| Common Name: | PROPANE |
| Manufacturer: | WORTHINGTON CYLINDER |
| SDS Revision Date: | 3/21/2021 |
| SDS Format: | GHS-US |
| Item Number(s): | 34AZ60, 60HH48 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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WORTHINGTON INDUSTRIES
SAFETY DATA SHEET
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER: PROPANE
OTHER MEANS OF IDENTIFICATION:
SDS NUMBER: WC002
RECOMMENDED USE: SOLDERING AND BRAZING.
RECOMMENDED RESTRICTIONS: NONE KNOWN.
MANUFACTURER/IMPORTER/SUPPLIER/DISTRIBUTOR INFORMATION:
MANUFACTURER/SUPPLIER: WORTHINGTON CYLINDER CORPORATION
ADDRESS:
300 E. BREED ST.
CHILTON, WI 53014
UNITED STATES
E-MAIL: SDSREQUEST@WORTHINGTONINDUSTRIES.COM
TELEPHONE: 1-800-359-9678
EMERGENCY TELEPHONE:
CHEMTREC:
1-800-424-9300 (USA)
1-703-527-3887 INTERNATIONAL
(CCN 628056)
| 2. HAZARD(S) IDENTIFICATION | |
PHYSICAL HAZARDS:
FLAMMABLE GASES: CATEGORY 1
GASES UNDER PRESSURE: LIQUEFIED GAS
HEALTH HAZARDS: NOT CLASSIFIED.
OSHA DEFINED HAZARDS: SIMPLE ASPHYXIANT
LABEL ELEMENTS:
FLAME
GAS CYLINDER
SIGNAL WORD: DANGER
HAZARD STATEMENT:
EXTREMELY FLAMMABLE GAS. CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF
HEATED. MAY DISPLACE OXYGEN AND CAUSE RAPID SUFFOCATION.
PRECAUTIONARY STATEMENT:
PREVENTION:
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING. KEEP
CONTAINER TIGHTLY CLOSED. USE ONLY WITH ADEQUATE VENTILATION.
RESPONSE:
LEAKING GAS FIRE:
DO NOT EXTINGUISH, UNLESS LEAK CAN BE STOPPED SAFELY. ELIMINATE ALL
IGNITION SOURCES IF SAFE TO DO SO.
STORAGE: PROTECT FROM SUNLIGHT. STORE IN A WELL-VENTILATED PLACE.
DISPOSAL:
DISPOSE OF WASTE AND RESIDUES IN ACCORDANCE WITH LOCAL AUTHORITY
REQUIREMENTS.
HAZARD(S) NOT OTHERWISE CLASSIFIED (HNOC):
CONTACT WITH LIQUEFIED GAS MAY CAUSE FROSTBITE.
SUPPLEMENTAL INFORMATION NONE.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
MIXTURES:
CHEMICAL NAME CAS NUMBER %
PROPANE 74-98-6 87.5 - 100
PROPYLENE 115-07-1 0 - 10
ETHANE 74-84-0 0 - 7
BUTANE 106-97-8 0 - 2.5
ADDITIVES:
CHEMICAL NAME COMMON NAME AND SYNONYMS CAS NUMBER %
ETHYL MERCAPTAN 75-08-1 <0.005
COMPOSITION COMMENTS: GAS CONCENTRATIONS ARE IN PERCENT BY VOLUME.
| 4. FIRST-AID MEASURES | |
INHALATION:
REMOVE FROM FURTHER EXPOSURE. FOR THOSE PROVIDING ASSISTANCE, AVOID
EXPOSURE TO YOURSELF OR OTHERS. USE ADEQUATE RESPIRATORY PROTECTION.
IF RESPIRATORY TRACT IRRITATION, DIZZINESS, NAUSEA, OR UNCONSCIOUSNESS
OCCURS, SEEK IMMEDIATE MEDICAL ASSISTANCE. IF BREATHING HAS STOPPED,
ASSIST VENTILATION WITH A MECHANICAL DEVICE OR USE MOUTH-TO-MOUTH
RESUSCITATION.
SKIN CONTACT:
NOT LIKELY, DUE TO THE FORM OF THE PRODUCT. IF FROSTBITE OCCURS, IMMERSE
AFFECTED AREA IN WARM WATER (NOT EXCEEDING 105 DEG. F/41 DEG. C). KEEP
IMMERSED FOR 20 TO 40 MINUTES. GET MEDICAL ATTENTION IMMEDIATELY.
