| Common Name: | HYDROFLUORIC ACID, 48 PERCENT, REAGENT, ACS |
| Manufacturer: | SPECTRUM CHEMICAL MFG. |
| SDS Revision Date: | 3/31/2021 |
| SDS Format: | No Format Specified |
| Item Number(s): | 6PHX9 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SPECTRUM(R*)
SAFETY DATA SHEET
SPECTRUM(R*)
REVISION DATE: 31-MARCH-2021
REVISION NUMBER: 6
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER:
PRODUCT NAME: HYDROFLUORIC ACID, 48 PERCENT, REAGENT, ACS
OTHER MEANS OF IDENTIFICATION:
PRODUCT CODE(S): H1045
UN/ID NO: UN1790
SYNONYMS: NONE
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE: NO INFORMATION AVAILABLE
RESTRICTIONS ON USE: NO INFORMATION AVAILABLE
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
SUPPLIER ADDRESS:
SPECTRUM CHEMICAL MFG. CORP.
14422 SOUTH SAN PEDRO ST.
GARDENA, CA 90248
(310) 516-8000
EMERGENCY TELEPHONE NUMBER:
EMERGENCY TELEPHONE:
CHEMTREC: 1-800-424-9300
| 2. HAZARD(S) IDENTIFICATION | |
CLASSIFICATION:
ACUTE TOXICITY - ORAL: CATEGORY 2
ACUTE TOXICITY - DERMAL: CATEGORY 1
ACUTE TOXICITY - INHALATION (GASES): CATEGORY 2
ACUTE TOXICITY - INHALATION (DUSTS/MISTS): CATEGORY 2
SKIN CORROSION/IRRITATION: CATEGORY 1 SUB-CATEGORY A
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 1
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 1
CORROSIVE TO METALS: CATEGORY 1
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC): NOT APPLICABLE
LABEL ELEMENTS:
DANGER
HAZARD STATEMENTS:
FATAL IF SWALLOWED
FATAL IN CONTACT WITH SKIN
FATAL IF INHALED
CAUSES SEVERE SKIN BURNS AND EYE DAMAGE
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE
MAY BE CORROSIVE TO METALS
THE BURNS MAY NOT BE PAINFUL OR VISIBLE
SKULLS AND CROSSBONES
HEALTH HAZARD
CORROSION
APPEARANCE: CLEAR
PHYSICAL STATE: LIQUID
ODOR: STRONG
PRECAUTIONARY STATEMENTS - PREVENTION:
WASH FACE, HANDS AND ANY EXPOSED SKIN THOROUGHLY AFTER HANDLING
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT
DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA
WEAR RESPIRATORY PROTECTION
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION
KEEP ONLY IN ORIGINAL CONTAINER
PRECAUTIONARY STATEMENTS - RESPONSE:
IMMEDIATELY CALL A POISON CENTER OR DOCTOR
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING
IMMEDIATELY CALL A POISON CENTER OR DOCTOR
IMMEDIATELY CALL A POISON CENTER OR DOCTOR
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER
WASH CONTAMINATED CLOTHING BEFORE REUSE
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING
IMMEDIATELY CALL A POISON CENTER OR DOCTOR
IF SWALLOWED: IMMEDIATELY CALL A POISON CENTER OR DOCTOR
RINSE MOUTH
DO NOT INDUCE VOMITING
ABSORB SPILLAGE TO PREVENT MATERIAL DAMAGE
PRECAUTIONARY STATEMENTS - STORAGE:
STORE LOCKED UP.
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED
STORE IN CORROSIVE RESISTANT/ .. CONTAINER WITH A RESISTANT INNER LINER
PRECAUTIONARY STATEMENTS - DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT
UNKNOWN ACUTE TOXICITY:
0% OF THE MIXTURE CONSISTS OF INGREDIENT(S) OF UNKNOWN ACUTE ORAL TOXICITY
0% OF THE MIXTURE CONSISTS OF INGREDIENT(S) OF UNKNOWN ACUTE DERMAL
TOXICITY
0% OF THE MIXTURE CONSISTS OF INGREDIENT(S) OF UNKNOWN ACUTE INHALATION
TOXICITY (GAS)
0% OF THE MIXTURE CONSISTS OF INGREDIENT(S) OF UNKNOWN ACUTE INHALATION
TOXICITY (DUST/MIST)
OTHER INFORMATION: NO INFORMATION AVAILABLE.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE: NOT APPLICABLE.
