| Common Name: | LOCTITE MR FLEX 80 KNOWN AS LOCTITE FIXMASTER FLEX 80 PUTTY, 97423_30012000, 702 |
| Manufacturer: | HENKEL |
| SDS Revision Date: | 6/7/2016 |
| SDS Format: | GHS-US |
| Item Number(s): | 5TT78 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
HENKEL
REVISION NUMBER: 006.1
ISSUE DATE: 06/07/2016
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: LOCTITE MR FLEX 80 KNOWN AS LOCTITE FIXMASTER FLEX 80 PUTTY
IDH NUMBER: 702234
PRODUCT TYPE: POLYURETHANE ADHESIVE
ITEM NUMBER: 97423_30012000
RESTRICTION OF USE: NONE IDENTIFIED
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: +1 (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
DANGER:
CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE IRRITATION.
FATAL IF INHALED.
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
HAZARD CLASS HAZARD CATEGORY
ACUTE TOXICITY INHALATION 2
SKIN IRRITATION 2
EYE IRRITATION 2A
RESPIRATORY SENSITIZATION 1
SKIN SENSITIZATION 1
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE 1
PICTOGRAM(S):
SKULLS AND CROSSBONES
HEALTH HAZARD
PRECAUTIONARY STATEMENTS:
PREVENTION:
DO NOT BREATHE VAPORS, MIST, OR SPRAY. WASH AFFECTED AREA THOROUGHLY AFTER
HANDLING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. USE ONLY
OUTDOORS OR IN A WELL-VENTILATED AREA. CONTAMINATED WORK CLOTHING SHOULD
NOT BE ALLOWED OUT OF THE WORKPLACE. WEAR PROTECTIVE GLOVES, EYE
PROTECTION, AND FACE PROTECTION. [IN CASE OF INADEQUATE VENTILATION] WEAR
RESPIRATORY PROTECTION.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ATTENTION.
IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION.
IF EXPERIENCING RESPIRATORY SYMPTOMS:
CALL A POISON CENTER OR PHYSICIAN. TAKE OFF CONTAMINATED CLOTHING.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE
LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL,
STATE/PROVINCIAL AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED NATIONS
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
(GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
POLYURETHANE PREPOLYMER PROPRIETARY 60 - 100
DICYCLOHEXYLMETHANE-4,4'-DIISOCYANATE 5124-30-1 10 - 30
METHYLENEBIS(PHENYLISOCYANATE) 101-68-8 1 - 5
POLYMERIC DIPHENYLMETHANE DIISOCYANATE 9016-87-9 1 - 5
* EXACT PERCENTAGE IS A TRADE SECRET. CONCENTRATION RANGE IS PROVIDED
TO ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. ASTHMATIC-TYPE SYMPTOMS MAY DEVELOP
AND MAY BE IMMEDIATE OR DELAYED UP TO SEVERAL HOURS. GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER (USING SOAP, IF AVAILABLE).
REMOVE CONTAMINATED CLOTHING AND FOOTWEAR. FOR SEVERE EXPOSURES, GET UNDER
SAFETY SHOWER AFTER REMOVING CLOTHING, THEN GET MEDICAL ATTENTION. FOR
LESSER EXPOSURE, SEEK MEDICAL ATTENTION IF IRRITATION DEVELOPS OR PERSISTS
AFTER AREA IS WASHED. WASH CLOTHING BEFORE REUSE. THOROUGHLY CLEAN SHOES
BEFORE REUSE.
EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS, FOR AT
LEAST 15 MINUTES. GET MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON. GET MEDICAL ATTENTION.
SYMPTOMS: SEE SECTION 11.
NOTES TO PHYSICIAN:
EYES:
STAIN FOR EVIDENCE OF CORNEAL INJURY. IF CORNEA IS BURNED, INSTILL
ANTIBIOTIC STEROID PREPARATION FREQUENTLY. WORKPLACE VAPORS HAVE
PRODUCED REVERSIBLE CORNEAL EPITHELIAL EDEMA IMPAIRING VISION.
SKIN:
THIS COMPOUND IS A KNOWN SKIN SENSITIZER. TREAT SYMPTOMATICALLY AS
FOR CONTACT DERMATITIS OR THERMAL BURNS.
INGESTION:
TREAT SYMPTOMATICALLY. THERE IS NO SPECIFIC ANTIDOTE. INDUCING VOMITING IS
CONTRAINDICATED BECAUSE OF THE IRRITATING NATURE OF THIS COMPOUND.
