODUCTS IF A RISK
ASSESSMENT INDICATES THIS IS NECESSARY.
BODY PROTECTION:
PERSONAL PROTECTIVE EQUIPMENT FOR THE BODY SHOULD BE SELECTED BASED ON THE
TASK BEING PERFORMED AND THE RISKS INVOLVED AND SHOULD BE APPROVED BY A
SPECIALIST BEFORE HANDLING THIS PRODUCT.
OTHER SKIN PROTECTION:
APPROPRIATE FOOTWEAR AND ANY ADDITIONAL SKIN PROTECTION MEASURES SHOULD BE
SELECTED BASED ON THE TASK BEING PERFORMED AND THE RISKS INVOLVED AND
SHOULD BE APPROVED BY A SPECIALIST BEFORE HANDLING THIS PRODUCT.
RESPIRATORY PROTECTION:
USE A PROPERLY FITTED, AIR-PURIFYING OR SUPPLIED AIR RESPIRATOR COMPLYING
WITH AN APPROVED STANDARD IF A RISK ASSESSMENT INDICATES THIS IS NECESSARY.
RESPIRATOR SELECTION MUST BE BASED ON KNOWN OR ANTICIPATED EXPOSURE LEVELS,
THE HAZARDS OF THE PRODUCT AND THE SAFE WORKING LIMITS OF THE SELECTED
RESPIRATOR.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: LIQUID.
COLOR: YELLOW. [LIGHT]
ODOR: MINERAL SPIRITS.
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
MELTING POINT: NOT AVAILABLE.
BOILING POINT: NOT AVAILABLE.
FLASH POINT:
CLOSED CUP: >112.78 DEG. C (>235 DEG. F)
EVAPORATION RATE: NOT AVAILABLE.
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE.
LOWER AND UPPER EXPLOSIVE (FLAMMABLE) LIMITS: NOT AVAILABLE.
VAPOR PRESSURE: NOT AVAILABLE.
VAPOR DENSITY: NOT AVAILABLE.
RELATIVE DENSITY: 0.803
SOLUBILITY: NOT AVAILABLE.
PARTITION COEFFICIENT N-OCTANOL/WATER: NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY: NOT AVAILABLE.
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY:
NO SPECIFIC TEST DATA RELATED TO REACTIVITY AVAILABLE FOR THIS PRODUCT OR
ITS INGREDIENTS.
CHEMICAL STABILITY: THE PRODUCT IS STABLE.
POSSIBILITY OF HAZARDOUS REACTIONS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS REACTIONS WILL NOT
OCCUR.
CONDITIONS TO AVOID: NO SPECIFIC DATA.
INCOMPATIBLE MATERIALS:
REACTIVE OR INCOMPATIBLE WITH THE FOLLOWING MATERIALS: OXIDIZING MATERIALS.
HAZARDOUS DECOMPOSITION PRODUCTS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS DECOMPOSITION
PRODUCTS SHOULD NOT BE PRODUCED.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
PRODUCT/INGREDIENT NAME RESULT SPECIES DOSE EXPOSURE
PYRETHRINS AND PYRETHROIDS LD50 DERMAL RABBIT 300 MG/KG
LD50 DERMAL RAT 1350 MG/KG
LD50 ORAL RAT 200 MG/KG
IRRITATION/CORROSION: THERE IS NO DATA AVAILABLE.
SENSITIZATION: THERE IS NO DATA AVAILABLE.
CARCINOGENICITY: THERE IS NO DATA AVAILABLE.
CLASSIFICATION:
PRODUCT/INGREDIENT NAME OSHA IARC NTP
2-(2-BUTOXYETHOXY)ETHYL 3
6-PROPYLPIPERONYL ETHER
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE):
THERE IS NO DATA AVAILABLE.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE):
THERE IS NO DATA AVAILABLE.
ASPIRATION HAZARD:
NAME RESULT
DISTILLATES (PETROLEUM), HYDROTREATED ASPIRATION HAZARD - CATEGORY 1
LIGHT
INFORMATION ON THE LIKELY ROUTES OF EXPOSURE:
DERMAL CONTACT. EYE CONTACT. INHALATION.
