| Common Name: | CHLORINATED RUBBER SWIMMING POOL PAINT ROYAL BLUE |
| Manufacturer: | BENJAMIN MOORE |
| SDS Revision Date: | 5/30/2018 |
| SDS Format: | GHS-US |
| Item Number(s): | 6GWA7 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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INSL-X(R*)
SAFETY DATA SHEET
REVISION DATE: 30-MAY-2018
REVISION NUMBER: 3
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: CHLORINATED RUBBER SWIMMING POOL PAINT ROYAL BLUE
PRODUCT CODE: CR-2624
ALTERNATE PRODUCT CODE: TR1724
PRODUCT CLASS: SOLVENT THINNED PAINT
COLOR: DARK BLUE
RECOMMENDED USE: PAINT
RESTRICTIONS ON USE: NO INFORMATION AVAILABLE
MANUFACTURER:
BENJAMIN MOORE & CO.
101 PARAGON DRIVE
MONTVALE, NJ 07645
PHONE: 1-866-708-9180
INSL-X.COM
EMERGENCY TELEPHONE:
CHEMTREC (US): 800-424-9300
CHEMTREC (OUTSIDE US): (703)-527-3887
| 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION
THIS CHEMICAL IS CONSIDERED HAZARDOUS BY THE 2012 OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200)
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2
SKIN SENSITIZATION: CATEGORY 1
CARCINOGENICITY: CATEGORY 1A
REPRODUCTIVE TOXICITY: CATEGORY 1B
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): CATEGORY 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 2
ASPIRATION TOXICITY: CATEGORY 1
FLAMMABLE LIQUIDS: CATEGORY 2
LABEL ELEMENTS:
DANGER:
HAZARD STATEMENTS:
CAUSES SKIN IRRITATION
CAUSES SERIOUS EYE IRRITATION
MAY CAUSE AN ALLERGIC SKIN REACTION
MAY CAUSE CANCER
MAY DAMAGE FERTILITY OR THE UNBORN CHILD
MAY CAUSE RESPIRATORY IRRITATION
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE
MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS
HIGHLY FLAMMABLE LIQUID AND VAPOR
EXCLAMATION MARK
HEALTH HAZARD
FLAME
APPEARANCE: LIQUID
ODOR: LITTLE OR NO ODOR
PRECAUTIONARY STATEMENTS - PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD
USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED
WASH FACE, HANDS AND ANY EXPOSED SKIN THOROUGHLY AFTER HANDLING
CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA
KEEP AWAY FROM HEAT, HOT SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION
SOURCES. NO SMOKING
KEEP CONTAINER TIGHTLY CLOSED
GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT
USE EXPLOSION-PROOF ELECTRICAL/VENTILATING/LIGHTING/EQUIPMENT
USE ONLY NON-SPARKING TOOLS
TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE KEEP COOL
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION
PRECAUTIONARY STATEMENTS - RESPONSE:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION
EYES:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION
SKIN:
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION
IF ON SKIN (OR HAIR):
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER
WASH CONTAMINATED CLOTHING BEFORE REUSE
INHALATION:
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING
INGESTION:
IF SWALLOWED: IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN
DO NOT INDUCE VOMITING
FIRE:
IN CASE OF FIRE: USE CO2, DRY CHEMICAL, OR FOAM FOR EXTINCTION
PRECAUTIONARY STATEMENTS - STORAGE:
STORE LOCKED UP
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED
PRECAUTIONARY STATEMENTS - DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC): NOT APPLICABLE
OTHER INFORMATION: NO INFORMATION AVAILABLE
| 3. COMPOSITION INFORMATION ON COMPONENTS | |
CHEMICAL NAME CAS NO. WEIGHT-%
XYLENE 1330-20-7 30
TALC 14807-96-6 20
VM&P NAPHTHA 64742-89-8 10
ETHYL BENZENE 100-41-4 10
CHLORINATED PARAFFIN 63449-39-8 10
TITANIUM DIOXIDE 13463-67-7 5
DIBUTYL PHTHALATE 84-74-2 5
TOLUENE 108-88-3 1
OCTANE 111-65-9 0.5
HEPTANE 142-82-5 0.5
4,4-ISOPROPYLIDENEDIPHENOL-EPICHLOROHYDRIN 25068-38-6 0.5
COPOLYMER
SILICA, CRYSTALLINE 14808-60-7 0.5
| 4. FIRST AID MEASURES | |
DESCRIPTION OF FIRST AID MEASURES:
GENERAL ADVICE:
IF SYMPTOMS PERSIST, CALL A PHYSICIAN. SHOW THIS SAFETY DATA SHEET TO THE
DOCTOR IN ATTENDANCE.