RESPIRATORY:
THIS COMPOUND IS A KNOWN PULMONARY SENSITIZER. TREAT SYMPTOMATICALLY AND
SUPPORTIVELY. AN INDIVIDUAL HAVING A DERMAL OR PULMONARY SENSITIZATION
REACTION TO THIS MATERIAL SHOULD BE REMOVED FROM FURTHER EXPOSURE TO ANY
DIISOCYANATE.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA: FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING, SUCH
AS TURN-OUT GEAR. DURING A FIRE, MDI VAPORS AND OTHER IRRITATING, HIGHLY
TOXIC GASES MAY BE GENERATED BY THERMAL DECOMPOSITION OR COMBUSTION.
EXPLOSIVE RUPTURE IS POSSIBLE.
UNUSUAL FIRE OR EXPLOSION HAZARDS:
SEALED CONTAINERS AT ELEVATED TEMPERATURES OR CONTAMINATED WITH WATER MAY
RUPTURE EXPLOSIVELY. WATER OR FOG MAY CAUSE FROTHING WHICH CAN BE VIOLENT
ESPECIALLY IF SPRAYED INTO CONTAINERS OF HOT OR BURNING LIQUID. DO NOT
ALLOW RUN-OFF FROM FIRE FIGHTING TO ENTER DRAINS OR WATER COURSES.
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF CARBON. OXIDES OF NITROGEN. HYDROGEN CYANIDE. ISOCYANATE VAPORS.
ACIDS. ALDEHYDES. KETONES. TOXIC FUMES. IRRITATING VAPORS.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS.
CLEAN-UP METHODS:
REMOVE ALL SOURCES OF IGNITION. EVACUATE AND VENTILATE SPILL AREA; DIKE
SPILL TO PREVENT ENTRY INTO WATER SYSTEM; WEAR FULL PROTECTIVE EQUIPMENT
DURING CLEAN-UP. IF TEMPORARY CONTROL OF ISOCYANATE VAPOR IS REQUIRED, A
BLANKET OF PROTEIN FOAM (AVAILABLE AT MOST FIRE DEPARTMENTS) MAY BE PLACED
OVER SPILL. LARGE QUANTITIES MAY BE PUMPED INTO CLOSED, BUT NOT SEALED
CONTAINERS FOR DISPOSAL. FOR MINOR SPILLS, ABSORB ISOCYANATES WITH SAWDUST
OR OTHER ABSORBENT, SHOVEL INTO SUITABLE UNSEALED CONTAINERS, TRANSPORT TO
WELL VENTILATED AREA (OUTSIDE) AND TREAT WITH NEUTRALIZING SOLUTION:
MIXTURE OF 80% WATER AND 20% NON-IONIC SURFACTANT TERGITOL TMN-10; OR
90% WATER, 3-8% CONCENTRATED AMMONIA AND 2% DETERGENT. ADD ABOUT TEN PARTS
OF NEUTRALIZER PER PART OF ISOCYANATE, WITH MIXING. ALLOW TO STAND
UNCOVERED FOR 48 HOURS TO LET CARBON DIOXIDE ESCAPE. DECONTAMINATE FLOOR
WITH DECONTAMINATION SOLUTION LETTING STAND FOR AT LEAST 15 MINUTES. REFER
TO SECTION 8 "EXPOSURE CONTROLS / PERSONAL PROTECTION" PRIOR TO CLEAN UP.
| 7. HANDLING AND STORAGE | |
HANDLING:
PREVENT CONTACT WITH EYES, SKIN AND CLOTHING. DO NOT BREATHE VAPOR AND
MIST. WASH THOROUGHLY AFTER HANDLING. USE ONLY WITH ADEQUATE VENTILATION.
KEEP CONTAINER CLOSED. PROTECT FROM MOISTURE. EMPLOYEE EDUCATION AND
TRAINING IN THE SAFE USE AND HANDLING OF THIS COMPOUND ARE REQUIRED UNDER
THE OSHA HAZARD COMMUNICATION STANDARD. REFER TO SECTION 8.
