| Common Name: | CUPRIC SULFATE, PENTAHYDRATE, FINE CRYSTAL, REAGENT, ACS |
| Manufacturer: | SPECTRUM CHEMICALS & LABORATORY PRODUCTS |
| SDS Revision Date: | 8/13/2018 |
| SDS Format: | No Format Specified |
| Item Number(s): | 6MMG7 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
SPECTRUM(R*)
S
ISO 9001-2015 REGISTERED
SAFETY DATA SHEET
PREPARATION DATE: 03/11/2015
REVISION DATE: 8/13/2018
REVISION NUMBER: G5
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER:
PRODUCT CODE: C1425
PRODUCT NAME: CUPRIC SULFATE, PENTAHYDRATE, FINE CRYSTAL, REAGENT, ACS
OTHER MEANS OF IDENTIFICATION:
SYNONYMS: BLUE VITRIOL; COPPER (II) SULFATE PENTAHYDRATE
CAS #: 7758-99-8
RTECS #: GL8900000
CI#: NOT AVAILABLE
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE: NO INFORMATION AVAILABLE.
USES ADVISED AGAINST: NO INFORMATION AVAILABLE
SUPPLIER:
SPECTRUM CHEMICAL MFG. CORP
14422 SOUTH SAN PEDRO ST.
GARDENA, CA 90248
(310) 516-8000
ORDER ONLINE AT: HTTPS://WWW.SPECTRUMCHEMICAL.COM
EMERGENCY TELEPHONE NUMBER:
CHEMTREC: 1-800-424-9300
CONTACT PERSON: MARTIN LABENZ (WEST COAST)
CONTACT PERSON: IBAD TIRMIZ (EAST COAST)
| 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION:
THIS CHEMICAL IS CONSIDERED HAZARDOUS ACCORDING TO THE 2012 OSHA HAZARD
COMMUNICATION STANDARD (29 CFR 1910.1200)
CONSIDERED A DANGEROUS SUBSTANCE OR MIXTURE ACCORDING TO THE GLOBALLY
HARMONIZED SYSTEM (GHS)
ACUTE TOXICITY - ORAL: CATEGORY 3
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2A
LABEL ELEMENTS:
DANGER:
HAZARD STATEMENTS:
TOXIC IF SWALLOWED
CAUSES SKIN IRRITATION
CAUSES SERIOUS EYE IRRITATION
EXCLAMATION MARK
SKULLS AND CROSSBONES
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC): NOT APPLICABLE
OTHER HAZARDS:
VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS
VERY TOXIC TO AQUATIC LIFE
PRECAUTIONARY STATEMENTS - PREVENTION:
WASH FACE, HANDS AND ANY EXPOSED SKIN THOROUGHLY AFTER HANDLING
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT
WEAR PROTECTIVE GLOVES
WEAR EYE/FACE PROTECTION
PRECAUTIONARY STATEMENTS - RESPONSE:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF ON SKIN: WASH WITH PLENTY OF WATER
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION
TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE
IF SWALLOWED: IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN
RINSE MOUTH
PRECAUTIONARY STATEMENTS - STORAGE: STORE LOCKED UP
PRECAUTIONARY STATEMENTS - DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
COMPONENTS CAS-NO. WEIGHT %
COPPER SULFATE, PENTAHYDRATE 7758-99-8 100
| 4. FIRST AID MEASURES | |
FIRST AID MEASURES:
GENERAL ADVICE:
NATIONAL CAPITAL POISON CENTER IN THE UNITED STATES CAN PROVIDE ASSISTANCE
IF YOU HAVE A POISON EMERGENCY AND NEED TO TALK TO A POISON SPECIALIST.
CALL 1-800-222-1222. ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE
MATERIAL(S) INVOLVED AND TAKE PRECAUTIONS TO PROTECT THEMSELVES. FIRST
AIDER NEEDS TO PROTECT HIMSELF.
SKIN CONTACT:
WASH OFF IMMEDIATELY WITH SOAP AND PLENTY OF WATER REMOVING ALL
CONTAMINATED CLOTHING AND SHOES. GET MEDICAL ATTENTION. IF SKIN IRRITATION
PERSISTS, CALL A PHYSICIAN.
EYE CONTACT: FLUSH EYES WITH WATER FOR 15 MINUTES. GET MEDICAL ATTENTION.
INHALATION:
MOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION.
WARNING!
IT MAY BE HAZARDOUS TO THE PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH
RESUSCITATION WHEN THE INHALED OR INGESTED MATERIAL IS TOXIC, INFECTIOUS
OR CORROSIVE. DO NOT USE MOUTH-TO-MOUTH RESUSCITATION IF VICTIM INGESTED
OR INHALED THE SUBSTANCE; INDUCE ARTIFICIAL RESPIRATION WITH THE AID OF A
POCKET MASK EQUIPPED WITH A ONE-WAY VALVE OR OTHER PROPER RESPIRATORY
MEDICAL DEVICE.
