| Common Name: | ZEREX ASIAN VEHICLE RED 50/50 ANTIFREEZE COOLANT |
| Manufacturer: | VALVOLINE |
| SDS Revision Date: | 11/4/2021 |
| SDS Format: | No Format Specified |
| Item Number(s): | 453A65, 6MGK1 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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V(TM)
VALVOLINE(TM)
SAFETY DATA SHEET
ZEREX(TM) ASIAN VEHICLE RED 50/50
ANTIFREEZE COOLANT
VERSION: 1.6
REVISION DATE: 11/04/2021
PRINT DATE: 06/21/2022
29 CFR 1910.1200 (OSHA HAZCOM 2012)
| SECTION 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT IDENTIFIER:
TRADE NAME:
ZEREX(TM) ASIAN VEHICLE RED 50/50
ANTIFREEZE COOLANT
PRODUCT CODE: 675130
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
VALVOLINE LLC
100 VALVOLINE WAY
LEXINGTON, KY 40509
UNITED STATES OF AMERICA
(USA)
1-800-TEAMVAL (1-800-832-6825)
SDS@VALVOLINE.COM
EMERGENCY TELEPHONE NUMBER: 1-800-VALVOLINE (1-800-825-8654)
REGULATORY INFORMATION NUMBER: 1-800-TEAMVAL (1-800-832-6825)
PRODUCT INFORMATION: 1-800-TEAMVAL (1-800-832-6825)
| SECTION 2. HAZARDS IDENTIFICATION | |
GHS CLASSIFICATION:
ACUTE TOXICITY (ORAL): CATEGORY 4
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE (ORAL):
CATEGORY 2 (KIDNEY, LIVER)
GHS LABEL ELEMENTS:
HAZARD PICTOGRAMS:
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: WARNING
HAZARD STATEMENTS:
HARMFUL IF SWALLOWED.
MAY CAUSE DAMAGE TO ORGANS (KIDNEY, LIVER) THROUGH PROLONGED OR REPEATED
EXPOSURE IF SWALLOWED.
PRECAUTIONARY STATEMENTS:
PREVENTION:
DO NOT BREATHE MIST OR VAPORS.
WASH SKIN THOROUGHLY AFTER HANDLING.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
RESPONSE:
IF SWALLOWED:
CALL A POISON CENTER/ DOCTOR IF YOU FEEL UNWELL. RINSE MOUTH.
GET MEDICAL ADVICE/ ATTENTION IF YOU FEEL UNWELL.
DISPOSAL:
DISPOSE OF CONTENTS/ CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT.
OTHER HAZARDS: NONE KNOWN.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE / MIXTURE: MIXTURE
HAZARDOUS COMPONENTS:
CHEMICAL NAME CAS-NO. CLASSIFICATION CONCENTRATION (%)
ETHYLENE GLYCOL 107-21-1 ACUTE TOX. 4; H302 >=40.00 - <50.00
STOT RE 2; H373
SODIUM BENZOATE 532-32-1 EYE IRRIT. 2A; H319 >=1.50 - <500
DIPOTASSIUM PHOSPHATE 7758-11-4 ACUTE TOX. 3; H311 >=0.50 - <100
ACTUAL CONCENTRATION IS WITHHELD AS A TRADE SECRET
| SECTION 4. FIRST AID MEASURES | |
GENERAL ADVICE:
MOVE OUT OF DANGEROUS AREA.
SHOW THIS SAFETY DATA SHEET TO THE DOCTOR IN ATTENDANCE.
DO NOT LEAVE THE VICTIM UNATTENDED.
IF INHALED:
IF UNCONSCIOUS, PLACE IN RECOVERY POSITION AND SEEK MEDICAL ADVICE.
IF SYMPTOMS PERSIST, CALL A PHYSICIAN.
IN CASE OF EYE CONTACT:
FLUSH EYES WITH WATER AS A PRECAUTION.
REMOVE CONTACT LENSES.
PROTECT UNHARMED EYE.
KEEP EYE WIDE OPEN WHILE RINSING.
IF EYE IRRITATION PERSISTS, CONSULT A SPECIALIST.
IF SWALLOWED:
INDUCE VOMITING IMMEDIATELY AND CALL A PHYSICIAN.
KEEP RESPIRATORY TRACT CLEAR.
DO NOT GIVE MILK OR ALCOHOLIC BEVERAGES.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
IF SYMPTOMS PERSIST, CALL A PHYSICIAN.