STORAGE:
FOR SAFE STORAGE, STORE BETWEEN 30 DEG. C (86 DEG. F) AND 40 DEG. C
(104 DEG. F) KEEP CONTAINER TIGHTLY CLOSED AND IN A COOL, WELL-VENTILATED
PLACE AWAY FROM INCOMPATIBLE MATERIALS. KEEP AWAY FROM HEAT, SPARK AND
FLAME. DO NOT LET MOISTURE CONTAMINATE THIS MATERIAL. PRODUCT REACTS WITH
WATER TO RELEASE CARBON DIOXIDE, WHICH COULD BUILD UP PRESSURE IN CLOSED
CONTAINERS AND LEAD TO BURSTING. DO NOT RESEAL IF MOISTURE CONTAMINATION
IS SUSPECTED. IF CONTAINER IS EXPOSED TO HIGH HEAT (204.4 DEG. C
(400 DEG. F)), IT CAN BE PRESSURIZED AND POSSIBLY RUPTURE.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE
THE NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL AIHA WEEL OTHER
POLYURETHANE PREPOLYMER NONE NONE NONE NONE
DICYCLOHEXYLMETHANE- 0.005 PPM TWA NONE NONE NONE
4,4'-DIISOCYANATE
METHYLENEBIS 0.005 PPM TWA 0.02 PPM
(PHENYLISOCYANATE) (0.2 MG/M3) NONE NONE
CEILING
POLYMERIC NONE NONE NONE NONE
DIPHENYLMETHANE
DIISOCYANATE
ENGINEERING CONTROLS:
LOCAL EXHAUST SHOULD BE USED TO MAINTAIN LEVELS BELOW THE TLV WHENEVER MDI
IS PROCESSED, HEATED OR SPRAY APPLIED. STANDARD REFERENCE SOURCES REGARDING
INDUSTRIAL VENTILATION (I.E., ACGIH INDUSTRIAL VENTILATION) SHOULD BE
CONSULTED FOR GUIDANCE ABOUT ADEQUATE VENTILATION.
AIR MONITORING:
ISOCYANATE EXPOSURE LEVELS MUST BE MONITORED. MONITORING OF AIRBORNE
ISOCYANATES IN THE BREATHING ZONE OF INDIVIDUALS SHOULD BECOME PART OF
THE OVERALL EMPLOYEE EXPOSURE CHARACTERIZATION PROGRAM. MONITORING
TECHNIQUES HAVE BEEN DEVELOPED BY NIOSH AND OSHA.
MEDICAL SURVEILLANCE:
MEDICAL SUPERVISION OF ALL EMPLOYEES WHO HANDLE OR COME IN CONTACT WITH
ISOCYANATES IS RECOMMENDED. THESE SHOULD INCLUDE PREEMPLOYMENT AND
PERIODIC MEDICAL EXAMINATIONS WITH PULMONARY FUNCTION TESTS (FEV, FVC
AS A MINIMUM). PERSONS WITH ASTHMATIC-TYPE CONDITIONS, CHRONIC BRONCHITIS,
OTHER CHRONIC RESPIRATORY DISEASES OR RECURRENT SKIN ECZEMA OR
SENSITIZATION SHOULD BE EXCLUDED FROM WORKING WITH ISOCYANATES. ONCE A
PERSON IS DIAGNOSED AS SENSITIZED TO AN ISOCYANATE, NO FURTHER EXPOSURE
CAN BE PERMITTED.
RESPIRATORY PROTECTION:
A POSITIVE PRESSURE, SUPPLIED-AIR RESPIRATOR OR A SELF-CONTAINED BREATHING
APPARATUS IS RECOMMENDED WHEN:
AIRBORNE CONCENTRATIONS OF ISOCYANATE ARE KNOWN TO EXCEED 0.005 PPM;
OPERATIONS ARE PERFORMED IN A CONFINED SPACE OR AREA WITH LIMITED
VENTILATION; MATERIAL IS HEATED OR SPRAYED. HOWEVER, THIS SHOULD BE
PERMITTED ONLY FOR SHORT PERIODS OF TIME (LESS THAN ONE HOUR) AT RELATIVELY
LOW CONCENTRATIONS (AT OR NEAR THE TLV). HOWEVER, DUE TO THE POOR WARNING
PROPERTIES OF MDI, PROPER FIT AND TIMELY REPLACEMENT OF FILTER ELEMENTS
MUST BE ENSURED. OBSERVE OSHA REGULATIONS FOR RESPIRATOR USE (29 CFR
1910.134).
EYE/FACE PROTECTION:
SAFETY GLASSES WITH SIDESHIELDS OR CHEMICAL SAFETY GOGGLES SHOULD BE WORN
IF THERE IS A RISK OF SPLASHING. FULL FACE PROTECTION SHOULD BE USED IF
THE POTENTIAL FOR SPLASHING OR SPRAYING OF PRODUCT EXISTS. SAFETY SHOWERS
AND EYE WASH STATIONS SHOULD BE AVAILABLE. VAPOR RESISTANT GOGGLES SHOULD
BE WORN WHEN CONTACT LENSES ARE IN USE.