INGESTION:
DO NOT INDUCE VOMITING WITHOUT MEDICAL ADVICE. NEVER GIVE ANYTHING BY
MOUTH TO AN UNCONSCIOUS PERSON. IMMEDIATE MEDICAL ATTENTION IS REQUIRED.
TOXIC IF SWALLOWED.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS:
CAUSES EYE IRRITATION
CAUSES SKIN IRRITATION
MAY CAUSE A GREENISH DISCOLORATION OF THE SKIN
MAY CAUSE DISCOLORATION OF THE CORNEA
MAY CAUSE ULCERATION OF THE CORNEA
INGESTION MAY CAUSE GASTROINTESTINAL IRRITATION, NAUSEA, VOMITING, AND
DIARRHEA
ORAL MUCOSA, VOMITUS, STOOLS, AND SALILVA MAY BE STAINED BLUE OR GREEN
FOLLOWING INGESTION
MAY CAUSE METALLIC TASTE
ABDOMINAL PAIN
MAY CAUSE METABOLIC ACIDOSIS
MAY CAUSE METHEMOGLOBINEMIA
MAY AFFECT THE LIVER
JAUNDICE
IT MAY AFFECT THE KIDNEYS
MAY CAUSE CENTRAL NERVOUS SYSTEM EFFECTS
MAY AFFECT THE CARDIOVASCULAR SYSTEM
HYPOTENSION
PERFORATION OF THE NASAL SEPTUM IF INHALED IN EXCESSIVE QUANTITIES
IRRITATING TO RESPIRATORY SYSTEM
COUGHING AND WHEEZING
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY.
PROTECTION OF FIRST-AIDERS:
FIRST-AID PROVIDERS:
AVOID EXPOSURE TO BLOOD OR BODY FLUIDS. WEAR GLOVES AND OTHER NECESSARY
PROTECTIVE CLOTHING. DISPOSE OF CONTAMINATED CLOTHING AND EQUIPMENT AS
BIO-HAZARDOUS WASTE.
| 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
THE PRODUCT IS NOT FLAMMABLE. IF IT IS INVOLVED IN A FIRE, EXTINGUISH
THE FIRE USING AN AGENT SUITABLE FOR THE TYPE OF SURROUNDING FIRE.
UNSUITABLE EXTINGUISHING MEDIA: NO INFORMATION AVAILABLE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
HAZARDOUS COMBUSTION PRODUCTS:
IF IT IS INVOLVED IN A FIRE THE FOLLOWING CAN BE RELEASED:
SULFUR OXIDES. COPPER OXIDES.
SPECIFIC HAZARDS: NO INFORMATION AVAILABLE.
SPECIAL PROTECTIVE ACTIONS FOR FIREFIGHTERS:
SPECIFIC METHODS: NO INFORMATION AVAILABLE.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND,
MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
KEEP PEOPLE AWAY FROM AND UPWIND OF SPILL/LEAK. ENSURE ADEQUATE
VENTILATION. DO NOT TOUCH DAMAGED CONTAINERS OR SPILLED MATERIAL UNLESS
WEARING APPROPRIATE PROTECTIVE CLOTHING. AVOID CONTACT WITH SKIN, EYES
AND CLOTHING. USE PERSONAL PROTECTIVE EQUIPMENT.
ENVIRONMENTAL PRECAUTIONS:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO. PREVENT PRODUCT FROM
ENTERING DRAINS. PREVENT ENTRY INTO WATERWAYS, SEWERS, BASEMENTS OR
CONFINED AREAS.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CONTAINMENT:
STOP LEAK IF YOU CAN DO IT WITHOUT RISK. COVER WITH PLASTIC SHEET TO
PREVENT SPREADING.
METHODS FOR CLEANING UP:
SWEEP UP AND SHOVEL INTO SUITABLE CONTAINERS FOR DISPOSAL. CLEAN
CONTAMINATED SURFACE THOROUGHLY.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
TECHNICAL MEASURES/PRECAUTIONS:
PROVIDE SUFFICIENT AIR EXCHANGE AND/OR EXHAUST IN WORK ROOMS. KEEP AWAY
FROM INCOMPATIBLE MATERIALS.
SAFE HANDLING ADVICE:
WEAR PERSONAL PROTECTIVE EQUIPMENT. AVOID CONTACT WITH SKIN, EYES AND
CLOTHING. DO NOT INGEST. DO NOT BREATHE VAPORS/DUST. HANDLE IN ACCORDANCE
WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
TECHNICAL MEASURES/STORAGE CONDITIONS:
KEEP CONTAINER TIGHTLY CLOSED IN A DRY AND WELL-VENTILATED PLACE. STORE AT
ROOM TEMPERATURE IN THE ORIGINAL CONTAINER. STORE AWAY FROM INCOMPATIBLE
MATERIALS.
