| Common Name: | LPS HDX, 01005, 01055 |
| Manufacturer: | ITW PRO BRANDS |
| SDS Revision Date: | 2/19/2018 |
| SDS Format: | GHS-US |
| Item Number(s): | 6JHX8, 6JHX9 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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ITW PRO BRANDS
SAFETY DATA SHEET
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER: LPS(R*) HDX
OTHER MEANS OF IDENTIFICATION:
PART NUMBER: 01005, 01055
RECOMMENDED USE:
A DEGREASER DESIGNED TO REMOVE GREASE, OIL, DIRT AND OTHER RESIDUES FROM
METAL AND OTHER HARD SURFACES NEAR IGNITION SOURCES.
RECOMMENDED RESTRICTIONS: NONE KNOWN.
MANUFACTURER/IMPORTER/SUPPLIER/DISTRIBUTOR INFORMATION:
MANUFACTURER:
COMPANY NAME: ITW PRO BRANDS
ADDRESS:
4647 HUGH HOWELL RD.
TUCKER, GA 30084
COUNTRY: (U.S.A.)
TEL: +1 770-243-8800
IN CASE OF EMERGENCY:
1-800-424-9300 (INSIDE U.S.)
+001 703-527-3887 (OUTSIDE U.S.)
WEBSITE: WWW.LPSLABS.COM
E-MAIL: LPSSDS@ITWPROBRANDS.COM
| 2. HAZARD(S) IDENTIFICATION | |
PHYSICAL HAZARDS: NOT CLASSIFIED.
HEALTH HAZARDS:
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2A
GERM CELL MUTAGENICITY: CATEGORY 2
CARCINOGENICITY: CATEGORY 1B
SPECIFIC TARGET ORGAN TOXICITY, SINGLE EXPOSURE:
CATEGORY 3 NARCOTIC EFFECTS
ENVIRONMENTAL HAZARDS: NOT CLASSIFIED.
OSHA DEFINED HAZARDS: NOT CLASSIFIED.
LABEL ELEMENTS:
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENT:
CAUSES SKIN IRRITATION. CAUSES SERIOUS EYE IRRITATION. SUSPECTED OF CAUSING
GENETIC DEFECTS. MAY CAUSE CANCER. MAY CAUSE DROWSINESS OR DIZZINESS.
PRECAUTIONARY STATEMENT:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. AVOID BREATHING MIST OR VAPOR.
WASH THOROUGHLY AFTER HANDLING. USE ONLY OUTDOORS OR IN A WELL-VENTILATED
AREA. WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE
PROTECTION.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EXPOSED OR CONCERNED:
GET MEDICAL ADVICE/ATTENTION. CALL A POISON CENTER/DOCTOR IF YOU FEEL
UNWELL.
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
IF EYE IRRITATION PERSISTS:
GET MEDICAL ADVICE/ATTENTION. TAKE OFF CONTAMINATED CLOTHING AND WASH
BEFORE REUSE.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE
LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
HAZARD(S) NOT OTHERWISE CLASSIFIED (HNOC): NONE KNOWN.
SUPPLEMENTAL INFORMATION: NONE KNOWN.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
MIXTURES:
CHEMICAL NAME COMMON NAME AND SYNONYMS CAS NUMBER %
1,1,2-TRICHLOROETHYLENE 79-01-6 90 - 100
| 4. FIRST-AID MEASURES | |
INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING. WASH WITH PLENTY OF SOAP AND WATER. IF SKIN
IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION. WASH CONTAMINATED CLOTHING
BEFORE REUSE.
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. REMOVE
CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING. GET MEDICAL
ATTENTION IF IRRITATION DEVELOPS AND PERSISTS.
INGESTION: RINSE MOUTH. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
MAY CAUSE DROWSINESS AND DIZZINESS. HEADACHE. NAUSEA, VOMITING. SEVERE EYE
IRRITATION. SYMPTOMS MAY INCLUDE STINGING, TEARING, REDNESS, SWELLING, AND
BLURRED VISION. SKIN IRRITATION. MAY CAUSE REDNESS AND PAIN.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
PROVIDE GENERAL SUPPORTIVE MEASURES AND TREAT SYMPTOMATICALLY. KEEP VICTIM
UNDER OBSERVATION. SYMPTOMS MAY BE DELAYED.
