| Common Name: | FOAM AND FABRIC 24 SPRAY ADHESIVE, ORANGE |
| Manufacturer: | 3M |
| SDS Revision Date: | 4/24/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 6KWY0 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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3M(TM) FOAM AND FABRIC 24 SPRAY ADHESIVE, ORANGE
04/24/15
3M
SAFETY DATA SHEET
COPYRIGHT, 2015, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 27-0728-9
VERSION NUMBER: 2.00
ISSUE DATE: 04/24/15
SUPERCEDES DATE: 05/17/10
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER: 3M(TM) FOAM AND FABRIC 24 SPRAY ADHESIVE, ORANGE
PRODUCT IDENTIFICATION NUMBERS:
ID NUMBER UPC
62-4923-4920-4
62-4923-4925-3
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE: ADHESIVE AEROSOL, INDUSTRIAL USE
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: INDUSTRIAL ADHESIVES AND TAPES DIVISION
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
2.1. HAZARD CLASSIFICATION:
FLAMMABLE AEROSOL: CATEGORY 1.
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 2B.
REPRODUCTIVE TOXICITY: CATEGORY 2.
SIMPLE ASPHYXIANT.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): CATEGORY 1.
SPECIFIC TARGET ORGAN TOXICITY (CENTRAL NERVOUS SYSTEM): CATEGORY 3.
SPECIFIC TARGET ORGAN TOXICITY (RESPIRATORY IRRITATION): CATEGORY 3.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 1.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS:
FLAME
EXCLAMATION MARK
HEALTH HAZARD
PICTOGRAMS:
FLAME
EXCLAMATION MARK
HEALTH HAZARD
HAZARD STATEMENTS:
EXTREMELY FLAMMABLE AEROSOL.
CAUSES EYE IRRITATION.
MAY CAUSE RESPIRATORY IRRITATION.
MAY CAUSE DROWSINESS OR DIZZINESS.
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
MAY DISPLACE OXYGEN AND CAUSE RAPID SUFFOCATION.
CAUSES DAMAGE TO ORGANS: CARDIOVASCULAR SYSTEM
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE:
NERVOUS SYSTEM
PRECAUTIONARY STATEMENTS:
GENERAL: KEEP OUT OF REACH OF CHILDREN.
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING.
DO NOT SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE.
PRESSURIZED CONTAINER: DO NOT PIERCE OR BURN, EVEN AFTER USE.
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
WEAR PROTECTIVE GLOVES.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH THOROUGHLY AFTER HANDLING.
RESPONSE:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO.
CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
SPECIFIC TREATMENT (SEE NOTES TO PHYSICIAN ON THIS LABEL).
STORAGE:
PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING 50C/122F.
KEEP CONTAINER TIGHTLY CLOSED.
STORE LOCKED UP IN A WELL-VENTILATED PLACE.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
NOTES TO PHYSICIAN:
EXPOSURE MAY INCREASE MYOCARDIAL IRRITABILITY. DO NOT ADMINISTER
SYMPATHOMIMETIC DRUGS UNLESS ABSOLUTELY NECESSARY.
2.3. HAZARDS NOT OTHERWISE CLASSIFIED:
INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING CONTENTS CAN
BE HARMFUL OR FATAL.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
METHYL ACETATE 79-20-9 25 - 35 TRADE SECRET *
NON-HAZARDOUS COMPONENTS TRADE SECRET* 15 - 30 TRADE SECRET *
(N.J.T.S. REG NO. 4499600-6763)
DIMETHYL ETHER 115-10-6 15 - 25 TRADE SECRET *
HEXANE 110-54-3 10 - 20 TRADE SECRET *
PROPANE 74-98-6 5 - 10 TRADE SECRET *
ISOBUTANE 75-28-5 5 - 10 TRADE SECRET *
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION)
OF THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION: REMOVE PERSON TO FRESH AIR. GET MEDICAL ATTENTION.
SKIN CONTACT:
WASH WITH SOAP AND WATER. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL
ATTENTION.
EYE CONTACT:
FLUSH WITH LARGE AMOUNTS OF WATER. REMOVE CONTACT LENSES IF EASY TO DO.
CONTINUE RINSING. IF SIGNS/SYMPTOMS PERSIST, GET MEDICAL ATTENTION.