INCOMPATIBLE MATERIALS:
HYDROXYLAMINE
ACETYLENE
HYDRAZINE
NITROMETHANE
STRONG REDUCING AGENTS
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
NATIONAL OCCUPATIONAL EXPOSURE LIMITS:
UNITED STATES:
COMPONENTS CAS-NO. OSHA NIOSH ACGIH AIHA WEEL
COPPER SULFATE, 7758-99-8 NONE 1 MG/M3 TWA 1 MG/M3 TWA NONE
PENTAHYDRATE (AS Cu) (AS Cu)
CANADA:
COMPONENT CAS NO CANADA - CANADA - CANADA - CANADA -
ALBERTA BRITISH ONTARIO QUEBEC
COLUMBIA
COPPER SULFATE, 7758-99-8 NONE NONE NONE NONE
PENTAHYDRATE
AUSTRALIA AND MEXICO:
COMPONENTS CAS-NO. AUSTRALIA MEXICO
COPPER SULFATE, PENTAHYDRATE 7758-99-8 NONE NONE
APPROPRIATE ENGINEERING CONTROLS:
ENGINEERING MEASURES TO REDUCE EXPOSURE:
ENSURE ADEQUATE VENTILATION. USE PROCESS ENCLOSURES, LOCAL EXHAUST
VENTILATION, OR OTHER ENGINEERING CONTROLS TO KEEP AIRBORNE LEVELS BELOW
RECOMMENDED EXPOSURE LIMITS. IF USER OPERATIONS GENERATE DUST, FUME OR
MIST, USE VENTILATION TO KEEP EXPOSURE TO AIRBORNE CONTAMINANTS BELOW THE
EXPOSURE LIMIT.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
PERSONAL PROTECTIVE EQUIPMENT:
EYE PROTECTION: GOGGLES OR SAFETY GLASSES WITH SIDE-SHIELDS
SKIN AND BODY PROTECTION:
CHEMICAL RESISTANT APRON
LONG SLEEVED CLOTHING
GLOVES
RESPIRATORY PROTECTION:
EFFECTIVE DUST MASK. USE A DUST RESPIRATOR UNDER CONDITIONS WHERE EXPOSURE
TO THE SUBSTANCE IS APPARENT (E.G. GENERATION OF HIGH CONCENTRATION OF
DUST (DUST CLOUDS), INADEQUATE VENTILATION, DEVELOPMENT OF RESPIRATORY
TRACT IRRITATION), AND ENGINEERING CONTROLS ARE NOT FEASIBLE. BE SURE TO
USE AN APPROVED/CERTIFIED RESPIRATOR OR EQUIVALENT.
HYGIENE MEASURES:
AVOID CONTACT WITH SKIN, EYES AND CLOTHING. WASH HANDS BEFORE BREAKS AND
IMMEDIATELY AFTER HANDLING THE PRODUCT. WHEN USING, DO NOT EAT, DRINK OR
SMOKE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: SOLID
APPEARANCE: CRYSTALS. GRANULAR. POWDER.
COLOR: LIGHT BLUE.
ODOR: ODORLESS.
TASTE: NAUSEATING. METALLIC.
FORMULA: CUSO4x5H2O
MOLECULAR/FORMULA WEIGHT (G/MOLE): 249.69
FLAMMABILITY: NO INFORMATION AVAILABLE
FLASHPOINT (DEG. C/DEG. F): NO INFORMATION AVAILABLE.
FLASH POINT TESTED ACCORDING TO: NOT AVAILABLE
AUTOIGNITION TEMPERATURE (DEG. C/DEG. F): NO INFORMATION AVAILABLE
LOWER EXPLOSION LIMIT (%): NO INFORMATION AVAILABLE
UPPER EXPLOSION LIMIT (%): NO INFORMATION AVAILABLE
MELTING POINT/RANGE (DEG. C/DEG. F): 110 DEG. C/230 DEG. F
DECOMPOSITION TEMPERATURE (DEG. C/DEG. F): NO INFORMATION AVAILABLE
BOILING POINT/RANGE (DEG. C/DEG. F): 150 DEG. C/302 DEG. F
BULK DENSITY: NO INFORMATION AVAILABLE
DENSITY (G/CM3): NO INFORMATION AVAILABLE
SPECIFIC GRAVITY: 2.28 @ 15.6 DEG. C
PH: NO INFORMATION AVAILABLE
VAPOR PRESSURE @ 20 DEG. C (KPA): NO INFORMATION AVAILABLE
EVAPORATION RATE: NO INFORMATION AVAILABLE
VAPOR DENSITY: NO INFORMATION AVAILABLE
VOC CONTENT (G/L): NO INFORMATION AVAILABLE
