| Common Name: | SODIUM HYPOCHLORITE, SOLUTION, 12 PERCENT AVAILABLE CHLORINE, REAGENT |
| Manufacturer: | SPECTRUM CHEMICALS & LABORATORY PRODUCTS |
| SDS Revision Date: | 4/3/2019 |
| SDS Format: | GHS-US |
| Item Number(s): | 6NNV0, 6NNV1 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
SPECTRUM(R*)
SAFETY DATA SHEET
PREPARATION DATE: 09/24/2015
REVISION DATE: 4/3/2019
REVISION NUMBER: G2
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER:
PRODUCT CODE: S1316
PRODUCT NAME:
SODIUM HYPOCHLORITE, SOLUTION, 12 PERCENT AVAILABLE CHLORINE, REAGENT
OTHER MEANS OF IDENTIFICATION:
SYNONYMS:
CHLORINE BLEACH
SODA BLEACH
CAS #: MIXTURE
RTECS #: NOT AVAILABLE
CI#: NOT AVAILABLE
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE: BLEACHING AGENT. DISINFECTANT.
USES ADVISED AGAINST: NO INFORMATION AVAILABLE
SUPPLIER:
SPECTRUM CHEMICAL MFG. CORP
14422 SOUTH SAN PEDRO ST.
GARDENA, CA 90248
(310) 516-8000
ORDER ONLINE AT: HTTPS://WWW.SPECTRUMCHEMICAL.COM
EMERGENCY TELEPHONE NUMBER:
CHEMTREC: 1-800-424-9300
CONTACT PERSON: TOM TYNER (USA - WEST COAST)
CONTACT PERSON: IBAD TIRMIZ (USA - EAST COAST)
| 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION:
THIS CHEMICAL IS CONSIDERED HAZARDOUS BY THE 2012 OSHA HAZARD
COMMUNICATION STANDARD (29 CFR 1910.1200)
CONSIDERED A DANGEROUS SUBSTANCE OR MIXTURE ACCORDING TO THE GLOBALLY
HARMONIZED SYSTEM (GHS)
SKIN CORROSION/IRRITATION: CATEGORY 1
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 1
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): CATEGORY 3
LABEL ELEMENTS:
DANGER
HAZARD STATEMENTS:
CAUSES SEVERE SKIN BURNS AND EYE DAMAGE
MAY CAUSE RESPIRATORY IRRITATION
CORROSION
EXCLAMATION MARK
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC): NOT APPLICABLE
OTHER HAZARDS: NOT AVAILABLE
PRECAUTIONARY STATEMENTS - PREVENTION:
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY
WASH FACE, HANDS AND ANY EXPOSED SKIN THOROUGHLY AFTER HANDLING
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA
PRECAUTIONARY STATEMENTS - RESPONSE:
IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
IF ON SKIN (OR HAIR):
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER
WASH CONTAMINATED CLOTHING BEFORE REUSE
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING
PRECAUTIONARY STATEMENTS - STORAGE:
STORE LOCKED UP
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED
PRECAUTIONARY STATEMENTS - DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
COMPONENT CAS NO WEIGHT-%
WATER 7732-18-5 85-87
SODIUM HYPOCHLORITE 7681-52-9 12-14
| 4. FIRST AID MEASURES | |
FIRST AID MEASURES:
GENERAL ADVICE:
NATIONAL CAPITAL POISON CENTER IN THE UNITED STATES CAN PROVIDE ASSISTANCE
IF YOU HAVE A POISON EMERGENCY AND NEED TO TALK TO A POISON SPECIALIST.
CALL 1-800-222-1222. ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE
MATERIAL(S) INVOLVED AND TAKE PRECAUTIONS TO PROTECT THEMSELVES.
FIRST AIDER NEEDS TO PROTECT HIMSELF.
SKIN CONTACT:
WASH OFF IMMEDIATELY WITH SOAP AND PLENTY OF WATER REMOVING ALL
CONTAMINATED CLOTHING AND SHOES. GET MEDICAL ATTENTION. IF SKIN IRRITATION
PERSISTS, CALL A PHYSICIAN.
EYE CONTACT:
FLUSH EYES WITH WATER FOR 15 MINUTES. IMMEDIATE MEDICAL ATTENTION IS
REQUIRED. CALL A PHYSICIAN IMMEDIATELY.
INHALATION:
MOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION.
WARNING!
IT MAY BE HAZARDOUS TO THE PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH
RESUSCITATION WHEN THE INHALED OR INGESTED MATERIAL IS TOXIC, INFECTIOUS
OR CORROSIVE. DO NOT USE MOUTH-TO-MOUTH RESUSCITATION IF VICTIM INGESTED
OR INHALED THE SUBSTANCE; INDUCE ARTIFICIAL RESPIRATION WITH THE AID OF A
POCKET MASK EQUIPPED WITH A ONE-WAY VALVE OR OTHER PROPER RESPIRATORY
MEDICAL DEVICE. IMMEDIATE MEDICAL ATTENTION IS REQUIRED. CALL A PHYSICIAN
IMMEDIATELY.
INGESTION:
DO NOT INDUCE VOMITING WITHOUT MEDICAL ADVICE. NEVER GIVE ANYTHING BY MOUTH
TO AN UNCONSCIOUS PERSON. IMMEDIATE MEDICAL ATTENTION IS REQUIRED. CALL A
PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS:
SEVERE SKIN AND EYE IRRITATION OR BURNS
IRRITATING TO RESPIRATORY SYSTEM
MAY CAUSE GASTROINTESTINAL (DIGESTIVE) TRACT BURNS
CAN BURN MOUTH, THROAT, AND STOMACH
ABDOMINAL PAIN
NAUSEA
VOMITING
MAY CAUSE DIARRHEA
MAY CAUSE PERFORATION OF THE DIGESTIVE TRACT
SHALLOW RESPIRATION
DYSPNEA (SHORTNESS OF BREATH AND DIFFICULTY BREATHING)
MAY CAUSE DIFFICULTY SWALLOWING
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY.