IF SWALLOWED: RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED:
EXPOSURE MAY INCREASE MYOCARDIAL IRRITABILITY. DO NOT ADMINISTER
SYMPATHOMIMETIC DRUGS UNLESS ABSOLUTELY NECESSARY.
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
USE A FIRE FIGHTING AGENT SUITABLE FOR THE SURROUNDING FIRE.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
CLOSED CONTAINERS EXPOSED TO HEAT FROM FIRE MAY BUILD PRESSURE AND EXPLODE.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
TOXIC VAPOR, GAS, PARTICULATE DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
WATER MAY NOT EFFECTIVELY EXTINGUISH FIRE; HOWEVER, IT SHOULD BE USED TO
KEEP FIRE-EXPOSED CONTAINERS AND SURFACES COOL AND PREVENT EXPLOSIVE
RUPTURE.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING.
USE ONLY NON-SPARKING TOOLS. VENTILATE THE AREA WITH FRESH AIR.
WARNING!
A MOTOR COULD BE AN IGNITION SOURCE AND COULD CAUSE FLAMMABLE GASES OR
VAPORS IN THE SPILL AREA TO BURN OR EXPLODE. REFER TO OTHER SECTIONS OF
THIS SDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH HAZARDS,
RESPIRATORY PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS: AVOID RELEASE TO THE ENVIRONMENT.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
IF POSSIBLE, SEAL LEAKING CONTAINER. PLACE LEAKING CONTAINERS IN A
WELL-VENTILATED AREA, PREFERABLY AN OPERATING EXHAUST HOOD, OR IF
NECESSARY OUTDOORS ON AN IMPERMEABLE SURFACE UNTIL APPROPRIATE PACKAGING
FOR THE LEAKING CONTAINER OR ITS CONTENTS IS AVAILABLE. CONTAIN SPILL.
COVER SPILL AREA WITH A FIRE-EXTINGUISHING FOAM. AN APPROPRIATE AQUEOUS
FILM FORMING FOAM (AFFF) IS RECOMMENDED. WORKING FROM AROUND THE EDGES OF
THE SPILL INWARD, COVER WITH BENTONITE, VERMICULITE, OR COMMERCIALLY
AVAILABLE INORGANIC ABSORBENT MATERIAL. MIX IN SUFFICIENT ABSORBENT UNTIL
IT APPEARS DRY. REMEMBER, ADDING AN ABSORBENT MATERIAL DOES NOT REMOVE A
PHYSICAL, HEALTH, OR ENVIRONMENTAL HAZARD. COLLECT AS MUCH OF THE SPILLED
MATERIAL AS POSSIBLE USING NON-SPARKING TOOLS. PLACE IN A METAL CONTAINER
APPROVED FOR TRANSPORTATION BY APPROPRIATE AUTHORITIES. CLEAN UP RESIDUE
WITH AN APPROPRIATE SOLVENT SELECTED BY A QUALIFIED AND AUTHORIZED PERSON.
VENTILATE THE AREA WITH FRESH AIR. READ AND FOLLOW SAFETY PRECAUTIONS ON
THE SOLVENT LABEL AND SDS. SEAL THE CONTAINER. DISPOSE OF COLLECTED
MATERIAL AS SOON AS POSSIBLE.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
KEEP OUT OF REACH OF CHILDREN. DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS
HAVE BEEN READ AND UNDERSTOOD. KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT
SURFACES. - NO SMOKING. DO NOT SPRAY ON AN OPEN FLAME OR OTHER IGNITION
SOURCE. DO NOT PIERCE OR BURN, EVEN AFTER USE. DO NOT BREATHE
DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN EYES, ON SKIN, OR ON
CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH
THOROUGHLY AFTER HANDLING. AVOID RELEASE TO THE ENVIRONMENT. AVOID CONTACT
WITH OXIDIZING AGENTS (EG. CHLORINE, CHROMIC ACID ETC.) USE PERSONAL
PROTECTIVE EQUIPMENT (GLOVES, RESPIRATORS, ETC.) AS REQUIRED.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. PROTECT
FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING 50C/122F. STORE
AWAY FROM HEAT. STORE AWAY FROM ACIDS. STORE AWAY FROM OXIDIZING AGENTS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL
COMMENTS
HEXANE 110-54-3 ACGIH TWA: 50 PPM SKIN NOTATION
HEXANE 110-54-3 OSHA TWA:
1800 MG/M3
(500 PPM)
DIMETHYL ETHER 115-10-6 AIHA TWA:
1880 MG/M3
(1000 PPM)
DIMETHYL ETHER 115-10-6 CMRG TWA: 1000 PPM
PROPANE 74-98-6 ACGIH LIMIT VALUE NOT
ESTABLISHED:
PROPANE 74-98-6 OSHA TWA:
1800 MG/M3
(1000 PPM)
ISOBUTANE 75-28-5 ACGIH STEL: 1000 PPM
NATURAL GAS 75-28-5 ACGIH LIMIT VALUE NOT
ESTABLISHED:
METHYL ACETATE 79-20-9 ACGIH TWA: 200 PPM
STEL: 250 PPM
METHYL ACETATE 79-20-9 OSHA TWA:
610 MG/M3
(200 PPM)
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
DO NOT REMAIN IN AREA WHERE AVAILABLE OXYGEN MAY BE REDUCED. USE GENERAL
DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO CONTROL AIRBORNE
EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR CONTROL
DUST/FUME/GAS/MIST/VAPORS/SPRAY.