GENERAL INFORMATION:
IF EXPOSED OR CONCERNED:
GET MEDICAL ADVICE/ATTENTION. IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE (SHOW
THE LABEL WHERE POSSIBLE). ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE
MATERIAL(S) INVOLVED, AND TAKE PRECAUTIONS TO PROTECT THEMSELVES. SHOW THIS
SAFETY DATA SHEET TO THE DOCTOR IN ATTENDANCE.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
WATER FOG. FOAM. DRY CHEMICAL POWDER. CARBON DIOXIDE (CO2).
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE WATER JET AS AN EXTINGUISHER, AS THIS WILL SPREAD THE FIRE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
DURING FIRE, GASES HAZARDOUS TO HEALTH MAY BE FORMED.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING MUST BE
WORN IN CASE OF FIRE.
FIRE FIGHTING EQUIPMENT/INSTRUCTIONS:
MOVE CONTAINERS FROM FIRE AREA IF YOU CAN DO SO WITHOUT RISK.
SPECIFIC METHODS:
USE STANDARD FIREFIGHTING PROCEDURES AND CONSIDER THE HAZARDS OF OTHER
INVOLVED MATERIALS.
GENERAL FIRE HAZARDS: NO UNUSUAL FIRE OR EXPLOSION HAZARDS NOTED.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
KEEP UNNECESSARY PERSONNEL AWAY. KEEP PEOPLE AWAY FROM AND UPWIND OF
SPILL/LEAK. WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND CLOTHING DURING
CLEAN-UP. AVOID BREATHING MIST OR VAPOR. DO NOT TOUCH DAMAGED CONTAINERS OR
SPILLED MATERIAL UNLESS WEARING APPROPRIATE PROTECTIVE CLOTHING. ENSURE
ADEQUATE VENTILATION. LOCAL AUTHORITIES SHOULD BE ADVISED IF SIGNIFICANT
SPILLAGES CANNOT BE CONTAINED.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
LARGE SPILLS:
STOP THE FLOW OF MATERIAL, IF THIS IS WITHOUT RISK. DIKE THE SPILLED
MATERIAL, WHERE THIS IS POSSIBLE. ABSORB IN VERMICULITE, DRY SAND OR EARTH
AND PLACE INTO CONTAINERS. FOLLOWING PRODUCT RECOVERY, FLUSH AREA WITH
WATER.
SMALL SPILLS:
WIPE UP WITH ABSORBENT MATERIAL (E.G. CLOTH, FLEECE). CLEAN SURFACE
THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION.
NEVER RETURN SPILLS TO ORIGINAL CONTAINERS FOR RE-USE. PUT MATERIAL IN
SUITABLE, COVERED, LABELED CONTAINERS.
ENVIRONMENTAL PRECAUTIONS:
AVOID DISCHARGE INTO DRAINS, WATER COURSES OR ONTO THE GROUND.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. AVOID BREATHING MIST OR VAPOR.
AVOID CONTACT WITH EYES, SKIN, AND CLOTHING. AVOID PROLONGED EXPOSURE.
SHOULD BE HANDLED IN CLOSED SYSTEMS, IF POSSIBLE. PROVIDE ADEQUATE
VENTILATION. WEAR APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT. OBSERVE GOOD
INDUSTRIAL HYGIENE PRACTICES.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE LOCKED UP. STORE IN ORIGINAL TIGHTLY CLOSED CONTAINER.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE LIMITS:
THE FOLLOWING CONSTITUENTS ARE THE ONLY CONSTITUENTS OF THE PRODUCT WHICH
HAVE A PEL, TLV OR OTHER RECOMMENDED EXPOSURE LIMIT. AT THIS TIME, THE
OTHER CONSTITUENTS HAVE NO KNOWN EXPOSURE LIMITS.
US. OSHA TABLE Z-1 LIMITS FOR AIR CONTAMINANTS (29 CFR 1910.1000):
COMPONENTS TYPE VALUE FORM
BUTANONE (CAS 78-93-3) PEL 590 MG/M3
200 PPM
CAMPHOR USP (CAS 76-22-2) PEL 2 MG/M3
DIPHENYL OXIDE (CAS 101-84-8) PEL 7 MG/M3 VAPOR.
