| Common Name: | SP010 CLEAR RTV SILICONE SEALANT |
| Manufacturer: | SPRAYON PRODUCTS GROUP |
| SDS Revision Date: | 11/28/2019 |
| SDS Format: | GHS-US |
| Item Number(s): | 6KDT3 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
SC0010000
| SECTION 1. IDENTIFICATION |  |
PRODUCT NAME: SP(TM)010 CLEAR RTV SILICONE SEALANT
PRODUCT CODE: SC0010000
OTHER MEANS OF IDENTIFICATION: NOT AVAILABLE.
PRODUCT TYPE: SPRAY
RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
PAINT OR PAINT RELATED MATERIAL.
MANUFACTURER:
SPRAYON PRODUCTS GROUP
101 W. PROSPECT AVENUE,
CLEVELAND, OHIO 44115
EMERGENCY TELEPHONE NUMBER OF THE COMPANY:
US / CANADA: (800) 424-9300
MEXICO:
SETIQ: 01-800-00-214-00 / (52) 55-5559-1588 24 HOURS / 365 DAYS A YEAR
PRODUCT INFORMATION TELEPHONE NUMBER:
US / CANADA: (800) 247-3266
MEXICO: NOT AVAILABLE
REGULATORY INFORMATION TELEPHONE NUMBER:
US / CANADA: (216) 566-2902
MEXICO: NOT AVAILABLE
TRANSPORTATION EMERGENCY TELEPHONE NUMBER:
US / CANADA: (800) 424-9300
MEXICO:
SETIQ: 01-800-00-214-00 / (52) 55-5559-1588 24 HOURS / 365 DAYS A YEAR
| SECTION 2. HAZARDS IDENTIFICATION | |
OSHA/HCS STATUS:
THIS MATERIAL IS CONSIDERED HAZARDOUS BY THE OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200).
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
FLAMMABLE AEROSOLS: CATEGORY 1
GASES UNDER PRESSURE: COMPRESSED GAS
SKIN CORROSION/IRRITATION: CATEGORY 1B
SERIOUS EYE DAMAGE/ EYE IRRITATION: CATEGORY 1
TOXIC TO REPRODUCTION (FERTILITY): CATEGORY 2
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 2
PERCENTAGE OF THE MIXTURE CONSISTING OF INGREDIENT(S) OF UNKNOWN ACUTE
ORAL TOXICITY: 6.9%
PERCENTAGE OF THE MIXTURE CONSISTING OF INGREDIENT(S) OF UNKNOWN ACUTE
DERMAL TOXICITY: 12.6%
PERCENTAGE OF THE MIXTURE CONSISTING OF INGREDIENT(S) OF UNKNOWN ACUTE
INHALATION TOXICITY: 12.6%
GHS LABEL ELEMENTS:
HAZARD PICTOGRAMS:
FLAME
GAS CYLINDER
CORROSION
HEALTH HAZARD
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
EXTREMELY FLAMMABLE AEROSOL.
CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
SUSPECTED OF DAMAGING FERTILITY.
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. WEAR PROTECTIVE GLOVES. WEAR
EYE OR FACE PROTECTION. WEAR PROTECTIVE CLOTHING. KEEP AWAY FROM HEAT,
HOT SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION SOURCES. NO SMOKING.
DO NOT SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE. DO NOT BREATHE
VAPOR. WASH HANDS THOROUGHLY AFTER HANDLING. PRESSURIZED CONTAINER: DO
NOT PIERCE OR BURN, EVEN AFTER USE.
RESPONSE:
GET MEDICAL ATTENTION IF YOU FEEL UNWELL.
IF EXPOSED OR CONCERNED: GET MEDICAL ATTENTION.
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. IMMEDIATELY
CALL A POISON CENTER OR PHYSICIAN.
IF SWALLOWED:
IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN. RINSE MOUTH. DO NOT INDUCE
VOMITING.
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH WATER OR
SHOWER. WASH CONTAMINATED CLOTHING BEFORE REUSE. IMMEDIATELY CALL A POISON
CENTER OR PHYSICIAN.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING. IMMEDIATELY CALL A POISON
CENTER OR PHYSICIAN.
STORAGE:
STORE LOCKED UP. PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES
EXCEEDING 50 DEG. C/122 DEG. F. STORE IN A WELL-VENTILATED PLACE.
DISPOSAL:
DISPOSE OF CONTENTS AND CONTAINER IN ACCORDANCE WITH ALL LOCAL, REGIONAL,
NATIONAL AND INTERNATIONAL REGULATIONS.
SUPPLEMENTAL LABEL ELEMENTS:
DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. CONTAINS SOLVENTS WHICH CAN
CAUSE PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY
DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS CAN BE HARMFUL OR
FATAL. FOR INDUSTRIAL USE ONLY.
PLEASE REFER TO THE SDS FOR ADDITIONAL INFORMATION. KEEP OUT OF REACH OF
CHILDREN. KEEP UPRIGHT IN A COOL, DRY PLACE. DO NOT DISCARD EMPTY CAN IN
TRASH COMPACTOR.