EYE CONTACT:
IMMEDIATELY FLUSH WITH PLENTY OF WATER. AFTER INITIAL FLUSHING, REMOVE ANY
CONTACT LENSES AND CONTINUE FLUSHING FOR AT LEAST 15 MINUTES. IF EYE
IRRITATION PERSISTS, CONSULT A SPECIALIST.
SKIN CONTACT:
WASH OFF IMMEDIATELY WITH SOAP AND PLENTY OF WATER WHILE REMOVING ALL
CONTAMINATED CLOTHES AND SHOES. IF SKIN IRRITATION PERSISTS, CALL A
PHYSICIAN. WASH CLOTHING BEFORE REUSE. DESTROY CONTAMINATED ARTICLES SUCH
AS SHOES.
INHALATION:
MOVE TO FRESH AIR. IF SYMPTOMS PERSIST, CALL A PHYSICIAN.
IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. CALL A PHYSICIAN
IMMEDIATELY.
INGESTION:
CLEAN MOUTH WITH WATER AND AFTERWARDS DRINK PLENTY OF WATER. DO NOT INDUCE
VOMITING WITHOUT MEDICAL ADVICE. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON. CONSULT A PHYSICIAN.
PROTECTION OF FIRST-AIDERS: USE PERSONAL PROTECTIVE EQUIPMENT.
MOST IMPORTANT SYMPTOMS/EFFECTS: MAY CAUSE ALLERGIC SKIN REACTION.
NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY.
| 5. FIRE-FIGHTING MEASURES | |
FLAMMABLE PROPERTIES:
VAPORS MAY TRAVEL CONSIDERABLE DISTANCE TO A SOURCE OF IGNITION AND FLASH
BACK. VAPORS MAY CAUSE FLASH FIRE.
SUITABLE EXTINGUISHING MEDIA:
FOAM, DRY POWDER OR WATER. USE EXTINGUISHING MEASURES THAT ARE APPROPRIATE
TO LOCAL CIRCUMSTANCES AND THE SURROUNDING ENVIRONMENT.
PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND,
MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR.
HAZARDOUS COMBUSTION PRODUCTS:
BURNING MAY RESULT IN CARBON DIOXIDE, CARBON MONOXIDE AND OTHER COMBUSTION
PRODUCTS OF VARYING COMPOSITION WHICH MAY BE TOXIC AND/OR IRRITATING.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
FLAMMABLE. FLASH BACK POSSIBLE OVER CONSIDERABLE DISTANCE. KEEP PRODUCT AND
EMPTY CONTAINER AWAY FROM HEAT AND SOURCES OF IGNITION. CLOSED CONTAINERS
MAY RUPTURE IF EXPOSED TO FIRE OR EXTREME HEAT. THERMAL DECOMPOSITION CAN
LEAD TO RELEASE OF IRRITATING GASES AND VAPORS.
SENSITIVITY TO MECHANICAL IMPACT: NO
SENSITIVITY TO STATIC DISCHARGE: YES
FLASH POINT DATA:
FLASH POINT (DEG. F): 60.0
FLASH POINT (DEG. C): 15.6
METHOD: PMCC
FLAMMABILITY LIMITS IN AIR:
LOWER FLAMMABILITY LIMIT: NOT AVAILABLE
UPPER FLAMMABILITY LIMIT: NOT AVAILABLE
NFPA:
HEALTH 2
FLAMMABILITY 3
INSTABILITY 0
SPECIAL NOT APPLICABLE
NFPA LEGEND:
0 - NOT HAZARDOUS
1 - SLIGHTLY
2 - MODERATE
3 - HIGH
4 - SEVERE
THE RATINGS ASSIGNED ARE ONLY SUGGESTED RATINGS, THE CONTRACTOR/EMPLOYER
HAS ULTIMATE RESPONSIBILITIES FOR NFPA RATINGS WHERE THIS SYSTEM IS USED.
ADDITIONAL INFORMATION REGARDING THE NFPA RATING SYSTEM IS AVAILABLE FROM
THE NATIONAL FIRE PROTECTION AGENCY (NFPA) AT WWW.NFPA.ORG.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS:
REMOVE ALL SOURCES OF IGNITION. TAKE PRECAUTIONS TO PREVENT FLASHBACK.