SKIN PROTECTION:
USE CHEMICAL RESISTANT, IMPERMEABLE CLOTHING INCLUDING GLOVES AND EITHER
AN APRON OR BODY SUIT TO PREVENT SKIN CONTACT. IF SKIN CREAMS ARE USED,
KEEP THE AREA COVERED BY THE CREAM TO A MINIMUM. COVER AS MUCH OF THE
EXPOSED SKIN AREA AS POSSIBLE WITH APPROPRIATE CLOTHING.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LOW VISCOSITY, LIQUID
COLOR: BROWN
ODOR: AROMATIC
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
VAPOR PRESSURE: 0.2 MM HG (25 DEG. C (77 DEG. F))
BOILING POINT/RANGE: NOT AVAILABLE.
MELTING POINT/ RANGE: NOT AVAILABLE.
SPECIFIC GRAVITY: 1.07
VAPOR DENSITY: NOT AVAILABLE.
FLASH POINT: > 162.77 DEG. C (> 324.99 DEG. F) TAGLIABUE CLOSED CUP
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT AVAILABLE.
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT AVAILABLE.
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
FLAMMABILITY: NOT APPLICABLE
EVAPORATION RATE: NOT AVAILABLE.
SOLUBILITY IN WATER:
REACTS SLOWLY WITH WATER TO LIBERATE CARBON DIOXIDE GAS.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT: 0 %; 0 G/L
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER NORMAL CONDITIONS OF STORAGE AND USE.
HAZARDOUS REACTIONS:
CONTACT WITH MOISTURE, OTHER MATERIALS THAT REACT WITH ISOCYANATES, OR
TEMPERATURES ABOVE 350 DEG. F (177 DEG. C), MAY CAUSE POLYMERIZATION.
UNCONTROLLED POLYMERIZATION MAY CAUSE RAPID EVOLUTION OF HEAT AND
INCREASE IN PRESSURE THAT COULD RESULT IN VIOLENT RUPTURE OF SEALED
STORAGE VESSELS OR CONTAINERS.
HAZARDOUS DECOMPOSITION PRODUCTS:
OXIDES OF CARBON. OXIDES OF NITROGEN. HYDROGEN CYANIDE. ISOCYANATE
VAPORS ACIDS. ALDEHYDES. KETONES. TOXIC FUMES. IRRITATING VAPORS.
INCOMPATIBLE MATERIALS:
WATER. AMINES. STRONG BASES. ALCOHOLS. WILL CAUSE SOME CORROSION TO
COPPER ALLOYS AND ALUMINUM. OXIDIZING AGENTS. STRONG ACIDS.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID:
KEEP AWAY FROM HEAT, IGNITION SOURCES AND INCOMPATIBLE MATERIALS.
CONTAMINATION WITH WATER.
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES, INGESTION
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION: THIS PRODUCT IS HARMFUL OR FATAL BY INHALATION.
ACUTE:
INHALATION OF DICYCLOHEXYLMETHANE-4,4'-DIISOCYANATE AT CONCENTRATIONS
ABOVE THE TLV CAN IRRITATE THE MUCOUS MEMBRANES IN THE RESPIRATORY TRACT
(NOSE, THROAT, LUNGS) CAUSING RUNNY NOSE, SORE THROAT, COUGHING, CHEST
DISCOMFORT, SHORTNESS OF BREATH AND REDUCED LUNG FUNCTION (BREATHING
OBSTRUCTION). PERSONS WITH PREEXISTING, NONSPECIFIC BRONCHIAL
HYPER-REACTIVITY CAN RESPOND TO CONCENTRATIONS BELOW THE TLV WITH SIMILAR
SYMPTOMS AS WELL AS LEAD TO BRONCHITIS, BRONCHIAL SPASM AND PULMONARY EDEMA
(FLUID IN LUNGS). THESE EFFECTS ARE USUALLY REVERSIBLE. CHEMICAL OR
HYPERSENSITIVE PNEUMONITIS WITH FLU-LIKE SYMPTOMS (E.G. FEVER, CHILLS)
HAVE ALSO BEEN REPORTED.
CHRONIC:
AS A RESULT OF PREVIOUS REPEATED OVEREXPOSURES OR A SINGLE LARGE DOSE,
CERTAIN INDIVIDUALS WILL DEVELOP ISOCYANATE SENSITIZATION (CHEMICAL
ASTHMA) WHICH WILL CAUSE THEM TO REACT TO A LATER EXPOSURE TO ISOCYANATE
AT LEVELS WELL BELOW THE TLV. CHRONIC OVEREXPOSURE TO ISOCYANATES HAS BEEN
REPORTED TO CAUSE LUNG DAMAGE. MAY CAUSE ALLERGIC RESPIRATORY REACTION.