HAZARDS NOT OTHERWISE CLASSIFIED: NONE KNOWN.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE/MIXTURE: MIXTURE
OTHER MEANS OF IDENTIFICATION: NOT AVAILABLE.
CAS NUMBER/OTHER IDENTIFIERS:
INGREDIENT NAME % BY WEIGHT CAS NUMBER
| OCTAMETHYLCYCLOTETRASILOXANE >/=25 - </=30 556-67-2
AMORPHOUS SILICA </=10 7631-86-9
1,1-DIFLUOROETHANE </=5 75-37-6
MIDDLE PETROLEUM DISTILLATES </=3 64742-46-7
ETHYL TRIACETOXYSILANE </=3 17689-77-9
METHYL TRIACETOXYSILANE </=3 4253-34-3
ANY CONCENTRATION SHOWN AS A RANGE IS TO PROTECT CONFIDENTIALITY
OR IS DUE TO BATCH VARIATION.
THERE ARE NO ADDITIONAL INGREDIENTS PRESENT WHICH, WITHIN THE CURRENT
KNOWLEDGE OF THE SUPPLIER AND IN THE CONCENTRATIONS APPLICABLE, ARE
CLASSIFIED AS HAZARDOUS TO HEALTH AND HENCE REQUIRE REPORTING IN THIS
SECTION.
OCCUPATIONAL EXPOSURE LIMITS, IF AVAILABLE, ARE LISTED IN SECTION 8.
| SECTION 4. FIRST AID MEASURES | |
DESCRIPTION OF NECESSARY FIRST AID MEASURES:
EYE CONTACT:
GET MEDICAL ATTENTION IMMEDIATELY. CALL A POISON CENTER OR PHYSICIAN.
CHEMICAL BURNS MUST BE TREATED PROMPTLY BY A PHYSICIAN.
INHALATION:
GET MEDICAL ATTENTION IMMEDIATELY. CALL A POISON CENTER OR PHYSICIAN. IF
IT IS SUSPECTED THAT FUMES ARE STILL PRESENT, THE RESCUER SHOULD WEAR AN
APPROPRIATE MASK OR SELF-CONTAINED BREATHING APPARATUS. IT MAY BE DANGEROUS
TO THE PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH RESUSCITATION. IN CASE
OF INHALATION OF DECOMPOSITION PRODUCTS IN A FIRE, SYMPTOMS MAY BE DELAYED.
THE EXPOSED PERSON MAY NEED TO BE KEPT UNDER MEDICAL SURVEILLANCE FOR
48 HOURS.
SKIN CONTACT:
GET MEDICAL ATTENTION IMMEDIATELY. CALL A POISON CENTER OR PHYSICIAN. WASH
CONTAMINATED CLOTHING THOROUGHLY WITH WATER BEFORE REMOVING IT, OR WEAR
GLOVES. CONTINUE TO RINSE FOR AT LEAST 10 MINUTES. CHEMICAL BURNS MUST BE
TREATED PROMPTLY BY A PHYSICIAN.
INGESTION:
GET MEDICAL ATTENTION IMMEDIATELY. CALL A POISON CENTER OR PHYSICIAN.
CHEMICAL BURNS MUST BE TREATED PROMPTLY BY A PHYSICIAN.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
INHALATION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SKIN CONTACT: CAUSES SEVERE BURNS.
INGESTION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
OVER-EXPOSURE SIGNS/SYMPTOMS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN
WATERING
REDNESS
INHALATION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN OR IRRITATION
REDNESS
BLISTERING MAY OCCUR
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
INGESTION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
STOMACH PAINS
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED, IF NECESSARY:
NOTES TO PHYSICIAN:
IN CASE OF INHALATION OF DECOMPOSITION PRODUCTS IN A FIRE, SYMPTOMS
MAY BE DELAYED. THE EXPOSED PERSON MAY NEED TO BE KEPT UNDER MEDICAL
SURVEILLANCE FOR 48 HOURS.
SPECIFIC TREATMENTS: NO SPECIFIC TREATMENT.
PROTECTION OF FIRST-AIDERS:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. IF IT IS SUSPECTED THAT FUMES ARE STILL PRESENT, THE RESCUER
SHOULD WEAR AN APPROPRIATE MASK OR SELF-CONTAINED BREATHING APPARATUS.
IT MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH
RESUSCITATION. WASH CONTAMINATED CLOTHING THOROUGHLY WITH WATER
BEFORE REMOVING IT, OR WEAR GLOVES.
SEE TOXICOLOGICAL INFORMATION (SECTION 11)
| SECTION 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE AN EXTINGUISHING AGENT SUITABLE FOR THE SURROUNDING FIRE.
