| Common Name: | DEVCON TITANIUM PUTTY RESIN, 0113, DEVCON TITANIUM PUTTY HARDENER, 5318N |
| Manufacturer: | ITW PERFORMANCE POLYMERS |
| SDS Revision Date: | 5/29/2019 |
| SDS Format: | GHS-US |
| Item Number(s): | 65KU65 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
SAFETY DATA SHEET
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER: DEVCON(R*) TITANIUM PUTTY RESIN
OTHER MEANS OF IDENTIFICATION:
SKU#: 0113
RECOMMENDED USE: NOT AVAILABLE.
RECOMMENDED RESTRICTIONS: NONE KNOWN.
MANUFACTURER/IMPORTER/SUPPLIER/DISTRIBUTOR INFORMATION:
MANUFACTURER:
COMPANY NAME: ITW PERFORMANCE POLYMERS
ADDRESS:
30 ENDICOTT STREET
DANVERS, MA 01923
UNITED STATES
TELEPHONE:
CUSTOMER SERVICE: 978-777-1100
WEBSITE: WWW.ITWPERFORMANCEPOLYMERS.COM
E-MAIL: NOT AVAILABLE.
CONTACT PERSON: EHS DEPARTMENT
EMERGENCY PHONE NUMBER:
CHEMTREC: 800-424-9300
INTERNATIONAL: 703-527-3887
| 2. HAZARD(S) IDENTIFICATION | |
PHYSICAL HAZARDS: NOT CLASSIFIED.
HEALTH HAZARDS:
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2A
SENSITIZATION, SKIN: CATEGORY 1
SPECIFIC TARGET ORGAN TOXICITY, SINGLE EXPOSURE:
CATEGORY 3 NARCOTIC EFFECTS
ENVIRONMENTAL HAZARDS: NOT CLASSIFIED.
OSHA DEFINED HAZARDS: NOT CLASSIFIED.
LABEL ELEMENTS: EXCLAMATION MARK
SIGNAL WORD: WARNING
HAZARD STATEMENT:
CAUSES SKIN IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION. CAUSES
SERIOUS EYE IRRITATION. MAY CAUSE DROWSINESS OR DIZZINESS.
PRECAUTIONARY STATEMENT:
PREVENTION:
WASH THOROUGHLY AFTER HANDLING. USE ONLY OUTDOORS OR IN A WELL-VENTILATED
AREA. CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
WEAR EYE PROTECTION/FACE PROTECTION. WEAR PROTECTIVE GLOVES.
RESPONSE
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING. CALL A POISON CENTER/DOCTOR IF
YOU FEEL UNWELL.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
IF EYE IRRITATION PERSISTS:
GET MEDICAL ADVICE/ATTENTION. TAKE OFF CONTAMINATED CLOTHING AND WASH IT
BEFORE REUSE.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE
LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
HAZARD(S) NOT OTHERWISE CLASSIFIED (HNOC): NONE KNOWN.
SUPPLEMENTAL INFORMATION: NONE.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
MIXTURES:
CHEMICAL NAME COMMON NAME CAS NUMBER %
AND SYNONYMS
FERROSILICON, [WITH >= 30% BUT 8049-17-0 40 - 70
<= 70% SILICON]
EPOXY RESIN:--REACTION PRODUCT 25068-38-6 15 - 40
OF BISPHENOL A AND
EPICHLOROHYDRIN (REFER TO
EPICHLOROHYDRIN)
OTHER COMPONENTS BELOW 7 - 13
REPORTABLE LEVELS
*DESIGNATES THAT A SPECIFIC CHEMICAL IDENTITY AND/OR PERCENTAGE OF
COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| 4. FIRST-AID MEASURES | |
INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING IMMEDIATELY AND WASH SKIN WITH SOAP AND
WATER. IN CASE OF ECZEMA OR OTHER SKIN DISORDERS: SEEK MEDICAL ATTENTION
AND TAKE ALONG THESE INSTRUCTIONS. WASH CONTAMINATED CLOTHING BEFORE
REUSE.
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES.
REMOVE CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING.
GET MEDICAL ATTENTION IF IRRITATION DEVELOPS AND PERSISTS.
INGESTION: RINSE MOUTH. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
MAY CAUSE DROWSINESS AND DIZZINESS. HEADACHE. NAUSEA, VOMITING. SEVERE EYE
IRRITATION. SYMPTOMS MAY INCLUDE STINGING, TEARING, REDNESS, SWELLING, AND
BLURRED VISION. SKIN IRRITATION. MAY CAUSE REDNESS AND PAIN. MAY CAUSE AN
ALLERGIC SKIN REACTION. DERMATITIS. RASH.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
PROVIDE GENERAL SUPPORTIVE MEASURES AND TREAT SYMPTOMATICALLY. KEEP VICTIM
UNDER OBSERVATION. SYMPTOMS MAY BE DELAYED.
GENERAL INFORMATION:
ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE MATERIAL(S) INVOLVED, AND
TAKE PRECAUTIONS TO PROTECT THEMSELVES. WASH CONTAMINATED CLOTHING BEFORE
REUSE.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
WATER FOG. FOAM. DRY CHEMICAL POWDER. CARBON DIOXIDE (CO2).
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE WATER JET AS AN EXTINGUISHER, AS THIS WILL SPREAD THE FIRE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
DURING FIRE, GASES HAZARDOUS TO HEALTH MAY BE FORMED.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING MUST BE
WORN IN CASE OF FIRE.
FIRE FIGHTING EQUIPMENT/INSTRUCTIONS:
MOVE CONTAINERS FROM FIRE AREA IF YOU CAN DO SO WITHOUT RISK.
SPECIFIC METHODS:
USE STANDARD FIREFIGHTING PROCEDURES AND CONSIDER THE HAZARDS OF OTHER
INVOLVED MATERIALS.
GENERAL FIRE HAZARDS: NO UNUSUAL FIRE OR EXPLOSION HAZARDS NOTED.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
KEEP UNNECESSARY PERSONNEL AWAY. KEEP PEOPLE AWAY FROM AND UPWIND OF
SPILL/LEAK. WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND CLOTHING DURING
CLEAN-UP. AVOID BREATHING MIST/VAPORS. DO NOT TOUCH DAMAGED CONTAINERS
OR SPILLED MATERIAL UNLESS WEARING APPROPRIATE PROTECTIVE CLOTHING. ENSURE
ADEQUATE VENTILATION. LOCAL AUTHORITIES SHOULD BE ADVISED IF SIGNIFICANT
SPILLAGES CANNOT BE CONTAINED. FOR PERSONAL PROTECTION, SEE SECTION 8 OF
THE SDS.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
LARGE SPILLS:
STOP THE FLOW OF MATERIAL, IF THIS IS WITHOUT RISK. DIKE THE SPILLED
MATERIAL, WHERE THIS IS POSSIBLE. ABSORB IN VERMICULITE, DRY SAND OR
EARTH AND PLACE INTO CONTAINERS. FOLLOWING PRODUCT RECOVERY, FLUSH AREA
WITH WATER.
SMALL SPILLS:
WIPE UP WITH ABSORBENT MATERIAL (E.G. CLOTH, FLEECE). CLEAN SURFACE
THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION.