ODOR THRESHOLD (PPM): NO INFORMATION AVAILABLE
PARTITION COEFFICIENT (N-OCTANOL/WATER): NO INFORMATION AVAILABLE
VISCOSITY: NO INFORMATION AVAILABLE
MISCIBILITY: NO INFORMATION AVAILABLE
SOLUBILITY:
EASILY SOLUBLE IN HOT WATER
SOLUBLE IN COLD WATER
SOLUBLE IN METHANOL
INSOLUBLE IN ETHANOL
IT READILY FORMS ALKALINE COMPLEXES AT SUFFICIENTLY HIGH CONCENTRATIONS
OF AMINES OR ALKALI CYANIDES
PRACTICALLY INSOLUBLE IN MOST ORGANIC SOLVENTS
| 10. STABILITY AND REACTIVITY | |
REACTIVITY:
ANHYDROUS COPPER SULFATE CAUSES HYDROXYLAMINE TO IGNITE AND THE HYDRATED
SALT IS VIGOROUSLY REDUCED
COPPER SALTS AND NITROMETHANE SPONTANEOUSLY FORM EXPLOSIVE MATERIALS
COPPER SALTS PROMOTE THE DECOMPOSITION OF HYDRAZINE
DANGEROUS ACETYLIDES MAY BE FORMED FROM MANY COPPER SALTS. THE COPPER
ACETYLIDES FORMED IN AMMONICAL OR CAUSTIC SOLUTIONS WITH Cu(II) SALTS AND
ACETYLENE ARE MORE EXPLOSIVE THAN THOSE DERIVED FROM CUPROUS Cu(I) SALTS
CHEMICAL STABILITY:
STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS: HAZARDOUS POLYMERIZATION DOES NOT OCCUR
CONDITIONS TO AVOID: INCOMPATIBLE MATERIALS.
INCOMPATIBLE MATERIALS:
HYDROXYLAMINE
ACETYLENE
HYDRAZINE
NITROMETHANE
STRONG REDUCING AGENTS
HAZARDOUS DECOMPOSITION PRODUCTS:
WHEN HEATED TO DECOMPOSITION IT EMITS TOXIC FUMES. SULFUR OXIDES.
OTHER INFORMATION:
CORROSIVITY: NO INFORMATION AVAILABLE
SPECIAL REMARKS ON CORROSIVITY: NO INFORMATION AVAILABLE
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
PRINCIPAL ROUTES OF EXPOSURE: INGESTION. INHALATION.
ACUTE TOXICITY:
COMPONENT INFORMATION:
COPPER SULFATE, PENTAHYDRATE:
CAS-NO.: 7758-99-8
LD50/ORAL/RAT:
960 MG/KG ORAL LD50 RAT
300 MG/KG ORAL LD50 RAT
462 MG/KG
LD50/ORAL/MOUSE: 43 MG/KG ORAL LD50 MOUSE
LD50/DERMAL/RABBIT: >8 G/KG DERMAL LD50 RABBIT
LD50/DERMAL/RAT: >2 G/KG DERMAL LD50 RAT
LC50/INHALATION/RAT: NO INFORMATION AVAILABLE
LC50/INHALATION/MOUSE: NO INFORMATION AVAILABLE
OTHER LD50 OR LC50 INFORMATION:
LOWEST LETHAL DOSE (LDL)ORAL FOR HUMAN: 1088 MG/KG
PRODUCT INFORMATION:
LD50/ORAL/RAT:
VALUE - ACUTE TOX ORAL: 300 MG/KG
LD50/ORAL/MOUSE:
VALUE - ACUTE TOX ORAL: 43 MG/KG
LD50/DERMAL/RABBIT:
VALUE-ACUTE TOX DERMAL: NO INFORMATION AVAILABLE
LD50/DERMAL/RAT:
VALUE - ACUTE TOX DERMAL: >2000 MG/KG
LC50/INHALATION/RAT:
VALUE-VAPOR: NO INFORMATION AVAILABLE
VALUE-GAS: NO INFORMATION AVAILABLE
VALUE-DUST/MIST: NO INFORMATION AVAILABLE
LC50/INHALATION/MOUSE:
VALUE-VAPOR: NO INFORMATION AVAILABLE
VALUE - GAS: NO INFORMATION AVAILABLE
VALUE - DUST/MIST: NO INFORMATION AVAILABLE
SYMPTOMS:
SKIN CONTACT:
CAUSES SKIN IRRITATION. MAY CAUSE SKIN BURNS, ITCHING ALLERGIC DERMATITIS,
ECZEMA, AND GREENISH DISCOLORATION OF THE SKIN AND HAIR.
EYE CONTACT:
CAUSES SERIOUS EYE IRRITATION. MAY CAUSE BURNS. MAY CAUSE CONJUNCTIVITIS.
MAY CAUSE CORNEAL OPACITY. MAY CAUSE CORNEAL DISCOLORATION, ULCERATION.