UNSUITABLE EXTINGUISHING MEDIA: NONE KNOWN.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
EXTREMELY FLAMMABLE AEROSOL. RUNOFF TO SEWER MAY CREATE FIRE OR EXPLOSION
HAZARD. IN A FIRE OR IF HEATED, A PRESSURE INCREASE WILL OCCUR AND THE
CONTAINER MAY BURST, WITH THE RISK OF A SUBSEQUENT EXPLOSION. GAS MAY
ACCUMULATE IN LOW OR CONFINED AREAS OR TRAVEL A CONSIDERABLE DISTANCE
TO A SOURCE OF IGNITION AND FLASH BACK, CAUSING FIRE OR EXPLOSION. BURSTING
AEROSOL CONTAINERS MAY BE PROPELLED FROM A FIRE AT HIGH SPEED.
HAZARDOUS THERMAL DECOMPOSITION PRODUCTS:
DECOMPOSITION PRODUCTS MAY INCLUDE THE FOLLOWING MATERIALS:
CARBON DIOXIDE
CARBON MONOXIDE
HALOGENATED COMPOUNDS
CARBONYL HALIDES
METAL OXIDE/OXIDES
SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
PROMPTLY ISOLATE THE SCENE BY REMOVING ALL PERSONS FROM THE VICINITY OF
THE INCIDENT IF THERE IS A FIRE. NO ACTION SHALL BE TAKEN INVOLVING ANY
PERSONAL RISK OR WITHOUT SUITABLE TRAINING. MOVE CONTAINERS FROM FIRE
AREA IF THIS CAN BE DONE WITHOUT RISK. USE WATER SPRAY TO KEEP
FIRE-EXPOSED CONTAINERS COOL.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
FOR NON-EMERGENCY PERSONNEL:
IN THE CASE OF AEROSOLS BEING RUPTURED, CARE SHOULD BE TAKEN DUE TO THE
RAPID ESCAPE OF THE PRESSURIZED CONTENTS AND PROPELLANT. IF A LARGE NUMBER
OF CONTAINERS ARE RUPTURED, TREAT AS A BULK MATERIAL SPILLAGE ACCORDING TO
THE INSTRUCTIONS IN THE CLEAN-UP SECTION. SHUT OFF ALL IGNITION SOURCES.
NO FLARES, SMOKING OR FLAMES IN HAZARD AREA.
FOR EMERGENCY RESPONDERS:
IF SPECIALIZED CLOTHING IS REQUIRED TO DEAL WITH THE SPILLAGE, TAKE NOTE OF
ANY INFORMATION IN SECTION 8 ON SUITABLE AND UNSUITABLE MATERIALS. SEE ALSO
THE INFORMATION IN "FOR NON-EMERGENCY PERSONNEL".
ENVIRONMENTAL PRECAUTIONS: NO SPECIFIC HAZARD.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SMALL SPILL: USE SPARK-PROOF TOOLS AND EXPLOSION-PROOF EQUIPMENT.
LARGE SPILL:
USE SPARK-PROOF TOOLS AND EXPLOSION-PROOF EQUIPMENT.
NOTE:
SEE SECTION 1 FOR EMERGENCY CONTACT INFORMATION AND SECTION 13 FOR
WASTE DISPOSAL.
| SECTION 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
PROTECTIVE MEASURES:
PRESSURIZED CONTAINER: PROTECT FROM SUNLIGHT AND DO NOT EXPOSE TO
TEMPERATURES EXCEEDING 50 DEG. C. DO NOT PIERCE OR BURN, EVEN AFTER
USE. AVOID EXPOSURE - OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. AVOID
EXPOSURE DURING PREGNANCY. DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS
HAVE BEEN READ AND UNDERSTOOD. DO NOT GET IN EYES OR ON SKIN OR CLOTHING.
USE ONLY WITH ADEQUATE VENTILATION. WEAR APPROPRIATE RESPIRATOR WHEN
VENTILATION IS INADEQUATE. STORE AND USE AWAY FROM HEAT, SPARKS, OPEN
FLAME OR ANY OTHER IGNITION SOURCE. USE EXPLOSION-PROOF ELECTRICAL
(VENTILATING, LIGHTING AND MATERIAL HANDLING) EQUIPMENT. USE ONLY
NON-SPARKING TOOLS.
ADVICE ON GENERAL OCCUPATIONAL HYGIENE:
WORKERS SHOULD WASH HANDS AND FACE BEFORE EATING, DRINKING AND SMOKING.
REMOVE CONTAMINATED CLOTHING AND PROTECTIVE EQUIPMENT BEFORE ENTERING
EATING AREAS. SEE ALSO SECTION 8 FOR ADDITIONAL INFORMATION ON HYGIENE
MEASURES.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE IN ACCORDANCE WITH LOCAL REGULATIONS. PROTECT FROM SUNLIGHT. STORE
LOCKED UP. ELIMINATE ALL IGNITION SOURCES. SEE SECTION 10 FOR INCOMPATIBLE
MATERIALS BEFORE HANDLING OR USE.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS (OSHA UNITED STATES):
INGREDIENT NAME CAS # EXPOSURE LIMITS
| OCTAMETHYLCYCLOTETRASILOXANE 556-67-2 AIHA WEEL (UNITED STATES,
| 7/2018).
