| Common Name: | M90016-30 12C-CRTRG (0.650 LBS-0.295 KG) |
| Manufacturer: | MOMENTIVE AMER SEAL |
| SDS Revision Date: | 4/10/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 5PWD2 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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MOMENTIVE(TM)
INVENTING POSSIBILITIES
SAFETY DATA SHEET
FOR INDUSTRIAL USE ONLY
M90016-30 12C-CRTRG (0.650 LBS-0.295 KG)
| SECTION 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: M90016-30 12C-CRTRG (0.650 LBS-0.295 KG)
CHEMICAL NAME: NOT AVAILABLE
MANUFACTURER/IMPORTER/DISTRIBUTOR INFORMATION:
MOMENTIVE AMER SEAL.
260 HUDSON RIVER ROAD
WATERFORD NY 12188
CONTACT PERSON: COMMERCIAL.SERVICES@MOMENTIVE.COM
TELEPHONE:
GENERAL INFORMATION: +1-800-295-2392
EMERGENCY TELEPHONE NUMBER:
SUPPLIER:
CHEMTREC: 1-800-424-9300
| SECTION 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2A
SKIN SENSITIZATION: CATEGORY 1
TOXIC TO REPRODUCTION: CATEGORY 1B
TOXIC TO REPRODUCTION: CATEGORY 1B
GHS LABEL ELEMENTS:
HAZARD PICTOGRAMS:
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
H315: CAUSES SKIN IRRITATION.
H319: CAUSES SERIOUS EYE IRRITATION.
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
H360F: MAY DAMAGE FERTILITY.
H360: MAY DAMAGE THE UNBORN CHILD.
PRECAUTIONARY STATEMENTS:
GENERAL: NOT APPLICABLE.
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED.
WEAR PROTECTIVE GLOVES.
WEAR EYE OR FACE PROTECTION.
AVOID BREATHING DUST.
WASH HANDS THOROUGHLY AFTER HANDLING.
CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE.
RESPONSE:
IF EXPOSED OR CONCERNED: GET MEDICAL ATTENTION.
IF ON SKIN:
WASH WITH PLENTY OF SOAP AND WATER.
TAKE OFF CONTAMINATED CLOTHING.
WASH CONTAMINATED CLOTHING BEFORE REUSE.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ATTENTION.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES.
REMOVE CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION.
STORAGE: STORE LOCKED UP.
DISPOSAL:
P501:
DISPOSE OF CONTENTS AND CONTAINER IN ACCORDANCE WITH ALL LOCAL, REGIONAL,
NATIONAL AND INTERNATIONAL REGULATIONS.
OTHER HAZARDS WHICH DO NOT RESULT IN CLASSIFICATION: NONE KNOWN.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE/MIXTURE: MIXTURE
CHEMICAL NAME: NOT AVAILABLE
HAZARDOUS INGREDIENTS % BY WEIGHT CAS NUMBER
OCTAMETHYLCYCLOTETRASILOXANE 1 - 5 556-67-2
SILANAMINE, 1,1,1-TRIMETHYL- 1 - 5 999-97-3
N-(TRIMETHYLSILYL)-
TIN, DIBUTYLBIS(2,4-PENTANEDIONATO-. 0.1 - 1 22673-19-4
KAPPA.O2,.KAPPA.O4)-, (OC-6-11)-
THERE ARE NO ADDITIONAL INGREDIENTS PRESENT WHICH, WITHIN THE CURRENT
KNOWLEDGE OF THE SUPPLIER AND IN THE CONCENTRATIONS APPLICABLE, ARE
CLASSIFIED AS HAZARDOUS TO HEALTH OR THE ENVIRONMENT AND HENCE REQUIRE
REPORTING IN THIS SECTION.
OCCUPATIONAL EXPOSURE LIMITS, IF AVAILABLE, ARE LISTED IN SECTION 8.
| SECTION 4. FIRST AID MEASURES | |
DESCRIPTION OF NECESSARY FIRST AID MEASURES:
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER, OCCASIONALLY LIFTING THE UPPER
AND LOWER EYELIDS. CHECK FOR AND REMOVE ANY CONTACT LENSES. CONTINUE TO
RINSE FOR AT LEAST 10 MINUTES. GET MEDICAL ATTENTION.
INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. IF NOT BREATHING, IF BREATHING IS IRREGULAR OR IF RESPIRATORY
ARREST OCCURS, PROVIDE ARTIFICIAL RESPIRATION OR OXYGEN BY TRAINED
PERSONNEL. IT MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE
MOUTH-TO-MOUTH RESUSCITATION. GET MEDICAL ATTENTION. IF UNCONSCIOUS, PLACE
IN RECOVERY POSITION AND GET MEDICAL ATTENTION IMMEDIATELY. MAINTAIN AN
OPEN AIRWAY. LOOSEN TIGHT CLOTHING SUCH AS A COLLAR, TIE, BELT OR
WAISTBAND.
SKIN CONTACT:
WASH WITH PLENTY OF SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND SHOES.
WASH CONTAMINATED CLOTHING THOROUGHLY WITH WATER BEFORE REMOVING IT, OR
WEAR GLOVES. CONTINUE TO RINSE FOR AT LEAST 10 MINUTES. GET MEDICAL
ATTENTION. IN THE EVENT OF ANY COMPLAINTS OR SYMPTOMS, AVOID FURTHER
EXPOSURE. WASH CLOTHING BEFORE REUSE. CLEAN SHOES THOROUGHLY BEFORE REUSE.