1 PPM VAPOR.
ISO AMYL ACETATE (CAS 123-92-2) PEL 525 MG/M3
100 PPM
TURPENTINE (CAS 8006-64-2) PEL 560 MG/M3
100 PPM
US. OSHA TABLE Z-2 (29 CFR 1910.1000):
COMPONENTS TYPE VALUE
1,1,2-TRICHLOROETHYLENE CEILING 200 PPM
(CAS 79-01-6) TWA 100 PPM
US. ACGIH THRESHOLD LIMIT VALUES:
COMPONENTS TYPE VALUE FORM
1,1,2-TRICHLOROETHYLENE STEL 25 PPM
(CAS 79-01-6) TWA 10 PPM
BUTANONE (CAS 78-93-3) STEL 300 PPM
TWA 200 PPM
CAMPHOR USP (CAS 76-22-2) STEL 3 PPM
TWA 2 PPM
DIPHENYL OXIDE (CAS 101-84-8) STEL 2 PPM VAPOR.
TWA 1 PPM VAPOR.
ISO AMYL ACETATE (CAS 123-92-2) STEL 100 PPM
TWA 50 PPM
TURPENTINE (CAS 8006-64-2) TWA 20 PPM
US. NIOSH: POCKET GUIDE TO CHEMICAL HAZARDS
COMPONENTS TYPE VALUE FORM
1,1,2-TRICHLOROETHYLENE CEILING 2 PPM
(CAS 79-01-6) TWA 25 PPM
BUTANONE (CAS 78-93-3) STEL 885 MG/M3
300 PPM
TWA 590 MG/M3
200 PPM
US. NIOSH: POCKET GUIDE TO CHEMICAL HAZARDS
COMPONENTS TYPE VALUE FORM
CAMPHOR USP (CAS 76-22-2) TWA 2 MG/M3
DIPHENYL OXIDE (CAS 101-84-8) TWA 7 MG/M3 VAPOR.
1 PPM VAPOR.
ISO AMYL ACETATE (CAS 123-92-2) TWA 525 MG/M3
100 PPM
TURPENTINE (CAS 8006-64-2) TWA 560 MG/M3
100 PPM
US. WORKPLACE ENVIRONMENTAL EXPOSURE LEVEL (WEEL) GUIDES:
COMPONENTS TYPE VALUE
1,2 BUTYLENE OXIDE TWA 5.9 MG/M3
(CAS 106-88-7) 2 PPM
BIOLOGICAL LIMIT VALUES:
ACGIH BIOLOGICAL EXPOSURE INDICES:
COMPONENTS VALUE DETERMINANT SPECIMEN SAMPLING
TIME
1,1,2-TRICHLOROETHYLENE 15 MG/L TRICHLOROACETIC URINE *
ACID 0.5 MG/L TRICHLOROETHANO BLOOD *
(CAS 79-01-6) L, WITHOUT
HYDROLYSIS
BUTANONE (CAS 78-93-3) 2 MG/L MEK URINE *
* - FOR SAMPLING DETAILS, PLEASE SEE THE SOURCE DOCUMENT.
APPROPRIATE ENGINEERING CONTROLS:
GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER HOUR) SHOULD BE
USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS. IF APPLICABLE, USE
PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO MAINTAIN AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. IF
EXPOSURE LIMITS HAVE NOT BEEN ESTABLISHED, MAINTAIN AIRBORNE LEVELS TO AN
ACCEPTABLE LEVEL. EYE WASH FACILITIES AND EMERGENCY SHOWER MUST BE
AVAILABLE WHEN HANDLING THIS PRODUCT.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION: WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES).
SKIN PROTECTION:
HAND PROTECTION: WEAR APPROPRIATE CHEMICAL RESISTANT GLOVES.
OTHER:
WEAR APPROPRIATE CHEMICAL RESISTANT CLOTHING. USE OF AN IMPERVIOUS APRON IS
RECOMMENDED.