INHALATION:
CAUSES RESPIRATORY TRACT (NOSE, THROAT, LUNG) IRRITATION WITH COUGHING
AND WHEEZING. MAY CAUSE ULCERATION AND PERFORATION OF THE NASAL SEPTUM
IF INHALED IN EXCESSIVE QUANTITIES. BURNING COPPER SULFATE MAY RESULT IN
IRRITATING AND POISONOUS GASES WHICH MAY IRRITATE THE RESPIRATORY TRACT
AND LUNGS, AND MAY CAUSE METAL FUME FEVER WHICH IS CHARACTERIZED BY
FLU-LIKE SYMPTOMS SUCH AS FEVER, CHILLS, MUSCLE ACHES.
INGESTION:
TOXIC IF SWALLOWED. MAY CAUSE GASTROINTESTINAL TRACT IRRITATION WITH
NAUSEA, VOMITING, HYPERMOTILITY, DIARRHEA, METALLIC TASTE, BURNING
SENSATION IN THE STOMACH OR EPIGASTRUM, ABDOMINAL PAIN, AND POSSIBLE
GASTROINTESTINAL TRACT BLEEDING. MAY AFFECT METABOLISM(METABOLIC ACIDOSIS,
ANOREXIA, WEIGHT LOSS), LIVER (LIVER DAMAGE, JAUNDICE), BLOOD (RARELY
METHEMOGLOBINEMIA, HEMALYTIC ANEMIA), URINARY SYSTEM (KIDNEY DAMAGE,
HEMATURIA, HEMOGLOBINURIA, ALBUMINURIA), BEHAVIOR/CENTRAL NERVOUS SYSTEM
(CNS DEPRESSION, HEADACHE, SEIZURES, SOMNOLENCE, TREMOR, PSYCHOSIS,
MUSCLE WEAKNESS, COMA), CARDIOVASCULAR SYSTEM (LOWERING OF BLOOD PRESSURE,
DYSRYTHMIA). ORAL MUCOSA, VOMITUS, STOOLS, AND SALIVA MAY BE STAINED BLUE
OR GREEN FOLLOWING INGESTION. ASPIRATION PNEUMONIA MAY DEVELOP FOLLOWING
EMESIS (VOMITING).
ASPIRATION HAZARD: NO INFORMATION AVAILABLE.
DELAYED AND IMMEDIATE EFFECTS AS WELL AS CHRONIC EFFECTS FROM SHORT AND
LONG-TERM EXPOSURE:
CHRONIC TOXICITY:
REPEATED OR PROLONGED SKIN CONTACT MAY CAUSE THICKENING OF THE SKIN.
SKIN:
PROLONGED OR REPEATED SKIN CONTACT MAY CAUSE ALLERGIC SKIN REACTION.
CHRONIC EXPOSURE MAY AFFECT THE LIVER AND KIDNEYS. PROLONGED OR REPEATED
INGESTION MAY CAUSE NAUSEA, VOMITING, DIARRHEA.
SENSITIZATION: NO INFORMATION AVAILABLE.
MUTAGENIC EFFECTS: ANIMAL EXPERIMENTS SHOWED MUTAGENIC EFFECTS
CARCINOGENIC EFFECTS: NOT CONSIDERED CARCINOGENIC.
COMPONENTS CAS-NO. IARC ACGIH - NTP
CARCINOGENS
COPPER SULFATE, 7758-99-8 NOT LISTED NOT LISTED NOT LISTED
PENTAHYDRATE
COMPONENTS OSHA HCS - AUSTRALIA - AUSTRALIA -
CARCINOGENS NOTIFIABLE PROHIBITED
CARCINOGENIC CARCINOGENIC
SUBSTANCES SUBSTANCES
COPPER SULFATE, NOT LISTED NOT LISTED NOT LISTED
PENTAHYDRATE
ACGIH (AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS)
IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER)
NTP (NATIONAL TOXICOLOGY PROGRAM)
OSHA (OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION OF THE US DEPARTMENT
OF LABOR)
REPRODUCTIVE TOXICITY: NO DATA IS AVAILABLE
REPRODUCTIVE EFFECTS: NO INFORMATION AVAILABLE
DEVELOPMENTAL EFFECTS: NO INFORMATION AVAILABLE
TERATOGENIC EFFECTS: NO INFORMATION AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY:
STOT - SINGLE EXPOSURE: NO INFORMATION AVAILABLE.
STOT - REPEATED EXPOSURE: NO INFORMATION AVAILABLE.
TARGET ORGANS: NO INFORMATION AVAILABLE.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
ECOTOXICITY EFFECTS: AQUATIC ENVIRONMENT.