NEVER RETURN SPILLS TO ORIGINAL CONTAINERS FOR RE-USE. FOR WASTE DISPOSAL,
SEE SECTION 13 OF THE SDS.
ENVIRONMENTAL PRECAUTIONS:
AVOID DISCHARGE INTO DRAINS, WATER COURSES OR ONTO THE GROUND.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
AVOID BREATHING MIST/VAPORS. AVOID CONTACT WITH EYES, SKIN, AND CLOTHING.
AVOID PROLONGED EXPOSURE. PROVIDE ADEQUATE VENTILATION. WEAR APPROPRIATE
PERSONAL PROTECTIVE EQUIPMENT. OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE LOCKED UP. STORE IN TIGHTLY CLOSED CONTAINER. STORE AWAY FROM
INCOMPATIBLE MATERIALS (SEE SECTION 10 OF THE SDS).
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE LIMITS:
THE FOLLOWING CONSTITUENTS ARE THE ONLY CONSTITUENTS OF THE PRODUCT WHICH
HAVE A PEL, TLV OR OTHER RECOMMENDED EXPOSURE LIMIT.
AT THIS TIME, THE OTHER CONSTITUENTS HAVE NO KNOWN EXPOSURE LIMITS.
BIOLOGICAL LIMIT VALUES:
NO BIOLOGICAL EXPOSURE LIMITS NOTED FOR THE INGREDIENT(S).
APPROPRIATE ENGINEERING CONTROLS:
GOOD GENERAL VENTILATION SHOULD BE USED. VENTILATION RATES SHOULD BE
MATCHED TO CONDITIONS. IF APPLICABLE, USE PROCESS ENCLOSURES, LOCAL
EXHAUST VENTILATION, OR OTHER ENGINEERING CONTROLS TO MAINTAIN AIRBORNE
LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. IF EXPOSURE LIMITS HAVE NOT BEEN
ESTABLISHED, MAINTAIN AIRBORNE LEVELS TO AN ACCEPTABLE LEVEL. PROVIDE
EYEWASH STATION AND SAFETY SHOWER.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION:
CHEMICAL RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE AND FULL FACEPIECE.
SKIN PROTECTION:
HAND PROTECTION: WEAR APPROPRIATE CHEMICAL RESISTANT GLOVES.
OTHER: WEAR APPROPRIATE CHEMICAL RESISTANT CLOTHING.
RESPIRATORY PROTECTION:
CHEMICAL RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE AND FULL FACEPIECE.
THERMAL HAZARDS:
WEAR APPROPRIATE THERMAL PROTECTIVE CLOTHING, WHEN NECESSARY.
GENERAL HYGIENE CONSIDERATIONS:
ALWAYS OBSERVE GOOD PERSONAL HYGIENE MEASURES, SUCH AS WASHING AFTER
HANDLING THE MATERIAL AND BEFORE EATING, DRINKING, AND/OR SMOKING.
ROUTINELY WASH WORK CLOTHING AND PROTECTIVE EQUIPMENT TO REMOVE
CONTAMINANTS. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT
OF THE WORKPLACE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: VISCOUS. LIQUID.
PHYSICAL STATE: LIQUID.
FORM: VISCOUS. LIQUID.
COLOR: NOT AVAILABLE.
ODOR: SLIGHT.
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
MELTING POINT/FREEZING POINT: NOT AVAILABLE.
INITIAL BOILING POINT AND BOILING RANGE: 608 DEG. F (320 DEG. C) ESTIMATED
FLASH POINT: > 399.9 DEG. F (> 204.4 DEG. C)
EVAPORATION RATE: NOT AVAILABLE.
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE.
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS:
FLAMMABILITY LIMIT - LOWER (%): NOT AVAILABLE.
FLAMMABILITY LIMIT - UPPER (%): NOT AVAILABLE.
EXPLOSIVE LIMIT - LOWER (%): NOT AVAILABLE.
EXPLOSIVE LIMIT - UPPER (%): NOT AVAILABLE.
VAPOR PRESSURE: NOT AVAILABLE.
VAPOR DENSITY: NOT AVAILABLE.
RELATIVE DENSITY: NOT AVAILABLE.
SOLUBILITY(IES):
SOLUBILITY (WATER): NOT AVAILABLE.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY: NOT AVAILABLE.
OTHER INFORMATION:
DENSITY: 1.52 G/CM3 ESTIMATED
EXPLOSIVE PROPERTIES: NOT EXPLOSIVE.
FLAMMABILITY CLASS: COMBUSTIBLE IIIB ESTIMATED
OXIDIZING PROPERTIES: NOT OXIDIZING.
SPECIFIC GRAVITY: 1.52 ESTIMATED
VOC: 0 G/L
| 10. STABILITY AND REACTIVITY | |
REACTIVITY:
THE PRODUCT IS STABLE AND NON-REACTIVE UNDER NORMAL CONDITIONS OF USE,
STORAGE AND TRANSPORT.
CHEMICAL STABILITY: MATERIAL IS STABLE UNDER NORMAL CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS:
NO DANGEROUS REACTION KNOWN UNDER CONDITIONS OF NORMAL USE.
CONDITIONS TO AVOID:
KEEP AWAY FROM HEAT, HOT SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION
SOURCES. CONTACT WITH INCOMPATIBLE MATERIALS.
INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS.
HAZARDOUS DECOMPOSITION PRODUCTS:
NO HAZARDOUS DECOMPOSITION PRODUCTS ARE KNOWN.
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INHALATION:
MAY CAUSE DROWSINESS AND DIZZINESS. HEADACHE. NAUSEA, VOMITING. PROLONGED
INHALATION MAY BE HARMFUL.
SKIN CONTACT: CAUSES SKIN IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INGESTION: EXPECTED TO BE A LOW INGESTION HAZARD.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
MAY CAUSE DROWSINESS AND DIZZINESS. HEADACHE. NAUSEA, VOMITING. SEVERE
EYE IRRITATION. SYMPTOMS MAY INCLUDE STINGING, TEARING, REDNESS, SWELLING,
AND BLURRED VISION. SKIN IRRITATION. MAY CAUSE REDNESS AND PAIN. MAY CAUSE
AN ALLERGIC SKIN REACTION. DERMATITIS. RASH.
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY: NOT KNOWN.
SKIN CORROSION/IRRITATION: CAUSES SKIN IRRITATION.
SERIOUS EYE DAMAGE/EYE IRRITATION: CAUSES SERIOUS EYE IRRITATION.
RESPIRATORY OR SKIN SENSITIZATION:
RESPIRATORY SENSITIZATION: NOT A RESPIRATORY SENSITIZER.
SKIN SENSITIZATION: MAY CAUSE AN ALLERGIC SKIN REACTION.
GERM CELL MUTAGENICITY:
NO DATA AVAILABLE TO INDICATE PRODUCT OR ANY COMPONENTS PRESENT AT GREATER
THAN 0.1% ARE MUTAGENIC OR GENOTOXIC.
CARCINOGENICITY: NOT CLASSIFIABLE AS TO CARCINOGENICITY TO HUMANS.