MIXTURE:
CHEMICAL NAME CAS NO WEIGHT-% TRADE SECRET
WATER 7732-18-5 48 - 54 *
HYDROGEN FLUORIDE 7664-39-3 46 - 52 *
*THE EXACT PERCENTAGE (CONCENTRATION) OF COMPOSITION HAS BEEN WITHHELD AS
A TRADE SECRET.
| 4. FIRST-AID MEASURES | |
DESCRIPTION OF FIRST AID MEASURES:
GENERAL ADVICE:
SHOW THIS SAFETY DATA SHEET TO THE DOCTOR IN ATTENDANCE. IMMEDIATE MEDICAL
ATTENTION IS REQUIRED.
INHALATION:
REMOVE TO FRESH AIR. IF BREATHING HAS STOPPED, GIVE ARTIFICIAL
RESPIRATION. GET MEDICAL ATTENTION IMMEDIATELY. DO NOT USE MOUTH-TO-MOUTH
METHOD IF VICTIM INGESTED OR INHALED THE SUBSTANCE; GIVE ARTIFICIAL
RESPIRATION WITH THE AID OF A POCKET MASK EQUIPPED WITH A ONE-WAY VALVE
OR OTHER PROPER RESPIRATORY MEDICAL DEVICE. IF BREATHING IS DIFFICULT,
(TRAINED PERSONNEL SHOULD) GIVE OXYGEN. DELAYED PULMONARY EDEMA MAY OCCUR.
GET IMMEDIATE MEDICAL ADVICE/ATTENTION.
EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS, FOR AT
LEAST 15 MINUTES. REMOVE CONTACT LENSES, IF PRESENT AND EASY TO DO.
CONTINUE RINSING. KEEP EYE WIDE OPEN WHILE RINSING. DO NOT RUB AFFECTED
AREA. GET IMMEDIATE MEDICAL ADVICE/ATTENTION.
SKIN CONTACT:
GET IMMEDIATE MEDICAL ADVICE/ATTENTION. WASH OFF IMMEDIATELY WITH SOAP AND
PLENTY OF WATER WHILE REMOVING ALL CONTAMINATED CLOTHES AND SHOES.
INGESTION:
CLEAN MOUTH WITH WATER AND DRINK AFTERWARDS PLENTY OF WATER. NEVER GIVE
ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. DO NOT INDUCE VOMITING. GET
IMMEDIATE MEDICAL ADVICE/ATTENTION.
SELF-PROTECTION OF THE FIRST AIDER:
AVOID CONTACT WITH SKIN, EYES OR CLOTHING. ENSURE THAT MEDICAL PERSONNEL
ARE AWARE OF THE MATERIAL(S) INVOLVED, TAKE PRECAUTIONS TO PROTECT
THEMSELVES AND PREVENT SPREAD OF CONTAMINATION. DO NOT BREATHE VAPOR OR
MIST. DO NOT USE MOUTH-TO-MOUTH METHOD IF VICTIM INGESTED OR INHALED THE
SUBSTANCE; GIVE ARTIFICIAL RESPIRATION WITH THE AID OF A POCKET MASK
EQUIPPED WITH A ONE-WAY VALVE OR OTHER PROPER RESPIRATORY MEDICAL DEVICE.
USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED. SEE SECTION 8 FOR MORE
INFORMATION.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS:
COUGHING AND/OR WHEEZING. DIFFICULTY IN BREATHING. BURNING SENSATION.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
NOTE TO PHYSICIANS:
PRODUCT IS A CORROSIVE MATERIAL. USE OF GASTRIC LAVAGE OR EMESIS IS
CONTRAINDICATED. POSSIBLE PERFORATION OF STOMACH OR ESOPHAGUS SHOULD BE
INVESTIGATED. DO NOT GIVE CHEMICAL ANTIDOTES. ASPHYXIA FROM GLOTTAL EDEMA
MAY OCCUR. MARKED DECREASE IN BLOOD PRESSURE MAY OCCUR WITH MOIST RALES,
FROTHY SPUTUM, AND HIGH PULSE PRESSURE.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
USE EXTINGUISHING MEASURES THAT ARE APPROPRIATE TO LOCAL CIRCUMSTANCES
AND THE SURROUNDING ENVIRONMENT.