EYE CONTACT:
NOT LIKELY, DUE TO THE FORM OF THE PRODUCT. IF FROSTBITE OCCURS,
IMMEDIATELY FLUSH EYES WITH PLENTY OF WARM WATER (NOT EXCEEDING
105 DEG. F/41 DEG. C) FOR AT LEAST 15 MINUTES. IF EASY TO DO,
REMOVE CONTACT LENSES. GET MEDICAL ATTENTION PROMPTLY IF SYMPTOMS
PERSIST OR OCCUR AFTER WASHING.
INGESTION:
THIS MATERIAL IS A GAS UNDER NORMAL ATMOSPHERIC CONDITIONS AND INGESTION
IS UNLIKELY.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
EXPOSURE TO RAPIDLY EXPANDING GAS OR VAPORIZING LIQUID MAY CAUSE
FROSTBITE ("COLD BURN"). VERY HIGH EXPOSURE CAN CAUSE SUFFOCATION
FROM LACK OF OXYGEN. SYMPTOMS MAY INCLUDE LOSS OF MOBILITY/CONSCIOUSNESS.
VICTIM MAY NOT BE AWARE OF ASPHYXIATION. ASPHYXIATION MAY BRING ABOUT
UNCONSCIOUSNESS WITHOUT WARNING AND SO RAPIDLY THAT VICTIM MAY BE UNABLE
TO PROTECT THEMSELF.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
EXPOSURE MAY AGGRAVATE PRE-EXISTING RESPIRATORY DISORDERS. PROVIDE GENERAL
SUPPORTIVE MEASURES AND TREAT SYMPTOMATICALLY.
GENERAL INFORMATION:
FIRST AID PERSONNEL MUST BE AWARE OF OWN RISK DURING RESCUE. IF YOU FEEL
UNWELL, SEEK MEDICAL ADVICE (SHOW THE LABEL WHERE POSSIBLE). ENSURE THAT
MEDICAL PERSONNEL ARE AWARE OF THE MATERIAL(S) INVOLVED, AND TAKE
PRECAUTIONS TO PROTECT THEMSELVES.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
DRY CHEMICAL POWDER. CARBON DIOXIDE (CO2). WATER FOG. FOAM.
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE WATER JET AS AN EXTINGUISHER, AS THIS WILL SPREAD THE FIRE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
EXTREMELY FLAMMABLE GAS. MAY FORM EXPLOSIVE MIXTURES WITH AIR. GAS MAY
TRAVEL CONSIDERABLE DISTANCE TO A SOURCE OF IGNITION AND FLASH BACK.
DURING FIRE, GASES HAZARDOUS TO HEALTH MAY BE FORMED.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING MUST BE
WORN IN CASE OF FIRE.
FIRE FIGHTING EQUIPMENT/INSTRUCTIONS:
DO NOT EXTINGUISH FIRES UNLESS GAS FLOW CAN BE STOPPED SAFELY; EXPLOSIVE
RE-IGNITION MAY OCCUR. PROMPTLY ISOLATE THE SCENE BY REMOVING ALL PERSONS
FROM THE VICINITY OF THE INCIDENT. NO ACTION SHALL BE TAKEN INVOLVING ANY
PERSONAL RISK OR WITHOUT SUITABLE TRAINING. FOR FIRES INVOLVING THIS
MATERIAL, DO NOT ENTER ANY ENCLOSED OR CONFINED FIRE SPACE WITHOUT PROPER
PROTECTIVE EQUIPMENT, INCLUDING SELF-CONTAINED BREATHING APPARATUS. STOP
FLOW OF MATERIAL. USE WATER TO KEEP FIRE EXPOSED CONTAINERS COOL AND TO
PROTECT PERSONNEL EFFECTING SHUTOFF. IF A LEAK OR SPILL HAS NOT IGNITED,
USE WATER SPRAY TO DISPERSE THE VAPORS AND TO PROTECT PERSONNEL ATTEMPTING
TO STOP LEAK. PREVENT RUNOFF FROM FIRE CONTROL OR DILUTION FROM ENTERING
STREAMS, SEWERS OR DRINKING WATER SUPPLY.