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
INHALATION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SKIN CONTACT: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
INGESTION: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
EYE CONTACT: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
INHALATION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SKIN CONTACT: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
INGESTION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING: NAUSEA OR VOMITING
DELAYED AND IMMEDIATE EFFECTS AND ALSO CHRONIC EFFECTS FROM SHORT AND LONG
TERM EXPOSURE:
SHORT TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS:
NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
POTENTIAL DELAYED EFFECTS:
NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
LONG TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS:
NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
POTENTIAL DELAYED EFFECTS:
NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
POTENTIAL CHRONIC HEALTH EFFECTS:
GENERAL: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
CARCINOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
MUTAGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
TERATOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
DEVELOPMENTAL EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
FERTILITY EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
NUMERICAL MEASURES OF TOXICITY:
ACUTE TOXICITY ESTIMATES: THERE IS NO DATA AVAILABLE.
| SECTION 12. ECOLOGICAL INFORMATION | |
TOXICITY:
PRODUCT/INGREDIENT RESULT SPECIES EXPOSURE
NAME
DISTILLATES ACUTE LC50: FISH - LEPOMIS 4 DAYS
(PETROLEUM), 2200 (MICRO)G/L MACROCHIRUS
HYDROTREATED FRESH WATER
LIGHT
2-(2-BUTOXYETHOXY) ACUTE EC50: DAPHNIA - DAPHNIA MAGNA 48 HOURS
ETHYL 6-PROPYL- 0.51 PPM
PIPERONYL ETHER FRESH WATER
ACUTE LC50: CRUSTACEANS - 48 HOURS
330 (MICRO)G/L CERIODAPHNIA DUBIA -
FRESH WATER NEONATE
ACUTE LC50: FISH - ONCORHYNCHUS 96 HOURS
1860 PPB MYKISS
FRESH WATER
CHRONIC NOEC: DAPHNIA - DAPHNIA MAGNA 21 DAYS
30 PPB
MARINE WATER
CHRONIC NOEC: FISH - PIMEPHALES 35 DAYS
0.23 PPM PROMELAS
PYRETHRINS AND ACUTE EC50: DAPHNIA - DAPHNIA MAGNA 48 HOURS
PYRETHROIDS 11.6 PPB
FRESH WATER
ACUTE LC50: CRUSTACEANS - HOMARUS 48 HOURS
0.73 (MICRO)G/L AMERICANUS - LARVAE
MARINE WATER
ACUTE LC50: FISH - ONCORHYNCHUS 96 HOURS
3.2 PPB MYKISS
FRESH WATER
CHRONIC NOEC: DAPHNIA - DAPHNIA MAGNA 21 DAYS
0.86 PPB
MARINE WATER
CHRONIC NOEC: FISH - PIMEPHALES 35 DAYS
1.9 PPB PROMELAS
PERSISTENCE AND DEGRADABILITY: THERE IS NO DATA AVAILABLE.
BIOACCUMULATIVE POTENTIAL:
PRODUCT/INGREDIENT NAME LOGPOW BCF POTENTIAL
2-(2-BUTOXYETHOXY)ETHYL 4.8 91 TO 380 LOW
6-PROPYLPIPERONYL ETHER
PYRETHRINS AND PYRETHROIDS 4.3 HIGH
MOBILITY IN SOIL:
SOIL/WATER PARTITION COEFFICIENT (KOC): THERE IS NO DATA AVAILABLE.
OTHER ADVERSE EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
THE GENERATION OF WASTE SHOULD BE AVOIDED OR MINIMIZED WHEREVER POSSIBLE.
DISPOSAL OF THIS PRODUCT, SOLUTIONS AND ANY BY-PRODUCTS SHOULD COMPLY WITH
THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION AND WASTE DISPOSAL LEGISLATION
AND ANY REGIONAL LOCAL AUTHORITY REQUIREMENTS. DISPOSE OF SURPLUS AND
NON-RECYCLABLE PRODUCTS VIA A LICENSED WASTE DISPOSAL CONTRACTOR. WASTE
SHOULD NOT BE DISPOSED OF UNTREATED TO THE SEWER UNLESS FULLY COMPLIANT
WITH THE REQUIREMENTS OF ALL AUTHORITIES WITH JURISDICTION. WASTE PACKAGING
SHOULD BE RECYCLED. INCINERATION OR LANDFILL SHOULD ONLY BE CONSIDERED WHEN
RECYCLING IS NOT FEASIBLE. THIS MATERIAL AND ITS CONTAINER MUST BE DISPOSED
OF IN A SAFE WAY. CARE SHOULD BE TAKEN WHEN HANDLING EMPTY CONTAINERS THAT
HAVE NOT BEEN CLEANED OR RINSED OUT. EMPTY CONTAINERS OR LINERS MAY RETAIN
SOME PRODUCT RESIDUES. AVOID DISPERSAL OF SPILLED MATERIAL AND RUNOFF AND
CONTACT WITH SOIL, WATERWAYS, DRAINS AND SEWERS.