TWA: 10 PPM 8 HOURS.
AMORPHOUS SILICA 7631-86-9 NIOSH REL (UNITED STATES,
10/2016).
TWA: 6 MG/M3 10 HOURS.
1,1-DIFLUOROETHANE 75-37-6 AIHA WEEL (UNITED STATES,
7/2018).
TWA: 1000 PPM 8 HOURS.
ACGIH TLV (UNITED STATES,
3/2019).
TWA:
2.5 MG/M3, (AS F) 8 HOURS.
OSHA PEL Z2 (UNITED STATES,
2/2013).
TWA: 2.5 MG/M3 8 HOURS.
FORM: DUST
OSHA PEL (UNITED STATES,
5/2018).
TWA:
2.5 MG/M3, (AS F) 8 HOURS.
MIDDLE PETROLEUM DISTILLATES 64742-46-7 NIOSH REL (UNITED STATES,
10/2016).
TWA: 5 MG/M3 10 HOURS.
FORM: MIST
STEL: 10 MG/M3 15 MINUTES.
FORM: MIST
ETHYL TRIACETOXYSILANE 17689-77-9 NONE.
METHYL TRIACETOXYSILANE 4253-34-3 NONE.
OCCUPATIONAL EXPOSURE LIMITS (CANADA):
INGREDIENT NAME CAS # EXPOSURE LIMITS
| OCTAMETHYLCYCLOTETRASILOXANE 556-67-2 AIHA WEEL (UNITED STATES,
| 7/2018).
TWA: 10 PPM 8 HOURS.
MIDDLE PETROLEUM DISTILLATES 64742-46-7 CA ALBERTA PROVINCIAL
(CANADA, 6/2018).
8 HRS OEL: 5 MG/M3 8 HOURS.
FORM: MIST
15 MIN OEL:
10 MG/M3 15 MINUTES.
FORM: MIST
CA QUEBEC PROVINCIAL
(CANADA, 1/2014).
TWAEV: 5 MG/M3 8 HOURS.
FORM: MIST
STEV: 10 MG/M3 15 MINUTES.
FORM: MIST
OCCUPATIONAL EXPOSURE LIMITS (MEXICO):
CAS # EXPOSURE LIMITS
| MIDDLE PETROLEUM DISTILLATES 64742-46-7 NOM-010-STPS-2014
| (MEXICO, 4/2016).
TWA: 5 MG/M3 8 HOURS.
FORM: MIST
APPROPRIATE ENGINEERING CONTROLS:
IF USER OPERATIONS GENERATE DUST, FUMES, GAS, VAPOR OR MIST, USE
PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION OR OTHER ENGINEERING
CONTROLS TO KEEP WORKER EXPOSURE TO AIRBORNE CONTAMINANTS BELOW ANY
RECOMMENDED OR STATUTORY LIMITS. THE ENGINEERING CONTROLS ALSO NEED
TO KEEP GAS, VAPOR OR DUST CONCENTRATIONS BELOW ANY LOWER EXPLOSIVE
LIMITS. USE EXPLOSION-PROOF VENTILATION EQUIPMENT.
ENVIRONMENTAL EXPOSURE CONTROLS:
EMISSIONS FROM VENTILATION OR WORK PROCESS EQUIPMENT SHOULD BE CHECKED
TO ENSURE THEY COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION
LEGISLATION. IN SOME CASES, FUME SCRUBBERS, FILTERS OR ENGINEERING
MODIFICATIONS TO THE PROCESS EQUIPMENT WILL BE NECESSARY TO REDUCE
EMISSIONS TO ACCEPTABLE LEVELS.
INDIVIDUAL PROTECTION MEASURES:
HYGIENE MEASURES:
WASH HANDS, FOREARMS AND FACE THOROUGHLY AFTER HANDLING CHEMICAL PRODUCTS,
BEFORE EATING, SMOKING AND USING THE LAVATORY AND AT THE END OF THE WORKING
PERIOD. APPROPRIATE TECHNIQUES SHOULD BE USED TO REMOVE POTENTIALLY
CONTAMINATED CLOTHING. WASH CONTAMINATED CLOTHING BEFORE REUSING. ENSURE
THAT EYEWASH STATIONS AND SAFETY SHOWERS ARE CLOSE TO THE WORKSTATION
LOCATION.
EYE/FACE PROTECTION:
SAFETY EYEWEAR COMPLYING WITH AN APPROVED STANDARD SHOULD BE USED WHEN A
RISK ASSESSMENT INDICATES THIS IS NECESSARY TO AVOID EXPOSURE TO LIQUID
SPLASHES, MISTS, GASES OR DUSTS. IF CONTACT IS POSSIBLE, THE FOLLOWING
PROTECTION SHOULD BE WORN, UNLESS THE ASSESSMENT INDICATES A HIGHER DEGREE
OF PROTECTION: CHEMICAL SPLASH GOGGLES AND/ OR FACE SHIELD. IF INHALATION
HAZARDS EXIST, A FULL-FACE RESPIRATOR MAY BE REQUIRED INSTEAD.