GROUND AND BOND ALL CONTAINERS AND HANDLING EQUIPMENT. TAKE PRECAUTIONARY
MEASURES AGAINST STATIC DISCHARGES. ENSURE ADEQUATE VENTILATION. AVOID
CONTACT WITH SKIN, EYES AND CLOTHING. USE PERSONAL PROTECTIVE EQUIPMENT.
OTHER INFORMATION:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO. DO NOT ALLOW MATERIAL
TO CONTAMINATE GROUND WATER SYSTEM. PREVENT PRODUCT FROM ENTERING DRAINS.
DO NOT FLUSH INTO SURFACE WATER OR SANITARY SEWER SYSTEM. LOCAL AUTHORITIES
SHOULD BE ADVISED IF SIGNIFICANT SPILLAGES CANNOT BE CONTAINED.
ENVIRONMENTAL PRECAUTIONS:
SEE SECTION 12 FOR ADDITIONAL ECOLOGICAL INFORMATION.
METHODS FOR CLEANING UP:
DAM UP. SOAK UP WITH INERT ABSORBENT MATERIAL. USE A NON-SPARKING OR
EXPLOSION PROOF MEANS TO TRANSFER MATERIAL TO A SEALED, APPROPRIATE
CONTAINER FOR DISPOSAL. CLEAN CONTAMINATED SURFACE THOROUGHLY.
| 7. HANDLING AND STORAGE | |
HANDLING:
AVOID CONTACT WITH SKIN, EYES AND CLOTHING. WEAR PERSONAL PROTECTIVE
EQUIPMENT. DO NOT BREATHE VAPORS OR SPRAY MIST. USE ONLY IN VENTILATED
AREAS. PREVENT VAPOR BUILD-UP BY PROVIDING ADEQUATE VENTILATION DURING
AND AFTER USE.
TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGES. TO AVOID IGNITION
OF VAPORS BY STATIC ELECTRICITY DISCHARGE, ALL METAL PARTS OF THE EQUIPMENT
MUST BE GROUNDED. KEEP AWAY FROM HEAT, SPARKS AND FLAME. DO NOT SMOKE.
EXTINGUISH ALL FLAMES AND PILOT LIGHTS, AND TURN OFF STOVES, HEATERS,
ELECTRIC MOTORS AND OTHER SOURCES OF IGNITION DURING USE AND UNTIL ALL
VAPORS ARE GONE. IGNITION AND/OR FLASH BACK MAY OCCUR.
STORAGE:
KEEP CONTAINERS TIGHTLY CLOSED IN A DRY, COOL AND WELL-VENTILATED PLACE.
KEEP AWAY FROM HEAT. KEEP AWAY FROM OPEN FLAMES, HOT SURFACES AND SOURCES
OF IGNITION. KEEP IN PROPERLY LABELED CONTAINERS. KEEP OUT OF THE REACH OF
CHILDREN.
INCOMPATIBLE MATERIALS:
INCOMPATIBLE WITH STRONG ACIDS AND BASES AND STRONG OXIDIZING AGENTS.
TECHNICAL MEASURES/PRECAUTIONS:
ENSURE ADEQUATE VENTILATION. USE ONLY WHERE AIRFLOW WILL KEEP VAPORS FROM
BUILDING UP IN OR NEAR THE WORK AREA IN ADJOINING ROOMS. COMPLY WITH ALL
NATIONAL, STATE, AND LOCAL CODES PERTAINING TO THE STORAGE, HANDLING,
DISPENSING AND DISPOSAL OF FLAMMABLE LIQUIDS.
