| Common Name: | SPINNERETTE MR VERTICAL |
| Manufacturer: | SPRAYON PRODUCTS GROUP |
| SDS Revision Date: | 9/23/2021 |
| SDS Format: | GHS-US |
| Item Number(s): | 6KDU0 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
A00522000
| SECTION 1. IDENTIFICATION |  |
PRODUCT NAME: SPRAYON(R*) SPINNERETTE MR VERTICAL
PRODUCT CODE: A00522000
OTHER MEANS OF IDENTIFICATION: NOT AVAILABLE.
PRODUCT TYPE: AEROSOL.
RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST PAINT OR PAINT: RELATED MATERIAL.
MANUFACTURER:
SPRAYON PRODUCTS GROUP
101 W. PROSPECT AVENUE
CLEVELAND, OH 44115
EMERGENCY TELEPHONE NUMBER OF THE COMPANY:
US / CANADA: (800) 424-9300
MEXICO:
SETIQ 800-00-214-00 / 55-5559-1588 AVAILABLE 24 HOURS AND 365 DAYS A YEAR
PRODUCT INFORMATION TELEPHONE NUMBER:
US / CANADA: (800) 251-2486
MEXICO: NOT AVAILABLE
REGULATORY INFORMATION TELEPHONE NUMBER:
US / CANADA: (216) 566-2902
MEXICO: NOT AVAILABLE
TRANSPORTATION EMERGENCY TELEPHONE NUMBER:
US / CANADA: (800) 424-9300
MEXICO:
SETIQ 800-00-214-00 / 55-5559-1588 AVAILABLE 24 HOURS AND 365 DAYS A YEAR
| SECTION 2. HAZARDS IDENTIFICATION | |
OSHA/HCS STATUS:
THIS MATERIAL IS CONSIDERED HAZARDOUS BY THE OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200).
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
FLAMMABLE AEROSOLS: CATEGORY 1
GASES UNDER PRESSURE: COMPRESSED GAS SKIN
CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2A
CARCINOGENICITY: CATEGORY 2
TOXIC TO REPRODUCTION: CATEGORY 1B
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (RESPIRATORY TRACT
IRRITATION): CATEGORY 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (NARCOTIC EFFECTS):
CATEGORY 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 2
PERCENTAGE OF THE MIXTURE CONSISTING OF INGREDIENT(S) OF UNKNOWN ACUTE
TOXICITY: 40% (ORAL), 88.2% (DERMAL), 49.4% (INHALATION)
GHS LABEL ELEMENTS:
HAZARD PICTOGRAMS:
FLAME
GAS CYLINDER
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
EXTREMELY FLAMMABLE AEROSOL.
CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
CAUSES SKIN IRRITATION.
CAUSES SERIOUS EYE IRRITATION.
MAY CAUSE RESPIRATORY IRRITATION.
MAY CAUSE DROWSINESS OR DIZZINESS.
SUSPECTED OF CAUSING CANCER.
MAY DAMAGE FERTILITY OR THE UNBORN CHILD.
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. WEAR PROTECTIVE GLOVES,
PROTECTIVE CLOTHING AND EYE OR FACE PROTECTION. KEEP AWAY FROM HEAT, HOT
SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION SOURCES. NO SMOKING. DO
NOT SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE. USE ONLY OUTDOORS OR
IN A WELL-VENTILATED AREA. DO NOT BREATHE DUST OR MIST. WASH THOROUGHLY
AFTER HANDLING. PRESSURIZED CONTAINER: DO NOT PIERCE OR BURN, EVEN AFTER
USE.
RESPONSE:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE OR ATTENTION.
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER OR DOCTOR IF YOU FEEL UNWELL. TAKE OFF CONTAMINATED CLOTHING
AND WASH IT BEFORE REUSE.
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE OR ATTENTION.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE OR ATTENTION.
STORAGE
STORE LOCKED UP. PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES
EXCEEDING 50 DEG. C/122 DEG. F. STORE IN A WELL-VENTILATED PLACE. KEEP
CONTAINER TIGHTLY CLOSED.
DISPOSAL:
DISPOSE OF CONTENTS AND CONTAINER IN ACCORDANCE WITH ALL LOCAL, REGIONAL,
NATIONAL AND INTERNATIONAL REGULATIONS.
SUPPLEMENTAL LABEL ELEMENTS:
DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. CONTAINS SOLVENTS WHICH CAN
CAUSE PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY
DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS CAN BE HARMFUL OR
FATAL.
WARNING:
THIS PRODUCT CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM. FOR INDUSTRIAL USE
ONLY. PLEASE REFER TO THE SDS FOR ADDITIONAL INFORMATION. KEEP OUT OF REACH
OF CHILDREN. KEEP UPRIGHT IN A COOL, DRY PLACE. DO NOT DISCARD EMPTY CAN IN
TRASH COMPACTOR.
HAZARDS NOT OTHERWISE CLASSIFIED: NONE KNOWN.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE/MIXTURE: MIXTURE
OTHER MEANS OF IDENTIFICATION: NOT AVAILABLE.
CAS NUMBER/OTHER IDENTIFIERS:
INGREDIENT NAME % BY WEIGHT CAS NUMBER
N-PROPYL BROMIDE >/=25 - </=50 106-94-5
1,1,1,2-TETRAFLUOROETHANE >/=25 - </=50 811-97-2
1-PROPANOL </=2.5 71-23-8
ETHYLOXIRANE </=0.3 106-88-7
ANY CONCENTRATION SHOWN AS A RANGE IS TO PROTECT CONFIDENTIALITY OR IS DUE
TO BATCH VARIATION.
THERE ARE NO ADDITIONAL INGREDIENTS PRESENT WHICH, WITHIN THE CURRENT
KNOWLEDGE OF THE SUPPLIER AND IN THE CONCENTRATIONS APPLICABLE, ARE
CLASSIFIED AND HENCE REQUIRE REPORTING IN THIS SECTION.