IARC MONOGRAPHS. OVERALL EVALUATION OF CARCINOGENICITY: NOT LISTED.
OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1053): NOT LISTED.
US. NATIONAL TOXICOLOGY PROGRAM (NTP) REPORT ON CARCINOGENS: NOT LISTED.
REPRODUCTIVE TOXICITY:
THIS PRODUCT IS NOT EXPECTED TO CAUSE REPRODUCTIVE OR DEVELOPMENTAL
EFFECTS.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
MAY CAUSE DROWSINESS AND DIZZINESS.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NOT CLASSIFIED.
ASPIRATION HAZARD: NOT AN ASPIRATION HAZARD.
CHRONIC EFFECTS: PROLONGED INHALATION MAY BE HARMFUL.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
THE PRODUCT IS NOT CLASSIFIED AS ENVIRONMENTALLY HAZARDOUS. HOWEVER, THIS
DOES NOT EXCLUDE THE POSSIBILITY THAT LARGE OR FREQUENT SPILLS CAN HAVE A
HARMFUL OR DAMAGING EFFECT ON THE ENVIRONMENT.
PERSISTENCE AND DEGRADABILITY:
NO DATA IS AVAILABLE ON THE DEGRADABILITY OF ANY INGREDIENTS IN THE
MIXTURE.
BIOACCUMULATIVE POTENTIAL:
MOBILITY IN SOIL: NO DATA AVAILABLE.
OTHER ADVERSE EFFECTS:
NO OTHER ADVERSE ENVIRONMENTAL EFFECTS (E.G. OZONE DEPLETION,
PHOTOCHEMICAL OZONE CREATION POTENTIAL, ENDOCRINE DISRUPTION,
GLOBAL WARMING POTENTIAL) ARE EXPECTED FROM THIS COMPONENT.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL INSTRUCTIONS:
COLLECT AND RECLAIM OR DISPOSE IN SEALED CONTAINERS AT LICENSED
WASTE DISPOSAL SITE. DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE
WITH LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
LOCAL DISPOSAL REGULATIONS:
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS.
HAZARDOUS WASTE CODE:
THE WASTE CODE SHOULD BE ASSIGNED IN DISCUSSION BETWEEN THE USER, THE
PRODUCER AND THE WASTE DISPOSAL COMPANY.
WASTE FROM RESIDUES / UNUSED PRODUCTS:
DISPOSE OF IN ACCORDANCE WITH LOCAL REGULATIONS. EMPTY CONTAINERS OR
LINERS MAY RETAIN SOME PRODUCT RESIDUES. THIS MATERIAL AND ITS CONTAINER
MUST BE DISPOSED OF IN A SAFE MANNER (SEE: DISPOSAL INSTRUCTIONS).
CONTAMINATED PACKAGING:
SINCE EMPTIED CONTAINERS MAY RETAIN PRODUCT RESIDUE, FOLLOW LABEL WARNINGS
EVEN AFTER CONTAINER IS EMPTIED. EMPTY CONTAINERS SHOULD BE TAKEN TO AN
APPROVED WASTE HANDLING SITE FOR RECYCLING OR DISPOSAL.
| 14. TRANSPORT INFORMATION | |
DOT: NOT REGULATED AS DANGEROUS GOODS.
IATA: NOT REGULATED AS DANGEROUS GOODS.
IMDG: NOT REGULATED AS DANGEROUS GOODS.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE:
NOT ESTABLISHED.
| 15. REGULATORY INFORMATION | |
US FEDERAL REGULATIONS:
THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.
TOXIC SUBSTANCES CONTROL ACT (TSCA):
TSCA SECTION 12(B) EXPORT NOTIFICATION (40 CFR 707, SUBPT. D):
NOT REGULATED.
CERCLA HAZARDOUS SUBSTANCE LIST (40 CFR 302.4): NOT LISTED.
SARA 304 EMERGENCY RELEASE NOTIFICATION: NOT REGULATED.
OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1053):
NOT LISTED.
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA):
SARA 302 EXTREMELY HAZARDOUS SUBSTANCE: NOT LISTED.
SARA 311/312 HAZARDOUS CHEMICAL: YES
CLASSIFIED HAZARD CATEGORIES:
SKIN CORROSION OR IRRITATION
SERIOUS EYE DAMAGE OR EYE IRRITATION
RESPIRATORY OR SKIN SENSITIZATION
SPECIFIC TARGET ORGAN TOXICITY (SINGLE OR REPEATED EXPOSURE)
SARA 313 (TRI REPORTING): NOT REGULATED.
OTHER FEDERAL REGULATIONS:
CLEAN AIR ACT (CAA) SECTION 112 HAZARDOUS AIR POLLUTANTS (HAPS) LIST:
NOT REGULATED.
CLEAN AIR ACT (CAA) SECTION 112(R) ACCIDENTAL RELEASE PREVENTION
(40 CFR 68.130): NOT REGULATED.
SAFE DRINKING WATER ACT (SDWA): NOT REGULATED.
US STATE REGULATIONS:
CALIFORNIA PROPOSITION 65:
WARNING:
THIS PRODUCT CAN EXPOSE YOU TO CHEMICALS INCLUDING BENZENE, WHICH IS KNOWN
TO THE STATE OF CALIFORNIA TO CAUSE CANCER AND BIRTH DEFECTS OR OTHER
REPRODUCTIVE HARM. FOR MORE INFORMATION GO TO WWW.P65WARNINGS.CA.GOV.
INTERNATIONAL INVENTORIES:
COUNTRY(S) OR REGION INVENTORY NAME ON INVENTORY
(YES/NO)*
AUSTRALIA AUSTRALIAN INVENTORY OF CHEMICAL NO
SUBSTANCES (AICS)
CANADA DOMESTIC SUBSTANCES LIST (DSL) NO
CANADA NON-DOMESTIC SUBSTANCES LIST (NDSL) NO
CHINA INVENTORY OF EXISTING CHEMICAL NO
SUBSTANCES IN CHINA (IECSC)
EUROPE EUROPEAN INVENTORY OF EXISTING NO
COMMERCIAL CHEMICAL SUBSTANCES
(EINECS)
EUROPE EUROPEAN LIST OF NOTIFIED CHEMICAL NO
SUBSTANCES (ELINCS)
JAPAN INVENTORY OF EXISTING AND NEW NO
CHEMICAL SUBSTANCES (ENCS)
KOREA EXISTING CHEMICALS LIST (ECL) NO
NEW ZEALAND NEW ZEALAND INVENTORY YES
PHILIPPINES PHILIPPINE INVENTORY OF CHEMICALS AND YES
CHEMICAL SUBSTANCES (PICCS)
TAIWAN TAIWAN CHEMICAL SUBSTANCE INVENTORY YES
(TCSI)
UNITED STATES & TOXIC SUBSTANCES CONTROL ACT (TSCA) YES
PUERTO RICO INVENTORY
*A "YES" INDICATES THAT ALL COMPONENTS OF THIS PRODUCT COMPLY WITH THE
INVENTORY REQUIREMENTS ADMINISTERED BY THE GOVERNING COUNTRY(S)
A "NO" INDICATES THAT ONE OR MORE COMPONENTS OF THE PRODUCT ARE NOT
LISTED OR EXEMPT FROM LISTING ON THE INVENTORY ADMINISTERED BY THE
GOVERNING COUNTRY(S).