THESE SYMPTOMS, WHICH CAN INCLUDE CHEST TIGHTNESS, WHEEZING, COUGH,
SHORTNESS OF BREATH OR ASTHMA ATTACK, COULD BE IMMEDIATE OR DELAYED
(UP TO SEVERAL HOURS AFTER EXPOSURE). SIMILAR TO MANY NON-SPECIFIC
ASTHMATIC RESPONSES, THERE ARE REPORTS THAT ONCE SENSITIZED AN INDIVIDUAL
CAN EXPERIENCE THESE SYMPTOMS UPON EXPOSURE TO DUST, COLD AIR, OR OTHER
IRRITANTS. THIS INCREASED LUNG SENSITIVITY CAN PERSIST FOR WEEKS AND IN
SEVERE CASES FOR SEVERAL YEARS. OVER EXPOSURE TO ISOCYANATES HAS ALSO BEEN
REPORTED TO CAUSE LUNG DAMAGE (INCLUDING DECREASE IN LUNG FUNCTION) WHICH
MAY BE PERMANENT. SENSITIZATION CAN EITHER BE TEMPORARY OR PERMANENT.
SKIN CONTACT:
ACUTE:
CAUSES SKIN IRRITATION. ISOCYANATES REACT WITH SKIN PROTEIN AND MOISTURE
AND CAN CAUSE IRRITATION WHICH MAY INCLUDE THE FOLLOWING SYMPTOMS:
REDDENING, SWELLING, RASH, SCALING OR BLISTERING. DICYCLOHEXYLMETHANE-
4,4'-DIISOCYANATE IS ALSO A POTENT SENSITIZER. MAY CAUSE ALLERGIC SKIN
REACTION. ONCE SENSITIZED, AN INDIVIDUAL MAY REACT EVEN TO AIRBORNE LEVELS
BELOW THE TLV WITH THE FOLLOWING SYMPTOMS:
ITCHING AND TINGLING OF THE EARLOBES AND NECK, RASH, HIVES, SWELLING OF
THE ARMS AND LEGS OR OTHER SYMPTOMS COMMON TO ALLERGIC DERMATITIS.
CHRONIC:
PROLONGED CONTACT CAN CAUSE REDDENING, SWELLING, RASH, SCALING, BLISTERING
AND IN SOME CASES, SKIN SENSITIZATION. INDIVIDUALS WHO HAVE SKIN
SENSITIZATION CAN DEVELOP THESE SYMPTOMS FROM CONTACT WITH LIQUID OR VAPOR.
ANIMAL TESTS HAVE INDICATED THAT RESPIRATORY SENSITIZATION CAN RESULT FROM
SKIN CONTACT WITH DICYCLOHEXYLMETHANE-4,4'-DIISOCYANATE. CURED MATERIAL IS
DIFFICULT TO REMOVE.
EYE CONTACT:
CAUSES SERIOUS EYE IRRITATION. STINGING. LIQUID, AEROSOLS OR VAPOR ARE
IRRITATING AND CAN CAUSE TEARING, REDDENING AND SWELLING. IF LEFT
UNTREATED, CORNEAL DAMAGE CAN OCCUR AND INJURY IS SLOW TO HEAL.
INGESTION:
IRRITATION AND CORROSIVE ACTION CAN OCCUR IN THE MOUTH, STOMACH TISSUE AND
DIGESTIVE TRACT IF SWALLOWED. SYMPTOMS CAN INCLUDE SORE THROAT, ABDOMINAL
PAIN, NAUSEA, VOMITING AND DIARRHEA.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED
HEALTH EFFECTS
POLYURETHANE PREPOLYMER NONE IRRITANT, ALLERGEN,
RESPIRATORY
DICYCLOHEXYLMETHANE- ORAL LD50 (RAT) = IRRITANT, ALLERGEN,
4,4'-DIISOCYANATE 1,065 MG/KG RESPIRATORY
DERMAL LD50 (RABBIT) =
>10,000 MG/KG
INHALATION LC50 (RAT,
4 H) = 0.295 MG/L
INHALATION LC50 (RAT,
4 H) = 0.307 MG/L
METHYLENEBIS INHALATION LC50 (RAT, IRRITANT,
(PHENYLISOCYANATE) 4 H) = 0.38 MG/L RESPIRATORY, ALLERGEN
INHALATION LC50 (RAT,
4 H) = 0.369 MG/L
POLYMERIC DIPHENYLMETHANE NONE ALLERGEN, IRRITANT,
DIISOCYANATE KIDNEY, LIVER,
RESPIRATORY
HAZARDOUS COMPONENT(S) NTP CARCINOGEN IARC CARCINOGEN OSHA CARCINOGEN
(SPECIFICALLY
REGULATED)
POLYURETHANE PREPOLYMER NO NO NO
DICYCLOHEXYLMETHANE- NO NO NO
4,4'-DIISOCYANATE
METHYLENEBIS NO NO NO
(PHENYLISOCYANATE)
POLYMERIC NO NO NO
DIPHENYLMETHANE
DIISOCYANATE
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
HAZARDOUS WASTE NUMBER: NOT A RCRA HAZARDOUS WASTE.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE
MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME:
AVIATION REGULATED LIQUID, N.O.S. (DICYCLOHEXYL METHANE DIISOCYANATE)
HAZARD CLASS OR DIVISION: 9
IDENTIFICATION NUMBER: UN 3334
PACKING GROUP: III
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS.