OCCUPATIONAL EXPOSURE LIMITS, IF AVAILABLE, ARE LISTED IN SECTION 8.
| SECTION 4. FIRST AID MEASURES | |
DESCRIPTION OF NECESSARY FIRST AID MEASURES:
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER, OCCASIONALLY LIFTING THE UPPER
AND LOWER EYELIDS. CHECK FOR AND REMOVE ANY CONTACT LENSES. CONTINUE TO
RINSE FOR AT LEAST 10 MINUTES. GET MEDICAL ATTENTION.
INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. IF IT IS SUSPECTED THAT FUMES ARE STILL PRESENT, THE RESCUER
SHOULD WEAR AN APPROPRIATE MASK OR SELF-CONTAINED BREATHING APPARATUS. IF
NOT BREATHING, IF BREATHING IS IRREGULAR OR IF RESPIRATORY ARREST OCCURS,
PROVIDE ARTIFICIAL RESPIRATION OR OXYGEN BY TRAINED PERSONNEL. IT MAY BE
DANGEROUS TO THE PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH RESUSCITATION.
GET MEDICAL ATTENTION. IF NECESSARY, CALL A POISON CENTER OR PHYSICIAN. IF
UNCONSCIOUS, PLACE IN RECOVERY POSITION AND GET MEDICAL ATTENTION
IMMEDIATELY. MAINTAIN AN OPEN AIRWAY. LOOSEN TIGHT CLOTHING SUCH AS A
COLLAR, TIE, BELT OR WAISTBAND. IN CASE OF INHALATION OF DECOMPOSITION
PRODUCTS IN A FIRE, SYMPTOMS MAY BE DELAYED. THE EXPOSED PERSON MAY NEED TO
BE KEPT UNDER MEDICAL SURVEILLANCE FOR 48 HOURS.
SKIN CONTACT:
FLUSH CONTAMINATED SKIN WITH PLENTY OF WATER. REMOVE CONTAMINATED CLOTHING
AND SHOES. WASH CONTAMINATED CLOTHING THOROUGHLY WITH WATER BEFORE REMOVING
IT, OR WEAR GLOVES. CONTINUE TO RINSE FOR AT LEAST 10 MINUTES. GET MEDICAL
ATTENTION. WASH CLOTHING BEFORE REUSE. CLEAN SHOES THOROUGHLY BEFORE REUSE.
INGESTION:
| WASH OUT MOUTH WITH WATER. REMOVE DENTURES IF ANY. IF MATERIAL HAS BEEN
| SWALLOWED AND THE EXPOSED PERSON IS CONSCIOUS, GIVE SMALL QUANTITIES OF
| WATER TO DRINK. STOP IF THE EXPOSED PERSON FEELS SICK AS VOMITING MAY BE
| DANGEROUS. DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL
| PERSONNEL. IF VOMITING OCCURS, THE HEAD SHOULD BE KEPT LOW SO THAT VOMIT
| DOES NOT ENTER THE LUNGS. GET MEDICAL ATTENTION. IF NECESSARY, CALL A
| POISON CENTER OR PHYSICIAN. NEVER GIVE ANYTHING BY MOUTH TO AN
| UNCONSCIOUS PERSON. IF UNCONSCIOUS, PLACE IN RECOVERY POSITION AND GET
| MEDICAL ATTENTION IMMEDIATELY. MAINTAIN AN OPEN AIRWAY. LOOSEN TIGHT
| CLOTHING SUCH AS A COLLAR, TIE, BELT OR WAISTBAND.
MOST IMPORTANT SYMPTOMS/EFFECTS ACUTE AND DELAYED:
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INHALATION:
CAN CAUSE CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION. MAY CAUSE DROWSINESS OR
DIZZINESS. MAY CAUSE RESPIRATORY IRRITATION.
SKIN CONTACT: CAUSES SKIN IRRITATION.
INGESTION: CAN CAUSE CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION.
OVER-EXPOSURE SIGNS/SYMPTOMS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN OR IRRITATION
WATERING
REDNESS
INHALATION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
RESPIRATORY TRACT IRRITATION
COUGHING
NAUSEA OR VOMITING
HEADACHE
DROWSINESS/FATIGUE
DIZZINESS/VERTIGO
UNCONSCIOUSNESS
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
IRRITATION
REDNESS
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
INGESTION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED, IF
NECESSARY:
NOTES TO PHYSICIAN:
IN CASE OF INHALATION OF DECOMPOSITION PRODUCTS IN A FIRE, SYMPTOMS MAY BE
DELAYED. THE EXPOSED PERSON MAY NEED TO BE KEPT UNDER MEDICAL SURVEILLANCE
FOR 48 HOURS.
SPECIFIC TREATMENTS: NO SPECIFIC TREATMENT.
PROTECTION OF FIRST-AIDERS:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. IF IT IS SUSPECTED THAT FUMES ARE STILL PRESENT, THE RESCUER
SHOULD WEAR AN APPROPRIATE MASK OR SELF-CONTAINED BREATHING APPARATUS. IT
MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH
RESUSCITATION. WASH CONTAMINATED CLOTHING THOROUGHLY WITH WATER BEFORE
REMOVING IT, OR WEAR GLOVES.
SEE TOXICOLOGICAL INFORMATION (SECTION 11)
| SECTION 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE AN EXTINGUISHING AGENT SUITABLE FOR THE SURROUNDING FIRE.
UNSUITABLE EXTINGUISHING MEDIA: NONE KNOWN.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
EXTREMELY FLAMMABLE AEROSOL. RUNOFF TO SEWER MAY CREATE FIRE OR EXPLOSION
HAZARD. IN A FIRE OR IF HEATED, A PRESSURE INCREASE WILL OCCUR AND THE
CONTAINER MAY BURST, WITH THE RISK OF A SUBSEQUENT EXPLOSION. GAS MAY
ACCUMULATE IN LOW OR CONFINED AREAS OR TRAVEL A CONSIDERABLE DISTANCE TO A
SOURCE OF IGNITION AND FLASH BACK, CAUSING FIRE OR EXPLOSION. BURSTING
AEROSOL CONTAINERS MAY BE PROPELLED FROM A FIRE AT HIGH SPEED.
