| Common Name: | MARINE PREMIUM FILLER PN 46004 (PINT); 46005 (QUART); 46006 (GALLON); 46003 (DMS |
| Manufacturer: | 3M |
| SDS Revision Date: | 9/25/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 59LY93, 6KHC8 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
3M(TM) MARINE PREMIUM FILLER PN 46004 (PINT); 46005 (QUART); 46006
(GALLON); 46003 (DMS); 46002 (6 FL. OZ.)
09/25/15
3M
SAFETY DATA SHEET
COPYRIGHT, 2015, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 07-4085-2
VERSION NUMBER: 11.00
ISSUE DATE: 09/25/15
SUPERCEDES DATE: 04/17/15
PRODUCT IDENTIFIER:
3M(TM) MARINE PREMIUM FILLER PN 46004 (PINT); 46005 (QUART); 46006
(GALLON); 46003 (DMS); 46002 (6 FL. OZ.)
ID NUMBER(S):
41-0003-7975-4, 41-0003-7976-2, 60-4550-6497-6, 60-9800-2714-2,
60-9800-2715-9, 60-9800-2716-7
RECOMMENDED USE: MARINE FILLER, MARINE
SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: MARINE & SPECIALTY VEHICLE
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
EMERGENCY TELEPHONE NUMBER: 1-800-364-3577 OR (651) 737-6501 (24 HOURS)
THIS PRODUCT IS A KIT OR A MULTIPART PRODUCT WHICH CONSISTS OF MULTIPLE,
INDEPENDENTLY PACKAGED COMPONENTS. A SAFETY DATA SHEET (SDS), ARTICLE
INFORMATION SHEET (AIS), OR ARTICLE INFORMATION LETTER (AIL) FOR EACH
OF THESE COMPONENTS IS INCLUDED. PLEASE DO NOT SEPARATE THE COMPONENT
DOCUMENTS FROM THIS COVER SHEET.
THE DOCUMENT NUMBERS FOR COMPONENTS OF THIS PRODUCT ARE:
29-5993-0, 07-4083-7
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY
OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED
IN ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
3M USA SDSS ARE AVAILABLE AT WWW.3M.COM
3M(TM) MARINE PREMIUM FILLER, PN 46004 (PINT); 46005 (QUART); 46006
(GALLON) ; 46021 (GALLON); 46002 (6 FL. OZ.)
09/25/15
3M
SAFETY DATA SHEET
COPYRIGHT, 2015, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 07-4083-7
VERSION NUMBER: 16.00
ISSUE DATE: 09/25/15
SUPERCEDES DATE: 04/17/15
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER:
3M(TM) MARINE PREMIUM FILLER, PN 46004 (PINT); 46005 (QUART); 46006
(GALLON); 46021 (GALLON); 46002 (6 FL. OZ.)
PRODUCT IDENTIFICATION NUMBERS:
LB-K100-0825-8, LB-T100-0090-1, LB-T100-0090-2, LB-T100-0090-3,
LB-K100-1036-0, 41-0003-6558-9, 41-3701-1598-6, 41-4901-0120-5,
60-9800-3969-1
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE: AUTOMOTIVE, MARINE FILLER
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: AUTOMOTIVE AFTERMARKET
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
THE LABEL ELEMENTS BELOW WERE PREPARED IN ACCORDANCE WITH OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200. THIS INFORMATION MAY BE DIFFERENT
FROM THE ACTUAL PRODUCT LABEL INFORMATION FOR LABELS REGULATED BY OTHER
AGENCIES.
2.1. HAZARD CLASSIFICATION:
FLAMMABLE LIQUID: CATEGORY 3.
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 2B.
CARCINOGENICITY: CATEGORY 1A.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): CATEGORY 1.
SPECIFIC TARGET ORGAN TOXICITY (CENTRAL NERVOUS SYSTEM): CATEGORY 3.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 1.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS:
FLAME
EXCLAMATION MARK
HEALTH HAZARD
PICTOGRAMS:
FLAME
EXCLAMATION MARK
HEALTH HAZARD
HAZARD STATEMENTS:
FLAMMABLE LIQUID AND VAPOR.
CAUSES EYE IRRITATION.
MAY CAUSE DROWSINESS OR DIZZINESS.
MAY CAUSE CANCER.
CAUSES DAMAGE TO ORGANS:
LIVER
SENSORY ORGANS
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE:
RESPIRATORY SYSTEM
SENSORY ORGANS
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE: LIVER
PRECAUTIONARY STATEMENTS:
GENERAL: KEEP OUT OF REACH OF CHILDREN.
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING.
GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT.
USE ONLY NON-SPARKING TOOLS.
TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
KEEP CONTAINER TIGHTLY CLOSED.
USE EXPLOSION-PROOF ELECTRICAL/VENTILATING/LIGHTING EQUIPMENT.
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
WEAR PROTECTIVE GLOVES AND EYE/FACE PROTECTION.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH THOROUGHLY AFTER HANDLING.
RESPONSE:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO.
CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
IN CASE OF FIRE:
USE A FIRE FIGHTING AGENT SUITABLE FOR FLAMMABLE LIQUIDS SUCH AS DRY
CHEMICAL OR CARBON DIOXIDE TO EXTINGUISH.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
KEEP COOL.
STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
2.3. HAZARDS NOT OTHERWISE CLASSIFIED: NONE.
26% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE ORAL TOXICITY.
26% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE INHALATION
TOXICITY.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
VINYL ESTER RESIN TRADE SECRET* 10 - 30 TRADE SECRET *
STYRENE MONOMER 100-42-5 10 - 30 TRADE SECRET *
LIMESTONE 1317-65-3 10 - 30 TRADE SECRET *
TALC 14807-96-6 5 - 10 TRADE SECRET *
ALUMINA TRIHYDRATE 21645-51-2 5 - 10 TRADE SECRET *
POLYESTER RESIN (PROPRIETARY) TRADE SECRET* 3 - 7 TRADE SECRET *
INERT FILLER TRADE SECRET* 3 - 7 TRADE SECRET *
MAGNESIUM CARBONATE 546-93-0 1 - 5 TRADE SECRET *
SYNTHETIC CRYSTALLINE-FREE 112926-00-8 1 - 5 TRADE SECRET *
SILICA GEL
TITANIUM DIOXIDE 13463-67-7 1 - 5 TRADE SECRET *
SYNTHETIC AMORPHOUS SILICA, 112945-52-5 0.5 - 1.5 TRADE SECRET *
CRYSTALLINE FREE
QUARTZ SILICA 14808-60-7 <0.25 TRADE SECRET *
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION)
OF THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND
WASH BEFORE REUSE. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES.
REMOVE CONTACT LENSES IF EASY TO DO. CONTINUE RINSING. IMMEDIATELY GET
MEDICAL ATTENTION.
IF SWALLOWED: RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
IN CASE OF FIRE:
USE A FIRE FIGHTING AGENT SUITABLE FOR FLAMMABLE LIQUIDS SUCH AS DRY
CHEMICAL OR CARBON DIOXIDE TO EXTINGUISH.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
CLOSED CONTAINERS EXPOSED TO HEAT FROM FIRE MAY BUILD PRESSURE AND
EXPLODE.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
HYDROCARBONS DURING COMBUSTION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
TOXIC VAPOR, GAS, PARTICULATE DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
WATER MAY NOT EFFECTIVELY EXTINGUISH FIRE; HOWEVER, IT SHOULD BE USED
TO KEEP FIRE-EXPOSED CONTAINERS AND SURFACES COOL AND PREVENT EXPLOSIVE
RUPTURE.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO
SMOKING. USE ONLY NON-SPARKING TOOLS. VENTILATE THE AREA WITH FRESH AIR.
FOR LARGE SPILL, OR SPILLS IN CONFINED SPACES, PROVIDE MECHANICAL
VENTILATION TO DISPERSE OR EXHAUST VAPORS, IN ACCORDANCE WITH GOOD
INDUSTRIAL HYGIENE PRACTICE.
WARNING!