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH, DELAYED HEALTH
CERCLA/SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS SUBJECT TO THE
REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND
COMMUNITY RIGHT-TO-KNOW ACT OF 1986 (40 CFR 372). METHYLENEBIS
(PHENYLISOCYANATE) (CAS# 101-68-8). DICYCLOHEXYLMETHANE-4,4'-
DIISOCYANATE (CAS# 5124-30-1). POLYMERIC DIPHENYLMETHANE DIISOCYANATE
(CAS# 9016-87-9).
CALIFORNIA PROPOSITION 65:
NO CALIFORNIA PROPOSITION 65 LISTED CHEMICALS ARE KNOWN TO BE PRESENT.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE CANADIAN
DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: 8
PREPARED BY: SHEILA GINES, REGULATORY AFFAIRS SPECIALIST
ISSUE DATE: 06/07/2016
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE
OF ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE
OR USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.
SAFETY DATA SHEET
HENKEL
REVISION NUMBER: 005.0
ISSUE DATE: 01/16/2020
| 1. PRODUCT AND COMPANY IDENTIFICATION | |
PRODUCT NAME: LOCTITE MR FLX 80 KNOWN AS LOCTITE FIXMASTER FLEX 80 PUTTY
IDH NUMBER: 702235
PRODUCT TYPE/USE: POLYURETHANE HARDENER
ITEM NUMBER: 97423_374000
RESTRICTION OF USE: NONE IDENTIFIED
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: +1 (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
DANGER
HARMFUL IF SWALLOWED.
CAUSES SERIOUS EYE DAMAGE.
SUSPECTED OF CAUSING CANCER.
MAY DAMAGE FERTILITY OR THE UNBORN CHILD.
HAZARD CLASS HAZARD CATEGORY
ACUTE TOXICITY ORAL 4
SERIOUS EYE DAMAGE 1
CARCINOGENICITY 2
REPRODUCTIVE TOXICITY 1B
PICTOGRAM(S):
HEALTH HAZARD
CORROSION
EXCLAMATION MARK
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. WASH AFFECTED AREA THOROUGHLY
AFTER HANDLING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WEAR
PROTECTIVE GLOVES, CLOTHING, EYE AND FACE PROTECTION.
RESPONSE:
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EXPOSED OR CONCERNED: GET MEDICAL ATTENTION.
STORAGE: STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL,
STATE/PROVINCIAL AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD
(29 CFR 1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED
NATIONS GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF
CHEMICALS (GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
DI(2-ETHYLHEXYL)PHTHALATE 117-81-7 60 - 80
DIETHYLMETHYLBENZENEDIAMINE 68479-98-1 30 - 60
CARBON BLACK 1333-86-4 1 - 5
* EXACT PERCENTAGES MAY VARY OR ARE TRADE SECRET. CONCENTRATION RANGE
IS PROVIDED TO ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION.
SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING AND FOOTWEAR. IMMEDIATELY FLUSH SKIN WITH
PLENTY OF WATER (USING SOAP, IF AVAILABLE). GET MEDICAL ATTENTION. WASH
CLOTHING BEFORE REUSE.
EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS, FOR AT
LEAST 15 MINUTES. GET MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET IMMEDIATE
MEDICAL ATTENTION.
SYMPTOMS: SEE SECTION 11.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
WATER SPRAY (FOG), FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING, SUCH
AS TURN-OUT GEAR.