TAKE VICTIM IMMEDIATELY TO HOSPITAL.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
HARMFUL IF SWALLOWED.
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE
IF SWALLOWED.
NO SYMPTOMS KNOWN OR EXPECTED.
NOTES TO PHYSICIAN:
NO HAZARDS WHICH REQUIRE SPECIAL FIRST AID MEASURES.
TREAT SYMPTOMATICALLY.
| SECTION 5. FIREFIGHTING MEASURES | |
UNSUITABLE EXTINGUISHING MEDIA: HIGH VOLUME WATER JET
HAZARDOUS COMBUSTION PRODUCTS: NO HAZARDOUS COMBUSTION PRODUCTS ARE KNOWN
SPECIFIC EXTINGUISHING METHODS:
FURTHER INFORMATION:
STANDARD PROCEDURE FOR CHEMICAL FIRES.
USE EXTINGUISHING MEASURES THAT ARE APPROPRIATE TO LOCAL CIRCUMSTANCES AND
THE SURROUNDING ENVIRONMENT.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
WEAR SELF-CONTAINED BREATHING APPARATUS FOR FIREFIGHTING IF NECESSARY.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
ENVIRONMENTAL PRECAUTIONS:
PREVENT PRODUCT FROM ENTERING DRAINS.
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO.
IF THE PRODUCT CONTAMINATES RIVERS AND LAKES OR DRAINS INFORM RESPECTIVE
AUTHORITIES.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SOAK UP WITH INERT ABSORBENT MATERIAL (E.G. SAND, SILICA GEL, ACID BINDER,
UNIVERSAL BINDER, SAWDUST).
KEEP IN SUITABLE, CLOSED CONTAINERS FOR DISPOSAL.
| SECTION 7. HANDLING AND STORAGE | |
ADVICE ON SAFE HANDLING:
DO NOT BREATHE VAPOURS/DUST.
FOR PERSONAL PROTECTION SEE SECTION 8.
SMOKING, EATING AND DRINKING SHOULD BE PROHIBITED IN THE APPLICATION AREA.
DISPOSE OF RINSE WATER IN ACCORDANCE WITH LOCAL AND NATIONAL REGULATIONS.
CONDITIONS FOR SAFE STORAGE:
KEEP CONTAINER TIGHTLY CLOSED IN A DRY AND WELL-VENTILATED PLACE.
ELECTRICAL INSTALLATIONS / WORKING MATERIALS MUST COMPLY WITH THE
TECHNOLOGICAL SAFETY STANDARDS.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
COMPONENTS WITH WORKPLACE CONTROL PARAMETERS:
COMPONENTS CAS-NO. VALUE TYPE CONTROL BASIS
(FORM OF PARAMETERS /
EXPOSURE) PERMISSIBLE
CONCENTRATION
ETHYLENE GLYCOL 107-21-1 TWA 25 PPM ACGIH
VAPOUR
STEL 50 PPM ACGIH
VAPOUR
STEL 10 MG/M3 ACGIH
INHALABLE
FRACTION,
AEROSOL ONLY
C 50 PPM OSHA P0
125 MG/M3
C 40 PPM CAL PEL
100 MG/M3
VAPOUR
PERSONAL PROTECTIVE EQUIPMENT:
RESPIRATORY PROTECTION:
NO PERSONAL RESPIRATORY PROTECTIVE EQUIPMENT NORMALLY REQUIRED.
HAND PROTECTION:
REMARKS:
THE SUITABILITY FOR A SPECIFIC WORKPLACE SHOULD BE DISCUSSED WITH
THE PRODUCERS OF THE PROTECTIVE GLOVES.
EYE PROTECTION:
EYE WASH BOTTLE WITH PURE WATER
TIGHTLY FITTING SAFETY GOGGLES
SKIN AND BODY PROTECTION:
IMPERVIOUS CLOTHING
CHOOSE BODY PROTECTION ACCORDING TO THE AMOUNT AND CONCENTRATION OF THE
DANGEROUS SUBSTANCE AT THE WORK PLACE.
HYGIENE MEASURES:
WHEN USING DO NOT EAT OR DRINK.
WHEN USING DO NOT SMOKE.