A MOTOR COULD BE AN IGNITION SOURCE AND COULD CAUSE FLAMMABLE GASES
OR VAPORS IN THE SPILL AREA TO BURN OR EXPLODE. REFER TO OTHER SECTIONS
OF THIS SDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH HAZARDS,
RESPIRATORY PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. FOR LARGER SPILLS, COVER DRAINS AND
BUILD DIKES TO PREVENT ENTRY INTO SEWER SYSTEMS OR BODIES OF WATER.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
CONTAIN SPILL. COVER SPILL AREA WITH A FIRE-EXTINGUISHING FOAM. AN
APPROPRIATE AQUEOUS FILM FORMING FOAM (AFFF) IS RECOMMENDED. WORKING FROM
AROUND THE EDGES OF THE SPILL INWARD, COVER WITH BENTONITE, VERMICULITE,
OR COMMERCIALLY AVAILABLE INORGANIC ABSORBENT MATERIAL. MIX IN SUFFICIENT
ABSORBENT UNTIL IT APPEARS DRY. REMEMBER, ADDING AN ABSORBENT MATERIAL DOES
NOT REMOVE A PHYSICAL, HEALTH, OR ENVIRONMENTAL HAZARD. COLLECT AS MUCH OF
THE SPILLED MATERIAL AS POSSIBLE USING NON-SPARKING TOOLS. PLACE IN A METAL
CONTAINER APPROVED FOR TRANSPORTATION BY APPROPRIATE AUTHORITIES. CLEAN UP
RESIDUE WITH AN APPROPRIATE SOLVENT SELECTED BY A QUALIFIED AND AUTHORIZED
PERSON. VENTILATE THE AREA WITH FRESH AIR. READ AND FOLLOW SAFETY
PRECAUTIONS ON THE SOLVENT LABEL AND SDS. SEAL THE CONTAINER. DISPOSE OF
COLLECTED MATERIAL AS SOON AS POSSIBLE.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
AVOID BREATHING OF DUST CREATED BY CUTTING, SANDING, GRINDING OR MACHINING.
KEEP OUT OF REACH OF CHILDREN. DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS
HAVE BEEN READ AND UNDERSTOOD. KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT
SURFACES. - NO SMOKING. USE ONLY NON-SPARKING TOOLS. TAKE PRECAUTIONARY
MEASURES AGAINST STATIC DISCHARGE. DO NOT BREATHE
DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN EYES, ON SKIN, OR ON
CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH
THOROUGHLY AFTER HANDLING. AVOID RELEASE TO THE ENVIRONMENT. AVOID CONTACT
WITH OXIDIZING AGENTS (EG. CHLORINE, CHROMIC ACID ETC.) WEAR LOW STATIC
OR PROPERLY GROUNDED SHOES. USE PERSONAL PROTECTIVE EQUIPMENT (GLOVES,
RESPIRATORS, ETC.) AS REQUIRED. TO MINIMIZE THE RISK OF IGNITION, DETERMINE
APPLICABLE ELECTRICAL CLASSIFICATIONS FOR THE PROCESS USING THIS PRODUCT
AND SELECT SPECIFIC LOCAL EXHAUST VENTILATION EQUIPMENT TO AVOID FLAMMABLE
VAPOR ACCUMULATION. GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT IF THERE
IS POTENTIAL FOR STATIC ELECTRICITY ACCUMULATION DURING TRANSFER.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
STORE IN A WELL-VENTILATED PLACE. KEEP COOL. KEEP CONTAINER TIGHTLY CLOSED.
PROTECT FROM SUNLIGHT. STORE AWAY FROM HEAT. STORE AWAY FROM ACIDS.
STORE AWAY FROM STRONG BASES. STORE AWAY FROM OXIDIZING AGENTS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL
COMMENTS
STYRENE MONOMER 100-42-5 ACGIH TWA: 20 PPM A4:
STEL: 40 PPM NOT CLASS.
AS HUMAN
CARCIN
STYRENE MONOMER 100-42-5 OSHA TWA: 100 PPM
CEIL: 200 PPM
SILICA, AMORPHOUS 112926-00-8 OSHA TWA
CONCENTRATION:
0.8 MG/M3
TWA:
20 MILLIONS
OF
PARTICLES/CU.
FT.
SILICA, AMORPHOUS 112945-52-5 OSHA TWA
CONCENTRATION:
0.8 MG/M3
TWA:
20 MILLIONS
OF
PARTICLES/CU.
FT.
LIMESTONE 1317-65-3 OSHA TWA (AS TOTAL
DUST):
15 MG/M3
TWA
(RESPIRABLE
FRACTION):
5 MG/M3
TITANIUM DIOXIDE 13463-67-7 ACGIH TWA: 10 MG/M3 A4:
NOT CLASS.
AS HUMAN
CARCIN
TITANIUM DIOXIDE 13463-67-7 CMRG TWA (AS
RESPIRABLE
DUST):
5 MG/M3
TITANIUM DIOXIDE 13463-67-7 OSHA TWA (AS
TOTAL DUST):
15 MG/M3
TALC 14807-96-6 ACGIH TWA A4:
(RESPIRABLE NOT CLASS.
FRACTION): AS HUMAN
2 MG/M3 CARCIN
TALC 14807-96-6 CMRG TWA (AS
RESPIRABLE
DUST):
0.5 MG/M3
TALC 14807-96-6 OSHA TWA
CONCENTRATION
(AS TOTAL
DUST):
0.3 MG/M3
TWA
CONCENTRATION
(RESPIRABLE):
0.1 MG/M3
(2.4 MILLIONS
OF
PARTICLES/CU.
FT.)
TWA:
20 MILLIONS
OF
PARTICLES/CU.
FT.
QUARTZ SILICA 14808-60-7 ACGIH TWA A2:
(RESPIRABLE SUSPECTED
FRACTION): HUMAN
0.025 MG/M3 CARCIN.
QUARTZ SILICA 14808-60-7 OSHA TWA
CONCENTRATION
(AS TOTAL
DUST):
0.3 MG/M3
TWA
CONCENTRATION
(RESPIRABLE):
0.1 MG/M3
(2.4 MILLIONS
OF
PARTICLES/CU.
FT.)
ALUMINUM, 21645-51-2 ACGIH TWA A4:
INSOLUBLE COMPOUNDS (RESPIRABLE NOT CLASS.
FRACTION): AS HUMAN
1 MG/M3 CARCIN
MAGNESIUM CARBONATE 546-93-0 OSHA TWA (AS TOTAL
DUST):
15 MG/M3
TWA
(RESPIRABLE
FRACTION):
5 MG/M3
INERT FILLER TRADE MANUFACTURER TWA (AS DUST):
SECRET DETERMINED 10 MG/M3
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
USE GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR
CONTROL DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE,
USE RESPIRATORY PROTECTION EQUIPMENT. USE EXPLOSION-PROOF VENTILATION
EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT. THE FOLLOWING EYE/FACE PROTECTION(S) ARE
RECOMMENDED: INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT
LOCAL STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN
EXPOSURE ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS
EXPOSURE LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND
DURATION, PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE
CONDITIONS. CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER
FOR SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
NOTE:
NITRILE GLOVES MAY BE WORN OVER POLYMER LAMINATE GLOVES TO IMPROVE
DEXTERITY.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED:
POLYVINYL ALCOHOL (PVA) POLYMER LAMINATE
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM.
BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT FROM THE FOLLOWING
RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
ORGANIC VAPORS AND PARTICULATES
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: LIQUID
ODOR, COLOR, GRADE: LIGHT YELLOW PASTE, STYRENIC ODOR
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NOT APPLICABLE
MELTING POINT: NOT APPLICABLE
BOILING POINT: 145 DEG. C [DETAILS: STYRENE]
FLASH POINT: 31 DEG. C [TEST METHOD: CLOSED CUP]
EVAPORATION RATE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLAMMABLE LIMITS (LEL): 1.1%
FLAMMABLE LIMITS (UEL): 6.1%
VAPOR PRESSURE: 4.3 MMHg [@ 20 DEG. C] [DETAILS: STYRENE]
VAPOR DENSITY: 3.6 [REF STD: AIR=1] [DETAILS: STYRENE]
DENSITY: 1.2 G/ML
SPECIFIC GRAVITY: 1.2 [REF STD: WATER=1]
SOLUBILITY IN WATER: NIL
SOLUBILITY-NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: 400,000 - 500,000 CENTIPOISE [DETAILS: 2.5 RPM WITH TD SPINDLE]
HAZARDOUS AIR POLLUTANTS: 0.374 LB HAPS/LB SOLIDS [TEST METHOD: CALCULATED]
VOLATILE ORGANIC COMPOUNDS:
246 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
VOLATILE ORGANIC COMPOUNDS:
20.5% WEIGHT [TEST METHOD: CALCULATED PER CARB TITLE 2]
PERCENT VOLATILE: NO DATA AVAILABLE
VOC LESS H2O & EXEMPT SOLVENTS:
246 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN
CONDITIONS - SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID:
HEAT
SPARKS AND/OR FLAMES
10.5. INCOMPATIBLE MATERIALS:
STRONG ACIDS
STRONG BASES
STRONG OXIDIZING AGENTS
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
STYRENE OXIDE NOT SPECIFIED
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING
COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR
THE SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT
BELOW THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL
MAY PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION: MAY BE HARMFUL IF INHALED.