IF VENTILATION IS NOT ADEQUATE, USE RESPIRATORY PROTECTION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING EYE/FACE PROTECTION(S) ARE RECOMMENDED:
INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT
LOCAL STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED:
BUTYL RUBBER
FLUOROELASTOMER
NITRILE RUBBER
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM.
BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT FROM THE FOLLOWING
RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE SUPPLIED-AIR RESPIRATOR
ORGANIC VAPOR RESPIRATORS MAY HAVE SHORT SERVICE LIFE.
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: LIQUID
SPECIFIC PHYSICAL FORM: AEROSOL
ODOR, COLOR, GRADE: ORANGE COLOR, MILD SOLVENT ODOR
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
MELTING POINT: NO DATA AVAILABLE
FLASH POINT: -137 DEG. F [DETAILS: PROPELLANT]
EVAPORATION RATE: 1.90 [REF STD: ETHER=1]
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLAMMABLE LIMITS(LEL): NO DATA AVAILABLE
FLAMMABLE LIMITS(UEL): NO DATA AVAILABLE
VAPOR PRESSURE: NO DATA AVAILABLE
VAPOR DENSITY: 2.97 [REF STD: AIR=1]
DENSITY: 0.73 - 0.77 G/ML
SPECIFIC GRAVITY: 0.73 - 0.77 [REF STD: WATER=1]
SOLUBILITY IN WATER: NIL
SOLUBILITY-NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: NOT APPLICABLE
HAZARDOUS AIR POLLUTANTS: 16.8% WEIGHT [TEST METHOD: CALCULATED]
VOLATILE ORGANIC COMPOUNDS:
388 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1] [DETAILS: MATERIAL VOC]
VOLATILE ORGANIC COMPOUNDS:
51.8% [TEST METHOD: CALCULATED PER CARB TITLE 2]
PERCENT VOLATILE: 77% WEIGHT
SOLIDS CONTENT: 17.3%
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN
CONDITIONS - SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID: HEAT
10.5. INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
NONE KNOWN.
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING
COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL
MAY PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
INTENTIONAL CONCENTRATION AND INHALATION MAY BE HARMFUL OR FATAL.
SIMPLE ASPHYXIATION:
SIGNS/SYMPTOMS MAY INCLUDE INCREASED HEART RATE, RAPID RESPIRATIONS,
DROWSINESS, HEADACHE, INCOORDINATION, ALTERED JUDGEMENT, NAUSEA, VOMITING,
LETHARGY, SEIZURES, COMA, AND MAY BE FATAL.
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
SKIN CONTACT:
MILD SKIN IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, AND
DRYNESS.
EYE CONTACT:
MODERATE EYE IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, PAIN, TEARING, AND BLURRED
OR HAZY VISION.
INGESTION:
GASTROINTESTINAL IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA, VOMITING
AND DIARRHEA.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
ADDITIONAL HEALTH EFFECTS:
SINGLE EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS:
CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION:
SIGNS/SYMPTOMS MAY INCLUDE HEADACHE, DIZZINESS, DROWSINESS, INCOORDINATION,
NAUSEA, SLOWED REACTION TIME, SLURRED SPEECH, GIDDINESS, AND
UNCONSCIOUSNESS.