WASH HANDS BEFORE BREAKS AND AT THE END OF WORKDAY.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: LIQUID
COLOUR: PINK
ODOUR: NO DATA AVAILABLE
ODOUR THRESHOLD: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
MELTING POINT/FREEZING POINT: -34 DEG. F / -37 DEG. C
BOILING POINT/BOILING RANGE:
212 DEG. F / 100 DEG. C (1,013.333333 HPA)
CALCULATED PHASE TRANSITION LIQUID/GAS
FLASH POINT: >250 DEG. F / >121 DEG. C
EVAPORATION RATE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
SELF-IGNITION: NO DATA AVAILABLE
UPPER EXPLOSION LIMIT / UPPER FLAMMABILITY LIMIT: 15.3%(V)
GLP: CALCULATED EXPLOSIVE LIMIT
LOWER EXPLOSION LIMIT / LOWER FLAMMABILITY LIMIT: 3.2%(V)
GLP: CALCULATED EXPLOSIVE LIMIT
VAPOUR PRESSURE:
23.3333333 HPA (68 DEG. F / 20 DEG. C) CALCULATED VAPOR PRESSURE
RELATIVE VAPOUR DENSITY: NO DATA AVAILABLE
RELATIVE DENSITY: NO DATA AVAILABLE
DENSITY: 1.0827 G/CM3 (60.1 DEG. F / 15.6 DEG. C)
SOLUBILITY(IES):
WATER SOLUBILITY: NO DATA AVAILABLE
SOLUBILITY IN OTHER SOLVENTS: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY:
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
OXIDIZING PROPERTIES: NO DATA AVAILABLE
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY: NO DECOMPOSITION IF STORED AND APPLIED AS DIRECTED.
CHEMICAL STABILITY: NO DECOMPOSITION IF STORED AND APPLIED AS DIRECTED.
POSSIBILITY OF HAZARDOUS REACTIONS:
NO DECOMPOSITION IF STORED AND APPLIED AS DIRECTED.
CONDITIONS TO AVOID: NO DATA AVAILABLE
INCOMPATIBLE MATERIALS:
ALDEHYDES
ALKALI METALS
ALKALINE EARTH METALS
IRON SALTS
STRONG ACIDS
STRONG ALKALIS
STRONG OXIDIZING AGENTS
SULPHUR COMPOUNDS
HAZARDOUS DECOMPOSITION PRODUCTS:
NO HAZARDOUS DECOMPOSITION PRODUCTS ARE KNOWN.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
ACUTE TOXICITY: HARMFUL IF SWALLOWED.
PRODUCT:
ACUTE ORAL TOXICITY:
ACUTE TOXICITY ESTIMATE: 1,014 MG/KG
METHOD: CALCULATION METHOD
ACUTE DERMAL TOXICITY:
ACUTE TOXICITY ESTIMATE: >5,000 MG/KG
METHOD: CALCULATION METHOD
COMPONENTS:
ETHYLENE GLYCOL:
ACUTE ORAL TOXICITY:
LD0 (HUMAN): ESTIMATED 1.56 G/KG
ASSESSMENT:
THE COMPONENT/MIXTURE IS MODERATELY TOXIC AFTER SINGLE INGESTION.
ACUTE INHALATION TOXICITY:
LC50 (RAT): 10.9 MG/L
EXPOSURE TIME: 1 H
TEST ATMOSPHERE: DUST/MIST
ASSESSMENT: THE SUBSTANCE OR MIXTURE HAS NO ACUTE INHALATION TOXICITY
ACUTE DERMAL TOXICITY:
LD50 (RABBIT): 9,530 MG/KG
ACUTE TOXICITY (OTHER ROUTES OF ADMINISTRATION):
LD50 (RAT): 5,010 MG/KG
APPLICATION ROUTE: INTRAPERITONEAL
LD50 (RAT): 3,260 MG/KG
APPLICATION ROUTE: INTRAVENOUS
SODIUM BENZOATE:
ACUTE ORAL TOXICITY:
LD50 (RAT, MALE AND FEMALE): 3,450 MG/KG
ACUTE INHALATION TOXICITY:
LC50 (RAT): >12.2 MG/L
EXPOSURE TIME: 4 H
TEST ATMOSPHERE: DUST/MIST
REMARKS:
THE TOXICOLOGICAL DATA HAS BEEN TAKEN FROM PRODUCTS OF SIMILAR COMPOSITION.
