| Common Name: | SHEILA SHINE (LIQUID) |
| Manufacturer: | SHEILA SHINE |
| SDS Revision Date: | 10/10/2019 |
| SDS Format: | No Format Specified |
| Item Number(s): | 392C92, 5URF8, 5URF9, 820RW6 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
ACCORDING TO OSHA HCS (29CFR 1910.1200) AND WHMIS 2015 REGULATIONS
REVISION: OCTOBER 10, 2019
| 1 IDENTIFICATION |  |
PRODUCT IDENTIFIER:
TRADE NAME: SHEILA SHINE (LIQUID)
OTHER MEANS OF IDENTIFICATION: NO OTHER IDENTIFIERS
RECOMMENDED USE AND RESTRICTION ON USE:
RECOMMENDED USE: POLISHING AGENT/ BURNISHING COMPOUND
RESTRICTIONS ON USE: NO RELEVANT INFORMATION AVAILABLE.
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
MANUFACTURER/SUPPLIER:
SHEILA SHINE INC.
7725 W 2ND COURT
HIALEAH, FL 33014
PHONE: (305) 557-1729
EMERGENCY TELEPHONE NUMBER:
CHEMTEL INC.
(800)255-3924 (NORTH AMERICA)
+1 (813)248-0585 (INTERNATIONAL)
| 2 HAZARD(S) IDENTIFICATION | |
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
FLAM. LIQ. 3 H226: FLAMMABLE LIQUID AND VAPOR.
SKIN IRRIT. 2 H315: CAUSES SKIN IRRITATION.
EYE IRRIT. 2A H319: CAUSES SERIOUS EYE IRRITATION.
CARC. 1B H350: MAY CAUSE CANCER.
STOT RE 2 H373:
MAY CAUSE DAMAGE TO THE HEARING ORGANS THROUGH PROLONGED OR REPEATED
EXPOSURE. ROUTE OF EXPOSURE: ORAL, INHALATION.
ASP. TOX. 1 H304: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
LABEL ELEMENTS:
GHS LABEL ELEMENTS:
THE PRODUCT IS CLASSIFIED AND LABELED ACCORDING TO THE GLOBALLY HARMONIZED
SYSTEM (GHS).
HAZARD PICTOGRAMS:
GHS02: FLAME
GHS07: EXCLAMATION MARK
GHS08: HEALTH HAZARD
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
H226: FLAMMABLE LIQUID AND VAPOR.
H315: CAUSES SKIN IRRITATION.
H319: CAUSES SERIOUS EYE IRRITATION.
H350: MAY CAUSE CANCER.
H373:
MAY CAUSE DAMAGE TO THE HEARING ORGANS THROUGH PROLONGED OR REPEATED
EXPOSURE. ROUTE OF EXPOSURE: ORAL, INHALATION.
H304: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
PRECAUTIONARY STATEMENTS:
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
P210: KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING.
P233: KEEP CONTAINER TIGHTLY CLOSED.
P240: GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT.
P241: USE EXPLOSION-PROOF ELECTRICAL/VENTILATING/LIGHTING/EQUIPMENT.
P242: USE ONLY NON-SPARKING TOOLS.
P243: TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
P264: WASH THOROUGHLY AFTER HANDLING.
P280: WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION.
P301+P310:
IF SWALLOWED: IMMEDIATELY CALL A POISON CENTER/DOCTOR.
P331: DO NOT INDUCE VOMITING.
P303+P361+P353:
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH WATER/
SHOWER.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
P308+P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
P314: GET MEDICAL ADVICE/ATTENTION IF YOU FEEL UNWELL.
P332+P313:
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
P362+P364: TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
P337+P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
P370+P378:
IN CASE OF FIRE: USE FOAM, POWDER, OR CARBON DIOXIDE FOR EXTINCTION.
P403+P235: STORE IN A WELL-VENTILATED PLACE. KEEP COOL.
P405: STORE LOCKED UP.
P501:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL/REGIONAL/NATIONAL/
INTERNATIONAL REGULATIONS.