COPPER SULFATE, PENTAHYDRATE - 7758-99-8:
FRESHWATER FISH SPECIES DATA:
0.66 - 1.15 MG/L LC50 LEPOMIS MACROCHIRUS 96 H SEMI-STATIC 1
0.96 - 1.8 MG/L LC50 LEPOMIS MACROCHIRUS 96 H STATIC 1
0.1478 - 0.165 MG/L LC50 ONCORHYNCHUS MYKISS 96 H FLOW-THROUGH 1
0.09 - 0.19 MG/L LC50 ONCORHYNCHUS MYKISS 96 H STATIC 1
0.6752 MG/L LC50 PIMEPHALES PROMELAS 96 H STATIC 1
WATER FLEA DATA: 0.147 - 0.227 MG/L EC50 DAPHNIA MAGNA 48 H
PERSISTENCE AND DEGRADABILITY:
IF RELEASED TO SOIL, COPPER SULFATE MAY LEACH TO GROUNDWATER, BE PARTLY
OXIDIZED, OR BIND TO HUMIC MATERIALS, CLAY, OR HYDROUS OF IRON AND
MANGANESE. IN WATER, IT WILL BIND TO CARBONATES AS WELL AS HUMIC MATERIALS,
CLAY AND HYDROUS OXIDES OF IRON AND MANGANESE. COPPER IS ACCUMULATED BY
PLANTS AND ANIMALS, BUT IT DOES NOT APPEAR TO BIOMAGNIFY FROM PLANTS TO
ANIMALS. THIS LACK OF BIOMAGNIFICATION APPEARS COMMON WITH HEAVY METALS.
IN AIR, COPPER AEROSOLS (IN GENERAL) HAVE A RESIDENCE TIME OF 2 TO 10 DAYS
IN AN UNPOLLUTED ATMOSPHERE AND 0.1 TO >4 IN A POLLUTED, URBAN AREAS.
BIOACCUMULATIVE POTENTIAL: NO INFORMATION AVAILABLE.
MOBILITY: NO INFORMATION AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
WASTE FROM RESIDUES / UNUSED PRODUCTS:
WASTE MUST BE DISPOSED OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL
REGULATION.
CONTAMINATED PACKAGING:
EMPTY CONTAINERS SHOULD BE TAKEN FOR LOCAL RECYCLING, RECOVERY OR WASTE
DISPOSAL
COMPONENTS CAS-NO. RCRA - F RCRA - K RCRA - P RCRA - U
SERIES SERIES SERIES SERIES
WASTES WASTES WASTES WASTES
COPPER SULFATE, 7758-99-8 NONE NONE NONE NONE
PENTAHYDRATE
| 14. TRANSPORT INFORMATION | |
DOT:
UN-NO: UN3077
PROPER SHIPPING NAME:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (CUPRIC SULFATE)
HAZARD CLASS: 9
SUBSIDIARY CLASS: NO INFORMATION AVAILABLE
PACKING GROUP: III
EMERGENCY RESPONSE GUIDE NUMBER: NO INFORMATION AVAILABLE
MARINE POLLUTANT: MARINE POLLUTANT
DOT RQ (LBS): NO INFORMATION AVAILABLE
SPECIAL PROVISIONS: NO INFORMATION AVAILABLE
SYMBOL(S):
[DOT]:
(G) - IDENTIFIES PROPER SHIPPING NAMES FOR WHICH ONE OR MORE TECHNICAL
NAMES OF THE HAZARDOUS MATERIAL MUST BE ENTERED IN PARENTHESES, IN
ASSOCIATION WITH THE BASIC DESCRIPTION.
DESCRIPTION:
UN3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.,9,PG III,
MARINE POLLUTANT
TDG (CANADA):
UN-NO: UN3077
PROPER SHIPPING NAME:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (COPPER SULFATE)
HAZARD CLASS: 9
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: III
MARINE POLLUTANT: NO INFORMATION AVAILABLE
DESCRIPTION:
UN3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.,9,PG III,
MARINE POLLUTANT
ADR:
UN-NO: UN3077
PROPER SHIPPING NAME:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (COPPER SULFATE)
HAZARD CLASS: 9
PACKING GROUP: III
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
DESCRIPTION:
UN3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.,9,III
IMO / IMDG:
UN-NO: UN3077
PROPER SHIPPING NAME:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (COPPER SULFATE)
HAZARD CLASS: 9
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: III
MARINE POLLUTANT: MARINE POLLUTANT
EMS: F-A
RID:
UN-NO: UN3077
PROPER SHIPPING NAME:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (COPPER SULFATE)
HAZARD CLASS: 9
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: III
DESCRIPTION:
UN3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.,9,III
ICAO:
UN-NO: UN3077
PROPER SHIPPING NAME:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (COPPER SULFATE)
HAZARD CLASS: 9
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: III
DESCRIPTION:
UN3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.,9,PG III
IATA:
UN-NO: UN3077
PROPER SHIPPING NAME:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (COPPER SULFATE)
HAZARD CLASS: 9
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: III
ERG CODE: 9L
SPECIAL PROVISIONS: NO INFORMATION AVAILABLE
DESCRIPTION:
UN3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.,9,PG III
| 15. REGULATORY INFORMATION | |
INTERNATIONAL INVENTORIES:
COMPONENTS CAS-NO. U.S. TSCA KOREA KECL PHILIPPINES (PICCS)
COPPER SULFATE, 7758-99-8 NOT LISTED NOT PRESENT PRESENT
PENTAHYDRATE
COMPONENTS JAPAN ENCS CHINA AUSTRALIA (AICS) EINECS-NO.