INGESTION:
WASH OUT MOUTH WITH WATER. REMOVE DENTURES IF ANY. REMOVE VICTIM TO FRESH
AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR BREATHING. IF MATERIAL
HAS BEEN SWALLOWED AND THE EXPOSED PERSON IS CONSCIOUS, GIVE SMALL
QUANTITIES OF WATER TO DRINK. STOP IF THE EXPOSED PERSON FEELS SICK AS
VOMITING MAY BE DANGEROUS. DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO
BY MEDICAL PERSONNEL. IF VOMITING OCCURS, THE HEAD SHOULD BE KEPT LOW SO
THAT VOMIT DOES NOT ENTER THE LUNGS. GET MEDICAL ATTENTION. NEVER GIVE
ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF UNCONSCIOUS, PLACE IN
RECOVERY POSITION AND GET MEDICAL ATTENTION IMMEDIATELY. MAINTAIN AN OPEN
AIRWAY. LOOSEN TIGHT CLOTHING SUCH AS A COLLAR, TIE, BELT OR WAISTBAND.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED, IF
NECESSARY:
NOTES TO PHYSICIAN:
IN CASE OF INHALATION OF DECOMPOSITION PRODUCTS IN A FIRE, SYMPTOMS MAY BE
DELAYED. THE EXPOSED PERSON MAY NEED TO BE KEPT UNDER MEDICAL SURVEILLANCE
FOR 48 HOURS.
SPECIFIC TREATMENTS: NO SPECIFIC TREATMENT.
PROTECTION OF FIRST AID PERSONNEL:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. IF IT IS SUSPECTED THAT FUMES ARE STILL PRESENT, THE RESCUER
SHOULD WEAR AN APPROPRIATE MASK OR SELF-CONTAINED BREATHING APPARATUS.
IT MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH
RESUSCITATION. WASH CONTAMINATED CLOTHING THOROUGHLY WITH WATER BEFORE
REMOVING IT, OR WEAR GLOVES.
SEE TOXICOLOGICAL INFORMATION (SECTION 11)
| SECTION 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE DRY CHEMICAL, CO2, ALCOHOL-RESISTANT FOAM OR WATER SPRAY (FOG).
UNSUITABLE EXTINGUISHING MEDIA: WATER JET
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
NO SPECIFIC FIRE OR EXPLOSION HAZARD.
HAZARDOUS THERMAL DECOMPOSITION PRODUCTS:
DECOMPOSITION PRODUCTS MAY INCLUDE THE FOLLOWING MATERIALS:
CARBON DIOXIDE
CARBON MONOXIDE
NITROGEN OXIDES
METAL OXIDE/OXIDES
MEASUREMENTS AT TEMPERATURES ABOVE 150 DEG. C IN PRESENCE OF AIR (OXYGEN)
HAVE SHOWN THAT SMALL AMOUNTS OF FORMALDEHYDE ARE FORMED DUE TO OXIDATIVE
DEGRADATION.
SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
PROMPTLY ISOLATE THE SCENE BY REMOVING ALL PERSONS FROM THE VICINITY OF
THE INCIDENT IF THERE IS A FIRE. NO ACTION SHALL BE TAKEN INVOLVING ANY
PERSONAL RISK OR WITHOUT SUITABLE TRAINING. USE WATER SPRAY TO KEEP
FIRE-EXPOSED CONTAINERS COOL. FIRE WATER CONTAMINATED WITH THIS MATERIAL
MUST BE CONTAINED AND PREVENTED FROM BEING DISCHARGED TO ANY WATERWAY,
SEWER OR DRAIN.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
FIRE-FIGHTERS SHOULD WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND
SELF-CONTAINED BREATHING APPARATUS (SCBA) WITH A FULL FACE-PIECE OPERATED
IN POSITIVE PRESSURE MODE.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
FOR NON-EMERGENCY PERSONNEL:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. EVACUATE SURROUNDING AREAS. KEEP UNNECESSARY AND UNPROTECTED
PERSONNEL FROM ENTERING. DO NOT TOUCH OR WALK THROUGH SPILLED MATERIAL.
PROVIDE ADEQUATE VENTILATION. WEAR APPROPRIATE RESPIRATOR WHEN VENTILATION
IS INADEQUATE. PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT.
FOR EMERGENCY RESPONDERS:
IF SPECIALISED CLOTHING IS REQUIRED TO DEAL WITH THE SPILLAGE, TAKE NOTE OF
ANY INFORMATION IN SECTION 8 ON SUITABLE AND UNSUITABLE MATERIALS. SEE ALSO
THE INFORMATION IN "FOR NON-EMERGENCY PERSONNEL".
ENVIRONMENTAL PRECAUTIONS:
AVOID DISPERSAL OF SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL,
WATERWAYS, DRAINS AND SEWERS. INFORM THE RELEVANT AUTHORITIES IF THE
PRODUCT HAS CAUSED ENVIRONMENTAL POLLUTION (SEWERS, WATERWAYS, SOIL
OR AIR).