DISSIPATE STATIC ELECTRICITY DURING TRANSFER BY GROUNDING AND BONDING
CONTAINERS AND EQUIPMENT BEFORE TRANSFERRING MATERIAL. ALL EQUIPMENT
SHOULD BE NON-SPARKING AND EXPLOSION PROOF. USE EXPLOSION PROOF ELECTRICAL
EQUIPMENT FOR VENTILATION, LIGHTING AND MATERIAL HANDLING.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
EXPOSURE LIMITS:
CHEMICAL NAME ACGIH TLV OSHA PEL
XYLENE 100 PPM - TWA 100 PPM - TWA
150 PPM - STEL 435 MG/M3 - TWA
TALC 2 MG/M3 - TWA 20 MPPCF - TWA
ETHYL BENZENE 20 PPM - TWA 100 PPM - TWA
435 MG/M3 - TWA
TITANIUM DIOXIDE 10 MG/M3 - TWA 15 MG/M3 - TWA
DIBUTYL PHTHALATE 5 MG/M3 - TWA 5 MG/M3 - TWA
TOLUENE 20 PPM - TWA 200 PPM - TWA
300 PPM - CEILING
OCTANE 300 PPM - TWA 500 PPM - TWA
2350 MG/M3 - TWA
HEPTANE 400 PPM - TWA 500 PPM - TWA
500 PPM - STEL 2000 MG/M3 - TWA
SILICA, CRYSTALLINE 0.025 MG/M3 - TWA
LEGEND:
ACGIH:
AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS EXPOSURE LIMITS
OSHA: OCCUPATIONAL SAFETY & HEALTH ADMINISTRATION EXPOSURE LIMITS
N/E: NOT ESTABLISHED
APPROPRIATE ENGINEERING CONTROLS:
ENGINEERING MEASURES:
ENSURE ADEQUATE VENTILATION, ESPECIALLY IN CONFINED AREAS.
PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION:
SAFETY GLASSES WITH SIDE-SHIELDS. IF SPLASHES ARE LIKELY TO OCCUR, WEAR:
TIGHTLY FITTING SAFETY GOGGLES.
SKIN PROTECTION: LONG SLEEVED CLOTHING. PROTECTIVE GLOVES.
RESPIRATORY PROTECTION:
USE ONLY WITH ADEQUATE VENTILATION. IN OPERATIONS WHERE EXPOSURE LIMITS
ARE EXCEEDED, USE A NIOSH APPROVED RESPIRATOR THAT HAS BEEN SELECTED BY A
TECHNICALLY QUALIFIED PERSON FOR THE SPECIFIC WORK CONDITIONS. WHEN
SPRAYING THE PRODUCT OR APPLYING IN CONFINED AREAS, WEAR A NIOSH APPROVED
RESPIRATOR SPECIFIED FOR PAINT SPRAY OR ORGANIC VAPORS.
HYGIENE MEASURES:
AVOID CONTACT WITH SKIN, EYES AND CLOTHING. REMOVE AND WASH CONTAMINATED
CLOTHING BEFORE RE-USE. WASH THOROUGHLY AFTER HANDLING.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: LIQUID
ODOR: LITTLE OR NO ODOR
ODOR THRESHOLD: NO INFORMATION AVAILABLE
DENSITY (LBS/GAL): 9.7 - 10.1
SPECIFIC GRAVITY: 1.17 - 1.21
PH: NO INFORMATION AVAILABLE
VISCOSITY (CPS): NO INFORMATION AVAILABLE
SOLUBILITY(IES): NO INFORMATION AVAILABLE
WATER SOLUBILITY: NO INFORMATION AVAILABLE
EVAPORATION RATE: NO INFORMATION AVAILABLE
VAPOR PRESSURE @ 20 DEG. C (KPA): NO INFORMATION AVAILABLE
VAPOR DENSITY: NO INFORMATION AVAILABLE
WT. % SOLIDS: 45 - 55
VOL. % SOLIDS: 25 - 35
WT. % VOLATILES: 45 - 55
VOL. % VOLATILES: 65 - 75
VOC REGULATORY LIMIT (G/L): <600
BOILING POINT (DEG. F): 240
BOILING POINT (DEG. C): 116
FREEZING POINT (DEG. F): NO INFORMATION AVAILABLE
FREEZING POINT (DEG. C): NO INFORMATION AVAILABLE
FLASH POINT (DEG. F): 60.0
FLASH POINT (DEG. C): 15.6
METHOD: PMCC
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
UPPER FLAMMABILITY LIMIT: NO INFORMATION AVAILABLE
LOWER FLAMMABILITY LIMIT: NO INFORMATION AVAILABLE
AUTOIGNITION TEMPERATURE (DEG. F): NO INFORMATION AVAILABLE
AUTOIGNITION TEMPERATURE (DEG. C): NO INFORMATION AVAILABLE
DECOMPOSITION TEMPERATURE (DEG. F): NO INFORMATION AVAILABLE
DECOMPOSITION TEMPERATURE (DEG. C): NO INFORMATION AVAILABLE
PARTITION COEFFICIENT: NO INFORMATION AVAILABLE
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: NO DATA AVAILABLE
CHEMICAL STABILITY:
STABLE UNDER NORMAL CONDITIONS. HAZARDOUS POLYMERISATION DOES NOT OCCUR.