COPPER SULFATE, NOT PRESENT PRESENT PRESENT NOT PRESENT
PENTAHYDRATE
U.S. REGULATIONS:
COPPER SULFATE, PENTAHYDRATE:
NEW JERSEY RTK HAZARDOUS SUBSTANCE LIST: SN 2215 (COPPER COMPOUNDS)
NEW JERSEY (EHS) LIST: SN 2215 500 LB. TPQ (COPPER COMPOUNDS)
NEW JERSEY - DISCHARGE PREVENTION - LIST OF HAZARDOUS SUBSTANCES:
PRESENT (COPPER COMPOUNDS)
PENNSYLVANIA RTK: ENVIRONMENTAL HAZARD (COPPER COMPOUNDS)
PENNSYLVANIA RTK - ENVIRONMENTAL HAZARD LIST: PRESENT (COPPER COMPOUNDS)
CALIFORNIA DIRECTORS LIST OF HAZARDOUS SUBSTANCES:
PRESENT (COPPER COMPOUNDS)
FDA - FOOD ADDITIVES GENERALLY RECOGNIZED AS SAFE (GRAS): 21 CFR 184.1261
CALIFORNIA PROP. 65: SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986.
CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER:
THIS PRODUCT DOES NOT CONTAIN A CHEMICAL REQUIRING A WARNING UNDER
CALIFORNIA PROP. 65. (SEE TABLE BELOW)
CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE REPRODUCTIVE TOXICITY:
THIS PRODUCT DOES NOT CONTAIN A CHEMICAL REQUIRING A WARNING UNDER
CALIFORNIA PROP. 65. (SEE TABLE BELOW)
COMPONENTS CAS-NO.
COPPER SULFATE, PENTAHYDRATE 7758-99-8
COMPONENTS CARCINOGEN DEVELOPMENTAL MALE FEMALE
TOXICITY REPRODUCTIVE REPRODUCTIVE
TOXICITY TOXICITY
COPPER SULFATE, NOT LISTED NOT LISTED NOT LISTED NOT LISTED
PENTAHYDRATE
CERCLA/SARA:
COMPONENTS CAS-NO. CERCLA - SECTION 302 SECTION 302
HAZARDOUS EXTREMELY EXTREMELY
SUBSTANCES HAZARDOUS HAZARDOUS
AND THEIR SUBSTANCES SUBSTANCES
REPORTABLE AND TPQS AND RQS
QUANTITIES
COPPER SULFATE, 7758-99-8 NONE NONE NONE
PENTAHYDRATE
COMPONENTS SECTION 313 - CHEMICAL SECTION 313 - REPORTING
CATEGORY DE MINIMIS
COPPER SULFATE, COPPER COMPOUNDS 1% DE MINIMIS
PENTAHYDRATE
U.S. TSCA
COMPONENTS CAS-NO. TSCA SECTION TSCA 8(D) - HEALTH
5(A)2 - CHEMICALS AND SAFETY REPORTING
WITH SIGNIFICANT NEW
USE RULES (SNURS)
COPPER SULFATE, 7758-99-8 NOT APPLICABLE NOT APPLICABLE
PENTAHYDRATE
CANADA:
WHIMIS 2015 - GHS CLASSIFICATIONS:
WHMIS 2015 HAZARD CLASSIFICATION INFORMATION:
COMPONENT WHMIS 2015 HAZARD CLASSIFICATION
COPPER SULFATE, PENTAHYDRATE ACUTE TOXICITY - ORAL - CATEGORY 4:
7758-99-8 (100) H302: HARMFUL IF SWALLOWED.
SERIOUS EYE DAMAGE/EYE IRRITATION - CATEGORY
2:
H319: CAUSES SERIOUS EYE IRRITATION.
CANADA HAZARDOUS PRODUCTS REGULATION:
THIS PRODUCT HAS BEEN CLASSIFIED ACCORDING TO THE HAZARD CRITERIA OF THE
HPR (HAZARDOUS PRODUCTS REGULATION) AND THE SDS CONTAINS ALL OF THE
INFORMATION REQUIRED BY THE HPR
WHMIS 1988 HAZARD CLASS:
ED2B: TOXIC MATERIALS
COMPONENTS WHMIS 1988
COPPER SULFATE, PENTAHYDRATE D2B
CANADA CONTROLLED PRODUCTS REGULATION:
THIS PRODUCT HAS BEEN CLASSIFIED ACCORDING TO THE HAZARD CRITERIA OF THE
CPR (CONTROLLED PRODUCTS REGULATION) AND THE MSDS CONTAINS ALL OF THE
INFORMATION REQUIRED BY THE CPR.