SPECIFIC METHODS:
USE STANDARD FIREFIGHTING PROCEDURES AND CONSIDER THE HAZARDS OF OTHER
INVOLVED MATERIALS. COOL CONTAINERS EXPOSED TO FLAMES WITH WATER UNTIL
WELL AFTER THE FIRE IS OUT.
GENERAL FIRE HAZARDS:
EXTREMELY FLAMMABLE GAS. CONTENTS UNDER PRESSURE. PRESSURIZED CONTAINER
MAY EXPLODE WHEN EXPOSED TO HEAT OR FLAME.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE THE AREA PROMPTLY. NO ACTION SHALL BE TAKEN INVOLVING ANY
PERSONAL RISK OR WITHOUT SUITABLE TRAINING. IN THE EVENT OF A LEAK
EVACUATE ALL PERSONNEL UNTIL VENTILATION CAN RESTORE OXYGEN CONCENTRATIONS
TO SAFE LEVELS. KEEP UNNECESSARY PERSONNEL AWAY. ELIMINATE ALL IGNITION
SOURCES (NO SMOKING, FLARES, SPARKS, OR FLAMES IN IMMEDIATE AREA). DO NOT
TOUCH DAMAGED CONTAINERS OR SPILLED MATERIAL UNLESS WEARING APPROPRIATE
PROTECTIVE CLOTHING. VENTILATE CLOSED SPACES BEFORE ENTERING THEM. WEAR
APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8).
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
ELIMINATE ALL IGNITION SOURCES (NO SMOKING, FLARES, SPARKS, OR FLAMES IN
IMMEDIATE AREA). KEEP COMBUSTIBLES (WOOD, PAPER, OIL, ETC.) AWAY FROM
SPILLED MATERIAL. STOP LEAK IF YOU CAN DO SO WITHOUT RISK. IF POSSIBLE,
TURN LEAKING CONTAINERS SO THAT GAS ESCAPES RATHER THAN LIQUID. ISOLATE
AREA UNTIL GAS HAS DISPERSED. FOR WASTE DISPOSAL, SEE SECTION 13 OF THE
SDS.
ENVIRONMENTAL PRECAUTIONS:
SHOULD NOT BE RELEASED INTO THE ENVIRONMENT. PREVENT FURTHER LEAKAGE OR
SPILLAGE IF SAFE TO DO SO.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING. DO NOT
HANDLE, STORE OR OPEN NEAR AN OPEN FLAME, SOURCES OF HEAT OR SOURCES OF
IGNITION. PROTECT MATERIAL FROM DIRECT SUNLIGHT. DO NOT SMOKE. ALL
EQUIPMENT USED WHEN HANDLING THE PRODUCT MUST BE GROUNDED. DO NOT
BREATHE GAS. AVOID PROLONGED EXPOSURE. DO NOT ENTER STORAGE AREAS
OR CONFINED SPACES UNLESS ADEQUATELY VENTILATED. USE ONLY OUTDOORS
OR IN A WELL-VENTILATED AREA. OXYGEN CONCENTRATION SHOULD NOT FALL
BELOW 19.5 % AT SEA LEVEL (PO2 = 135 MMHG). MECHANICAL VENTILATION
OR LOCAL EXHAUST VENTILATION MAY BE REQUIRED. WEAR APPROPRIATE PERSONAL
PROTECTIVE EQUIPMENT. OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
DO NOT STORE, INCINERATE, OR HEAT THIS MATERIAL ABOVE 120 DEGREES
FAHRENHEIT. KEEP AWAY FROM HEAT, SPARKS AND OPEN FLAME. THIS MATERIAL
CAN ACCUMULATE STATIC CHARGE WHICH MAY CAUSE SPARK AND BECOME AN IGNITION
SOURCE. PREVENT ELECTROSTATIC CHARGE BUILD-UP BY USING COMMON BONDING
AND GROUNDING TECHNIQUES. STORE IN A COOL, DRY PLACE OUT OF DIRECT
SUNLIGHT. CYLINDERS SHOULD BE STORED UPRIGHT, WITH VALVE PROTECTION CAP
IN PLACE, AND FIRMLY SECURED TO PREVENT FALLING OR BEING KNOCKED OVER.