HAZARDOUS THERMAL DECOMPOSITION PRODUCTS:
DECOMPOSITION PRODUCTS MAY INCLUDE THE FOLLOWING MATERIALS:
CARBON DIOXIDE
CARBON MONOXIDE
HALOGENATED COMPOUNDS
CARBONYL HALIDES
SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
PROMPTLY ISOLATE THE SCENE BY REMOVING ALL PERSONS FROM THE VICINITY OF
THE INCIDENT IF THERE IS A FIRE. NO ACTION SHALL BE TAKEN INVOLVING ANY
PERSONAL RISK OR WITHOUT SUITABLE TRAINING. MOVE CONTAINERS FROM FIRE AREA
IF THIS CAN BE DONE WITHOUT RISK. USE WATER SPRAY TO KEEP FIRE-EXPOSED
CONTAINERS COOL.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
FIRE-FIGHTERS SHOULD WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND
SELF-CONTAINED BREATHING APPARATUS (SCBA) WITH A FULL FACE-PIECE OPERATED
IN POSITIVE PRESSURE MODE.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
FOR NON-EMERGENCY PERSONNEL:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. EVACUATE SURROUNDING AREAS. KEEP UNNECESSARY AND UNPROTECTED
PERSONNEL FROM ENTERING. IN THE CASE OF AEROSOLS BEING RUPTURED, CARE
SHOULD BE TAKEN DUE TO THE RAPID ESCAPE OF THE PRESSURIZED CONTENTS AND
PROPELLANT. IF A LARGE NUMBER OF CONTAINERS ARE RUPTURED, TREAT AS A BULK
MATERIAL SPILLAGE ACCORDING TO THE INSTRUCTIONS IN THE CLEAN-UP SECTION. DO
NOT TOUCH OR WALK THROUGH SPILLED MATERIAL. SHUT OFF ALL IGNITION SOURCES.
NO FLARES, SMOKING OR FLAMES IN HAZARD AREA. AVOID BREATHING VAPOR OR MIST.
PROVIDE ADEQUATE VENTILATION. WEAR APPROPRIATE RESPIRATOR WHEN VENTILATION
IS INADEQUATE. PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT.
FOR EMERGENCY RESPONDERS:
IF SPECIALIZED CLOTHING IS REQUIRED TO DEAL WITH THE SPILLAGE, TAKE NOTE OF
ANY INFORMATION IN SECTION 8 ON SUITABLE AND UNSUITABLE MATERIALS. SEE ALSO
THE INFORMATION IN "FOR NON-EMERGENCY PERSONNEL".
ENVIRONMENTAL PRECAUTIONS:
AVOID DISPERSAL OF SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL,
WATERWAYS, DRAINS AND SEWERS. INFORM THE RELEVANT AUTHORITIES IF THE
PRODUCT HAS CAUSED ENVIRONMENTAL POLLUTION (SEWERS, WATERWAYS, SOIL OR
AIR).
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SMALL SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. USE SPARK-PROOF
TOOLS AND EXPLOSION-PROOF EQUIPMENT. DILUTE WITH WATER AND MOP UP IF
WATER-SOLUBLE. ALTERNATIVELY, OR IF WATER-INSOLUBLE, ABSORB WITH AN INERT
DRY MATERIAL AND PLACE IN AN APPROPRIATE WASTE DISPOSAL CONTAINER. DISPOSE
OF VIA A LICENSED WASTE DISPOSAL CONTRACTOR.
LARGE SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. USE SPARK-PROOF
TOOLS AND EXPLOSION-PROOF EQUIPMENT. APPROACH RELEASE FROM UPWIND. PREVENT
ENTRY INTO SEWERS, WATER COURSES, BASEMENTS OR CONFINED AREAS. WASH
SPILLAGES INTO AN EFFLUENT TREATMENT PLANT OR PROCEED AS FOLLOWS. CONTAIN
AND COLLECT SPILLAGE WITH NON-COMBUSTIBLE, ABSORBENT MATERIAL E.G. SAND,
EARTH, VERMICULITE OR DIATOMACEOUS EARTH AND PLACE IN CONTAINER FOR
DISPOSAL ACCORDING TO LOCAL REGULATIONS (SEE SECTION 13). DISPOSE OF VIA A
LICENSED WASTE DISPOSAL CONTRACTOR. CONTAMINATED ABSORBENT MATERIAL MAY
POSE THE SAME HAZARD AS THE SPILLED PRODUCT.
NOTE:
SEE SECTION 1 FOR EMERGENCY CONTACT INFORMATION AND SECTION 13 FOR WASTE
DISPOSAL.
| SECTION 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
PROTECTIVE MEASURES:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8).
PRESSURIZED CONTAINER: PROTECT FROM SUNLIGHT AND DO NOT EXPOSE TO
TEMPERATURES EXCEEDING 50 DEG. C. DO NOT PIERCE OR BURN, EVEN AFTER USE.
AVOID EXPOSURE - OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. AVOID EXPOSURE
DURING PREGNANCY. DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN
READ AND UNDERSTOOD. DO NOT GET IN EYES OR ON SKIN OR CLOTHING. DO NOT
BREATHE VAPOR OR MIST. DO NOT INGEST. AVOID BREATHING GAS. USE ONLY WITH
ADEQUATE VENTILATION. WEAR APPROPRIATE RESPIRATOR WHEN VENTILATION IS
INADEQUATE. STORE AND USE AWAY FROM HEAT, SPARKS, OPEN FLAME OR ANY OTHER
IGNITION SOURCE. USE EXPLOSION-PROOF ELECTRICAL (VENTILATING, LIGHTING AND
MATERIAL HANDLING) EQUIPMENT. USE ONLY NON-SPARKING TOOLS. EMPTY
CONTAINERS RETAIN PRODUCT RESIDUE AND CAN BE HAZARDOUS.