UNUSUAL FIRE OR EXPLOSION HAZARDS:
CLOSED CONTAINERS MAY RUPTURE (DUE TO BUILD UP OF PRESSURE) WHEN EXPOSED
TO EXTREME HEAT. IN CASE OF FIRE, KEEP CONTAINERS COOL WITH WATER SPRAY.
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF CARBON, OXIDES OF NITROGEN, IRRITATING ORGANIC VAPORS.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS.
CLEAN-UP METHODS:
REMOVE ALL SOURCES OF IGNITION. EVACUATE AND VENTILATE SPILL AREA; DIKE
SPILL TO PREVENT ENTRY INTO WATER SYSTEM; WEAR FULL PROTECTIVE EQUIPMENT
DURING CLEAN-UP. SOAK UP WITH INERT ABSORBENT MATERIAL (E.G. SAND, SILICA
GEL, ACID BINDER, UNIVERSAL BINDER, SAWDUST). SCRAPE UP SPILLED MATERIAL
AND PLACE IN A CLOSED CONTAINER FOR DISPOSAL. FLUSH AREA WITH WATER TO
REMOVE TRACE RESIDUE. REFER TO SECTION 8 "EXPOSURE CONTROLS / PERSONAL
PROTECTION" PRIOR TO CLEAN UP.
| 7. HANDLING AND STORAGE | |
HANDLING:
DO NOT TASTE OR SWALLOW. PREVENT CONTACT WITH EYES, SKIN AND CLOTHING.
DO NOT BREATHE VAPOR AND MIST. WASH THOROUGHLY AFTER HANDLING. KEEP
CONTAINER CLOSED. USE ONLY WITH ADEQUATE VENTILATION. REFER TO SECTION 8.
STORAGE:
KEEP CONTAINER TIGHTLY CLOSED AND IN A COOL, WELL-VENTILATED PLACE AWAY
FROM INCOMPATIBLE MATERIALS. STORE AWAY FROM HEAT, SPARKS, FLAMES, OR
OTHER SOURCES OF IGNITION.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE
THE NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL AIHA WEEL OTHER
DI(2-ETHYLHEXYL)- 5 MG/M3 TWA 5 MG/M3 PEL NONE NONE
PHTHALATE
DIETHYLMETHYL- NONE NONE NONE NONE
BENZENEDIAMINE
CARBON BLACK 3 MG/M3 TWA 3.5 MG/M3 PEL NONE NONE
INHALABLE
FRACTION.
ENGINEERING CONTROLS:
PROVIDE ADEQUATE LOCAL EXHAUST VENTILATION TO MAINTAIN WORKER EXPOSURE
BELOW EXPOSURE LIMITS.
RESPIRATORY PROTECTION:
USE NIOSH APPROVED RESPIRATOR IF THERE IS POTENTIAL TO EXCEED EXPOSURE
LIMIT(S).
EYE/FACE PROTECTION:
SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS. FULL FACE PROTECTION
SHOULD BE USED IF THE POTENTIAL FOR SPLASHING OR SPRAYING OF PRODUCT
EXISTS. SAFETY SHOWERS AND EYE WASH STATIONS SHOULD BE AVAILABLE.
SKIN PROTECTION:
USE CHEMICAL RESISTANT, IMPERMEABLE CLOTHING INCLUDING GLOVES AND EITHER
AN APRON OR BODY SUIT TO PREVENT SKIN CONTACT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID, LOW VISCOSITY
COLOR: BLACK
ODOR: AROMATIC
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
VAPOR PRESSURE: 0.2 MM Hg
BOILING POINT/RANGE: NOT AVAILABLE.
MELTING POINT/ RANGE: NOT AVAILABLE.
SPECIFIC GRAVITY: NOT DETERMINED
VAPOR DENSITY: NOT AVAILABLE.
FLASH POINT: 163 DEG. C (325.4 DEG. F) CLOSED CUP
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT AVAILABLE.
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT AVAILABLE.
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
FLAMMABILITY: NOT APPLICABLE
EVAPORATION RATE: NOT AVAILABLE.
SOLUBILITY IN WATER: PARTIALLY SOLUBLE
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT: 0 %; 0 G/L
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER NORMAL CONDITIONS OF STORAGE AND USE.
HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
HAZARDOUS DECOMPOSITION PRODUCTS:
OXIDES OF CARBON. OXIDES OF SULFUR. HYDROGEN SULFIDE. CYANIDES.
IRRITATING ORGANIC VAPOURS.
INCOMPATIBLE MATERIALS: ACIDS. OXIDIZING AGENTS.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID:
STORE AWAY FROM INCOMPATIBLE MATERIALS. HEAT, FLAMES, SPARKS AND OTHER
SOURCES OF IGNITION.
