| Common Name: | SILVER OXIDE BUTTON BATTERY |
| Manufacturer: | FDK JAPAN |
| SDS Revision Date: | 1/1/2019 |
| SDS Format: | GHS-US |
| Item Number(s): | 5U085 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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FDK
SILVER OXIDE BUTTON BATTERY
ISSUED DATE: JANUARY 1, 2019
DOCUMENT NUMBER: SB2019E01
SAFETY DATA SHEET (SDS)
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT CATEGORY: SILVER OXIDE BUTTON BATTERY
TYPE: SR44 / SR43 / SR41 / SR1120 / SR1130
NOMINAL VOLTAGE: 1.5 V
SUPPLIER'S NAME: FDK CORPORATION
SUPPLIER'S ADDRESS:
1-6-41 KONAN
MINATO-KU, TOKYO 108-8212
JAPAN
TELEPHONE: +81-3-5715-7435
EMERGENCY CONTACT: SAME AS ABOVE
NOTE:
SDS IS NOT APPLIED TO THE PRODUCT HERMETICALLY SEALED AS DRY BATTERY. THE
BATTERY HAS NO RISK TO LIFE AND HEALTH UNDER NORMAL USE OR TRANSPORTATION
BECAUSE INGREDIENTS OF BATTERY ARE NOT LEAKED OUT BY VIRTUE OF HERMETICAL
SEALING WITH METAL CASE.
THIS SDS NOTIFIES POSSIBLE RISK OF OUR BATTERY UNDER ABNORMAL USE BUT
MAINLY AIM TO PROVIDE INFORMATION ABOUT INGREDIENTS, NOTICE OF HANDLING
AND TRANSPORTATION REGULATIONS AS A USEFUL REFERENCE.
| 2. HAZARDS IDENTIFICATION | |
THE IMPORTANT HAZARDS AND ADVERSE EFFECTS OF THE CHEMICAL PRODUCT:
NO INFORMATION AVAILABLE
CHEMICAL PRODUCT - SPECIFIC HAZARDS: NO INFORMATION AVAILABLE
OUTLINE OF AN ANTICIPATED EMERGENCY:
CHEMICAL CONTENTS ARE SEALED IN METAL CAN. HOWEVER, IF BATTERY IS
MECHANICALLY OR ELECTRICALLY ABUSED OR PLACED ON HIGH TEMPERATURE
CONDITION, RISK OF LEAKAGE, HEAT GENERATION OR IN EXTREME CASE EXPLOSION
MAY BE ANTICIPATED.
MOST LIKELY RISK IS ATTACHING OF RELEASED CAUSTIC ALKALI (KOH) TO SKIN
AND EYE. ANTICIPATED VOLUME OF LEAKAGE IS VERY LITTLE. FOR CONSUMER USE,
WARNING TO ABUSE IS INDICATED ON PACKAGE.
NOTE):
OUR BATTERY IS NOT CLASSIFIED IN ACCORDANCE WITH THE GHS CLASSIFICATION.
| 3. COMPOSITION AND INGREDIENTS INFORMATION | |
(METAL CASING PREVENT FROM LEAKING OUT OF INTERNAL INGREDIENTS)
MATERIAL CAS NO. CONTENTS
SILVER OXIDE [Ag2O] 206676-12-3 25 - 40 WT%
MANGANESE DIOXIDE [MnO2] 1313-13-9 0 - 10 WT%
GRAPHITE [C] 7782-42-5 0.1 - 3 WT%
ZINC [Zn] 7440-66-6 7 - 11 WT%
MERCURY [Hg] 7439-97-6 0.2 - 0.4 WT%
POTASSIUM HYDROXIDE [KOH] 1310-58-3 4 - 8 WT%
| 4. FIRST-AID MEASURES | |
CHEMICAL CONTENTS ARE SEALED IN METAL CAN. THEREFORE, RISK OF EXPOSURE
NEVER OCCURS UNLESS BATTERY IS MECHANICALLY OR ELECTRICALLY ABUSED.
FIRST AID SHOWN BELOW MAY NEED IN SUCH ABNORMAL CASE ONLY.
INHALATION: NO INFORMATION AVAILABLE
SKIN CONTACT:
RELEASED CONTENTS FROM BATTERY MAY CAUSE SKIN IRRITATION AND/OR CHEMICAL
BURNS. REMOVE CONTAMINATED CLOTHES AND RINSE SKIN WITH PLENTY OF WATER. IF
CHEMICAL BURN OCCURS OR IF IRRITATION PERSISTS, GET MEDICAL ASSISTANCE.