RESPIRATORY PROTECTION:
USE A POSITIVE-PRESSURE AIR-SUPPLIED RESPIRATOR IF THERE IS ANY POTENTIAL
FOR AN UNCONTROLLED RELEASE, EXPOSURE LEVELS ARE NOT KNOWN, OR ANY OTHER
CIRCUMSTANCES WHERE AIR-PURIFYING RESPIRATORS MAY NOT PROVIDE ADEQUATE
PROTECTION.
THERMAL HAZARDS:
WEAR APPROPRIATE THERMAL PROTECTIVE CLOTHING, WHEN NECESSARY.
GENERAL HYGIENE CONSIDERATIONS:
OBSERVE ANY MEDICAL SURVEILLANCE REQUIREMENTS. ALWAYS OBSERVE GOOD PERSONAL
HYGIENE MEASURES, SUCH AS WASHING AFTER HANDLING THE MATERIAL AND BEFORE
EATING, DRINKING, AND/OR SMOKING. ROUTINELY WASH WORK CLOTHING AND
PROTECTIVE EQUIPMENT TO REMOVE CONTAMINANTS.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: LIQUID.
FORM: LIQUID.
COLOR: LIGHT BROWN.
ODOR: SWEET, SPICE.
ODOR THRESHOLD: NOT ESTABLISHED
PH: NOT APPLICABLE
MELTING POINT/FREEZING POINT: NOT ESTABLISHED
INITIAL BOILING POINT AND BOILING RANGE: 188.6 DEG. F (87 DEG. C)
FLASH POINT: TAG CLOSED CUP (NONE)
EVAPORATION RATE: 0.3 (ETHYL ETHER = 1)
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE.
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS:
FLAMMABILITY LIMIT - LOWER (%): 8%
FLAMMABILITY LIMIT - UPPER (%): 10.5%
EXPLOSIVE LIMIT - LOWER (%): NOT AVAILABLE.
EXPLOSIVE LIMIT - UPPER (%): NOT AVAILABLE.
VAPOR PRESSURE: 58 MMHg @ 20 DEG. C
VAPOR DENSITY: 4.5
RELATIVE DENSITY: NOT AVAILABLE.
SOLUBILITY(IES):
SOLUBILITY (WATER): 0.1%
PARTITION COEFFICIENT (N-OCTANOL/WATER): 2.4
AUTO-IGNITION TEMPERATURE: >788 DEG. F (>420 DEG. C)
DECOMPOSITION TEMPERATURE: NOT ESTABLISHED
VISCOSITY: 0.53 CP @ 25 DEG. C
OTHER INFORMATION:
EXPLOSIVE PROPERTIES: NOT EXPLOSIVE.
HEAT OF COMBUSTION: <20 KJ/G
OXIDIZING PROPERTIES: NOT OXIDIZING.
PERCENT VOLATILE: 100%
SPECIFIC GRAVITY: 1.41 - 1.47 @ 20 DEG. C
VOC: 100%
| 10. STABILITY AND REACTIVITY | |
REACTIVITY:
THE PRODUCT IS STABLE AND NON-REACTIVE UNDER NORMAL CONDITIONS OF USE,
STORAGE AND TRANSPORT.
CHEMICAL STABILITY: MATERIAL IS STABLE UNDER NORMAL CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION DOES NOT OCCUR.
CONDITIONS TO AVOID: CONTACT WITH INCOMPATIBLE MATERIALS.
INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS.
HAZARDOUS DECOMPOSITION PRODUCTS: CARBON OXIDES.
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INHALATION:
MAY CAUSE DROWSINESS AND DIZZINESS. HEADACHE. NAUSEA, VOMITING. PROLONGED
INHALATION MAY BE HARMFUL.
SKIN CONTACT: CAUSES SKIN IRRITATION.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INGESTION: EXPECTED TO BE A LOW INGESTION HAZARD.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
MAY CAUSE DROWSINESS AND DIZZINESS. HEADACHE. NAUSEA, VOMITING. SEVERE EYE
IRRITATION. SYMPTOMS MAY INCLUDE STINGING, TEARING, REDNESS, SWELLING, AND
BLURRED VISION. SKIN IRRITATION. MAY CAUSE REDNESS AND PAIN.
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY: NARCOTIC EFFECTS.