PROTECT CYLINDERS FROM DAMAGE. STORED CONTAINERS SHOULD BE PERIODICALLY
CHECKED FOR GENERAL CONDITION AND LEAKAGE. STORE IN ORIGINAL TIGHTLY
CLOSED CONTAINER. STORE IN A WELL-VENTILATED PLACE. STORE AWAY FROM
INCOMPATIBLE MATERIALS (SEE SECTION 10 OF THE SDS).
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE LIMITS:
US. OSHA TABLE Z-1 LIMITS FOR AIR CONTAMINANTS (29 CFR 1910.1000):
COMPONENTS TYPE VALUE
PROPANE (CAS 74-98-6) PEL 1800 MG/M3
1000 PPM
US. ACGIH THRESHOLD LIMIT VALUES:
COMPONENTS TYPE VALUE
BUTANE (CAS 106-97-8) STEL 1000 PPM
PROPYLENE (CAS 115-07-1) TWA 500 PPM
US. NIOSH: POCKET GUIDE TO CHEMICAL HAZARDS
COMPONENTS TYPE VALUE
BUTANE (CAS 106-97-8) TWA 1900 MG/M3
800 PPM
PROPANE (CAS 74-98-6) TWA 1800 MG/M3
1000 PPM
BIOLOGICAL LIMIT VALUES:
NO BIOLOGICAL EXPOSURE LIMITS NOTED FOR THE INGREDIENT(S).
EXPOSURE GUIDELINES: FOLLOW STANDARD MONITORING PROCEDURES.
APPROPRIATE ENGINEERING CONTROLS:
PROVIDE ADEQUATE VENTILATION AND MINIMIZE THE RISK OF INHALATION OF
GAS. USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER
ENGINEERING CONTROLS TO CONTROL AIRBORNE LEVELS BELOW RECOMMENDED
EXPOSURE LIMITS.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION:
WEAR APPROVED SAFETY GLASSES OR GOGGLES. FACE SHIELD IS RECOMMENDED.
SKIN PROTECTION:
HAND PROTECTION: WEAR COLD INSULATING GLOVES.
SKIN PROTECTION:
OTHER: WEAR PROTECTIVE CLOTHING APPROPRIATE FOR THE RISK OF EXPOSURE.
RESPIRATORY PROTECTION:
IF ENGINEERING CONTROLS DO NOT MAINTAIN AIRBORNE CONCENTRATIONS BELOW
RECOMMENDED EXPOSURE LIMITS (WHERE APPLICABLE) OR TO AN ACCEPTABLE LEVEL
(IN COUNTRIES WHERE EXPOSURE LIMITS HAVE NOT BEEN ESTABLISHED), AN
APPROVED RESPIRATOR MUST BE WORN. THE TYPE OF RESPIRATORY PROTECTION
SELECTED MUST COMPLY WITH THE REQUIREMENTS SET FORTH IN OSHA'S
RESPIRATORY PROTECTION STANDARD (29 CFR 1910.134).
WARNING!
AIR-PURIFYING RESPIRATORS DO NOT PROTECT WORKERS IN OXYGEN DEFICIENT
ATMOSPHERES.
THERMAL HAZARDS:
CONTACT WITH LIQUEFIED GAS MIGHT CAUSE FROSTBITES, IN SOME CASES WITH
TISSUE DAMAGE. WEAR APPROPRIATE THERMAL PROTECTIVE CLOTHING, WHEN
NECESSARY.
GENERAL HYGIENE CONSIDERATIONS:
DO NOT EAT, DRINK OR SMOKE WHEN USING THE PRODUCT. WASH THOROUGHLY AFTER
HANDLING. PROVIDE EYEWASH STATION AND SAFETY SHOWER. HANDLE IN ACCORDANCE
WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICES.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: GAS.
FORM: COMPRESSED LIQUEFIED GAS.
COLOR: COLORLESS.
ODOR: ROTTEN EGG.
ODOR THRESHOLD: NOT DETERMINED.
PH: NOT APPLICABLE.
MELTING POINT/FREEZING POINT: -306.4 DEG. F (-188 DEG. C)
INITIAL BOILING POINT AND BOILING RANGE:
-43.6 DEG. F (-42 DEG. C) 14.7 PSIA
FLASH POINT: -155.2 DEG. F (-104.0 DEG. C)
EVAPORATION RATE: NOT DETERMINED.
FLAMMABILITY (SOLID, GAS): EXTREMELY FLAMMABLE GAS.