| 16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION | |
OR LAST REVISION
ISSUE DATE: 05-29-2019
VERSION #: 01
HMIS(R*) RATINGS:
HEALTH 2
FLAMMABILITY 1
PHYSICAL HAZARD 0
NFPA RATINGS:
HEALTH 2
FLAMMABILITY 1
INSTABILITY 0
DISCLAIMER:
ITW PERFORMANCE POLYMERS CANNOT ANTICIPATE ALL CONDITIONS UNDER WHICH
THIS INFORMATION AND ITS PRODUCT, OR THE PRODUCTS OF OTHER MANUFACTURERS
IN COMBINATION WITH ITS PRODUCT, MAY BE USED. IT IS THE USER'S
RESPONSIBILITY TO ENSURE SAFE CONDITIONS FOR HANDLING, STORAGE AND
DISPOSAL OF THE PRODUCT, AND TO ASSUME LIABILITY FOR LOSS, INJURY,
DAMAGE OR EXPENSE DUE TO IMPROPER USE. THE INFORMATION PROVIDED IN
THIS SAFETY DATA SHEET IS CORRECT TO THE BEST OF OUR KNOWLEDGE,
INFORMATION AND BELIEF AT THE DATE OF ITS PUBLICATION. THE INFORMATION
RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID
FOR SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY
PROCESS, UNLESS SPECIFIED IN THE TEXT. THE INFORMATION GIVEN IS DESIGNED
ONLY AS A GUIDANCE FOR SAFE HANDLING, USE, PROCESSING, STORAGE,
TRANSPORTATION, DISPOSAL AND RELEASE.
MATERIAL NAME: DEVCON(R*) TITANIUM PUTTY RESIN
SDS US
SAFETY DATA SHEET
| 1. IDENTIFICATION | |
PRODUCT IDENTIFIER: DEVCON(R*) TITANIUM PUTTY HARDENER
OTHER MEANS OF IDENTIFICATION:
SKU#: 5318N
RECOMMENDED USE: NOT AVAILABLE.
RECOMMENDED RESTRICTIONS: NONE KNOWN.
MANUFACTURER/IMPORTER/SUPPLIER/DISTRIBUTOR INFORMATION:
MANUFACTURER:
COMPANY NAME: ITW PERFORMANCE POLYMERS
ADDRESS:
30 ENDICOTT STREET
DANVERS, MA 01923
UNITED STATES
TELEPHONE:
CUSTOMER SERVICE: 978-777-1100
WEBSITE: WWW.ITWPERFORMANCEPOLYMERS.COM
E-MAIL: NOT AVAILABLE.
CONTACT PERSON: EHS DEPARTMENT
EMERGENCY PHONE NUMBER:
CHEMTREC: 800-424-9300
INTERNATIONAL: 703-527-3887
| 2. HAZARD(S) IDENTIFICATION | |
PHYSICAL HAZARDS: NOT CLASSIFIED.
HEALTH HAZARDS:
ACUTE TOXICITY, ORAL: CATEGORY 4
ACUTE TOXICITY, DERMAL: CATEGORY 4
SKIN CORROSION/IRRITATION: CATEGORY 1
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 1
SENSITIZATION, SKIN: CATEGORY 1
SPECIFIC TARGET ORGAN TOXICITY, SINGLE EXPOSURE:
CATEGORY 3 NARCOTIC EFFECTS
ENVIRONMENTAL HAZARDS: NOT CLASSIFIED.
OSHA DEFINED HAZARDS: NOT CLASSIFIED.
LABEL ELEMENTS:
CORROSION
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENT:
HARMFUL IF SWALLOWED. HARMFUL IN CONTACT WITH SKIN. CAUSES SEVERE SKIN
BURNS AND EYE DAMAGE. MAY CAUSE AN ALLERGIC SKIN REACTION. CAUSES SERIOUS
EYE DAMAGE. MAY CAUSE DROWSINESS OR DIZZINESS.
PRECAUTIONARY STATEMENT:
PREVENTION:
AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY. WASH THOROUGHLY AFTER
HANDLING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. USE ONLY
OUTDOORS OR IN A WELL-VENTILATED AREA.
CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE. WEAR
PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
RESPONSE:
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING.
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF IN EYES: RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES.
REMOVE CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IMMEDIATELY CALL A POISON CENTER/DOCTOR.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE
LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
HAZARD(S) NOT OTHERWISE CLASSIFIED (HNOC): NONE KNOWN.
SUPPLEMENTAL INFORMATION: NONE.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
MIXTURES:
CHEMICAL NAME COMMON NAME AND SYNONYMS CAS NUMBER %
FERROSILICON, 8049-17-0 10 - 30
[WITH >= 30% BUT
<= 70% SILICON]
FORMALDEHYDE, 32610-77-8 10 - 30
OLIGOMERIC REACTION
PRODUCTS WITH PHENOL
AND TRIETHYLENETETRAMINE
GLASS OXIDE 65997-17-3 5 - 10
PHENOL 108-95-2 5 - 10
TRIETHYLENETETRAMINE 112-24-3 5 - 10
1H-IMIDAZOLE, 931-36-2 2.5 - 10
2-ETHYL-4-METHYL-
TITANIUM DIOXIDE 13463-67-7 1 - 5
METHYLIMIDAZOLE, 4- 822-36-6 0.1 - 1
OTHER COMPONENTS BELOW 10 - 20
REPORTABLE LEVELS
*DESIGNATES THAT A SPECIFIC CHEMICAL IDENTITY AND/OR PERCENTAGE OF
COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| 4. FIRST-AID MEASURES | |
INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING IMMEDIATELY AND WASH SKIN WITH SOAP AND
WATER. CALL A PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. CHEMICAL
BURNS MUST BE TREATED BY A PHYSICIAN. WASH CONTAMINATED CLOTHING BEFORE
REUSE.
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES.
REMOVE CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING.
CALL A PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY.
INGESTION:
CALL A PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. RINSE MOUTH. DO
NOT INDUCE VOMITING. IF VOMITING OCCURS, KEEP HEAD LOW SO THAT STOMACH
CONTENT DOESN'T GET INTO THE LUNGS.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
MAY CAUSE DROWSINESS AND DIZZINESS. HEADACHE. NAUSEA, VOMITING. BURNING
PAIN AND SEVERE CORROSIVE SKIN DAMAGE. CAUSES SERIOUS EYE DAMAGE. SYMPTOMS
MAY INCLUDE STINGING, TEARING, REDNESS, SWELLING, AND BLURRED VISION.
PERMANENT EYE DAMAGE INCLUDING BLINDNESS COULD RESULT.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
PROVIDE GENERAL SUPPORTIVE MEASURES AND TREAT SYMPTOMATICALLY.
CHEMICAL BURNS:
FLUSH WITH WATER IMMEDIATELY. WHILE FLUSHING, REMOVE CLOTHES WHICH DO
NOT ADHERE TO AFFECTED AREA. CALL AN AMBULANCE. CONTINUE FLUSHING DURING
TRANSPORT TO HOSPITAL. KEEP VICTIM WARM. KEEP VICTIM UNDER OBSERVATION.