EYES CONTACT:
IF RELEASED CONTENT FROM BATTERY IS ATTACHED ON EYES, SEVERE IRRITATION
AND CHEMICAL BURNS OCCUR. IMMEDIATELY RINSE WITH PLENTY OF WATER FOR
SEVERAL MINUTES (REMOVE CONTACT LENSES IF POSSIBLE), GET MEDICAL
ASSISTANCE.
SWALLOWING:
IN CASE OF SWALLOWING BATTERY, IMMEDIATELY REFER FOR MEDICAL ATTENTION.
| 5. FIRE-FIGHTING MEASURES | |
FIRE EXTINGUISHING AGENT:
WATER AND ALL KIND OF EXTINGUISHERS ARE AVAILABLE.
EXTINGUISHING METHOD:
BECAUSE PACKAGING MATERIAL OF BATTERY IS PAPER, USE WATER EXTINGUISHER,
CO2 EXTINGUISHER OR POWDER EXTINGUISHER AS NORMAL EXTINGUISHER.
SINCE VAPOR, GENERATED FROM BURNING BATTERIES MAY MAKE EYES, NOSE AND
THROAT IRRITATES, BE SURE TO EXTINGUISH THE FIRE ON THE WINDWARD SIDE.
WEAR THE RESPIRATORY PROTECTION EQUIPMENT IN SOME CASES.
SPECIAL EQUIPMENT FOR THE PROTECTION OF FIREFIGHTERS:
HAND PROTECTION: A PAIR OF FLAME-PROOF GROVES
EYE PROTECTION: FACE MASK
PROTECTIVE WEAR OF SKIN AND/OR BODY: PROTECTIVE CLOTHING
| 6. ACCIDENTAL RELEASE MEASURES | |
CHEMICAL CONTENTS ARE SEALED IN METAL CAN. HOWEVER, IF THE BATTERY IS
MECHANICALLY OR ELECTRICALLY ABUSED, CONTENTS MAY LEAK OUT. IN SUCH CASE,
TAKE ACTION AS SHOWING BELOW.
PERSONAL PRECAUTIONS:
TEMPORARY ATTACHING OF ELECTROLYTE TO SKIN DOES NOT CAUSE SERIOUS HEALTH
HAZARD. BE SURE THE VENTILATION AND WASHING OUT OF ELECTROLYTE QUICKLY.
ENVIRONMENTAL PRECAUTIONS:
CLEAN UP IT QUICKLY. SPECIFIC ENVIRONMENTAL PRECAUTION IS NOT NECESSARY.
METHOD AND MATERIALS FOR CONTAINMENT AND METHODS AND MATERIALS FOR CLEANING
UP: NOT APPLICABLE. CLEAN UP AND DISPOSE OF IT ACCORDING TO SECTION 13
PREVENTION OF SECONDARY HAZARDS: NO NEED.
| 7. HANDLING AND STORING | |
TRANSPORTATION AND FREIGHT HANDLING:
(1) PREVENT WETTING OF PACKING BY RAIN OR DEW CONDENSATION.
(2) DO NOT PLACE PACKING NEAR SOURCE OF HEAT.
(3) DO NOT DROP PACKING FROM MORE THAN 1M HEIGHT AND DO NOT PRESS PACKING
ALLOWING DEFORM IT.
HANDLING:
(1) DO NOT CHARGE, SHORT-CIRCUIT, DISASSEMBLE, DEFORM OR DISPOSED OF IN
FIRE.
(2) DO NOT PILE UP OR MINGLE BATTERIES WITH EACH OTHER.
(3) DO NOT PLACE BATTERY ON METAL CASE, METAL PLATE OR ANTISTATIC MATERIAL.
(4) IN CASE OF MULTI BATTERIES APPLICATION, REPLACE ALL BATTERIES TO NEW
AT ONCE WHEN REPLACEMENT OF USED BATTERIES.
(5) DO NOT ALLOW CHILDREN TO REPLACE BATTERIES WITHOUT ADULT SUPERVISION.
STORAGE:
(1) BE SURE TO STORE BATTERIES IN WELL-VENTILATED, DRY AND COOL CONDITIONS.
(2) PREVENT WETTING OF PACKING BY RAIN, SNOW, FROST OR DEW CONDENSATION.
(3) DO NOT STORE BATTERIES NEAR SOURCE OF HEAT OR NOZZLE OF HOT AIR.
(4) DO NOT STORE BATTERIES IN DIRECT SUNSHINE.
(5) TAKE CARE OF WETTING OF PACKING CAUSED BY DEW CONDENSATION WHEN PACKING
IS REMOVED FROM COLD TO WARM AND HUMID CONDITION.
(6) KEEP BATTERIES OUT OF REACH OF CHILDREN.
| 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION | |
THERE IS NO NEED OF PERSONAL PROTECTIVE EQUIPMENT ON REGULAR HANDLING AND
STORAGE, BUT LOT OF ELECTROLYTE IS RELEASED BY MECHANICAL OR ELECTRICAL
ABUSE, USE THE PROTECTIONS AS SHOWN BELOW.
RESPIRATORY PROTECTION: MASK (WITH A FILTER PREFERABLY)
HAND PROTECTION: SYNTHETIC RUBBER GLOVES
EYE PROTECTION: GOGGLES OR GLASSES
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
STATE: SOLID
SHAPE: ROUND
SINCE BATTERY IS NOT CHEMICAL PRODUCT OTHER THAN ABOVE INFORMATION IS NOT
APPLICABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE ON REGULAR HANDLING
CONDITIONS TO AVOID:
EXTERNAL SHORT CIRCUIT OF BATTERY, DEFORMATION BY CRUSH, EXPOSURE AT HIGH
TEMPERATURE OF MORE THAN 85 DEGREE C (MAY CAUSE LEAKAGE AND RUPTURE),
DIRECT SUNLIGHT, HIGH HUMIDITY
MATERIALS TO AVOID:
WATER, A CHAIN, AND A PIECE OF METAL THAT MAY CAUSE SHORT CIRCUIT.
HAZARDOUS DECOMPOSITION PRODUCT: EMITTED ACRID OR POISONOUS GASES IN FIRE.
| 11. TOXICOLOGICAL INFORMATION | |
SINCE CHEMICALS ARE CONTAINED IN A SEALED CAN, THERE ARE NO HAZARDS.
| 12. ECOLOGICAL INFORMATION | |
ANTICIPATED BEHAVIOR OF CHEMICAL PRODUCT IN ENVIRONMENT/POSSIBLE
ENVIRONMENTAL IMPACT/ECOTOXICITY: NO INFORMATION AVAILABLE
PERSISTENCE AND DEGRADABILITY: NO INFORMATION AVAILABLE
BIOACCUMULATIVE POTENTIAL: NO INFORMATION AVAILABLE
MOBILITY IN SOIL: NO INFORMATION AVAILABLE
EXPOSURE OF INTERNAL CONTENT OF BATTERY MAY OCCUR BY CORROSION OF METAL
CASE OF BATTERY AFTER BATTERIES ARE DISPOSED OF IN GROUND AND KEPT FOR LONG
TIME. BUT NO AVAILABLE INFORMATION ABOUT ENVIRONMENTAL HAZARD IS REPORTED
AFTER EVALUATION OF LONG TERM LANDFILL EXPERIMENT.
OUR BATTERY DOES NOT INVOLVE MORE THAN LIMITED CONTENTS OF HAZARDOUS
MATERIALS PROHIBITED IN EU BATTERY DIRECTIVE (2006/66/EC).
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSE OF BATTERIES IN ACCORDANCE WITH APPLICABLE FEDERAL, STATE AND LOCAL
REGULATIONS.
FOR SAFETY PRECAUTION, BATTERY SHOULD INSULATE IN PROPER MANNER; COVERING
BOTH TERMINALS BY TAPE, WRAPPING OF BATTERY IN INSULATIVE BAG OR PACKING
BATTERY IN ORIGINAL PACKAGE IS RECOMMENDED FOR PREVENT FROM LEAKAGE AND
RUPTURE DUE TO SHORT-CIRCUIT.
| 14. TRANSPORT INFORMATION | |
CAUTION FOR HANDLING:
AVOID ROUGH HANDLING OF BATTERY CARTONS. BATTERIES SHALL BE KEPT IN DRY
AND COOL CONDITIONS.
DO NOT PLACE BATTERIES IN A PLACE EXPOSED TO DIRECT SUNSHINE FOR A LONG
TIME OR SPLASHED BY RAIN WATER.
DO NOT MIX UNPACKED BATTERIES SO AS TO AVOID MECHANICAL DAMAGE AND/OR
SHORT-CIRCUIT AMONG EACH OTHER.
COMPLIANCE WITH SPECIAL PROVISION OF TRANSPORTATION:
BECAUSE OUR BATTERY IS COMPLIANCE WITH US DOT SPECIAL PROVISION 130 AND
IATA SP A123 AS FOLLOWINGS, ANY TRANSPORTATION IS AVAILABLE.
SILVER OXIDE BUTTON BATTERIES ARE CONSIDERED TO BE "DRY CELL" BATTERIES AND
ARE UNREGULATED FOR PURPOSES OF TRANSPORTATION BY THE U.S. DEPARTMENT OF
TRANSPORTATION (DOT), INTERNATIONAL CIVIL AVIATION ADMINISTRATION (ICAO),
INTERNATIONAL AIR TRANSPORT ASSOCIATION (IATA) AND THE INTERNATIONAL
MARITIME ORGANIZATION (IMO). THE ONLY REQUIREMENT FOR SHIPPING THESE
BATTERIES BY DOT IS SPECIAL PROVISION 130 WHICH STATES:
"BATTERIES, DRY ARE NOT SUBJECT TO THE REQUIREMENTS OF THIS SUBCHAPTER ONLY
WHEN THEY ARE OFFERED FOR TRANSPORTATION IN A MANNER THAT PREVENTS THE
DANGEROUS EVOLUTION OF HEAT (FOR EXAMPLE, BY THE EFFECTIVE INSULATION OF
EXPOSED TERMINALS). THE REQUIREMENTS FOR SHIPPING OF THESES BATTERIES BY
ICAO AND IATA IS SPECIAL PROVISION A123 WHICH STATES:
"A BATTERY OR BATTERY POWERED DEVICE HAVING THE POTENTIAL OF DANGEROUS
EVOLUTIONS OF HEAT THAT IS NOT PREPARED SO AS TO PREVENT A SHORT-CIRCUIT
(E.G. IN THE CASE OF BATTERIES, BY THE EFFECTIVE INSULATION OF EXPOSED
TERMINALS; OR IN THE CASE OF EQUIPMENT, BY DISCONNECTION OF THE BATTERY
AND PROTECTION OF EXPOSED TERMINALS) IS FORBIDDEN FROM TRANSPORTATION. IN
ADDITION, IN THE CASE OF AIR TRANSPORTATION OF BATTERIES WHICH IS CONFORMED
TO THIS REQUIREMENT, THE INFORMATION "NOT RESTRICTED, AS PER SPECIAL
PROVISION A123" SHALL BE NOTED IN CERTAIN COLUMN OF "SUBSTANCES" OF AIR
WAYBILL."
OUR BATTERY COMPLIES ABOVE REQUIREMENTS BECAUSE OF IMPLEMENTATION OF
APPLICABLE PACKAGING PREVENTING OUTER SHORT-CIRCUIT BY APPLYING EFFECTIVE
PACKING AND OBEYING OF WAYBILL NOTATION REQUIREMENT.
NECESSARY INFORMATION IN WAYBILL FOR EACH TRANSPORTATION
AIR TRANSPORT: "NOT RESTRICTED, AS PER SPECIAL PROVISION A123"
MARINE/WATER TRANSPORT: NONE
GROUND TRANSPORT: NONE
| 15. REGULATORY INFORMATION | |
ENVIRONMENT-RELATED LAW OF BATTERIES; EU NATIONS HAVE APPLICABLE LAW IN
ACCORDANCE WITH DIRECTIVE 2006/66/EC AND OTHER SOME COUNTRIES, CHINA,
KOREA, BRAZIL, SOME PROVINCES OF USA AND CANADA OR SO HAVE SIMILAR LAW.
| 16. OTHER INFORMATION | |
REFERENCE; DANGEROUS GOODS REGULATIONS - 60TH EDITION, EFFECTIVE 1 JANUARY
2019: INTERNATIONAL AIR TRANSPORT ASSOCIATION (IATA)
THE INFORMATION AND THE RECOMMENDATIONS SET FORTH ARE MADE IN GOOD FAITH
AND BELIEVED TO BE ACCURATE UNTIL VALIDATED DATE SHOWN BELOW.
THE PRESENT FILE REFERS TO NORMAL USE OF THE PRODUCT IN QUESTION. FDK
CORP. MAKES NO WARRANTY EXPRESSED OR IMPLIED.
VALIDATED DATE: DECEMBER 31, 2019