OTHER HAZARDS:
THERE ARE NO OTHER HAZARDS NOT OTHERWISE CLASSIFIED THAT HAVE BEEN
IDENTIFIED.
| 3 COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL CHARACTERIZATION: MIXTURES
COMPONENTS:
64741-89-5 DISTILLATES (PETROLEUM), SOLVENT-REFINED LIGHT 30-60%
PARAFFINIC
CARC. 1B, H350
127-18-4 TETRACHLOROETHYLENE 10-30%
CARC. 2, H351
64741-88-4 DISTILLATES (PETROLEUM), SOLVENT-REFINED 10-30%
HEAVY PARAFFINIC
CARC. 1B, H350
1330-20-7 XYLENE 7-13%
FLAM. LIQ. 3, H226
ASP. TOX. 1, H304
ACUTE TOX. 4, H312; ACUTE
TOX. 4, H332; SKIN IRRIT. 2, H315; EYE IRRIT.
2A, H319; STOT SE 3, H335
100-41-4 ETHYLBENZENE 1-5%
FLAM. LIQ. 2, H225
CARC. 2, H351; STOT RE 2, H373;
ASP. TOX. 1, H304
ACUTE TOX. 4, H332
ADDITIONAL INFORMATION:
FOR THE WORDING OF THE LISTED HAZARD STATEMENTS, REFER TO SECTION 16.
FOR THE LISTED INGREDIENT(S), THE IDENTITY AND/OR EXACT PERCENTAGE(S) ARE
BEING WITHHELD AS A TRADE SECRET.
| 4 FIRST-AID MEASURES | |
DESCRIPTION OF FIRST AID MEASURES:
AFTER INHALATION:
SUPPLY FRESH AIR; CONSULT DOCTOR IN CASE OF COMPLAINTS.
PROVIDE OXYGEN TREATMENT IF AFFECTED PERSON HAS DIFFICULTY BREATHING.
IN CASE OF IRREGULAR BREATHING OR RESPIRATORY ARREST PROVIDE ARTIFICIAL
RESPIRATION.
IN CASE OF UNCONSCIOUSNESS PLACE PATIENT STABLY IN SIDE POSITION FOR
TRANSPORTATION.
AFTER SKIN CONTACT:
IMMEDIATELY WASH WITH WATER AND SOAP AND RINSE THOROUGHLY.
SEEK MEDICAL TREATMENT IN CASE OF COMPLAINTS.
AFTER EYE CONTACT:
REMOVE CONTACT LENSES IF WORN.
RINSE OPENED EYE FOR SEVERAL MINUTES UNDER RUNNING WATER. IF SYMPTOMS
PERSIST, CONSULT A DOCTOR.
AFTER SWALLOWING:
RINSE OUT MOUTH AND THEN DRINK PLENTY OF WATER.
DO NOT INDUCE VOMITING; IMMEDIATELY CALL FOR MEDICAL HELP.
A PERSON VOMITING WHILE LYING ON THEIR BACK SHOULD BE TURNED ONTO THEIR
SIDE.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
COUGHING
DIZZINESS
BREATHING DIFFICULTY
IRRITANT TO SKIN AND MUCOUS MEMBRANES.
CAUSES EYE IRRITATION.
NAUSEA
GASTRIC OR INTESTINAL DISORDERS WHEN INGESTED.
DISORIENTATION
DANGER:
MAY BE HARMFUL IF INHALED.
MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
DANGER OF IMPAIRED BREATHING.
DANGER OF DISTURBED CARDIAC RHYTHM.
DANGER OF CONVULSION.
CARCINOGENIC.
MAY CAUSE DAMAGE TO THE HEARING ORGANS THROUGH PROLONGED OR REPEATED
EXPOSURE. ROUTE OF EXPOSURE: ORAL, INHALATION.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED:
MEDICAL SUPERVISION FOR AT LEAST 48 HOURS.
LATER OBSERVATION FOR PNEUMONIA AND PULMONARY EDEMA.
IF NECESSARY OXYGEN RESPIRATION TREATMENT.
MONITOR CIRCULATION.
| 5 FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING AGENTS:
WATER FOG / HAZE
FOAM
FIRE-EXTINGUISHING POWDER
CARBON DIOXIDE
FOR SAFETY REASONS UNSUITABLE EXTINGUISHING AGENTS: WATER STREAM.
SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
DURING HEATING OR IN CASE OF FIRE POISONOUS GASES ARE PRODUCED.
ADVICE FOR FIREFIGHTERS:
PROTECTIVE EQUIPMENT:
WEAR SELF-CONTAINED RESPIRATORY PROTECTIVE DEVICE.
WEAR FULLY PROTECTIVE SUIT.
ADDITIONAL INFORMATION:
ELIMINATE ALL IGNITION SOURCES IF SAFE TO DO SO.
COOL ENDANGERED CONTAINERS WITH WATER FOG.
| 6 ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
USE RESPIRATORY PROTECTIVE DEVICE AGAINST THE EFFECTS OF FUMES/DUST/
AEROSOL.
WEAR PROTECTIVE EQUIPMENT. KEEP UNPROTECTED PERSONS AWAY.
ENSURE ADEQUATE VENTILATION.
KEEP AWAY FROM IGNITION SOURCES.
PARTICULAR DANGER OF SLIPPING ON LEAKED/SPILLED PRODUCT.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW TO ENTER SEWERS/ SURFACE OR GROUND WATER.
INFORM RESPECTIVE AUTHORITIES IN CASE OF SEEPAGE INTO WATER COURSE OR
SEWAGE SYSTEM.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
ABSORB WITH NON-COMBUSTIBLE LIQUID-BINDING MATERIAL (SAND, DIATOMITE, ACID
BINDERS, UNIVERSAL BINDERS).
REMOVE FROM THE WATER SURFACE (E.G. SKIM OR SUCK OFF).
SEND FOR RECOVERY OR DISPOSAL IN SUITABLE RECEPTACLES.
REFERENCE TO OTHER SECTIONS:
SEE SECTION 7 FOR INFORMATION ON SAFE HANDLING.
SEE SECTION 8 FOR INFORMATION ON PERSONAL PROTECTION EQUIPMENT.
SEE SECTION 13 FOR DISPOSAL INFORMATION.
| 7 HANDLING AND STORAGE | |
HANDLING:
PRECAUTIONS FOR SAFE HANDLING:
KEEP AWAY FROM HEAT AND DIRECT SUNLIGHT.
AVOID SPLASHES OR SPRAY IN ENCLOSED AREAS.
USE ONLY IN WELL VENTILATED AREAS.
RAGS, METAL WOOLS / CUTTINGS / SHAVINGS AND WASTE PAPERS SOAKED WITH
PRODUCT MUST BE PLACED IN A SEALED METAL CONTAINER RATED FOR FLAMMABLE
WASTE.
INFORMATION ABOUT PROTECTION AGAINST EXPLOSIONS AND FIRES:
EMERGENCY COOLING MUST BE AVAILABLE IN CASE OF NEARBY FIRE.
KEEP IGNITION SOURCES AWAY - DO NOT SMOKE.
PREVENT IMPACT AND FRICTION.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
REQUIREMENTS TO BE MET BY STOREROOMS AND RECEPTACLES:
AVOID STORAGE NEAR EXTREME HEAT, IGNITION SOURCES OR OPEN FLAME.
STORE IN COOL, DRY CONDITIONS IN WELL SEALED RECEPTACLES.
INFORMATION ABOUT STORAGE IN ONE COMMON STORAGE FACILITY:
STORE AWAY FROM FOODSTUFFS.
STORE AWAY FROM OXIDIZING AGENTS.
SPECIFIC END USE(S): NO RELEVANT INFORMATION AVAILABLE.
| 8 EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
COMPONENTS WITH LIMIT VALUES THAT REQUIRE MONITORING AT THE WORKPLACE:
127-18-4 TETRACHLOROETHYLENE:
PEL (USA) LONG-TERM VALUE: 100 PPM
CEILING LIMIT VALUE: 200; 300* PPM
*5-MIN PEAK IN ANY 3 HRS
REL (USA): MINIMIZE WORKPLACE EXP. CONCS.;POCKET GUIDE APP. A
TLV (USA):
SHORT-TERM VALUE: 685 MG/M3, 100 PPM
LONG-TERM VALUE: 170 MG/M3, 25 PPM
BEI
EL (CANADA):
SHORT-TERM VALUE: 100 PPM
LONG-TERM VALUE: 25 PPM
IARC 2A
EV (CANADA):
SHORT-TERM VALUE: 100 PPM
LONG-TERM VALUE: 25 PPM
LMPE (MEXICO):
SHORT-TERM VALUE: 100 PPM
LONG-TERM VALUE: 25 PPM
A3, IBE
1330-20-7 XYLENE:
PEL (USA):
LONG-TERM VALUE: 435 MG/M3, 100 PPM
REL (USA):
SHORT-TERM VALUE: 655 MG/M3, 150 PPM
LONG-TERM VALUE: 435 MG/M3, 100 PPM
TLV (USA):
SHORT-TERM VALUE: 651 MG/M3, 150 PPM
LONG-TERM VALUE: 434 MG/M3, 100 PPM
BEI
EL (CANADA):
SHORT-TERM VALUE: 150 PPM
LONG-TERM VALUE: 100 PPM
EV (CANADA):
SHORT-TERM VALUE: 650 MG/M3, 150 PPM
LONG-TERM VALUE: 435 MG/M3, 100 PPM
LMPE (MEXICO):
SHORT-TERM VALUE: 150 PPM
LONG-TERM VALUE: 100 PPM
A4, IBE
100-41-4 ETHYLBENZENE:
PEL (USA):
LONG-TERM VALUE: 435 MG/M3, 100 PPM
REL (USA):
SHORT-TERM VALUE: 545 MG/M3, 125 PPM
LONG-TERM VALUE: 435 MG/M3, 100 PPM
TLV (USA):
LONG-TERM VALUE: 87 MG/M3, 20 PPM
BEI
EL (CANADA):
LONG-TERM VALUE: 20 PPM
IARC 2B
EV (CANADA):
SHORT-TERM VALUE: 540 MG/M3, 125 PPM
LONG-TERM VALUE: 435 MG/M3, 100 PPM
LMPE (MEXICO):
LONG-TERM VALUE: 20 PPM
INGREDIENTS WITH BIOLOGICAL LIMIT VALUES:
127-18-4 TETRACHLOROETHYLENE:
BEI (USA):
3 PPM
MEDIUM: END-EXHALED AIR
TIME: PRIOR TO SHIFT
PARAMETER: TETRACHLOROETHYLENE
0.5 MG/L
MEDIUM: BLOOD
TIME: PRIOR TO SHIFT
PARAMETER: TETRACHLOROETHYLENE
1330-20-7 XYLENE:
BEI (USA):
1.5 G/G CREATININE
MEDIUM: URINE
TIME: END OF SHIFT
PARAMETER: METHYLHIPPURIC ACIDS
100-41-4 ETHYLBENZENE:
BEI (USA):
0.7 G/G CREATININE
MEDIUM: URINE
TIME: END OF SHIFT AT END OF WORKWEEK
PARAMETER:
SUM OF MANDELIC ACID AND PHENYLGLYOXYLIC ACID (NONSPECIFIC, SEMI-
QUANTITATIVE)
MEDIUM: END-EXHALED AIR
TIME: NOT CRITICAL
PARAMETER: ETHYL BENZENE (SEMI-QUANTITATIVE)
EXPOSURE CONTROLS:
GENERAL PROTECTIVE AND HYGIENIC MEASURES:
THE USUAL PRECAUTIONARY MEASURES FOR HANDLING CHEMICALS SHOULD BE
FOLLOWED.
KEEP AWAY FROM FOODSTUFFS, BEVERAGES AND FEED.
WASH HANDS BEFORE BREAKS AND AT THE END OF WORK.
AVOID CONTACT WITH THE EYES AND SKIN.
DO NOT INHALE GASES / FUMES / AEROSOLS.
DO NOT CARRY PRODUCT IMPREGNATED CLEANING CLOTHS IN TROUSER POCKETS.
ENGINEERING CONTROLS: NO RELEVANT INFORMATION AVAILABLE.
BREATHING EQUIPMENT:
USE SUITABLE RESPIRATORY PROTECTIVE DEVICE IN CASE OF INSUFFICIENT
VENTILATION.
USE SUITABLE RESPIRATORY PROTECTIVE DEVICE WHEN AEROSOL OR MIST IS FORMED.
FOR SPILLS, RESPIRATORY PROTECTION MAY BE ADVISABLE.
NIOSH OR EN APPROVED ORGANIC VAPOR RESPIRATOR EQUIPPED WITH A DUST/MIST
PREFILTER SHOULD BE USED.
PROTECTION OF HANDS: PROTECTIVE GLOVES
THE GLOVE MATERIAL HAS TO BE IMPERMEABLE AND RESISTANT TO THE PRODUCT/
THE SUBSTANCE/ THE PREPARATION.
EYE PROTECTION: SAFETY GLASSES
BODY PROTECTION: PROTECTIVE WORK CLOTHING
LIMITATION AND SUPERVISION OF EXPOSURE INTO THE ENVIRONMENT:
NO RELEVANT INFORMATION AVAILABLE.
RISK MANAGEMENT MEASURES: NO RELEVANT INFORMATION AVAILABLE.
| 9 PHYSICAL AND CHEMICAL PROPERTIES | |
INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
APPEARANCE:
FORM: LIQUID
COLOR: CLEAR
ODOR: PLEASANT
ODOR THRESHOLD: NOT DETERMINED.
PH-VALUE: NOT DETERMINED.
MELTING POINT/MELTING RANGE: NOT DETERMINED.
BOILING POINT/BOILING RANGE: 112 DEG. C (233.6 DEG. F)
FLASH POINT: 56 DEG. C (132.8 DEG. F) (TOC)
FLAMMABILITY (SOLID, GASEOUS): NOT APPLICABLE.
AUTO-IGNITION TEMPERATURE: NOT DETERMINED.
DECOMPOSITION TEMPERATURE: NOT DETERMINED.
DANGER OF EXPLOSION:
PRODUCT IS NOT EXPLOSIVE. HOWEVER, FORMATION OF EXPLOSIVE AIR/VAPOR
MIXTURES ARE POSSIBLE.
EXPLOSION LIMITS:
LOWER: APPROX.1.1 VOL %
UPPER: APPROX.7.0 VOL %
OXIDIZING PROPERTIES: NON-OXIDIZING.
VAPOR PRESSURE AT 20 DEG. C (68 DEG. F): 10 MMHg
DENSITY:
RELATIVE DENSITY AT 20 DEG. C (68 DEG. F): 0.964 G/CM3 (8.04 LBS/GAL)
VAPOR DENSITY AT 20 DEG. C (68 DEG. F): >1 (AIR = 1)
EVAPORATION RATE AT 20 DEG. C (68 DEG. F): <1 (BUTYL ACETATE = 1)
SOLUBILITY IN / MISCIBILITY WITH WATER: NOT MISCIBLE OR DIFFICULT TO MIX.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT DETERMINED.
VISCOSITY:
DYNAMIC: NOT DETERMINED.
KINEMATIC AT 40 DEG. C (104 DEG. F): <20.5 MM2/S
OTHER INFORMATION: NO RELEVANT INFORMATION AVAILABLE.
| 10 STABILITY AND REACTIVITY | |
REACTIVITY: NO RELEVANT INFORMATION AVAILABLE.
CHEMICAL STABILITY:
THERMAL DECOMPOSITION / CONDITIONS TO BE AVOIDED:
NO DECOMPOSITION IF USED AND STORED ACCORDING TO SPECIFICATIONS.
POSSIBILITY OF HAZARDOUS REACTIONS:
DEVELOPS READILY FLAMMABLE GASES / FUMES.
CAN FORM EXPLOSIVE MIXTURES IN AIR IF HEATED ABOVE FLASH POINT AND/OR WHEN
SPRAYED OR ATOMIZED.
USED EMPTY CONTAINERS MAY CONTAIN PRODUCT GASES WHICH FORM EXPLOSIVE
MIXTURES WITH AIR.
TOXIC FUMES MAY BE RELEASED IF HEATED ABOVE THE DECOMPOSITION POINT.
REACTS WITH STRONG ACIDS AND OXIDIZING AGENTS.
REACTS WITH CERTAIN METALS.
CONDITIONS TO AVOID: EXCESSIVE HEAT.
INCOMPATIBLE MATERIALS: NO RELEVANT INFORMATION AVAILABLE.
HAZARDOUS DECOMPOSITION PRODUCTS:
CARBON MONOXIDE AND CARBON DIOXIDE
HYDROCARBONS
CHLORINE COMPOUNDS
| 11 TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
LD/LC50 VALUES THAT ARE RELEVANT FOR CLASSIFICATION:
127-18-4 TETRACHLOROETHYLENE:
ORAL:
LD50: 2629 MG/KG (RAT)
1330-20-7 XYLENE:
ORAL:
LD50: 4300 MG/KG (RAT)
DERMAL:
LD50: 2000 MG/KG (RABBIT)
100-41-4 ETHYLBENZENE:
ORAL:
LD50: 3500 MG/KG (RAT)
DERMAL:
LD50: 17800 MG/KG (RABBIT)
PRIMARY IRRITANT EFFECT:
ON THE SKIN: IRRITANT TO SKIN AND MUCOUS MEMBRANES.
ON THE EYE: CAUSES EYE IRRITATION.
SENSITIZATION:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER):
127-18-4 TETRACHLOROETHYLENE: 2A
100-41-4 ETHYLBENZENE: 2B
NTP (NATIONAL TOXICOLOGY PROGRAM):
127-18-4 TETRACHLOROETHYLENE: R
OSHA-CA (OCCUPATIONAL SAFETY & HEALTH ADMINISTRATION):
NONE OF THE INGREDIENTS ARE LISTED.
PROBABLE ROUTE(S) OF EXPOSURE:
INGESTION.
INHALATION.
EYE CONTACT.
SKIN CONTACT.
GERM CELL MUTAGENICITY:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
CARCINOGENICITY: MAY CAUSE CANCER.
REPRODUCTIVE TOXICITY:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
STOT-SINGLE EXPOSURE:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
STOT-REPEATED EXPOSURE:
MAY CAUSE DAMAGE TO THE HEARING ORGANS THROUGH PROLONGED OR REPEATED
EXPOSURE. ROUTE OF EXPOSURE: ORAL, INHALATION.
ASPIRATION HAZARD: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
| 12 ECOLOGICAL INFORMATION | |
TOXICITY:
AQUATIC TOXICITY: TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
127-18-4 TETRACHLOROETHYLENE:
LC50: 4.99 MG/L (ONCORHYNCHUS MYKISS)
1330-20-7 XYLENE:
LC50: 13.4 MG/L (PIMEPHALES PROMELAS)
100-41-4 ETHYLBENZENE:
EC50: 1-10 MG/KG (DAPHNIA)
LC50: 1-10 MG/L (GREEN ALGAE (CHLOROPHYTA))
4.2 MG/L (ONCORHYNCHUS MYKISS)
PERSISTENCE AND DEGRADABILITY:
THE PRODUCT IS PARTIALLY BIODEGRADABLE. SIGNIFICANT RESIDUALS REMAIN.
BIOACCUMULATIVE POTENTIAL: NO RELEVANT INFORMATION AVAILABLE.
MOBILITY IN SOIL: NO RELEVANT INFORMATION AVAILABLE.
ADDITIONAL ECOLOGICAL INFORMATION:
GENERAL NOTES:
DUE TO AVAILABLE DATA ON ELIMINABILITY/DECOMPOSITION AND BIOACCUMULATION
POTENTIAL PROLONGED TERM DAMAGE OF THE ENVIRONMENT CAN NOT BE EXCLUDED.
DO NOT ALLOW PRODUCT TO REACH GROUND WATER, WATER COURSE OR SEWAGE SYSTEM.
OTHER ADVERSE EFFECTS: NO RELEVANT INFORMATION AVAILABLE.
| 13 DISPOSAL CONSIDERATIONS | |
WASTE TREATMENT METHODS:
RECOMMENDATION:
THE USER OF THIS MATERIAL HAS THE RESPONSIBILITY TO DISPOSE OF UNUSED
MATERIAL, RESIDUES AND CONTAINERS IN COMPLIANCE WITH ALL RELEVANT LOCAL,
STATE AND FEDERAL LAWS AND REGULATIONS REGARDING TREATMENT, STORAGE AND
DISPOSAL FOR HAZARDOUS AND NONHAZARDOUS WASTES.
UNCLEANED PACKAGINGS:
RECOMMENDATION: DISPOSAL MUST BE MADE ACCORDING TO OFFICIAL REGULATIONS.
| 14 TRANSPORT INFORMATION | |
UN-NUMBER:
DOT, ADR/RID/ADN, IMDG, IATA: UN1992
UN PROPER SHIPPING NAME:
DOT: FLAMMABLE LIQUIDS, TOXIC, N.O.S. (ETHYLBENZENE, TETRACHLOROETHYLENE)
ADR/RID/ADN, IMDG:
FLAMMABLE LIQUID, TOXIC, N.O.S. (ETHYLBENZENE, TETRACHLOROETHYLENE)
IATA: FLAMMABLE LIQUID, TOXIC, N.O.S. (ETHYLBENZENE, TETRACHLOROETHYLENE)
TRANSPORT HAZARD CLASS(ES):
DOT:
FLAMMABLE LIQUID, CLASS/DIVISION 3.1, 3.2, 3.3
POISON, CLASS/DIVISION 6.1 PACKING GROUP I OR II
CLASS: 3
LABEL: 3, 6.1
ADR/RID/ADN:
CLASS 3, FLAMMABLE LIQUIDS
CLASS 6.1, TOXIC
CLASS: 3 (FT1)
LABEL: 3, 6.1
IMDG:
CLASS 3 - FLAMMABLE LIQUIDS
CLASS 6.1 - TOXIC
CLASS: 3
LABEL: 3/6.1
IATA:
CLASS 3, FLAMMABLE LIQUIDS
CLASS 6.1, TOXIC
CLASS: 3
LABEL: 3 (6.1)
PACKING GROUP:
DOT, ADR/RID/ADN, IMDG, IATA: III
ENVIRONMENTAL HAZARDS PRODUCT CONTAINS ENVIRONMENTALLY HAZARDOUS
SUBSTANCES: TETRACHLOROETHYLENE
MARINE POLLUTANT:
ENVIRONMENT: YES
SPECIAL PRECAUTIONS FOR USER:
WARNING: FLAMMABLE LIQUIDS
DANGER CODE (KEMLER): 36
EMS NUMBER: F-E,S-D
SEGREGATION GROUPS: LIQUID HALOGENATED HYDROCARBONS
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL73/78 AND THE IBC CODE:
NOT APPLICABLE.
TRANSPORT/ADDITIONAL INFORMATION:
DOT: LIMITED QUANTITY FOR PACKAGES NOT PREPARED FOR AIR TRANSPORT
LIMITED QUANTITY FOR PACKAGES LESS THAN 30 KG GROSS AND INNER PACKAGINGS
LESS THAN 5 L EACH.
LABELING AS A MARINE POLLUTANT IS ONLY REQUIRED FOR BULK SINGLE PACKAGE
SHIPMENTS. BULK PACKAGING CONSISTS OF A MAXIMUM CAPACITY OF GREATER THAN
450 L (119 GALLONS) FOR A LIQUID AND A MAXIMUM NET MASS GREATER THAN 400
KG (882 POUNDS) FOR A SOLID. (SEE 171.4(C))
ADR/RID/ADN: LIMITED QUANTITY FOR PACKAGES NOT PREPARED FOR AIR TRANSPORT
LIMITED QUANTITY FOR PACKAGES LESS THAN 30 KG GROSS AND INNER PACKAGINGS
LESS THAN 5 L EACH.
MARINE POLLUTANTS PACKAGED IN SINGLE OR COMBINATION PACKAGINGS CONTAINING
A NET QUANTITY PER SINGLE OR INNER PACKAGING OF 5 L OR LESS FOR LIQUIDS OR
HAVING A NET MASS PER SINGLE OR INNER PACKAGING OF 5 KG OR LESS FOR SOLIDS
ARE NOT SUBJECT TO PROVISIONS RELEVANT TO MARINE POLLUTANTS. (SEE 5.2.1.
8.1)
IMDG: LIMITED QUANTITY FOR PACKAGES NOT PREPARED FOR AIR TRANSPORT
LIMITED QUANTITY FOR PACKAGES LESS THAN 30 KG GROSS AND INNER PACKAGINGS
LESS THAN 5 L EACH.
MARINE POLLUTANTS PACKAGED IN SINGLE OR COMBINATION PACKAGINGS CONTAINING
A NET QUANTITY PER SINGLE OR INNER PACKAGING OF 5 L OR LESS FOR LIQUIDS OR
HAVING A NET MASS PER SINGLE OR INNER PACKAGING OF 5 KG OR LESS FOR SOLIDS
ARE NOT SUBJECT TO PROVISIONS RELEVANT TO MARINE POLLUTANTS. (SEE 2.10.
2.7)
IATA: LIMITED QUANTITY MARKING FOR PACKAGES PREPARED FOR AIR TRANSPORT
LIMITED QUANTITY FOR PACKAGES LESS THAN 30 KG GROSS AND INNER PACKAGINGS
LESS THAN 1 L EACH / 2 L NET.
| 15 REGULATORY INFORMATION | |
SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR THE
SUBSTANCE OR MIXTURE
UNITED STATES (USA):
SARA:
SECTION 302 (EXTREMELY HAZARDOUS SUBSTANCES):
NONE OF THE INGREDIENTS ARE LISTED.