PROTECTION OF FIRST-AIDERS:
FIRST-AID PROVIDERS:
AVOID EXPOSURE TO BLOOD OR BODY FLUIDS. WEAR GLOVES AND OTHER NECESSARY
PROTECTIVE CLOTHING. DISPOSE OF CONTAMINATED CLOTHING AND EQUIPMENT AS
BIO-HAZARDOUS WASTE.
| 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
THE PRODUCT IS NOT FLAMMABLE. IF IT IS INVOLVED IN A FIRE, EXTINGUISH THE
FIRE USING AN AGENT SUITABLE FOR THE TYPE OF SURROUNDING FIRE.
UNSUITABLE EXTINGUISHING MEDIA: NO INFORMATION AVAILABLE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
HAZARDOUS COMBUSTION PRODUCTS:
IF IT IS INVOLVED IN A FIRE THE FOLLOWING CAN BE RELEASED:
CHLORINE GAS. HYDROGEN CHLORIDE. SODIUM CHLORATE.
HYPOCHLOROUS ACID.
SPECIFIC HAZARDS:
CONTACT WITH COMBUSTIBLE OR ORGANIC MATERIALS MAY CAUSE FIRE. CONTACT WITH
METALS MAY EVOLVE FLAMMABLE HYDROGEN GAS. RELEASES CHLORINE WHEN HEATED
ABOVE 35 DEG. C. THE SUBSTANCE ITSELF IS NON-COMBUSTIBLE AND DOES NOT
BURN. HOWEVER, WHEN HEATED TO DECOMPOSITION IT EMITS CORROSIVE AND/OR
TOXIC FUMES OF Na2O AND CHLORIDES (HYDROGEN CHLORIDE), CHLORINE,
HYPOCHLOROUS ACID, HYDROCHLORIC ACID. ADDITIONAL DECOMPOSITION PRODUCTS,
WHICH DEPENDS UPON TEMPERATURE, PH, AND TIME, ARE SODIUM CHLORIDE, SODIUM
CHLORATE AND OXYGEN. ANYDROUS SODIUM HYPOCHLORITE IS VERY EXPLOSIVE.
PRIMARY AMINES AND CALCIUM HYPOCHLORITE OR SODIUM HYPOCHLORITE REACT TO
FORM NORMAL CHLOROAMINES, WHICH ARE EXPLOSIVE. INTERACTION OF
ETHYLENEIMINE WITH SODIUM (OR OTHER) HYPOCHLORITE GIVES THE EXPLOSIVE
N-CHLORO CMPD. REMOVAL OF FORMIC ACID FROM INDUSTRIAL WASTE STREAMS WITH
SODIUM HYPOCHLORITE SOLN BECOMES EXPLOSIVE AT 55 DEG C. SEVERAL EXPLOSIONS
INVOLVING METHANOL AND SODIUM HYPOCHLORITE WERE ATTRIBUTED TO FORMATION OF
METHYL HYPOCHLORITE, ESPECIALLY IN PRESENCE OF ACID OR OTHER ESTERIFICATION
CATALYST. USE OF SODIUM HYPOCHLORITE SOLN TO DESTROY ACIDIFIED BENZYL
CYANIDE RESIDUES CAUSED A VIOLENT EXPLOSION, THOUGHT TO HAVE BEEN DUE TO
FORMATION OF NITROGEN TRICHLORIDE.
SPECIAL PROTECTIVE ACTIONS FOR FIREFIGHTERS:
SPECIFIC METHODS: NO INFORMATION AVAILABLE
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND,
MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
ENSURE ADEQUATE VENTILATION. KEEP PEOPLE AWAY FROM AND UPWIND OF
SPILL/LEAK. USE PERSONAL PROTECTIVE EQUIPMENT. AVOID CONTACT WITH SKIN,
EYES AND CLOTHING. DO NOT TOUCH DAMAGED CONTAINERS OR SPILLED MATERIAL
UNLESS WEARING APPROPRIATE PROTECTIVE CLOTHING. KEEP COMBUSTIBLES (WOOD,
PAPER, OIL, CLOTHING, ETC.) AWAY FROM SPILLED MATERIAL.
ENVIRONMENTAL PRECAUTIONS:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO. DO NOT LET PRODUCT
ENTER DRAINS.
PREVENT ENTRY INTO WATERWAYS, SEWERS, BASEMENTS OR CONFINED AREAS.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CONTAINMENT:
STOP LEAK IF YOU CAN DO IT WITHOUT RISK. ABSORB SPILL WITH INERT MATERIAL
(E.G. VERMICULITE, DRY SAND OR EARTH).
METHODS FOR CLEANING UP:
NEUTRALIZE THE RESIDUE WITH A DILUTE SOLUTION OF ACETIC ACID. USE
APPROPRIATE TOOLS TO PUT THE SPILLED MATERIAL IN A SUITABLE CHEMICAL WASTE
DISPOSAL CONTAINER. CLEAN CONTAMINATED SURFACE THOROUGHLY.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
TECHNICAL MEASURES/PRECAUTIONS:
PROVIDE SUFFICIENT AIR EXCHANGE AND/OR EXHAUST IN WORK ROOMS. KEEP AWAY
FROM INCOMPATIBLE MATERIALS.
SAFE HANDLING ADVICE:
WEAR PERSONAL PROTECTIVE EQUIPMENT. AVOID CONTACT WITH SKIN, EYES AND
CLOTHING. DO NOT BREATHE VAPORS OR SPRAY MIST. DO NOT INGEST. DO NOT SMOKE.
KEEP AWAY FROM COMBUSTIBLE MATERIAL. HANDLE IN ACCORDANCE WITH GOOD
INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
TECHNICAL MEASURES/STORAGE CONDITIONS:
STORE AT TEMPERATURES BETWEEN 4 DEG. C TO 20 DEG. F. KEEP AT TEMPERATURE
NOT EXCEEDING 35 DEG. C/ 95 DEG. F. KEEP CONTAINERS TIGHTLY CLOSED IN A
DRY, COOL AND WELL-VENTILATED PLACE. STORE AWAY FROM INCOMPATIBLE
MATERIALS. STORE IN A SEGREGATED AND APPROVED AREA.
INCOMPATIBLE MATERIALS:
REDUCING AGENTS
COMBUSTIBLE MATERIALS
ORGANIC MATERIALS
METALS
ACIDS
INCOMPATIBLE WITH AMMONIUM ACETATE, AMMONIUM CARBONATE, AMMONIUM NITRATE,
AMMONIUM OXALATE, AND AMMONIUM PHOSPHATE, PRIMARY AMINES, PHENYL
ACETONITRILE, ETHYLENEIMINE, METHANOL, ACIDIFIED BENZYL CYANIDE, FORMIC
ACID, UREA, NITRO COMPOUNDS, METHYLSCELLULOSE, CELLOLUSE, AZIRIDINE, ETHER
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
NATIONAL OCCUPATIONAL EXPOSURE LIMITS:
UNITED STATES:
COMPONENT CAS NO OSHA NIOSH ACGIH AIHA WEEL
WATER 7732-18-5 NONE NONE NONE NONE
SODIUM HYPOCHLORITE 7681-52-9 NONE NONE NONE 2 MG/M3 STEL
CANADA:
COMPONENT CAS NO CANADA - CANADA - CANADA - CANADA -
ALBERTA BRITISH ONTARIO QUEBEC
COLUMBIA
WATER 7732-18-5 NONE NONE NONE NONE
SODIUM HYPOCHLORITE 7681-52-9 NONE NONE NONE NONE
AUSTRALIA AND MEXICO:
COMPONENT CAS NO AUSTRALIA MEXICO
WATER 7732-18-5 NONE NONE
SODIUM HYPOCHLORITE 7681-52-9 NONE NONE
APPROPRIATE ENGINEERING CONTROLS:
ENGINEERING MEASURES TO REDUCE EXPOSURE:
ENSURE ADEQUATE VENTILATION. PROVIDE EXHAUST VENTILATION OR OTHER
ENGINEERING CONTROLS TO KEEP THE AIRBORNE CONCENTRATIONS OF VAPORS AND MIST
BELOW THEIR RESPECTIVE THRESHOLD LIMIT VALUE.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
PERSONAL PROTECTIVE EQUIPMENT:
EYE PROTECTION: FACE-SHIELD.
SKIN AND BODY PROTECTION:
CHEMICAL RESISTANT PROTECTIVE SUIT
GLOVES
BOOTS
RESPIRATORY PROTECTION:
VAPOR RESPIRATOR. BE SURE TO USE AN APPROVED/CERTIFIED RESPIRATOR OR
EQUIVALENT.
HYGIENE MEASURES:
AVOID CONTACT WITH SKIN, EYES AND CLOTHING. WHEN USING, DO NOT EAT, DRINK
OR SMOKE. WASH HANDS BEFORE BREAKS AND IMMEDIATELY AFTER HANDLING THE
PRODUCT
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
APPEARANCE: NO INFORMATION AVAILABLE.
COLOR: GREENISH-YELLOW.
ODOR: CHARACTERISTIC. SLIGHT CHLORINE-LIKE.
TASTE: NO INFORMATION AVAILABLE.