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
SKIN CONTACT:
MILD SKIN IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, AND
DRYNESS.
EYE CONTACT:
MODERATE EYE IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, PAIN, TEARING, AND BLURRED
OR HAZY VISION.
INGESTION:
GASTROINTESTINAL IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA, VOMITING
AND DIARRHEA.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
ADDITIONAL HEALTH EFFECTS:
SINGLE EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS:
AUDITORY EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE HEARING IMPAIRMENT, BALANCE DYSFUNCTION AND
RINGING IN THE EARS.
LIVER EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE LOSS OF APPETITE, WEIGHT LOSS, FATIGUE,
WEAKNESS, ABDOMINAL TENDERNESS AND JAUNDICE.
CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION:
SIGNS/SYMPTOMS MAY INCLUDE HEADACHE, DIZZINESS, DROWSINESS, INCOORDINATION,
NAUSEA, SLOWED REACTION TIME, SLURRED SPEECH, GIDDINESS, AND
UNCONSCIOUSNESS.
PROLONGED OR REPEATED EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS:
LIVER EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE LOSS OF APPETITE, WEIGHT LOSS, FATIGUE,
WEAKNESS, ABDOMINAL TENDERNESS AND JAUNDICE.
PROLONGED OR REPEATED EXPOSURE BY INHALATION MAY CAUSE:
PNEUMOCONIOSIS:
SIGN/SYMPTOMS MAY INCLUDE PERSISTENT COUGH, BREATHLESSNESS, CHEST PAIN,
INCREASED AMOUNTS OF SPUTUM, AND CHANGES IN LUNG FUNCTION TESTS.
OCULAR EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE BLURRED OR SIGNIFICANTLY IMPAIRED VISION.
CARCINOGENICITY: CONTAINS A CHEMICAL OR CHEMICALS WHICH CAN CAUSE CANCER.
INGREDIENT CAS NO. CLASS DESCRIPTION REGULATION
SILICA, CRYS 14808-60-7 KNOWN HUMAN NATIONAL TOXICOLOGY
AIRRESP CARCINOGEN PROGRAM CARCINOGENS
INERT FILLER TRADE SECRET GRP. 2B: INTERNATIONAL AGENCY
POSSIBLE HUMAN FOR RESEARCH ON
CARC. CANCER
INERT FILLER TRADE SECRET ANTICIPATED HUMAN NATIONAL TOXICOLOGY
CARCINOGEN PROGRAM CARCINOGENS
QUARTZ SILICA 14808-60-7 GRP. 1: INTERNATIONAL AGENCY
CARCINOGENIC TO FOR RESEARCH ON
HUMANS CANCER
STYRENE MONOMER 100-42-5 GRP. 2B: INTERNATIONAL AGENCY
POSSIBLE HUMAN FOR RESEARCH ON
CARC. CANCER
STYRENE MONOMER 100-42-5 ANTICIPATED HUMAN NATIONAL TOXICOLOGY
CARCINOGEN PROGRAM CARCINOGENS
TITANIUM DIOXIDE 13463-67-7 GRP. 2B: INTERNATIONAL AGENCY
POSSIBLE HUMAN FOR RESEARCH ON
CARC. CANCER
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE
NOT SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT INHALATION- NO DATA AVAILABLE;
VAPOR(4 HR) CALCULATED ATE:
20 - 50 MG/L
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE:
>5,000 MG/KG
STYRENE MONOMER DERMAL RAT LD50: >2,000 MG/KG
STYRENE MONOMER INHALATION- RAT LC50: 8.3 MG/L
VAPOR
(4 HOURS)
STYRENE MONOMER INGESTION RAT LD50: 5,000 MG/KG
LIMESTONE DERMAL RAT LD50: >2,000 MG/KG
LIMESTONE INHALATION- RAT LC50: 3 MG/L
DUST/MIST
(4 HOURS)
LIMESTONE INGESTION RAT LD50: 6,450 MG/KG
ALUMINA TRIHYDRATE DERMAL LD50:
ESTIMATED TO BE
>5,000 MG/KG
ALUMINA TRIHYDRATE INGESTION RAT LD50: >5,000 MG/KG
TALC DERMAL LD50:
ESTIMATED TO BE
>5,000 MG/KG
TALC INGESTION LD50:
ESTIMATED TO BE
>5,000 MG/KG
INERT FILLER DERMAL LD50:
ESTIMATED TO BE
>5,000 MG/KG
INERT FILLER INGESTION LD50:
ESTIMATED TO BE
2,000 - 5,000 MG/KG
SYNTHETIC CRYSTALLINE-FREE DERMAL RABBIT LD50: >5,000 MG/KG
SILICA GEL
SYNTHETIC CRYSTALLINE-FREE INHALATION- RAT LC50: >0.691 MG/L
SILICA GEL DUST/MIST
(4 HOURS)
SYNTHETIC CRYSTALLINE-FREE INGESTION RAT LD50: >5,110 MG/KG
SILICA GEL
TITANIUM DIOXIDE DERMAL RABBIT LD50: >10,000 MG/KG
TITANIUM DIOXIDE INHALATION- RAT LC50: >6.82 MG/L
DUST/MIST
(4 HOURS)
TITANIUM DIOXIDE INGESTION RAT LD50: >10,000 MG/KG
MAGNESIUM CARBONATE INGESTION MOUSE LD50: >5,000 MG/KG
SYNTHETIC AMORPHOUS DERMAL RABBIT LD50: >5,000 MG/KG
SILICA, CRYSTALLINE FREE
SYNTHETIC AMORPHOUS INHALATION- RAT LC50: >0.691 MG/L
SILICA, CRYSTALLINE FREE DUST/MIST
(4 HOURS)
SYNTHETIC AMORPHOUS INGESTION RAT LD50: >5,110 MG/KG
SILICA, CRYSTALLINE FREE
QUARTZ SILICA DERMAL LD50:
ESTIMATED TO BE
>5,000 MG/KG
QUARTZ SILICA INGESTION LD50:
ESTIMATED TO BE
>5,000 MG/KG
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
STYRENE MONOMER OFFICIAL MILD IRRITANT
CLASSIFICATION
LIMESTONE RABBIT NO SIGNIFICANT IRRITATION
ALUMINA TRIHYDRATE RABBIT NO SIGNIFICANT IRRITATION
TALC RABBIT NO SIGNIFICANT IRRITATION
INERT FILLER PROFESSIONAL NO SIGNIFICANT IRRITATION
JUDGEMENT
SYNTHETIC CRYSTALLINE-FREE RABBIT NO SIGNIFICANT IRRITATION
SILICA GEL
TITANIUM DIOXIDE RABBIT NO SIGNIFICANT IRRITATION
MAGNESIUM CARBONATE IN VITRO DATA MINIMAL IRRITATION
SYNTHETIC AMORPHOUS SILICA, RABBIT NO SIGNIFICANT IRRITATION
CRYSTALLINE FREE
QUARTZ SILICA PROFESSIONAL NO SIGNIFICANT IRRITATION
JUDGEMENT
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
STYRENE MONOMER OFFICIAL MODERATE IRRITANT
CLASSIFICATION
LIMESTONE RABBIT NO SIGNIFICANT IRRITATION
ALUMINA TRIHYDRATE RABBIT NO SIGNIFICANT IRRITATION
TALC RABBIT NO SIGNIFICANT IRRITATION
INERT FILLER PROFESSIONAL NO SIGNIFICANT IRRITATION
JUDGEMENT
SYNTHETIC CRYSTALLINE-FREE RABBIT NO SIGNIFICANT IRRITATION
SILICA GEL
TITANIUM DIOXIDE RABBIT NO SIGNIFICANT IRRITATION
MAGNESIUM CARBONATE RABBIT MILD IRRITANT
SYNTHETIC AMORPHOUS SILICA, RABBIT NO SIGNIFICANT IRRITATION
CRYSTALLINE FREE
SKIN SENSITIZATION:
NAME SPECIES VALUE
STYRENE MONOMER GUINEA PIG NOT SENSITIZING
ALUMINA TRIHYDRATE GUINEA PIG NOT SENSITIZING
SYNTHETIC CRYSTALLINE-FREE HUMAN AND NOT SENSITIZING
SILICA GEL ANIMAL
TITANIUM DIOXIDE HUMAN AND NOT SENSITIZING
ANIMAL
SYNTHETIC AMORPHOUS SILICA, HUMAN AND NOT SENSITIZING
CRYSTALLINE FREE ANIMAL
RESPIRATORY SENSITIZATION:
NAME SPECIES VALUE
TALC HUMAN NOT SENSITIZING
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
STYRENE MONOMER IN VITRO SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
STYRENE MONOMER IN VIVO SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
TALC IN VITRO NOT MUTAGENIC