CARDIAC SENSITIZATION:
SIGNS/SYMPTOMS MAY INCLUDE IRREGULAR HEARTBEAT (ARRHYTHMIA), FAINTNESS,
CHEST PAIN, AND MAY BE FATAL.
PROLONGED OR REPEATED EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS:
PERIPHERAL NEUROPATHY:
SIGNS/SYMPTOMS MAY INCLUDE TINGLING OR NUMBNESS OF THE EXTREMITIES,
INCOORDINATION, WEAKNESS OF THE HANDS AND FEET, TREMORS AND MUSCLE
ATROPHY.
REPRODUCTIVE/DEVELOPMENTAL TOXICITY:
CONTAINS A CHEMICAL OR CHEMICALS WHICH CAN CAUSE BIRTH DEFECTS OR OTHER
REPRODUCTIVE HARM.
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE:
>5,000 MG/KG
METHYL ACETATE DERMAL RAT LD50: >2,000 MG/KG
METHYL ACETATE INHALATION- RAT LC50: >49 MG/L
VAPOR
(4 HOURS)
METHYL ACETATE INGESTION RAT LD50: >5,000 MG/KG
HEXANE DERMAL RABBIT LD50: >2,000 MG/KG
HEXANE INHALATION- RAT LC50: 170 MG/L
VAPOR
(4 HOURS)
HEXANE INGESTION RAT LD50: >28,700 MG/KG
DIMETHYL ETHER INHALATION- RAT LC50: 164,000 PPM
GAS
(4 HOURS)
ISOBUTANE INHALATION- RAT LC50: 276,000 PPM
GAS
(4 HOURS)
PROPANE INHALATION- RAT LC50: >200,000 PPM
GAS
(4 HOURS)
NON-HAZARDOUS COMPONENTS DERMAL NOT LD50: >2,000 MG/KG
(N.J.T.S. REG NO. AVAILABLE
4499600-6763)
NON-HAZARDOUS COMPONENTS INGESTION NOT LD50: >2,000 MG/KG
(N.J.T.S. REG NO. AVAILABLE
4499600-6763)
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
METHYL ACETATE RABBIT NO SIGNIFICANT IRRITATION
HEXANE HUMAN AND MILD IRRITANT
ANIMAL
ISOBUTANE PROFESSIONAL NO SIGNIFICANT IRRITATION
JUDGEMENT
PROPANE RABBIT MINIMAL IRRITATION
NON-HAZARDOUS COMPONENTS PROFESSIONAL NO SIGNIFICANT IRRITATION
(N.J.T.S. REG NO. 4499600-6763) JUDGEMENT
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
METHYL ACETATE RABBIT MODERATE IRRITANT
HEXANE RABBIT MILD IRRITANT
ISOBUTANE PROFESSIONAL NO SIGNIFICANT IRRITATION
JUDGEMENT
PROPANE RABBIT MILD IRRITANT
NON-HAZARDOUS COMPONENTS PROFESSIONAL NO SIGNIFICANT IRRITATION
(N.J.T.S. REG NO. 4499600-6763) JUDGEMENT
SKIN SENSITIZATION:
NAME SPECIES VALUE
METHYL ACETATE HUMAN NOT SENSITIZING
HEXANE HUMAN NOT SENSITIZING
NON-HAZARDOUS COMPONENTS NOT SENSITIZING
(N.J.T.S. REG NO. 4499600-6763)
RESPIRATORY SENSITIZATION:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR
THE DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
METHYL ACETATE IN VITRO NOT MUTAGENIC
METHYL ACETATE IN VIVO NOT MUTAGENIC
HEXANE IN VITRO NOT MUTAGENIC
HEXANE IN VIVO NOT MUTAGENIC
DIMETHYL ETHER IN VITRO NOT MUTAGENIC
DIMETHYL ETHER IN VIVO NOT MUTAGENIC
ISOBUTANE IN VITRO NOT MUTAGENIC
PROPANE IN VITRO NOT MUTAGENIC
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
HEXANE DERMAL MOUSE NOT CARCINOGENIC
HEXANE INHALATION MOUSE SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
DIMETHYL ETHER INHALATION RAT NOT CARCINOGENIC
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE
HEXANE INGESTION NOT TOXIC TO DEVELOPMENT
HEXANE INHALATION SOME POSITIVE DEVELOPMENTAL DATA
EXIST, BUT THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION
HEXANE INGESTION TOXIC TO MALE REPRODUCTION
HEXANE INHALATION TOXIC TO MALE REPRODUCTION
DIMETHYL ETHER INHALATION NOT TOXIC TO FEMALE REPRODUCTION
DIMETHYL ETHER INHALATION NOT TOXIC TO MALE REPRODUCTION
DIMETHYL ETHER INHALATION NOT TOXIC TO DEVELOPMENT
NAME SPECIES TEST RESULT EXPOSURE DURATION
HEXANE MOUSE NOAEL: 2,200 MG/KG/DAY DURING ORGANOGENESIS
HEXANE RAT NOAEL: 0.7 MG/L DURING GESTATION