FORMULA: NO INFORMATION AVAILABLE
MOLECULAR/FORMULA WEIGHT (G/MOLE): NO INFORMATION AVAILABLE
FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
FLASHPOINT (DEG. C/DEG. F): NO INFORMATION AVAILABLE
FLASH POINT TESTED ACCORDING TO: NOT AVAILABLE
AUTOIGNITION TEMPERATURE (DEG. C/DEG. F): NO INFORMATION AVAILABLE
LOWER EXPLOSION LIMIT (%): NO INFORMATION AVAILABLE
UPPER EXPLOSION LIMIT (%): NO INFORMATION AVAILABLE
MELTING POINT/RANGE (DEG. C/DEG. F):
FREEZING POINT: -23.889-(-19) DEG. C/-11-(-3) DEG. F
DECOMPOSITION TEMPERATURE (DEG. C/DEG. F): NO INFORMATION AVAILABLE
BOILING POINT/RANGE (DEG. C/DEG. F): 100 DEG. C/212 DEG. F (WATER)
BULK DENSITY: NO INFORMATION AVAILABLE
DENSITY (G/CM3): NO INFORMATION AVAILABLE
SPECIFIC GRAVITY: 1.165-1.19
PH: 12 [BASIC]
VAPOR PRESSURE @ 20 DEG. C (KPA): 1.6
EVAPORATION RATE: NO INFORMATION AVAILABLE
VAPOR DENSITY: 0.62
VOC CONTENT (G/L): NO INFORMATION AVAILABLE
ODOR THRESHOLD (PPM): NO INFORMATION AVAILABLE
PARTITION COEFFICIENT (N-OCTANOL/WATER): NO INFORMATION AVAILABLE
VISCOSITY: NO INFORMATION AVAILABLE
MISCIBILITY: NO INFORMATION AVAILABLE
SOLUBILITY:
EASILY SOLUBLE IN COLD WATER
EASILY SOLUBLE IN HOT WATER
| 10. STABILITY AND REACTIVITY | |
REACTIVITY:
DECOMPOSITION OF SODIUM HYPOCHLORITE TAKES PLACE WITHIN A FEW SECONDS WITH
THE FOLLOWING SALTS:
AMMONIUM ACETATE, AMMONIUM CARBONATE; AMMONIUM NITRATE, AMMONIUM OXALATE
AND AMMONIUM PHOSPHATE
PRIMARY AMINES AND SODIUM HYPOCHLORITE REACT TO FORM NORMAL CHLOROAMINES,
WHICH ARE EXPLOSIVE CHLORAMINE GAS MAY BE EVOLVED WHEN AMMONIA AND BLEACH
ARE MIXED
MIXING SODIUM HYPOCHLORITE WITH AMMONIA, ACIDS, DETERGENTS OR ORGANIC
MATTER (E.G URINE, FECES, ETC.) WILL RELEASE CHLORINE GAS CHLORINATION OF
ETHYLENEIMINE WITH SODIUM HYPOCHLORITE PRODUCES THE EXPLOSIVE COMPOUND
1-CHLOROETHYLENEIMINE
EVOLVES FLAMMABLE HYDROGEN GAS ON CONTACT WITH METALS
IT MAY BE A FIRE RISK IN CONTACT WITH ORGANIC MATERIALS
CONTACT WITH COMBUSTIBLE MATERIALS (WOOD, PAPER, OIL, CLOTHING, ETC.) MAY
CAUSE FIRE
CHEMICAL STABILITY:
STABILITY:
STABLE AT NORMAL CONDITIONS. UNSTABLE IN AIR UNLESS MIXED WITH SODUIM
HYDROXIDE. SLOWLY DECOMPOSES ON CONTACT WITH AIR. DECOMPOSED BY CARBON
DIOXIDE FROM AIR. DECOMPOSED BY HOT WATER. SENSITIVE TO LIGHT. EXPOSURE TO
LIGHT ACCELERATES DECOMPOSITION.
POSSIBILITY OF HAZARDOUS REACTIONS: HAZARDOUS POLYMERIZATION DOES NOT OCCUR
CONDITIONS TO AVOID:
HEAT. RELEASES CHLORINE WHEN HEATED ABOVE 35 DEG. C. INCOMPATIBLE
MATERIALS.
INCOMPATIBLE MATERIALS:
REDUCING AGENTS
COMBUSTIBLE MATERIALS
ORGANIC MATERIALS
METALS
ACIDS
INCOMPATIBLE WITH AMMONIUM ACETATE, AMMONIUM CARBONATE, AMMONIUM NITRATE,
AMMONIUM OXALATE, AND AMMONIUM PHOSPHATE, PRIMARY AMINES, PHENYL
ACETONITRILE, ETHYLENEIMINE, METHANOL, ACIDIFIED BENZYL CYANIDE, FORMIC
ACID, UREA, NITRO COMPOUNDS, METHYLSCELLULOSE, CELLOLUSE, AZIRIDINE, ETHER
HAZARDOUS DECOMPOSITION PRODUCTS:
WHEN HEATED TO DECOMPOSITION IT EMITS TOXIC FUMES. HYDROGEN CHLORIDE GAS.
HYDROGEN CHLORIDE. SODIUM OXIDES. CHLORINE.
OTHER INFORMATION:
CORROSIVITY:
EXTREMELY CORROSIVE IN PRESENCE OF ALUMINUM
CORROSIVE IN PRESENCE OF STAINLESS STEEL (304)
CORROSIVE IN PRESENCE OF STAINLESS STEEL (316)
SPECIAL REMARKS ON CORROSIVITY:
SODIUM HYPOCHLORITE IS EXTREMELY CORROSIVE TO BRASS AND MODERATELY
CORROSIVE TO BRONZE
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
PRINCIPAL ROUTES OF EXPOSURE: SKIN. INHALATION. INGESTION. EYES.
ACUTE TOXICITY:
COMPONENT INFORMATION:
WATER:
CAS NO: 7732-18-5
LD50/ORAL/RAT: >90 ML/KG ORAL LD50 RAT
LD50/ORAL/MOUSE: NO INFORMATION AVAILABLE
LD50/DERMAL/RABBIT: NO INFORMATION AVAILABLE
LD50/DERMAL/RAT: NO INFORMATION AVAILABLE
LC50/INHALATION/RAT: NO INFORMATION AVAILABLE
LC50/INHALATION/MOUSE: NO INFORMATION AVAILABLE
OTHER LD50 OR LC50 INFORMATION: NO INFORMATION AVAILABLE
SODIUM HYPOCHLORITE:
CAS NO: 7681-52-9
LD50/ORAL/RAT: 8.91 G/KG ORAL
LD50 RAT LD50/ORAL/MOUSE: NO INFORMATION AVAILABLE
LD50/DERMAL/RABBIT:
8200 MG/KG
>10000 MG/KG DERMAL
LD50 RABBIT LD50/DERMAL/RAT: NO INFORMATION AVAILABLE
LC50/INHALATION/RAT: NO INFORMATION AVAILABLE
LC50/INHALATION/MOUSE: NO INFORMATION AVAILABLE
OTHER LD50 OR LC50 INFORMATION: NO INFORMATION AVAILABLE
PRODUCT INFORMATION:
LD50/ORAL/RAT:
VALUE - ACUTE TOX: NO INFORMATION AVAILABLE
LD50/ORAL/MOUSE:
VALUE - ACUTE TOX ORAL: NO INFORMATION AVAILABLE
LD50/DERMAL/RABBIT:
VALUE - ACUTE TOX: NO INFORMATION AVAILABLE
LD50/DERMAL/RAT:
VALUE - ACUTE TOX DERMAL: NO INFORMATION AVAILABLE
LC50/INHALATION/RAT:
VALUE-VAPOR: NO INFORMATION AVAILABLE
VALUE-GAS: NO INFORMATION AVAILABLE
VALUE-DUST/MIST: NO INFORMATION AVAILABLE
LC50/INHALATION/MOUSE:
VALUE-VAPOR: NO INFORMATION AVAILABLE
VALUE - GAS: NO INFORMATION AVAILABLE
VALUE - DUST/MIST: NO INFORMATION AVAILABLE
SYMPTOMS:
SKIN CONTACT:
CONTACT CAUSES SEVERE SKIN IRRITATION AND POSSIBLE BURNS. CAN CAUSE BURNING
PAIN, INFLAMMATION AND BLISTERS. CONTACT WITH SKIN MAY ALSO CAUSE VESICULAR
ERUPTIONS AND ECZEMATOID DERMATITIS WHICH BECOMES EVIDENT UPON RE-EXPOSURE.
EYE CONTACT:
SEVERE EYE IRRITATION. CAUSES EYE BURNS. EYE CONTACT MAY ALSO CAUSE
LACRIMATION, CORNEAL CLOUDING, CATARACT FORMATION, NECROSIS OF THE CORNEA,
CORNEAL AND CONJUNCTIVAL EDEMA, CONJUNCTIVAL HEMORRHAGES.
INHALATION:
IRRITATING TO RESPIRATORY SYSTEM. INHALATION CAUSES SLIGHT TO SEVERE
RESPIRATORY TRACT IRRITATION AND DELAYED PULMONARY EDEMA. CAN CAUSE DYSPNEA
(SHORTNESS OF BREATH AND DIFFICULTY BREATHING). OTHER SYMPTOMS MAY INCLUDE
SORE THROAT, CHEST TIGHTNESS, COUGHING. MAY CAUSE ASTHMATIC RESPONSES.
INGESTION:
CAUSES DIGESTIVE OR GASTROINTESTINAL TRACT BURNS. SYMPTOMS OF ACUTE
INGESTION MAY INCLUDE:
1. PAIN AND INFLAMMATION OF THE MOUTH, PHARYNX, ESOPHAGUS, AND STOMACH,
DIFFICULTY SWALLOWING, ABDOMINAL PAIN, DROOLING
2. EROSION OF THE MUCOUS MEMBRANES (CHIEFLY OF THE STOMACH), NAUSEA,
VOMITING, DIARRHEA, CHOKING, COUGHING, HEMORRHAGE
3. HYPOTENSION AND CIRCULATORY COLLAPSE WITH COLD AND CLAMMY SKIN (DUE TO
METHEMOGLOBINEMIA), CYANOSIS, AND SHORTNESS OF BREATH AND SHALLOW
RESPIRATIONS
4. CONFUSION, DELIRIUM, SOMNOLENCE, COMA
5. EDEMA OF THE PHARYNX, GLOTTIS, LARYNX WITH STRIDOR AND OBSTRUCTION
6. PERFORATION OF THE ESOPHAGUS, OR STOMACH, WITH MEDIASTINITIS OR
PERITONITIS.
ASPIRATION HAZARD: NO INFORMATION AVAILABLE.
DELAYED AND IMMEDIATE EFFECTS AS WELL AS CHRONIC EFFECTS FROM SHORT AND
LONG-TERM EXPOSURE:
CHRONIC TOXICITY: NO INFORMATION AVAILABLE.
SENSITIZATION: NO INFORMATION AVAILABLE.
MUTAGENIC EFFECTS:
FOR SODIUM HYPOCHLORITE:
MAY AFFECT GENETIC MATERIAL
EXPERIMENTS WITH BACTERIA AND/OR YEAST HAVE SHOWN MUTAGENIC EFFECTS
CARCINOGENIC EFFECTS:
NOT CONSIDERED CARCINOGENIC. NOT CLASSIFIABLE AS TO ITS CARCINOGENICITY TO
HUMANS.
COMPONENT CAS NO IARC ACGIH - NTP
CARCINOGENS
WATER 7732-18-5 NOT LISTED NOT LISTED NOT LISTED
SODIUM 7681-52-9 GROUP 3 - NOT NOT LISTED NOT LISTED
HYPOCHLORITE CLASSIFIABLE -
MONOGRAPH 52 [1991]
HYPOCHLORITE SALTS
COMPONENT OSHA HCS - AUSTRALIA - AUSTRALIA -
CARCINOGENS NOTIFIABLE PROHIBITED
CARCINOGENIC CARCINOGENIC
SUBSTANCES SUBSTANCES
WATER NOT LISTED NOT LISTED NOT LISTED
SODIUM HYPOCHLORITE NOT LISTED NOT LISTED NOT LISTED
ACGIH (AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS):
IARC: (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER)
NTP: (NATIONAL TOXICOLOGY PROGRAM)
OSHA (OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION OF THE US DEPARTMENT
OF LABOR):
REPRODUCTIVE TOXICITY: NO DATA IS AVAILABLE
REPRODUCTIVE EFFECTS: NO INFORMATION AVAILABLE
DEVELOPMENTAL EFFECTS: NO INFORMATION AVAILABLE
TERATOGENIC EFFECTS: NO INFORMATION AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY:
STOT - SINGLE EXPOSURE: NO INFORMATION AVAILABLE.
STOT - REPEATED EXPOSURE: NO INFORMATION AVAILABLE.
TARGET ORGANS: LUNGS. MUCOUS MEMBRANE. RESPIRATORY SYSTEM. SKIN. EYES.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
ECOTOXICITY EFFECTS: AQUATIC ENVIRONMENT. TOXIC TO AQUATIC ORGANISMS.
SODIUM HYPOCHLORITE - 7681-52-9:
ALGAE/AQUATIC PLANTS:
FISH:
0.095 MG/L EC50 SKELETONEMA COSTATUM 24 H 0.06 - 0.11 MG/L
LC50 PIMEPHALES PROMELAS 96 H FLOW-THROUGH 1 4.5 - 7.6MG/L
LC50 PIMEPHALES PROMELAS 96 H STATIC 1 0.4 - 0.8 MG/L
LC50 LEPOMIS MACROCHIRUS 96 H STATIC 1 0.28 - 1 MG/L
LC50 LEPOMIS MACROCHIRUS 96 H FLOW-THROUGH 1 0.05 - 0.771 MG/L
LC50 ONCORHYNCHUS MYKISS 96 H FLOW-THROUGH 1 0.03 - 0.19 MG/L
LC50 ONCORHYNCHUS MYKISS 96 H SEMI-STATIC 1 0.18 - 0.22 MG/L
LC50 ONCORHYNCHUS MYKISS 96 H STATIC 1 0.033 - 0.044 MG/L
EC50 DAPHNIA MAGNA 48 H 2.1 MG/L EC50 DAPHNIA MAGNA 96H
CRUSTACEA:
PERSISTENCE AND DEGRADABILITY: NO INFORMATION AVAILABLE
BIOACCUMULATIVE POTENTIAL: NO INFORMATION AVAILABLE.
MOBILITY IN SOIL: NO INFORMATION AVAILABLE
OTHER ADVERSE EFFECTS: NO INFORMATION AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
WASTE FROM RESIDUES / UNUSED PRODUCTS:
WASTE MUST BE DISPOSED OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL
REGULATION.
CONTAMINATED PACKAGING:
EMPTY CONTAINERS SHOULD BE TAKEN FOR LOCAL RECYCLING, RECOVERY OR WASTE
DISPOSAL
COMPONENT CAS NO RCRA - F RCRA - K RCRA - P RCRA - U
SERIES SERIES SERIES SERIES
WASTES WASTES WASTES WASTES
WATER 7732-18-5 NONE NONE NONE NONE
SODIUM 7681-52-9 NONE NONE NONE NONE
HYPOCHLORITE
| 14. TRANSPORT INFORMATION | |
DOT:
UN-NO: UN1791
PROPER SHIPPING NAME: HYPOCHLORITE SOLUTIONS
HAZARD CLASS: 8
SUBSIDIARY CLASS: NO INFORMATION AVAILABLE
PACKING GROUP: III
EMERGENCY RESPONSE GUIDE NUMBER: 154
MARINE POLLUTANT: NO DATA AVAILABLE
DOT RQ (LBS): NO INFORMATION AVAILABLE
SPECIAL PROVISIONS: IB3, N34, T4, TP2, TP24
SYMBOL(S): NO INFORMATION AVAILABLE
DESCRIPTION: UN1791, HYPOCHLORITE SOLUTIONS, 8, III
TDG (CANADA):
UN-NO: UN1791
PROPER SHIPPING NAME: HYPOCHLORITE SOLUTION
HAZARD CLASS: 8
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: III
MARINE POLLUTANT: NO INFORMATION AVAILABLE
DESCRIPTION: UN1791, HYPOCHLORITE SOLUTION, 8, III
ADR:
UN NUMBER: UN1791
PROPER SHIPPING NAME: HYPOCHLORITE SOLUTION
TRANSPORT HAZARD CLASS(ES): 8
PACKING GROUP: III
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
SPECIAL PROVISIONS: 521
DESCRIPTION:
UN1791, HYPOCHLORITE SOLUTION, 8, III, ENVIRONMENTALLY HAZARDOUS
IMDG:
UN-NO: UN1791
PROPER SHIPPING NAME: HYPOCHLORITE SOLUTIONS
HAZARD CLASS: 8
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: III
MARINE POLLUTANT: NO INFORMATION AVAILABLE
EMS: F-A
SPECIAL PROVISIONS: 223
DESCRIPTION: UN1791, HYPOCHLORITE SOLUTION, 8, III, MARINE POLLUTANT
RID:
UN NUMBER: UN1791
PROPER SHIPPING NAME: HYPOCHLORITE SOLUTION
TRANSPORT HAZARD CLASS(ES): 8
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: III
SPECIAL PROVISIONS: 521
DESCRIPTION:
UN1791, HYPOCHLORITE SOLUTION, 8, III, ENVIRONMENTALLY HAZARDOUS
ICAO (AIR):
UN-NO: UN1791
PROPER SHIPPING NAME: HYPOCHLORITE SOLUTION
HAZARD CLASS: 8
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: III
DESCRIPTION: UN1791, HYPOCHLORITE SOLUTION, 8, III
SPECIAL PROVISIONS: A3
IATA:
UN NUMBER: UN1791
PROPER SHIPPING NAME: HYPOCHLORITE SOLUTION
TRANSPORT HAZARD CLASS(ES): 8
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: III
PRECAUTIONARY STATEMENTS - RESPONSE: 8L
SPECIAL PROVISIONS: NO INFORMATION AVAILABLE
DESCRIPTION: UN1791, HYPOCHLORITE SOLUTION, 8, III
| 15. REGULATORY INFORMATION | |
INTERNATIONAL INVENTORIES:
COMPONENT CAS NO U.S. TSCA KOREA KECL PHILIPPINES
(PICCS)
WATER 7732-18-5 PRESENT ACTIVE PRESENT PRESENT
KE-35400
SODIUM 7681-52-9 PRESENT ACTIVE PRESENT PRESENT
HYPOCHLORITE KE-31506
COMPONENT JAPAN ENCS CHINA IECSC AUSTRALIA EINECS-NO.
(AICS)
WATER NOT PRESENT PRESENT PRESENT PRESENT
231-791-2
SODIUM PRESENT PRESENT PRESENT PRESENT
HYPOCHLORITE (1)-237 231-668-3
U.S. REGULATIONS:
SODIUM HYPOCHLORITE:
MASSACHUSETTS RTK: PRESENT
NEW JERSEY RTK HAZARDOUS SUBSTANCE LIST: 1707
NEW JERSEY - DISCHARGE PREVENTION - LIST OF HAZARDOUS SUBSTANCES: PRESENT
PENNSYLVANIA RTK: ENVIRONMENTAL HAZARD
PENNSYLVANIA RTK - ENVIRONMENTAL HAZARD LIST PRESENT
MINNESOTA - HAZARDOUS SUBSTANCE LIST: PRESENT
NEW YORK RELEASE REPORTING - LIST OF HAZARDOUS SUBSTANCES: 100 LB RQ
LOUISANA REPORTABLE QUANTITY LIST FOR POLLUTANTS:
100 LB FINAL RQ
45.4 KG FINAL RQ
CALIFORNIA DIRECTORS LIST OF HAZARDOUS SUBSTANCES: PRESENT
FDA - DIRECT FOOD ADDITIVES: 21 CFR 173.315
FDA - 21 CFR - TOTAL FOOD ADDITIVES - LIST SOURCED FROM EAFUS:
172.892, 173.315, 175.105, 176.170, 177.2800, 178.1010
CALIFORNIA PROP. 65: SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986.
CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER:
THIS PRODUCT DOES NOT CONTAIN A CHEMICAL REQUIRING A WARNING UNDER
CALIFORNIA PROP. 65. (SEE TABLE BELOW)
CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE REPRODUCTIVE TOXICITY:
THIS PRODUCT DOES NOT CONTAIN A CHEMICAL REQUIRING A WARNING UNDER
CALIFORNIA PROP. 65. (SEE TABLE BELOW)
COMPONENT CAS NO
WATER 7732-18-5
SODIUM HYPOCHLORITE 7681-52-9
COMPONENT CARCINOGEN DEVELOPMENTAL MALE FEMALE
TOXICITY REPRODUCTIVE REPRODUCTIVE
TOXICITY TOXICITY:
WATER NOT LISTED NOT LISTED NOT LISTED NOT LISTED
SODIUM NOT LISTED NOT LISTED NOT LISTED NOT LISTED
HYPOCHLORITE
CERCLA/SARA:
COMPONENT CAS NO CERCLA - HAZARDOUS SECTION 302 EXTREMELY
SUBSTANCES AND THEIR HAZARDOUS SUBSTANCES
REPORTABLE QUANTITIES AND TPQS RQS
WATER 7732-18-5 NONE NONE
SODIUM 7681-52-9 100 LB FINAL RQ NONE
HYPOCHLORITE 45.4 KG FINAL RQ
COMPONENT SECTION 302 SECTION 313 - SECTION 313 -
EXTREMELY HAZARDOUS CHEMICAL REPORTING
SUBSTANCES AND RQS CATEGORY DE MINIMIS
WATER NONE NONE NONE
SODIUM HYPOCHLORITE NONE NONE NONE
U.S. TSCA:
COMPONENT CAS NO TSCA SECTION 5(A)2 - TSCA 8(D) - HEALTH
CHEMICALS WITH AND SAFETY REPORTING
SIGNIFICANT NEW
USE RULES (SNURS)
WATER 7732-18-5 NOT APPLICABLE NOT APPLICABLE
SODIUM 7681-52-9 NOT APPLICABLE NOT APPLICABLE
HYPOCHLORITE
CANADA:
WHIMIS 2015 - GHS CLASSIFICATIONS:
WHMIS 2015 HAZARD CLASSIFICATION INFORMATION:
THE WHMIS 2015 CLASSIFICATION OF THIS PRODUCT HAS NOT BEEN VALIDATED OR
REVIEWED YET.
COMPONENT:
WATER: 7732-18-5 (85-87)
SODIUM HYPOCHLORITE: 7681-52-9 (12-14)
WHMIS 2015 HAZARD CLASSIFICATION:
NOT A DANGEROUS PRODUCT ACCORDING TO HPR CLASSIFICATION CRITERIA
SKIN CORROSION/IRRITATION - CATEGORY 2:
H315: CAUSES SKIN IRRITATION. (12%)
SERIOUS EYE DAMAGE/EYE IRRITATION - CATEGORY 1:
H318: CAUSES SERIOUS EYE DAMAGE. (12%)
SERIOUS EYE DAMAGE/EYE IRRITATION - CATEGORY 2A:
H319: CAUSES SERIOUS EYE IRRITATION. (4%)
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE - CATEGORY 3:
H335: MAY CAUSE RESPIRATORY IRRITATION. (12%)
CANADA HAZARDOUS PRODUCTS REGULATION:
THIS PRODUCT HAS BEEN CLASSIFIED ACCORDING TO THE HAZARD CRITERIA OF THE
HPR (HAZARDOUS PRODUCTS REGULATION) AND THE SDS CONTAINS ALL OF THE
INFORMATION REQUIRED BY THE HPR
DSL/NDSL:
COMPONENT CAS NO CANADA (DSL) CANADA (NDSL)
WATER 7732-18-5 PRESENT NOT LISTED
SODIUM HYPOCHLORITE 7681-52-9 PRESENT NOT LISTED
COMPONENT CAS NO CEPA SCHEDULE I - TOXIC SUBSTANCES
WATER 7732-18-5 NOT LISTED
SODIUM HYPOCHLORITE 7681-52-9 NOT LISTED
COMPONENT CAS NO CEPA - 2010 GREENHOUSE GASES SUBJECT
TO MANDATORY REPORTING
WATER 7732-18-5 NOT LISTED
SODIUM HYPOCHLORITE 7681-52-9 NOT LISTED
EU CLASSIFICATION:
EU GHS - SV - CLP 1272/2008:
COMPONENT CAS NO EU GHS - SV - CLP (1272/2008)
WATER 7732-18-5
SODIUM HYPOCHLORITE 7681-52-9 SKIN CORROSION/IRRITATION - SKIN
CORR. 1B:
H314 CAUSES SEVERE SKIN BURNS AND
EYE DAMAGE.
HAZARDOUS TO AQUATIC ENVIRONMENT -
ACUTE HAZARD - AQUATIC ACUTE 1:
H400 VERY TOXIC TO AQUATIC LIFE.
SUPPLEMENTAL HAZARDS:
EUH031 CONTACT WITH ACIDS LIBERATES
TOXIC GAS. (C >=5%) 017-011-00-1
SUPPLEMENTAL HAZARDS: EUH031
CONTACT WITH ACIDS LIBERATES TOXIC
GAS. (C >=5%) 017-011-00-1
EU - CLP (1272/2008):
R-PHRASE(S):
R31: CONTACT WITH ACIDS LIBERATES TOXIC GAS
R34: CAUSES BURNS
R50: VERY TOXIC TO AQUATIC ORGANISMS
S-PHRASE(S):
S28: AFTER CONTACT WITH SKIN, WASH IMMEDIATELY WITH PLENTY OF WATER
S45:
IN CASE OF ACCIDENT OR IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE IMMEDIATELY
(SHOW THE LABEL WHERE POSSIBLE)
S50A: DO NOT MIX WITH ACIDS
S 1/2: KEEP LOCKED UP AND OUT OF THE REACH OF CHILDREN.
COMPONENT CAS NO CLASSIFICATION CONCENTRATION SAFETY PHRASES
LIMITS:
WATER 7732-18-5 NO INFORMATION
SODIUM 7681-52-9 R31 10%<C S(1/2)-S28-
HYPOCHLORITE C; R34 C;R31-34% S45-S50
N; R50 5%<=C<=10%
XI;R31-36/38%
THE PRODUCT IS CLASSIFIED IN ACCORDANCE WITH ANNEX VI TO DIRECTIVE
67/548/EEC
INDICATION OF DANGER:
C - CORROSIVE
C:
E - CORROSIVE MATERIAL
| 16. OTHER INFORMATION | |
PREPARATION DATE: 09/24/2015
REVISION DATE: 4/3/2019
PREPARED BY: SONIA OWEN
DISCLAIMER:
ALL CHEMICALS MAY POSE UNKNOWN HAZARDS AND SHOULD BE USED WITH CAUTION.
THIS SAFETY DATA SHEET (SDS) APPLIES ONLY TO THE MATERIAL AS PACKAGED.
IF THIS PRODUCT IS COMBINED WITH OTHER MATERIALS, DETERIORATES, OR BECOMES
CONTAMINATED, IT MAY POSE HAZARDS NOT MENTIONED IN THIS SDS. THE PHYSICAL
PROPERTIES REPORTED IN THIS SDS ARE OBTAINED FROM THE LITERATURE AND DO NOT
CONSTITUTE PRODUCT SPECIFICATIONS. INFORMATION CONTAINED HEREIN DOES NOT
CONSTITUTE A WARRANTY, WHETHER EXPRESSED OR IMPLIED, AS TO THE SAFETY,
MERCHANTABILITY OR FITNESS OF THE GOODS FOR A PARTICULAR PURPOSE. SPECTRUM
CHEMICALS & LABORATORY PRODUCTS, INC. ASSUMES NO RESPONSIBILITY FOR RESULTS
OBTAINED OR FOR INCIDENTAL OR CONSEQUENTIAL DAMAGES, INCLUDING LOST
PROFITS, ARISING FROM THE USE OF THESE DATA. NO WARRANTY AGAINST
INFRINGEMENT OF ANY PATENT, COPYRIGHT OR TRADEMARK IS MADE OR IMPLIED.
IT SHALL BE THE USER'S RESPONSIBILITY TO DEVELOP PROPER METHODS OF HANDLING
AND PERSONAL PROTECTION BASED ON THE ACTUAL CONDITIONS OF USE. WHILE THIS
SDS IS BASED ON TECHNICAL DATA JUDGED TO BE RELIABLE, SPECTRUM ASSUMES NO
RESPONSIBILITY FOR THE COMPLETENESS OR ACCURACY OF THE INFORMATION
CONTAINED HEREIN.