COMPONENTS SPECIES TEST RESULTS
1,1,2-TRICHLOROETHYLENE (CAS 79-01-6):
ACUTE:
ORAL:
LD50 RAT 4920 MG/KG
1,2 BUTYLENE OXIDE (CAS 106-88-7):
ACUTE:
DERMAL:
LD50 RABBIT 1500 - 2950 MG/KG, 24 HOURS
INHALATION:
VAPOR:
LC50 RAT >6.3 MG/L, 4 HOURS
ORAL:
LD50 RAT 1 - 1.58 MG/KG
BUTANONE (CAS 78-93-3):
ACUTE:
ORAL:
LD50 RAT 2054 MG/KG
DIPHENYL OXIDE (CAS 101-84-8):
ACUTE:
ORAL:
LD50 RAT 2.83 G/KG
TURPENTINE (CAS 8006-64-2):
ACUTE:
INHALATION:
VAPOR:
LC50 RAT 13.7 MG/L, 4 HOURS
SKIN CORROSION/IRRITATION: CAUSES SKIN IRRITATION.
SERIOUS EYE DAMAGE/EYE IRRITATION: CAUSES SERIOUS EYE IRRITATION.
RESPIRATORY OR SKIN SENSITIZATION:
ACGIH SENSITIZATION:
TURPENTINE AND SELECTED MONOTERPENES (CAS 8006-64-2): DERMAL SENSITIZATION
RESPIRATORY SENSITIZATION: NOT A RESPIRATORY SENSITIZER.
SKIN SENSITIZATION:
THIS PRODUCT IS NOT EXPECTED TO CAUSE SKIN SENSITIZATION.
GERM CELL MUTAGENICITY: SUSPECTED OF CAUSING GENETIC DEFECTS.
CARCINOGENICITY: MAY CAUSE CANCER.
ACGIH CARCINOGENS:
1,1,2-TRICHLOROETHYLENE (CAS 79-01-6): A2 SUSPECTED HUMAN CARCINOGEN.
CAMPHOR USP (CAS 76-22-2): A4 NOT CLASSIFIABLE AS A HUMAN CARCINOGEN.
TURPENTINE (CAS 8006-64-2): A4 NOT CLASSIFIABLE AS A HUMAN CARCINOGEN.
IARC MONOGRAPHS. OVERALL EVALUATION OF CARCINOGENICITY:
1,1,2-TRICHLOROETHYLENE (CAS 79-01-6): 1 CARCINOGENIC TO HUMANS.
1,2 BUTYLENE OXIDE (CAS 106-88-7): 2B POSSIBLY CARCINOGENIC TO HUMANS.
OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1052):
NOT REGULATED.
US. NATIONAL TOXICOLOGY PROGRAM (NTP) REPORT ON CARCINOGENS:
1,1,2-TRICHLOROETHYLENE (CAS 79-01-6):
REASONABLY ANTICIPATED TO BE A HUMAN CARCINOGEN.
REPRODUCTIVE TOXICITY:
THIS PRODUCT IS NOT EXPECTED TO CAUSE REPRODUCTIVE OR DEVELOPMENTAL
EFFECTS.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
MAY CAUSE DROWSINESS AND DIZZINESS.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NOT CLASSIFIED.
ASPIRATION HAZARD: NOT AN ASPIRATION HAZARD.
CHRONIC EFFECTS:
PROLONGED INHALATION MAY BE HARMFUL. PROLONGED EXPOSURE MAY CAUSE CHRONIC
EFFECTS.
FURTHER INFORMATION: SYMPTOMS MAY BE DELAYED.
| 12. ECOLOGICAL INFORMATION | |
THE PRODUCT IS NOT CLASSIFIED AS ENVIRONMENTALLY HAZARDOUS. HOWEVER, THIS
DOES NOT EXCLUDE THE POSSIBILITY THAT LARGE OR FREQUENT SPILLS CAN HAVE A
HARMFUL OR DAMAGING EFFECT ON THE ENVIRONMENT. ECOTOXICITY
COMPONENTS SPECIES TEST RESULTS
1,1,2-TRICHLOROETHYLENE (CAS 79-01-6):
AQUATIC:
FISH LC50 FLAGFISH (JORDANELLA 3.1 MG/L, 96 HOURS
FLORIDAE)
BUTANONE (CAS 78-93-3):
AQUATIC:
CRUSTACEA EC50 WATER FLEA (DAPHNIA 4025 - 6440 MG/L,
MAGNA) 48 HOURS
FISH LC50 SHEEPSHEAD MINNOW >400 MG/L, 96 HOURS
(CYPRINODON
VARIEGATUS)
DIPHENYL OXIDE (CAS 101-84-8):
AQUATIC:
FISH LC50 SHEEPSHEAD MINNOW 1.8 - 3.2 MG/L,
(CYPRINODON 96 HOURS
VARIEGATUS)
PERSISTENCE AND DEGRADABILITY:
NO DATA IS AVAILABLE ON THE DEGRADABILITY OF THIS PRODUCT.
BIOACCUMULATIVE POTENTIAL:
PARTITION COEFFICIENT N-OCTANOL / WATER (LOG KOW):
LPS(R*) HDX: 2.4
1,1,2-TRICHLOROETHYLENE: 2.61
BUTANONE: 0.29
DIPHENYL OXIDE: 4.21
MOBILITY IN SOIL: NO DATA AVAILABLE.
OTHER ADVERSE EFFECTS: NONE KNOWN.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL INSTRUCTIONS:
COLLECT AND RECLAIM OR DISPOSE IN SEALED CONTAINERS AT LICENSED WASTE
DISPOSAL SITE. DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
LOCAL DISPOSAL REGULATIONS:
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS.
HAZARDOUS WASTE CODE:
THE WASTE CODE SHOULD BE ASSIGNED IN DISCUSSION BETWEEN THE USER, THE
PRODUCER AND THE WASTE DISPOSAL COMPANY.
D040: WASTE TRICHLOROETHYLENE
F001
WASTE FROM RESIDUES / UNUSED PRODUCTS:
DISPOSE OF IN ACCORDANCE WITH LOCAL REGULATIONS. EMPTY CONTAINERS OR LINERS
MAY RETAIN SOME PRODUCT RESIDUES. THIS MATERIAL AND ITS CONTAINER MUST BE
DISPOSED OF IN A SAFE MANNER (SEE: DISPOSAL INSTRUCTIONS).
CONTAMINATED PACKAGING:
SINCE EMPTIED CONTAINERS MAY RETAIN PRODUCT RESIDUE, FOLLOW LABEL WARNINGS
EVEN AFTER CONTAINER IS EMPTIED. EMPTY CONTAINERS SHOULD BE TAKEN TO AN
APPROVED WASTE HANDLING SITE FOR RECYCLING OR DISPOSAL.
| 14. TRANSPORT INFORMATION | |
DOT:
UN NUMBER: UN1710
UN PROPER SHIPPING NAME: TRICHLOROETHYLENE
TRANSPORT HAZARD CLASS(ES):
CLASS: 6.1(PGIII)
SUBSIDIARY RISK:
LABEL(S): 6.1
PACKING GROUP: III
ENVIRONMENTAL HAZARDS:
MARINE POLLUTANT: NO
SPECIAL PRECAUTIONS FOR USER: NOT AVAILABLE.
SPECIAL PROVISIONS: IB3, N36, T4, TP1
PACKAGING EXCEPTIONS: 153
PACKAGING NON BULK: 203
PACKAGING BULK: 241
IATA:
UN NUMBER: UN1710
UN PROPER SHIPPING NAME: TRICHLOROETHYLENE
TRANSPORT HAZARD CLASS(ES):
CLASS: 6.1(PGIII)
SUBSIDIARY RISK:
PACKING GROUP: III
ENVIRONMENTAL HAZARDS: NO
ERG CODE: 6A
SPECIAL PRECAUTIONS FOR USER: NOT AVAILABLE.
OTHER INFORMATION:
PASSENGER AND CARGO AIRCRAFT: ALLOWED WITH RESTRICTIONS.
CARGO AIRCRAFT ONLY: ALLOWED WITH RESTRICTIONS.
IMDG:
UN NUMBER: UN1710
UN PROPER SHIPPING NAME: TRICHLOROETHYLENE
TRANSPORT HAZARD CLASS(ES):
CLASS: 6.1(PGIII)
SUBSIDIARY RISK:
PACKING GROUP: III
ENVIRONMENTAL HAZARDS:
MARINE POLLUTANT: NO
EMS: F-A, S-A
SPECIAL PRECAUTIONS FOR USER: NOT AVAILABLE.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE:
NOT ESTABLISHED.