DIPOTASSIUM PHOSPHATE:
ACUTE ORAL TOXICITY:
LD50 (RAT): >500 MG/KG
LD50 (RAT, FEMALE): >2,000 MG/KG
METHOD: OECD TEST GUIDELINE 420
ASSESSMENT: THE SUBSTANCE OR MIXTURE HAS NO ACUTE ORAL TOXICITY
ACUTE DERMAL TOXICITY:
LD50 (RABBIT): >300 MG/KG
LD50 (RABBIT): >5,000 MG/KG
METHOD: OECD TEST GUIDELINE 402
SKIN CORROSION/IRRITATION: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
COMPONENTS:
ETHYLENE GLYCOL:
SPECIES: RABBIT
RESULT: NO SKIN IRRITATION
SODIUM BENZOATE:
ASSESSMENT: SLIGHT, TRANSIENT IRRITATION
RESULT: SLIGHT, TRANSIENT IRRITATION
DIPOTASSIUM PHOSPHATE:
SPECIES: RABBIT
RESULT: SLIGHT, TRANSIENT IRRITATION
SERIOUS EYE DAMAGE/EYE IRRITATION:
NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
COMPONENTS:
ETHYLENE GLYCOL:
RESULT: SLIGHT, TRANSIENT IRRITATION
SODIUM BENZOATE:
SPECIES: RABBIT
RESULT: IRRITATING TO EYES.
METHOD: OECD TEST GUIDELINE 405
DIPOTASSIUM PHOSPHATE:
SPECIES: RABBIT
RESULT: SLIGHT, TRANSIENT IRRITATION
RESPIRATORY OR SKIN SENSITISATION:
SKIN SENSITISATION: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
RESPIRATORY SENSITISATION: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
COMPONENTS:
ETHYLENE GLYCOL:
TEST TYPE: MAXIMISATION TEST
SPECIES: GUINEA PIG
ASSESSMENT: DOES NOT CAUSE SKIN SENSITISATION.
DIPOTASSIUM PHOSPHATE:
TEST TYPE: LOCAL LYMPH NODE ASSAY
SPECIES: MOUSE
ASSESSMENT: DID NOT CAUSE SENSITISATION ON LABORATORY ANIMALS.
METHOD: OECD TEST GUIDELINE 429
REMARKS:
THE TOXICOLOGICAL DATA HAS BEEN TAKEN FROM PRODUCTS OF SIMILAR
COMPOSITION.
GERM CELL MUTAGENICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
COMPONENTS:
ETHYLENE GLYCOL:
GENOTOXICITY IN VITRO:
TEST TYPE: AMES TEST
TEST SYSTEM: SALMONELLA TYPHIMURIUM
METABOLIC ACTIVATION: WITH AND WITHOUT METABOLIC ACTIVATION
RESULT: NEGATIVE
DIPOTASSIUM PHOSPHATE:
GENOTOXICITY IN VITRO:
TEST TYPE: AMES TEST
TEST SYSTEM: SALMONELLA TYPHIMURIUM
METABOLIC ACTIVATION: WITH AND WITHOUT METABOLIC ACTIVATION
METHOD: OECD TEST GUIDELINE 471
RESULT: NEGATIVE
REMARKS:
THE TOXICOLOGICAL DATA HAS BEEN TAKEN FROM PRODUCTS OF SIMILAR COMPOSITION.
CARCINOGENICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
IARC:
GROUP 2A: PROBABLY CARCINOGENIC TO HUMANS
SODIUM NITRATE 7631-99-4
(NITRATE (INGESTED) UNDER CONDITIONS THAT RESULT IN ENDOGENOUS NITROSATION)
OSHA:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS ON OSHA'S LIST OF REGULATED CARCINOGENS.
NTP:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A KNOWN OR ANTICIPATED CARCINOGEN BY NTP.
REPRODUCTIVE TOXICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
STOT - SINGLE EXPOSURE: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
STOT - REPEATED EXPOSURE:
MAY CAUSE DAMAGE TO ORGANS (KIDNEY, LIVER) THROUGH PROLONGED OR REPEATED
EXPOSURE IF SWALLOWED.