| SECTION 14. TRANSPORT INFORMATION | |
DOT CLASSIFICATION IMDG IATA
UN NUMBER UN3082 UN3082 UN3082
UN PROPER ENVIRONMENTALLY ENVIRONMENTALLY ENVIRONMENTALLY
SHIPPING HAZARDOUS HAZARDOUS HAZARDOUS
NAME SUBSTANCE, LIQUID, SUBSTANCE, LIQUID, SUBSTANCE, LIQUID,
N.O.S. (2-(2- N.O.S. (2-(2- N.O.S. (2-(2-
BUTOXYETHOXY)ETHYL BUTOXYETHOXY)ETHYL BUTOXYETHOXY)ETHYL
6-PROPYLPIPERONYL 6-PROPYLPIPERONYL 6-PROPYLPIPERONYL
ETHER) ETHER) ETHER)
TRANSPORT 9 9 9
HAZARD
CLASS(ES) CLASS 9, CLASS/ CLASS 9 - CLASS 9, CLASS/
DIVISION 9 MISCELLANEOUS DIVISION 9
PACKING GROUP III PACKING GROUP III
ENVIRONMENT
ENVIRONMENT
PACKING GROUP III III III
ENVIRONMENTAL YES. YES. YES.
HAZARDS
ADDITIONAL REPORTABLE THE MARINE THE ENVIRONMENTALLY
INFORMATION QUANTITY: POLLUTANT MARK IS HAZARDOUS SUBSTANCE
769.23 LBS / NOT REQUIRED WHEN MARK IS NOT REQUIRED
349.23 KG TRANSPORTED IN WHEN TRANSPORTED IN
[114.89 GAL / SIZES OF </=5 L SIZES OF </=5 L OR
434.91 L] OR </=5 KG. </=5 KG.
THE CLASSIFICATION EMERGENCY
OF THE PRODUCT IS SCHEDULES (EMS):
DUE SOLELY TO THE F-A, S-F
PRESENCE OF ONE
OR MORE US DOT-
LISTED 'HAZARDOUS
SUBSTANCES' THAT
ARE SUBJECT TO
REPORTABLE
QUANTITY
REQUIREMENTS AND
ONLY APPLIES TO
SHIPMENTS OF
PACKAGES GREATER
THAN, OR EQUAL TO,
THE PRODUCT
REPORTABLE
QUANTITY. PACKAGE
SIZES LESS THAN
THE PRODUCT
REPORTABLE
QUANTITY ARE NOT
REGULATED AS
HAZARDOUS
MATERIALS.
AERG: 171
SPECIAL PRECAUTIONS FOR USER:
TRANSPORT WITHIN USER'S PREMISES:
ALWAYS TRANSPORT IN CLOSED CONTAINERS THAT ARE UPRIGHT AND SECURE. ENSURE
THAT PERSONS TRANSPORTING THE PRODUCT KNOW WHAT TO DO IN THE EVENT OF AN
ACCIDENT OR SPILLAGE.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE:
NOT AVAILABLE.
| SECTION 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
TSCA 8(A) CDR EXEMPT/PARTIAL EXEMPTION: NOT DETERMINED
UNITED STATES INVENTORY (TSCA 8B): NOT DETERMINED.
CLEAN AIR ACT SECTION 112 (B) HAZARDOUS AIR POLLUTANTS (HAPS): NOT LISTED
CLEAN AIR ACT SECTION 602 CLASS I SUBSTANCES: NOT LISTED
CLEAN AIR ACT SECTION 602 CLASS II SUBSTANCES: NOT LISTED
DEA LIST I CHEMICALS (PRECURSOR CHEMICALS): NOT LISTED
DEA LIST II CHEMICALS (ESSENTIAL CHEMICALS): NOT LISTED
SARA 302/304:
COMPOSITION/INFORMATION ON INGREDIENTS: NO PRODUCTS WERE FOUND.
SARA 304 RQ: NOT APPLICABLE.
SARA 311/312:
CLASSIFICATION: NOT APPLICABLE.
