| Common Name: | 257395 CONSAV TUBE TURBOKRETE CONCRETE REPAIR, CONSAV TUBE TURBOKRETE CONCRETE R |
| Manufacturer: | RUST-OLEUM |
| SDS Revision Date: | 9/11/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 6DNX5 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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RUST-OLEUM CORPORATION
REVISION DATE: 9/11/2015
RUST-OLEUM MULTI COMPONENT PRODUCT INFORMATION SHEET
257395 CONSAV TUBE TURBOKRETE CONCRETE REPAIR IS A MULTI COMPONENT PRODUCT
COMPOSED OF THE FOLLOWING INDIVIDUAL CHEMICAL COMPONENTS:
257395A CONSAV TUBE TURBOKRETE CONCRETE REPAIR PART A
257395B CONSAV TUBE TURBOKRETE CONCRETE REPAIR PART B
SDSS FOR EACH COMPONENT FOLLOW THIS COVER SHEET.
TRANSPORTATION INFORMATION:
DOMESTIC INTERNATIONAL AIR (IATA) TDG (CANADA)
(USDOT) (IMDG)
UN NUMBER 1760 1760 1760 1760
PROPER CORROSIVE CORROSIVE CORROSIVE CORROSIVE
SHIPPING LIQUIDS, LIQUIDS, LIQUIDS, LIQUIDS,
NAME N.O.S. N.O.S. N.O.S. N.O.S.
(AMINOETHYL- (AMINOETHYL- (AMINOETHYL- (AMINOETHYL-
PIPERAZINE, PIPERAZINE, PIPERAZINE, PIPERAZINE,
4-NONYLPHENOL, 4-NONYLPHENOL, 4-NONYLPHENOL, 4-NONYLPHENOL,
BRANCHED) BRANCHED) BRANCHED) BRANCHED)
HAZARD 8 8 8 8
CLASS
PACKING III III III III
GROUP
LIMITED YES MARINE YES YES
QUANTITY POLLUTANT
FINISHED GOOD SCHEDULE B HARMONIZED TARIFF CODE: 3907.30.0000
DATE PRINTED: 9/11/2015
SAFETY DATA SHEET
RUST-OLEUM CORPORATION
TRUSTED QUALITY SINCE 1921
WWW.RUSTOLEUM.COM
| 1. IDENTIFICATION |  |
PRODUCT NAME: CONSAV TUBE TURBOKRETE CONCRETE REPAIR PART A
PRODUCT IDENTIFIER: 257395A
PRODUCT USE/CLASS: CONCRETE REPAIR/TURBOKRETE PART A
REVISION DATE: 9/10/2015
SUPERCEDES DATE: 9/8/2015
SUPPLIER:
RUST-OLEUM CORPORATION
11 HAWTHORN PARKWAY
VERNON HILLS, IL 60061
USA
MANUFACTURER:
RUST-OLEUM CORPORATION
11 HAWTHORN PARKWAY
VERNON HILLS, IL 60061
USA
PREPARER: REGULATORY DEPARTMENT
EMERGENCY TELEPHONE:
24 HOUR HOTLINE: 847-367-7700
| 2. HAZARD IDENTIFICATION | |
CLASSIFICATION:
SYMBOL(S) OF PRODUCT:
EXCLAMATION MARK
HEALTH HAZARD
SIGNAL WORD: WARNING
GHS HAZARD STATEMENTS:
SKIN IRRITATION, CATEGORY 2:
H315: CAUSES SKIN IRRITATION.
SKIN SENSITIZER, CATEGORY 1:
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
EYE IRRITATION, CATEGORY 2B:
H320: CAUSES EYE IRRITATION.
CARCINOGENICITY, CATEGORY 2:
H351:
SUSPECTED OF CAUSING CANCER. CLASSIFIED AS CATEGORY 2 BASED ON LIMITED
EVIDENCE ON HUMAN AND/OR ANIMAL STUDIES. MIXTURES WITH CONCENTRATIONS OF
SUSPECTED CARCINOGENS INGREDIENTS AT CONCENTRATION PRESENT BETWEEN 0.1% AND
1.0% LABELLING THE SDS WILL BE OPTIONAL DEPENDING ON AUTHORITIES. IF
CATEGORY 2 CARCINOGENIC PRESENT AT A CONCENTRATION OF 1% OR ABOVE LABELLING
THE SDS WILL BE EXPECTED ROUTES OF EXPOSURE ARE DEPENDANT ON INGREDIENT
FORM.
GHS LABEL PRECAUTIONARY STATEMENTS:
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
P261: AVOID BREATHING DUST, FUMES, GASES, MISTS, VAPORS, OR SPRAY.
P280:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
P281: USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED.
P302+P352:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
P308+P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
P333+P313:
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
P362: TAKE OFF CONTAMINATED CLOTHING.