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
SMALL SPILL:
MOVE CONTAINERS FROM SPILL AREA. VACUUM OR SWEEP UP MATERIAL AND PLACE IN A
DESIGNATED, LABELED WASTE CONTAINER. DISPOSE OF VIA A LICENSED WASTE
DISPOSAL CONTRACTOR.
NOTE:
SEE SECTION 1 OF SDS FOR EMERGENCY CONTACT INFORMATION AND SECTION 13 OF
SDS FOR WASTE DISPOSAL.
LARGE SPILL:
MOVE CONTAINERS FROM SPILL AREA. APPROACH RELEASE FROM UPWIND.
PREVENT ENTRY INTO SEWERS, WATER COURSES, BASEMENTS OR CONFINED AREAS.
VACUUM OR SWEEP UP MATERIAL AND PLACE IN A DESIGNATED, LABELED WASTE
CONTAINER. DISPOSE OF VIA A LICENSED WASTE DISPOSAL CONTRACTOR.
NOTE:
SEE SECTION 1 OF SDS FOR EMERGENCY CONTACT INFORMATION AND SECTION 13 OF
SDS FOR WASTE DISPOSAL.
| SECTION 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
PROTECTIVE MEASURES:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8 OF SDS).
PERSONS WITH A HISTORY OF SKIN SENSITIZATION PROBLEMS SHOULD NOT BE
EMPLOYED IN ANY PROCESS IN WHICH THIS PRODUCT IS USED. AVOID EXPOSURE -
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. AVOID EXPOSURE DURING PREGNANCY.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
DO NOT GET IN EYES OR ON SKIN OR CLOTHING. DO NOT INGEST. USE ONLY WITH
ADEQUATE VENTILATION. KEEP IN THE ORIGINAL CONTAINER OR AN APPROVED
ALTERNATIVE MADE FROM A COMPATIBLE MATERIAL, KEPT TIGHTLY CLOSED WHEN NOT
IN USE. EMPTY CONTAINERS RETAIN PRODUCT RESIDUE AND CAN BE HAZARDOUS.
ADVICE ON GENERAL OCCUPATIONAL HYGIENE:
EATING, DRINKING AND SMOKING SHOULD BE PROHIBITED IN AREAS WHERE THIS
MATERIAL IS HANDLED, STORED AND PROCESSED. WORKERS SHOULD WASH HANDS AND
FACE BEFORE EATING, DRINKING AND SMOKING. SEE ALSO SECTION 8 FOR ADDITIONAL
INFORMATION ON HYGIENE MEASURES.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE IN ACCORDANCE WITH LOCAL REGULATIONS. STORE IN ORIGINAL CONTAINER
PROTECTED FROM DIRECT SUNLIGHT IN A DRY, COOL AND WELL-VENTILATED AREA,
AWAY FROM INCOMPATIBLE MATERIALS (SEE SECTION 10 OF SDS) AND FOOD AND
DRINK. STORE LOCKED UP. KEEP CONTAINER TIGHTLY CLOSED AND SEALED UNTIL
READY FOR USE. CONTAINERS THAT HAVE BEEN OPENED MUST BE CAREFULLY RESEALED
AND KEPT UPRIGHT TO PREVENT LEAKAGE. DO NOT STORE IN UNLABELED CONTAINERS.
USE APPROPRIATE CONTAINMENT TO AVOID ENVIRONMENTAL CONTAMINATION.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
INGREDIENT NAME EXPOSURE LIMITS
OCTAMETHYLCYCLOTETRASILOXANE ( ) RECOMMENDED EXPOSURE LIMIT (REL): 5 PPM
APPROPRIATE ENGINEERING CONTROLS:
IF USER OPERATIONS GENERATE DUST, FUMES, GAS, VAPOR OR MIST, USE PROCESS
ENCLOSURES, LOCAL EXHAUST VENTILATION OR OTHER ENGINEERING CONTROLS TO KEEP
WORKER EXPOSURE TO AIRBORNE CONTAMINANTS BELOW ANY RECOMMENDED OR STATUTORY
LIMITS.
ENVIRONMENTAL EXPOSURE CONTROLS:
EMISSIONS FROM VENTILATION OR WORK PROCESS EQUIPMENT SHOULD BE CHECKED TO
ENSURE THEY COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION
LEGISLATION. IN SOME CASES, FUME SCRUBBERS, FILTERS OR ENGINEERING
MODIFICATIONS TO THE PROCESS EQUIPMENT WILL BE NECESSARY TO REDUCE
EMISSIONS TO ACCEPTABLE LEVELS.
INDIVIDUAL PROTECTION MEASURES:
HYGIENE MEASURES:
WASH HANDS, FOREARMS AND FACE THOROUGHLY AFTER HANDLING CHEMICAL PRODUCTS,
BEFORE EATING, SMOKING AND USING THE LAVATORY AND AT THE END OF THE WORKING
PERIOD. APPROPRIATE TECHNIQUES SHOULD BE USED TO REMOVE POTENTIALLY
CONTAMINATED CLOTHING. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT
OF THE WORKPLACE. WASH CONTAMINATED CLOTHING BEFORE REUSING. ENSURE THAT
EYEWASH STATIONS AND SAFETY SHOWERS ARE CLOSE TO THE WORKSTATION LOCATION.
