| Common Name: | LOCTITE SI 5049CL SILICONE, CLEAR KNOWN AS LOCTITE SUPERFLEX SPEEDSEAL, 1311327 |
| Manufacturer: | HENKEL |
| SDS Revision Date: | 5/16/2019 |
| SDS Format: | GHS-US |
| Item Number(s): | 6JZW7 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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HENKEL
SAFETY DATA SHEET
REVISION NUMBER: 004.0
ISSUE DATE: 05/16/2019
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME:
LOCTITE SI 5049CL SILICONE, CLEAR KNOWN AS LOCTITE(R*) SUPERFLEX(R*)
SPEEDSEAL(TM)
IDH NUMBER: 1311327
ITEM NUMBER: 1311327
PRODUCT TYPE/USE: SILICONE
RESTRICTION OF USE: NONE IDENTIFIED
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: +1 (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
WARNING:
CAUSES SKIN IRRITATION.
CAUSES SERIOUS EYE IRRITATION.
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
HAZARD CLASS HAZARD CATEGORY
SKIN IRRITATION 2
EYE IRRITATION 2A
REPRODUCTIVE TOXICITY 2
PICTOGRAM(S):
HEALTH HAZARD
EXCLAMATION MARK
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. WASH AFFECTED AREA THOROUGHLY
AFTER HANDLING. WEAR PROTECTIVE GLOVES, CLOTHING, EYE AND FACE PROTECTION.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EXPOSED OR CONCERNED: GET MEDICAL ATTENTION.
IF SKIN IRRITATION OCCURS: GET MEDICAL ATTENTION.
IF EYE IRRITATION PERSISTS:
GET MEDICAL ATTENTION. TAKE OFF CONTAMINATED CLOTHING.
STORAGE: STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/PROVINCIAL
AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD
(29 CFR 1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED
NATIONS GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF
CHEMICALS (GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
SILICA, AMORPHOUS, FUMED, CRYSTAL-FREE 112945-52-5 5 - 10
METHYLSILANETRIYL TRIACETATE 4253-34-3 1 - 5
OCTAMETHYLCYCLOTETRASILOXANE 556-67-2 0.1 - 1
* EXACT PERCENTAGES MAY VARY OR ARE TRADE SECRET. CONCENTRATION RANGE IS
PROVIDED TO ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION. IF SYMPTOMS DEVELOP AND PERSIST,
GET MEDICAL ATTENTION.
SKIN CONTACT:
WIPE OFF PASTE WITH PAPER TOWEL OR CLOTH. WASH WITH SOAP AND WATER. IF SKIN
IRRITATION PERSISTS, CALL A PHYSICIAN.
EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS, FOR AT
LEAST 15 MINUTES. IF EYE IRRITATION PERSISTS, CONSULT A SPECIALIST.
INGESTION:
DO NOT INDUCE VOMITING. IF A PERSON FEELS UNWELL OR SYMPTOMS OF SKIN
IRRITATION APPEAR, CONSULT A PHYSICIAN.
SYMPTOMS: SEE SECTION 11.
NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA: FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIREFIGHTING PROCEDURES: NONE
UNUSUAL FIRE OR EXPLOSION HAZARDS: NONE
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF CARBON. OXIDES OF SILICON. FORMALDEHYDE.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOM6MENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS.
CLEAN-UP METHODS:
STORE IN A PARTLY FILLED, CLOSED CONTAINER UNTIL DISPOSAL. SPILLED MATERIAL
WILL SOLIDIFY. SCRAPE UP AS MUCH MATERIAL AS POSSIBLE. MAINTAIN GOOD
VENTILATION FOR LARGE SPILLS.
| 7. HANDLING AND STORAGE | |
HANDLING:
AVOID CONTACT WITH EYES, SKIN AND CLOTHING. DO NOT HANDLE CONTACT LENSES
UNTIL ALL SEALANT HAS BEEN REMOVED FROM HANDS. RESIDUAL SEALANT MAY
TRANSFER TO LENSES AND CAUSE EYE IRRITATION.
STORAGE:
FOR SAFE STORAGE, STORE BETWEEN 0 DEG. C (32 DEG. F) AND 60 DGE. C
(140 DEG. F)
KEEP CONTAINER CLOSED.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE
THE NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL
SILICA, AMORPHOUS, FUMED, CRYSTAL-FREE 10 MG/M3 TWA 20 MPPCF TWA
INHALABLE DUST. 0.8 MG/M3 TWA
3 MG/M3 TWA
RESPIRABLE FRACTION.
METHYLSILANETRIYL TRIACETATE NONE NONE
OCTAMETHYLCYCLOTETRASILOXANE NONE NONE
HAZARDOUS COMPONENT(S) AIHA WEEL OTHER
SILICA, AMORPHOUS, FUMED, CRYSTAL-FREE NONE NONE
METHYLSILANETRIYL TRIACETATE NONE NONE
OCTAMETHYLCYCLOTETRASILOXANE 10 PPM TWA NONE
ENGINEERING CONTROLS:
ENSURE ADEQUATE VENTILATION, ESPECIALLY IN CONFINED AREAS. USE LOCAL
VENTILATION IF GENERAL VENTILATION IS INSUFFICIENT TO MAINTAIN VAPOR
CONCENTRATION BELOW ESTABLISHED EXPOSURE LIMITS.