SYMPTOMS MAY BE DELAYED.
GENERAL INFORMATION:
ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE MATERIAL(S) INVOLVED, AND
TAKE PRECAUTIONS TO PROTECT THEMSELVES. SHOW THIS SAFETY DATA SHEET TO THE
DOCTOR IN ATTENDANCE. WASH CONTAMINATED CLOTHING BEFORE REUSE.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
WATER FOG. FOAM. DRY CHEMICAL POWDER. CARBON DIOXIDE (CO2).
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE WATER JET AS AN EXTINGUISHER, AS THIS WILL SPREAD THE FIRE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
DURING FIRE, GASES HAZARDOUS TO HEALTH MAY BE FORMED.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING MUST BE
WORN IN CASE OF FIRE.
FIRE FIGHTING EQUIPMENT/INSTRUCTIONS:
USE WATER SPRAY TO COOL UNOPENED CONTAINERS.
SPECIFIC METHODS:
USE STANDARD FIREFIGHTING PROCEDURES AND CONSIDER THE HAZARDS OF OTHER
INVOLVED MATERIALS.
GENERAL FIRE HAZARDS: NO UNUSUAL FIRE OR EXPLOSION HAZARDS NOTED.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
KEEP UNNECESSARY PERSONNEL AWAY. KEEP PEOPLE AWAY FROM AND UPWIND OF
SPILL/LEAK. WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND CLOTHING DURING
CLEAN-UP. DO NOT TOUCH DAMAGED CONTAINERS OR SPILLED MATERIAL UNLESS
WEARING APPROPRIATE PROTECTIVE CLOTHING. ENSURE ADEQUATE VENTILATION.
LOCAL AUTHORITIES SHOULD BE ADVISED IF SIGNIFICANT SPILLAGES CANNOT BE
CONTAINED. FOR PERSONAL PROTECTION, SEE SECTION 8 OF THE SDS.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
LARGE SPILLS:
STOP THE FLOW OF MATERIAL, IF THIS IS WITHOUT RISK. DIKE THE SPILLED
MATERIAL, WHERE THIS IS POSSIBLE. ABSORB IN VERMICULITE, DRY SAND OR
EARTH AND PLACE INTO CONTAINERS. FOLLOWING PRODUCT RECOVERY, FLUSH
AREA WITH WATER.
SMALL SPILLS:
WIPE UP WITH ABSORBENT MATERIAL (E.G. CLOTH, FLEECE). CLEAN SURFACE
THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION.
NEVER RETURN SPILLS TO ORIGINAL CONTAINERS FOR RE-USE. FOR WASTE DISPOSAL,
SEE SECTION 13 OF THE SDS.
ENVIRONMENTAL PRECAUTIONS:
AVOID DISCHARGE INTO DRAINS, WATER COURSES OR ONTO THE GROUND.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING. DO NOT TASTE OR SWALLOW.
AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY. AVOID PROLONGED EXPOSURE.
WHEN USING, DO NOT EAT, DRINK OR SMOKE. PROVIDE ADEQUATE VENTILATION. WEAR
APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT. WASH HANDS THOROUGHLY AFTER
HANDLING. WASH CONTAMINATED CLOTHING BEFORE REUSE. OBSERVE GOOD INDUSTRIAL
HYGIENE PRACTICES.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE LOCKED UP. STORE IN TIGHTLY CLOSED CONTAINER. STORE AWAY FROM
INCOMPATIBLE MATERIALS (SEE SECTION 10 OF THE SDS).
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE LIMITS:
THE FOLLOWING CONSTITUENTS ARE THE ONLY CONSTITUENTS OF THE PRODUCT WHICH
HAVE A PEL, TLV OR OTHER RECOMMENDED EXPOSURE LIMIT. AT THIS TIME, THE
OTHER CONSTITUENTS HAVE NO KNOWN EXPOSURE LIMITS.
US. OSHA TABLE Z-1 LIMITS FOR AIR CONTAMINANTS (29 CFR 1910.1000):
COMPONENTS TYPE VALUE FORM
PHENOL PEL 19 MG/M3
(CAS 108-95-2) 5 PPM
TITANIUM DIOXIDE PEL 15 MG/M3 TOTAL DUST.
(CAS 13463-67-7)
US. OSHA TABLE Z-3 (29 CFR 1910.1000):
COMPONENTS TYPE VALUE FORM
TITANIUM DIOXIDE TWA 5 MG/M3 RESPIRABLE FRACTION.
(CAS 13463-67-7) 15 MG/M3 TOTAL DUST.
50 MPPCF TOTAL DUST.
15 MPPCF RESPIRABLE FRACTION.
US. ACGIH THRESHOLD LIMIT VALUES:
COMPONENTS TYPE VALUE
PHENOL TWA 5 PPM
(CAS 108-95-2)
TITANIUM DIOXIDE TWA 10 MG/M3
(CAS 13463-67-7)
US. NIOSH: POCKET GUIDE TO CHEMICAL HAZARDS
COMPONENTS TYPE VALUE FORM
GLASS OXIDE TWA 3 FIBERS/CM3 FIBER.
(CAS 65997-17-3) 3 FIBERS/CM3 FIBROUS DUST.
5 MG/M3 FIBERS, TOTAL DUST
5 MG/M3 FIBER, TOTAL
PHENOL CEILING 60 MG/M3
(CAS 108-95-2) 15.6 PPM
US. NIOSH: POCKET GUIDE TO CHEMICAL HAZARDS
COMPONENTS TYPE VALUE FORM
TWA 19 MG/M3
5 PPM
US. WORKPLACE ENVIRONMENTAL EXPOSURE LEVEL (WEEL) GUIDES:
COMPONENTS TYPE VALUE
TRIETHYLENETETRAMINE TWA 6 MG/M3
(CAS 112-24-3) 1 PPM
BIOLOGICAL LIMIT VALUES:
ACGIH BIOLOGICAL EXPOSURE INDICES:
COMPONENTS VALUE DETERMINANT SPECIMEN SAMPLING TIME
PHENOL 250 MG/G PHENOL WITH CREATININE *
(CAS 108-95-2) HYDROLYSIS IN URINE
* - FOR SAMPLING DETAILS, PLEASE SEE THE SOURCE DOCUMENT.
EXPOSURE GUIDELINES:
US - CALIFORNIA OELS:
SKIN DESIGNATION:
PHENOL (CAS 108-95-2): CAN BE ABSORBED THROUGH THE SKIN.
US - MINNESOTA HAZ SUBS:
SKIN DESIGNATION APPLIES:
PHENOL (CAS 108-95-2): SKIN DESIGNATION APPLIES.
US - TENNESSEE OELS:
SKIN DESIGNATION:
PHENOL (CAS 108-95-2): CAN BE ABSORBED THROUGH THE SKIN.
US ACGIH THRESHOLD LIMIT VALUES:
SKIN DESIGNATION:
PHENOL (CAS 108-95-2): CAN BE ABSORBED THROUGH THE SKIN.