INVENTORY:
COMPONENTS CAS-NO. CANADA (DSL) CANADA (NDSL)
COPPER SULFATE, PENTAHYDRATE 7758-99-8 NOT LISTED NOT LISTED
COMPONENTS CAS-NO. CEPA SCHEDULE I - TOXIC
SUBSTANCES
COPPER SULFATE, PENTAHYDRATE 7758-99-8 NOT LISTED
COMPONENTS CAS-NO. CEPA - 2010 GREENHOUSE GASES
SUBJECT TO MANDATORY REPORTING
COPPER SULFATE, PENTAHYDRATE 7758-99-8 NOT LISTED
EU CLASSIFICATION:
EU GHS - SV - CLP 1272/2008:
COMPONENTS CAS-NO. EU GHS - SV - CLP (1272/2008)
COPPER SULFATE, PENTAHYDRATE 7758-99-8 ACUTE TOXICITY - ORAL - ACUTE
TOX. 4:
H302: HARMFUL IF SWALLOWED.
SERIOUS EYE DAMAGE/EYE
IRRITATION - EYE DAM. 1:
H318: CAUSES SERIOUS EYE DAMAGE.
HAZARDOUS TO AQUATIC
ENVIRONMENT - ACUTE
HAZARD - AQUATIC ACUTE 1:
H400:
VERY TOXIC TO AQUATIC LIFE.
(M FACTOR: 10)
HAZARDOUS TO AQUATIC
ENVIRONMENT - CHRONIC
HAZARD - AQUATIC CHRONIC 1:
H410:
VERY TOXIC TO AQUATIC LIFE WITH
LONG LASTING EFFECTS.
(M FACTOR: 10)029-023-00-4
EU - CLP (1272/2008):
R-PHRASE(S):
R22: HARMFUL IF SWALLOWED.
R50: VERY TOXIC TO AQUATIC ORGANISMS.
R53: MAY CAUSE LONG-TERM ADVERSE EFFECTS IN THE AQUATIC ENVIRONMENT.
R36/38: IRRITATING TO EYES AND SKIN.
S-PHRASE(S):
S22: DO NOT BREATHE DUST.
560:
THIS MATERIAL AND ITS CONTAINER MUST BE DISPOSED OF AS HAZARDOUS WASTE.
561:
AVOID RELEASE TO THE ENVIRONMENT. REFER TO SPECIAL INSTRUCTIONS/SAFETY
DATA SHEETS.
COMPONENTS CAS-NO. CLASSIFICATION CONCENTRATION SAFETY PHRASES
LIMITS
COPPER SULFATE, 7758-99-8 R22 R50 R53 NO INFORMATION S22 S60 S61
PENTAHYDRATE R36/38
THE PRODUCT IS CLASSIFIED IN ACCORDANCE WITH ANNEX VI TO DIRECTIVE
67/548/EEC:
INDICATION OF DANGER:
XN: HARMFUL.
XI: IRRITANT.
N: DANGEROUS FOR THE ENVIRONMENT.
| 16. OTHER INFORMATION | |
PREPARATION DATE: 03/11/2015
REVISION DATE: 8/13/2018
PREPARED BY: SONIA OWEN
DISCLAIMER:
ALL CHEMICALS MAY POSE UNKNOWN HAZARDS AND SHOULD BE USED WITH CAUTION.
THIS SAFETY DATA SHEET (SDS) APPLIES ONLY TO THE MATERIAL AS PACKAGED. IF
THIS PRODUCT IS COMBINED WITH OTHER MATERIALS, DETERIORATES, OR BECOMES
CONTAMINATED, IT MAY POSE HAZARDS NOT MENTIONED IN THIS SDS. THE PHYSICAL
PROPERTIES REPORTED IN THIS SDS ARE OBTAINED FROM THE LITERATURE AND DO
NOT CONSTITUTE PRODUCT SPECIFICATIONS. INFORMATION CONTAINED HEREIN DOES
NOT CONSTITUTE A WARRANTY, WHETHER EXPRESSED OR IMPLIED, AS TO THE SAFETY,
MERCHANTABILITY OR FITNESS OF THE GOODS FOR A PARTICULAR PURPOSE. SPECTRUM
CHEMICALS & LABORATORY PRODUCTS, INC. ASSUMES NO RESPONSIBILITY FOR
RESULTS OBTAINED OR FOR INCIDENTAL OR CONSEQUENTIAL DAMAGES, INCLUDING
LOST PROFITS, ARISING FROM THE USE OF THESE DATA. NO WARRANTY AGAINST
INFRINGEMENT OF ANY PATENT, COPYRIGHT OR TRADEMARK IS MADE OR IMPLIED. IT
SHALL BE THE USER'S RESPONSIBILITY TO DEVELOP PROPER METHODS OF HANDLING
AND PERSONAL PROTECTION BASED ON THE ACTUAL CONDITIONS OF USE. WHILE THIS
SDS IS BASED ON TECHNICAL DATA JUDGED TO BE RELIABLE, SPECTRUM ASSUMES
NO RESPONSIBILITY FOR THE COMPLETENESS OR ACCURACY OF THE INFORMATION
CONTAINED HEREIN.