GHS SDS PRECAUTIONARY STATEMENTS:
P363: WASH CONTAMINATED CLOTHING BEFORE REUSE.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
HAZARDOUS SUBSTANCES:
CHEMICAL NAME CAS-NO. WT.% GHS SYMBOLS GHS STATEMENTS
RANGE
BISPHENOL A EPOXY 25085-99-8 50-75 NO INFORMATION NO INFORMATION
RESIN
NONHAZARDOUS PROPRIETARY 10-25 GHS07-GHS08 H315-317-320-351
INGREDIENTS
TITANIUM DIOXIDE 13463-67-7 1.0-2.5 NO INFORMATION NO INFORMATION
| 4. FIRST-AID MEASURES | |
FIRST AID - EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES HOLDING
EYELIDS OPEN. GET MEDICAL ATTENTION. DO NOT ALLOW RUBBING OF EYES OR
KEEPING EYES CLOSED.
FIRST AID - SKIN CONTACT:
WASH SKIN WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. GET MEDICAL
ATTENTION IF IRRITATION DEVELOPS OR PERSISTS.
FIRST AID - INHALATION:
REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. GET IMMEDIATE MEDICAL ATTENTION. DO
NOT USE MOUTH-TO-MOUTH RESUSCITATION. IF YOU EXPERIENCE DIFFICULTY IN
BREATHING, LEAVE THE AREA TO OBTAIN FRESH AIR. IF CONTINUED DIFFICULTY IS
EXPERIENCED, GET MEDICAL ASSISTANCE IMMEDIATELY.
FIRST AID - INGESTION:
IF SWALLOWED, RINSE MOUTH WITH WATER. IF FEELING UNWELL, GET MEDICAL
ATTENTION. SWALLOWING LESS THAN AN OUNCE WILL NOT CAUSE SIGNIFICANT HARM.
FOR LARGER AMOUNTS, DO NOT INDUCE VOMITING, BUT GIVE ONE OR TWO GLASSES OF
WATER TO DRINK AND GET MEDICAL ATTENTION.
| 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
ALCOHOL FILM FORMING FOAM, CARBON DIOXIDE, DRY CHEMICAL, DRY SAND, WATER
FOG
UNUSUAL FIRE AND EXPLOSION HAZARDS:
KEEP CONTAINERS TIGHTLY CLOSED. FLASH POINT IS TESTED TO BE GREATER THAN
200 DEGREES F. NO UNUSUAL FIRE OR EXPLOSION HAZARDS NOTED.
SPECIAL FIREFIGHTING PROCEDURES:
WATER MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT BUILDUP OF STEAM.
IF WATER IS USED, FOG NOZZLES ARE PREFERRED.
| 6. ACCIDENTAL RELEASE MEASURES | |
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
IF SPILLED, CONTAIN SPILLED MATERIAL AND REMOVE WITH INERT ABSORBENT.
DISPOSE OF CONTAMINATED ABSORBENT, CONTAINER, AND UNUSED CONTENTS IN
ACCORDANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS. DO NOT INCINERATE
CLOSED CONTAINERS
| 7. HANDLING AND STORAGE | |
HANDLING:
WASH THOROUGHLY AFTER HANDLING. WASH HANDS BEFORE EATING. REMOVE
CONTAMINATED CLOTHING AND LAUNDER BEFORE REUSE. USE ONLY WITH ADEQUATE
VENTILATION. FOLLOW ALL MSDS/LABEL PRECAUTIONS EVEN AFTER CONTAINER IS
EMPTIED BECAUSE IT MAY RETAIN PRODUCT RESIDUES. AVOID BREATHING FUMES,
VAPORS, OR MIST. AVOID CONTACT WITH EYES, SKIN AND CLOTHING.
STORAGE:
STORE IN A DRY, WELL VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED WHEN
NOT IN USE.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CHEMICAL NAME CAS-NO. WEIGHT % LESS THAN
BISPHENOL A EPOXY RESIN 25085-99-8 75.0
NONHAZARDOUS INGREDIENTS PROPRIETARY 20.0
TITANIUM DIOXIDE 13463-67-7 1.0
CHEMICAL NAME ACGIH ACGIH OSHA OSHA PEL-
TLV-TWA TLV-STEL PEL-TWA CEILING
BISPHENOL A EPOXY RESIN N.E. N.E. N.E. N.E.
NONHAZARDOUS INGREDIENTS N.E. N.E. N.E. N.E.
TITANIUM DIOXIDE 10 MG/M3 N.E. 15 MG/M3 N.E.
PERSONAL PROTECTION:
ENGINEERING CONTROLS:
USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO CONTROL AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS.
PREVENT BUILD-UP OF VAPORS BY OPENING ALL DOORS AND WINDOWS TO ACHIEVE
CROSS-VENTILATION.
RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA 1910.134 AND ANSI Z88.2
REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A
RESPIRATOR'S USE.
SKIN PROTECTION:
USE GLOVES TO PREVENT PROLONGED SKIN CONTACT. NITRILE OR NEOPRENE GLOVES
MAY AFFORD ADEQUATE SKIN PROTECTION.
EYE PROTECTION:
USE SAFETY EYEWEAR DESIGNED TO PROTECT AGAINST SPLASH OF LIQUIDS.