US NIOSH POCKET GUIDE TO CHEMICAL HAZARDS:
SKIN DESIGNATION:
PHENOL (CAS 108-95-2): CAN BE ABSORBED THROUGH THE SKIN.
US WEEL GUIDES:
SKIN DESIGNATION:
TRIETHYLENETETRAMINE (CAS 112-24-3): CAN BE ABSORBED THROUGH THE SKIN.
US. OSHA TABLE Z-1 LIMITS FOR AIR CONTAMINANTS (29 CFR 1910.1000):
PHENOL (CAS 108-95-2): CAN BE ABSORBED THROUGH THE SKIN.
APPROPRIATE ENGINEERING CONTROLS:
GOOD GENERAL VENTILATION SHOULD BE USED. VENTILATION RATES SHOULD BE
MATCHED TO CONDITIONS. IF APPLICABLE, USE PROCESS ENCLOSURES, LOCAL
EXHAUST VENTILATION, OR OTHER ENGINEERING CONTROLS TO MAINTAIN AIRBORNE
LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. IF EXPOSURE LIMITS HAVE NOT
BEEN ESTABLISHED, MAINTAIN AIRBORNE LEVELS TO AN ACCEPTABLE LEVEL. EYE
WASH FACILITIES AND EMERGENCY SHOWER MUST BE AVAILABLE WHEN HANDLING
THIS PRODUCT.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION:
WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES) AND A FACE SHIELD.
SKIN PROTECTION:
HAND PROTECTION: WEAR APPROPRIATE CHEMICAL RESISTANT GLOVES.
OTHER:
WEAR APPROPRIATE CHEMICAL RESISTANT CLOTHING. USE OF AN IMPERVIOUS APRON
IS RECOMMENDED.
RESPIRATORY PROTECTION:
IN CASE OF INSUFFICIENT VENTILATION, WEAR SUITABLE RESPIRATORY EQUIPMENT.
CHEMICAL RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE.
THERMAL HAZARDS:
WEAR APPROPRIATE THERMAL PROTECTIVE CLOTHING, WHEN NECESSARY.
GENERAL HYGIENE CONSIDERATIONS:
KEEP AWAY FROM FOOD AND DRINK. ALWAYS OBSERVE GOOD PERSONAL HYGIENE
MEASURES, SUCH AS WASHING AFTER HANDLING THE MATERIAL AND BEFORE EATING,
DRINKING, AND/OR SMOKING. ROUTINELY WASH WORK CLOTHING AND PROTECTIVE
EQUIPMENT TO REMOVE CONTAMINANTS. CONTAMINATED WORK CLOTHING SHOULD NOT
BE ALLOWED OUT OF THE WORKPLACE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: PASTE.
PHYSICAL STATE: SOLID.
FORM: PASTE.
COLOR: OFF-WHITE.
ODOR: AMMONIACAL.
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
MELTING POINT/FREEZING POINT: 53.6 DEG. F (12 DEG. C) ESTIMATED
INITIAL BOILING POINT AND BOILING RANGE:
510.8 DEG. F (266 DEG. C) ESTIMATED
FLASH POINT: 276.1 DEG. F (135.6 DEG. C) ESTIMATED
EVAPORATION RATE: NOT AVAILABLE.
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE.
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS:
FLAMMABILITY LIMIT - LOWER (%): NOT AVAILABLE.
FLAMMABILITY LIMIT - UPPER (%): NOT AVAILABLE.
EXPLOSIVE LIMIT - LOWER (%): NOT AVAILABLE.
EXPLOSIVE LIMIT - UPPER (%): NOT AVAILABLE.
VAPOR PRESSURE: 0.001 HPA ESTIMATED
VAPOR DENSITY: NOT AVAILABLE.
RELATIVE DENSITY: NOT AVAILABLE.
SOLUBILITY(IES):
SOLUBILITY (WATER): NOT AVAILABLE.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: 640 DEG. F (337.78 DEG. C) ESTIMATED
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY: NOT AVAILABLE.
OTHER INFORMATION:
DENSITY: 1.65 G/CM3 ESTIMATED
EXPLOSIVE PROPERTIES: NOT EXPLOSIVE.
OXIDIZING PROPERTIES: NOT OXIDIZING.
SPECIFIC GRAVITY: 1.65 ESTIMATED
VOC: 0 G/L
| 10. STABILITY AND REACTIVITY | |
REACTIVITY:
THE PRODUCT IS STABLE AND NON-REACTIVE UNDER NORMAL CONDITIONS OF USE,
STORAGE AND TRANSPORT.
CHEMICAL STABILITY: MATERIAL IS STABLE UNDER NORMAL CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION DOES NOT OCCUR.
CONDITIONS TO AVOID:
KEEP AWAY FROM HEAT, HOT SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION
SOURCES. CONTACT WITH INCOMPATIBLE MATERIALS.
INCOMPATIBLE MATERIALS: PEROXIDES. PHENOLS.
HAZARDOUS DECOMPOSITION PRODUCTS:
NO HAZARDOUS DECOMPOSITION PRODUCTS ARE KNOWN.
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INHALATION:
MAY CAUSE DROWSINESS AND DIZZINESS. HEADACHE. NAUSEA, VOMITING. MAY CAUSE
IRRITATION TO THE RESPIRATORY SYSTEM. PROLONGED INHALATION MAY BE HARMFUL.
SKIN CONTACT:
CAUSES SEVERE SKIN BURNS. HARMFUL IN CONTACT WITH SKIN. MAY CAUSE AN
ALLERGIC SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
INGESTION: CAUSES DIGESTIVE TRACT BURNS. HARMFUL IF SWALLOWED.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
MAY CAUSE DROWSINESS AND DIZZINESS. HEADACHE. NAUSEA, VOMITING. BURNING
PAIN AND SEVERE CORROSIVE SKIN DAMAGE. CAUSES SERIOUS EYE DAMAGE. SYMPTOMS
MAY INCLUDE STINGING, TEARING, REDNESS, SWELLING, AND BLURRED VISION.
PERMANENT EYE DAMAGE INCLUDING BLINDNESS COULD RESULT.
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
IN HIGH CONCENTRATIONS, VAPORS ARE ANESTHETIC AND MAY CAUSE HEADACHE,
FATIGUE, DIZZINESS AND CENTRAL NERVOUS SYSTEM EFFECTS. HARMFUL IN
CONTACT WITH SKIN. HARMFUL IF SWALLOWED.
COMPONENTS SPECIES TEST RESULTS
METHYLIMIDAZOLE, 4- (CAS 822-36-6):
ACUTE:
DERMAL:
LD50 RABBIT 440 MG/KG
PHENOL (CAS 108-95-2):
ACUTE:
DERMAL:
LD50 RAT 669 MG/KG
TRIETHYLENETETRAMINE (CAS 112-24-3):
ACUTE:
DERMAL:
LIQUID:
LD50 RAT 1465 MG/KG
ORAL:
LIQUID:
LD50 RAT 1716 MG/KG
SKIN CORROSION/IRRITATION: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
SERIOUS EYE DAMAGE/EYE IRRITATION: CAUSES SERIOUS EYE DAMAGE.