SKIN PROTECTION:
HAND PROTECTION:
BODY PROTECTION:
PERSONAL PROTECTIVE EQUIPMENT FOR THE BODY SHOULD BE SELECTED BASED ON THE
TASK BEING PERFORMED AND THE RISKS INVOLVED AND SHOULD BE APPROVED BY A
SPECIALIST BEFORE HANDLING THIS PRODUCT. WHEN THERE IS A RISK OF IGNITION
FROM STATIC ELECTRICITY, WEAR ANTISTATIC PROTECTIVE CLOTHING. FOR THE
GREATEST PROTECTION FROM STATIC DISCHARGES, CLOTHING SHOULD INCLUDE
ANTI-STATIC OVERALLS, BOOTS AND GLOVES.
OTHER SKIN PROTECTION:
APPROPRIATE FOOTWEAR AND ANY ADDITIONAL SKIN PROTECTION MEASURES SHOULD
BE SELECTED BASED ON THE TASK BEING PERFORMED AND THE RISKS INVOLVED AND
SHOULD BE APPROVED BY A SPECIALIST BEFORE HANDLING THIS PRODUCT.
RESPIRATORY PROTECTION:
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: LIQUID.
COLOR: NOT AVAILABLE.
ODOR: NOT AVAILABLE.
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
MELTING POINT/FREEZING POINT: NOT AVAILABLE.
BOILING POINT/BOILING RANGE: NOT AVAILABLE.
FLASH POINT:
CLOSED CUP: -29 DEG. C (-20.2 DEG. F) [PENSKY-MARTENS CLOSED CUP]
EVAPORATION RATE: NOT AVAILABLE.
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE.
LOWER AND UPPER EXPLOSIVE (FLAMMABLE) LIMITS:
LOWER: 0.75%
UPPER: 16.9%
VAPOR PRESSURE: 101.3 KPA (760 MM HG) [AT 20 DEG. C]
VAPOR DENSITY: 2.4 [AIR = 1]
RELATIVE DENSITY: 1.01
SOLUBILITY: NOT AVAILABLE.
PARTITION COEFFICIENT N-OCTANOL/WATER: NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY:
KINEMATIC: (40 DEG. C (104 DEG. F)): >0.205 CM2/S (>20.5 CST)
MOLECULAR WEIGHT: NOT APPLICABLE.
AEROSOL PRODUCT:
TYPE OF AEROSOL: SPRAY
HEAT OF COMBUSTION: 3.823 KJ/G
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY:
NO SPECIFIC TEST DATA RELATED TO REACTIVITY AVAILABLE FOR THIS PRODUCT
OR ITS INGREDIENTS.
CHEMICAL STABILITY: THE PRODUCT IS STABLE.
POSSIBILITY OF HAZARDOUS REACTIONS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS REACTIONS WILL
NOT OCCUR.
CONDITIONS TO AVOID:
AVOID ALL POSSIBLE SOURCES OF IGNITION (SPARK OR FLAME).
INCOMPATIBLE MATERIALS: NO SPECIFIC DATA.
HAZARDOUS DECOMPOSITION PRODUCTS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS DECOMPOSITION
PRODUCTS SHOULD NOT BE PRODUCED.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
PRODUCT/INGREDIENT RESULT SPECIES DOSE EXPOSURE
NAME
| OCTAMETHYLCYCLOT- LC50 RAT 36 G/M3 4 HOURS
| ETRASILOXANE INHALATION
| VAPOR
LD50 DERMAL RAT 1770 MG/KG
LD50 ORAL RAT 1540 MG/KG
METHYL LD50 ORAL RAT 2060 MG/KG
TRIACETOXYSILANE
IRRITATION/CORROSION:
PRODUCT/INGREDIENT RESULT SPECIES SCORE EXPOSURE OBSERVATION
NAME
| OCTAMETHYLCYCLO- EYES - MILD RABBIT 24 HOURS
| TETRASILOXANE IRRITANT 500 MG
SKIN - MILD RABBIT 24 HOURS
IRRITANT 500 MG
AMORPHOUS SILICA EYES - MILD RABBIT 24 HOURS
IRRITANT 25 MG
SENSITIZATION: NOT AVAILABLE.
MUTAGENICITY: NOT AVAILABLE.
CARCINOGENICITY: NOT AVAILABLE.
CLASSIFICATION:
PRODUCT/INGREDIENT NAME OSHA IARC NTP
AMORPHOUS SILICA 3
REPRODUCTIVE TOXICITY: NOT AVAILABLE.