LARGE FIRE:
CAUTION: USE OF WATER SPRAY WHEN FIGHTING FIRE MAY BE INEFFICIENT.
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT SCATTER SPILLED MATERIAL WITH HIGH PRESSURE WATER STREAMS.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
THE PRODUCT CAUSES BURNS OF EYES, SKIN AND MUCOUS MEMBRANES. THERMAL
DECOMPOSITION CAN LEAD TO RELEASE OF IRRITATING GASES AND VAPORS.
HAZARDOUS COMBUSTION PRODUCTS: HYDROGEN FLUORIDE GAS.
EXPLOSION DATA:
SENSITIVITY TO MECHANICAL IMPACT: NONE.
SENSITIVITY TO STATIC DISCHARGE: NONE.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
FIREFIGHTERS SHOULD WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL
FIREFIGHTING TURNOUT GEAR. USE PERSONAL PROTECTION EQUIPMENT.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
AVOID CONTACT WITH SKIN, EYES OR CLOTHING. ENSURE ADEQUATE VENTILATION.
USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED. EVACUATE PERSONNEL TO SAFE
AREAS. DO NOT BREATHE VAPOR OR MIST. KEEP PEOPLE AWAY FROM AND UPWIND OF
SPILL/LEAK. ATTENTION! CORROSIVE MATERIAL.
OTHER INFORMATION:
REFER TO PROTECTIVE MEASURES LISTED IN SECTIONS 7 AND 8.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CONTAINMENT:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO.
METHODS FOR CLEANING UP:
PICK UP AND TRANSFER TO PROPERLY LABELED CONTAINERS.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
ADVICE ON SAFE HANDLING:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
AVOID CONTACT WITH SKIN, EYES OR CLOTHING. TAKE OFF CONTAMINATED CLOTHING
AND WASH BEFORE REUSE. DO NOT BREATHE VAPOR OR MIST. IN CASE OF
INSUFFICIENT VENTILATION, WEAR SUITABLE RESPIRATORY EQUIPMENT. HANDLE
PRODUCT ONLY IN CLOSED SYSTEM OR PROVIDE APPROPRIATE EXHAUST VENTILATION.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE CONDITIONS:
KEEP CONTAINERS TIGHTLY CLOSED IN A DRY, COOL AND WELL-VENTILATED PLACE.
PROTECT FROM MOISTURE. STORE LOCKED UP. KEEP OUT OF THE REACH OF CHILDREN.
STORE AWAY FROM OTHER MATERIALS.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
EXPOSURE LIMITS:
THE FOLLOWING INGREDIENTS ARE THE ONLY INGREDIENTS OF THE PRODUCT ABOVE
THE CUT-OFF LEVEL (OR LEVEL THAT CONTRIBUTES TO THE HAZARD CLASSIFICATION
OF THE MIXTURE) WHICH HAVE AN EXPOSURE LIMIT APPLICABLE IN THE REGION FOR
WHICH THIS SAFETY DATA SHEET IS INTENDED OR OTHER RECOMMENDED LIMIT. AT
THIS TIME, THE OTHER RELEVANT CONSTITUENTS HAVE NO KNOWN EXPOSURE LIMITS
FROM THE SOURCES LISTED HERE.
CHEMICAL NAME ACGIH TLV OSHA PEL NIOSH IDLH
HYDROGEN FLUORIDE NO DATA AVAILABLE 3 PPM TWA 30 PPM IDLH (AS F)
7664-39-3
APPROPRIATE ENGINEERING CONTROLS:
ENGINEERING CONTROLS:
SHOWERS
EYEWASH STATIONS
VENTILATION SYSTEMS.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION: TIGHT SEALING SAFETY GOGGLES. FACE PROTECTION SHIELD.
HAND PROTECTION: WEAR SUITABLE GLOVES. IMPERVIOUS GLOVES.
SKIN AND BODY PROTECTION:
IMPERVIOUS CLOTHING. WEAR SUITABLE PROTECTIVE CLOTHING. LONG SLEEVED
CLOTHING. CHEMICAL RESISTANT APRON.
RESPIRATORY PROTECTION:
WHEN WORKERS ARE FACING CONCENTRATIONS ABOVE THE EXPOSURE LIMIT THEY MUST
USE APPROPRIATE CERTIFIED RESPIRATORS.