CONDITIONS TO AVOID:
KEEP AWAY FROM OPEN FLAMES, HOT SURFACES, STATIC ELECTRICITY AND SOURCES
OF IGNITION. SPARKS. ELEVATED TEMPERATURE.
INCOMPATIBLE MATERIALS:
INCOMPATIBLE WITH STRONG ACIDS AND BASES AND STRONG OXIDIZING AGENTS.
HAZARDOUS DECOMPOSITION PRODUCTS:
THERMAL DECOMPOSITION CAN LEAD TO RELEASE OF IRRITATING GASES AND VAPORS.
POSSIBILITY OF HAZARDOUS REACTIONS: NONE UNDER NORMAL CONDITIONS OF USE.
| 11. TOXICOLOGICAL INFORMATION | |
PRODUCT INFORMATION:
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
PRINCIPAL ROUTES OF EXPOSURE: EYE CONTACT, SKIN CONTACT AND INHALATION.
ACUTE TOXICITY:
PRODUCT INFORMATION:
REPEATED OR PROLONGED EXPOSURE TO ORGANIC SOLVENTS MAY LEAD TO PERMANENT
BRAIN AND NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY DELIBERATELY
CONCENTRATING AND INHALING VAPORS MAY BE HARMFUL OR FATAL.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
SYMPTOMS: NO INFORMATION AVAILABLE
DELAYED AND IMMEDIATE EFFECTS AS WELL AS CHRONIC EFFECTS FROM SHORT AND
LONG-TERM EXPOSURE:
EYE CONTACT:
CAUSES SERIOUS EYE IRRITATION. MAY CAUSE REDNESS, ITCHING, AND PAIN.
SKIN CONTACT:
MAY CAUSE SKIN IRRITATION AND/OR DERMATITIS. PROLONGED SKIN CONTACT MAY
DEFAT THE SKIN AND PRODUCE DERMATITIS.
INGESTION:
HARMFUL IF SWALLOWED. INGESTION MAY CAUSE IRRITATION TO MUCOUS MEMBRANES.
SMALL AMOUNTS OF THIS PRODUCT ASPIRATED INTO THE RESPIRATORY SYSTEM DURING
INGESTION OR VOMITING MAY CAUSE MILD TO SEVERE PULMONARY INJURY, POSSIBLY
PROGRESSING TO DEATH.
INHALATION:
HARMFUL BY INHALATION. HIGH VAPOR / AEROSOL CONCENTRATIONS ARE IRRITATING
TO THE EYES, NOSE, THROAT AND LUNGS AND MAY CAUSE HEADACHES, DIZZINESS,
DROWSINESS, UNCONSCIOUSNESS, AND OTHER CENTRAL NERVOUS SYSTEM EFFECTS.
SENSITIZATION: MAY CAUSE AN ALLERGIC SKIN REACTION
NEUROLOGICAL EFFECTS: NO INFORMATION AVAILABLE.
MUTAGENIC EFFECTS: NO INFORMATION AVAILABLE.
REPRODUCTIVE EFFECTS: MAY DAMAGE FERTILITY OR THE UNBORN CHILD.
DEVELOPMENTAL EFFECTS: NO INFORMATION AVAILABLE.
TARGET ORGAN EFFECTS: NO INFORMATION AVAILABLE.
STOT - REPEATED EXPOSURE:
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE IF INHALED.
MAY CAUSE DISORDER AND DAMAGE TO THE. CENTRAL NERVOUS SYSTEM. CAUSES DAMAGE
TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
STOT - SINGLE EXPOSURE:
MAY CAUSE DISORDER AND DAMAGE TO THE. RESPIRATORY SYSTEM. CENTRAL NERVOUS
SYSTEM.
OTHER ADVERSE EFFECTS: NO INFORMATION AVAILABLE.
ASPIRATION HAZARD:
MAY BE HARMFUL IF SWALLOWED AND ENTERS AIRWAYS. SMALL AMOUNTS OF THIS
PRODUCT ASPIRATED INTO THE RESPIRATORY SYSTEM DURING INGESTION OR VOMITING
MAY CAUSE MILD TO SEVERE PULMONARY INJURY, POSSIBLY PROGRESSING TO DEATH.