OTHER PROTECTIVE EQUIPMENT:
REFER TO SAFETY SUPERVISOR OR INDUSTRIAL HYGIENIST FOR FURTHER GUIDANCE
REGARDING TYPES OF PERSONAL PROTECTIVE EQUIPMENT AND THEIR APPLICATIONS.
HYGIENIC PRACTICES:
WASH THOROUGHLY WITH SOAP AND WATER BEFORE EATING, DRINKING OR SMOKING.
REMOVE CONTAMINATED CLOTHING IMMEDIATELY AND LAUNDER BEFORE REUSE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: GEL/PASTE
PHYSICAL STATE: LIQUID
ODOR: MILD
ODOR THRESHOLD: N.E.
RELATIVE DENSITY: 1.360
PH: N.A.
FREEZE POINT, DEG. C: N.D.
VISCOSITY: N.D.
SOLUBILITY IN WATER: NONE
PARTITION COEFFICIENT, N-OCTANOL/WATER: N.D.
DECOMPOSITION TEMP., DEG. C: N.D.
BOILING RANGE, DEG. C: -18 - 320
EXPLOSIVE LIMITS, VOL%: 1.3 - 13.0
FLAMMABILITY: DOES NOT SUPPORT COMBUSTION
FLASH POINT, DEG. C: 149
EVAPORATION RATE: SLOWER THAN ETHER
AUTO-IGNITION TEMP., DEG. C: N.D.
VAPOR DENSITY: HEAVIER THAN AIR
VAPOR PRESSURE: N.D.
(SEE "OTHER INFORMATION" SECTION FOR ABBREVIATION LEGEND)
| 10. STABILITY AND REACTIVITY | |
CONDITIONS TO AVOID: AVOID CONTACT WITH STRONG ACID AND STRONG BASES.
INCOMPATIBILITY:
INCOMPATIBLE WITH STRONG OXIDIZING AGENTS, STRONG ACIDS AND STRONG
ALKALIES.
HAZARDOUS DECOMPOSITION:
WHEN HEATED TO DECOMPOSITION, IT EMITS ACRID SMOKE AND IRRITATING FUMES.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR UNDER NORMAL CONDITIONS.
STABILITY: THIS PRODUCT IS STABLE UNDER NORMAL STORAGE CONDITIONS.
| 11. TOXICOLOGICAL INFORMATION | |
EFFECTS OF OVEREXPOSURE - EYE CONTACT:
IRRITATING, AND MAY INJURE EYE TISSUE IF NOT REMOVED PROMPTLY.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT:
LOW HAZARD FOR USUAL INDUSTRIAL HANDLING OR COMMERCIAL HANDLING BY TRAINED
PERSONNEL.
EFFECTS OF OVEREXPOSURE - INHALATION:
HIGH GAS, VAPOR, MIST OR DUST CONCENTRATIONS MAY BE HARMFUL IF INHALED.
AVOID BREATHING FUMES, SPRAY, VAPORS, OR MIST.
EFFECTS OF OVEREXPOSURE - INGESTION: SUBSTANCE MAY BE HARMFUL IF SWALLOWED.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS:
CONTAINS TITANIUM DIOXIDE. TITANIUM DIOXIDE IS LISTED AS A GROUP 2B-
"POSSIBLY CARCINOGENIC TO HUMANS" BY IARC. NO SIGNIFICANT EXPOSURE TO
TITANIUM DIOXIDE IS THOUGHT TO OCCUR DURING THE USE OF PRODUCTS IN WHICH
TITANIUM DIOXIDE IS BOUND TO OTHER MATERIALS, SUCH AS IN PAINTS DURING
BRUSH APPLICATION OR DRYING. RISK OF OVEREXPOSURE DEPENDS ON DURATION AND
LEVEL OF EXPOSURE TO DUST FROM REPEATED SANDING OF SURFACES OR SPRAY MIST
AND THE ACTUAL CONCENTRATION OF TITANIUM DIOXIDE IN THE FORMULA. (REF: IARC
MONOGRAPH, VOL. 93, 2010)
PRIMARY ROUTE(S) OF ENTRY:
EYE CONTACT, INGESTION, INHALATION, SKIN ABSORPTION, SKIN CONTACT
ACUTE TOXICITY VALUES:
THE ACUTE EFFECTS OF THIS PRODUCT HAVE NOT BEEN TESTED. DATA ON INDIVIDUAL
COMPONENTS ARE TABULATED BELOW:
CAS-NO. CHEMICAL NAME ORAL LD50 DERMAL LD50 VAPOR LC50
13463-67-7 TITANIUM DIOXIDE >10000 MG/KG RAT N.I. N.I.
N.I. - NO INFORMATION
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: PRODUCT IS A MIXTURE OF LISTED COMPONENTS.
| 13. DISPOSAL INFORMATION | |
DISPOSAL INFORMATION:
DISPOSE OF MATERIAL IN ACCORDANCE TO LOCAL, STATE, AND FEDERAL REGULATIONS
AND ORDINANCES. DO NOT ALLOW TO ENTER WATERWAYS, WASTEWATER, SOIL, STORM
DRAINS OR SEWER SYSTEMS.
| 14. TRANSPORT INFORMATION | |
DOMESTIC INTERNATIONAL AIR (IATA) TDG (CANADA)
(USDOT) (IMDG)
UN NUMBER N.A. N.A. N.A. N.A.
