| Common Name: | SHEILA SHINE (AEROSOL) |
| Manufacturer: | SHEILA SHINE |
| SDS Revision Date: | 12/7/2018 |
| SDS Format: | No Format Specified |
| Item Number(s): | 5URF7 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
ACC. TO OSHA HCS (29CFR 1910.1200) AND WHMIS 2015 REGULATIONS
PRINTING DATE: DECEMBER 07, 2018
REVISION: DECEMBER 07, 2018
| 1 IDENTIFICATION |  |
PRODUCT IDENTIFIER:
TRADE NAME: SHEILA SHINE (AEROSOL)
OTHER MEANS OF IDENTIFICATION: NO OTHER IDENTIFIERS
RECOMMENDED USE AND RESTRICTION ON USE:
RECOMMENDED USE: POLISHING AGENT/ BURNISHING COMPOUND
RESTRICTIONS ON USE: NO RELEVANT INFORMATION AVAILABLE.
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
MANUFACTURER/SUPPLIER:
SHEILA SHINE INC.
7725 W 2ND COURT
HIALEAH, FL 33014
PHONE: (305) 557-1729
EMERGENCY TELEPHONE NUMBER:
CHEMTEL INC.
(800)255-3924 (NORTH AMERICA)
+1 (813)248-0585 (INTERNATIONAL)
| 2 HAZARD(S) IDENTIFICATION | |
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
FLAM. AEROSOL 1:
H222: EXTREMELY FLAMMABLE AEROSOL.
PRESS. GAS:
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
SKIN IRRIT. 2:
H315: CAUSES SKIN IRRITATION.
EYE IRRIT. 2A:
H319: CAUSES SERIOUS EYE IRRITATION.
CARC. 1B:
H350: MAY CAUSE CANCER.
STOT RE 2:
H373:
MAY CAUSE DAMAGE TO THE HEARING ORGANS THROUGH PROLONGED OR REPEATED
EXPOSURE.
ASP. TOX. 1:
H304: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
LABEL ELEMENTS:
GHS LABEL ELEMENTS:
THE PRODUCT IS CLASSIFIED AND LABELED ACCORDING TO THE GLOBALLY HARMONIZED
SYSTEM (GHS).
HAZARD PICTOGRAMS:
GHS02: FLAME
GHS04: GAS CYLINDER
GHS07: EXCLAMATION MARK
GHS08: HEALTH HAZARD
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
H222: EXTREMELY FLAMMABLE AEROSOL.
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
H315: CAUSES SKIN IRRITATION.
H319: CAUSES SERIOUS EYE IRRITATION.
H350: MAY CAUSE CANCER.
H373:
MAY CAUSE DAMAGE TO THE HEARING ORGANS THROUGH PROLONGED OR REPEATED
EXPOSURE.
H304: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
PRECAUTIONARY STATEMENTS:
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
P210: KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING.
P211: DO NOT SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE.
P251:
PRESSURIZED CONTAINER: DO NOT PIERCE OR BURN, EVEN AFTER USE.
P260: DO NOT BREATHE MIST/VAPORS/SPRAY.
P264: WASH THOROUGHLY AFTER HANDLING.
P280: WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION.
P301+P310:
IF SWALLOWED: IMMEDIATELY CALL A POISON CENTER/DOCTOR.
P331: DO NOT INDUCE VOMITING.
P302+P352:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
P308+P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
P314: GET MEDICAL ADVICE/ATTENTION IF YOU FEEL UNWELL.
P332+P313:
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
P362+P364: TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
P337+P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
P403: STORE IN A WELL-VENTILATED PLACE.
P405: STORE LOCKED UP.
P410+P412:
PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING 50
DEG. C/122 DEG. F.
P501:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL/REGIONAL/NATIONAL/
INTERNATIONAL REGULATIONS.
NFPA RATINGS (SCALE 0 - 4):
HEALTH 1
FIRE 2
INSTABILITY 0
HMIS-RATINGS (SCALE 0 - 4):
HEALTH 1*
FIRE 2
REACTIVITY 0
*:
INDICATES A LONG TERM HEALTH HAZARD FROM REPEATED OR PROLONGED EXPOSURES.