TERATOGENICITY: NOT AVAILABLE.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE):
NAME CATEGORY ROUTE OF EXPOSURE TARGET ORGANS
| 1,1-DIFLUOROETHANE CATEGORY 3 NOT APPLICABLE. NARCOTIC EFFECTS
CATEGORY 3 NOT APPLICABLE. RESPIRATORY TRACT
IRRITATION
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE):
NAME CATEGORY ROUTE OF EXPOSURE TARGET ORGANS
1,1-DIFLUOROETHANE CATEGORY 2 NOT DETERMINED NOT DETERMINED
ASPIRATION HAZARD:
NAME RESULT
MIDDLE PETROLEUM DISTILLATES ASPIRATION HAZARD - CATEGORY 1
INFORMATION ON THE LIKELY ROUTES OF EXPOSURE: NOT AVAILABLE.
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
INHALATION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SKIN CONTACT: CAUSES SEVERE BURNS.
INGESTION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN
WATERING
REDNESS
INHALATION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN OR IRRITATION
REDNESS
BLISTERING MAY OCCUR
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
INGESTION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
STOMACH PAINS
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
DELAYED AND IMMEDIATE EFFECTS AND ALSO CHRONIC EFFECTS FROM SHORT AND
LONG TERM EXPOSURE:
SHORT TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE.
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE.
LONG TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE.
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE.
POTENTIAL CHRONIC HEALTH EFFECTS: NOT AVAILABLE.
GENERAL: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
CARCINOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
MUTAGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
TERATOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
DEVELOPMENTAL EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
FERTILITY EFFECTS: SUSPECTED OF DAMAGING FERTILITY.
NUMERICAL MEASURES OF TOXICITY:
ACUTE TOXICITY ESTIMATES:
ROUTE ATE VALUE
| ORAL 3176.62 MG/KG
DERMAL 5030.22 MG/KG
| SECTION 12. ECOLOGICAL INFORMATION | |
TOXICITY:
PRODUCT/INGREDIENT RESULT SPECIES EXPOSURE
NAME
| OCTAMETHYLCYCLO- ACUTE LC50 >1000 FISH - ONCORHYNCHUS 4 DAYS
| TETRASILOXANE PPM FRESH WATER MYKISS
CHRONIC NOEC 1 TO ALGAE - 96 HOURS
29 (MICRO)G/L PSEUDOKIRCHNERIELLA
SUBCAPITATA
CHRONIC NOEC 7.9 DAPHNIA - DAPHNIA 21 DAYS
(MICRO)G/L FRESH MAGNA
WATER
CHRONIC NOEC 4.4 FISH - ONCORHYNCHUS 93 DAYS
(MICRO)G/L FRESH MYKISS - EGG
WATER
PERSISTENCE AND DEGRADABILITY: NOT AVAILABLE.
BIOACCUMULATIVE POTENTIAL:
PRODUCT/INGREDIENT NAME LOGPOW BCF POTENTIAL
| OCTAMETHYLCYCLOTETRASILOXANE 13400 HIGH
MOBILITY IN SOIL:
SOIL/WATER PARTITION COEFFICIENT (KOC): NOT AVAILABLE.
OTHER ADVERSE EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
THE GENERATION OF WASTE SHOULD BE AVOIDED OR MINIMIZED WHEREVER POSSIBLE.
DISPOSAL OF THIS PRODUCT, SOLUTIONS AND ANY BY-PRODUCTS SHOULD AT ALL TIMES
COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION AND WASTE DISPOSAL
LEGISLATION AND ANY REGIONAL LOCAL AUTHORITY REQUIREMENTS. DISPOSE OF
SURPLUS AND NON-RECYCLABLE PRODUCTS VIA A LICENSED WASTE DISPOSAL
CONTRACTOR. WASTE SHOULD NOT BE DISPOSED OF UNTREATED TO THE SEWER UNLESS
FULLY COMPLIANT WITH THE REQUIREMENTS OF ALL AUTHORITIES WITH JURISDICTION.
WASTE PACKAGING SHOULD BE RECYCLED. INCINERATION OR LANDFILL SHOULD ONLY BE
CONSIDERED WHEN RECYCLING IS NOT FEASIBLE. THIS MATERIAL AND ITS CONTAINER
MUST BE DISPOSED OF IN A SAFE WAY. EMPTY CONTAINERS OR LINERS MAY RETAIN
SOME PRODUCT RESIDUES.
| SECTION 14. TRANSPORT INFORMATION | |
DOT TDG MEXICO
CLASSIFICATION CLASSIFICATION CLASSIFICATION
UN NUMBER UN1950 UN1950 UN1950
UN PROPER AEROSOLS AEROSOLS AEROSOLS
SHIPPING NAME
TRANSPORT 2.2 2.2 2.2
HAZARD CLASS(ES)
NON-FLAMMABLE GAS, CLASS 2.2, CLASS 2.2,
CLASS/DIVISION 2.2 NON-FLAMMABLE NON-FLAMMABLE
AND NON-TOXIC AND NON-TOXIC
GASES GASES
PACKING GROUP
ENVIRONMENTAL NO. NO. NO.