ADVICE ON GENERAL OCCUPATIONAL HYGIENE:
EATING, DRINKING AND SMOKING SHOULD BE PROHIBITED IN AREAS WHERE THIS
MATERIAL IS HANDLED, STORED AND PROCESSED. WORKERS SHOULD WASH HANDS AND
FACE BEFORE EATING, DRINKING AND SMOKING. REMOVE CONTAMINATED CLOTHING AND
PROTECTIVE EQUIPMENT BEFORE ENTERING EATING AREAS. SEE ALSO SECTION 8 FOR
ADDITIONAL INFORMATION ON HYGIENE MEASURES.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE IN ACCORDANCE WITH LOCAL REGULATIONS. STORE AWAY FROM DIRECT SUNLIGHT
IN A DRY, COOL AND WELL-VENTILATED AREA, AWAY FROM INCOMPATIBLE MATERIALS
(SEE SECTION 10) AND FOOD AND DRINK. PROTECT FROM SUNLIGHT. STORE LOCKED
UP. ELIMINATE ALL IGNITION SOURCES. USE APPROPRIATE CONTAINMENT TO AVOID
ENVIRONMENTAL CONTAMINATION. SEE SECTION 10 FOR INCOMPATIBLE MATERIALS
BEFORE HANDLING OR USE.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS (OSHA UNITED STATES):
INGREDIENT NAME CAS # EXPOSURE LIMITS
| N-PROPYL BROMIDE 106-94-5 ACGIH TLV (UNITED STATES, 1/2021).
TWA: 0.1 PPM 8 HOURS.
1,1,1,2-TETRAFLUOROETHANE 811-97-2 OSHA PEL Z2 (UNITED STATES, 2/2013).
TWA: 2.5 MG/M3 8 HOURS.
FORM: DUST
OARS WEEL (UNITED STATES, 1/2021).
TWA: 1000 PPM 8 HOURS.
ACGIH TLV (UNITED STATES, 1/2021).
TWA: 2.5 MG/M3, (AS F) 8 HOURS.
OSHA PEL (UNITED STATES, 5/2018).
TWA: 2.5 MG/M3, (AS F) 8 HOURS.
1-PROPANOL 71-23-8 NIOSH REL (UNITED STATES, 10/2020).
ABSORBED THROUGH SKIN.
TWA: 200 PPM 10 HOURS.
TWA: 500 MG/M3 10 HOURS.
STEL: 250 PPM 15 MINUTES.
STEL: 625 MG/M3 15 MINUTES.
OSHA PEL (UNITED STATES, 5/2018).
TWA: 200 PPM 8 HOURS.
TWA: 500 MG/M3 8 HOURS.
ACGIH TLV (UNITED STATES, 1/2021).
TWA: 100 PPM 8 HOURS.
1,2-EPOXYBUTANE 106-88-7 OARS WEEL (UNITED STATES, 1/2021).
TWA: 2 PPM 8 HOURS.
OCCUPATIONAL EXPOSURE LIMITS (MEXICO):
INGREDIENT NAME CAS # EXPOSURE LIMITS
| N-PROPYL BROMIDE 106-94-5 CA BRITISH COLUMBIA PROVINCIAL
| (CANADA, 1/2021).
TWA: 0.1 PPM 8 HOURS.
CA ONTARIO PROVINCIAL (CANADA,
6/2019).
TWA: 0.1 PPM 8 HOURS.
CA SASKATCHEWAN PROVINCIAL (CANADA,
7/2013).
STEL: 20 PPM 15 MINUTES.
TWA: 10 PPM 8 HOURS.
N-PROPYL ALCOHOL 71-23-8 CA ALBERTA PROVINCIAL (CANADA,
6/2018).
8 HRS OEL: 492 MG/M3 8 HOURS.
15 MIN OEL: 984 MG/M3 15 MINUTES.
15 MIN OEL: 400 PPM 15 MINUTES.
8 HRS OEL: 200 PPM 8 HOURS.
CA BRITISH COLUMBIA PROVINCIAL
(CANADA, 1/2021).
TWA: 100 PPM 8 HOURS.
CA ONTARIO PROVINCIAL (CANADA,
6/2019).
TWA: 100 PPM 8 HOURS.
CA QUEBEC PROVINCIAL (CANADA,
7/2019).
ABSORBED THROUGH SKIN.
TWAEV: 200 PPM 8 HOURS.
TWAEV: 492 MG/M3 8 HOURS.
STEV: 250 PPM 15 MINUTES.
STEV: 614 MG/M3 15 MINUTES.
CA SASKATCHEWAN PROVINCIAL (CANADA,
7/2013).
STEL: 400 PPM 15 MINUTES.
TWA: 200 PPM 8 HOURS.
1,2-EPOXYBUTANE 106-88-7 OARS WEEL (UNITED STATES, 1/2021).
TWA: 2 PPM 8 HOURS.
OCCUPATIONAL EXPOSURE LIMITS (MEXICO):
CAS # EXPOSURE LIMITS
N-PROPYL BROMIDE 106-94-5 NOM-010-STPS-2014 (MEXICO, 4/2016).
TWA: 10 PPM 8 HOURS.
N-PROPAN-1-OL 71-23-8 NOM-010-STPS-2014 (MEXICO, 4/2016).
TWA: 100 PPM 8 HOURS.
APPROPRIATE ENGINEERING CONTROLS:
USE ONLY WITH ADEQUATE VENTILATION. USE PROCESS ENCLOSURES, LOCAL EXHAUST
VENTILATION OR OTHER ENGINEERING CONTROLS TO KEEP WORKER EXPOSURE TO
AIRBORNE CONTAMINANTS BELOW ANY RECOMMENDED OR STATUTORY LIMITS. THE
ENGINEERING CONTROLS ALSO NEED TO KEEP GAS, VAPOR OR DUST CONCENTRATIONS
BELOW ANY LOWER EXPLOSIVE LIMITS. USE EXPLOSION-PROOF VENTILATION
EQUIPMENT.
ENVIRONMENTAL EXPOSURE CONTROLS:
EMISSIONS FROM VENTILATION OR WORK PROCESS EQUIPMENT SHOULD BE CHECKED
TO ENSURE THEY COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION
LEGISLATION. IN SOME CASES, FUME SCRUBBERS, FILTERS OR ENGINEERING
MODIFICATIONS TO THE PROCESS EQUIPMENT WILL BE NECESSARY TO REDUCE
EMISSIONS TO ACCEPTABLE LEVELS.