GENERAL HYGIENE CONSIDERATIONS:
WEAR SUITABLE GLOVES AND EYE/FACE PROTECTION. DO NOT EAT, DRINK OR SMOKE
WHEN USING THIS PRODUCT. REGULAR CLEANING OF EQUIPMENT, WORK AREA AND
CLOTHING IS RECOMMENDED. WASH HANDS BEFORE BREAKS AND IMMEDIATELY AFTER
HANDLING THE PRODUCT. AVOID CONTACT WITH SKIN, EYES OR CLOTHING. REMOVE AND
WASH CONTAMINATED CLOTHING AND GLOVES, INCLUDING THE INSIDE, BEFORE RE-USE.
DO NOT BREATHE VAPOR OR MIST. CONTAMINATED WORK CLOTHING SHOULD NOT BE
ALLOWED OUT OF THE WORKPLACE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
APPEARANCE: CLEAR
COLOR: COLORLESS
ODOR: STRONG
ODOR THRESHOLD: NO INFORMATION AVAILABLE
PROPERTY VALUES REMARKS - METHOD
PH NO DATA AVAILABLE NONE KNOWN
MELTING POINT/FREEZING POINT -37 DEG. C / NONE KNOWN
-34.6 DEG. F
BOILING POINT/BOILING RANGE 112 DEG. C / NONE KNOWN
233.6 DEG. F
FLASH POINT NO DATA AVAILABLE NONE KNOWN
EVAPORATION RATE NO DATA AVAILABLE NONE KNOWN
FLAMMABILITY (SOLID, GAS) NO DATA AVAILABLE NONE KNOWN
FLAMMABILITY LIMIT IN AIR NONE KNOWN
UPPER FLAMMABILITY OR EXPLOSIVE NO DATA AVAILABLE
LIMITS
LOWER FLAMMABILITY OR EXPLOSIVE NO DATA AVAILABLE
LIMITS
VAPOR PRESSURE 1.65 @ 20 DEG. C NONE KNOWN
(KPA)
VAPOR DENSITY NO DATA AVAILABLE NONE KNOWN
RELATIVE DENSITY 1.15 NONE KNOWN
WATER SOLUBILITY EASILY SOLUBLE IN NONE KNOWN
HOT WATER
EASILY SOLUBLE IN
COLD WATER
SOLUBILITY(IES) VERY SOLUBLE IN NONE KNOWN
ACETONE
SLIGHTLY SOLUBLE
IN ETHER
PARTITION COEFFICIENT NO DATA AVAILABLE NONE KNOWN
AUTOIGNITION TEMPERATURE NO DATA AVAILABLE NONE KNOWN
DECOMPOSITION TEMPERATURE NONE KNOWN
KINEMATIC VISCOSITY NO DATA AVAILABLE NONE KNOWN
DYNAMIC VISCOSITY NO DATA AVAILABLE NONE KNOWN
OTHER INFORMATION:
EXPLOSIVE PROPERTIES NO INFORMATION
AVAILABLE
OXIDIZING PROPERTIES NO INFORMATION
AVAILABLE
SOFTENING POINT NO INFORMATION
AVAILABLE
MOLECULAR WEIGHT 20.01
VOC CONTENT (%) NO INFORMATION
AVAILABLE
LIQUID DENSITY NO INFORMATION
AVAILABLE
BULK DENSITY NO INFORMATION
AVAILABLE
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: NO INFORMATION AVAILABLE.
CHEMICAL STABILITY: STABLE UNDER NORMAL CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
CONDITIONS TO AVOID:
EXPOSURE TO AIR OR MOISTURE OVER PROLONGED PERIODS. EXCESSIVE HEAT.
INCOMPATIBLE MATERIALS: OXIDIZING AGENT. ACIDS. BASES.
HAZARDOUS DECOMPOSITION PRODUCTS: NONE KNOWN BASED ON INFORMATION SUPPLIED.
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
PRODUCT INFORMATION:
INHALATION:
SPECIFIC TEST DATA FOR THE SUBSTANCE OR MIXTURE IS NOT AVAILABLE. FATAL
IF INHALED. (BASED ON COMPONENTS). CORROSIVE BY INHALATION. INHALATION OF
CORROSIVE FUMES/GASES MAY CAUSE COUGHING, CHOKING, HEADACHE, DIZZINESS,
AND WEAKNESS FOR SEVERAL HOURS. PULMONARY EDEMA MAY OCCUR WITH TIGHTNESS
IN THE CHEST, SHORTNESS OF BREATH, BLUISH SKIN, DECREASED BLOOD PRESSURE,
AND INCREASED HEART RATE. INHALED CORROSIVE SUBSTANCES CAN LEAD TO A TOXIC
EDEMA OF THE LUNGS. PULMONARY EDEMA CAN BE FATAL.
EYE CONTACT:
SPECIFIC TEST DATA FOR THE SUBSTANCE OR MIXTURE IS NOT AVAILABLE. CAUSES
SERIOUS EYE DAMAGE. (BASED ON COMPONENTS). CORROSIVE TO THE EYES AND MAY
CAUSE SEVERE DAMAGE INCLUDING BLINDNESS. MAY CAUSE IRREVERSIBLE DAMAGE
TO EYES.
SKIN CONTACT:
SPECIFIC TEST DATA FOR THE SUBSTANCE OR MIXTURE IS NOT AVAILABLE. FATAL IN
CONTACT WITH SKIN. (BASED ON COMPONENTS). CORROSIVE. CAUSES BURNS.
INGESTION:
SPECIFIC TEST DATA FOR THE SUBSTANCE OR MIXTURE IS NOT AVAILABLE. CAUSES
BURNS. (BASED ON COMPONENTS). INGESTION CAUSES BURNS OF THE UPPER DIGESTIVE
AND RESPIRATORY TRACTS. MAY CAUSE SEVERE BURNING PAIN IN THE MOUTH AND
STOMACH WITH VOMITING AND DIARRHEA OF DARK BLOOD. BLOOD PRESSURE MAY
DECREASE. BROWNISH OR YELLOWISH STAINS MAY BE SEEN AROUND THE MOUTH.
SWELLING OF THE THROAT MAY CAUSE SHORTNESS OF BREATH AND CHOKING. MAY
CAUSE LUNG DAMAGE IF SWALLOWED. FATAL IF SWALLOWED.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
SYMPTOMS:
COUGHING AND/OR WHEEZING. DIFFICULTY IN BREATHING. REDNESS. BURNING.
MAY CAUSE BLINDNESS.
ACUTE TOXICITY:
NUMERICAL MEASURES OF TOXICITY:
THE FOLLOWING VALUES ARE CALCULATED BASED ON CHAPTER 3.1 OF THE
GHS DOCUMENT:
ATEMIX (ORAL): 10.89 MG/KG
ATEMIX (DERMAL): 10.90 MG/KG
ATEMIX (INHALATION-GAS): 217.41 PPM
ATEMIX (INHALATION-DUST/MIST): 0.11 MG/L
UNKNOWN ACUTE TOXICITY:
0% OF THE MIXTURE CONSISTS OF INGREDIENT(S) OF UNKNOWN ACUTE ORAL TOXICITY
0% OF THE MIXTURE CONSISTS OF INGREDIENT(S) OF UNKNOWN ACUTE DERMAL
TOXICITY
0% OF THE MIXTURE CONSISTS OF INGREDIENT(S) OF UNKNOWN ACUTE INHALATION
TOXICITY (GAS)
0% OF THE MIXTURE CONSISTS OF INGREDIENT(S) OF UNKNOWN ACUTE INHALATION
TOXICITY (DUST/MIST)
COMPONENT INFORMATION:
CHEMICAL NAME ORAL LD50 DERMAL LD50 INHALATION LC50
WATER 90 ML/KG (RAT)
7732-18-5
HYDROGEN FLUORIDE =0.79 MG/L (RAT) 1 H
7664-39-3
DELAYED AND IMMEDIATE EFFECTS AS WELL AS CHRONIC EFFECTS FROM SHORT AND
LONG-TERM EXPOSURE:
SKIN CORROSION/IRRITATION:
CLASSIFICATION BASED ON DATA AVAILABLE FOR INGREDIENTS. CAUSES BURNS.
SERIOUS EYE DAMAGE/EYE IRRITATION:
CLASSIFICATION BASED ON DATA AVAILABLE FOR INGREDIENTS. RISK OF SERIOUS
DAMAGE TO EYES. CAUSES BURNS.
RESPIRATORY OR SKIN SENSITIZATION: NO INFORMATION AVAILABLE.
GERM CELL MUTAGENICITY: NO INFORMATION AVAILABLE.
REPRODUCTIVE TOXICITY: NO INFORMATION AVAILABLE.
STOT - SINGLE EXPOSURE: NO INFORMATION AVAILABLE.
STOT - REPEATED EXPOSURE:
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
TARGET ORGAN EFFECTS: RESPIRATORY SYSTEM, EYES, SKIN.
ASPIRATION HAZARD: NO INFORMATION AVAILABLE.
OTHER ADVERSE EFFECTS: NO INFORMATION AVAILABLE.
INTERACTIVE EFFECTS: NO INFORMATION AVAILABLE.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
CHEMICAL NAME ALGAE/AQUATIC FISH TOXICITY TO CRUSTACEA
PLANTS MICROORGANISMS
HYDROGEN LC50: EC50:
FLUORIDE =660 MG/L =270 MG/L
7664-39-3 (48H, (48H,
LEUCISCUS DAPHNIA
IDUS) SPECIES)
PERSISTENCE AND DEGRADABILITY: NO INFORMATION AVAILABLE.
BIOACCUMULATION: INHERENTLY BIODEGRADABLE.
COMPONENT INFORMATION:
CHEMICAL NAME PARTITION COEFFICIENT
HYDROGEN FLUORIDE -1.4
7664-39-3
OTHER ADVERSE EFFECTS: NO INFORMATION AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
WASTE TREATMENT METHODS:
WASTE FROM RESIDUES/UNUSED PRODUCTS:
DISPOSE OF IN ACCORDANCE WITH LOCAL REGULATIONS. DISPOSE OF WASTE IN
ACCORDANCE WITH ENVIRONMENTAL LEGISLATION.
CONTAMINATED PACKAGING: DO NOT REUSE EMPTY CONTAINERS.
| 14. TRANSPORT INFORMATION | |
DOT:
UN/ID NO: UN1790
PROPER SHIPPING NAME: HYDROFLUORIC ACID SOLUTION
HAZARD CLASS: 8
SUBSIDIARY CLASS: 6.1
PACKING GROUP: II
SPECIAL PROVISIONS: A7, B15, IB2, N5, N34, T8, TP2,
MARINE POLLUTANT: SEVERE MARINE POLLUTANT
DESCRIPTION: UN1790, HYDROFLUORIC ACID SOLUTION, 8 (6.1), II
EMERGENCY RESPONSE GUIDE NUMBER: 157
TDG:
UN-NO: UN1790
PROPER SHIPPING NAME: HYDROFLUORIC ACID SOLUTION
HAZARD CLASS: 8
SUBSIDIARY CLASS: 6.1
PACKING GROUP: II
DESCRIPTION: UN1790, HYDROFLUORIC ACID SOLUTION, 8 (6.1), II
MEX:
UN-NO: UN1790
PROPER SHIPPING NAME: HYDROFLUORIC ACID SOLUTION
HAZARD CLASS: 8
SUBSIDIARY CLASS: 6.1
PACKING GROUP: II
DESCRIPTION: UN1790, HYDROFLUORIC ACID SOLUTION, 8 (6.1), II
ICAO (AIR):
UN-NO: UN1790
PROPER SHIPPING NAME: HYDROFLUORIC ACID SOLUTION
HAZARD CLASS: 8
SUBSIDIARY HAZARD CLASS: 6.1
PACKING GROUP: II
DESCRIPTION: UN1790, HYDROFLUORIC ACID SOLUTION, 8 (6.1), II
IATA:
UN NUMBER: UN1790
PROPER SHIPPING NAME: HYDROFLUORIC ACID SOLUTION
TRANSPORT HAZARD CLASS(ES): 8
SUBSIDIARY HAZARD CLASS: 6.1
PACKING GROUP: II
DESCRIPTION: UN1790, HYDROFLUORIC ACID SOLUTION, 8 (6.1), II
IMDG:
UN NUMBER: UN1790
PROPER SHIPPING NAME: HYDROFLUORIC ACID SOLUTION
TRANSPORT HAZARD CLASS(ES): 8
SUBSIDIARY HAZARD CLASS: 6.1
PACKING GROUP: II
EMS-NO: F-A, S-B
MARINE POLLUTANT: NP1
DESCRIPTION: UN1790, HYDROFLUORIC ACID SOLUTION, 8 (6.1), II
RID:
UN NUMBER: UN1790
PROPER SHIPPING NAME: HYDROFLUORIC ACID SOLUTION
TRANSPORT HAZARD CLASS(ES): 8
PACKING GROUP: II
CLASSIFICATION CODE: CT1
DESCRIPTION: UN1790, HYDROFLUORIC ACID SOLUTION, 8 (6.1), II
LABELS: 8 + 6.1
ADR:
UN NUMBER: 1790
PROPER SHIPPING NAME: HYDROFLUORIC ACID SOLUTION
TRANSPORT HAZARD CLASS(ES): 8
SUBSIDIARY HAZARD CLASS: 6.1
PACKING GROUP: II
CLASSIFICATION CODE: CT1
TUNNEL RESTRICTION CODE: (E)
DESCRIPTION: 1790, HYDROFLUORIC ACID SOLUTION, 8 (6.1), II, (E)
LABELS: 8 + 6.1
ADN:
UN/ID NO: UN1790
PROPER SHIPPING NAME: HYDROFLUORIC ACID SOLUTION
TRANSPORT HAZARD CLASS(ES): 8
PACKING GROUP: II
CLASSIFICATION CODE: CT1
SPECIAL PROVISIONS: 802
DESCRIPTION: UN1790, HYDROFLUORIC ACID SOLUTION, 8 (+ 6.1), II
HAZARD LABEL(S): 8 + 6.1
LIMITED QUANTITY (LQ): 1 L
VENTILATION: VE02
EQUIPMENT REQUIREMENTS: PP, EP, TOX, A
| 15. REGULATORY INFORMATION | |
INTERNATIONAL INVENTORIES:
TSCA: COMPLIES
DSL/NDSL: COMPLIES
EINECS/ELINCS: COMPLIES
ENCS: THIS PRODUCT COMPLIES WITH ENCS
IECSC: THIS PRODUCT COMPLIES WITH CHINA
KECL: COMPLIES
PICCS: COMPLIES
AICS:
ALL THE CONSTITUENTS OF THIS MATERIAL ARE LISTED ON THE AUSTRALIAN
INVENTORY OF CHEMICAL SUBSTANCES (AICS).
LEGEND:
TSCA: UNITED STATES TOXIC SUBSTANCES CONTROL ACT SECTION 8(B) INVENTORY
DSL/NDSL: CANADIAN DOMESTIC SUBSTANCES LIST/NON-DOMESTIC SUBSTANCES LIST
EINECS/ELINCS:
EUROPEAN INVENTORY OF EXISTING CHEMICAL SUBSTANCES/EUROPEAN LIST OF
NOTIFIED CHEMICAL SUBSTANCES
ENCS: JAPAN EXISTING AND NEW CHEMICAL SUBSTANCES
IECSC: CHINA INVENTORY OF EXISTING CHEMICAL SUBSTANCES
KECL: KOREAN EXISTING AND EVALUATED CHEMICAL SUBSTANCES
PICCS: PHILIPPINES INVENTORY OF CHEMICALS AND CHEMICAL SUBSTANCES
US FEDERAL REGULATIONS:
SARA 313:
SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION
ACT OF 1986 (SARA). THIS PRODUCT CONTAINS A CHEMICAL OR CHEMICALS WHICH ARE
SUBJECT TO THE REPORTING REQUIREMENTS OF THE ACT AND TITLE 40 OF THE CODE
OF FEDERAL REGULATIONS, PART 372.
CHEMICAL NAME SARA 313 - THRESHOLD VALUES %
HYDROGEN FLUORIDE - 7664-39-3 1.0
SARA 311/312 HAZARD CATEGORIES:
SHOULD THIS PRODUCT MEET EPCRA 311/312 TIER REPORTING CRITERIA AT 40 CFR
370, REFER TO SECTION 2 OF THIS SDS FOR APPROPRIATE CLASSIFICATIONS.
CWA (CLEAN WATER ACT):
THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES WHICH ARE REGULATED
POLLUTANTS PURSUANT TO THE CLEAN WATER ACT (40 CFR 122.21 AND 40 CFR
122.42).