TALC IN VIVO NOT MUTAGENIC
INERT FILLER IN VITRO SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
SYNTHETIC CRYSTALLINE-FREE IN VITRO NOT MUTAGENIC
SILICA GEL
TITANIUM DIOXIDE IN VITRO NOT MUTAGENIC
TITANIUM DIOXIDE IN VIVO NOT MUTAGENIC
SYNTHETIC AMORPHOUS SILICA, IN VITRO NOT MUTAGENIC
CRYSTALLINE FREE
QUARTZ SILICA IN VITRO SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
QUARTZ SILICA IN VIVO SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
STYRENE MONOMER INGESTION MOUSE CARCINOGENIC
STYRENE MONOMER INHALATION HUMAN CARCINOGENIC
AND
ANIMAL
ALUMINA TRIHYDRATE NOT MULTIPLE NOT CARCINOGENIC
SPECIFIED ANIMAL
SPECIES
TALC INHALATION RAT SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
INERT FILLER INHALATION MULTIPLE SOME POSITIVE DATA
ANIMAL EXIST, BUT THE DATA
SPECIES ARE NOT SUFFICIENT
FOR CLASSIFICATION
SYNTHETIC CRYSTALLINE-FREE NOT MOUSE SOME POSITIVE DATA
SILICA GEL SPECIFIED EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
TITANIUM DIOXIDE INGESTION MULTIPLE NOT CARCINOGENIC
ANIMAL
SPECIES
TITANIUM DIOXIDE INHALATION RAT CARCINOGENIC
SYNTHETIC AMORPHOUS SILICA, NOT MOUSE SOME POSITIVE DATA
CRYSTALLINE FREE SPECIFIED EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
QUARTZ SILICA INHALATION HUMAN CARCINOGENIC
AND
ANIMAL
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE
STYRENE MONOMER INGESTION NOT TOXIC TO FEMALE REPRODUCTION
STYRENE MONOMER INHALATION NOT TOXIC TO FEMALE REPRODUCTION
STYRENE MONOMER INHALATION NOT TOXIC TO MALE REPRODUCTION
STYRENE MONOMER INGESTION SOME POSITIVE MALE REPRODUCTIVE
DATA EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR CLASSIFICATION
STYRENE MONOMER INGESTION SOME POSITIVE DEVELOPMENTAL DATA
EXIST, BUT THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION
STYRENE MONOMER INHALATION SOME POSITIVE DEVELOPMENTAL DATA
EXIST, BUT THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION
LIMESTONE INGESTION NOT TOXIC TO DEVELOPMENT
ALUMINA TRIHYDRATE INGESTION NOT TOXIC TO DEVELOPMENT
TALC INGESTION NOT TOXIC TO DEVELOPMENT
SYNTHETIC CRYSTALLINE-FREE INGESTION NOT TOXIC TO FEMALE REPRODUCTION
SILICA GEL
SYNTHETIC CRYSTALLINE-FREE INGESTION NOT TOXIC TO MALE REPRODUCTION
SILICA GEL
SYNTHETIC CRYSTALLINE-FREE INGESTION NOT TOXIC TO DEVELOPMENT
SILICA GEL
SYNTHETIC AMORPHOUS INGESTION NOT TOXIC TO FEMALE REPRODUCTION
SILICA, CRYSTALLINE FREE
SYNTHETIC AMORPHOUS INGESTION NOT TOXIC TO MALE REPRODUCTION
SILICA, CRYSTALLINE FREE
SYNTHETIC AMORPHOUS INGESTION NOT TOXIC TO DEVELOPMENT
SILICA, CRYSTALLINE FREE
NAME SPECIES TEST RESULT EXPOSURE DURATION
STYRENE MONOMER RAT NOAEL: 3 GENERATION
21 MG/KG/DAY
STYRENE MONOMER RAT NOAEL: 2 GENERATION
2.1 MG/L
STYRENE MONOMER RAT NOAEL: 2 GENERATION
2.1 MG/L
STYRENE MONOMER RAT NOAEL: 60 DAYS
400 MG/KG/DAY
STYRENE MONOMER RAT NOAEL: DURING GESTATION
400 MG/KG/DAY
STYRENE MONOMER MULTIPLE NOAEL: DURING GESTATION
ANIMAL 2.1 MG/L
SPECIES
LIMESTONE RAT NOAEL: PREMATING &
625 MG/KG/DAY DURING GESTATION
ALUMINA TRIHYDRATE RAT NOAEL: DURING
768 MG/KG/DAY ORGANOGENESIS
TALC RAT NOAEL: DURING
1,600 MG/KG ORGANOGENESIS
SYNTHETIC CRYSTALLINE-FREE RAT NOAEL: 1 GENERATION
SILICA GEL 509 MG/KG/DAY
SYNTHETIC CRYSTALLINE-FREE RAT NOAEL: 1 GENERATION
SILICA GEL 497 MG/KG/DAY
SYNTHETIC CRYSTALLINE-FREE RAT NOAEL: DURING
SILICA GEL 1,350 MG/KG/DAY ORGANOGENESIS
SYNTHETIC AMORPHOUS RAT NOAEL: 1 GENERATION
SILICA, CRYSTALLINE FREE 509 MG/KG/DAY
SYNTHETIC AMORPHOUS RAT NOAEL: 1 GENERATION
SILICA, CRYSTALLINE FREE 497 MG/KG/DAY
SYNTHETIC AMORPHOUS RAT NOAEL: DURING
SILICA, CRYSTALLINE FREE 1,350 MG/KG/DAY ORGANOGENESIS
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
STYRENE MONOMER INHALATION AUDITORY SYSTEM CAUSES DAMAGE TO
ORGANS
STYRENE MONOMER INHALATION LIVER CAUSES DAMAGE TO
ORGANS
STYRENE MONOMER INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
STYRENE MONOMER INHALATION RESPIRATORY SOME POSITIVE DATA
IRRITATION EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
STYRENE MONOMER INHALATION ENDOCRINE SYSTEM ALL DATA ARE NEGATIVE
STYRENE MONOMER INHALATION KIDNEY AND/OR ALL DATA ARE NEGATIVE
BLADDER
LIMESTONE INHALATION RESPIRATORY SYSTEM ALL DATA ARE NEGATIVE
NAME SPECIES TEST RESULT EXPOSURE DURATION
STYRENE MONOMER MULTIPLE LOAEL: 4.3 MG/L NOT AVAILABLE
ANIMAL
SPECIES
STYRENE MONOMER MOUSE LOAEL: 2.1 MG/L NOT AVAILABLE
STYRENE MONOMER HUMAN NOAEL: OCCUPATIONAL
NOT AVAILABLE EXPOSURE
STYRENE MONOMER HUMAN AND NOAEL:
ANIMAL NOT AVAILABLE
STYRENE MONOMER RAT NOAEL: NOT AVAILABLE
NOT AVAILABLE
STYRENE MONOMER MULTIPLE NOAEL: 2.1 MG/L NOT AVAILABLE
ANIMAL
SPECIES
LIMESTONE RAT NOAEL: 0.812 MG/L 90 MINUTES
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
STYRENE MONOMER INHALATION EYES CAUSES DAMAGE TO
ORGANS THROUGH
PROLONGED OR
REPEATED EXPOSURE
STYRENE MONOMER INHALATION AUDITORY SYSTEM MAY CAUSE DAMAGE
TO ORGANS THOUGH
PROLONGED OR
REPEATED EXPOSURE
STYRENE MONOMER INHALATION LIVER MAY CAUSE DAMAGE
TO ORGANS THOUGH
PROLONGED OR
REPEATED EXPOSURE
STYRENE MONOMER INHALATION NERVOUS SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
STYRENE MONOMER INHALATION HEMATOPOIETIC SOME POSITIVE DATA
SYSTEM EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
STYRENE MONOMER INHALATION ENDOCRINE SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
STYRENE MONOMER INHALATION RESPIRATORY SOME POSITIVE DATA
SYSTEM EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
STYRENE MONOMER INHALATION HEART | ALL DATA ARE
BONE, TEETH, NEGATIVE
NAILS, AND/OR
HAIR |
MUSCLES |
KIDNEY AND/OR
BLADDER
STYRENE MONOMER INGESTION NERVOUS SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
STYRENE MONOMER INGESTION IMMUNE SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
STYRENE MONOMER INGESTION LIVER | SOME POSITIVE DATA
KIDNEY AND/OR EXIST, BUT THE DATA
BLADDER ARE NOT SUFFICIENT
FOR CLASSIFICATION
STYRENE MONOMER INGESTION HEMATOPOIETIC SOME POSITIVE DATA