INDIVIDUAL PROTECTION MEASURES:
HYGIENE MEASURES:
WASH HANDS, FOREARMS AND FACE THOROUGHLY AFTER HANDLING CHEMICAL PRODUCTS,
BEFORE EATING, SMOKING AND USING THE LAVATORY AND AT THE END OF THE WORKING
PERIOD. APPROPRIATE TECHNIQUES SHOULD BE USED TO REMOVE POTENTIALLY
CONTAMINATED CLOTHING. WASH CONTAMINATED CLOTHING BEFORE REUSING. ENSURE
THAT EYEWASH STATIONS AND SAFETY SHOWERS ARE CLOSE TO THE WORKSTATION
LOCATION.
EYE/FACE PROTECTION:
SAFETY EYEWEAR COMPLYING WITH AN APPROVED STANDARD SHOULD BE USED WHEN A
RISK ASSESSMENT INDICATES THIS IS NECESSARY TO AVOID EXPOSURE TO LIQUID
SPLASHES, MISTS, GASES OR DUSTS. IF CONTACT IS POSSIBLE, THE FOLLOWING
PROTECTION SHOULD BE WORN, UNLESS THE ASSESSMENT INDICATES A HIGHER DEGREE
OF PROTECTION: CHEMICAL SPLASH GOGGLES.
SKIN PROTECTION:
HAND PROTECTION:
CHEMICAL-RESISTANT, IMPERVIOUS GLOVES COMPLYING WITH AN APPROVED STANDARD
SHOULD BE WORN AT ALL TIMES WHEN HANDLING CHEMICAL PRODUCTS IF A RISK
ASSESSMENT INDICATES THIS IS NECESSARY. CONSIDERING THE PARAMETERS
SPECIFIED BY THE GLOVE MANUFACTURER, CHECK DURING USE THAT THE GLOVES ARE
STILL RETAINING THEIR PROTECTIVE PROPERTIES. IT SHOULD BE NOTED THAT THE
TIME TO BREAKTHROUGH FOR ANY GLOVE MATERIAL MAY BE DIFFERENT FOR DIFFERENT
GLOVE MANUFACTURERS. IN THE CASE OF MIXTURES, CONSISTING OF SEVERAL
SUBSTANCES, THE PROTECTION TIME OF THE GLOVES CANNOT BE ACCURATELY
ESTIMATED.
BODY PROTECTION:
PERSONAL PROTECTIVE EQUIPMENT FOR THE BODY SHOULD BE SELECTED BASED ON THE
TASK BEING PERFORMED AND THE RISKS INVOLVED AND SHOULD BE APPROVED BY A
SPECIALIST BEFORE HANDLING THIS PRODUCT. WHEN THERE IS A RISK OF IGNITION
FROM STATIC ELECTRICITY, WEAR ANTI- STATIC PROTECTIVE CLOTHING. FOR THE
GREATEST PROTECTION FROM STATIC DISCHARGES, CLOTHING SHOULD INCLUDE
ANTI-STATIC OVERALLS, BOOTS AND GLOVES.
OTHER SKIN PROTECTION:
APPROPRIATE FOOTWEAR AND ANY ADDITIONAL SKIN PROTECTION MEASURES SHOULD BE
SELECTED BASED ON THE TASK BEING PERFORMED AND THE RISKS INVOLVED AND
SHOULD BE APPROVED BY A SPECIALIST BEFORE HANDLING THIS PRODUCT.
RESPIRATORY PROTECTION:
BASED ON THE HAZARD AND POTENTIAL FOR EXPOSURE, SELECT A RESPIRATOR THAT
MEETS THE APPROPRIATE STANDARD OR CERTIFICATION. RESPIRATORS MUST BE USED
ACCORDING TO A RESPIRATORY PROTECTION PROGRAM TO ENSURE PROPER FITTING,
TRAINING, AND OTHER IMPORTANT ASPECTS OF USE.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
THE CONDITIONS OF MEASUREMENT OF ALL PROPERTIES ARE AT STANDARD TEMPERATURE
AND PRESSURE UNLESS OTHERWISE INDICATED.
APPEARANCE:
PHYSICAL STATE: LIQUID.
COLOR: NOT AVAILABLE.
ODOR: NOT AVAILABLE.
ODOR THRESHOLD: NOT AVAILABLE.
PH: 7
MELTING POINT/FREEZING POINT: NOT AVAILABLE.
BOILING POINT, INITIAL BOILING POINT, AND BOILING RANGE: NOT AVAILABLE.
FLASH POINT:
CLOSED CUP: NOT APPLICABLE.
EVAPORATION RATE: 1.3 (BUTYL ACETATE = 1)
FLAMMABILITY: NOT AVAILABLE.
LOWER AND UPPER EXPLOSION LIMIT/FLAMMABILITY LIMIT:
LOWER: 2.1%
UPPER: 13.7%
| VAPOR PRESSURE: 101.3 KPA (760 MMHg)
RELATIVE VAPOR DENSITY: 2.1 [AIR = 1]
RELATIVE DENSITY: 1.23
SOLUBILITY: NOT AVAILABLE.
| PARTITION COEFFICIENT N-OCTANOL/WATER: NOT APPLICABLE.
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| VISCOSITY:
| KINEMATIC (40 DEG. C (104 DEG. F)): <20.5 MM2/S (<20.5 CST)
MOLECULAR WEIGHT: NOT APPLICABLE.
AEROSOL PRODUCT:
TYPE OF AEROSOL: SPRAY
HEAT OF COMBUSTION: 0.617 KJ/G
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY:
NO SPECIFIC TEST DATA RELATED TO REACTIVITY AVAILABLE FOR THIS PRODUCT OR
ITS INGREDIENTS.
CHEMICAL STABILITY: THE PRODUCT IS STABLE.
POSSIBILITY OF HAZARDOUS REACTIONS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS REACTIONS WILL NOT
OCCUR.
CONDITIONS TO AVOID:
AVOID ALL POSSIBLE SOURCES OF IGNITION (SPARK OR FLAME).
INCOMPATIBLE MATERIALS: NO SPECIFIC DATA.