SECTION 355 (EXTREMELY HAZARDOUS SUBSTANCES):
NONE OF THE INGREDIENTS ARE LISTED.
SECTION 313 (SPECIFIC TOXIC CHEMICAL LISTINGS):
127-18-4 TETRACHLOROETHYLENE
1330-20-7 XYLENE
100-41-4 ETHYLBENZENE
TSCA (TOXIC SUBSTANCES CONTROL ACT): ALL INGREDIENTS ARE LISTED OR EXEMPT.
PROPOSITION 65 (CALIFORNIA):
CHEMICALS KNOWN TO CAUSE CANCER:
127-18-4 TETRACHLOROETHYLENE
100-41-4 ETHYLBENZENE
CHEMICALS KNOWN TO CAUSE DEVELOPMENTAL TOXICITY FOR FEMALES:
NONE OF THE INGREDIENTS ARE LISTED.
CHEMICALS KNOWN TO CAUSE DEVELOPMENTAL TOXICITY FOR MALES:
NONE OF THE INGREDIENTS ARE LISTED.
CHEMICALS KNOWN TO CAUSE DEVELOPMENTAL TOXICITY:
NONE OF THE INGREDIENTS ARE LISTED.
EPA (ENVIRONMENTAL PROTECTION AGENCY):
127-18-4 TETRACHLOROETHYLENE: L
1330-20-7 XYLENE: I
100-41-4 ETHYLBENZENE: D
IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER):
127-18-4 TETRACHLOROETHYLENE: 2A
100-41-4 ETHYLBENZENE: 2B
CANADIAN DOMESTIC SUBSTANCES LIST (DSL):
ALL INGREDIENTS ARE LISTED OR EXEMPT.
| 16 OTHER INFORMATION | |
THIS INFORMATION IS BASED ON OUR PRESENT KNOWLEDGE. HOWEVER, THIS SHALL
NOT CONSTITUTE A GUARANTEE FOR ANY SPECIFIC PRODUCT FEATURES AND SHALL NOT
ESTABLISH A LEGALLY VALID CONTRACTUAL RELATIONSHIP.
ABBREVIATIONS AND ACRONYMS:
ADR:
EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS
GOODS BY ROAD
IMDG: INTERNATIONAL MARITIME CODE FOR DANGEROUS GOODS
DOT: US DEPARTMENT OF TRANSPORTATION
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
CAS:
CHEMICAL ABSTRACTS SERVICE (DIVISION OF THE AMERICAN CHEMICAL SOCIETY)
LC50: LETHAL CONCENTRATION, 50 PERCENT
LD50: LETHAL DOSE, 50 PERCENT
OSHA: OCCUPATIONAL SAFETY & HEALTH ADMINISTRATION
FLAM. LIQ. 2: FLAMMABLE LIQUIDS - CATEGORY 2
FLAM. LIQ. 3: FLAMMABLE LIQUIDS - CATEGORY 3
ACUTE TOX. 4: ACUTE TOXICITY - CATEGORY 4
SKIN IRRIT. 2: SKIN CORROSION/IRRITATION - CATEGORY 2
EYE IRRIT. 2A: SERIOUS EYE DAMAGE/EYE IRRITATION - CATEGORY 2A
CARC. 1B: CARCINOGENICITY - CATEGORY 1B
CARC. 2: CARCINOGENICITY - CATEGORY 2
STOT SE 3: SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) - CATEGORY 3
STOT RE 2: SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - CATEGORY 2
ASP. TOX. 1: ASPIRATION HAZARD - CATEGORY 1
SOURCES:
WEBSITE, EUROPEAN CHEMICALS AGENCY (ECHA.EUROPA.EU)
WEBSITE, US EPA SUBSTANCE REGISTRY SERVICES (OFMPUB.EPA.GOV/SOR INTERNET
/REGISTRY/SUBSTREG/HOME/OVERVIEW/HOME.DO)
WEBSITE, CHEMICAL ABSTRACTS REGISTRY, AMERICAN CHEMICAL SOCIETY
(WWW.CAS.ORG)
PATTY'S INDUSTRIAL HYGIENE, 6TH ED., ROSE, VERNON, ED.
ISBN: 978-0-470-07488-6
CASARETT AND DOULL'S TOXICOLOGY: THE BASIC SCIENCE OF POISONS, 8TH ED.,
KLAASEN, CURTIS D., ED., ISBN: 978-0-07-176923-5.
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