HAZARDS
ADDITIONAL PRODUCT CLASSIFIED
INFORMATION AS PER THE
FOLLOWING SECTIONS
OF THE
TRANSPORTATION OF
DANGEROUS GOODS
REGULATIONS: 2.
13-2.17 (CLASS 2).
ERG NO.: 126 ERG NO.: 126 ERG NO.: 126
IATA IMDG
UN NUMBER UN1950 UN1950
UN PROPER AEROSOLS, NON-FLAMMABLE AEROSOLS
SHIPPING NAME
TRANSPORT 2.2 2.2
HAZARD CLASS(ES)
CLASS 2.2, CLASS 2.2 -
NON-FLAMMABLE NON-FLAMMABLE
AND NON-TOXIC GASES
GASES
PACKING GROUP
ENVIRONMENTAL NO. NO.
HAZARDS
ADDITIONAL EMERGENCY SCHEDULES
INFORMATION (EMS): F-D, S-U
SPECIAL PRECAUTIONS FOR USER:
MULTI-MODAL SHIPPING DESCRIPTIONS ARE PROVIDED FOR INFORMATIONAL PURPOSES
AND DO NOT CONSIDER CONTAINER SIZES. THE PRESENCE OF A SHIPPING DESCRIPTION
FOR A PARTICULAR MODE OF TRANSPORT (SEA, AIR, ETC.), DOES NOT INDICATE THAT
THE PRODUCT IS PACKAGED SUITABLY FOR THAT MODE OF TRANSPORT. ALL PACKAGING
MUST BE REVIEWED FOR SUITABILITY PRIOR TO SHIPMENT, AND COMPLIANCE WITH THE
APPLICABLE REGULATIONS IS THE SOLE RESPONSIBILITY OF THE PERSON OFFERING
THE PRODUCT FOR TRANSPORT. PEOPLE LOADING AND UNLOADING DANGEROUS GOODS
MUST BE TRAINED ON ALL OF THE RISKS DERIVING FROM THE SUBSTANCES AND ON
ALL ACTIONS IN CASE OF EMERGENCY SITUATIONS.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL AND THE IBC CODE:
NOT AVAILABLE.
PROPER SHIPPING NAME: NOT AVAILABLE.
SHIP TYPE: NOT AVAILABLE.
POLLUTION CATEGORY: NOT AVAILABLE.
| SECTION 15. REGULATORY INFORMATION | |
SARA 313:
SARA 313 (40 CFR 372.45) SUPPLIER NOTIFICATION CAN BE FOUND ON THE
ENVIRONMENTAL DATA SHEET.
CALIFORNIA PROP. 65: NOT APPLICABLE.
INTERNATIONAL REGULATIONS:
| INTERNATIONAL LISTS:
| AUSTRALIA INVENTORY (AICS): NOT DETERMINED.
CHINA INVENTORY (IECSC): NOT DETERMINED.
JAPAN INVENTORY (ENCS): NOT DETERMINED.
JAPAN INVENTORY (ISHL): NOT DETERMINED.
KOREA INVENTORY (KECI): NOT DETERMINED.
NEW ZEALAND INVENTORY OF CHEMICALS (NZIOC): NOT DETERMINED.
PHILIPPINES INVENTORY (PICCS): NOT DETERMINED.
TAIWAN CHEMICAL SUBSTANCES INVENTORY (TCSI): NOT DETERMINED.
THAILAND INVENTORY: NOT DETERMINED.
TURKEY INVENTORY: NOT DETERMINED.
VIETNAM INVENTORY: NOT DETERMINED.
| SECTION 16. OTHER INFORMATION | |
HAZARDOUS MATERIAL INFORMATION SYSTEM (U.S.A.):
HEALTH 3*
| FLAMMABILITY 3
PHYSICAL HAZARDS 3
THE CUSTOMER IS RESPONSIBLE FOR DETERMINING THE PPE CODE FOR THIS MATERIAL.
FOR MORE INFORMATION ON HMIS(R*) PERSONAL PROTECTIVE EQUIPMENT (PPE) CODES,
CONSULT THE HMIS(R*) IMPLEMENTATION MANUAL.
CAUTION:
HMIS(R*) RATINGS ARE BASED ON A 0-4 RATING SCALE, WITH 0 REPRESENTING
MINIMAL HAZARDS OR RISKS, AND 4 REPRESENTING SIGNIFICANT HAZARDS OR RISKS.
ALTHOUGH HMIS(R*) RATINGS AND THE ASSOCIATED LABEL ARE NOT REQUIRED ON
SDSS OR PRODUCTS LEAVING A FACILITY UNDER 29 CFR 1910.1200, THE PREPARER
MAY CHOOSE TO PROVIDE THEM. HMIS(R*) RATINGS ARE TO BE USED WITH A FULLY
IMPLEMENTED HMIS(R*) PROGRAM. HMIS(R*) IS A REGISTERED TRADEMARK AND
SERVICE MARK OF THE AMERICAN COATINGS ASSOCIATION, INC.