HAZARDOUS DECOMPOSITION PRODUCTS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS DECOMPOSITION
PRODUCTS SHOULD NOT BE PRODUCED.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
PRODUCT/INGREDIENT NAME RESULT SPECIES DOSE EXPOSURE
N-PROPYL BROMIDE LD50 ORAL RAT 3600 MG/KG
1,1,1,2-TETRAFLUOROETHANE LC50 INHALATION RAT 1500 G/M3 4 HOURS
VAPOR
1-PROPANOL LD50 DERMAL RABBIT 5040 MG/KG
LD50 ORAL RAT 1870 MG/KG
1,2-EPOXYBUTANE LC50 INHALATION RAT 6300 MG/M3 4 HOURS
VAPOR
LD50 ORAL RAT 500 MG/KG
IRRITATION/CORROSION:
PRODUCT/INGREDIENT RESULT SPECIES SCORE EXPOSURE OBSERVATION
NAME
1-PROPANOL EYES - MODERATE RABBIT 24 HOURS
IRRITANT 20 MG
SKIN - MILD HUMAN 47 HOURS
IRRITANT 100%
SKIN - MILD HUMAN 24 HOURS
IRRITANT 100%
SKIN - MILD RABBIT 500 MG
IRRITANT
1,2-EPOXYBUTANE EYES - MODERATE RABBIT 24 HOURS
IRRITANT 100 MG
SKIN - MILD RABBIT 24 HOURS
IRRITANT 500 MG
SENSITIZATION: NOT AVAILABLE.
MUTAGENICITY: NOT AVAILABLE.
CARCINOGENICITY: NOT AVAILABLE.
CLASSIFICATION:
PRODUCT/INGREDIENT NAME OSHA IARC NTP
N-PROPYL BROMIDE 2B REASONABLY ANTICIPATED TO BE A HUMAN
CARCINOGEN.
1,2-EPOXYBUTANE 2B
REPRODUCTIVE TOXICITY: NOT AVAILABLE.
TERATOGENICITY: NOT AVAILABLE.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE):
NAME CATEGORY ROUTE OF EXPOSURE TARGET ORGANS
N-PROPYL BROMIDE CATEGORY 3 RESPIRATORY TRACT
IRRITATION
CATEGORY 3 NARCOTIC EFFECTS
1,1,1,2-TETRA- CATEGORY 3 RESPIRATORY TRACT
FLUOROETHANE IRRITATION
CATEGORY 3 NARCOTIC EFFECTS
1-PROPANOL CATEGORY 3 RESPIRATORY TRACT
IRRITATION
CATEGORY 3 NARCOTIC EFFECTS
1,2-EPOXYBUTANE CATEGORY 3 RESPIRATORY TRACT
IRRITATION
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE):
NAME CATEGORY ROUTE OF TARGET ORGANS
EXPOSURE
N-PROPYL BROMIDE CATEGORY 2
1,1,1,2-TETRAFLUOROETHANE CATEGORY 2
1-PROPANOL CATEGORY 2
ASPIRATION HAZARD: NOT AVAILABLE.
INFORMATION ON THE LIKELY ROUTES OF EXPOSURE: NOT AVAILABLE.
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INHALATION:
CAN CAUSE CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION. MAY CAUSE DROWSINESS OR
DIZZINESS. MAY CAUSE RESPIRATORY IRRITATION.
SKIN CONTACT: CAUSES SKIN IRRITATION.
INGESTION: CAN CAUSE CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION.
SYMPTOMS RELATED TO THE PHYSICAL. CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN OR IRRITATION
WATERING
REDNESS
INHALATION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
RESPIRATORY TRACT IRRITATION
COUGHING
NAUSEA OR VOMITING
HEADACHE
DROWSINESS/FATIGUE
DIZZINESS/VERTIGO
UNCONSCIOUSNESS
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
IRRITATION
REDNESS
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
INGESTION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
DELAYED AND IMMEDIATE EFFECTS AND ALSO CHRONIC EFFECTS FROM SHORT AND LONG
TERM EXPOSURE:
SHORT TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE.
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE.
LONG TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE.
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE.
POTENTIAL CHRONIC HEALTH EFFECTS: NOT AVAILABLE.
GENERAL:
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
CARCINOGENICITY:
SUSPECTED OF CAUSING CANCER. RISK OF CANCER DEPENDS ON DURATION AND LEVEL
OF EXPOSURE.
MUTAGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
TERATOGENICITY: MAY DAMAGE THE UNBORN CHILD.
DEVELOPMENTAL EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
FERTILITY EFFECTS: MAY DAMAGE FERTILITY.
NUMERICAL MEASURES OF TOXICITY:
ACUTE TOXICITY ESTIMATES:
ROUTE ATE VALUE
ORAL 4272.14 MG/KG
| SECTION 12. ECOLOGICAL INFORMATION | |
TOXICITY:
PRODUCT/INGREDIENT RESULT SPECIES EXPOSURE
NAME
N-PROPYL BROMIDE ACUTE LC50: FISH - PIMEPHALES 96 HOURS
67300 (MICRO)G/L PROMELAS
FRESH WATER
1-PROPANOL ACUTE EC50: ALGAE - SELENASTRUM SP. 96 HOURS
4480000 (MICRO)G/L
FRESH WATER
ACUTE LC50: CRUSTACEANS - GAMMARUS 48 HOURS
1000000 (MICRO)G/L PULEX
FRESH WATER
ACUTE LC50: DAPHNIA - DAPHNIA PULEX 48 HOURS
2950000 (MICRO)G/L
FRESH WATER
ACUTE LC50: FISH - ALBURNUS ALBURNUS 96 HOURS
3800000 (MICRO)G/L
MARINE WATER
PERSISTENCE AND DEGRADABILITY: NOT AVAILABLE.
BIOACCUMULATIVE POTENTIAL: NOT AVAILABLE.
MOBILITY IN SOIL:
SOIL/WATER PARTITION COEFFICIENT (KOC): NOT AVAILABLE.
OTHER ADVERSE EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
THE GENERATION OF WASTE SHOULD BE AVOIDED OR MINIMIZED WHEREVER POSSIBLE.
DISPOSAL OF THIS PRODUCT, SOLUTIONS AND ANY BY-PRODUCTS SHOULD AT ALL TIMES
COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION AND WASTE DISPOSAL
LEGISLATION AND ANY REGIONAL LOCAL AUTHORITY REQUIREMENTS. DISPOSE OF
SURPLUS AND NON-RECYCLABLE PRODUCTS VIA A LICENSED WASTE DISPOSAL
CONTRACTOR. WASTE SHOULD NOT BE DISPOSED OF UNTREATED TO THE SEWER UNLESS
FULLY COMPLIANT WITH THE REQUIREMENTS OF ALL AUTHORITIES WITH JURISDICTION.