NUMERICAL MEASURES OF TOXICITY:
THE FOLLOWING VALUES ARE CALCULATED BASED ON CHAPTER 3.1 OF THE GHS
DOCUMENT:
ATEMIX (ORAL): 8678 MG/KG
ATEMIX (DERMAL): 3297 MG/KG
ATEMIX (INHALATION-DUST/MIST): 5.1 MG/L
ATEMIX (INHALATION-VAPOR): 33 MG/L
ACUTE TOXICITY:
COMPONENT INFORMATION:
XYLENE:
LD50 ORAL: 4300 MG/KG (RAT)
LD50 DERMAL: >1700 MG/KG (RABBIT)
LC50 INHALATION (VAPOR): 5000 PPM (RAT, 4 HR.)
ETHYL BENZENE:
LD50 ORAL: MG/KG (RAT)
LD50 DERMAL: >MG/KG (RABBIT)
LC50 INHALATION (VAPOR): MG/M3 (RAT, 2 HR.)
CHLORINATED PARAFFIN:
LD50 ORAL: 26100 MG/KG (RAT)
LD50 DERMAL: >10 ML/KG (RABBIT)
TITANIUM DIOXIDE:
LD50 ORAL: >10000 MG/KG (RAT)
DIBUTYL PHTHALATE:
LD50 ORAL: 7,499 MG/KG (RAT)
LD50 DERMAL: >20 ML/KG (RABBIT)
LC50 INHALATION (VAPOR): 4,250 MG/M3 (RAT)
TOLUENE:
LD50 ORAL: 636 MG/KG (RAT)
LD50 DERMAL: 14100 (MICRO)L/KG (RABBIT)
LC50 INHALATION (VAPOR): 49000 MG/M3 (RAT, 4 HR.)
HEPTANE:
LC50 INHALATION (VAPOR): 103000 MG/M3 (RAT, 4 HR.)
4,4-ISOPROPYLIDENEDIPHENOL-EPICHLOROHYDRIN COPOLYMER:
LD50 ORAL: MG/KG (RAT)
SILICA, CRYSTALLINE:
LD50 ORAL: 500 MG/KG (RAT)
CARCINOGENICITY:
THE INFORMATION BELOW INDICATES WHETHER EACH AGENCY HAS LISTED ANY
INGREDIENT AS A CARCINOGEN:
CHEMICAL NAME IARC NTP OSHA
ETHYL BENZENE 2B - POSSIBLE HUMAN LISTED
CARCINOGEN
CHLORINATED PARAFFIN 2B - POSSIBLE HUMAN LISTED
CARCINOGEN
TITANIUM DIOXIDE 2B - POSSIBLE HUMAN LISTED
CARCINOGEN
SILICA, CRYSTALLINE 1 - HUMAN CARCINOGEN KNOWN HUMAN LISTED
CARCINOGEN
CRYSTALLINE SILICA HAS BEEN DETERMINED TO BE CARCINOGENIC TO HUMANS BY IARC
(1) WHEN IN RESPIRABLE FORM. RISK OF CANCER DEPENDS ON DURATION AND LEVEL
OF INHALATION EXPOSURE TO SPRAY MIST OR DUST FROM SANDING THE DRIED PAINT.
ALTHOUGH IARC HAS CLASSIFIED TITANIUM DIOXIDE AS POSSIBLY CARCINOGENIC TO
HUMANS (2B), THEIR SUMMARY CONCLUDES:
"NO SIGNIFICANT EXPOSURE TO TITANIUM DIOXIDE IS THOUGHT TO OCCUR DURING
THE USE OF PRODUCTS IN WHICH TITANIUM DIOXIDE IS BOUND TO OTHER MATERIALS,
SUCH AS PAINT."
LEGEND:
IARC - INTERNATIONAL AGENCY FOR RESEARCH ON CANCER
NTP - NATIONAL TOXICITY PROGRAM
OSHA - OCCUPATIONAL SAFETY & HEALTH ADMINISTRATION
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY EFFECTS:
THE ENVIRONMENTAL IMPACT OF THIS PRODUCT HAS NOT BEEN FULLY INVESTIGATED.
PRODUCT INFORMATION:
ACUTE TOXICITY TO FISH: NO INFORMATION AVAILABLE
ACUTE TOXICITY TO AQUATIC INVERTEBRATES: NO INFORMATION AVAILABLE
ACUTE TOXICITY TO AQUATIC PLANTS: NO INFORMATION AVAILABLE
PERSISTENCE / DEGRADABILITY: NO INFORMATION AVAILABLE.
BIOACCUMULATION: THERE IS NO DATA FOR THIS PRODUCT.
MOBILITY IN ENVIRONMENTAL MEDIA: NO INFORMATION AVAILABLE.