DOT: POISON, CLASS/DIVISION 6.1 PACKING GROUP I OR II
IATA; IMDG: CLASS 6.1 - TOXIC
| 15. REGULATORY INFORMATION | |
US FEDERAL REGULATIONS:
THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.
TSCA SECTION 12(B) EXPORT NOTIFICATION (40 CFR 707, SUBPT. D):
1,1,2-TRICHLOROETHYLENE (CAS 79-01-6):
0.1% ONE-TIME EXPORT NOTIFICATION ONLY.
CERCLA HAZARDOUS SUBSTANCE LIST (40 CFR 302.4):
1,1,2-TRICHLOROETHYLENE (CAS 79-01-6): LISTED.
1,2 BUTYLENE OXIDE (CAS 106-88-7): LISTED.
BUTANONE (CAS 78-93-3): LISTED.
ISO AMYL ACETATE (CAS 123-92-2): LISTED.
SARA 304 EMERGENCY RELEASE NOTIFICATION: NOT REGULATED.
OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1052):
NOT REGULATED.
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA):
SARA 302 EXTREMELY HAZARDOUS SUBSTANCE: NOT LISTED.
SARA 311/312 HAZARDOUS CHEMICAL: YES
SARA 313 (TRI REPORTING):
CHEMICAL NAME CAS NUMBER % BY WT.
TRICHLOROETHYLENE 79-01-6 90 - 100
OTHER FEDERAL REGULATIONS:
CLEAN AIR ACT (CAA) SECTION 112 HAZARDOUS AIR POLLUTANTS (HAPS) LIST:
1,1,2-TRICHLOROETHYLENE (CAS 79-01-6)
1,2 BUTYLENE OXIDE (CAS 106-88-7)
CLEAN AIR ACT (CAA) SECTION 112(R) ACCIDENTAL RELEASE PREVENTION (40 CFR
68.130): NOT REGULATED.
SAFE DRINKING WATER ACT (SDWA): NOT REGULATED.
DRUG ENFORCEMENT ADMINISTRATION (DEA). LIST 2, ESSENTIAL CHEMICALS (21 CFR
1310.02(B) AND 1310.04(F)(2) AND CHEMICAL CODE NUMBER:
BUTANONE (CAS 78-93-3): 6714
DRUG ENFORCEMENT ADMINISTRATION (DEA). LIST 1 & 2 EXEMPT CHEMICAL MIXTURES
(21 CFR 1310.12(C)):
BUTANONE (CAS 78-93-3): 35%WV
DEA EXEMPT CHEMICAL MIXTURES CODE NUMBER:
BUTANONE (CAS 78-93-3): 6714
FEMA PRIORITY SUBSTANCES RESPIRATORY HEALTH AND SAFETY IN THE FLAVOR
MANUFACTURING WORKPLACE:
BUTANONE (CAS 78-93-3): LOW PRIORITY
DIPHENYL OXIDE (CAS 101-84-8): LOW PRIORITY
ISO AMYL ACETATE (CAS 123-92-2): LOW PRIORITY
US STATE REGULATIONS:
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
US. NEW JERSEY WORKER AND COMMUNITY RIGHT-TO-KNOW ACT:
1,1,2-TRICHLOROETHYLENE (CAS 79-01-6)
1,2 BUTYLENE OXIDE (CAS 106-88-7)
BUTANONE (CAS 78-93-3)
CAMPHOR USP (CAS 76-22-2)
DIPHENYL OXIDE (CAS 101-84-8)
ISO AMYL ACETATE (CAS 123-92-2)
TURPENTINE (CAS 8006-64-2)
CALIFORNIA PROPOSITION 65:
CALIFORNIA PROPOSITION 65 - CRT: LISTED DATE/CARCINOGENIC SUBSTANCE
1,1,2-TRICHLOROETHYLENE (CAS 79-01-6):
LISTED: APRIL 1, 1988
CALIFORNIA PROPOSITION 65 - CRT: LISTED DATE/DEVELOPMENTAL TOXIN
1,1,2-TRICHLOROETHYLENE (CAS 79-01-6):
LISTED: JAN 31, 2014
CALIFORNIA PROPOSITION 65 - CRT: LISTED DATE/MALE REPRODUCTIVE TOXIN