PROPER SHIPPING NOT NOT NOT NOT
NAME REGULATED REGULATED REGULATED REGULATED
HAZARD CLASS N.A. N.A. N.A. N.A.
PACKING GROUP N.A. N.A. N.A. N.A.
LIMITED QUANTITY NO NO NO NO
| 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
CERCLA - SARA HAZARD CATEGORY:
THIS PRODUCT HAS BEEN REVIEWED ACCORDING TO THE EPA 'HAZARD CATEGORIES'
PROMULGATED UNDER SECTIONS 311 AND 312 OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 (SARA TITLE III) AND IS CONSIDERED, UNDER
APPLICABLE DEFINITIONS, TO MEET THE FOLLOWING CATEGORIES:
ACUTE HEALTH HAZARD, CHRONIC HEALTH HAZARD
SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372:
NO SARA 313 COMPONENTS EXIST IN THIS PRODUCT.
TOXIC SUBSTANCES CONTROL ACT:
THIS PRODUCT CONTAINS THE FOLLOWING CHEMICAL SUBSTANCES SUBJECT TO THE
REPORTING REQUIREMENTS OF TSCA 12(B) IF EXPORTED FROM THE UNITED STATES:
NO TSCA 12(B) COMPONENTS EXIST IN THIS PRODUCT.
| 16. OTHER INFORMATION | |
HMIS RATINGS:
HEALTH 1
FLAMMABILITY 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION B
NFPA RATINGS:
HEALTH 1
FLAMMABILITY 1
INSTABILITY 0
VOLATILE ORGANIC COMPOUNDS, G/L: 0
SDS REVISION DATE: 9/10/2015
REASON FOR REVISION:
REGULATORY FORMULA SOURCE CHANGED
PRODUCT COMPOSITION CHANGED
SUBSTANCE AND/OR PRODUCT PROPERTIES CHANGED IN SECTION(S):
01 - IDENTIFICATION
02 - HAZARD IDENTIFICATION
09 - PHYSICAL & CHEMICAL PROPERTIES
16 - OTHER INFORMATION
STATEMENT(S) CHANGED
LEGEND:
N.A. - NOT APPLICABLE
N.E. - NOT ESTABLISHED
N.D. - NOT DETERMINED
RUST-OLEUM CORPORATION BELIEVES, TO THE BEST OF ITS KNOWLEDGE, INFORMATION
AND BELIEF, THE INFORMATION CONTAINED HEREIN TO BE ACCURATE AND RELIABLE AS
OF THE DATE OF THIS SAFETY DATA SHEET. HOWEVER, BECAUSE THE CONDITIONS OF
HANDLING, USE, AND STORAGE OF THESE MATERIALS ARE BEYOND OUR CONTROL, WE
ASSUME NO RESPONSIBILITY OR LIABILITY FOR PERSONAL INJURY OR PROPERTY
DAMAGE INCURRED BY THE USE OF THESE MATERIALS. RUST-OLEUM CORPORATION MAKES
NO WARRANTY, EXPRESSED OR IMPLIED, REGARDING THE ACCURACY OR RELIABILITY OF
THE DATA OR RESULTS OBTAINED FROM THEIR USE. ALL MATERIALS MAY PRESENT
UNKNOWN HAZARDS AND SHOULD BE USED WITH CAUTION. THE INFORMATION AND
RECOMMENDATIONS IN THIS MATERIAL SAFETY DATA SHEET ARE OFFERED FOR THE
USERS' CONSIDERATION AND EXAMINATION. IT IS THE RESPONSIBILITY OF THE USER
TO DETERMINE THE FINAL SUITABILITY OF THIS INFORMATION AND TO COMPLY WITH
ALL APPLICABLE INTERNATIONAL, FEDERAL, STATE, AND LOCAL LAWS AND
REGULATIONS.
DATE PRINTED: 9/11/2015
SAFETY DATA SHEET
RUST-OLEUM CORPORATION
TRUSTED QUALITY SINCE 1921
WWW.RUSTOLEUM.COM
| 1. IDENTIFICATION | |
PRODUCT NAME: CONSAV TUBE TURBOKRETE CONCRETE REPAIR PART B
PRODUCT IDENTIFIER: 257395B
PRODUCT USE/CLASS: CONCRETE REPAIR/TURBOKRETE PART B
REVISION DATE: 9/10/2015
SUPERCEDES DATE: 9/8/2015
SUPPLIER:
RUST-OLEUM CORPORATION
11 HAWTHORN PARKWAY
VERNON HILLS, IL 60061
USA
MANUFACTURER:
RUST-OLEUM CORPORATION
11 HAWTHORN PARKWAY
VERNON HILLS, IL 60061
USA
PREPARER: REGULATORY DEPARTMENT
EMERGENCY TELEPHONE:
24 HOUR HOTLINE: 847-367-7700
| 2. HAZARD IDENTIFICATION | |
CLASSIFICATION:
SYMBOL(S) OF PRODUCT:
CORROSION
EXCLAMATION MARK
HEALTH HAZARD
SIGNAL WORD: DANGER
POSSIBLE HAZARDS:
32% OF THE MIXTURE CONSISTS OF INGREDIENT(S) OF UNKNOWN ACUTE TOXICITY.
GHS HAZARD STATEMENTS:
ACUTE TOXICITY, ORAL, CATEGORY 4:
H302: HARMFUL IF SWALLOWED.
ACUTE TOXICITY, DERMAL, CATEGORY 4:
H312: HARMFUL IN CONTACT WITH SKIN.
SKIN CORROSION, CATEGORY 1:
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
SKIN SENSITIZER, CATEGORY 1:
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
ACUTE TOXICITY, INHALATION, CATEGORY 4:
H332: HARMFUL IF INHALED.
CARCINOGENICITY, CATEGORY 1A:
H350:
MAY CAUSE CANCER. CLASSIFIED AS CARCINOGENIC CATEGORY 1 ON THE BASIS OF
EPIDEMIOLOGICAL AND/OR ANIMAL DATA. MIXTURES ARE CLASSIFIED AS CARCINOGENIC
WHEN AT LEAST 1 INGREDIENT HAS BEEN CLASSIFIED AS CARCINOGENIC AND IS
PRESENT AT 0.1% OR ABOVE ROUTES OF EXPOSURE ARE DEPENDENT ON INGREDIENT
FORM.
REPRODUCTIVE TOXICITY, CATEGORY 2:
H361:
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD. CLASSIFIED CATEGORY 2
SUSPECTED HUMAN REPRODUCTIVE TOXICANT IRREVERSIBLE EFFECTS SUCH AS
STRUCTURAL MALFUNCTIONS, EMBRYO/FOETAL LETHALITY, POST NATAL FUNCTIONAL
DEFICIENCIES.
GHS LABEL PRECAUTIONARY STATEMENTS:
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
P260: DO NOT BREATHE DUST, FUMES, GASES, MISTS, VAPORS, OR SPRAY.
P280:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
P301+P330+P331:
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING.
P302+P352:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
P303+P361+P353:
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
P308+P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
P310: IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
P333+P313:
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
GHS SDS PRECAUTIONARY STATEMENTS:
P270: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
P363: WASH CONTAMINATED CLOTHING BEFORE REUSE.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
HAZARDOUS SUBSTANCES:
CHEMICAL NAME CAS-NO. WT.% GHS SYMBOLS GHS STATEMENTS
RANGE
NONHAZARDOUS PROPRIETARY 25-50 GHS05-GHS08 H314-350-361
INGREDIENTS
4-NONYLPHENOL, 84852-15-3 25-50 GHS05-GHS07 H302-314
BRANCHED
1-(2-AMINOETHYL) 140-31-8 10-25 GHS05-GHS06 H311-314-317
PIPERAZINE
TRIS-2,4,6- 90-72-2 2.5-10 GHS07 H302-312-315-319
(DIMETHYLAMINO-
METHYL)PHENOL
BENZYL ALCOHOL 100-51-6 2.5-10 GHS06 H302-312-331
TRIETHYLENETE- 112-24-3 2.5-10 GHS05-GHS06 H311-314-317
TRAMINE
ETHYLENE GLYCOL 107-21-1 2.5-10 NO INFORMATION NO INFORMATION
CRYSTALLINE 14808-60-7 1.0-2.5 GHS07 H302
SILICA / QUARTZ
| 4. FIRST-AID MEASURES | |
FIRST AID - EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES
HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION. DO NOT ALLOW RUBBING OF
EYES OR KEEPING EYES CLOSED.
FIRST AID - SKIN CONTACT:
WASH SKIN WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. GET MEDICAL
ATTENTION IF IRRITATION DEVELOPS OR PERSISTS. IMMEDIATELY FLUSH SKIN WITH
PLENTY OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CLOTHING. GET
MEDICAL ATTENTION IMMEDIATELY. WASH CLOTHING SEPARATELY BEFORE REUSE.
DESTROY CONTAMINATED SHOES.
FIRST AID - INHALATION:
REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. GET IMMEDIATE MEDICAL ATTENTION. DO
NOT USE MOUTH-TO-MOUTH RESUSCITATION. IF YOU EXPERIENCE DIFFICULTY IN
BREATHING, LEAVE THE AREA TO OBTAIN FRESH AIR. IF CONTINUED DIFFICULTY IS
EXPERIENCED, GET MEDICAL ASSISTANCE IMMEDIATELY.
FIRST AID - INGESTION:
IF SWALLOWED, DO NOT INDUCE VOMITING. IF VICTIM IS CONSCIOUS AND ALERT,
GIVE 2 TO 4 CUPFULS OF WATER OR MILK. CALL A PHYSICIAN OR POISON CONTROL
CENTER IMMEDIATELY. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
TREAT SYMPTOMATICALLY AND SUPPORTIVELY. DO NOT INDUCE VOMITING UNLESS
ADVISED BY A PHYSICIAN. CALL NEAREST POISON CONTROL CENTER OR PHYSICIAN
IMMEDIATELY.
| 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
ALCOHOL FILM FORMING FOAM, CARBON DIOXIDE, DRY CHEMICAL, DRY SAND, WATER
FOG
UNUSUAL FIRE AND EXPLOSION HAZARDS:
KEEP CONTAINERS TIGHTLY CLOSED. NO UNUSUAL FIRE OR EXPLOSION HAZARDS NOTED.
SPECIAL FIREFIGHTING PROCEDURES:
CONTAINERS CAN RUPTURE AND RELEASE HIGHLY TOXIC MATERIAL IF EXPOSED TO
HEAT. SUBSTANCE IS NON-COMBUSTIBLE BUT REACTS WITH MANY METALS TO FORM
EXPLOSIVE HYDROGEN GAS. USE WATER SPRAY TO KEEP FIRE-EXPOSED CONTAINERS
COOL. CONTAINERS MAY EXPLODE WHEN HEATED.
| 6. ACCIDENTAL RELEASE MEASURES | |
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
AVOID RUNOFF INTO SEWERS AND WATERWAYS. PROVIDE VENTILATION AND APPROACH
SPILL FROM UPWIND USING PROPER PERSONAL PROTECTIVE EQUIPMENT AS INDICATED
IN SECTION 8. CAREFULLY NEUTRALIZE SPILL WITH SODIUM BICARBONATE (NaHCO3).
CONTAIN SPILLED LIQUID WITH SAND OR EARTH. DO NOT USE COMBUSTIBLE MATERIALS
SUCH AS SAWDUST. DISPOSE OF ACCORDING TO LOCAL, STATE (PROVINCIAL) AND
FEDERAL REGULATIONS. DO NOT INCINERATE CLOSED CONTAINERS.
| 7. HANDLING AND STORAGE | |
HANDLING:
WASH THOROUGHLY AFTER HANDLING. WASH HANDS BEFORE EATING. REMOVE
CONTAMINATED CLOTHING AND LAUNDER BEFORE REUSE. USE ONLY WITH ADEQUATE
VENTILATION. FOLLOW ALL MSDS/LABEL PRECAUTIONS EVEN AFTER CONTAINER IS
EMPTIED BECAUSE IT MAY RETAIN PRODUCT RESIDUES. AVOID BREATHING FUMES,
VAPORS, OR MIST. AVOID CONTACT WITH EYES, SKIN AND CLOTHING.
STORAGE:
STORE IN A DRY, WELL VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED WHEN
NOT IN USE.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CHEMICAL NAME CAS-NO. WEIGHT % LESS THAN
NONHAZARDOUS INGREDIENTS PROPRIETARY 35.0
4-NONYLPHENOL, BRANCHED 84852-15-3 30.0
1-(2-AMINOETHYL)PIPERAZINE 140-31-8 15.0
TRIS-2,4,6-(DIMETHYLAMINOMETHYL)PHENOL 90-72-2 10.0
ETHYLENE GLYCOL 107-21-1 5.0
TRIETHYLENETETRAMINE 112-24-3 5.0
BENZYL ALCOHOL 100-51-6 5.0
CRYSTALLINE SILICA / QUARTZ 14808-60-7 5.0
CHEMICAL NAME ACGIH ACGIH OSHA OSHA PEL-
TLV-TWA TLV-STEL PEL-TWA CEILING
NONHAZARDOUS INGREDIENTS N.E. N.E. N.E. N.E.
4-NONYLPHENOL, BRANCHED N.E. N.E. N.E. N.E.
1-(2-AMINOETHYL)PIPERAZINE N.E. N.E. N.E. N.E.
TRIS-2,4,6-(DIMETHYLAMINO- N.E. N.E. N.E. N.E.
METHYL)PHENOL
ETHYLENE GLYCOL N.E. N.E. N.E. N.E.
TRIETHYLENETETRAMINE N.E. N.E. N.E. N.E.
BENZYL ALCOHOL N.E. N.E. N.E. N.E.
CRYSTALLINE SILICA / 0.025 MG/M3 N.E. N.E. N.E.
QUARTZ
PERSONAL PROTECTION:
ENGINEERING CONTROLS:
USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO CONTROL AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS.
PROVIDE GENERAL DILUTION OF LOCAL EXHAUST VENTILATION IN VOLUME AND PATTERN
TO KEEP TLV OF HAZARDOUS INGREDIENTS BELOW ACCEPTABLE LIMITS. PREVENT
BUILD-UP OF VAPORS BY OPENING ALL DOORS AND WINDOWS TO ACHIEVE
CROSS-VENTILATION.
RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA 1910.134 AND ANSI Z88.2
REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A
RESPIRATOR'S USE.
SKIN PROTECTION:
USE GLOVES TO PREVENT PROLONGED SKIN CONTACT. USE IMPERVIOUS GLOVES TO
PREVENT SKIN CONTACT AND ABSORPTION OF THIS MATERIAL THROUGH THE SKIN.
NITRILE OR NEOPRENE GLOVES MAY AFFORD ADEQUATE SKIN PROTECTION.
EYE PROTECTION:
USE SAFETY EYEWEAR DESIGNED TO PROTECT AGAINST SPLASH OF LIQUIDS.
OTHER PROTECTIVE EQUIPMENT:
REFER TO SAFETY SUPERVISOR OR INDUSTRIAL HYGIENIST FOR FURTHER GUIDANCE
REGARDING TYPES OF PERSONAL PROTECTIVE EQUIPMENT AND THEIR APPLICATIONS.
HYGIENIC PRACTICES:
WASH THOROUGHLY WITH SOAP AND WATER BEFORE EATING, DRINKING OR SMOKING.
REMOVE CONTAMINATED CLOTHING IMMEDIATELY AND LAUNDER BEFORE REUSE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: GEL/PASTE
PHYSICAL STATE: LIQUID
ODOR: MILD
ODOR THRESHOLD: N.E.
RELATIVE DENSITY: 1.350
PH: N.A.
FREEZE POINT, DEG. C: N.D.
VISCOSITY: N.D.
SOLUBILITY IN WATER: NONE
PARTITION COEFFICIENT, N-OCTANOL/WATER: N.D.
DECOMPOSITION TEMP., DEG. C: N.D.
BOILING RANGE, DEG. C: -18 - 2,230
EXPLOSIVE LIMITS, VOL%: 1.1 - 13.0
FLAMMABILITY: DOES NOT SUPPORT COMBUSTION
FLASH POINT, DEG. C: 94
EVAPORATION RATE: SLOWER THAN ETHER
AUTO-IGNITION TEMP., DEG. C: N.D.
VAPOR DENSITY: HEAVIER THAN AIR
VAPOR PRESSURE: N.D.
(SEE "OTHER INFORMATION" SECTION FOR ABBREVIATION LEGEND)
| 10. STABILITY AND REACTIVITY | |
CONDITIONS TO AVOID:
AVOID CONTACT WITH STRONG ACID AND STRONG BASES. AVOID CONTACT WITH METALS.
INCOMPATIBILITY:
INCOMPATIBLE WITH STRONG OXIDIZING AGENTS, STRONG ACIDS AND STRONG
ALKALIES. PRODUCT SLOWLY CORRODES COPPER, ALUMINUM, ZINC, AND GALVANIZED
SURFACES.
HAZARDOUS DECOMPOSITION:
DECOMPOSITION PRODUCES HYDROGEN CHLORIDE, CHLORINE AND HYDROGEN GASES.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR UNDER NORMAL CONDITIONS.
STABILITY: THIS PRODUCT IS STABLE UNDER NORMAL STORAGE CONDITIONS.
| 11. TOXICOLOGICAL INFORMATION | |
EFFECTS OF OVEREXPOSURE - EYE CONTACT:
SUBSTANCE CAUSES SEVERE EYE IRRITATION. INJURY MAY BE PERMANENT.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT:
SEVERELY IRRITATING; MAY CAUSE PERMANENT SKIN DAMAGE.
EFFECTS OF OVEREXPOSURE - INHALATION:
HARMFUL IF INHALED. HIGH GAS, VAPOR, MIST OR DUST CONCENTRATIONS MAY BE
HARMFUL IF INHALED. AVOID BREATHING FUMES, SPRAY, VAPORS, OR MIST. HIGH
VAPOR CONCENTRATIONS ARE IRRITATING TO THE EYES, NOSE, THROAT AND LUNGS.
EFFECTS OF OVEREXPOSURE - INGESTION:
CORROSIVE AND MAY CAUSE SEVERE AND PERMANENT DAMAGE TO MOUTH, THROAT AND
STOMACH. SUBSTANCE MAY BE HARMFUL IF SWALLOWED.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS:
REPEATED EXPOSURE TO LOW CONCENTRATIONS OF HCl VAPOR OR MIST MAY CAUSE
BLEEDING OF NOSE AND GUMS.
PRIMARY ROUTE(S) OF ENTRY:
EYE CONTACT, INGESTION, INHALATION, SKIN ABSORPTION, SKIN CONTACT
ACUTE TOXICITY VALUES:
THE ACUTE EFFECTS OF THIS PRODUCT HAVE NOT BEEN TESTED. DATA ON INDIVIDUAL
COMPONENTS ARE TABULATED BELOW:
CAS-NO. CHEMICAL NAME ORAL LD50 DERMAL LD50 VAPOR LC50
PROPRIETARY NONHAZARDOUS N.I. N.I. 21
INGREDIENTS
84852-15-3 4-NONYLPHENOL, 580 MG/KG 2031 MG/KG N.I.
BRANCHED RAT RABBIT
140-31-8 1-(2-AMINOETHYL) 2140 MG/KG 866 MG/KG N.I.
PIPERAZINE RAT RABBIT
90-72-2 TRIS-2,4,6- 1000 MG/KG 1280 MG/KG N.I.
(DIMETHYLAMINO- RAT RAT
METHYL)PHENOL
100-51-6 BENZYL ALCOHOL 1230 MG/KG 2000 MG/KG 8.8 MG/L RAT
RAT RABBIT
112-24-3 TRIETHYLENETE- 2500 MG/KG 550 MG/KG N.I.
TRAMINE RAT RABBIT
107-21-1 ETHYLENE GLYCOL 4000 MG/KG N.I. N.I.
RAT
14808-60-7 CRYSTALLINE 500 MG/KG N.I. N.I.
SILICA / QUARTZ RAT
N.I. - NO INFORMATION
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: PRODUCT IS A MIXTURE OF LISTED COMPONENTS.
| 13. DISPOSAL INFORMATION | |
DISPOSAL INFORMATION:
DISPOSE OF MATERIAL IN ACCORDANCE TO LOCAL, STATE, AND FEDERAL REGULATIONS
AND ORDINANCES. DO NOT ALLOW TO ENTER WATERWAYS, WASTEWATER, SOIL, STORM
DRAINS OR SEWER SYSTEMS.
| 14. TRANSPORT INFORMATION | |
DOMESTIC INTERNATIONAL AIR (IATA) TDG (CANADA)
(USDOT) (IMDG)
UN NUMBER N.A. 1759 1759 N.A.
PROPER NOT CORROSIVE CORROSIVE NOT REGULATED
SHIPPING REGULATED SOLIDS, NOS SOLIDS, NOS
NAME (AMINOETHYL- (AMINOETHYL-
PIPERAZINE, PIPERAZINE,
NONYLPHENOL) NONYLPHENOL)
HAZARD CLASS N.A. N.A. N.A. N.A.
PACKING GROUP N.A. III III N.A.
LIMITED YES NO NO YES
QUANTITY
| 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
CERCLA - SARA HAZARD CATEGORY:
THIS PRODUCT HAS BEEN REVIEWED ACCORDING TO THE EPA 'HAZARD CATEGORIES'
PROMULGATED UNDER SECTIONS 311 AND 312 OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 (SARA TITLE III) AND IS CONSIDERED, UNDER
APPLICABLE DEFINITIONS, TO MEET THE FOLLOWING CATEGORIES:
CHRONIC HEALTH HAZARD
SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372:
CHEMICAL NAME CAS-NO.
ETHYLENE GLYCOL 107-21-1
TOXIC SUBSTANCES CONTROL ACT:
THIS PRODUCT CONTAINS THE FOLLOWING CHEMICAL SUBSTANCES SUBJECT TO THE
REPORTING REQUIREMENTS OF TSCA 12(B) IF EXPORTED FROM THE UNITED STATES:
NO TSCA 12(B) COMPONENTS EXIST IN THIS PRODUCT.
| 16. OTHER INFORMATION | |
HMIS RATINGS:
HEALTH 2*
FLAMMABILITY 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA RATINGS:
HEALTH 2
FLAMMABILITY 1
INSTABILITY 0
VOLATILE ORGANIC COMPOUNDS, G/L: 107
SDS REVISION DATE: 9/10/2015
REASON FOR REVISION:
REGULATORY FORMULA SOURCE CHANGED
PRODUCT COMPOSITION CHANGED
SUBSTANCE AND/OR PRODUCT PROPERTIES CHANGED IN SECTION(S):
02 - HAZARD IDENTIFICATION
05 - FIRE-FIGHTING MEASURES
09 - PHYSICAL & CHEMICAL PROPERTIES
16 - OTHER INFORMATION
STATEMENT(S) CHANGED
LEGEND:
N.A. - NOT APPLICABLE
N.E. - NOT ESTABLISHED
N.D. - NOT DETERMINED
RUST-OLEUM CORPORATION BELIEVES, TO THE BEST OF ITS KNOWLEDGE, INFORMATION
AND BELIEF, THE INFORMATION CONTAINED HEREIN TO BE ACCURATE AND RELIABLE AS
OF THE DATE OF THIS SAFETY DATA SHEET. HOWEVER, BECAUSE THE CONDITIONS OF
HANDLING, USE, AND STORAGE OF THESE MATERIALS ARE BEYOND OUR CONTROL, WE
ASSUME NO RESPONSIBILITY OR LIABILITY FOR PERSONAL INJURY OR PROPERTY
DAMAGE INCURRED BY THE USE OF THESE MATERIALS. RUST-OLEUM CORPORATION MAKES
NO WARRANTY, EXPRESSED OR IMPLIED, REGARDING THE ACCURACY OR RELIABILITY OF
THE DATA OR RESULTS OBTAINED FROM THEIR USE. ALL MATERIALS MAY PRESENT
UNKNOWN HAZARDS AND SHOULD BE USED WITH CAUTION. THE INFORMATION AND
RECOMMENDATIONS IN THIS MATERIAL SAFETY DATA SHEET ARE OFFERED FOR THE
USERS' CONSIDERATION AND EXAMINATION. IT IS THE RESPONSIBILITY OF THE USER
TO DETERMINE THE FINAL SUITABILITY OF THIS INFORMATION AND TO COMPLY WITH
ALL APPLICABLE INTERNATIONAL, FEDERAL, STATE, AND LOCAL LAWS AND
REGULATIONS.