HEXANE RAT NOAEL: 1,140 MG/KG/DAY 90 DAYS
HEXANE RAT LOAEL: 3.52 MG/L 28 DAYS
DIMETHYL ETHER RAT NOAEL: 25,000 PPM 2 YEARS
DIMETHYL ETHER RAT NOAEL: 25,000 PPM 2 YEARS
DIMETHYL ETHER RAT NOAEL: 40,000 PPM DURING ORGANOGENESIS
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
METHYL ACETATE INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
METHYL ACETATE INHALATION RESPIRATORY MAY CAUSE RESPIRATORY
IRRITATION IRRITATION
METHYL ACETATE INHALATION BLINDNESS SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
METHYL ACETATE INGESTION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
HEXANE INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
HEXANE INHALATION RESPIRATORY SOME POSITIVE DATA
IRRITATION EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
HEXANE INHALATION RESPIRATORY SOME POSITIVE DATA
SYSTEM EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
DIMETHYL ETHER INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
DIMETHYL ETHER INHALATION CARDIAC SOME POSITIVE DATA
SENSITIZATION EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
ISOBUTANE INHALATION CARDIAC CAUSES DAMAGE TO ORGANS
SENSITIZATION
ISOBUTANE INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
ISOBUTANE INHALATION RESPIRATORY ALL DATA ARE NEGATIVE
IRRITATION
PROPANE INHALATION CARDIAC CAUSES DAMAGE TO ORGANS
SENSITIZATION
PROPANE INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
PROPANE INHALATION RESPIRATORY ALL DATA ARE NEGATIVE
IRRITATION
NAME SPECIES TEST RESULT EXPOSURE DURATION
METHYL ACETATE HUMAN AND NOAEL: NOT AVAILABLE
ANIMAL
METHYL ACETATE HUMAN AND NOAEL: NOT AVAILABLE
ANIMAL
METHYL ACETATE NOAEL: NOT AVAILABLE
METHYL ACETATE NOAEL: NOT AVAILABLE
HEXANE HUMAN NOAEL: NOT AVAILABLE NOT AVAILABLE
HEXANE RABBIT NOAEL: NOT AVAILABLE 8 HOURS
HEXANE RAT NOAEL: 24.6 MG/L 8 HOURS
DIMETHYL ETHER RAT LOAEL: 10,000 PPM 30 MINUTES
DIMETHYL ETHER DOG NOAEL: 100,000 PPM 5 MINUTES
ISOBUTANE MULTIPLE NOAEL: NOT AVAILABLE
ANIMAL
SPECIES
ISOBUTANE HUMAN AND NOAEL: NOT AVAILABLE
ANIMAL
ISOBUTANE MOUSE NOAEL: NOT AVAILABLE
PROPANE HUMAN NOAEL: NOT AVAILABLE
PROPANE HUMAN NOAEL: NOT AVAILABLE
PROPANE HUMAN NOAEL: NOT AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
METHYL ACETATE INHALATION RESPIRATORY SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
METHYL ACETATE INHALATION ENDOCRINE SYSTEM SOME POSITIVE DATA
HEMATOPOIETIC EXIST, BUT THE DATA
SYSTEM ARE NOT SUFFICIENT
LIVER FOR CLASSIFICATION
IMMUNE SYSTEM
KIDNEY AND/OR
BLADDER
HEXANE INHALATION PERIPHERAL NERVOUS CAUSES DAMAGE TO ORGANS
SYSTEM THROUGH PROLONGED OR
REPEATED EXPOSURE
HEXANE INHALATION RESPIRATORY SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
HEXANE INHALATION LIVER SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
HEXANE INHALATION KIDNEY AND/OR SOME POSITIVE DATA
BLADDER EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
HEXANE INHALATION HEMATOPOIETIC SOME POSITIVE DATA
SYSTEM EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
HEXANE INHALATION AUDITORY SYSTEM SOME POSITIVE DATA
IMMUNE SYSTEM EXIST, BUT THE DATA
EYES ARE NOT SUFFICIENT
FOR CLASSIFICATION
HEXANE INHALATION HEART ALL DATA ARE NEGATIVE
SKIN
ENDOCRINE SYSTEM
HEXANE INGESTION PERIPHERAL NERVOUS SOME POSITIVE DATA
SYSTEM EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