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES, INGESTION
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION:
MAY CAUSE DIZZINESS, INCOORDINATION, HEADACHE, NAUSEA, AND VOMITING.
MAY CAUSE IRRITATION TO NOSE AND THROAT.
SKIN CONTACT: MAY CAUSE SKIN IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
INGESTION: HARMFUL IF SWALLOWED.
HAZARDOUS LD50S AND LC50S IMMEDIATE AND DELAYED
COMPONENT(S) HEALTH EFFECTS
DI(2-ETHYLHEXYL)- ORAL LD50 (RABBIT) CENTRAL NERVOUS SYSTEM,
PHTHALATE = 33.9 G/KG DEVELOPMENTAL, KIDNEY,
LIVER, REPRODUCTIVE, SOME
ORAL LD50 (MOUSE) EVIDENCE OF CARCINOGENICITY
= >30 G/KG
ORAL LD50 (RAT)
= >25 G/KG
DERMAL LD50 (RABBIT)
= 25 G/KG
DIETHYLMETHYL- NONE PANCREAS, ADRENALS, EYES
BENZENEDIAMINE
CARBON BLACK ORAL LD50 (RAT) RESPIRATORY, SOME EVIDENCE
= >8,000 MG/KG OF CARCINOGENICITY
HAZARDOUS COMPONENT(S) NTP IARC OSHA CARCINOGEN
CARCINOGEN CARCINOGEN (SPECIFICALLY
REGULATED)
DI(2-ETHYLHEXYL)- REASONABLY GROUP 2B NO
PHTHALATE ANTICIPATED TO
BE A HUMAN
CARCINOGEN.
DIETHYLMETHYL- NO NO NO
BENZENEDIAMINE
CARBON BLACK NO GROUP 2B NO
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
HAZARDOUS WASTE NUMBER: NOT A RCRA HAZARDOUS WASTE.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES
TO THE MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME:
RQ, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
HAZARD CLASS OR DIVISION: 9
IDENTIFICATION NUMBER: UN 3082
PACKING GROUP: III
DOT HAZARDOUS SUBSTANCE(S): DIETHYLHEXYL PHTHALATE
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME:
RQ, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(DIETHYLTOLUENE DIAMINE)
HAZARD CLASS OR DIVISION: 9
IDENTIFICATION NUMBER: UN 3082
PACKING GROUP: III
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME:
RQ, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(DIETHYLTOLUENE DIAMINE)
HAZARD CLASS OR DIVISION: 9
IDENTIFICATION NUMBER: UN 3082
PACKING GROUP: III
MARINE POLLUTANT: DIETHYLTOLUENE DIAMINE
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED AS ACTIVE OR ARE EXEMPT FROM LISTING ON THE
TOXIC SUBSTANCES CONTROL ACT (TSCA) INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: AROMATIC DIAMINE (CAS# 68479-98-1).
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS.
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH, DELAYED HEALTH
CERCLA/SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS SUBJECT TO THE
REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND
COMMUNITY RIGHT-TO-KNOW ACT OF 1986 (40 CFR 372).
DI(2-ETHYLHEXYL)PHTHALATE (CAS# 117-81-7).
CERCLA REPORTABLE QUANTITY:
DI(2-ETHYLHEXYL)PHTHALATE (CAS# 117-81-7) 100 LBS. (45.4 KG)
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO
CAUSE CANCER. THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE CANADIAN
DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: 2
PREPARED BY: PRODUCT SAFETY AND REGULATORY AFFAIRS
ISSUE DATE: 01/16/2020
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE
OF ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE OR
USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.
THIS SAFETY DATA SHEET HAS BEEN GENERATED BASED ON OSHA HAZARD
COMMUNICATION STANDARD (29 CFR 1910.1200) AND PROVIDES INFORMATION
IN ACCORDANCE WITH U.S. FEDERAL LAW ONLY. NO WARRANTY OR REPRESENTATION
OF ANY KIND IS GIVEN WITH RESPECT TO THE SUBSTANTIVE OR EXPORT LAWS OF
ANY OTHER JURISDICTION OR COUNTRY. PLEASE CONFIRM THAT THE INFORMATION
PROVIDED HEREIN CONFORMS TO THE SUBSTANTIVE EXPORT OR OTHER LAW OF ANY
OTHER JURISDICTION PRIOR TO EXPORT. PLEASE CONTACT HENKEL PRODUCT SAFETY
AND REGULATORY AFFAIRS FOR ADDITIONAL ASSISTANCE.