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS:
EXPLOSIVE LIMIT - LOWER (%): 2.15 %
EXPLOSIVE LIMIT - UPPER (%): 9.6 %
VAPOR PRESSURE: 127 PSIG (21 DEG. C / 70 DEG. F)
VAPOR DENSITY: NOT DETERMINED.
RELATIVE DENSITY:
0.504 (LIQUID)
1.5 (VAPOR) (AIR=1) (59 DEG. F (15 DEG. C))
SOLUBILITY(IES):
SOLUBILITY (WATER): SLIGHTLY SOLUBLE IN WATER.
PARTITION COEFFICIENT (N-OCTANOL/WATER): 1.77
AUTO-IGNITION TEMPERATURE: 809.6 DEG. F (432 DEG. C)
DECOMPOSITION TEMPERATURE: NOT DETERMINED.
VISCOSITY: NOT APPLICABLE.
OTHER INFORMATION:
DENSITY: NOT DETERMINED.
EXPLOSIVE PROPERTIES: NOT EXPLOSIVE.
KINEMATIC VISCOSITY: NOT DETERMINED.
MOLECULAR WEIGHT: 45 G/MOL
OXIDIZING PROPERTIES: NOT OXIDIZING.
PARTICLE SIZE: NOT APPLICABLE.
PERCENT VOLATILE: 100 %
| 10. STABILITY AND REACTIVITY | |
REACTIVITY:
REACTS VIOLENTLY WITH STRONG OXIDANTS, NITRITES, INORGANIC CHLORIDES,
CHLORITES AND PERCHLORATES CAUSING FIRE AND EXPLOSION HAZARD.
CHEMICAL STABILITY:
STABLE UNDER NORMAL TEMPERATURE CONDITIONS AND RECOMMENDED USE.
POSSIBILITY OF HAZARDOUS REACTIONS:
POLYMERIZATION WILL NOT OCCUR. MAY FORM EXPLOSIVE MIXTURE WITH AIR. THIS
PRODUCT MAY REACT WITH OXIDIZING AGENTS.
CONDITIONS TO AVOID:
AVOID HEAT, SPARKS, OPEN FLAMES AND OTHER IGNITION SOURCES. AVOID
TEMPERATURES EXCEEDING THE FLASH POINT. CONTACT WITH INCOMPATIBLE
MATERIALS.
INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS. HALOGENS. NITRATES.
HAZARDOUS DECOMPOSITION PRODUCTS:
THERMAL DECOMPOSITION OF THIS PRODUCT CAN GENERATE CARBON MONOXIDE AND
CARBON DIOXIDE. HYDROCARBONS.
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INHALATION:
HIGH CONCENTRATIONS: SUFFOCATION (ASPHYXIANT) HAZARD - IF ALLOWED TO
ACCUMULATE TO CONCENTRATIONS THAT REDUCE OXYGEN BELOW SAFE BREATHING
LEVELS. BREATHING OF HIGH CONCENTRATIONS MAY CAUSE DIZZINESS,
LIGHT-HEADEDNESS, HEADACHE, NAUSEA AND LOSS OF COORDINATION. CONTINUED
INHALATION MAY RESULT IN UNCONSCIOUSNESS.
SKIN CONTACT: CONTACT WITH LIQUEFIED GAS MAY CAUSE FROSTBITE.
EYE CONTACT: CONTACT WITH LIQUEFIED GAS MAY CAUSE FROSTBITE.
INGESTION:
THIS MATERIAL IS A GAS UNDER NORMAL ATMOSPHERIC CONDITIONS AND INGESTION
IS UNLIKELY.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
EXPOSURE TO RAPIDLY EXPANDING GAS OR VAPORIZING LIQUID MAY CAUSE FROSTBITE
("COLD BURN"). VERY HIGH EXPOSURE CAN CAUSE SUFFOCATION FROM LACK OF
OXYGEN. SYMPTOMS MAY INCLUDE LOSS OF MOBILITY/CONSCIOUSNESS. VICTIM MAY
NOT BE AWARE OF ASPHYXIATION. ASPHYXIATION MAY BRING ABOUT UNCONSCIOUSNESS
WITHOUT WARNING AND SO RAPIDLY THAT VICTIM MAY BE UNABLE TO PROTECT
THEMSELF.