OTHER HAZARDS:
THERE ARE NO OTHER HAZARDS NOT OTHERWISE CLASSIFIED THAT HAVE BEEN
IDENTIFIED.
| 3 COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL CHARACTERIZATION: MIXTURES
COMPONENTS:
64741-89-5 DISTILLATES (PETROLEUM), SOLVENT-REFINED 30-60%
LIGHT PARAFFINIC
CARC. 1B, H350
127-18-4 TETRACHLOROETHYLENE 10-30%
CARC. 2, H351
64741-88-4 DISTILLATES (PETROLEUM), SOLVENT-REFINED 10-30%
HEAVY PARAFFINIC
CARC. 1B, H350
1330-20-7 XYLENE 7-13%
FLAM. LIQ. 3, H226
ASP. TOX. 1, H304
ACUTE TOX. 4, H312; ACUTE TOX. 4, H332;
SKIN IRRIT. 2, H315; EYE IRRIT. 2A, H319;
STOT SE 3, H335
124-38-9 CARBON DIOXIDE <10%
PRESS. GAS, H280
SIMPLE ASPHYXIANT
100-41-4 ETHYLBENZENE 1-5%
FLAM. LIQ. 2, H225
CARC. 2, H351; STOT RE 2, H373; ASP. TOX.
1, H304
ACUTE TOX. 4, H332
ADDITIONAL INFORMATION:
FOR THE WORDING OF THE LISTED HAZARD STATEMENTS, REFER TO SECTION 16.
FOR THE LISTED INGREDIENT(S), THE IDENTITY AND/OR EXACT PERCENTAGE(S) ARE
BEING WITHHELD AS A TRADE SECRET.
| 4 FIRST-AID MEASURES | |
DESCRIPTION OF FIRST AID MEASURES:
AFTER INHALATION:
SUPPLY FRESH AIR; CONSULT DOCTOR IN CASE OF COMPLAINTS.
PROVIDE OXYGEN TREATMENT IF AFFECTED PERSON HAS DIFFICULTY BREATHING.
IN CASE OF IRREGULAR BREATHING OR RESPIRATORY ARREST PROVIDE ARTIFICIAL
RESPIRATION.
IN CASE OF UNCONSCIOUSNESS PLACE PATIENT STABLY IN SIDE POSITION FOR
TRANSPORTATION.
AFTER SKIN CONTACT:
IMMEDIATELY REMOVE ANY CLOTHING SOILED BY THE PRODUCT.
IMMEDIATELY WASH WITH WATER AND SOAP AND RINSE THOROUGHLY.
SEEK MEDICAL TREATMENT IN CASE OF COMPLAINTS.
AFTER EYE CONTACT:
REMOVE CONTACT LENSES IF WORN.
RINSE OPENED EYE FOR SEVERAL MINUTES UNDER RUNNING WATER. IF SYMPTOMS
PERSIST, CONSULT A DOCTOR.
AFTER SWALLOWING:
UNLIKELY ROUTE OF EXPOSURE.
RINSE OUT MOUTH AND THEN DRINK PLENTY OF WATER.
DO NOT INDUCE VOMITING; IMMEDIATELY CALL FOR MEDICAL HELP.
A PERSON VOMITING WHILE LYING ON THEIR BACK SHOULD BE TURNED ONTO THEIR
SIDE.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
COUGHING
BREATHING DIFFICULTY
DIZZINESS
IRRITANT TO SKIN AND MUCOUS MEMBRANES.
NAUSEA
SLIGHT IRRITANT EFFECT ON EYES.
GASTRIC OR INTESTINAL DISORDERS WHEN INGESTED.
DISORIENTATION
DANGER:
MAY BE HARMFUL IF INHALED.
MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
DANGER OF IMPAIRED BREATHING.
DANGER OF DISTURBED CARDIAC RHYTHM.
DANGER OF CONVULSION.
CARCINOGENIC.
MAY CAUSE DAMAGE TO THE HEARING ORGANS THROUGH PROLONGED OR REPEATED
EXPOSURE.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED:
MEDICAL SUPERVISION FOR AT LEAST 48 HOURS.
IF NECESSARY OXYGEN RESPIRATION TREATMENT.
MONITOR CIRCULATION.
| 5 FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING AGENTS:
WATER FOG / HAZE
FOAM
FIRE-EXTINGUISHING POWDER
CARBON DIOXIDE
FOR SAFETY REASONS UNSUITABLE EXTINGUISHING AGENTS: WATER STREAM.
SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
DANGER OF RECEPTACLES BURSTING BECAUSE OF HIGH VAPOR PRESSURE IF HEATED.
DURING HEATING OR IN CASE OF FIRE POISONOUS GASES ARE PRODUCED.