EYE/FACE PROTECTION:
SAFETY EYEWEAR COMPLYING WITH AN APPROVED STANDARD SHOULD BE USED WHEN A
RISK ASSESSMENT INDICATES THIS IS NECESSARY TO AVOID EXPOSURE TO LIQUID
SPLASHES, MISTS, GASES OR DUSTS. IF CONTACT IS POSSIBLE, THE FOLLOWING
PROTECTION SHOULD BE WORN, UNLESS THE ASSESSMENT INDICATES A HIGHER DEGREE
OF PROTECTION: CHEMICAL SPLASH GOGGLES.
SKIN PROTECTION:
HAND PROTECTION:
CHEMICAL-RESISTANT, IMPERVIOUS GLOVES COMPLYING WITH AN APPROVED STANDARD
SHOULD BE WORN AT ALL TIMES WHEN HANDLING CHEMICAL PRODUCTS IF A RISK
ASSESSMENT INDICATES THIS IS NECESSARY. CONSIDERING THE PARAMETERS
SPECIFIED BY THE GLOVE MANUFACTURER, CHECK DURING USE THAT THE GLOVES ARE
STILL RETAINING THEIR PROTECTIVE PROPERTIES. IT SHOULD BE NOTED THAT THE
TIME TO BREAKTHROUGH FOR ANY GLOVE MATERIAL MAY BE DIFFERENT FOR DIFFERENT
GLOVE MANUFACTURERS. IN THE CASE OF MIXTURES, CONSISTING OF SEVERAL
SUBSTANCES, THE PROTECTION TIME OF THE GLOVES CANNOT BE ACCURATELY
ESTIMATED.
BODY PROTECTION:
PERSONAL PROTECTIVE EQUIPMENT FOR THE BODY SHOULD BE SELECTED BASED ON THE
TASK BEING PERFORMED AND THE RISKS INVOLVED AND SHOULD BE APPROVED BY A
SPECIALIST BEFORE HANDLING THIS PRODUCT.
OTHER SKIN PROTECTION:
APPROPRIATE FOOTWEAR AND ANY ADDITIONAL SKIN PROTECTION MEASURES SHOULD BE
SELECTED BASED ON THE TASK BEING PERFORMED AND THE RISKS INVOLVED AND
SHOULD BE APPROVED BY A SPECIALIST BEFORE HANDLING THIS PRODUCT.
RESPIRATORY PROTECTION:
USE A PROPERLY FITTED, PARTICULATE FILTER RESPIRATOR COMPLYING WITH AN
APPROVED STANDARD IF A RISK ASSESSMENT INDICATES THIS IS NECESSARY.
RESPIRATOR SELECTION MUST BE BASED ON KNOWN OR ANTICIPATED EXPOSURE LEVELS,
THE HAZARDS OF THE PRODUCT AND THE SAFE WORKING LIMITS OF THE SELECTED
RESPIRATOR.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: SOLID
COLOR: COLORLESS.
ODOR: AMMONIA
ODOR THRESHOLD: NOT AVAILABLE
PH: NOT APPLICABLE.
MELTING POINT: NOT APPLICABLE.
BOILING POINT: NOT APPLICABLE.
FLASH POINT: 110.00 DEG. C (230.00 DEG. F) (PENSKY-MARTENS.)
BURNING TIME: NOT AVAILABLE
BURNING RATE: NOT AVAILABLE
EVAPORATION RATE: NOT AVAILABLE
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE
LOWER AND UPPER EXPLOSIVE (FLAMMABLE) LIMITS:
LOWER: NOT APPLICABLE.
UPPER: NOT APPLICABLE.
VAPOR PRESSURE: 1.33 HPA
VAPOR DENSITY: NOT AVAILABLE
RELATIVE DENSITY: 1.03
DENSITY: 1.035 G/CM3
SOLUBILITY: TOLUENE
SOLUBILITY IN WATER: NEGLIGIBLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NOT AVAILABLE
AUTO-IGNITION TEMPERATURE: NOT APPLICABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE
SADT: NOT AVAILABLE
VISCOSITY:
DYNAMIC: NOT AVAILABLE
KINEMATIC: NOT AVAILABLE
VOLATILE ORGANIC CONTENT:
2.8% (W/W)
33 G/L
OTHER INFORMATION: NO ADDITIONAL INFORMATION.
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY: STABLE UNDER NORMAL CONDITIONS.
CHEMICAL STABILITY: THE PRODUCT IS STABLE.
POSSIBILITY OF HAZARDOUS REACTIONS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS REACTIONS WILL NOT
OCCUR.
CONDITIONS TO AVOID: NO SPECIFIC DATA.
INCOMPATIBLE MATERIALS: NO SPECIFIC DATA.