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY: NOT EXPECTED TO BE ACUTELY TOXIC.
COMPONENTS SPECIES TEST RESULTS
PROPANE (CAS 74-98-6):
ACUTE:
INHALATION:
GAS:
LC50 RAT >80000 PPM, 15 MINUTES
PROPYLENE (CAS 115-07-1):
ACUTE:
INHALATION:
GAS:
LC50 RAT >65000 PPM, 4 HOURS
SKIN CORROSION/IRRITATION: NOT CLASSIFIED.
SERIOUS EYE DAMAGE/EYE IRRITATION: NOT CLASSIFIED.
RESPIRATORY OR SKIN SENSITIZATION:
RESPIRATORY SENSITIZATION: NOT A RESPIRATORY SENSITIZER.
SKIN SENSITIZATION:
THIS PRODUCT IS NOT EXPECTED TO CAUSE SKIN SENSITIZATION.
GERM CELL MUTAGENICITY:
NO DATA AVAILABLE TO INDICATE PRODUCT OR ANY COMPONENTS PRESENT AT
GREATER THAN 0.1% ARE MUTAGENIC OR GENOTOXIC.
CARCINOGENICITY: NOT CLASSIFIABLE AS TO CARCINOGENICITY TO HUMANS.
IARC MONOGRAPHS. OVERALL EVALUATION OF CARCINOGENICITY:
PROPYLENE (CAS 115-07-1) 3 NOT CLASSIFIABLE AS TO
CARCINOGENICITY TO HUMANS.
NTP REPORT ON CARCINOGENS: NOT LISTED.
OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1053):
NOT LISTED.
REPRODUCTIVE TOXICITY:
THIS PRODUCT IS NOT EXPECTED TO CAUSE REPRODUCTIVE OR DEVELOPMENTAL
EFFECTS.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: NOT CLASSIFIED.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NOT CLASSIFIED.
ASPIRATION HAZARD: NOT RELEVANT, DUE TO THE FORM OF THE PRODUCT.
CHRONIC EFFECTS:
EXPOSURE OVER A LONG PERIOD OF TIME MAY CAUSE CENTRAL NERVOUS SYSTEM
EFFECTS.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
THE PRODUCT IS NOT EXPECTED TO BE HAZARDOUS TO THE ENVIRONMENT.
PERSISTENCE AND DEGRADABILITY:
NOT RELEVANT, DUE TO THE FORM OF THE PRODUCT.
BIOACCUMULATIVE POTENTIAL: NOT RELEVANT, DUE TO THE FORM OF THE PRODUCT.
PARTITION COEFFICIENT N-OCTANOL / WATER (LOG KOW):
PROPANE (CAS 74-98-6) 2.36
PROPYLENE (CAS 115-07-1) 1.77
MOBILITY IN SOIL: NOT RELEVANT, DUE TO THE FORM OF THE PRODUCT.
OTHER ADVERSE EFFECTS:
THE PRODUCT CONTAINS VOLATILE ORGANIC COMPOUNDS WHICH HAVE A PHOTOCHEMICAL
OZONE CREATION POTENTIAL.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL INSTRUCTIONS:
USE THE CONTAINER UNTIL EMPTY. DO NOT DISPOSE OF ANY NON-EMPTY CONTAINER.
EMPTY CONTAINERS HAVE RESIDUAL VAPOR THAT IS FLAMMABLE AND EXPLOSIVE.
CYLINDERS SHOULD BE EMPTIED AND RETURNED TO A HAZARDOUS WASTE COLLECTION
POINT. DO NOT PUNCTURE OR INCINERATE EVEN WHEN EMPTY. DISPOSE IN
ACCORDANCE WITH ALL APPLICABLE REGULATIONS.
LOCAL DISPOSAL REGULATIONS:
DISPOSE OF IN ACCORDANCE WITH LOCAL REGULATIONS.
HAZARDOUS WASTE CODE:
D001: WASTE FLAMMABLE MATERIAL WITH A FLASH POINT <140 DEG. F
THE WASTE CODE SHOULD BE ASSIGNED IN DISCUSSION BETWEEN THE USER, THE
PRODUCER AND THE WASTE DISPOSAL COMPANY.
WASTE FROM RESIDUES / UNUSED PRODUCTS:
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS.