OZONE: NOT APPLICABLE
COMPONENT INFORMATION:
ACUTE TOXICITY TO FISH:
XYLENE:
LC50: 13.5 MG/L (RAINBOW TROUT - 96 HR.)
ETHYL BENZENE:
LC50: 12.1 MG/L (FATHEAD MINNOW - 96 HR.)
TITANIUM DIOXIDE:
LC50: >1000 MG/L (FATHEAD MINNOW - 96 HR.)
4,4-ISOPROPYLIDENEDIPHENOL-EPICHLOROHYDRIN COPOLYMER:
LC50: 1.5 MG/L (RAINBOW TROUT - 96 HR.)
ACUTE TOXICITY TO AQUATIC INVERTEBRATES:
ETHYL BENZENE:
EC50: 1.8 MG/L (DAPHNIA MAGNA - 48 HR.)
ACUTE TOXICITY TO AQUATIC PLANTS:
ETHYL BENZENE:
EC50: 4.6 MG/L (GREEN ALGAE (SCENEDESMUS SUBSPICATUS), 72 HRS.)
| 13. DISPOSAL CONSIDERATIONS | |
WASTE DISPOSAL METHOD:
DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL REGULATIONS.
LOCAL REQUIREMENTS MAY VARY, CONSULT YOUR SANITATION DEPARTMENT OR
STATE-DESIGNATED ENVIRONMENTAL PROTECTION AGENCY FOR MORE DISPOSAL
OPTIONS.
EMPTY CONTAINER WARNING:
EMPTIED CONTAINERS MAY RETAIN PRODUCT RESIDUE. FOLLOW LABEL WARNINGS EVEN
AFTER CONTAINER IS EMPTIED. RESIDUAL VAPORS MAY EXPLODE ON IGNITION.
| 14. TRANSPORT INFORMATION | |
DOT:
PROPER SHIPPING NAME: PAINT
HAZARD CLASS: 3
UN-NO.: UN1263
PACKING GROUP: II
DESCRIPTION: UN1263, PAINT, 3, II
ICAO / IATA: CONTACT THE PREPARER FOR FURTHER INFORMATION.
IMDG / IMO: CONTACT THE PREPARER FOR FURTHER INFORMATION.
| 15. REGULATORY INFORMATION | |
INTERNATIONAL INVENTORIES:
TSCA:
UNITED STATES:
YES: ALL COMPONENTS ARE LISTED OR EXEMPT.
DSL:
CANADA:
YES: ALL COMPONENTS ARE LISTED OR EXEMPT.
FEDERAL REGULATIONS:
SARA 311/312 HAZARDOUS CATEGORIZATION:
ACUTE HEALTH HAZARD: YES
CHRONIC HEALTH HAZARD: YES
FIRE HAZARD: YES
SUDDEN RELEASE OF PRESSURE HAZARD: NO
REACTIVE HAZARD: NO
SARA 313:
SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION
ACT OF 1986 (SARA). THIS PRODUCT CONTAINS A CHEMICAL OR CHEMICALS WHICH
ARE SUBJECT TO THE REPORTING REQUIREMENTS OF THE ACT AND TITLE 40 OF THE
CODE OF FEDERAL REGULATIONS, PART 372:
CHEMICAL NAME CAS NO. WEIGHT-% CERCLA/SARA 313
(DE MINIMIS CONCENTRATION)
XYLENE 1330-20-7 30 1.0
ETHYL BENZENE 100-41-4 10 0.1
DIBUTYL PHTHALATE 84-74-2 5 1.0
CLEAN AIR ACT, SECTION 112 HAZARDOUS AIR POLLUTANTS (HAPS) (SEE 40 CFR 61):
THIS PRODUCT CONTAINS THE FOLLOWING HAPS:
CHEMICAL NAME CAS NO. WEIGHT-% HAZARDOUS AIR POLLUTANT (HAP)
XYLENE 1330-20-7 30 LISTED
ETHYL BENZENE 100-41-4 10 LISTED
DIBUTYL PHTHALATE 84-74-2 5 LISTED
TOLUENE 108-88-3 1 LISTED
US STATE REGULATIONS:
CALIFORNIA PROPOSITION 65:
WARNING: CANCER AND REPRODUCTIVE HARM-WWW.P65WARNINS.CA.GOV
STATE RIGHT-TO-KNOW:
CHEMICAL NAME MASSACHUSETTS NEW JERSEY PENNSYLVANIA
XYLENE X X X
TALC X X X
ETHYL BENZENE X X X
CHLORINATED PARAFFIN X
TITANIUM DIOXIDE X X X
DIBUTYL PHTHALATE X X X
SILICA, CRYSTALLINE X X X
LEGEND: X - LISTED
| 16. OTHER INFORMATION | |
HMIS:
HEALTH 2*
FLAMMABILITY 3
REACTIVITY 0
PPE
HMIS LEGEND:
0 - MINIMAL HAZARD
1 - SLIGHT HAZARD
2 - MODERATE HAZARD
3 - SERIOUS HAZARD
4 - SEVERE HAZARD * - CHRONIC HAZARD
X - CONSULT YOUR SUPERVISOR OR S.O.P. FOR "SPECIAL" HANDLING INSTRUCTIONS.