COMPONENTS:
ETHYLENE GLYCOL:
EXPOSURE ROUTES: INGESTION
TARGET ORGANS: KIDNEY, LIVER
ASSESSMENT:
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
ASPIRATION TOXICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
EXPERIENCE WITH HUMAN EXPOSURE:
COMPONENTS:
ETHYLENE GLYCOL:
INGESTION:
TARGET ORGANS: KIDNEY
FURTHER INFORMATION:
PRODUCT:
REMARKS: NO DATA AVAILABLE
| SECTION 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
PRODUCT:
ECOTOXICOLOGY ASSESSMENT:
SHORT-TERM (ACUTE) AQUATIC HAZARD:
NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
LONG-TERM (CHRONIC) AQUATIC HAZARD:
NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
COMPONENTS:
ETHYLENE GLYCOL:
TOXICITY TO FISH:
LC50 (LEPOMIS MACROCHIRUS (BLUEGILL SUNFISH)): 27,540 MG/L
EXPOSURE TIME: 96 H
TEST TYPE: STATIC TEST
LC50 (PIMEPHALES PROMELAS (FATHEAD MINNOW)): 8,050 MG/L
EXPOSURE TIME: 96 H
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES:
LC50 (DAPHNIA MAGNA (WATER FLEA)): >10,000 MG/L
EXPOSURE TIME: 48 H
TEST TYPE: STATIC TEST
TOXICITY TO ALGAE:
EC50 (PSEUDOKIRCHNERIELLA SUBCAPITATA (GREEN ALGAE)): 6,500 - 13,000 MG/L
END POINT: GROWTH INHIBITION
EXPOSURE TIME: 7 DAYS
TOXICITY TO FISH (CHRONIC TOXICITY):
NOEC (PIMEPHALES PROMELAS (FATHEAD MINNOW)): 32,000 MG/L
EXPOSURE TIME: 7 D
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES (CHRONIC TOXICITY):
NOEC (DAPHNIA MAGNA (WATER FLEA)): 24,000 MG/L
EXPOSURE TIME: 7 D
ECOTOXICOLOGY ASSESSMENT:
SHORT-TERM (ACUTE) AQUATIC HAZARD:
NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
LONG-TERM (CHRONIC) AQUATIC HAZARD:
NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
SODIUM BENZOATE:
TOXICITY TO FISH:
LC50 (PIMEPHALES PROMELAS (FATHEAD MINNOW)): >100 MG/L
EXPOSURE TIME: 96 H
TEST TYPE: STATIC TEST
METHOD: STATIC
REMARKS: MORTALITY
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES:
LC50 (DAPHNIA MAGNA (WATER FLEA)): >100 MG/L
EXPOSURE TIME: 96 H
TEST TYPE: STATIC TEST
METHOD: STATIC
REMARKS: MORTALITY
DIPOTASSIUM PHOSPHATE:
TOXICITY TO FISH:
LC50 (ONCORHYNCHUS MYKISS (RAINBOW TROUT)): >100 MG/L
EXPOSURE TIME: 96 H
TEST TYPE: SEMI-STATIC TEST
METHOD: OECD TEST GUIDELINE 203
REMARKS:
THE TOXICOLOGICAL DATA HAS BEEN TAKEN FROM PRODUCTS OF SIMILAR COMPOSITION.
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES:
EC50 (DAPHNIA MAGNA (WATER FLEA)): >100 MG/L
EXPOSURE TIME: 48 H
TEST TYPE: STATIC TEST
METHOD: OECD TEST GUIDELINE 202
REMARKS:
THE TOXICOLOGICAL DATA HAS BEEN TAKEN FROM PRODUCTS OF SIMILAR COMPOSITION.
TOXICITY TO ALGAE:
EC50 (DESMODESMUS SUBSPICATUS (GREEN ALGAE)): >100 MG/L
END POINT: GROWTH INHIBITION
EXPOSURE TIME: 72 H
TEST TYPE: STATIC TEST
METHOD: OECD TEST GUIDELINE 201
REMARKS:
THE TOXICOLOGICAL DATA HAS BEEN TAKEN FROM PRODUCTS OF SIMILAR COMPOSITION.
NOEC (DESMODESMUS SUBSPICATUS (GREEN ALGAE)): >100 MG/L
END POINT: GROWTH INHIBITION
EXPOSURE TIME: 72 H
TEST TYPE: STATIC TEST
METHOD: OECD TEST GUIDELINE 201
REMARKS:
THE TOXICOLOGICAL DATA HAS BEEN TAKEN FROM PRODUCTS OF SIMILAR COMPOSITION.
PERSISTENCE AND DEGRADABILITY:
COMPONENTS:
ETHYLENE GLYCOL:
BIODEGRADABILITY:
RESULT: READILY BIODEGRADABLE.
BIODEGRADATION: 90 - 100%
EXPOSURE TIME: 10 D
METHOD: OECD TEST GUIDELINE 301
SODIUM BENZOATE:
BIODEGRADABILITY:
RESULT: READILY BIODEGRADABLE.