CONTAMINATED PACKAGING:
EMPTY CONTAINERS SHOULD BE TAKEN TO AN APPROVED WASTE HANDLING SITE FOR
RECYCLING OR DISPOSAL.
| 14. TRANSPORT INFORMATION | |
DOT:
UN NUMBER: UN1075
UN PROPER SHIPPING NAME: PETROLEUM GASES, LIQUEFIED
TRANSPORT HAZARD CLASS(ES):
CLASS: 2.1
SUBSIDIARY RISK:
LABEL(S): 2.1
PACKING GROUP:
ENVIRONMENTAL HAZARDS:
MARINE POLLUTANT: NO
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
SPECIAL PROVISIONS: T50
PACKAGING EXCEPTIONS: 306
PACKAGING NON BULK: 304
PACKAGING BULK: 314, 315
IATA:
UN NUMBER: UN1075
UN PROPER SHIPPING NAME: PETROLEUM GASES, LIQUEFIED
TRANSPORT HAZARD CLASS(ES):
CLASS: 2.1
SUBSIDIARY RISK:
PACKING GROUP:
ENVIRONMENTAL HAZARDS: NO
ERG CODE: 10L
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
IMDG:
UN NUMBER: UN1075
UN PROPER SHIPPING NAME: PETROLEUM GASES, LIQUEFIED
TRANSPORT HAZARD CLASS(ES):
CLASS: 2.1
SUBSIDIARY RISK:
PACKING GROUP:
ENVIRONMENTAL HAZARDS:
MARINE POLLUTANT: NO
EMS: E-D, S-U
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE:
NOT APPLICABLE.
| 15. REGULATORY INFORMATION | |
US FEDERAL REGULATIONS:
THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.
TSCA SECTION 12(B) EXPORT NOTIFICATION (40 CFR 707, SUBPT. D):
NOT REGULATED.
CERCLA HAZARDOUS SUBSTANCE LIST (40 CFR 302.4):
BUTANE (CAS 106-97-8) LISTED.
ETHYL MERCAPTAN (CAS 75-08-1) LISTED.
PROPANE (CAS 74-98-6) LISTED.
PROPYLENE (CAS 115-07-1) LISTED.
SARA 304 EMERGENCY RELEASE NOTIFICATION: NOT REGULATED.
OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1053):
NOT LISTED.
TOXIC SUBSTANCES CONTROL ACT (TSCA):
ALL COMPONENTS OF THE MIXTURE ON THE TSCA 8(B) INVENTORY ARE DESIGNATED
"ACTIVE".
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA):
SARA 302 EXTREMELY HAZARDOUS SUBSTANCE: NOT LISTED.
SARA 311/312 HAZARDOUS CHEMICAL: YES
CLASSIFIED HAZARD CATEGORIES:
FLAMMABLE (GASES, AEROSOLS, LIQUIDS, OR SOLIDS)
GAS UNDER PRESSURE
SIMPLE ASPHYXIANT
HAZARD NOT OTHERWISE CLASSIFIED (HNOC)
SARA 313 (TRI REPORTING):
CHEMICAL NAME CAS NUMBER % BY WT.
PROPYLENE 115-07-1 0 - 10
OTHER FEDERAL REGULATIONS:
CLEAN AIR ACT (CAA) SECTION 112 HAZARDOUS AIR POLLUTANTS (HAPS) LIST:
NOT REGULATED.
CLEAN AIR ACT (CAA) SECTION 112(R) ACCIDENTAL RELEASE PREVENTION
(40 CFR 68.130):
BUTANE (CAS 106-97-8)
ETHYL MERCAPTAN (CAS 75-08-1)
PROPANE (CAS 74-98-6)
PROPYLENE (CAS 115-07-1)
SAFE DRINKING WATER ACT (SDWA): NOT REGULATED.