SYSTEM EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
STYRENE MONOMER INGESTION HEART | ALL DATA ARE
RESPIRATORY NEGATIVE
SYSTEM
LIMESTONE INHALATION RESPIRATORY SOME POSITIVE DATA
SYSTEM EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
TALC INHALATION PNEUMOCONIOSIS CAUSES DAMAGE TO
ORGANS THROUGH
PROLONGED OR
REPEATED EXPOSURE
TALC INHALATION PULMONARY SOME POSITIVE DATA
FIBROSIS | EXIST, BUT THE DATA
RESPIRATORY ARE NOT SUFFICIENT
SYSTEM FOR CLASSIFICATION
INERT FILLER INHALATION RESPIRATORY SOME POSITIVE DATA
SYSTEM EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
SYNTHETIC INHALATION RESPIRATORY ALL DATA ARE
CRYSTALLINE-FREE SYSTEM | NEGATIVE
SILICA GEL SILICOSIS
TITANIUM DIOXIDE INHALATION RESPIRATORY SOME POSITIVE DATA
SYSTEM EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
TITANIUM DIOXIDE INHALATION PULMONARY ALL DATA ARE
FIBROSIS NEGATIVE
SYNTHETIC AMORPHOUS INHALATION RESPIRATORY ALL DATA ARE
SILICA, CRYSTALLINE SYSTEM | NEGATIVE
FREE SILICOSIS
QUARTZ SILICA INHALATION SILICOSIS CAUSES DAMAGE TO
ORGANS THROUGH
PROLONGED OR
REPEATED EXPOSURE
NAME SPECIES TEST RESULT EXPOSURE DURATION
STYRENE MONOMER HUMAN NOAEL: OCCUPATIONAL
NOT AVAILABLE EXPOSURE
STYRENE MONOMER MULTIPLE NOAEL: 1.3 MG/L NOT AVAILABLE
ANIMAL
SPECIES
STYRENE MONOMER MOUSE LOAEL: 0.85 MG/L 13 WEEKS
STYRENE MONOMER MULTIPLE LOAEL: 1.1 MG/L NOT AVAILABLE
ANIMAL
SPECIES
STYRENE MONOMER RAT NOAEL: 0.85 MG/L 7 DAYS
STYRENE MONOMER RAT NOAEL: 0.6 MG/L 10 DAYS
STYRENE MONOMER MULTIPLE LOAEL: 0.09 MG/L NOT AVAILABLE
ANIMAL
SPECIES
STYRENE MONOMER MULTIPLE NOAEL: 4.3 MG/L 2 YEARS
ANIMAL
SPECIES
STYRENE MONOMER RAT LOAEL: 8 WEEKS
500 MG/KG/DAY
STYRENE MONOMER MULTIPLE NOAEL: NOT AVAILABLE
ANIMAL NOT AVAILABLE
SPECIES
STYRENE MONOMER RAT NOAEL: 6 MONTHS
677 MG/KG/DAY
STYRENE MONOMER DOG NOAEL: 470 DAYS
600 MG/KG/DAY
STYRENE MONOMER RAT NOAEL: 105 WEEKS
35 MG/KG/DAY
LIMESTONE HUMAN NOAEL: OCCUPATIONAL
NOT AVAILABLE EXPOSURE
TALC HUMAN NOAEL: OCCUPATIONAL
NOT AVAILABLE EXPOSURE
TALC RAT NOAEL: 18 MG/M3 113 WEEKS
INERT FILLER HUMAN NOAEL: OCCUPATIONAL
NOT AVAILABLE EXPOSURE
SYNTHETIC HUMAN NOAEL: OCCUPATIONAL
CRYSTALLINE-FREE NOT AVAILABLE EXPOSURE
SILICA GEL
TITANIUM DIOXIDE RAT LOAEL: 0.01 MG/L 2 YEARS
TITANIUM DIOXIDE HUMAN NOAEL: OCCUPATIONAL
NOT AVAILABLE EXPOSURE
SYNTHETIC AMORPHOUS HUMAN NOAEL: OCCUPATIONAL
SILICA, CRYSTALLINE FREE NOT AVAILABLE EXPOSURE
QUARTZ SILICA HUMAN NOAEL: OCCUPATIONAL
NOT AVAILABLE EXPOSURE
ASPIRATION HAZARD:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR
THE DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
INCINERATE IN A PERMITTED WASTE INCINERATION FACILITY. COMBUSTION PRODUCTS
WILL INCLUDE HALOGEN ACID (HCl/HF/HBr). FACILITY MUST BE CAPABLE OF
HANDLING HALOGENATED MATERIALS. AS A DISPOSAL ALTERNATIVE, DISPOSE OF
WASTE PRODUCT IN A PERMITTED INDUSTRIAL WASTE FACILITY. EMPTY
DRUMS/BARRELS/CONTAINERS USED FOR TRANSPORTING AND HANDLING HAZARDOUS
CHEMICALS (CHEMICAL SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS
HAZARDOUS AS PER APPLICABLE REGULATIONS) SHALL BE CONSIDERED, STORED,
TREATED & DISPOSED OF AS HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY
APPLICABLE WASTE REGULATIONS. CONSULT WITH THE RESPECTIVE REGULATING
AUTHORITIES TO DETERMINE THE AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
311/312 HAZARD CATEGORIES:
FIRE HAZARD: YES
PRESSURE HAZARD: NO
REACTIVITY HAZARD: NO
IMMEDIATE HAZARD: YES
DELAYED HAZARD: YES
SECTION 313 TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF THAT
SECTION AND 40 CFR PART 372 (EPCRA):
INGREDIENT C.A.S. NO % BY WT
STYRENE MONOMER 100-42-5 TRADE SECRET 10 - 30
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
CALIFORNIA PROPOSITION 65:
INGREDIENT C.A.S. NO. CLASSIFICATION
SILICA, CRYSTALLINE NONE CARCINOGEN
(AIRBORNE PARTICLES OF RESPIRABLE SIZE)
TITANIUM DIOXIDE 13463-67-7 CARCINOGEN
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE NEW SUBSTANCE
NOTIFICATION REQUIREMENTS OF CEPA.
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 2
FLAMMABILITY 3
INSTABILITY 1
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED
FOR USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED
ON THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO
INCLUDE THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT
ARE KNOWN TO BE GENERATED IN SIGNIFICANT QUANTITIES.
DOCUMENT GROUP: 07-4083-7
VERSION NUMBER: 16.00
ISSUE DATE: 09/25/15
SUPERCEDES DATE: 04/17/15
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY
OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED
IN ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
3M USA SDSS ARE AVAILABLE AT WWW.3M.COM
3M(TM) CREAM HARDENER (RED, WHITE & BLUE)
02/06/17
3M
SAFETY DATA SHEET
COPYRIGHT, 2017, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 29-5993-0
VERSION NUMBER: 3.04
ISSUE DATE: 02/06/17
SUPERCEDES DATE: 12/15/16
| SECTION 1: IDENTIFICATION | |
1.1. PRODUCT IDENTIFIER: 3M(TM) CREAM HARDENER (RED, WHITE & BLUE)
PRODUCT IDENTIFICATION NUMBERS:
LB-K100-0965-7, LB-K100-0965-8, LB-K100-0965-9, LB-K100-0966-0,
LB-K100-0966-1, LB-K100-0966-2, LB-K100-0966-3, LB-K100-1035-6,
LB-K100-1045-4, LB-K100-1286-7, 41-0003-6674-4, 41-0003-6682-7,
41-0003-6685-0, 41-0003-6686-8, 41-0003-6687-6, 41-0003-7901-0,
41-0003-7903-6, 41-0003-7904-4, 41-0003-7922-6, 41-0003-7928-3,
41-0003-7930-9, 41-0003-7931-7, 41-0003-7932-5, 41-0003-7933-3,
41-0003-7935-8, 41-0003-7987-9, 41-0003-8072-9, 41-0003-8073-7,
41-0003-8074-5, 60-4550-6617-9, 60-4550-6830-8, 60-4550-6981-9,
60-4550-6982-7, 60-4550-8123-6
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE: AUTOMOTIVE, HARDENER FOR BODY FILLERS & GLAZES
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: AUTOMOTIVE AFTERMARKET
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
THE LABEL ELEMENTS BELOW WERE PREPARED IN ACCORDANCE WITH OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.
THIS INFORMATION MAY BE DIFFERENT FROM THE ACTUAL PRODUCT LABEL INFORMATION
FOR LABELS REGULATED BY OTHER AGENCIES.
2.1. HAZARD CLASSIFICATION:
ORGANIC PEROXIDE: TYPE E.
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 2A.
SKIN SENSITIZER: CATEGORY 1.
2.2. LABEL ELEMENTS:
SIGNAL WORD: WARNING
SYMBOLS:
FLAME
EXCLAMATION MARK
PICTOGRAMS:
FLAME
EXCLAMATION MARK
HAZARD STATEMENTS:
HEATING MAY CAUSE A FIRE.
CAUSES SERIOUS EYE IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
PRECAUTIONARY STATEMENTS:
GENERAL: KEEP OUT OF REACH OF CHILDREN.
PREVENTION:
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING.
KEEP AWAY FROM CLOTHING AND OTHER COMBUSTIBLE MATERIALS.
KEEP ONLY IN ORIGINAL CONTAINER.
AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY.
WEAR PROTECTIVE GLOVES AND EYE/FACE PROTECTION.
WASH THOROUGHLY AFTER HANDLING.
CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
RESPONSE:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
WASH CONTAMINATED CLOTHING BEFORE REUSE.
STORAGE:
PROTECT FROM SUNLIGHT.
STORE AT TEMPERATURES NOT EXCEEDING 32C/90F. KEEP COOL.
STORE AWAY FROM OTHER MATERIALS.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
2.3. HAZARDS NOT OTHERWISE CLASSIFIED: NONE.
8% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE INHALATION
TOXICITY.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
BENZOYL PEROXIDE 94-36-0 30 - 60 TRADE SECRET *
WATER 7732-18-5 10 - 30 TRADE SECRET *
BENZOIC ACID, C9-11-BRANCHED 131298-44-7 10 - 30 TRADE SECRET *
ALKYL ESTERS
ZINC STEARATE 557-05-1 3 - 7 TRADE SECRET *
OXIRANE, POLYMER WITH METHYLOXIRANE, 9038-95-3 1 - 5 TRADE SECRET *
MONOBUTYL ETHER
CALCIUM SULFATE 7778-18-9 1 - 5 TRADE SECRET *
IRON OXIDE (FE2O3) 1309-37-1 1 - 5 TRADE SECRET *
FERRIC FERROCYANIDE 14038-43-8 0 - 1 TRADE SECRET *
FERRIC AMMONIUM FERROCYANIDE 25869-00-5 0 - 1 TRADE SECRET *
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION)
OF THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND
WASH BEFORE REUSE. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER. REMOVE CONTACT LENSES IF
EASY TO DO. CONTINUE RINSING. GET MEDICAL ATTENTION.
IF SWALLOWED: RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
IN CASE OF FIRE:
USE A FIRE FIGHTING AGENT SUITABLE FOR ORDINARY COMBUSTIBLE MATERIAL SUCH
AS WATER OR FOAM TO EXTINGUISH.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
CLOSED CONTAINERS EXPOSED TO HEAT FROM FIRE MAY BUILD PRESSURE AND EXPLODE.
PART OF THE OXYGEN FOR COMBUSTION IS SUPPLIED BY THE PEROXIDE ITSELF.
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
NO SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS ARE ANTICIPATED.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. ELIMINATE ALL IGNITION SOURCES IF SAFE TO DO SO. KEEP AWAY
FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING. USE ONLY
NON-SPARKING TOOLS. VENTILATE THE AREA WITH FRESH AIR. FOR LARGE SPILL, OR
SPILLS IN CONFINED SPACES, PROVIDE MECHANICAL VENTILATION TO DISPERSE OR
EXHAUST VAPORS, IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE PRACTICE.
WARNING!
A MOTOR COULD BE AN IGNITION SOURCE AND COULD CAUSE FLAMMABLE GASES OR
VAPORS IN THE SPILL AREA TO BURN OR EXPLODE. REFER TO OTHER SECTIONS OF
THIS SDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH HAZARDS, RESPIRATORY
PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. FOR LARGER SPILLS, COVER DRAINS AND
BUILD DIKES TO PREVENT ENTRY INTO SEWER SYSTEMS OR BODIES OF WATER.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
CONTAIN SPILL. WORKING FROM AROUND THE EDGES OF THE SPILL INWARD, COVER
WITH BENTONITE, VERMICULITE, OR COMMERCIALLY AVAILABLE INORGANIC ABSORBENT
MATERIAL. MIX IN SUFFICIENT ABSORBENT UNTIL IT APPEARS DRY. REMEMBER,
ADDING AN ABSORBENT MATERIAL DOES NOT REMOVE A PHYSICAL, HEALTH, OR
ENVIRONMENTAL HAZARD. COLLECT AS MUCH OF THE SPILLED MATERIAL AS POSSIBLE
USING NON-SPARKING TOOLS. CLEAN UP RESIDUE WITH AN APPROPRIATE SOLVENT
SELECTED BY A QUALIFIED AND AUTHORIZED PERSON. VENTILATE THE AREA WITH
FRESH AIR. READ AND FOLLOW SAFETY PRECAUTIONS ON THE SOLVENT LABEL AND SDS.
SEAL THE CONTAINER. DISPOSE OF COLLECTED MATERIAL AS SOON AS POSSIBLE.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
AVOID BREATHING OF DUST CREATED BY CUTTING, SANDING, GRINDING OR MACHINING.
DO NOT USE IN A CONFINED AREA WITH MINIMAL AIR EXCHANGE. KEEP OUT OF REACH
OF CHILDREN. KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO
SMOKING. AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN
EYES, ON SKIN, OR ON CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS
PRODUCT. WASH THOROUGHLY AFTER HANDLING. CONTAMINATED WORK CLOTHING SHOULD
NOT BE ALLOWED OUT OF THE WORKPLACE. AVOID RELEASE TO THE ENVIRONMENT.
WASH CONTAMINATED CLOTHING BEFORE REUSE.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
KEEP CONTAINER TIGHTLY CLOSED. PROTECT FROM SUNLIGHT. STORE AWAY FROM
HEAT. STORE AT TEMPERATURES NOT EXCEEDING 32C/90F. KEEP COOL. KEEP ONLY
IN ORIGINAL CONTAINER. STORE AWAY FROM OTHER MATERIALS. KEEP/STORE AWAY
FROM CLOTHING AND OTHER COMBUSTIBLE MATERIALS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL
COMMENTS
IRON OXIDE (FE2O3) 1309-37-1 ACGIH TWA A4:
(RESPIRABLE NOT CLASS.
FRACTION): AS HUMAN
5 MG/M3 CARCIN
IRON OXIDE (FE2O3) 1309-37-1 OSHA TWA (AS FUME):
10 MG/M3
CYANIDES 14038-43-8 OSHA TWA (AS CN): SKIN
5 MG/M3
ZINC STEARATE 557-05-1 OSHA TWA (AS
TOTAL DUST):
15 MG/M3
TWA
(RESPIRABLE
FRACTION):
5 MG/M3
CALCIUM SULFATE 7778-18-9 ACGIH TWA (INHALABLE
FRACTION):
10 MG/M3
CALCIUM SULFATE 7778-18-9 OSHA TWA (AS
TOTAL DUST):
15 MG/M3
TWA
(RESPIRABLE
FRACTION):
5 MG/M3
BENZOYL PEROXIDE 94-36-0 ACGIH TWA: 5 MG/M3 A4:
NOT CLASS.