NOTE:
THE PPE RATING HAS INTENTIONALLY BEEN LEFT BLANK. CHOOSE APPROPRIATE PPE
THAT WILL PROTECT EMPLOYEES FROM THE HAZARDS THE MATERIAL WILL PRESENT
UNDER THE ACTUAL NORMAL CONDITIONS OF USE.
CAUTION:
HMIS(R*) RATINGS ARE BASED ON A 0-4 RATING SCALE, WITH 0 REPRESENTING
MINIMAL HAZARDS OR RISKS, AND 4 REPRESENTING SIGNIFICANT HAZARDS OR RISKS.
ALTHOUGH HMIS(R*) RATINGS ARE NOT REQUIRED ON MSDSS UNDER 29 CFR 1910.1200,
THE PREPARER, HAS CHOSEN TO PROVIDE THEM. HMIS(R*) RATINGS ARE TO BE USED
ONLY IN CONJUNCTION WITH A FULLY IMPLEMENTED HMIS(R*) PROGRAM BY WORKERS
WHO HAVE RECEIVED APPROPRIATE HMIS(R*) TRAINING. HMIS(R*) IS A REGISTERED
TRADE AND SERVICE MARK OF THE NPCA. HMIS(R*) MATERIALS MAY BE PURCHASED
EXCLUSIVELY FROM J. J. KELLER (800) 327-6868.
WARNING!
IF YOU SCRAPE, SAND, OR REMOVE OLD PAINT, YOU MAY RELEASE LEAD DUST. LEAD
IS TOXIC. EXPOSURE TO LEAD DUST CAN CAUSE SERIOUS ILLNESS, SUCH AS BRAIN
DAMAGE, ESPECIALLY IN CHILDREN. PREGNANT WOMEN SHOULD ALSO AVOID EXPOSURE.
WEAR A NIOSH APPROVED RESPIRATOR TO CONTROL LEAD EXPOSURE. CLEAN UP
CAREFULLY WITH A HEPA VACUUM AND A WET MOP. BEFORE YOU START, FIND OUT HOW
TO PROTECT YOURSELF AND YOUR FAMILY BY CONTACTING THE NATIONAL LEAD
INFORMATION HOTLINE AT 1-800-424-LEAD OR LOG ON TO WWW.EPA.GOV/LEAD.
PREPARED BY:
PRODUCT STEWARDSHIP DEPARTMENT
BENJAMIN MOORE & CO.
101 PARAGON DRIVE
MONTVALE, NJ 07645
800-225-5554
REVISION DATE: 30-MAY-2018
REVISION SUMMARY: NOT AVAILABLE
DISCLAIMER:
THE INFORMATION CONTAINED HEREIN IS PRESENTED IN GOOD FAITH AND BELIEVED
TO BE ACCURATE AS OF THE EFFECTIVE DATE SHOWN ABOVE. THIS INFORMATION IS
FURNISHED WITHOUT WARRANTY OF ANY KIND. EMPLOYERS SHOULD USE THIS
INFORMATION ONLY AS A SUPPLEMENT TO OTHER INFORMATION GATHERED BY THEM AND
MUST MAKE INDEPENDENT DETERMINATION OF SUITABILITY AND COMPLETENESS OF
INFORMATION FROM ALL SOURCES TO ASSURE PROPER USE OF THESE MATERIALS AND
THE SAFETY AND HEALTH OF EMPLOYEES. ANY USE OF THIS DATA AND INFORMATION
MUST BE DETERMINED BY THE USER TO BE IN ACCORDANCE WITH APPLICABLE FEDERAL,
PROVINCIAL, AND LOCAL LAWS AND REGULATIONS.