BIODEGRADATION: 88%
EXPOSURE TIME: 28 D
METHOD: OECD TEST GUIDELINE 301
DIPOTASSIUM PHOSPHATE:
BIODEGRADABILITY:
REMARKS:
THE METHODS FOR DETERMINING BIODEGRADABILITY ARE NOT APPLICABLE TO
INORGANIC SUBSTANCES.
NO DATA AVAILABLE
BIOACCUMULATIVE POTENTIAL:
COMPONENTS:
ETHYLENE GLYCOL:
BIOACCUMULATION:
SPECIES: CRAYFISH (PROCAMBARUS)
BIOCONCENTRATION FACTOR (BCF): 0.27
EXPOSURE TIME: 61 D
CONCENTRATION: 1000 MG/L
METHOD: FLOW THROUGH
PARTITION COEFFICIENT N-OCTANOL/WATER:
LOG POW: -1.36
NO DATA AVAILABLE
MOBILITY IN SOIL:
COMPONENTS: NO DATA AVAILABLE
OTHER ADVERSE EFFECTS: NO DATA AVAILABLE
PRODUCT:
REGULATION:
40 CFR PROTECTION OF ENVIRONMENT; PART 82 PROTECTION OF STRATOSPHERIC
OZONE - CAA SECTION 602 CLASS I SUBSTANCES
REMARKS:
THIS PRODUCT NEITHER CONTAINS, NOR WAS MANUFACTURED WITH A CLASS I OR
CLASS II ODS AS DEFINED BY THE U.S. CLEAN AIR ACT SECTION 602 (40 CFR
82, SUBPT. A, APP.A + B).
ADDITIONAL ECOLOGICAL INFORMATION: NO DATA AVAILABLE
COMPONENTS:
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
GENERAL ADVICE:
DO NOT DISPOSE OF WASTE INTO SEWER.
DO NOT CONTAMINATE PONDS, WATERWAYS OR DITCHES WITH CHEMICAL OR USED
CONTAINER.
SEND TO A LICENSED WASTE MANAGEMENT COMPANY.
CONTAMINATED PACKAGING:
EMPTY REMAINING CONTENTS.
DISPOSE OF AS UNUSED PRODUCT.
DO NOT RE-USE EMPTY CONTAINERS.
| SECTION 14. TRANSPORT INFORMATION | |
INTERNATIONAL REGULATIONS:
UNRTDG: NOT REGULATED AS A DANGEROUS GOOD
IATA-DGR: NOT REGULATED AS A DANGEROUS GOOD
IMDG-CODE: NOT REGULATED AS A DANGEROUS GOOD
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE:
NOT APPLICABLE FOR PRODUCT AS SUPPLIED.
NATIONAL REGULATIONS:
CFR_ROAD: NOT REGULATED AS A DANGEROUS GOOD
DANGEROUS GOODS DESCRIPTIONS (IF INDICATED ABOVE) MAY NOT REFLECT QUANTITY,
END-USE OR REGION-SPECIFIC EXCEPTIONS THAT CAN BE APPLIED. CONSULT SHIPPING
DOCUMENTS FOR DESCRIPTIONS THAT ARE SPECIFIC TO THE SHIPMENT.
| SECTION 15. REGULATORY INFORMATION | |
EPCRA - EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT:
CERCLA REPORTABLE QUANTITY:
COMPONENTS CAS-NO. COMPONENT RQ CALCULATED PRODUCT RQ
(LBS) (LBS)
ETHYLENE GLYCOL 107-21-1 5000
SARA 304 EXTREMELY HAZARDOUS SUBSTANCES REPORTABLE QUANTITY:
THIS MATERIAL DOES NOT CONTAIN ANY COMPONENTS WITH A SECTION 304 EHS RQ.
SARA 302 EXTREMELY HAZARDOUS SUBSTANCES THRESHOLD PLANNING QUANTITY:
THIS MATERIAL DOES NOT CONTAIN ANY COMPONENTS WITH A SECTION 302 EHS TPQ.
SARA 311/312 HAZARDS:
ACUTE TOXICITY (ANY ROUTE OF EXPOSURE)
SPECIFIC TARGET ORGAN TOXICITY (SINGLE OR REPEATED EXPOSURE)
SARA 313:
THE FOLLOWING COMPONENTS ARE SUBJECT TO REPORTING LEVELS ESTABLISHED BY
SARA TITLE III, SECTION 313:
ETHYLENE GLYCOL 107-21-1 >=30 - <50%
CLEAN AIR ACT:
THIS PRODUCT NEITHER CONTAINS, NOR WAS MANUFACTURED WITH A CLASS I OR
CLASS II ODS AS DEFINED BY THE U.S. CLEAN AIR ACT SECTION 602 (40 CFR
82, SUBPT. A, APP.A + B).