AS HUMAN
CARCIN
BENZOYL PEROXIDE 94-36-0 OSHA TWA: 5 MG/M3
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
PROVIDE VENTILATION ADEQUATE TO MAINTAIN DUST CONCENTRATION BELOW MINIMUM
EXPLOSIVE CONCENTRATIONS. USE GENERAL DILUTION VENTILATION AND/OR LOCAL
EXHAUST VENTILATION TO CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT
EXPOSURE LIMITS AND/OR CONTROL DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF
VENTILATION IS NOT ADEQUATE, USE RESPIRATORY PROTECTION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE
RESULTS OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING EYE/FACE PROTECTION(S) ARE RECOMMENDED:
INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT LOCAL
STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED: NITRILE RUBBER
IF THIS PRODUCT IS USED IN A MANNER THAT PRESENTS A HIGHER POTENTIAL FOR
EXPOSURE (EG. SPRAYING, HIGH SPLASH POTENTIAL ETC.), THEN USE OF
PROTECTIVE COVERALLS MAY BE NECESSARY. SELECT AND USE BODY PROTECTION TO
PREVENT CONTACT BASED ON THE RESULTS OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING PROTECTIVE CLOTHING MATERIAL(S) ARE RECOMMENDED:
APRON - NITRILE
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM.
BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT FROM THE FOLLOWING
RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
ORGANIC VAPORS AND PARTICULATES
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: SOLID
SPECIFIC PHYSICAL FORM: VISCOUS
ODOR, COLOR, GRADE: RED PASTE WITH SLIGHT ESTER ODOR
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
MELTING POINT: NO DATA AVAILABLE
BOILING POINT: NO DATA AVAILABLE
FLASH POINT: 111 DEG. C [TEST METHOD: ESTIMATED]
EVAPORATION RATE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS):
ORGANIC PEROXIDE: TYPE E.
FLAMMABLE LIMITS(LEL): NOT APPLICABLE
FLAMMABLE LIMITS(UEL): NOT APPLICABLE
VAPOR PRESSURE: NOT APPLICABLE
VAPOR DENSITY: NOT APPLICABLE
DENSITY: 1.2 G/CM3
SPECIFIC GRAVITY: 1.2 [@ 25 DEG. C] [REF STD: WATER=1]
SOLUBILITY IN WATER: NEGLIGIBLE
SOLUBILITY-NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: NO DATA AVAILABLE
HAZARDOUS AIR POLLUTANTS: 0 LB HAPS/LB SOLIDS [TEST METHOD: CALCULATED]
MOLECULAR WEIGHT: NOT APPLICABLE
VOLATILE ORGANIC COMPOUNDS:
0 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
VOLATILE ORGANIC COMPOUNDS:
0 % WEIGHT [TEST METHOD: CALCULATED PER CARB TITLE 2]
PERCENT VOLATILE: 20 % [DETAILS: WATER IS THE VOLATILE COMPONENT]
VOC LESS H2O & EXEMPT SOLVENTS:
0 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN
CONDITIONS - SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY:
STABLE. STABLE UNLESS EXPOSED TO HEAT, FLAMES AND DRYING CONDITIONS.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID: HEAT
10.5. INCOMPATIBLE MATERIALS: ACCELERATORS
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
CARBON MONOXIDE NOT SPECIFIED
CARBON DIOXIDE NOT SPECIFIED
TOXIC VAPOR, GAS, PARTICULATE NOT SPECIFIED
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR
THE SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT
BELOW THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL
MAY PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
MAY BE HARMFUL IF INHALED.
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
SKIN CONTACT: MAY BE HARMFUL IN CONTACT WITH SKIN.
CONTACT WITH THE SKIN DURING PRODUCT USE IS NOT EXPECTED TO RESULT IN
SIGNIFICANT IRRITATION.
ALLERGIC SKIN REACTION (NON-PHOTO INDUCED):
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, BLISTERING, AND ITCHING.
EYE CONTACT:
SEVERE EYE IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE SIGNIFICANT REDNESS, SWELLING, PAIN, TEARING,
CLOUDY APPEARANCE OF THE CORNEA, AND IMPAIRED VISION.
INGESTION:
GASTROINTESTINAL IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA, VOMITING
AND DIARRHEA.
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT DERMAL NO DATA AVAILABLE;
CALCULATED ATE:
2,000 - 5,000 MG/KG
OVERALL PRODUCT INHALATION- NO DATA AVAILABLE;
DUST/MIST CALCULATED ATE:
(4 HR) 5 - 12.5 MG/L
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE:
>5,000 MG/KG
BENZOYL PEROXIDE DERMAL LD50 ESTIMATED TO BE:
2,000 - 5,000 MG/KG
BENZOYL PEROXIDE INHALATION- RAT LC50: >24.3 MG/L
DUST/MIST
(4 HOURS)
BENZOYL PEROXIDE INGESTION RAT LD50: >5,000 MG/KG
BENZOIC ACID, DERMAL RABBIT LD50: >2,000 MG/KG
C9-11-BRANCHED
ALKYL ESTERS
BENZOIC ACID, INHALATION- RAT LC50: >5 MG/L
C9-11-BRANCHED DUST/MIST
ALKYL ESTERS (4 HOURS)
BENZOIC ACID, INGESTION RAT LD50: >5,000 MG/KG
C9-11-BRANCHED
ALKYL ESTERS
ZINC STEARATE DERMAL RABBIT LD50: >2,000 MG/KG
ZINC STEARATE INHALATION- RAT LC50: >50 MG/L
DUST/MIST
(4 HOURS)
ZINC STEARATE INGESTION RAT LD50: >5,000 MG/KG
CALCIUM SULFATE DERMAL PROFESSIONAL LD50 ESTIMATED TO BE:
JUDGEMENT >5,000 MG/KG
OXIRANE, POLYMER DERMAL RABBIT LD50: >16,960 MG/KG
WITH METHYLOXIRANE,
MONOBUTYL ETHER
CALCIUM SULFATE INGESTION RAT LD50: >5,000 MG/KG
OXIRANE, POLYMER INHALATION- RAT LC50: >5 MG/L
WITH METHYLOXIRANE, DUST/MIST
MONOBUTYL ETHER (4 HOURS)
OXIRANE, POLYMER INGESTION RAT LD50: 4,240 MG/KG
WITH METHYLOXIRANE,
MONOBUTYL ETHER
IRON OXIDE (FE2O3) DERMAL NOT LD50: 3,100 MG/KG
AVAILABLE
IRON OXIDE (FE2O3) INGESTION NOT LD50: 3,700 MG/KG
AVAILABLE
FERRIC AMMONIUM DERMAL LD50 ESTIMATED TO BE:
FERROCYANIDE >5,000 MG/KG
FERRIC FERROCYANIDE DERMAL LD50 ESTIMATED TO BE:
>5,000 MG/KG
FERRIC AMMONIUM INGESTION RAT LD50: >5,110 MG/KG
FERROCYANIDE
FERRIC FERROCYANIDE INGESTION RAT LD50: >8,000 MG/KG
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
BENZOYL PEROXIDE RABBIT MINIMAL IRRITATION
ZINC STEARATE RABBIT NO SIGNIFICANT IRRITATION
OXIRANE, POLYMER WITH RABBIT MINIMAL IRRITATION
METHYLOXIRANE, MONOBUTYL ETHER
IRON OXIDE (FE2O3) RABBIT NO SIGNIFICANT IRRITATION
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
BENZOYL PEROXIDE RABBIT SEVERE IRRITANT
ZINC STEARATE RABBIT NO SIGNIFICANT IRRITATION
OXIRANE, POLYMER WITH RABBIT NO SIGNIFICANT IRRITATION
METHYLOXIRANE, MONOBUTYL ETHER
IRON OXIDE (FE2O3) RABBIT NO SIGNIFICANT IRRITATION
SKIN SENSITIZATION:
NAME SPECIES VALUE
BENZOYL PEROXIDE GUINEA PIG SENSITIZING
IRON OXIDE (FE2O3) HUMAN SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT FOR