PROCEDURE USED TO DERIVE THE CLASSIFICATION:
CLASSIFICATION JUSTIFICATION
FLAMMABLE AEROSOLS: CATEGORY 1 ON BASIS OF TEST DATA
GASES UNDER PRESSURE: COMPRESSED GAS CALCULATION METHOD
SKIN CORROSION/IRRITATION: CATEGORY 1B CALCULATION METHOD
SERIOUS EYE DAMAGE/ EYE IRRITATION: CATEGORY 1 CALCULATION METHOD
TOXIC TO REPRODUCTION (FERTILITY): CATEGORY 2 CALCULATION METHOD
SPECIFIC TARGET ORGAN TOXICITY (REPEATED CALCULATION METHOD
EXPOSURE): CATEGORY 2
HISTORY:
DATE OF PRINTING: 11/28/2019
DATE OF ISSUE/DATE OF REVISION: 11/28/2019
DATE OF PREVIOUS ISSUE: 7/5/2018
VERSION: 7
KEY TO ABBREVIATIONS:
ATE = ACUTE TOXICITY ESTIMATE
BCF = BIOCONCENTRATION FACTOR
GHS = GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELLING OF
CHEMICALS
IATA = INTERNATIONAL AIR TRANSPORT ASSOCIATION
IBC = INTERMEDIATE BULK CONTAINER
IMDG = INTERNATIONAL MARITIME DANGEROUS GOODS
LOGPOW = LOGARITHM OF THE OCTANOL/WATER PARTITION COEFFICIENT
MARPOL = INTERNATIONAL CONVENTION FOR THE PREVENTION OF POLLUTION FROM
SHIPS, 1973 AS MODIFIED BY THE PROTOCOL OF 1978. ("MARPOL" = MARINE
POLLUTION)
N/A = NOT AVAILABLE
SGG = SEGREGATION GROUP
UN = UNITED NATIONS
| INDICATES INFORMATION THAT HAS CHANGED FROM PREVIOUSLY ISSUED VERSION.
NOTICE TO READER:
IT IS RECOMMENDED THAT EACH CUSTOMER OR RECIPIENT OF THIS SAFETY DATA SHEET
(SDS) STUDY IT CAREFULLY AND CONSULT RESOURCES, AS NECESSARY OR
APPROPRIATE, TO BECOME AWARE OF AND UNDERSTAND THE DATA CONTAINED IN THIS
SDS AND ANY HAZARDS ASSOCIATED WITH THE PRODUCT. THIS INFORMATION IS
PROVIDED IN GOOD FAITH AND BELIEVED TO BE ACCURATE AS OF THE EFFECTIVE DATE
HEREIN. HOWEVER, NO WARRANTY, EXPRESS OR IMPLIED, IS GIVEN. THE INFORMATION
PRESENTED HERE APPLIES ONLY TO THE PRODUCT AS SHIPPED. THE ADDITION OF ANY
MATERIAL CAN CHANGE THE COMPOSITION, HAZARDS AND RISKS OF THE PRODUCT.
PRODUCTS SHALL NOT BE REPACKAGED, MODIFIED, OR TINTED EXCEPT AS
SPECIFICALLY INSTRUCTED BY THE MANUFACTURER, INCLUDING BUT NOT LIMITED TO
THE INCORPORATION OF PRODUCTS NOT SPECIFIED BY THE MANUFACTURER, OR THE USE
OR ADDITION OF PRODUCTS IN PROPORTIONS NOT SPECIFIED BY THE MANUFACTURER.
REGULATORY REQUIREMENTS ARE SUBJECT TO CHANGE AND MAY DIFFER BETWEEN
VARIOUS LOCATIONS AND JURISDICTIONS. THE CUSTOMER/BUYER/USER IS RESPONSIBLE
TO ENSURE THAT HIS ACTIVITIES COMPLY WITH ALL COUNTRY, FEDERAL, STATE,
PROVINCIAL OR LOCAL LAWS. THE CONDITIONS FOR USE OF THE PRODUCT ARE NOT
UNDER THE CONTROL OF THE MANUFACTURER; THE CUSTOMER/BUYER/USER IS
RESPONSIBLE TO DETERMINE THE CONDITIONS NECESSARY FOR THE SAFE USE OF THIS
PRODUCT. THE CUSTOMER/BUYER/USER SHOULD NOT USE THE PRODUCT FOR ANY PURPOSE
OTHER THAN THE PURPOSE SHOWN IN THE APPLICABLE SECTION OF THIS SDS WITHOUT
FIRST REFERRING TO THE SUPPLIER AND OBTAINING WRITTEN HANDLING
INSTRUCTIONS. DUE TO THE PROLIFERATION OF SOURCES FOR INFORMATION SUCH AS
MANUFACTURER-SPECIFIC SDS, THE MANUFACTURER CANNOT BE RESPONSIBLE FOR SDSS
OBTAINED FROM ANY OTHER SOURCE.
SHW-85-NA-GHS-US