HAZARDOUS DECOMPOSITION PRODUCTS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS DECOMPOSITION
PRODUCTS SHOULD NOT BE PRODUCED.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
PRODUCT/INGREDIENT NAME RESULT SPECIES DOSE EXPOSURE
OCTAMETHYLCYCLOTETRA- LD50 ORAL RAT 4,800 MG/KG
SILOXANE OECD-GUIDELINE
401 (ACUTE
ORAL TOXICITY)
LC50 RAT >12.1 MG/L 4 H
INHALATION
LC50 RAT 36 MG/L OECD 4 H
INHALATION TEST GUIDELINE
403
LD50 DERMAL RAT >2,400 MG/KG
OECD TEST
GUIDELINE 402
SILANAMINE, LD50 ORAL RAT 850 MG/KG
1,1,1-TRIMETHYL-
N-(TRIMETHYLSILYL)- LC50 RAT 9 MG/L 4 H
INHALATION
CONCLUSION/SUMMARY: NOT DETERMINED
IRRITATION/CORROSION:
PRODUCT/INGREDIENT RESULT SPECIES SCORE EXPOSURE OBSERVATION
NAME
OCTAMETHYLCYCLOTETRA- SKIN RAT
SILOXANE OECD-
GUIDELINE
404 (ACUTE
DERMAL
IRRITATION/
CORROSION)
REMARKS NON-IRRITATING TO THE SKIN.
EYES RABBIT
OECD-
GUIDELINE
405 (ACUTE
EYE
IRRITATION/
CORROSION)
REMARKS NON-IRRITATING TO THE EYES.
SILANAMINE, SKIN RABBIT
1,1,1-TRIMETHYL-N- SEVERE
(TRIMETHYLSILYL)- IRRITANT
CONCLUSION/SUMMARY:
SKIN: NOT DETERMINED
EYES: NOT DETERMINED
RESPIRATORY: NOT DETERMINED
SENSITIZATION:
PRODUCT/INGREDIENT NAME ROUTE OF SPECIES RESULT
EXPOSURE
OCTAMETHYLCYCLOTETRASILOXANE GUINEA PIG NOT SENSITIZING
OECD-GUIDELINE 406
(SKIN SENSITISATION)
CONCLUSION/SUMMARY:
SKIN: NOT DETERMINED
RESPIRATORY: NOT DETERMINED
MUTAGENICITY:
PRODUCT/INGREDIENT NAME TEST EXPERIMENT RESULT
OCTAMETHYLCYCLOTETRASILOXANE OECD-GUIDELINE IN VITRO NEGATIVE
471 (GENETIC
TOXICOLOGY:
SALMONELLA
TYPHIMURIUM,
REVERSE MUTATION
ASSAY)
MOUSE LYMPHOMA IN VITRO NEGATIVE
ASSAY (OECD
GUIDLINE 476)
OECD-GUIDELINE IN VIVO NEGATIVE
474 (GENETIC
TOXICOLOGY:
MICRONUCLEUS TEST)
CONCLUSION/SUMMARY: NOT DETERMINED
CARCINOGENICITY:
PRODUCT/INGREDIENT NAME RESULT SPECIES DOSE EXPOSURE
OCTAMETHYLCYCLOTETRA- INHALATION - RAT - FEMALE 150 MG/KG 24 MONTHS
SILOXANE OECD 453
REMARKS NOAEC
INHALATION - RAT - MALE >700 MG/KG 24 MONTHS
OECD 453
REMARKS NOAEC
CONCLUSION/SUMMARY: NOT DETERMINED
REPRODUCTIVE TOXICITY:
PRODUCT/ MATERNAL FERTILITY DEVELOPMENT SPECIES DOSE EXPOSURE
INGREDIENT TOXICITY TOXIN
NAME
OCTAMETHYL- RAT INHA-
CYCLOTETRA- LATION:
SILOXANE 300 MG/KG
OECD 416
REMARKS NOAEL PARENTS
RAT INHA-
LATION:
300 MG/KG
OECD 416
REMARKS NOAEL F1
CONCLUSION/SUMMARY: NOT DETERMINED
TERATOGENICITY:
PRODUCT/INGREDIENT NAME RESULT SPECIES DOSE EXPOSURE
OCTAMETHYLCYCLOTETRA- INHALATION RABBIT 500 MG/KG 18 DAYS
SILOXANE OECD TEST
GUIDELINE 414
REMARKS NOAEL
INHALATION RABBIT 300 MG/KG 18 DAYS
OECD TEST
GUIDELINE 414
REMARKS NOAEL MATERNITY
CONCLUSION/SUMMARY: NOT DETERMINED
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE):
PRODUCT/INGREDIENT NAME CATEGORY ROUTE OF EXPOSURE TARGET ORGANS
TIN, DIBUTYLBIS(2,4- CATEGORY 1 THYMUS
PENTANEDIONATO-.
KAPPA.O2,.KAPPA.O4)-,
(OC-6-11)-
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE):
PRODUCT/INGREDIENT NAME CATEGORY ROUTE OF EXPOSURE TARGET ORGANS
TIN, DIBUTYLBIS(2,4- CATEGORY 1 THYMUS
PENTANEDIONATO-.
KAPPA.O2,.KAPPA.O4)-,
(OC-6-11)-
ASPIRATION HAZARD: NOT AVAILABLE
INFORMATION ON THE LIKELY ROUTES OF EXPOSURE: NOT AVAILABLE
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INHALATION:
EXPOSURE TO DECOMPOSITION PRODUCTS MAY CAUSE A HEALTH HAZARD.
SERIOUS EFFECTS MAY BE DELAYED FOLLOWING EXPOSURE.
SKIN CONTACT: CAUSES SKIN IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION.