CLASSIFICATION
RESPIRATORY SENSITIZATION:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR
THE DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
BENZOYL PEROXIDE IN VITRO NOT MUTAGENIC
BENZOYL PEROXIDE IN VIVO NOT MUTAGENIC
IRON OXIDE (FE2O3) IN VITRO NOT MUTAGENIC
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
BENZOYL PEROXIDE INGESTION MULTIPLE NOT CARCINOGENIC
ANIMAL
SPECIES
BENZOYL PEROXIDE DERMAL MOUSE SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
OXIRANE, POLYMER INGESTION RAT NOT CARCINOGENIC
WITH METHYLOXIRANE,
MONOBUTYL ETHER
IRON OXIDE (FE2O3) INHALATION HUMAN SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE
BENZOYL PEROXIDE INGESTION NOT TOXIC TO FEMALE REPRODUCTION
BENZOYL PEROXIDE INGESTION SOME POSITIVE MALE REPRODUCTIVE
DATA EXIST, BUT THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION
BENZOYL PEROXIDE INGESTION SOME POSITIVE DEVELOPMENTAL DATA
EXIST, BUT THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION
OXIRANE, POLYMER INHALATION SOME POSITIVE MALE REPRODUCTIVE
WITH METHYLOXIRANE, DATA EXIST, BUT THE DATA ARE NOT
MONOBUTYL ETHER SUFFICIENT FOR CLASSIFICATION
NAME SPECIES TEST RESULT EXPOSURE DURATION
BENZOYL PEROXIDE RAT NOAEL: PREMATING &
1,000 MG/KG/DAY DURING GESTATION
BENZOYL PEROXIDE RAT NOAEL: PREMATING &
500 MG/KG/DAY DURING GESTATION
BENZOYL PEROXIDE RAT NOAEL: PREMATING &
500 MG/KG/DAY DURING GESTATION
OXIRANE, POLYMER RAT NOAEL: 1 MG/L 2 WEEKS
WITH METHYLOXIRANE,
MONOBUTYL ETHER
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
OXIRANE, POLYMER INGESTION NERVOUS SYSTEM SOME POSITIVE DATA
WITH METHYLOXIRANE, EXIST, BUT THE DATA
MONOBUTYL ETHER ARE NOT SUFFICIENT
FOR CLASSIFICATION
NAME SPECIES TEST RESULT EXPOSURE DURATION
OXIRANE, POLYMER RAT NOAEL:
WITH METHYLOXIRANE, NOT AVAILABLE
MONOBUTYL ETHER
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
OXIRANE, POLYMER INHALATION ENDOCRINE SYSTEM SOME POSITIVE DATA
WITH METHYLOXIRANE, HEMATOPOIETIC EXIST, BUT THE DATA
MONOBUTYL ETHER SYSTEM ARE NOT SUFFICIENT
LIVER FOR CLASSIFICATION
NERVOUS SYSTEM
OXIRANE, POLYMER INHALATION KIDNEY AND/OR SOME POSITIVE DATA
WITH METHYLOXIRANE, BLADDER EXIST, BUT THE DATA
MONOBUTYL ETHER ARE NOT SUFFICIENT
FOR CLASSIFICATION
OXIRANE, POLYMER INHALATION RESPIRATORY SOME POSITIVE DATA
WITH METHYLOXIRANE, SYSTEM EXIST, BUT THE DATA
MONOBUTYL ETHER ARE NOT SUFFICIENT
FOR CLASSIFICATION
OXIRANE, POLYMER INHALATION HEART ALL DATA ARE
WITH METHYLOXIRANE, NEGATIVE
MONOBUTYL ETHER
OXIRANE, POLYMER INGESTION LIVER SOME POSITIVE DATA
WITH METHYLOXIRANE, KIDNEY AND/OR EXIST, BUT THE DATA
MONOBUTYL ETHER BLADDER ARE NOT SUFFICIENT
FOR CLASSIFICATION
OXIRANE, POLYMER INGESTION HEMATOPOIETIC ALL DATA ARE
WITH METHYLOXIRANE, SYSTEM NEGATIVE
MONOBUTYL ETHER
OXIRANE, POLYMER INGESTION HEART ALL DATA ARE
WITH METHYLOXIRANE, ENDOCRINE SYSTEM NEGATIVE
MONOBUTYL ETHER RESPIRATORY
SYSTEM
IRON OXIDE (FE2O3) INHALATION PULMONARY FIBROSIS SOME POSITIVE DATA
PNEUMOCONIOSIS EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
NAME SPECIES TEST RESULT EXPOSURE DURATION
OXIRANE, POLYMER RAT NOAEL: 1 MG/L 2 WEEKS
WITH METHYLOXIRANE,
MONOBUTYL ETHER
OXIRANE, POLYMER RAT NOAEL: 2 WEEKS
WITH METHYLOXIRANE, 0.005 MG/L
MONOBUTYL ETHER
OXIRANE, POLYMER RAT LOAEL: 2 WEEKS
WITH METHYLOXIRANE, 0.001 MG/L
MONOBUTYL ETHER
OXIRANE, POLYMER RAT NOAEL: 0.5 MG/L 2 WEEKS
WITH METHYLOXIRANE,
MONOBUTYL ETHER
OXIRANE, POLYMER RAT NOAEL: 90 DAYS
WITH METHYLOXIRANE, 145 MG/KG/DAY
MONOBUTYL ETHER
OXIRANE, POLYMER RAT NOAEL: 2 YEARS
WITH METHYLOXIRANE, 500 MG/KG/DAY
MONOBUTYL ETHER
OXIRANE, POLYMER RAT NOAEL: 90 DAYS
WITH METHYLOXIRANE, 3,770 MG/KG/DAY
MONOBUTYL ETHER
IRON OXIDE (FE2O3) HUMAN NOAEL: OCCUPATIONAL
NOT AVAILABLE EXPOSURE
ASPIRATION HAZARD:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR
THE DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
INCINERATE UNCURED PRODUCT IN A PERMITTED WASTE INCINERATION FACILITY.
PROPER DESTRUCTION MAY REQUIRE THE USE OF ADDITIONAL FUEL DURING
INCINERATION PROCESSES. EMPTY DRUMS/BARRELS/CONTAINERS USED FOR
TRANSPORTING AND HANDLING HAZARDOUS CHEMICALS (CHEMICAL
SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS HAZARDOUS AS PER
APPLICABLE REGULATIONS) SHALL BE CONSIDERED, STORED, TREATED & DISPOSED
OF AS HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY APPLICABLE WASTE
REGULATIONS. CONSULT WITH THE RESPECTIVE REGULATING AUTHORITIES TO
DETERMINE THE AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
311/312 HAZARD CATEGORIES:
FIRE HAZARD: YES
PRESSURE HAZARD: NO
REACTIVITY HAZARD: YES
IMMEDIATE HAZARD: YES
DELAYED HAZARD: YES
SECTION 313 TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF
THAT SECTION AND 40 CFR PART 372 (EPCRA):
INGREDIENT C.A.S. NO % BY WT
ZINC STEARATE (ZINC COMPOUNDS) 557-05-1 3 - 7
BENZOYL PEROXIDE 94-36-0 TRADE SECRET 30 - 60
FERRIC FERROCYANIDE (CYANIDES) 14038-43-8 0 - 1
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 2
FLAMMABILITY 2
INSTABILITY 1
SPECIAL HAZARDS OXIDIZER
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED
FOR USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS
OF FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED
ON THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO
INCLUDE THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT
ARE KNOWN TO BE GENERATED IN SIGNIFICANT QUANTITIES.
HMIS HAZARD CLASSIFICATION:
HEALTH 2
FLAMMABILITY 1
PHYSICAL HAZARD 1
PERSONAL PROTECTION X - SEE PPE SECTION.
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM (HMIS(R*) IV) HAZARD RATINGS ARE
DESIGNED TO INFORM EMPLOYEES OF CHEMICAL HAZARDS IN THE WORKPLACE. THESE
RATINGS ARE BASED ON THE INHERENT PROPERTIES OF THE MATERIAL UNDER EXPECTED
CONDITIONS OF NORMAL USE AND ARE NOT INTENDED FOR USE IN EMERGENCY
SITUATIONS. HMIS(R*) IV RATINGS ARE TO BE USED WITH A FULLY IMPLEMENTED
HMIS(R*) IV PROGRAM. HMIS(R*) IS A REGISTERED MARK OF THE AMERICAN COATINGS
ASSOCIATION (ACA).
DOCUMENT GROUP: 29-5993-0
VERSION NUMBER: 3.04
ISSUE DATE: 02/06/17
SUPERCEDES DATE: 12/15/16
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED
IN ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
3M USA SDSS ARE AVAILABLE AT WWW.3M.COM