1,1,2-TRICHLOROETHYLENE (CAS 79-01-6):
LISTED: JAN 31, 2014
US. CALIFORNIA. CANDIDATE CHEMICALS LIST. SAFER CONSUMER PRODUCTS
REGULATIONS (CAL. CODE REGS, TIT. 22, 69502.3, SUBD. (A)):
1,1,2-TRICHLOROETHYLENE (CAS 79-01-6)
1,2 BUTYLENE OXIDE (CAS 106-88-7)
BUTANONE (CAS 78-93-3)
INTERNATIONAL INVENTORIES:
COUNTRY(S) OR INVENTORY NAME ON INVENTORY
REGION (YES/NO)*
AUSTRALIA AUSTRALIAN INVENTORY OF CHEMICAL YES
SUBSTANCES (AICS)
CANADA DOMESTIC SUBSTANCES LIST (DSL) YES
CANADA NON-DOMESTIC SUBSTANCES LIST (NDSL) NO
CHINA INVENTORY OF EXISTING CHEMICAL YES
SUBSTANCES IN CHINA (IECSC)
EUROPE EUROPEAN INVENTORY OF EXISTING YES
COMMERCIAL CHEMICAL SUBSTANCES
(EINECS)
EUROPE EUROPEAN LIST OF NOTIFIED CHEMICAL NO
SUBSTANCES (ELINCS)
JAPAN INVENTORY OF EXISTING AND NEW YES
CHEMICAL SUBSTANCES (ENCS)
KOREA EXISTING CHEMICALS LIST (ECL) YES
NEW ZEALAND NEW ZEALAND INVENTORY YES
PHILIPPINES PHILIPPINE INVENTORY OF CHEMICALS YES
AND CHEMICAL SUBSTANCES (PICCS)
TAIWAN TAIWAN TOXIC CHEMICAL SUBSTANCES (TCS) YES
UNITED STATES TOXIC SUBSTANCES CONTROL ACT (TSCA) YES
& PUERTO RICO INVENTORY
*A "YES" INDICATES THAT ALL COMPONENTS OF THIS PRODUCT COMPLY WITH THE
INVENTORY REQUIREMENTS ADMINISTERED BY THE GOVERNING COUNTRY (S)
A "NO" INDICATES THAT ONE OR MORE COMPONENTS OF THE PRODUCT ARE NOT LISTED
OR EXEMPT FROM LISTING ON THE INVENTORY ADMINISTERED BY THE GOVERNING
COUNTRY(S).
| 16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION | |
OR LAST REVISION
ISSUE DATE: 10-18-2016
REVISION DATE: 02-19-2018
VERSION #: 02
DISCLAIMER:
ITW PRO BRANDS CANNOT ANTICIPATE ALL CONDITIONS UNDER WHICH THIS
INFORMATION AND ITS PRODUCT, OR THE PRODUCTS OF OTHER MANUFACTURERS IN
COMBINATION WITH ITS PRODUCT, MAY BE USED. IT IS THE USER'S RESPONSIBILITY
TO ENSURE SAFE CONDITIONS FOR HANDLING, STORAGE AND DISPOSAL OF THE
PRODUCT, AND TO ASSUME LIABILITY FOR LOSS, INJURY, DAMAGE OR EXPENSE DUE TO
IMPROPER USE. THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT
TO THE BEST OF OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS
PUBLICATION. THE INFORMATION GIVEN IS DESIGNED ONLY AS A GUIDANCE FOR SAFE
HANDLING, USE, PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE
AND IS NOT TO BE CONSIDERED A WARRANTY OR QUALITY SPECIFICATION. THE
INFORMATION RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE
VALID FOR SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN
ANY PROCESS, UNLESS SPECIFIED IN THE TEXT.
REVISION INFORMATION:
PHYSICAL & CHEMICAL PROPERTIES: MULTIPLE PROPERTIES
MATERIAL NAME: LPS(R*) HDX
SDS: US