US STATE REGULATIONS:
US. MASSACHUSETTS RTK - SUBSTANCE LIST:
BUTANE (CAS 106-97-8)
ETHYL MERCAPTAN (CAS 75-08-1)
PROPANE (CAS 74-98-6)
PROPYLENE (CAS 115-07-1)
US. NEW JERSEY WORKER AND COMMUNITY RIGHT-TO-KNOW ACT:
BUTANE (CAS 106-97-8)
ETHYL MERCAPTAN (CAS 75-08-1)
PROPANE (CAS 74-98-6)
PROPYLENE (CAS 115-07-1)
US. PENNSYLVANIA WORKER AND COMMUNITY RIGHT-TO-KNOW LAW:
BUTANE (CAS 106-97-8)
ETHYL MERCAPTAN (CAS 75-08-1)
PROPANE (CAS 74-98-6)
PROPYLENE (CAS 115-07-1)
US. RHODE ISLAND RTK:
BUTANE (CAS 106-97-8)
ETHYL MERCAPTAN (CAS 75-08-1)
PROPANE (CAS 74-98-6)
PROPYLENE (CAS 115-07-1)
CALIFORNIA PROPOSITION 65:
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986
(PROPOSITION 65):
THIS MATERIAL IS NOT KNOWN TO CONTAIN ANY CHEMICALS CURRENTLY LISTED
AS CARCINOGENS OR REPRODUCTIVE TOXINS. FOR MORE INFORMATION GO TO
WWW.P65WARNINGS.CA.GOV.
US. CALIFORNIA. CANDIDATE CHEMICALS LIST. SAFER CONSUMER PRODUCTS
REGULATIONS (CAL. CODE REGS, TIT. 22, 69502.3, SUBD. (A)):
BUTANE (CAS 106-97-8)
PROPYLENE (CAS 115-07-1)
INTERNATIONAL INVENTORIES:
COUNTRY(S) OR REGION INVENTORY NAME ON INVENTORY (YES/NO)*
AUSTRALIA AUSTRALIAN INVENTORY OF YES
INDUSTRIAL CHEMICALS
(AICIS)
CANADA DOMESTIC SUBSTANCES LIST YES
(DSL)
CANADA NON-DOMESTIC SUBSTANCES NO
LIST (NDSL)
CHINA INVENTORY OF EXISTING YES
CHEMICAL SUBSTANCES IN
CHINA (IECSC)
EUROPE EUROPEAN INVENTORY OF YES
EXISTING COMMERCIAL
CHEMICAL SUBSTANCES
(EINECS)
EUROPE EUROPEAN LIST OF NO
NOTIFIED CHEMICAL
SUBSTANCES (ELINCS)
JAPAN INVENTORY OF EXISTING YES
AND NEW CHEMICAL
SUBSTANCES (ENCS)
KOREA EXISTING CHEMICALS YES
LIST (ECL)
NEW ZEALAND NEW ZEALAND INVENTORY YES
PHILIPPINES PHILIPPINE INVENTORY OF YES
CHEMICALS AND CHEMICAL
SUBSTANCES (PICCS)
TAIWAN TAIWAN CHEMICAL YES
SUBSTANCE INVENTORY
(TCSI)
UNITED STATES & TOXIC SUBSTANCES YES
PUERTO RICO CONTROL ACT (TSCA)
INVENTORY
*A "YES" INDICATES THAT ALL COMPONENTS OF THIS PRODUCT COMPLY WITH THE
INVENTORY REQUIREMENTS ADMINISTERED BY THE GOVERNING COUNTRY(S)
A "NO" INDICATES THAT ONE OR MORE COMPONENTS OF THE PRODUCT ARE NOT LISTED
OR EXEMPT FROM LISTING ON THE INVENTORY ADMINISTERED BY THE GOVERNING
COUNTRY(S).
| 16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION | |
OR LAST REVISION
ISSUE DATE: 05-MAY-2014
REVISION DATE: 21-MARCH-2021
VERSION #: 03
HMIS(R*) RATINGS:
HEALTH 2
FLAMMABILITY 4
PHYSICAL HAZARD 3
NFPA RATINGS:
2
4
0
DISCLAIMER:
ALL INFORMATION IN THIS SAFETY DATA SHEET IS BELIEVED TO BE ACCURATE AND
RELIABLE. HOWEVER, NO GUARANTEE OR WARRANTY OF ANY KIND IS MADE WITH
REGARD TO THE ACCURACY OF INFORMATION OR THE SUITABILITY OF THE
RECOMMENDATIONS CONTAINED HEREIN. IT IS THE USER'S RESPONSIBILITY TO
ASSESS THE SAFETY AND TOXICITY OF THIS PRODUCT UNDER THEIR OWN CONDITIONS
OF USE AND TO COMPLY WITH ALL APPLICABLE LAWS AND REGULATIONS.
919503
SDS US