THE FOLLOWING CHEMICAL(S) ARE LISTED AS HAP UNDER THE U.S. CLEAN AIR ACT,
SECTION 112 (40 CFR 61):
ETHYLENE GLYCOL 107-21-1 >=30 - <50%
THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS LISTED UNDER THE U.S. CLEAN
AIR ACT SECTION 112(R) FOR ACCIDENTAL RELEASE PREVENTION (40 CFR 68.130,
SUBPART F).
THE FOLLOWING CHEMICAL(S) ARE LISTED UNDER THE U.S. CLEAN AIR ACT SECTION
111 SOCMI INTERMEDIATE OR FINAL VOC'S (40 CFR 60.489):
ETHYLENE GLYCOL 107-21-1 >=30 - <50%
SODIUM BENZOATE 532-32-1 >= 1 - <5%
CLEAN WATER ACT:
THIS PRODUCT DOES NOT CONTAIN ANY HAZARDOUS SUBSTANCES LISTED UNDER THE
U.S. CLEANWATER ACT, SECTION 311, TABLE 116.4A.
THIS PRODUCT DOES NOT CONTAIN ANY HAZARDOUS CHEMICALS LISTED UNDER THE
U.S. CLEAN WATER ACT, SECTION 311, TABLE 117.3.
THIS PRODUCT DOES NOT CONTAIN ANY TOXIC POLLUTANTS LISTED UNDER THE U.S.
CLEAN WATER ACT SECTION 307
THIS PRODUCT DOES NOT CONTAIN ANY PRIORITY POLLUTANTS RELATED TO THE U.S.
CLEAN WATER ACT
CALIFORNIA PROP. 65:
WARNING: REPRODUCTIVE HARM - WWW.F65WAMINGS.CA.GOV.
THE COMPONENTS OF THIS PRODUCT ARE REPORTED IN THE FOLLOWING INVENTORIES:
TCSI: NOT IN COMPLIANCE WITH THE INVENTORY
TSCA: ALL SUBSTANCES LISTED AS ACTIVE ON THE TSCA INVENTORY
AIIC: NOT IN COMPLIANCE WITH THE INVENTORY
DSL: ALL COMPONENTS OF THIS PRODUCT ARE ON THE CANADIAN DSL
ENCS: NOT IN COMPLIANCE WITH THE INVENTORY
ISHL: NOT IN COMPLIANCE WITH THE INVENTORY
KECI: ON THE INVENTORY, OR IN COMPLIANCE WITH THE INVENTORY
PICCS: ON THE INVENTORY, OR IN COMPLIANCE WITH THE INVENTORY
IECSC: ON THE INVENTORY, OR IN COMPLIANCE WITH THE INVENTORY
NZIOC: NOT IN COMPLIANCE WITH THE INVENTORY
TECI: NOT IN COMPLIANCE WITH THE INVENTORY
TSCA LIST:
NO SUBSTANCES ARE SUBJECT TO A SIGNIFICANT NEW USE RULE.
NO SUBSTANCES ARE SUBJECT TO TSCA 12(B) EXPORT NOTIFICATION REQUIREMENTS.
INVENTORIES:
AIIC (AUSTRALIA), DSL (CANADA), IECSC (CHINA), REACH (EUROPEAN UNION),
ENCS (JAPAN), ISHL (JAPAN), KECI (KOREA), NZIOC (NEW ZEALAND), PICCS
(PHILIPPINES), TCSI (TAIWAN), TECI (THAILAND), TSCA (USA)
| SECTION 16. OTHER INFORMATION | |
FURTHER INFORMATION:
INTERNAL INFORMATION: 000000141647
NFPA:
HEALTH 0
FLAMMABILITY 1
INSTABILITY 0
SPECIAL HAZARD
HMIS III:
HEALTH 2*
FLAMMABILITY 1
PHYSICAL HAZARD 0
0 = NOT SIGNIFICANT
1 = SLIGHT
2 = MODERATE
3 = HIGH
4 = EXTREME
* = CHRONIC
NFPA FLAMMABLE AND COMBUSTIBLE LIQUIDS CLASSIFICATION:
COMBUSTIBLE LIQUID CLASS IIIB
FULL TEXT OF H-STATEMENTS:
H302: HARMFUL IF SWALLOWED.