ADVICE FOR FIREFIGHTERS:
PROTECTIVE EQUIPMENT:
WEAR SELF-CONTAINED RESPIRATORY PROTECTIVE DEVICE.
WEAR FULLY PROTECTIVE SUIT.
ADDITIONAL INFORMATION:
ELIMINATE ALL IGNITION SOURCES IF SAFE TO DO SO.
LEAKING GAS FIRE: DO NOT EXTINGUISH, UNLESS LEAK CAN BE STOPPED SAFELY.
COOL ENDANGERED CONTAINERS WITH WATER FOG.
| 6 ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
USE RESPIRATORY PROTECTIVE DEVICE AGAINST THE EFFECTS OF FUMES/DUST/
AEROSOL.
WEAR PROTECTIVE EQUIPMENT. KEEP UNPROTECTED PERSONS AWAY.
ENSURE ADEQUATE VENTILATION.
KEEP AWAY FROM IGNITION SOURCES.
KEEP PEOPLE AT A DISTANCE AND STAY UPWIND.
PARTICULAR DANGER OF SLIPPING ON LEAKED/SPILLED PRODUCT.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW TO ENTER SEWERS/ SURFACE OR GROUND WATER.
INFORM RESPECTIVE AUTHORITIES IN CASE OF SEEPAGE INTO WATER COURSE OR
SEWAGE SYSTEM.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
ABSORB WITH NON-COMBUSTIBLE LIQUID-BINDING MATERIAL (SAND, DIATOMITE, ACID
BINDERS, UNIVERSAL BINDERS).
REMOVE FROM THE WATER SURFACE (E.G. SKIM OR SUCK OFF).
SEND FOR RECOVERY OR DISPOSAL IN SUITABLE RECEPTACLES.
REFERENCE TO OTHER SECTIONS:
SEE SECTION 7 FOR INFORMATION ON SAFE HANDLING.
SEE SECTION 8 FOR INFORMATION ON PERSONAL PROTECTION EQUIPMENT.
SEE SECTION 13 FOR DISPOSAL INFORMATION.
| 7 HANDLING AND STORAGE | |
HANDLING:
PRECAUTIONS FOR SAFE HANDLING:
AVOID CONTACT WITH THE EYES AND SKIN.
AVOID BREATHING MIST, VAPORS, OR SPRAY.
HANDLE WITH CARE.
USE ONLY IN WELL VENTILATED AREAS.
AVOID SPLASHES OR SPRAY IN ENCLOSED AREAS.
RAGS, METAL WOOLS / CUTTINGS / SHAVINGS AND WASTE PAPERS SOAKED WITH
PRODUCT MUST BE PLACED IN A SEALED METAL CONTAINER RATED FOR FLAMMABLE
WASTE.
INFORMATION ABOUT PROTECTION AGAINST EXPLOSIONS AND FIRES:
EMERGENCY COOLING MUST BE AVAILABLE IN CASE OF NEARBY FIRE.
KEEP IGNITION SOURCES AWAY - DO NOT SMOKE.
PREVENT IMPACT AND FRICTION.
FLAMMABLE GAS-AIR MIXTURES MAY BE FORMED IN EMPTY CONTAINERS/RECEPTACLES.
PRESSURIZED CONTAINER: PROTECT FROM SUNLIGHT AND DO NOT EXPOSE TO
TEMPERATURES EXCEEDING 120 DEG. F / 49 DEG. C, I.E. ELECTRIC LIGHTS.
DO NOT PIERCE OR BURN, EVEN AFTER USE.
DO NOT SPRAY ON A NAKED FLAME OR ANY INCANDESCENT MATERIAL.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
REQUIREMENTS TO BE MET BY STOREROOMS AND RECEPTACLES:
AVOID STORAGE NEAR EXTREME HEAT, IGNITION SOURCES OR OPEN FLAME.
INFORMATION ABOUT STORAGE IN ONE COMMON STORAGE FACILITY:
STORE AWAY FROM FOODSTUFFS.
STORE AWAY FROM OXIDIZING AGENTS.
FURTHER INFORMATION ABOUT STORAGE CONDITIONS:
STORE IN A COOL PLACE. HEAT WILL INCREASE PRESSURE AND MAY LEAD TO THE
RECEPTACLE BURSTING.
SPECIFIC END USE(S): NO RELEVANT INFORMATION AVAILABLE.
| 8 EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
COMPONENTS WITH LIMIT VALUES THAT REQUIRE MONITORING AT THE WORKPLACE:
127-18-4 TETRACHLOROETHYLENE:
PEL (USA):
LONG-TERM VALUE: 100 PPM
CEILING LIMIT VALUE: 200; 300* PPM
*5-MIN PEAK IN ANY 3 HRS
REL (USA): MINIMIZE WORKPLACE EXP. CONCS.;POCKET GUIDE APP. A
TLV (USA):
SHORT-TERM VALUE: 685 MG/M3, 100 PPM
LONG-TERM VALUE: 170 MG/M3, 25 PPM
BEI
EL (CANADA):
SHORT-TERM VALUE: 100 PPM
LONG-TERM VALUE: 25 PPM
IARC 2A
EV (CANADA):
SHORT-TERM VALUE: 100 PPM
LONG-TERM VALUE: 25 PPM
LMPE (MEXICO):
SHORT-TERM VALUE: 100 PPM
LONG-TERM VALUE: 25 PPM
A3, IBE
1330-20-7 XYLENE:
PEL (USA):
LONG-TERM VALUE: 435 MG/M3, 100 PPM
REL (USA):
SHORT-TERM VALUE: 655 MG/M3, 150 PPM
LONG-TERM VALUE: 435 MG/M3, 100 PPM
TLV (USA):
SHORT-TERM VALUE: 651 MG/M3, 150 PPM
LONG-TERM VALUE: 434 MG/M3, 100 PPM
BEI
EL (CANADA):
SHORT-TERM VALUE: 150 PPM
LONG-TERM VALUE: 100 PPM
EV (CANADA):
SHORT-TERM VALUE: 650 MG/M3, 150 PPM
LONG-TERM VALUE: 435 MG/M3, 100 PPM
LMPE (MEXICO):
SHORT-TERM VALUE: 150 PPM
LONG-TERM VALUE: 100 PPM
A4, IBE
124-38-9 CARBON DIOXIDE:
PEL (USA):
LONG-TERM VALUE: 9000 MG/M3, 5000 PPM
REL (USA):
SHORT-TERM VALUE: 54,000 MG/M3, 30,000 PPM
LONG-TERM VALUE: 9000 MG/M3, 5000 PPM
TLV (USA):
SHORT-TERM VALUE: 54,000 MG/M3, 30,000 PPM
LONG-TERM VALUE: 9000 MG/M3, 5000 PPM
EL (CANADA):
SHORT-TERM VALUE: 15000 PPM
LONG-TERM VALUE: 5000 PPM
EV (CANADA):
SHORT-TERM VALUE: 54,000 MG/M3, 30,000 PPM
LONG-TERM VALUE: 9,000 MG/M3, 5,000 PPM
LMPE (MEXICO):
SHORT-TERM VALUE: 30000 PPM
LONG-TERM VALUE: 5000 PPM
100-41-4 ETHYLBENZENE:
PEL (USA):
LONG-TERM VALUE: 435 MG/M3, 100 PPM
REL (USA):
SHORT-TERM VALUE: 545 MG/M3, 125 PPM
LONG-TERM VALUE: 435 MG/M3, 100 PPM
TLV (USA):
LONG-TERM VALUE: 87 MG/M3, 20 PPM
BEI
EL (CANADA):
LONG-TERM VALUE: 20 PPM
IARC 2B
EV (CANADA):
SHORT-TERM VALUE: 540 MG/M3, 125 PPM
LONG-TERM VALUE: 435 MG/M3, 100 PPM
LMPE (MEXICO):
LONG-TERM VALUE: 20 PPM
INGREDIENTS WITH BIOLOGICAL LIMIT VALUES:
127-18-4 TETRACHLOROETHYLENE:
BEI (USA): 3 PPM
MEDIUM: END-EXHALED AIR
TIME: PRIOR TO SHIFT
PARAMETER: TETRACHLOROETHYLENE 0.5 MG/L
MEDIUM: BLOOD
TIME: PRIOR TO SHIFT
PARAMETER: TETRACHLOROETHYLENE
1330-20-7 XYLENE:
BEI (USA): 1.5 G/G CREATININE
MEDIUM: URINE
TIME: END OF SHIFT
PARAMETER: METHYLHIPPURIC ACIDS
100-41-4 ETHYLBENZENE:
BEI (USA): 0.7 G/G CREATININE
MEDIUM: URINE
TIME: END OF SHIFT AT END OF WORKWEEK
PARAMETER:
SUM OF MANDELIC ACID AND PHENYLGLYOXYLIC ACID (NONSPECIFIC, SEMI-
QUANTITATIVE)
MEDIUM: END-EXHALED AIR
TIME: NOT CRITICAL
PARAMETER: ETHYL BENZENE (SEMI-QUANTITATIVE)
EXPOSURE CONTROLS:
GENERAL PROTECTIVE AND HYGIENIC MEASURES:
THE USUAL PRECAUTIONARY MEASURES FOR HANDLING CHEMICALS SHOULD BE
FOLLOWED.
KEEP AWAY FROM FOODSTUFFS, BEVERAGES AND FEED.
WASH HANDS BEFORE BREAKS AND AT THE END OF WORK.
AVOID CONTACT WITH THE EYES AND SKIN.
DO NOT INHALE GASES / FUMES / AEROSOLS.
DO NOT CARRY PRODUCT IMPREGNATED CLEANING CLOTHS IN TROUSER POCKETS.
ENGINEERING CONTROLS: NO RELEVANT INFORMATION AVAILABLE.
BREATHING EQUIPMENT:
USE SUITABLE RESPIRATORY PROTECTIVE DEVICE IN CASE OF INSUFFICIENT
VENTILATION.
FOR SPILLS, RESPIRATORY PROTECTION MAY BE ADVISABLE.
NIOSH OR EN APPROVED ORGANIC VAPOR RESPIRATOR EQUIPPED WITH A DUST/MIST
PREFILTER SHOULD BE USED.
PROTECTION OF HANDS: PROTECTIVE GLOVES
THE GLOVE MATERIAL HAS TO BE IMPERMEABLE AND RESISTANT TO THE PRODUCT/ THE
SUBSTANCE/ THE PREPARATION.
EYE PROTECTION: SAFETY GLASSES
BODY PROTECTION: PROTECTIVE WORK CLOTHING
LIMITATION AND SUPERVISION OF EXPOSURE INTO THE ENVIRONMENT:
NO RELEVANT INFORMATION AVAILABLE.
RISK MANAGEMENT MEASURES: NO RELEVANT INFORMATION AVAILABLE.
| 9 PHYSICAL AND CHEMICAL PROPERTIES | |
INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
APPEARANCE:
FORM: LIQUID
COLOR: CLEAR
ODOR: PLEASANT
ODOR THRESHOLD: NOT DETERMINED.
PH-VALUE: NOT DETERMINED.
MELTING POINT/MELTING RANGE: NOT DETERMINED.
BOILING POINT/BOILING RANGE: 110 DEG. C (230 DEG. F)
FLASH POINT: 53 DEG. C (127.4 DEG. F) (TOC OF LIQUID)
FLAMMABILITY (SOLID, GASEOUS): NOT APPLICABLE.
AUTO-IGNITION TEMPERATURE: NOT DETERMINED.
DECOMPOSITION TEMPERATURE: NOT DETERMINED.
DANGER OF EXPLOSION:
PRODUCT IS NOT EXPLOSIVE. HOWEVER, FORMATION OF EXPLOSIVE AIR/VAPOR
MIXTURES ARE POSSIBLE.
EXPLOSION LIMITS:
LOWER: APPROX.1.1 VOL %
UPPER: APPROX.7.0 VOL %
OXIDIZING PROPERTIES: NON-OXIDIZING.
VAPOR PRESSURE AT 20 DEG. C (68 DEG. F):
10 MMHG / 838 PSIG (LIQUID / PROPELLANT)
DENSITY:
RELATIVE DENSITY: 0.964
VAPOR DENSITY AT 20 DEG. C (68 DEG. F): >1 (AIR = 1)
EVAPORATION RATE AT 20 DEG. C (68 DEG. F): <1 (BUTYL ACETATE = 1)
SOLUBILITY IN / MISCIBILITY WITH WATER: NOT MISCIBLE OR DIFFICULT TO MIX.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT DETERMINED.
VISCOSITY:
DYNAMIC: NOT DETERMINED.
KINEMATIC: NOT DETERMINED.
OTHER INFORMATION: NO RELEVANT INFORMATION AVAILABLE.
| 10 STABILITY AND REACTIVITY | |
REACTIVITY: NO RELEVANT INFORMATION AVAILABLE.
CHEMICAL STABILITY:
THERMAL DECOMPOSITION / CONDITIONS TO BE AVOIDED:
NO DECOMPOSITION IF USED AND STORED ACCORDING TO SPECIFICATIONS.
POSSIBILITY OF HAZARDOUS REACTIONS:
DEVELOPS READILY FLAMMABLE GASES / FUMES.
CAN FORM EXPLOSIVE MIXTURES IN AIR IF HEATED ABOVE FLASH POINT AND/OR
WHEN SPRAYED OR ATOMIZED.
REACTS WITH STRONG ACIDS AND OXIDIZING AGENTS.
REACTS WITH CERTAIN METALS.
TOXIC FUMES MAY BE RELEASED IF HEATED ABOVE THE DECOMPOSITION POINT.
CONDITIONS TO AVOID: EXCESSIVE HEAT.
INCOMPATIBLE MATERIALS: OXIDIZERS
HAZARDOUS DECOMPOSITION PRODUCTS:
CARBON MONOXIDE AND CARBON DIOXIDE
HYDROCARBONS
CHLORINE COMPOUNDS
| 11 TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
LD/LC50 VALUES THAT ARE RELEVANT FOR CLASSIFICATION:
127-18-4 TETRACHLOROETHYLENE:
ORAL:
LD50: 2629 MG/KG (RAT)
1330-20-7 XYLENE:
ORAL:
LD50: 4300 MG/KG (RAT)
DERMAL:
LD50: 2000 MG/KG (RABBIT)
100-41-4 ETHYLBENZENE:
ORAL:
LD50: 3500 MG/KG (RAT)
DERMAL:
LD50: 17800 MG/KG (RABBIT)
PRIMARY IRRITANT EFFECT:
ON THE SKIN: IRRITANT TO SKIN AND MUCOUS MEMBRANES.
ON THE EYE: CAUSES EYE IRRITATION.
SENSITIZATION:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER):
127-18-4 TETRACHLOROETHYLENE 2A
100-41-4 ETHYLBENZENE 2B
NTP (NATIONAL TOXICOLOGY PROGRAM):
127-18-4 TETRACHLOROETHYLENE R
OSHA-CA (OCCUPATIONAL SAFETY & HEALTH ADMINISTRATION):
NONE OF THE INGREDIENTS ARE LISTED.
PROBABLE ROUTE(S) OF EXPOSURE:
INHALATION.
EYE CONTACT.
SKIN CONTACT.
GERM CELL MUTAGENICITY:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
CARCINOGENICITY: MAY CAUSE CANCER.
REPRODUCTIVE TOXICITY:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
STOT-SINGLE EXPOSURE:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
STOT-REPEATED EXPOSURE:
MAY CAUSE DAMAGE TO THE HEARING ORGANS THROUGH PROLONGED OR REPEATED
EXPOSURE.
ASPIRATION HAZARD: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
| 12 ECOLOGICAL INFORMATION | |
TOXICITY:
AQUATIC TOXICITY: TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
127-18-4 TETRACHLOROETHYLENE:
LC50: 4.99 MG/L (ONCORHYNCHUS MYKISS)
1330-20-7 XYLENE:
LC50: 13.4 MG/L (PIMEPHALES PROMELAS)
100-41-4 ETHYLBENZENE:
EC50: 1-10 MG/KG (DAPHNIA)
LC50: 1-10 MG/L (GREEN ALGAE (CHLOROPHYTA))
4.2 MG/L (ONCORHYNCHUS MYKISS)
PERSISTENCE AND DEGRADABILITY: NO RELEVANT INFORMATION AVAILABLE.
BIOACCUMULATIVE POTENTIAL: NO RELEVANT INFORMATION AVAILABLE.
MOBILITY IN SOIL: NO RELEVANT INFORMATION AVAILABLE.
ADDITIONAL ECOLOGICAL INFORMATION:
GENERAL NOTES:
DUE TO AVAILABLE DATA ON ELIMINABILITY/DECOMPOSITION AND BIOACCUMULATION
POTENTIAL PROLONGED TERM DAMAGE OF THE ENVIRONMENT CAN NOT BE EXCLUDED.
DO NOT ALLOW PRODUCT TO REACH GROUND WATER, WATER COURSE OR SEWAGE SYSTEM.
RESULTS OF PBT AND VPVB ASSESSMENT:
PBT: NOT APPLICABLE.
VPVB: NOT APPLICABLE.
OTHER ADVERSE EFFECTS: NO RELEVANT INFORMATION AVAILABLE.
| 13 DISPOSAL CONSIDERATIONS | |
WASTE TREATMENT METHODS:
RECOMMENDATION:
CONTACT WASTE PROCESSORS FOR RECYCLING INFORMATION.
THE USER OF THIS MATERIAL HAS THE RESPONSIBILITY TO DISPOSE OF UNUSED
MATERIAL, RESIDUES AND CONTAINERS IN COMPLIANCE WITH ALL RELEVANT LOCAL,
STATE AND FEDERAL LAWS AND REGULATIONS REGARDING TREATMENT, STORAGE AND
DISPOSAL FOR HAZARDOUS AND NONHAZARDOUS WASTES.
UNCLEANED PACKAGINGS:
RECOMMENDATION: DISPOSAL MUST BE MADE ACCORDING TO OFFICIAL REGULATIONS.
| 14 TRANSPORT INFORMATION | |
UN-NUMBER: UN1950
DOT, ADR/RID/ADN, IMDG, IATA:
UN PROPER SHIPPING NAME:
DOT: AEROSOLS
ADR/RID/ADN, IMDG: AEROSOLS
IATA:
AEROSOLS, FLAMMABLE, CONTAINING SUBSTANCES IN DIVISION 6.1, PACKING
GROUP III
TRANSPORT HAZARD CLASS(ES):
DOT: FLAMMABLE GAS, CLASS/DIVISION 2.1
CLASS: 2.1
LABEL: 2.1
ADR/RID/ADN:
CLASS 2.1, FLAMMABLE GASES
CLASS 6.1, TOXIC
CLASS: 2 5F
LABEL: 2.1+6.1
IMDG:
CLASS 2.1 - FLAMMABLE GASES
CLASS 6.1 - TOXIC
CLASS: 2.1
LABEL: 2.1/6.1
IATA:
CLASS 2.1, FLAMMABLE GASES
CLASS 6.1, TOXIC
CLASS: 2.1
LABEL: 2.1 (6.1)
PACKING GROUP: AEROSOLS ARE NOT ASSIGNED A PACKING GROUP.
ENVIRONMENTAL HAZARDS:
PRODUCT CONTAINS ENVIRONMENTALLY HAZARDOUS SUBSTANCES: TETRACHLOROETHYLENE
MARINE POLLUTANT:
ENVIRONMENT: YES
SPECIAL PRECAUTIONS FOR USER WARNING: GASES
DANGER CODE (KEMLER):
EMS NUMBER: F-D,S-U
SEGREGATION GROUPS: LIQUID HALOGENATED HYDROCARBONS
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL73/78 AND THE IBC CODE:
NOT APPLICABLE.
TRANSPORT/ADDITIONAL INFORMATION:
DOT:
LIMITED QUANTITTY FOR PACKAGES NOT PREPARED FOR AIR TRANSPORT
LIMITED QUANTITY FOR PACKAGES LESS THAN 30 KG GROSS AND INNER PACKAGINGS
LESS THAN 1000 ML.
ADR/RID/ADN:
LIMITED QUANTITTY FOR PACKAGES NOT PREPARED FOR AIR TRANSPORT
LIMITED QUANTITY FOR PACKAGES LESS THAN 30 KG GROSS AND INNER PACKAGINGS
LESS THAN 120 ML.
IMDG:
LIMITED QUANTITTY FOR PACKAGES NOT PREPARED FOR AIR TRANSPORT
LIMITED QUANTITY FOR PACKAGES LESS THAN 30 KG GROSS AND INNER PACKAGINGS
LESS THAN 120 ML.
IATA:
LIMITED QUANTITY MARKING FOR PACKAGES PREPARED FOR AIR TRANSPORT
LIMITED QUANTITY FOR PACKAGES LESS THAN 30 KG GROSS AND INNER PACKAGINGS
LESS THAN 120 ML.
| 15 REGULATORY INFORMATION | |
SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR THE
SUBSTANCE OR MIXTURE:
UNITED STATES (USA):
SARA:
SECTION 302 (EXTREMELY HAZARDOUS SUBSTANCES):
NONE OF THE INGREDIENTS ARE LISTED.
SECTION 355 (EXTREMELY HAZARDOUS SUBSTANCES):
NONE OF THE INGREDIENTS ARE LISTED.
SECTION 313 (SPECIFIC TOXIC CHEMICAL LISTINGS):
127-18-4 TETRACHLOROETHYLENE
1330-20-7 XYLENE
100-41-4 ETHYLBENZENE
TSCA (TOXIC SUBSTANCES CONTROL ACT): ALL INGREDIENTS ARE LISTED.
PROPOSITION 65 (CALIFORNIA):
CHEMICALS KNOWN TO CAUSE CANCER:
127-18-4 TETRACHLOROETHYLENE
100-41-4 ETHYLBENZENE
CHEMICALS KNOWN TO CAUSE DEVELOPMENTAL TOXICITY FOR FEMALES:
NONE OF THE INGREDIENTS ARE LISTED.
CHEMICALS KNOWN TO CAUSE DEVELOPMENTAL TOXICITY FOR MALES:
NONE OF THE INGREDIENTS ARE LISTED.
CHEMICALS KNOWN TO CAUSE DEVELOPMENTAL TOXICITY:
NONE OF THE INGREDIENTS ARE LISTED.
EPA (ENVIRONMENTAL PROTECTION AGENCY):
127-18-4 TETRACHLOROETHYLENE L
1330-20-7 XYLENE I
100-41-4 ETHYLBENZENE D
IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER):
127-18-4 TETRACHLOROETHYLENE 2A
100-41-4 ETHYLBENZENE 2B
CANADIAN DOMESTIC SUBSTANCES LIST (DSL) (SUBSTANCES NOT LISTED.):
ALL INGREDIENTS ARE LISTED.
| 16 OTHER INFORMATION | |
THIS INFORMATION IS BASED ON OUR PRESENT KNOWLEDGE. HOWEVER, THIS SHALL
NOT CONSTITUTE A GUARANTEE FOR ANY SPECIFIC PRODUCT FEATURES AND SHALL NOT
ESTABLISH A LEGALLY VALID CONTRACTUAL RELATIONSHIP.
ABBREVIATIONS AND ACRONYMS:
ADR:
EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS
GOODS BY ROAD
IMDG: INTERNATIONAL MARITIME CODE FOR DANGEROUS GOODS
DOT: US DEPARTMENT OF TRANSPORTATION
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
CAS:
CHEMICAL ABSTRACTS SERVICE (DIVISION OF THE AMERICAN CHEMICAL SOCIETY)
NFPA: NATIONAL FIRE PROTECTION ASSOCIATION (USA)
HMIS: HAZARDOUS MATERIALS IDENTIFICATION SYSTEM (USA)
LC50: LETHAL CONCENTRATION, 50 PERCENT
LD50: LETHAL DOSE, 50 PERCENT
PBT: PERSISTANT, BIO-ACCUMULABLE, TOXIC
VPVB: VERY PERSISTENT AND VERY BIOACCUMULATIVE
OSHA: OCCUPATIONAL SAFETY & HEALTH ADMINISTRATION
FLAM. AEROSOL 1: AEROSOLS - CATEGORY 1
PRESS. GAS: GASES UNDER PRESSURE - COMPRESSED GAS
PRESS. GAS: GASES UNDER PRESSURE - LIQUEFIED GAS
FLAM. LIQ. 2: FLAMMABLE LIQUIDS - CATEGORY 2
FLAM. LIQ. 3: FLAMMABLE LIQUIDS - CATEGORY 3
ACUTE TOX. 4: ACUTE TOXICITY - CATEGORY 4
SKIN IRRIT. 2: SKIN CORROSION/IRRITATION - CATEGORY 2
EYE IRRIT. 2A: SERIOUS EYE DAMAGE/EYE IRRITATION - CATEGORY 2A
CARC. 1B: CARCINOGENICITY - CATEGORY 1B
CARC. 2: CARCINOGENICITY - CATEGORY 2
STOT SE 3: SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) - CATEGORY 3
STOT RE 2: SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - CATEGORY 2
ASP. TOX. 1: ASPIRATION HAZARD - CATEGORY 1
SOURCES:
WEBSITE, EUROPEAN CHEMICALS AGENCY (ECHA.EUROPA.EU)
WEBSITE, US EPA SUBSTANCE REGISTRY SERVICES(OFMPUB.EPA.GOV/SORINTERNET
/REGISTRY/SUBSTREG/HOME/OVERVIEW/HOME.DO)
WEBSITE, CHEMICAL ABSTRACTS REGISTRY, AMERICAN CHEMICAL SOCIETY
(WWW.CAS.ORG)
PATTY'S INDUSTRIAL HYGIENE, 6TH ED., ROSE, VERNON, ED.
ISBN: 978-0-470-07488-6
CASARETT AND DOULL'S TOXICOLOGY:
THE BASIC SCIENCE OF POISONS, 8TH ED., KLAASEN, CURTIS D., ED., ISBN:
978-0-07-176923-5.
SAFETY DATA SHEETS, INDIVIDUAL MANUFACTURERS
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