RESPIRATORY OR SKIN SENSITIZATION:
RESPIRATORY SENSITIZATION: NOT A RESPIRATORY SENSITIZER.
SKIN SENSITIZATION: MAY CAUSE AN ALLERGIC SKIN REACTION.
GERM CELL MUTAGENICITY:
NO DATA AVAILABLE TO INDICATE PRODUCT OR ANY COMPONENTS PRESENT AT GREATER
THAN 0.1% ARE MUTAGENIC OR GENOTOXIC.
CARCINOGENICITY:
RISK OF CANCER CANNOT BE EXCLUDED WITH PROLONGED EXPOSURE.
IARC MONOGRAPHS. OVERALL EVALUATION OF CARCINOGENICITY:
METHYLIMIDAZOLE, 4- (CAS 822-36-6): 2B POSSIBLY CARCINOGENIC TO HUMANS.
PHENOL (CAS 108-95-2): 3 NOT CLASSIFIABLE AS TO CARCINOGENICITY TO HUMANS.
TITANIUM DIOXIDE (CAS 13463-67-7): 2B POSSIBLY CARCINOGENIC TO HUMANS.
OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1053):
NOT LISTED.
US. NATIONAL TOXICOLOGY PROGRAM (NTP) REPORT ON CARCINOGENS: NOT LISTED.
REPRODUCTIVE TOXICITY:
THIS PRODUCT IS NOT EXPECTED TO CAUSE REPRODUCTIVE OR DEVELOPMENTAL
EFFECTS.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
MAY CAUSE DROWSINESS AND DIZZINESS.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NOT APPLICABLE.
ASPIRATION HAZARD: NOT AN ASPIRATION HAZARD.
CHRONIC EFFECTS:
PROLONGED INHALATION MAY BE HARMFUL. PROLONGED EXPOSURE MAY CAUSE CHRONIC
EFFECTS.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
THE PRODUCT IS NOT CLASSIFIED AS ENVIRONMENTALLY HAZARDOUS. HOWEVER, THIS
DOES NOT EXCLUDE THE POSSIBILITY THAT LARGE OR FREQUENT SPILLS CAN HAVE A
HARMFUL OR DAMAGING EFFECT ON THE ENVIRONMENT.
PERSISTENCE AND DEGRADABILITY:
NO DATA IS AVAILABLE ON THE DEGRADABILITY OF ANY INGREDIENTS IN THE
MIXTURE.
BIOACCUMULATIVE POTENTIAL:
PARTITION COEFFICIENT N-OCTANOL / WATER (LOG KOW):
PHENOL: 1.46
MOBILITY IN SOIL: NO DATA AVAILABLE.
OTHER ADVERSE EFFECTS:
NO OTHER ADVERSE ENVIRONMENTAL EFFECTS (E.G. OZONE DEPLETION,
PHOTOCHEMICAL OZONE CREATION POTENTIAL, ENDOCRINE DISRUPTION,
GLOBAL WARMING POTENTIAL) ARE EXPECTED FROM THIS COMPONENT.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL INSTRUCTIONS:
COLLECT AND RECLAIM OR DISPOSE IN SEALED CONTAINERS AT LICENSED WASTE
DISPOSAL SITE. INCINERATE THE MATERIAL UNDER CONTROLLED CONDITIONS IN
AN APPROVED INCINERATOR. DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE
WITH LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
LOCAL DISPOSAL REGULATIONS:
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS.
HAZARDOUS WASTE CODE:
D002:
WASTE CORROSIVE MATERIAL [PH <=2 OR =>12.5, OR CORROSIVE TO STEEL]
THE WASTE CODE SHOULD BE ASSIGNED IN DISCUSSION BETWEEN THE USER, THE
PRODUCER AND THE WASTE DISPOSAL COMPANY.
WASTE FROM RESIDUES / UNUSED PRODUCTS:
DISPOSE OF IN ACCORDANCE WITH LOCAL REGULATIONS. EMPTY CONTAINERS OR
LINERS MAY RETAIN SOME PRODUCT RESIDUES. THIS MATERIAL AND ITS CONTAINER
MUST BE DISPOSED OF IN A SAFE MANNER (SEE: DISPOSAL INSTRUCTIONS).
CONTAMINATED PACKAGING:
SINCE EMPTIED CONTAINERS MAY RETAIN PRODUCT RESIDUE, FOLLOW LABEL WARNINGS
EVEN AFTER CONTAINER IS EMPTIED. EMPTY CONTAINERS SHOULD BE TAKEN TO AN
APPROVED WASTE HANDLING SITE FOR RECYCLING OR DISPOSAL.
| 14. TRANSPORT INFORMATION | |
DOT:
UN NUMBER: UN3259
UN PROPER SHIPPING NAME:
AMINES, SOLID, CORROSIVE, N.O.S., OR POLYAMINES, SOLID, CORROSIVE N.O.S.
(TRIETHYLENETETRAMINE, METHYLIMIDAZOLE, 4-), LIMITED QUANTITY
TRANSPORT HAZARD CLASS(ES):
CLASS: 8
SUBSIDIARY RISK:
LABEL(S): 8
PACKING GROUP: III
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
SPECIAL PROVISIONS: IB8, IP3, T1, TP33
PACKAGING EXCEPTIONS: 154
PACKAGING NON BULK: 213
PACKAGING BULK: 240
IATA:
UN NUMBER: UN3259
UN PROPER SHIPPING NAME:
AMINES, SOLID, CORROSIVE, N.O.S. (TRIETHYLENETETRAMINE, METHYLIMIDAZOLE,
4-), LIMITED QUANTITY
TRANSPORT HAZARD CLASS(ES):
CLASS: 8
SUBSIDIARY RISK:
PACKING GROUP: III
ENVIRONMENTAL HAZARDS: NO.
ERG CODE: 8L
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
OTHER INFORMATION:
PASSENGER AND CARGO AIRCRAFT: ALLOWED WITH RESTRICTIONS.
CARGO AIRCRAFT ONLY: ALLOWED WITH RESTRICTIONS.
IMDG:
UN NUMBER: UN3259
UN PROPER SHIPPING NAME:
AMINES, SOLID, CORROSIVE, N.O.S. OR POLYAMINES, SOLID, CORROSIVE, N.O.S.
(TRIETHYLENETETRAMINE, METHYLIMIDAZOLE, 4-), LIMITED QUANTITY
TRANSPORT HAZARD CLASS(ES):
CLASS: 8
SUBSIDIARY RISK:
PACKING GROUP: III
ENVIRONMENTAL HAZARDS:
MARINE POLLUTANT: NO.
EMS: F-A, S-B
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE:
NOT APPLICABLE.
DOT; IMDG: LIMITED QUANTITY FOR PACKAGES NOT PREPARED FOR AIR TRANSPORT
IATA: LIMITED QUANTITY MARKING FOR PACKAGES PREPARED FOR AIR TRANSPORT
| 15. REGULATORY INFORMATION | |
US FEDERAL REGULATIONS:
THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.
US EPCRA (SARA TITLE III) SECTION 313 - TOXIC CHEMICAL:
DE MINIMIS CONCENTRATION:
PHENOL (CAS 108-95-2): % 1.0
US EPCRA (SARA TITLE III) SECTION 313 - TOXIC CHEMICAL:
LISTED SUBSTANCE:
PHENOL (CAS 108-95-2): LISTED.
TOXIC SUBSTANCES CONTROL ACT (TSCA):
TSCA SECTION 12(B) EXPORT NOTIFICATION (40 CFR 707, SUBPT. D):
NOT REGULATED.
CERCLA HAZARDOUS SUBSTANCE LIST (40 CFR 302.4):
PHENOL (CAS 108-95-2): LISTED.
SARA 304 EMERGENCY RELEASE NOTIFICATION:
PHENOL (CAS 108-95-2): 1000 LBS
OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1053):
NOT LISTED.
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA):
SARA 302 EXTREMELY HAZARDOUS SUBSTANCE:
CHEMICAL CAS REPORTABLE THRESHOLD THRESHOLD THRESHOLD
NAME NUMBER QUANTITY PLANNING PLANNING PLANNING
(POUNDS) QUANTITY QUANTITY, QUANTITY,
(POUNDS) LOWER VALUE UPPER VALUE
(POUNDS) (POUNDS)
PHENOL 108-95-2 1000 500 10000
SARA 311/312 HAZARDOUS CHEMICAL: YES
CLASSIFIED HAZARD CATEGORIES:
ACUTE TOXICITY (ANY ROUTE OF EXPOSURE)
SKIN CORROSION OR IRRITATION
SERIOUS EYE DAMAGE OR EYE IRRITATION
RESPIRATORY OR SKIN SENSITIZATION
SPECIFIC TARGET ORGAN TOXICITY (SINGLE OR REPEATED EXPOSURE)
SARA 313 (TRI REPORTING):
CHEMICAL NAME CAS NUMBER % BY WT.
PHENOL 108-95-2 5 - 10
OTHER FEDERAL REGULATIONS:
CLEAN AIR ACT (CAA) SECTION 112 HAZARDOUS AIR POLLUTANTS (HAPS) LIST:
PHENOL (CAS 108-95-2)
CLEAN AIR ACT (CAA) SECTION 112(R) ACCIDENTAL RELEASE PREVENTION
(40 CFR 68.130): NOT REGULATED.
SAFE DRINKING WATER ACT (SDWA): NOT REGULATED.
FEMA PRIORITY SUBSTANCES RESPIRATORY HEALTH AND SAFETY IN THE FLAVOR
MANUFACTURING WORKPLACE:
PHENOL (CAS 108-95-2): LOW PRIORITY
US STATE REGULATIONS:
CALIFORNIA PROPOSITION 65:
WARNING:
THIS PRODUCT CAN EXPOSE YOU TO CHEMICALS INCLUDING TITANIUM DIOXIDE, WHICH
IS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER. FOR MORE INFORMATION
GO TO WWW.P65WARNINGS.CA.GOV.
CALIFORNIA PROPOSITION 65 - CRT:
LISTED DATE/CARCINOGENIC SUBSTANCE:
METHYLIMIDAZOLE, 4- (CAS 822-36-6):
LISTED: JANUARY 7, 2011
TITANIUM DIOXIDE (CAS 13463-67-7):
LISTED: SEPTEMBER 2, 2011
US. CALIFORNIA. CANDIDATE CHEMICALS LIST. SAFER CONSUMER PRODUCTS
REGULATIONS (CAL. CODE REGS, TIT. 22, 69502.3, SUBD. (A)):
GLASS OXIDE (CAS 65997-17-3)
METHYLIMIDAZOLE, 4- (CAS 822-36-6)
PHENOL (CAS 108-95-2)
TITANIUM DIOXIDE (CAS 13463-67-7)
INTERNATIONAL INVENTORIES:
COUNTRY(S) OR REGION INVENTORY NAME ON INVENTORY (YES/NO)*
AUSTRALIA AUSTRALIAN INVENTORY OF NO
CHEMICAL SUBSTANCES (AICS)
CANADA DOMESTIC SUBSTANCES LIST NO
(DSL)
CANADA NON-DOMESTIC SUBSTANCES NO
LIST (NDSL)
CHINA INVENTORY OF EXISTING NO
CHEMICAL SUBSTANCES IN
CHINA (IECSC)
EUROPE EUROPEAN INVENTORY OF NO
EXISTING COMMERCIAL
CHEMICAL SUBSTANCES
(EINECS)
EUROPE EUROPEAN LIST OF NO
NOTIFIED CHEMICAL
SUBSTANCES (ELINCS)
JAPAN INVENTORY OF EXISTING NO
AND NEW CHEMICAL
SUBSTANCES (ENCS)
KOREA EXISTING CHEMICALS NO
LIST (ECL)
NEW ZEALAND NEW ZEALAND INVENTORY YES
PHILIPPINES PHILIPPINE INVENTORY YES
OF CHEMICALS AND CHEMICAL
SUBSTANCES (PICCS)
TAIWAN TAIWAN CHEMICAL SUBSTANCE YES
INVENTORY (TCSI)
UNITED STATES TOXIC SUBSTANCES CONTROL YES
& PUERTO RICO ACT (TSCA) INVENTORY
*A "YES" INDICATES THAT ALL COMPONENTS OF THIS PRODUCT COMPLY WITH THE
INVENTORY REQUIREMENTS ADMINISTERED BY THE GOVERNING COUNTRY(S)
A "NO" INDICATES THAT ONE OR MORE COMPONENTS OF THE PRODUCT ARE NOT LISTED
OR EXEMPT FROM LISTING ON THE INVENTORY ADMINISTERED BY THE GOVERNING
COUNTRY(S).
| 16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION | |
OR LAST REVISION
ISSUE DATE: 05-29-2019
VERSION #: 01
HMIS(R*) RATINGS:
HEALTH 3
FLAMMABILITY 1
PHYSICAL HAZARD 0
NFPA RATINGS:
HEALTH 3
FLAMMABILITY 1
INSTABILITY 0
DISCLAIMER:
ITW PERFORMANCE POLYMERS CANNOT ANTICIPATE ALL CONDITIONS UNDER
WHICH THIS INFORMATION AND ITS PRODUCT, OR THE PRODUCTS OF OTHER
MANUFACTURERS IN COMBINATION WITH ITS PRODUCT, MAY BE USED. IT IS
THE USER'S RESPONSIBILITY TO ENSURE SAFE CONDITIONS FOR HANDLING,
STORAGE AND DISPOSAL OF THE PRODUCT, AND TO ASSUME LIABILITY FOR
LOSS, INJURY, DAMAGE OR EXPENSE DUE TO IMPROPER USE. THE INFORMATION
PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT TO THE BEST OF OUR
KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS PUBLICATION.
THE INFORMATION RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND
MAY NOT BE VALID FOR SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER
MATERIALS OR IN ANY PROCESS, UNLESS SPECIFIED IN THE TEXT. THE INFORMATION
GIVEN IS DESIGNED ONLY AS A GUIDANCE FOR SAFE HANDLING, USE, PROCESSING,
STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE.
MATERIAL NAME: DEVCON(R)* TITANIUM PUTTY HARDENER
SDS US