RESPIRATORY PROTECTION:
USE NIOSH APPROVED RESPIRATOR IF THERE IS POTENTIAL TO EXCEED EXPOSURE
LIMIT(S).
EYE/FACE PROTECTION: SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS.
SKIN PROTECTION: CHEMICAL RESISTANT, IMPERMEABLE GLOVES.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID OR PASTE
COLOR: CLEAR
ODOR: ACETIC ACID
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
VAPOR PRESSURE: <10 MMHg (20 DEG. C (68 DEG. F))
BOILING POINT/RANGE: NOT AVAILABLE.
MELTING POINT/RANGE: NOT AVAILABLE.
SPECIFIC GRAVITY: 1.03 AT 20 DEG. C (68 DEG. F)
VAPOR DENSITY: HEAVIER THAN AIR.
FLASH POINT: >93.0 DEG. C (>199.4 DEG. F)
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: 4 % (ACETIC ACID)
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: 19.9 % (ACETIC ACID)
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
FLAMMABILITY: NOT APPLICABLE
EVAPORATION RATE: NOT AVAILABLE.
SOLUBILITY IN WATER: NOT SOLUBLE. POLYMERIZES IN PRESENCE OF WATER.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT:
2.2%
<40 G/L (CALCULATED)
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER NORMAL CONDITIONS OF STORAGE AND USE.
HAZARDOUS REACTIONS: WILL NOT OCCUR.
HAZARDOUS DECOMPOSITION PRODUCTS:
OXIDES OF CARBON. OXIDES OF SILICON. FORMALDEHYDE. ACETIC ACID IS LIBERATED
SLOWLY UPON CONTACT WITH MOISTURE.
INCOMPATIBLE MATERIALS: WATER. BASES. OXIDIZING AGENTS. ACIDS.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID:
PROLONGED HEATING AT TEMPERATURES ABOVE 150 DEG. C. EXPOSURE TO MOISTURE.
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES, INGESTION
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION:
ACETIC ACID PRODUCED DURING CURE MAY IRRITATE EYES, NOSE AND THROAT. WHEN
HEATED TO TEMPERATURES EXCEEDING 300 DEG. F (150 DEG. C) IN THE PRESENCE OF
AIR, SILICONES MAY FORM FORMALDEHYDE VAPORS. FORMALDEHYDE IS A POTENTIAL
CANCER HAZARD AND A KNOWN SKIN AND RESPIRATORY SENSITIZER. VAPORS IRRITATE
THE EYES, NOSE AND THROAT. SAFE HANDLING CONDITIONS MAY BE MAINTAINED BY
KEEPING FORMALDEHYDE VAPOR CONCENTRATIONS BELOW THE OSHA PERMISSIBLE LIMIT.
SKIN CONTACT: CAUSES SKIN IRRITATION.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INGESTION:
NOT EXPECTED UNDER NORMAL CONDITIONS OF USE. MAY CAUSE GASTROINTESTINAL
TRACT IRRITATION IF SWALLOWED.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED
HEALTH EFFECTS
SILICA, AMORPHOUS, FUMED, NONE NUISANCE DUST
CRYSTAL-FREE
METHYLSILANETRIYL TRIACETATE NONE IRRITANT, ALLERGEN
OCTAMETHYLCYCLOTETRASILOXANE NONE IRRITANT
HAZARDOUS COMPONENT(S) NTP CARCINOGEN IARC CARCINOGEN OSHA CARCINOGEN
(SPECIFICALLY
REGULATED)
SILICA, AMORPHOUS, FUMED, NO NO NO
CRYSTAL-FREE
METHYLSILANETRIYL NO NO NO
TRIACETATE
OCTAMETHYLCYCLOTETRA- NO NO NO
SILOXANE
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
CURED RUBBER CAN BE INCINERATED OR LANDFILLED FOLLOWING EPA AND LOCAL
REGULATIONS.
HAZARDOUS WASTE NUMBER: NOT A RCRA HAZARDOUS WASTE.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE
MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8(B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT INVENTORY.
TSCA 12(B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS.
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH
CERCLA/SARA SECTION 313: NONE ABOVE REPORTING DE MINIMIS.
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE
CANCER.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ONE OR MORE COMPONENTS ARE NOT LISTED ON, AND ARE NOT EXEMPT FROM LISTING
ON EITHER THE DOMESTIC SUBSTANCES LIST OR THE NON-DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: 2
PREPARED BY: PRODUCT SAFETY AND REGULATORY AFFAIRS
ISSUE DATE: 05/16/2019
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
('HENKEL') DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE OF
ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE OR
USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.
THIS SAFETY DATA SHEET HAS BEEN GENERATED BASED ON OSHA HAZARD
COMMUNICATION STANDARD (29 CFR 1910.1200) AND PROVIDES INFORMATION IN
ACCORDANCE WITH U.S. FEDERAL LAW ONLY. NO WARRANTY OR REPRESENTATION OF ANY
KIND IS GIVEN WITH RESPECT TO THE SUBSTANTIVE OR EXPORT LAWS OF ANY OTHER
JURISDICTION OR COUNTRY. PLEASE CONFIRM THAT THE INFORMATION PROVIDED
HEREIN CONFORMS TO THE SUBSTANTIVE EXPORT OR OTHER LAW OF ANY OTHER
JURISDICTION PRIOR TO EXPORT. PLEASE CONTACT HENKEL PRODUCT SAFETY AND
REGULATORY AFFAIRS FOR ADDITIONAL ASSISTANCE.