HEXANE INGESTION ENDOCRINE SYSTEM SOME POSITIVE DATA
HEMATOPOIETIC EXIST, BUT THE DATA
SYSTEM ARE NOT SUFFICIENT
LIVER FOR CLASSIFICATION
IMMUNE SYSTEM
KIDNEY AND/OR
BLADDER
DIMETHYL ETHER INHALATION HEMATOPOIETIC SOME POSITIVE DATA
SYSTEM EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
DIMETHYL ETHER INHALATION LIVER SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
ISOBUTANE INHALATION KIDNEY AND/OR SOME POSITIVE DATA
BLADDER EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
NAME SPECIES TEST RESULT EXPOSURE DURATION
METHYL ACETATE RAT NOAEL: 1.1 MG/L 28 DAYS
METHYL ACETATE RAT NOAEL: 6.1 MG/L 28 DAYS
HEXANE HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL
EXPOSURE
HEXANE MOUSE LOAEL: 1.76 MG/L 13 WEEKS
HEXANE RAT NOAEL: NOT AVAILABLE 6 MONTHS
HEXANE RAT LOAEL: 1.76 MG/L 6 MONTHS
HEXANE MOUSE NOAEL: 35.2 MG/L 13 WEEKS
HEXANE HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL
EXPOSURE
HEXANE RAT NOAEL: 1.76 MG/L 6 MONTHS
HEXANE RAT NOAEL: 1,140 MG/KG/DAY 90 DAYS
HEXANE RAT NOAEL: NOT AVAILABLE 13 WEEKS
DIMETHYL ETHER RAT NOAEL: 25,000 PPM 2 YEARS
DIMETHYL ETHER RAT NOAEL: 20,000 PPM 30 WEEKS
ISOBUTANE RAT NOAEL: 4,500 PPM 13 WEEKS
ASPIRATION HAZARD:
NAME VALUE
HEXANE ASPIRATION HAZARD
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
INCINERATE IN A PERMITTED WASTE INCINERATION FACILITY. FACILITY MUST BE
CAPABLE OF HANDLING AEROSOL CANS. AS A DISPOSAL ALTERNATIVE, UTILIZE AN
ACCEPTABLE PERMITTED WASTE DISPOSAL FACILITY. EMPTY
DRUMS/BARRELS/CONTAINERS USED FOR TRANSPORTING AND HANDLING HAZARDOUS
CHEMICALS (CHEMICAL SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS
HAZARDOUS AS PER APPLICABLE REGULATIONS) SHALL BE CONSIDERED, STORED,
TREATED & DISPOSED OF AS HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY
APPLICABLE WASTE REGULATIONS. CONSULT WITH THE RESPECTIVE REGULATING
AUTHORITIES TO DETERMINE THE AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
EPA HAZARDOUS WASTE NUMBER (RCRA): D001 (IGNITABLE)
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
311/312 HAZARD CATEGORIES:
FIRE HAZARD: YES
PRESSURE HAZARD: YES
REACTIVITY HAZARD: NO
IMMEDIATE HAZARD: YES
DELAYED HAZARD: YES
SECTION 313 TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF THAT
SECTION AND 40 CFR PART 372 (EPCRA):
INGREDIENT C.A.S. NO % BY WT
HEXANE 110-54-3 10 - 20
HEXANE (HEXANE) 110-54-3 10 - 20
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA. CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 2
FLAMMABILITY 4
INSTABILITY 0
SPECIAL HAZARDS NONE
AEROSOL STORAGE CODE: 3
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED
FOR USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED
ON THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO
INCLUDE THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT
ARE KNOWN TO BE GENERATED IN SIGNIFICANT QUANTITIES.
DOCUMENT GROUP: 27-0728-9
VERSION NUMBER: 2.00
ISSUE DATE: 04/24/15
SUPERCEDES DATE: 05/17/10
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AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY
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SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
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INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
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