INGESTION: IRRITATING TO MOUTH, THROAT AND STOMACH.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN OR IRRITATION
WATERING
REDNESS
INHALATION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
IRRITATION
REDNESS
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
INGESTION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
DELAYED AND IMMEDIATE EFFECTS AND ALSO CHRONIC EFFECTS FROM SHORT AND LONG
TERM EXPOSURE:
SHORT TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE
LONG TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE
POTENTIAL CHRONIC HEALTH EFFECTS:
PRODUCT/INGREDIENT NAME RESULT SPECIES DOSE EXPOSURE
OCTAMETHYLCYCLOTETRASILOXANE NOAEC RAT 150 MG/KG 24 MONTHS
INHALATION OECD 453
REMARKS NOAEC
NOAEL RABBIT >1 MG/KG 3 WEEKS
DERMAL OECD 410
REMARKS NOAEL
CONCLUSION/SUMMARY: NOT DETERMINED
GENERAL:
ONCE SENSITIZED, A SEVERE ALLERGIC REACTION MAY OCCUR WHEN SUBSEQUENTLY
EXPOSED TO VERY LOW LEVELS.
CARCINOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
MUTAGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
TERATOGENICITY: MAY DAMAGE THE UNBORN CHILD.
DEVELOPMENTAL EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
FERTILITY EFFECTS: MAY DAMAGE FERTILITY.
NUMERICAL MEASURES OF TOXICITY:
ACUTE TOXICITY ESTIMATES:
ROUTE ATE VALUE
ORAL 20,650.2 MG/KG
ROUTE ATE VALUE
DERMAL 21,642.6 MG/KG
ROUTE ATE VALUE
INHALATION (VAPORS) 793.6 MG/L
OTHER INFORMATION:
OCTAMETHYLCYCLOTETRASILOXANE (D4) INGESTION:
RODENTS GIVEN LARGE DOSES VIA ORAL GAVAGE OF OCTAMETHYLCYCLOTETRASILOXANE
(1600 MG/KG/DAY, 14 DAYS), DEVELOPED INCREASED LIVER WEIGHTS RELATIVE TO
UNEXPOSED CONTROL ANIMALS DUE TO HEPATOCELLULAR HYPERPLASIA (INCREASED
NUMBER OF LIVER CELLS WHICH APPEAR NORMAL) AS WELL AS HYPERTROPHY
(INCREASED CELL SIZE). INHALATION: IN INHALATION STUDIES, LABORATORY
RODENTS EXPOSED TO OCTAMETHYLCYCLOTETRASILOXANE (300 PPM FIVE DAYS/WEEK,
90 DAYS) DEVELOPED INCREASED LIVER WEIGHTS IN FEMALE ANIMALS RELATIVE TO
UNEXPOSED CONTROL ANIMALS. WHEN THE EXPOSURE WAS STOPPED, LIVER WEIGHTS
RETURNED TO NORMAL. MICROSCOPIC EXAMINATION OF THE LIVER CELLS DID NOT SHOW
ANY EVIDENCE OF PATHOLOGY. THIS RESPONSE IN RATS, WHICH DOES NOT AFFECT THE
ANIMAL'S HEALTH, IS WELL-DOCUMENTED AND WIDELY RECOGNIZED. IT IS RELATED TO
AN INCREASE OF LIVER ENZYMES THAT METABOLIZE AND ELIMINATE A MATERIAL FROM
THE BODY. THE INCREASED LIVER WEIGHT REVERSES EVEN WHILE THE D4 EXPOSURE
CONTINUES. THE FINDING IS NOT ADVERSE, BUT IS CONSIDERED A NATURAL ADAPTIVE
CHANGE IN RATS, AND DOES NOT REPRESENT A HAZARD TO HUMANS. INHALATION
STUDIES UTILIZING LABORATORY RABBITS AND GUINEA PIGS SHOWED NO EFFECTS ON
LIVER WEIGHTS. INHALATION EXPOSURES TYPICAL OF INDUSTRIAL USAGE (5-10 PPM)
SHOWED NO TOXIC EFFECTS IN RODENTS. RANGE FINDING REPRODUCTIVE STUDIES WERE
CONDUCTED (WHOLE BODY INHALATION, 70 DAYS PRIOR TO MATING, THROUGH MATING,
GESTATION AND LACTATION), WITH D4. RATS WERE EXPOSED TO 70 AND 700 PPM.
IN THE 700 PPM GROUP, THERE WAS A STATISTICALLY SIGNIFICANT REDUCTION IN
MEAN LITTER SIZE AND IN IMPLANTATION SITES. NO D4 RELATED CLINICAL SIGNS
WERE OBSERVED IN THE PUPS AND NO EXPOSURE RELATED PATHOLOGICAL FINDINGS
WERE FOUND. A TWO-YEAR, COMBINED CHRONIC/CARCINOGENICITY STUDY, DURING
WHICH RATS WERE EXPOSED TO D4 BY INHALATION, DATA SHOWED A STATISTICALLY
SIGNIFICANT INCREASE IN A BENIGN UTERINE TUMOR IN FEMALE RATS EXPOSED AT
THE HIGHEST LEVEL--A LEVEL MUCH HIGHER THAN THE LOW LEVELS THAT CONSUMERS
OR WORKERS MAY ENCOUNTER. AN EXPERT PANEL OF INDEPENDENT SCIENTISTS WHO
HAVE REVIEWED THE RESULTS OF THIS RESEARCH CONCUR THAT THE FINDING SEEN IN
THE TWO-YEAR STUDY OCCURRED THROUGH A BIOLOGICAL PATHWAY THAT IS SPECIFIC
TO THE RAT AND IS NOT RELEVANT TO HUMANS. THEREFORE, THIS OBSERVED EFFECT
DOES NOT INDICATE A POTENTIAL HEALTH HAZARD TO HUMANS. IN DEVELOPMENTAL
TOXICITY STUDIES, RATS AND RABBITS WERE EXPOSED TO D4 AT CONCENTRATIONS UP
TO 700 PPM AND 500 PPM, RESPECTIVELY. NO TERATOGENIC EFFECTS
(BIRTH DEFECTS) WERE OBSERVED IN EITHER STUDY.
| SECTION 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
CONCLUSION/SUMMARY: NOT AVAILABLE
PERSISTENCE/DEGRADABILITY:
PRODUCT/INGREDIENT TEST RESULT DOSE INOCULUM
NAME
OCTAMETHYLCYCLOTETRA- 310 READY 3.7 % - 29 D ACTIVATED
SILOXANE BIODEGRADABILITY SLUDGE
- CO2 IN SEALED
VESSELS
(HEADSPACE TEST)
REMARKS NOT READILY BIODEGRADABLE.
CONCLUSION/SUMMARY: NOT AVAILABLE
BIOACCUMULATIVE POTENTIAL:
PRODUCT/INGREDIENT NAME SPECIES EXPOSURE LOGPOW BCF POTENTIAL
OCTAMETHYLCYCLOTETRA- FATHEAD 28 D 12.40 LOW
SILOXANE MINNOW
SILANAMINE, 1,1,1- 1.19 LOW
TRIMETHYL-N-
(TRIMETHYLSILYL)-
MOBILITY IN SOIL:
SOIL/WATER PARTITION COEFFICIENT (KOC): NOT AVAILABLE
OTHER ADVERSE EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
OTHER INFORMATION:
OCTAMETHYLCYCLOTETRASILOXANE (D4) MEETS THE CURRENT REACH ANNEX XIII
CRITERIA FOR PBT AND VPVB. HOWEVER, D4 DOES NOT BEHAVE SIMILARLY TO KNOWN
PBT/VPVB SUBSTANCES. THE SILICONES INDUSTRIES INTERPRETATION OF THE
AVAILABLE DATA IS THAT THE WEIGHT OF SCIENTIFIC EVIDENCE FROM FIELD STUDIES
SHOWS THAT D4 IS NOT BIOMAGNIFYING IN AQUATIC AND TERRESTRIAL FOOD WEBS.
D4 IN AIR WILL DEGRADE BY REACTION WITH NATURALLY OCCURRING HYDROXYL
RADICALS IN THE ATMOSPHERE. ANY D4 IN AIR THAT DOES NOT DEGRADE BY REACTION
WITH HYDROXYL RADICALS IS NOT EXPECTED TO DEPOSIT FROM THE AIR TO WATER, TO
LAND, OR TO LIVING ORGANISMS.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
THE GENERATION OF WASTE SHOULD BE AVOIDED OR MINIMIZED WHEREVER POSSIBLE.
DISPOSAL OF THIS PRODUCT, SOLUTIONS AND ANY BY-PRODUCTS SHOULD AT ALL TIMES
COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION AND WASTE DISPOSAL
LEGISLATION AND ANY REGIONAL LOCAL AUTHORITY REQUIREMENTS. DISPOSE OF
SURPLUS AND NON-RECYCLABLE PRODUCTS VIA A LICENSED WASTE DISPOSAL
CONTRACTOR. WASTE SHOULD NOT BE DISPOSED OF UNTREATED TO THE SEWER UNLESS
FULLY COMPLIANT WITH THE REQUIREMENTS OF ALL AUTHORITIES WITH JURISDICTION.
WASTE PACKAGING SHOULD BE RECYCLED. INCINERATION OR LANDFILL SHOULD ONLY BE
CONSIDERED WHEN RECYCLING IS NOT FEASIBLE. THIS MATERIAL AND ITS CONTAINER
MUST BE DISPOSED OF IN A SAFE WAY. CARE SHOULD BE TAKEN WHEN HANDLING
EMPTIED CONTAINERS THAT HAVE NOT BEEN CLEANED OR RINSED OUT. EMPTY
CONTAINERS OR LINERS MAY RETAIN SOME PRODUCT RESIDUES. AVOID DISPERSAL OF
SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL, WATERWAYS, DRAINS AND
SEWERS.
| SECTION 14. TRANSPORT INFORMATION | |
SPECIAL PRECAUTIONS FOR USER:
THIS PRODUCT IS NOT REGARDED AS DANGEROUS GOODS ACCORDING TO THE NATIONAL
AND INTERNATIONAL REGULATIONS ON THE TRANSPORT OF DANGEROUS GOODS.
| SECTION 15. REGULATORY INFORMATION | |
UNITED STATES:
U.S. FEDERAL REGULATIONS:
UNITED STATES - TSCA 12(B) - CHEMICAL EXPORT NOTIFICATION: NONE REQUIRED.
UNITED STATES - TSCA 5(A)2 - FINAL SIGNIFICANT NEW USE RULES: NOT LISTED
UNITED STATES - TSCA 5(A)2 - PROPOSED SIGNIFICANT NEW USE RULES: NOT LISTED
UNITED STATES - TSCA 5(E) - SUBSTANCES CONSENT ORDER: NOT LISTED
SARA 311/312:
CLASSIFICATION:
IMMEDIATE (ACUTE) HEALTH HAZARD
DELAYED (CHRONIC) HEALTH HAZARD
CALIFORNIA PROP. 65:
WARNING:
THIS PRODUCT CONTAINS LESS THAN 1% OF A CHEMICAL KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
CANADA:
WHMIS (CANADA):
CLASS D-2A: MATERIAL CAUSING OTHER TOXIC EFFECTS (VERY TOXIC).
CLASS D-2B: MATERIAL CAUSING OTHER TOXIC EFFECTS (TOXIC).
INTERNATIONAL REGULATIONS:
INTERNATIONAL LISTS:
AUSTRALIA INVENTORY (AICS): ALL COMPONENTS ARE LISTED OR EXEMPTED.
CANADA INVENTORY: ALL COMPONENTS ARE LISTED OR EXEMPTED.
JAPAN INVENTORY: NOT DETERMINED.
CHINA INVENTORY (IECSC): ALL COMPONENTS ARE LISTED OR EXEMPTED.
KOREA INVENTORY: NOT DETERMINED.
NEW ZEALAND INVENTORY (NZIOC): NOT DETERMINED.
PHILIPPINES INVENTORY (PICCS): NOT DETERMINED.
UNITED STATES INVENTORY (TSCA 8B): ALL COMPONENTS ARE LISTED OR EXEMPTED.
TAIWAN INVENTORY (CSNN): NOT DETERMINED.
| SECTION 16. OTHER INFORMATION | |
HAZARDOUS MATERIAL INFORMATION SYSTEM III (U.S.A.):
HEALTH 1
FLAMMABILITY 1
PHYSICAL HAZARDS 0
CAUTION:
HMIS(R*) RATINGS ARE BASED ON A 0-4 RATING SCALE, WITH 0 REPRESENTING
MINIMAL HAZARDS OR RISKS, AND 4 REPRESENTING SIGNIFICANT HAZARDS OR RISKS
ALTHOUGH HMIS(R*) RATINGS ARE NOT REQUIRED ON MSDSS UNDER 29 CFR 1910.1200,
THE PREPARER MAY CHOOSE TO PROVIDE THEM. HMIS(R*) RATINGS ARE TO BE USED
WITH A FULLY IMPLEMENTED HMIS(R*) PROGRAM. HMIS(R*) IS A REGISTERED MARK OF
THE NATIONAL PAINT & COATINGS ASSOCIATION (NPCA). HMIS(R*) MATERIALS MAY BE
PURCHASED EXCLUSIVELY FROM J. J. KELLER (800) 327-6868. THE CUSTOMER IS
RESPONSIBLE FOR DETERMINING THE PPE CODE FOR THIS MATERIAL.
FULL TEXT OF ABBREVIATED H STATEMENTS: NOT APPLICABLE.
HISTORY:
DATE OF PRINTING: 02/22/2016
DATE OF ISSUE/DATE OF REVISION: 04/10/2015
DATE OF PREVIOUS ISSUE: 04/03/2015
VERSION: 1.4
PREPARED BY: PRODUCT SAFETY STEWARDSHIP
KEY TO ABBREVIATIONS:
ATE: ACUTE TOXICITY ESTIMATE
BCF: BIOCONCENTRATION FACTOR
GHS:
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELLING OF CHEMICALS
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
IBC: INTERMEDIATE BULK CONTAINER
IMDG: INTERNATIONAL MARITIME DANGEROUS GOODS
LOGPOW: LOGARITHM OF THE OCTANOL/WATER PARTITION COEFFICIENT
MARPOL 73/78:
INTERNATIONAL CONVENTION FOR THE PREVENTION OF POLLUTION FROM SHIPS, 1973
AS MODIFIED BY THE PROTOCOL OF 1978. ("MARPOL" = MARINE POLLUTION)
RID:
THE REGULATIONS CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY
RAIL
UN: UNITED NATIONS
REFERENCES: NOT AVAILABLE
NOTICE TO READER:
UNLESS OTHERWISE SPECIFIED IN SECTION 1, MOMENTIVE PRODUCTS ARE INTENDED
FOR INDUSTRIAL APPLICATION ONLY. THEY ARE NOT INTENDED FOR SPECIFIC MEDICAL
APPLICATIONS, NEITHER FOR LONG-LASTING (>30 DAYS) IMPLANTATION INTO THE
HUMAN BODY, INJECTED OR DIRECTLY INGESTED, NOR FOR THE MANUFACTURE OF
MULTIPLE USABLE CONTRACEPTIVES KEEP OUT OF THE REACH OF CHILDREN.
FURTHER INFORMATION:
THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT TO THE BEST
OF OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS PUBLICATION.
THE INFORMATION GIVEN IS DESIGNED ONLY AS A GUIDANCE FOR SAFE HANDLING,
USE, PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE AND IS NOT
TO BE CONSIDERED A WARRANTY OR QUALITY SPECIFICATION. THE INFORMATION
RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR
SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY
PROCESS, UNLESS SPECIFIED IN THE TEXT.
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