WASTE PACKAGING SHOULD BE RECYCLED. INCINERATION OR LANDFILL SHOULD ONLY
BE CONSIDERED WHEN RECYCLING IS NOT FEASIBLE. THIS MATERIAL AND ITS
CONTAINER MUST BE DISPOSED OF IN A SAFE WAY. EMPTY CONTAINERS OR LINERS MAY
RETAIN SOME PRODUCT RESIDUES. DO NOT PUNCTURE OR INCINERATE CONTAINER.
| SECTION 14. TRANSPORT INFORMATION | |
DOT TDG MEXICO
CLASSIFICATION CLASSIFICATION CLASSIFICATION
UN NUMBER UN1950 UN1950 UN1950
UN PROPER AEROSOLS AEROSOLS AEROSOLS
SHIPPING NAME
TRANSPORT 2.2 2.2 2.2
HAZARD CLASS(ES) NON-FLAMMABLE CLASS 2.2, CLASS 2.2,
GAS, CLASS/ NON-FLAMMABLE NON-FLAMMABLE
DIVISION 2.2 AND NON-TOXIC AND NON-TOXIC
GASES GASES
PACKING GROUP
ENVIRONMENTAL NO. NO. NO.
HAZARDS
ADDITIONAL ERG NO.: 126 PRODUCT ERG NO.: 126
INFORMATION CLASSIFIED
AS PER THE
FOLLOWING
SECTIONS OF
THE
TRANSPORTATION
OF DANGEROUS
GOODS
REGULATIONS:
2.13-2.17
(CLASS 2).
ERG NO.: 126
DEPENDENT UPON DEPENDENT UPON DEPENDENT UPON
CONTAINER SIZE, CONTAINER SIZE, CONTAINER SIZE,
THIS PRODUCT THIS PRODUCT THIS PRODUCT
MAY SHIP UNDER MAY SHIP UNDER MAY SHIP UNDER
THE LIMITED THE LIMITED THE LIMITED
QUANTITY QUANTITY QUANTITY
SHIPPING SHIPPING SHIPPING
EXCEPTION. EXCEPTION. EXCEPTION.
IATA IMDG
UN NUMBER UN1950 UN1950
UN PROPER AEROSOLS, NON- AEROSOLS
SHIPPING NAME FLAMMABLE
TRANSPORT 2.2 2.2
HAZARD CLASS(ES) CLASS 2.2 NON- CLASS 2.2 - NON-FLAMMABLE
FLAMMABLE NON- GASES
TOXIC GASES
PACKING GROUP
ENVIRONMENTAL NO. NO.
HAZARDS
ADDITIONAL EMERGENCY SCHEDULES: F-D, S-U
INFORMATION
DEPENDENT UPON DEPENDENT UPON
CONTAINER SIZE, THIS CONTAINER SIZE, THIS
PRODUCT MAY SHIP UNDER PRODUCT MAY SHIP UNDER
THE LIMITED QUANTITY THE LIMITED QUANTITY
SHIPPING EXCEPTION. SHIPPING EXCEPTION.
SPECIAL PRECAUTIONS FOR USER:
MULTI-MODAL SHIPPING DESCRIPTIONS ARE PROVIDED FOR INFORMATIONAL PURPOSES
AND DO NOT CONSIDER CONTAINER SIZES. THE PRESENCE OF A SHIPPING DESCRIPTION
FOR A PARTICULAR MODE OF TRANSPORT (SEA, AIR, ETC.), DOES NOT INDICATE THAT
THE PRODUCT IS PACKAGED SUITABLY FOR THAT MODE OF TRANSPORT. ALL PACKAGING
MUST BE REVIEWED FOR SUITABILITY PRIOR TO SHIPMENT, AND COMPLIANCE WITH THE
APPLICABLE REGULATIONS IS THE SOLE RESPONSIBILITY OF THE PERSON OFFERING
THE PRODUCT FOR TRANSPORT. PEOPLE LOADING AND UNLOADING DANGEROUS GOODS
MUST BE TRAINED ON ALL OF THE RISKS DERIVING FROM THE SUBSTANCES AND ON ALL
ACTIONS IN CASE OF EMERGENCY SITUATIONS.
TRANSPORT IN BULK ACCORDING TO IMO INSTRUMENTS: NOT AVAILABLE.
PROPER SHIPPING NAME: NOT AVAILABLE.
| SECTION 15. REGULATORY INFORMATION | |
TSCA 5(A)2 PROPOSED SIGNIFICANT NEW USE RULES: 1-METHYL-2-PYRROLIDONE
SARA 313:
SARA 313 (40 CFR 372.45) SUPPLIER NOTIFICATION CAN BE FOUND ON THE
ENVIRONMENTAL DATA SHEET.
CALIFORNIA PROP. 65:
WARNING:
THIS PRODUCT CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
INTERNATIONAL REGULATIONS:
INTERNATIONAL LISTS:
AUSTRALIA INVENTORY (AIIC): NOT DETERMINED.
CHINA INVENTORY (IECSC): NOT DETERMINED.
JAPAN INVENTORY (CSCL): NOT DETERMINED.
JAPAN INVENTORY (ISHL): NOT DETERMINED.
KOREA INVENTORY (KECI): NOT DETERMINED.
NEW ZEALAND INVENTORY OF CHEMICALS (NZIOC): NOT DETERMINED.
PHILIPPINES INVENTORY (PICCS): NOT DETERMINED.
TAIWAN CHEMICAL SUBSTANCES INVENTORY (TCSI): NOT DETERMINED.
THAILAND INVENTORY: NOT DETERMINED.
TURKEY INVENTORY: NOT DETERMINED.
VIETNAM INVENTORY: NOT DETERMINED.
| SECTION 16. OTHER INFORMATION | |
HAZARDOUS MATERIAL INFORMATION SYSTEM (U.S.A.):
HEALTH 3*
FLAMMABILITY 2
PHYSICAL HAZARDS 0
THE CUSTOMER IS RESPONSIBLE FOR DETERMINING THE PPE CODE FOR THIS MATERIAL.
FOR MORE INFORMATION ON HMIS(R*) PERSONAL PROTECTIVE EQUIPMENT (PPE) CODES,
CONSULT THE HMIS(R*) IMPLEMENTATION MANUAL.
CAUTION:
HMIS(R*) RATINGS ARE BASED ON A 0-4 RATING SCALE, WITH 0 REPRESENTING
MINIMAL HAZARDS OR RISKS, AND 4 REPRESENTING SIGNIFICANT HAZARDS OR RISKS.
ALTHOUGH HMIS(R*) RATINGS AND THE ASSOCIATED LABEL ARE NOT REQUIRED ON SDSS
OR PRODUCTS LEAVING A FACILITY UNDER 29 CFR 1910.1200, THE PREPARER MAY
CHOOSE TO PROVIDE THEM. HMIS(R*) RATINGS ARE TO BE USED WITH A FULLY
IMPLEMENTED HMIS(R*) PROGRAM. HMIS(R*) IS A REGISTERED TRADEMARK AND
SERVICE MARK OF THE AMERICAN COATINGS ASSOCIATION, INC.
PROCEDURE USED TO DERIVE THE CLASSIFICATION:
CLASSIFICATION JUSTIFICATION
| FLAMMABLE AEROSOLS - CATEGORY 1 ON BASIS OF TEST DATA
GASES UNDER PRESSURE - COMPRESSED GAS CALCULATION METHOD
SKIN CORROSION/IRRITATION - CATEGORY 2 CALCULATION METHOD
SERIOUS EYE DAMAGE/EYE IRRITATION - CATEGORY 2A CALCULATION METHOD
CARCINOGENICITY - CATEGORY 2 CALCULATION METHOD
TOXIC TO REPRODUCTION - CATEGORY 1B CALCULATION METHOD
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) CALCULATION METHOD
(RESPIRATORY TRACT IRRITATION) - CATEGORY 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) CALCULATION METHOD
(NARCOTIC EFFECTS) - CATEGORY 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - CALCULATION METHOD
CATEGORY 2
HISTORY:
DATE OF PRINTING: 9/23/2021
DATE OF ISSUE/DATE OF REVISION: 9/23/2021
DATE OF PREVIOUS ISSUE: 4/16/2021
VERSION: 9.01
KEY TO ABBREVIATIONS:
ATE: ACUTE TOXICITY ESTIMATE
BCF: BIOCONCENTRATION FACTOR
GHS:
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
IBC: INTERMEDIATE BULK CONTAINER
IMDG: INTERNATIONAL MARITIME DANGEROUS GOODS
LOGPOW: LOGARITHM OF THE OCTANOL/WATER PARTITION COEFFICIENT
MARPOL:
INTERNATIONAL CONVENTION FOR THE PREVENTION OF POLLUTION FROM SHIPS, 1973
AS MODIFIED BY THE PROTOCOL OF 1978. ("MARPOL" = MARINE POLLUTION)
N/A = NOT AVAILABLE
SGG: SEGREGATION GROUP
UN: UNITED NATIONS
| INDICATES INFORMATION THAT HAS CHANGED FROM PREVIOUSLY ISSUED VERSION.
NOTICE TO READER:
IT IS RECOMMENDED THAT EACH CUSTOMER OR RECIPIENT OF THIS SAFETY DATA SHEET
(SDS) STUDY IT CAREFULLY AND CONSULT RESOURCES, AS NECESSARY OR
APPROPRIATE, TO BECOME AWARE OF AND UNDERSTAND THE DATA CONTAINED IN THIS
SDS AND ANY HAZARDS ASSOCIATED WITH THE PRODUCT. THIS INFORMATION IS
PROVIDED IN GOOD FAITH AND BELIEVED TO BE ACCURATE AS OF THE EFFECTIVE DATE
HEREIN. HOWEVER, NO WARRANTY, EXPRESS OR IMPLIED, IS GIVEN. THE INFORMATION
PRESENTED HERE APPLIES ONLY TO THE PRODUCT AS SHIPPED. THE ADDITION OF ANY
MATERIAL CAN CHANGE THE COMPOSITION, HAZARDS AND RISKS OF THE PRODUCT.
PRODUCTS SHALL NOT BE REPACKAGED, MODIFIED, OR TINTED EXCEPT AS
SPECIFICALLY INSTRUCTED BY THE MANUFACTURER, INCLUDING BUT NOT LIMITED TO
THE INCORPORATION OF PRODUCTS NOT SPECIFIED BY THE MANUFACTURER, OR THE USE
OR ADDITION OF PRODUCTS IN PROPORTIONS NOT SPECIFIED BY THE MANUFACTURER.
REGULATORY REQUIREMENTS ARE SUBJECT TO CHANGE AND MAY DIFFER BETWEEN
VARIOUS LOCATIONS AND JURISDICTIONS. THE CUSTOMER/BUYER/USER IS RESPONSIBLE
TO ENSURE THAT HIS ACTIVITIES COMPLY WITH ALL COUNTRY, FEDERAL, STATE,
PROVINCIAL OR LOCAL LAWS. THE CONDITIONS FOR USE OF THE PRODUCT ARE NOT
UNDER THE CONTROL OF THE MANUFACTURER; THE CUSTOMER/BUYER/USER IS
RESPONSIBLE TO DETERMINE THE CONDITIONS NECESSARY FOR THE SAFE USE OF THIS
PRODUCT. THE CUSTOMER/BUYER/USER SHOULD NOT USE THE PRODUCT FOR ANY PURPOSE
OTHER THAN THE PURPOSE SHOWN IN THE APPLICABLE SECTION OF THIS SDS WITHOUT
FIRST REFERRING TO THE SUPPLIER AND OBTAINING WRITTEN HANDLING
INSTRUCTIONS. DUE TO THE PROLIFERATION OF SOURCES FOR INFORMATION SUCH AS
MANUFACTURER-SPECIFIC SDS, THE MANUFACTURER CANNOT BE RESPONSIBLE FOR SDSS
OBTAINED FROM ANY OTHER SOURCE.
SHW-85-NA-GHS-US