H311: TOXIC IN CONTACT WITH SKIN.
H319: CAUSES SERIOUS EYE IRRITATION.
H373:
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE IF
SWALLOWED.
SOURCES OF KEY DATA USED TO COMPILE THE SAFETY DATA SHEET
VALVOLINE INTERNAL DATA INCLUDING OWN AND SPONSORED TEST REPORTS
THE UNECE ADMINISTERS REGIONAL AGREEMENTS IMPLEMENTING HARMONISED
CLASSIFICATION FOR LABELLING (GHS) AND TRANSPORT.
THE INFORMATION ACCUMULATED HEREIN IS BELIEVED TO BE ACCURATE BUT IS NOT
WARRANTED TO BE WHETHER ORIGINATING WITH THE COMPANY OR NOT. RECIPIENTS
ARE ADVISED TO CONFIRM IN ADVANCE OF NEED THAT THE INFORMATION IS CURRENT,
APPLICABLE, AND SUITABLE TO THEIR CIRCUMSTANCES. THIS SDS HAS BEEN PREPARED
BY VALVOLINE'S ENVIRONMENTAL HEALTH AND SAFETY DEPARTMENT
(1-800-VALVOLINE).
LIST OF ABBREVIATIONS AND ACRONYMS THAT COULD BE, BUT NOT NECESSARILY ARE,
USED IN THIS SAFETY DATA SHEET:
ACGIH: AMERICAN CONFERENCE OF INDUSTRIAL HYGIENISTS
BEI: BIOLOGICAL EXPOSURE INDEX
CAS:
CHEMICAL ABSTRACTS SERVICE (DIVISION OF THE AMERICAN CHEMICAL SOCIETY).
CMR: CARCINOGENIC, MUTAGENIC OR TOXIC FOR REPRODUCTION
FG: FOOD GRADE
GHS:
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS.
H-STATEMENT: HAZARD STATEMENT
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION.
IATA-DGR:
DANGEROUS GOODS REGULATION BY THE "INTERNATIONAL AIR TRANSPORT ASSOCIATION"
(IATA).
ICAO: INTERNATIONAL CIVIL AVIATION ORGANIZATION
ICAO-TI (ICAO):
TECHNICAL INSTRUCTIONS BY THE "INTERNATIONAL CIVIL AVIATION ORGANIZATION"
IMDG: INTERNATIONAL MARITIME CODE FOR DANGEROUS GOODS
ISO: INTERNATIONAL ORGANIZATION FOR STANDARDIZATION
LOGPOW: OCTANOL-WATER PARTITION COEFFICIENT
LCXX: LETHAL CONCENTRATION, FOR XX PERCENT OF TEST POPULATION
LDXX: LETHAL DOSE, FOR XX PERCENT OF TEST POPULATION.
ICXX: INHIBITORY CONCENTRATION FOR XX OF A SUBSTANCE
ECXX: EFFECTIVE CONCENTRATION OF XX
N.O.S.: NOT OTHERWISE SPECIFIED
OECD: ORGANIZATION FOR ECONOMIC CO-OPERATION AND DEVELOPMENT
OEL: OCCUPATIONAL EXPOSURE LIMIT
P-STATEMENT: PRECAUTIONARY STATEMENT
PBT: PERSISTENT, BIOACCUMULATIVE AND TOXIC
PPE: PERSONAL PROTECTIVE EQUIPMENT
STEL: SHORT-TERM EXPOSURE LIMIT
STOT: SPECIFIC TARGET ORGAN TOXICITY
TLV: THRESHOLD LIMIT VALUE
TWA: TIME-WEIGHTED AVERAGE
VPVB: VERY PERSISTENT AND VERY BIOACCUMULATIVE
WEL: WORKPLACE EXPOSURE LEVEL
CERCLA:
COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION, AND LIABILITY ACT
DOT: DEPARTMENT OF TRANSPORTATION
FIFRA: FEDERAL INSECTICIDE, FUNGICIDE, AND RODENTICIDE ACT
HMIRC: HAZARDOUS MATERIALS INFORMATION REVIEW COMMISSION
HMIS: HAZARDOUS MATERIALS IDENTIFICATION SYSTEM
NFPA: NATIONAL FIRE PROTECTION ASSOCIATION
NIOSH: NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH
OSHA: OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION
PMRA: HEALTH CANADA PEST MANAGEMENT REGULATORY AGENCY
RTK: RIGHT TO KNOW
WHMIS: WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM