| Common Name: | M90006-30 12C-CRTRG (0.707 LBS-0.321 KG) |
| Manufacturer: | MOMENTIVE AMER SEAL |
| SDS Revision Date: | 9/23/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 5PWD3 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
MOMENTIVE(TM)
INVENTING POSSIBILITIES
SAFETY DATA SHEET
FOR INDUSTRIAL USE ONLY
M90006-30 12C-CRTRG (0.707 LBS-0.321 KG)
| SECTION 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: M90006-30 12C-CRTRG (0.707 LBS-0.321 KG)
MANUFACTURER/IMPORTER/DISTRIBUTOR INFORMATION:
MOMENTIVE AMER SEAL.
260 HUDSON RIVER ROAD
WATERFORD NY 12188
CONTACT PERSON: COMMERCIAL.SERVICES@MOMENTIVE.COM
TELEPHONE:
GENERAL INFORMATION: +1-800-295-2392
EMERGENCY TELEPHONE NUMBER:
SUPPLIER:
CHEMTREC: 1-800-424-9300
| SECTION 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
SKIN CORROSION/IRRITATION: CATEGORY 2
TOXIC TO REPRODUCTION: CATEGORY 2
GHS LABEL ELEMENTS:
HAZARD PICTOGRAMS:
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: WARNING
HAZARD STATEMENTS:
H315: CAUSES SKIN IRRITATION.
H36: IF SUSPECTED OF DAMAGING FERTILITY.
PRECAUTIONARY STATEMENTS:
GENERAL: NOT APPLICABLE.
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED.
WEAR PROTECTIVE GLOVES.
WASH HANDS THOROUGHLY AFTER HANDLING.
RESPONSE:
IF EXPOSED OR CONCERNED: GET MEDICAL ATTENTION.
IF ON SKIN:
WASH WITH PLENTY OF SOAP AND WATER.
TAKE OFF CONTAMINATED CLOTHING.
WASH CONTAMINATED CLOTHING BEFORE REUSE.
IF SKIN IRRITATION OCCURS: GET MEDICAL ATTENTION.
STORAGE: STORE LOCKED UP.
DISPOSAL:
P501:
DISPOSE OF CONTENTS AND CONTAINER IN ACCORDANCE WITH ALL LOCAL, REGIONAL,
NATIONAL AND INTERNATIONAL REGULATIONS.
OTHER HAZARDS WHICH DO NOT RESULT IN CLASSIFICATION:
UNCURED PRODUCT IS IRRITATING TO EYES, SKIN, AND RESPIRATORY SYSTEM.
GENERATES ACETIC ACID DURING CURE. UNCURED PRODUCT IS IRRITATING TO EYES,
SKIN, AND RESPIRATORY SYSTEM. GENERATES ACETIC ACID DURING CURE.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE/MIXTURE: MIXTURE
CHEMICAL NAME: NOT AVAILABLE
HAZARDOUS INGREDIENTS % BY WEIGHT CAS NUMBER
SILANETRIOL, 1-METHYL-, 1,1,1-TRIACETATE 1 - 5 4253-34-3
OCTAMETHYLCYCLOTETRASILOXANE 0.1 - 1 556-67-2
THERE ARE NO ADDITIONAL INGREDIENTS PRESENT WHICH, WITHIN THE CURRENT
KNOWLEDGE OF THE SUPPLIER AND IN THE CONCENTRATIONS APPLICABLE, ARE
CLASSIFIED AS HAZARDOUS TO HEALTH OR THE ENVIRONMENT AND HENCE REQUIRE
REPORTING IN THIS SECTION.
OCCUPATIONAL EXPOSURE LIMITS, IF AVAILABLE, ARE LISTED IN SECTION 8.
| SECTION 4. FIRST AID MEASURES | |
DESCRIPTION OF NECESSARY FIRST AID MEASURES:
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER, OCCASIONALLY LIFTING THE UPPER
AND LOWER EYELIDS. CHECK FOR AND REMOVE ANY CONTACT LENSES. CONTINUE TO
RINSE FOR AT LEAST 10 MINUTES. GET MEDICAL ATTENTION.
INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. IF NOT BREATHING, IF BREATHING IS IRREGULAR OR IF RESPIRATORY
ARREST OCCURS, PROVIDE ARTIFICIAL RESPIRATION OR OXYGEN BY TRAINED
PERSONNEL. IT MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE
MOUTH-TO-MOUTH RESUSCITATION. GET MEDICAL ATTENTION. IF UNCONSCIOUS, PLACE
IN RECOVERY POSITION AND GET MEDICAL ATTENTION IMMEDIATELY. MAINTAIN AN
OPEN AIRWAY. LOOSEN TIGHT CLOTHING SUCH AS A COLLAR, TIE, BELT OR
WAISTBAND.
SKIN CONTACT:
FLUSH CONTAMINATED SKIN WITH PLENTY OF WATER. REMOVE CONTAMINATED CLOTHING
AND SHOES. CONTINUE TO RINSE FOR AT LEAST 10 MINUTES. GET MEDICAL
ATTENTION. WASH CLOTHING BEFORE REUSE. CLEAN SHOES THOROUGHLY BEFORE REUSE.
INGESTION:
WASH OUT MOUTH WITH WATER. REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN
A POSITION COMFORTABLE FOR BREATHING. IF MATERIAL HAS BEEN SWALLOWED AND
THE EXPOSED PERSON IS CONSCIOUS, GIVE SMALL QUANTITIES OF WATER TO DRINK.
DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL. IF
VOMITING OCCURS, THE HEAD SHOULD BE KEPT LOW SO THAT VOMIT DOES NOT ENTER
THE LUNGS. GET MEDICAL ATTENTION. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON. IF UNCONSCIOUS, PLACE IN RECOVERY POSITION AND GET
MEDICAL ATTENTION IMMEDIATELY. MAINTAIN AN OPEN AIRWAY. LOOSEN TIGHT
CLOTHING SUCH AS A COLLAR, TIE, BELT OR WAISTBAND.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED,
IF NECESSARY:
NOTES TO PHYSICIAN:
TREAT SYMPTOMATICALLY. CONTACT POISON TREATMENT SPECIALIST IMMEDIATELY IF
LARGE QUANTITIES HAVE BEEN INGESTED OR INHALED.
SPECIFIC TREATMENTS: NO SPECIFIC TREATMENT.
PROTECTION OF FIRST AID PERSONNEL:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. IT MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE
MOUTH-TO-MOUTH RESUSCITATION.
SEE TOXICOLOGICAL INFORMATION (SECTION 11)
| SECTION 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE DRY CHEMICAL, CO2, ALCOHOL-RESISTANT FOAM OR WATER SPRAY (FOG).
UNSUITABLE EXTINGUISHING MEDIA: WATER JET
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
IN A FIRE OR IF HEATED, A PRESSURE INCREASE WILL OCCUR AND THE CONTAINER
MAY BURST.
HAZARDOUS THERMAL DECOMPOSITION PRODUCTS:
MEASUREMENTS AT TEMPERATURES ABOVE 150 DEG. C IN PRESENCE OF AIR (OXYGEN)
HAVE SHOWN THAT SMALL AMOUNTS OF FORMALDEHYDE ARE FORMED DUE TO OXIDATIVE
DEGRADATION.
SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
PROMPTLY ISOLATE THE SCENE BY REMOVING ALL PERSONS FROM THE VICINITY OF
THE INCIDENT IF THERE IS A FIRE. NO ACTION SHALL BE TAKEN INVOLVING ANY
PERSONAL RISK OR WITHOUT SUITABLE TRAINING. USE WATER SPRAY TO KEEP
FIRE-EXPOSED CONTAINERS COOL. FIRE WATER CONTAMINATED WITH THIS MATERIAL
MUST BE CONTAINED AND PREVENTED FROM BEING DISCHARGED TO ANY WATERWAY,
SEWER OR DRAIN.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
FIRE-FIGHTERS SHOULD WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND
SELF-CONTAINED BREATHING APPARATUS (SCBA) WITH A FULL FACE-PIECE OPERATED
IN POSITIVE PRESSURE MODE. FIREFIGHTERS MUST WEAR NIOSH/MSHA APPROVED
POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS WITH FULL FACE MASK
AND FULL PROTECTIVE CLOTHING.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
FOR NON-EMERGENCY PERSONNEL:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. EVACUATE SURROUNDING AREAS. KEEP UNNECESSARY AND UNPROTECTED
PERSONNEL FROM ENTERING. DO NOT TOUCH OR WALK THROUGH SPILLED MATERIAL.
AVOID BREATHING VAPOR OR MIST. PROVIDE ADEQUATE VENTILATION. WEAR
APPROPRIATE RESPIRATOR WHEN VENTILATION IS INADEQUATE. PUT ON APPROPRIATE
PERSONAL PROTECTIVE EQUIPMENT.
FOR EMERGENCY RESPONDERS:
IF SPECIALISED CLOTHING IS REQUIRED TO DEAL WITH THE SPILLAGE, TAKE NOTE
OF ANY INFORMATION IN SECTION 8 ON SUITABLE AND UNSUITABLE MATERIALS. SEE
ALSO THE INFORMATION IN "FOR NON-EMERGENCY PERSONNEL".
ENVIRONMENTAL PRECAUTIONS:
AVOID DISPERSAL OF SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL,
WATERWAYS, DRAINS AND SEWERS. INFORM THE RELEVANT AUTHORITIES IF THE
PRODUCT HAS CAUSED ENVIRONMENTAL POLLUTION (SEWERS, WATERWAYS, SOIL OR
AIR).
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
SMALL SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. DILUTE WITH
WATER AND MOP UP IF WATER-SOLUBLE. ALTERNATIVELY, OR IF WATER-INSOLUBLE,
ABSORB WITH AN INERT DRY MATERIAL AND PLACE IN AN APPROPRIATE WASTE
DISPOSAL CONTAINER.
NOTE:
SEE SECTION 1 OF SDS FOR EMERGENCY CONTACT INFORMATION AND SECTION 13 OF
SDS FOR WASTE DISPOSAL.
LARGE SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. APPROACH
RELEASE FROM UPWIND. PREVENT ENTRY INTO SEWERS, WATER COURSES, BASEMENTS
OR CONFINED AREAS. WASH SPILLAGES INTO AN EFFLUENT TREATMENT PLANT OR
PROCEED AS FOLLOWS. CONTAIN AND COLLECT SPILLAGE WITH NON-COMBUSTIBLE,
ABSORBENT MATERIAL E.G. SAND, EARTH, VERMICULITE OR DIATOMACEOUS EARTH
AND PLACE IN CONTAINER FOR DISPOSAL ACCORDING TO LOCAL REGULATIONS
(SEE SECTION 13 OF SDS). DISPOSE OF VIA A LICENSED WASTE DISPOSAL
CONTRACTOR. CONTAMINATED ABSORBENT MATERIAL MAY POSE THE SAME HAZARD AS
THE SPILLED PRODUCT.
NOTE:
SEE SECTION 1 OF SDS FOR EMERGENCY CONTACT INFORMATION AND SECTION 13 OF
SDS FOR WASTE DISPOSAL.
| SECTION 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
PROTECTIVE MEASURES:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8 OF SDS).
AVOID EXPOSURE - OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. AVOID EXPOSURE
DURING PREGNANCY. DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ
AND UNDERSTOOD. DO NOT INGEST. AVOID CONTACT WITH EYES, SKIN AND CLOTHING.
AVOID BREATHING VAPOR OR MIST. USE ONLY WITH ADEQUATE VENTILATION. KEEP IN
THE ORIGINAL CONTAINER OR AN APPROVED ALTERNATIVE MADE FROM A COMPATIBLE
MATERIAL, KEPT TIGHTLY CLOSED WHEN NOT IN USE. EMPTY CONTAINERS RETAIN
PRODUCT RESIDUE AND CAN BE HAZARDOUS.
ADVICE ON GENERAL OCCUPATIONAL HYGIENE:
EATING, DRINKING AND SMOKING SHOULD BE PROHIBITED IN AREAS WHERE THIS
MATERIAL IS HANDLED, STORED AND PROCESSED. WORKERS SHOULD WASH HANDS AND
FACE BEFORE EATING, DRINKING AND SMOKING. SEE ALSO SECTION 8 FOR ADDITIONAL
INFORMATION ON HYGIENE MEASURES.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE IN ACCORDANCE WITH LOCAL REGULATIONS. STORE IN ORIGINAL CONTAINER
PROTECTED FROM DIRECT SUNLIGHT IN A DRY, COOL AND WELL-VENTILATED AREA,
AWAY FROM INCOMPATIBLE MATERIALS (SEE SECTION 10 OF SDS) AND FOOD AND
DRINK. STORE LOCKED UP. KEEP CONTAINER TIGHTLY CLOSED AND SEALED UNTIL
READY FOR USE. CONTAINERS THAT HAVE BEEN OPENED MUST BE CAREFULLY RESEALED
AND KEPT UPRIGHT TO PREVENT LEAKAGE. DO NOT STORE IN UNLABELED CONTAINERS.
USE APPROPRIATE CONTAINMENT TO AVOID ENVIRONMENTAL CONTAMINATION.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
INGREDIENT NAME EXPOSURE LIMITS
OCTAMETHYLCYCLOTETRASILOXANE ()
RECOMMENDED EXPOSURE LIMIT (REL): 5 PPM
APPROPRIATE ENGINEERING CONTROLS:
IF USER OPERATIONS GENERATE DUST, FUMES, GAS, VAPOR OR MIST, USE PROCESS
ENCLOSURES, LOCAL EXHAUST VENTILATION OR OTHER ENGINEERING CONTROLS TO
KEEP WORKER EXPOSURE TO AIRBORNE CONTAMINANTS BELOW ANY RECOMMENDED OR
STATUTORY LIMITS.
ENVIRONMENTAL EXPOSURE CONTROLS:
EMISSIONS FROM VENTILATION OR WORK PROCESS EQUIPMENT SHOULD BE CHECKED
TO ENSURE THEY COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION
LEGISLATION. IN SOME CASES, FUME SCRUBBERS, FILTERS OR ENGINEERING
MODIFICATIONS TO THE PROCESS EQUIPMENT WILL BE NECESSARY TO REDUCE
EMISSIONS TO ACCEPTABLE LEVELS.
INDIVIDUAL PROTECTION MEASURES:
HYGIENE MEASURES:
WASH HANDS, FOREARMS AND FACE THOROUGHLY AFTER HANDLING CHEMICAL PRODUCTS,
BEFORE EATING, SMOKING AND USING THE LAVATORY AND AT THE END OF THE WORKING
PERIOD. APPROPRIATE TECHNIQUES SHOULD BE USED TO REMOVE POTENTIALLY
CONTAMINATED CLOTHING. WASH CONTAMINATED CLOTHING BEFORE REUSING. ENSURE
THAT EYEWASH STATIONS AND SAFETY SHOWERS ARE CLOSE TO THE WORKSTATION
LOCATION.
EYE/FACE PROTECTION:
SAFETY EYEWEAR COMPLYING WITH AN APPROVED STANDARD SHOULD BE USED WHEN A
RISK ASSESSMENT INDICATES THIS IS NECESSARY TO AVOID EXPOSURE TO LIQUID
SPLASHES, MISTS, GASES OR DUSTS. IF CONTACT IS POSSIBLE, THE FOLLOWING
PROTECTION SHOULD BE WORN, UNLESS THE ASSESSMENT INDICATES A HIGHER DEGREE
OF PROTECTION: CHEMICAL SPLASH GOGGLES.
SKIN PROTECTION:
HAND PROTECTION:
CHEMICAL-RESISTANT, IMPERVIOUS GLOVES COMPLYING WITH AN APPROVED STANDARD
SHOULD BE WORN AT ALL TIMES WHEN HANDLING CHEMICAL PRODUCTS IF A RISK
ASSESSMENT INDICATES THIS IS NECESSARY. CONSIDERING THE PARAMETERS
SPECIFIED BY THE GLOVE MANUFACTURER, CHECK DURING USE THAT THE GLOVES ARE
STILL RETAINING THEIR PROTECTIVE PROPERTIES. IT SHOULD BE NOTED THAT THE
TIME TO BREAKTHROUGH FOR ANY GLOVE MATERIAL MAY BE DIFFERENT FOR DIFFERENT
GLOVE MANUFACTURERS. IN THE CASE OF MIXTURES, CONSISTING OF SEVERAL
SUBSTANCES, THE PROTECTION TIME OF THE GLOVES CANNOT BE ACCURATELY
ESTIMATED.
BODY PROTECTION:
PERSONAL PROTECTIVE EQUIPMENT FOR THE BODY SHOULD BE SELECTED BASED ON THE
TASK BEING PERFORMED AND THE RISKS INVOLVED AND SHOULD BE APPROVED BY A
SPECIALIST BEFORE HANDLING THIS PRODUCT.
OTHER SKIN PROTECTION:
APPROPRIATE FOOTWEAR AND ANY ADDITIONAL SKIN PROTECTION MEASURES SHOULD
BE SELECTED BASED ON THE TASK BEING PERFORMED AND THE RISKS INVOLVED AND
SHOULD BE APPROVED BY A SPECIALIST BEFORE HANDLING THIS PRODUCT.
RESPIRATORY PROTECTION:
USE A PROPERLY FITTED, AIR-PURIFYING OR AIR-FED RESPIRATOR COMPLYING WITH
AN APPROVED STANDARD IF A RISK ASSESSMENT INDICATES THIS IS NECESSARY.
RESPIRATOR SELECTION MUST BE BASED ON KNOWN OR ANTICIPATED EXPOSURE LEVELS,
THE HAZARDS OF THE PRODUCT AND THE SAFE WORKING LIMITS OF THE SELECTED
RESPIRATOR. IF EXPOSURE LIMITS ARE EXCEEDED OR RESPIRATORY IRRITATION IS
EXPERIENCED, NIOSH/MSHA APPROVED RESPIRATORY PROTECTION SHOULD BE WORN.
SUPPLIED AIR RESPIRATORS MAY BE REQUIRED FOR NON-ROUTINE OR EMERGENCY
SITUATIONS. RESPIRATORY PROTECTION MUST BE PROVIDED IN ACCORDANCE WITH
OSHA REGULATIONS (SEE 29 CFR 1910.134).
RESPIRATOR SELECTION MUST BE BASED ON KNOWN OR ANTICIPATED EXPOSURE LEVELS,
THE HAZARDS OF THE PRODUCT AND THE SAFE WORKING LIMITS OF THE SELECTED
RESPIRATOR.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: PASTE
COLOR: COLORLESS.
ODOR: ACETIC ACID.
ODOR THRESHOLD: NOT AVAILABLE
PH: NOT APPLICABLE.
MELTING POINT: NOT AVAILABLE
BOILING POINT: NOT AVAILABLE
FLASH POINT: 94 DEG. C (201.20 DEG. F) (ESTIMATED.)
BURNING TIME: NOT AVAILABLE
BURNING RATE: NOT AVAILABLE
EVAPORATION RATE: NOT AVAILABLE
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE
LOWER AND UPPER EXPLOSIVE (FLAMMABLE) LIMITS:
LOWER: NOT APPLICABLE.
UPPER: NOT APPLICABLE.
VAPOR PRESSURE: NOT APPLICABLE.
VAPOR DENSITY: NOT AVAILABLE
RELATIVE DENSITY: 1.04
DENSITY: 1.04 G/CM3
SOLUBILITY: INSOLUBLE
SOLUBILITY IN WATER: INSOLUBLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NOT AVAILABLE
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE
DECOMPOSITION TEMPERATURE: NOT AVAILABLE
SADT: NOT AVAILABLE
VISCOSITY:
DYNAMIC: NOT AVAILABLE
KINEMATIC: NOT AVAILABLE
VOLATILE ORGANIC CONTENT:
3.1% (W/W)
36 G/L
OTHER INFORMATION: NO ADDITIONAL INFORMATION.
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY: STABLE UNDER NORMAL CONDITIONS.
CHEMICAL STABILITY: THE PRODUCT IS STABLE.
POSSIBILITY OF HAZARDOUS REACTIONS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS REACTIONS WILL NOT
OCCUR.
CONDITIONS TO AVOID: NO SPECIFIC DATA.
INCOMPATIBLE MATERIALS: NO SPECIFIC DATA.
HAZARDOUS DECOMPOSITION PRODUCTS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS DECOMPOSITION
PRODUCTS SHOULD NOT BE PRODUCED.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
PRODUCT/INGREDIENT NAME RESULT SPECIES DOSE EXPOSURE
OCTAMETHYLCYCLO- LD50 ORAL RAT 4,800 MG/KG
TETRASILOXANE OECD-GUIDELINE
401 (ACUTE
ORAL TOXICITY)
LC50 RAT >12.1 MG/L 4 H
INHALATION
LC50 RAT 36 MG/L OECD 4 H
INHALATION TEST GUIDELINE
403
LD50 DERMAL RAT >2,400 MG/KG
OECD TEST
GUIDELINE 402
CONCLUSION/SUMMARY: NOT DETERMINED
IRRITATION/CORROSION:
PRODUCT/INGREDIENT RESULT SPECIES SCORE EXPOSURE OBSERVATION
NAME
PRODUCT TOXICOLOGICAL SKIN RABBIT
DATA MODERATE
IRRITANT
OECD-
GUIDELINE
404 (ACUTE
DERMAL
IRRITATION/
CORROSION)
REMARKS: CLASSIFICATION ACCORDING TO TEST STUDY DATA OF A SIMILAR PRODUCT.
EYES - MILD RABBIT
IRRITANT
OECD-
GUIDELINE
405 (ACUTE
EYE
IRRITATION/
CORROSION)
REMARKS: CLASSIFICATION ACCORDING TO TEST STUDY DATA OF A SIMILAR PRODUCT.
OCTAMETHYLCYCLOTETRA- SKIN RAT
SILOXANE OECD-
GUIDELINE
404 (ACUTE
DERMAL
IRRITATION/
CORROSION)
REMARKS: NON-IRRITATING TO THE SKIN.
EYES RABBIT
OECD-
GUIDELINE
405 (ACUTE
EYE
IRRITATION/
CORROSION)
REMARKS: NON-IRRITATING TO THE EYES.
CONCLUSION/SUMMARY:
SKIN: MODERATE IRRITANT
EYES: MILD IRRITANT
RESPIRATORY: NOT DETERMINED
SENSITIZATION:
PRODUCT/INGREDIENT NAME ROUTE OF SPECIES RESULT
EXPOSURE
OCTAMETHYLCYCLOTETRASILOXANE GUINEA PIG NOT SENSITIZING
OECD-GUIDELINE
406 (SKIN
SENSITISATION)
CONCLUSION/SUMMARY:
SKIN: NOT DETERMINED
RESPIRATORY: NOT DETERMINED
MUTAGENICITY:
PRODUCT/INGREDIENT NAME TEST EXPERIMENT RESULT
OCTAMETHYLCYCLOTETRASILOXANE OECD-GUIDELINE 471 IN VITRO NEGATIVE
(GENETIC TOXICOLOGY:
SALMONELLA
TYPHIMURIUM, REVERSE
MUTATION ASSAY)
MOUSE LYMPHOMA ASSAY IN VITRO NEGATIVE
(OECD GUIDLINE 476)
OECD-GUIDELINE 474 IN VIVO NEGATIVE
(GENETIC TOXICOLOGY:
MICRONUCLEUS TEST)
CONCLUSION/SUMMARY: NOT DETERMINED
CARCINOGENICITY:
PRODUCT/INGREDIENT RESULT SPECIES DOSE EXPOSURE
NAME
OCTAMETHYLCYCLOTETRA- INHALATION - RAT - FEMALE 150 MG/KG 24 MONTHS
SILOXANE OECD 453
REMARKS: NOAEC
INHALATION - RAT - MALE >700 MG/KG 24 MONTHS
OECD 453
REMARKS: NOAEC
CONCLUSION/SUMMARY: NOT DETERMINED
REPRODUCTIVE TOXICITY:
PRODUCT/ MATERNAL FERTILITY DEVELOPMENT SPECIES DOSE EXPOSURE
INGREDIENT TOXICITY TOXIN
NAME
OCTAMETHYL- RAT INHALA-
CYCLOTETRA- TION:
SILOXANE 300 MG/KG
OECD 416
REMARKS: NOAEL PARENTS
RAT INHALA-
TION:
300 MG/KG
OECD 416
REMARKS: NOAEL F1
CONCLUSION/SUMMARY: NOT DETERMINED
TERATOGENICITY:
PRODUCT/INGREDIENT NAME RESULT SPECIES DOSE EXPOSURE
OCTAMETHYLCYCLOTETRASILOXANE INHALATION RABBIT 500 MG/KG 18 DAYS
OECD TEST
GUIDELINE
414
REMARKS: NOAEL
INHALATION RABBIT 300 MG/KG 18 DAYS
OECD TEST
GUIDELINE
414
REMARKS: NOAEL MATERNITY
CONCLUSION/SUMMARY: NOT DETERMINED
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE):
PRODUCT/INGREDIENT NAME CATEGORY ROUTE OF EXPOSURE TARGET ORGANS
SILANETRIOL, 1-METHYL-, CATEGORY 3 RESPIRATORY
1,1,1-TRIACETATE TRACT IRRITATION
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): NOT AVAILABLE
ASPIRATION HAZARD: NOT AVAILABLE
INFORMATION ON THE LIKELY ROUTES OF EXPOSURE: NOT AVAILABLE
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INHALATION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SKIN CONTACT: CAUSES SKIN IRRITATION.
INGESTION: IRRITATING TO MOUTH, THROAT AND STOMACH.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN OR IRRITATION
WATERING
REDNESS
INHALATION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
IRRITATION
REDNESS
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
INGESTION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
DELAYED AND IMMEDIATE EFFECTS AND ALSO CHRONIC EFFECTS FROM SHORT AND LONG
TERM EXPOSURE:
SHORT TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE
LONG TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE
POTENTIAL CHRONIC HEALTH EFFECTS:
PRODUCT/INGREDIENT NAME RESULT SPECIES DOSE EXPOSURE
OCTAMETHYLCYCLOTETRASILOXANE NOAEC RAT 150 MG/KG 24 MONTHS
INHALATION OECD 453
REMARKS: NOAEC
NOAEL RABBIT >1 MG/KG 3 WEEKS
DERMAL OECD 410
REMARKS: NOAEL
CONCLUSION/SUMMARY: NOT DETERMINED
GENERAL: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
CARCINOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
MUTAGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
TERATOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
DEVELOPMENTAL EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
FERTILITY EFFECTS: SUSPECTED OF DAMAGING FERTILITY.
NUMERICAL MEASURES OF TOXICITY:
ACUTE TOXICITY ESTIMATES:
ROUTE ATE VALUE
ORAL 16,517.8 MG/KG
OTHER INFORMATION:
OCTAMETHYLCYCLOTETRASILOXANE (D4) INGESTION:
RODENTS GIVEN LARGE DOSES VIA ORAL GAVAGE OF OCTAMETHYLCYCLOTETRASILOXANE
(1600 MG/KG/DAY, 14 DAYS), DEVELOPED INCREASED LIVER WEIGHTS RELATIVE TO
UNEXPOSED CONTROL ANIMALS DUE TO HEPATOCELLULAR HYPERPLASIA (INCREASED
NUMBER OF LIVER CELLS WHICH APPEAR NORMAL) AS WELL AS HYPERTROPHY
(INCREASED CELL SIZE).
INHALATION:
IN INHALATION STUDIES, LABORATORY RODENTS EXPOSED TO
OCTAMETHYLCYCLOTETRASILOXANE (300 PPM FIVE DAYS/WEEK, 90 DAYS) DEVELOPED
INCREASED LIVER WEIGHTS IN FEMALE ANIMALS RELATIVE TO UNEXPOSED CONTROL
ANIMALS. WHEN THE EXPOSURE WAS STOPPED, LIVER WEIGHTS RETURNED TO NORMAL.
MICROSCOPIC EXAMINATION OF THE LIVER CELLS DID NOT SHOW ANY EVIDENCE OF
PATHOLOGY. THIS RESPONSE IN RATS, WHICH DOES NOT AFFECT THE ANIMAL'S
HEALTH, IS WELL-DOCUMENTED AND WIDELY RECOGNIZED. IT IS RELATED TO AN
INCREASE OF LIVER ENZYMES THAT METABOLIZE AND ELIMINATE A MATERIAL FROM
THE BODY. THE INCREASED LIVER WEIGHT REVERSES EVEN WHILE THE D4 EXPOSURE
CONTINUES. THE FINDING IS NOT ADVERSE, BUT IS CONSIDERED A NATURAL
ADAPTIVE CHANGE IN RATS, AND DOES NOT REPRESENT A HAZARD TO HUMANS.
INHALATION STUDIES UTILIZING LABORATORY RABBITS AND GUINEA PIGS SHOWED NO
EFFECTS ON LIVER WEIGHTS. INHALATION EXPOSURES TYPICAL OF INDUSTRIAL USAGE
(5-10 PPM) SHOWED NO TOXIC EFFECTS IN RODENTS. RANGE FINDING REPRODUCTIVE
STUDIES WERE CONDUCTED (WHOLE BODY INHALATION, 70 DAYS PRIOR TO MATING,
THROUGH MATING, GESTATION AND LACTATION), WITH D4. RATS WERE EXPOSED TO
70 AND 700 PPM. IN THE 700 PPM GROUP, THERE WAS A STATISTICALLY SIGNIFICANT
REDUCTION IN MEAN LITTER SIZE AND IN IMPLANTATION SITES. NO D4 RELATED
CLINICAL SIGNS WERE OBSERVED IN THE PUPS AND NO EXPOSURE RELATED
PATHOLOGICAL FINDINGS WERE FOUND. A TWO-YEAR, COMBINED
CHRONIC/CARCINOGENICITY STUDY, DURING WHICH RATS WERE EXPOSED TO D4 BY
INHALATION, DATA SHOWED A STATISTICALLY SIGNIFICANT INCREASE IN A BENIGN
UTERINE TUMOR IN FEMALE RATS EXPOSED AT THE HIGHEST LEVEL-A LEVEL MUCH
HIGHER THAN THE LOW LEVELS THAT CONSUMERS OR WORKERS MAY ENCOUNTER. AN
EXPERT PANEL OF INDEPENDENT SCIENTISTS WHO HAVE REVIEWED THE RESULTS OF
THIS RESEARCH CONCUR THAT THE FINDING SEEN IN THE TWO-YEAR STUDY OCCURRED
THROUGH A BIOLOGICAL PATHWAY THAT IS SPECIFIC TO THE RAT AND IS NOT
RELEVANT TO HUMANS. THEREFORE, THIS OBSERVED EFFECT DOES NOT INDICATE A
POTENTIAL HEALTH HAZARD TO HUMANS. IN DEVELOPMENTAL TOXICITY STUDIES, RATS
AND RABBITS WERE EXPOSED TO D4 AT CONCENTRATIONS UP TO 700 PPM AND 500 PPM,
RESPECTIVELY. NO TERATOGENIC EFFECTS (BIRTH DEFECTS) WERE OBSERVED IN
EITHER STUDY.
| SECTION 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
CONCLUSION/SUMMARY: NOT AVAILABLE
PERSISTENCE/DEGRADABILITY:
PRODUCT/INGREDIENT NAME TEST RESULT DOSE INOCULUM
OCTAMETHYLCYCLOTETRA- 310 READY 3.7% - 29 D ACTIVATED
SILOXANE BIODEGRADABILITY SLUDGE
- CO2 IN SEALED
VESSELS
(HEADSPACE TEST)
REMARKS: NOT READILY BIODEGRADABLE.
CONCLUSION/SUMMARY: NOT AVAILABLE
BIOACCUMULATIVE POTENTIAL:
PRODUCT/INGREDIENT NAME SPECIES EXPOSURE LOGPOW BCF POTENTIAL
OCTAMETHYLCYCLOTETRA- FATHEAD 28 D 12.40 LOW
SILOXANE MINNOW
MOBILITY IN SOIL:
SOIL/WATER PARTITION COEFFICIENT (KOC): NOT AVAILABLE
OTHER ADVERSE EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
OTHER INFORMATION:
OCTAMETHYLCYCLOTETRASILOXANE (D4) MEETS THE CURRENT REACH ANNEX XIII
CRITERIA FOR PBT AND VPVB. HOWEVER, D4 DOES NOT BEHAVE SIMILARLY TO KNOWN
PBT/VPVB SUBSTANCES. THE SILICONES INDUSTRIES INTERPRETATION OF THE
AVAILABLE DATA IS THAT THE WEIGHT OF SCIENTIFIC EVIDENCE FROM FIELD STUDIES
SHOWS THAT D4 IS NOT BIOMAGNIFYING IN AQUATIC AND TERRESTRIAL FOOD WEBS.
D4 IN AIR WILL DEGRADE BY REACTION WITH NATURALLY OCCURRING HYDROXYL
RADICALS IN THE ATMOSPHERE. ANY D4 IN AIR THAT DOES NOT DEGRADE BY REACTION
WITH HYDROXYL RADICALS IS NOT EXPECTED TO DEPOSIT FROM THE AIR TO WATER,
TO LAND, OR TO LIVING ORGANISMS.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
THE GENERATION OF WASTE SHOULD BE AVOIDED OR MINIMIZED WHEREVER POSSIBLE.
DISPOSAL OF THIS PRODUCT, SOLUTIONS AND ANY BY-PRODUCTS SHOULD AT ALL TIMES
COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION AND WASTE DISPOSAL
LEGISLATION AND ANY REGIONAL LOCAL AUTHORITY REQUIREMENTS. DISPOSE OF
SURPLUS AND NON-RECYCLABLE PRODUCTS VIA A LICENSED WASTE DISPOSAL
CONTRACTOR. WASTE SHOULD NOT BE DISPOSED OF UNTREATED TO THE SEWER UNLESS
FULLY COMPLIANT WITH THE REQUIREMENTS OF ALL AUTHORITIES WITH JURISDICTION.
WASTE PACKAGING SHOULD BE RECYCLED. INCINERATION OR LANDFILL SHOULD ONLY
BE CONSIDERED WHEN RECYCLING IS NOT FEASIBLE. THIS MATERIAL AND ITS
CONTAINER MUST BE DISPOSED OF IN A SAFE WAY. CARE SHOULD BE TAKEN WHEN
HANDLING EMPTIED CONTAINERS THAT HAVE NOT BEEN CLEANED OR RINSED OUT. EMPTY
CONTAINERS OR LINERS MAY RETAIN SOME PRODUCT RESIDUES. AVOID DISPERSAL OF
SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL, WATERWAYS, DRAINS AND
SEWERS. SEE SECTION 8 FOR INFORMATION ON APPROPRIATE PERSONAL PROTECTIVE
EQUIPMENT.
| SECTION 14. TRANSPORT INFORMATION | |
SPECIAL PRECAUTIONS FOR USER:
THIS PRODUCT IS NOT REGARDED AS DANGEROUS GOODS ACCORDING TO THE NATIONAL
AND INTERNATIONAL REGULATIONS ON THE TRANSPORT OF DANGEROUS GOODS.
| SECTION 15. REGULATORY INFORMATION | |
UNITED STATES:
U.S. FEDERAL REGULATIONS:
UNITED STATES - TSCA 12(B) - CHEMICAL EXPORT NOTIFICATION:
ONE TIME NOTIFICATION CYCLOTETRASILOXANE, 2,2,4,4,6,6,8,8-OCTAMETHYL-
UNITED STATES - TSCA 5(A)2 - FINAL SIGNIFICANT NEW USE RULES: NOT LISTED
UNITED STATES - TSCA 5(A)2 - PROPOSED SIGNIFICANT NEW USE RULES: NOT LISTED
UNITED STATES - TSCA 5(E) - SUBSTANCES CONSENT ORDER: NOT LISTED
SARA 311/312:
CLASSIFICATION:
IMMEDIATE (ACUTE) HEALTH HAZARD
DELAYED (CHRONIC) HEALTH HAZARD
CALIFORNIA PROP. 65: NONE REQUIRED.
CANADA:
WHMIS (CANADA):
CLASS D-2A: MATERIAL CAUSING OTHER TOXIC EFFECTS (VERY TOXIC).
CLASS D-2B: MATERIAL CAUSING OTHER TOXIC EFFECTS (TOXIC).
INTERNATIONAL REGULATIONS:
INTERNATIONAL LISTS:
AUSTRALIA INVENTORY (AICS): ALL COMPONENTS ARE LISTED OR EXEMPTED.
CANADA INVENTORY:
AT LEAST ONE COMPONENT IS NOT LISTED IN DSL BUT ALL SUCH COMPONENTS ARE
LISTED IN NDSL. (QUANTITY RESTRICTED)
JAPAN INVENTORY: NOT DETERMINED.
CHINA INVENTORY (IECSC): ALL COMPONENTS ARE LISTED OR EXEMPTED.
KOREA INVENTORY: ALL COMPONENTS ARE LISTED OR EXEMPTED.
NEW ZEALAND INVENTORY (NZIOC): NOT DETERMINED.
PHILIPPINES INVENTORY (PICCS): ALL COMPONENTS ARE LISTED OR EXEMPTED.
UNITED STATES INVENTORY (TSCA 8B): ALL COMPONENTS ARE LISTED OR EXEMPTED.
TAIWAN INVENTORY (CSNN): NOT DETERMINED.
| SECTION 16. OTHER INFORMATION | |
LABEL REQUIREMENTS:
CAUSES SKIN IRRITATION. CONTAINS OCTAMETHYLCYCLOTETRASILOXANE WHICH MAY
CAUSE REPRODUCTIVE EFFECTS BASED ON ANIMAL DATA.
HAZARDOUS MATERIAL INFORMATION SYSTEM III (U.S.A.):
HEALTH 1
FLAMMABILITY 1
PHYSICAL HAZARDS 0
CAUTION:
HMIS(R*) RATINGS ARE BASED ON A 0-4 RATING SCALE, WITH 0 REPRESENTING
MINIMAL HAZARDS OR RISKS, AND 4 REPRESENTING SIGNIFICANT HAZARDS OR RISKS
ALTHOUGH HMIS(R*) RATINGS ARE NOT REQUIRED ON MSDSS UNDER 29 CFR
1910.1200, THE PREPARER MAY CHOOSE TO PROVIDE THEM. HMIS(R*) RATINGS ARE
TO BE USED WITH A FULLY IMPLEMENTED HMIS(R*) PROGRAM. HMIS(R*) IS A
REGISTERED MARK OF THE NATIONAL PAINT & COATINGS ASSOCIATION (NPCA).
HMIS(R*) MATERIALS MAY BE PURCHASED EXCLUSIVELY FROM J. J. KELLER
(800) 327-6868.
THE CUSTOMER IS RESPONSIBLE FOR DETERMINING THE PPE CODE FOR THIS MATERIAL.
FULL TEXT OF ABBREVIATED H STATEMENTS: NOT APPLICABLE.
HISTORY:
DATE OF PRINTING: 04/07/2016
DATE OF ISSUE/DATE OF REVISION: 09/23/2015
DATE OF PREVIOUS ISSUE: 05/19/2015
VERSION: 1.5
PREPARED BY: PRODUCT SAFETY STEWARDSHIP
KEY TO ABBREVIATIONS:
ATE: ACUTE TOXICITY ESTIMATE
BCF: BIOCONCENTRATION FACTOR
GHS:
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELLING OF CHEMICALS
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
IBC: INTERMEDIATE BULK CONTAINER
IMDG: INTERNATIONAL MARITIME DANGEROUS GOODS
LOGPOW: LOGARITHM OF THE OCTANOL/WATER PARTITION COEFFICIENT
MARPOL 73/78:
INTERNATIONAL CONVENTION FOR THE PREVENTION OF POLLUTION FROM SHIPS, 1973
AS MODIFIED BY THE PROTOCOL OF 1978. ("MARPOL" = MARINE POLLUTION)
RID:
THE REGULATIONS CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS
BY RAIL
UN: UNITED NATIONS
REFERENCES: NOT AVAILABLE
NOTICE TO READER:
UNLESS OTHERWISE SPECIFIED IN SECTION 1, MOMENTIVE PRODUCTS ARE INTENDED
FOR INDUSTRIAL APPLICATION ONLY. THEY ARE NOT INTENDED FOR SPECIFIC MEDICAL
APPLICATIONS, NEITHER FOR LONG-LASTING (>30 DAYS) IMPLANTATION INTO THE
HUMAN BODY, INJECTED OR DIRECTLY INGESTED, NOR FOR THE MANUFACTURE OF
MULTIPLE USABLE CONTRACEPTIVES KEEP OUT OF THE REACH OF CHILDREN.
FURTHER INFORMATION:
THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT TO THE BEST
OF OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS PUBLICATION.
THE INFORMATION GIVEN IS DESIGNED ONLY AS A GUIDANCE FOR SAFE HANDLING,
USE, PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE AND IS NOT
TO BE CONSIDERED A WARRANTY OR QUALITY SPECIFICATION. THE INFORMATION
RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR
SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY
PROCESS, UNLESS SPECIFIED IN THE TEXT.