COMPOSITION/INFORMATION ON INGREDIENTS:
NAME % FIRE SUDDEN REACTIVE IMMEDIATE DELAYED
HAZARD RELEASE (ACUTE) (CHRONIC)
OF HEALTH HEALTH
PRESSURE HAZARD HAZARD
DISTILLATES 60 - 100 YES. NO. NO. NO. NO.
(PETROLEUM),
HYDROTREATED
LIGHT
PYRETHRINS 0.1 - 1 YES. NO. NO. YES. NO.
AND
PYRETHROIDS
SARA 313:
PRODUCT NAME CAS NUMBER %
FORM R - REPORTING REQUIREMENTS:
2-(2-BUTOXYETHOXY)ETHYL 6-PROPYLPIPERONYL ETHER 51-03-6 1 - 5
SUPPLIER NOTIFICATION:
2-(2-BUTOXYETHOXY)ETHYL 6-PROPYLPIPERONYL ETHER 51-03-6 1 - 5
SARA 313 NOTIFICATIONS MUST NOT BE DETACHED FROM THE SDS AND ANY COPYING
AND REDISTRIBUTION OF THE SDS SHALL INCLUDE COPYING AND REDISTRIBUTION OF
THE NOTICE ATTACHED TO COPIES OF THE SDS SUBSEQUENTLY REDISTRIBUTED.
STATE REGULATIONS:
MASSACHUSETTS: NONE OF THE COMPONENTS ARE LISTED.
NEW YORK: NONE OF THE COMPONENTS ARE LISTED.
NEW JERSEY:
THE FOLLOWING COMPONENTS ARE LISTED:
2-(2-BUTOXYETHOXY)ETHYL 6-PROPYLPIPERONYL ETHER
PENNSYLVANIA: NONE OF THE COMPONENTS ARE LISTED.
CALIFORNIA PROP. 65: NO PRODUCTS WERE FOUND.
INTERNATIONAL REGULATIONS:
CHEMICAL WEAPON CONVENTION LIST SCHEDULES I, II & III CHEMICALS:
NOT LISTED.
MONTREAL PROTOCOL (ANNEXES A, B, C, E): NOT LISTED.
STOCKHOLM CONVENTION ON PERSISTENT ORGANIC POLLUTANTS: NOT LISTED.
ROTTERDAM CONVENTION ON PRIOR INFORM CONSENT (PIC): NOT LISTED.
UNECE AARHUS PROTOCOL ON POPS AND HEAVY METALS: NOT LISTED.
| SECTION 16. OTHER INFORMATION | |
HISTORY:
DATE OF ISSUE MM/DD/YYYY: 12/15/2014
DATE OF PREVIOUS ISSUE: 01/01/2014
VERSION: 1.1
REVISED SECTION(S): 1, 16
PREPARED BY: KMK REGULATORY SERVICES INC.
KEY TO ABBREVIATIONS:
ATE: ACUTE TOXICITY ESTIMATE
BCF: BIOCONCENTRATION FACTOR
GHS:
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELLING OF CHEMICALS
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
IBC: INTERMEDIATE BULK CONTAINER
IMDG: INTERNATIONAL MARITIME DANGEROUS GOODS
LOGPOW: LOGARITHM OF THE OCTANOL/WATER PARTITION COEFFICIENT
MARPOL 73/78:
INTERNATIONAL CONVENTION FOR THE PREVENTION OF POLLUTION FROM SHIPS, 1973
AS MODIFIED BY THE PROTOCOL OF 1978. ("MARPOL" = MARINE POLLUTION)
UN: UNITED NATIONS
NOTICE TO READER:
TO THE BEST OF OUR KNOWLEDGE, THE INFORMATION CONTAINED HEREIN IS ACCURATE.
HOWEVER, NEITHER THE ABOVE-NAMED SUPPLIER, NOR ANY OF ITS SUBSIDIARIES,
ASSUMES ANY LIABILITY WHATSOEVER FOR THE ACCURACY OR COMPLETENESS OF THE
INFORMATION CONTAINED HEREIN.
FINAL DETERMINATION OF SUITABILITY OF ANY MATERIAL IS THE SOLE
RESPONSIBILITY OF THE USER. ALL MATERIALS MAY PRESENT UNKNOWN HAZARDS AND
SHOULD BE USED WITH CAUTION. ALTHOUGH CERTAIN HAZARDS ARE DESCRIBED HEREIN,
WE CANNOT GUARANTEE THAT THESE ARE THE ONLY HAZARDS THAT EXIST.
KMK
KMK REGULATORY SERVICES
TEL: +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767)
WWW.KMKREGSERVICES.COM
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