CHEMICAL NAME CWA - CWA - CWA - CWA -
REPORTABLE TOXIC PRIORITY HAZARDOUS
QUANTITIES POLLUTANTS POLLUTANTS SUBSTANCES
HYDROGEN FLUORIDE PRESENT
7664-39-3
CERCLA:
THIS MATERIAL, AS SUPPLIED, CONTAINS ONE OR MORE SUBSTANCES REGULATED AS
A HAZARDOUS SUBSTANCE UNDER THE COMPREHENSIVE ENVIRONMENTAL RESPONSE
COMPENSATION AND LIABILITY ACT (CERCLA) (40 CFR 302).
CHEMICAL NAME HAZARDOUS EXTREMELY HAZARDOUS
SUBSTANCES RQS SUBSTANCES RQS
HYDROGEN FLUORIDE 100 LB FINAL RQ
7664-39-3 45.4 KG FINAL RQ
US STATE REGULATIONS:
CALIFORNIA PROPOSITION 65:
THIS PRODUCT DOES NOT CONTAIN ANY PROPOSITION 65 CHEMICALS.
U.S. STATE RIGHT-TO-KNOW REGULATIONS:
THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES REGULATED UNDER APPLICABLE
STATE RIGHT-TO-KNOW REGULATIONS
U.S. EPA LABEL INFORMATION:
EPA PESTICIDE REGISTRATION NUMBER: NOT APPLICABLE
| 16. OTHER INFORMATION | |
NFPA:
HEALTH HAZARDS 4
FLAMMABILITY 0
INSTABILITY 0
PHYSICAL AND CHEMICAL PROPERTIES
HMIS:
HEALTH HAZARDS 4*
FLAMMABILITY 0
PHYSICAL HAZARDS 0
PERSONAL PROTECTION X
KEY OR LEGEND TO ABBREVIATIONS AND ACRONYMS USED IN THE SAFETY DATA SHEET:
LEGEND SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
TWA: TWA (TIME-WEIGHTED AVERAGE)
STEL: STEL (SHORT TERM EXPOSURE LIMIT)
CEILING: MAXIMUM LIMIT VALUE
KEY LITERATURE REFERENCES AND SOURCES FOR DATA USED TO COMPILE THE SDS:
AGENCY FOR TOXIC SUBSTANCES AND DISEASE REGISTRY (ATSDR)
U.S. ENVIRONMENTAL PROTECTION AGENCY CHEMVIEW DATABASE
EUROPEAN FOOD SAFETY AUTHORITY (EFSA)
EPA (ENVIRONMENTAL PROTECTION AGENCY)
ACUTE EXPOSURE GUIDELINE LEVEL(S) (AEGL(S))
U.S. ENVIRONMENTAL PROTECTION AGENCY FEDERAL INSECTICIDE, FUNGICIDE, AND
RODENTICIDE ACT
U.S. ENVIRONMENTAL PROTECTION AGENCY HIGH PRODUCTION VOLUME CHEMICALS
FOOD RESEARCH JOURNAL
HAZARDOUS SUBSTANCE DATABASE
INTERNATIONAL UNIFORM CHEMICAL INFORMATION DATABASE (IUCLID)
JAPAN GHS CLASSIFICATION
AUSTRALIA NATIONAL INDUSTRIAL CHEMICALS NOTIFICATION AND ASSESSMENT
SCHEME (NICNAS)
NIOSH (NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH)
NATIONAL LIBRARY OF MEDICINE'S CHEMID PLUS (NLM CIP)
NATIONAL LIBRARY OF MEDICINE'S PUBMED DATABASE (NLM PUBMED)
NATIONAL TOXICOLOGY PROGRAM (NTP)
NEW ZEALAND'S CHEMICAL CLASSIFICATION AND INFORMATION DATABASE (CCID)
ORGANIZATION FOR ECONOMIC CO-OPERATION AND DEVELOPMENT ENVIRONMENT,
HEALTH, AND SAFETY PUBLICATIONS
ORGANIZATION FOR ECONOMIC CO-OPERATION AND DEVELOPMENT HIGH PRODUCTION
VOLUME CHEMICALS PROGRAM
ORGANIZATION FOR ECONOMIC CO-OPERATION AND DEVELOPMENT SCREENING
INFORMATION DATA SET
WORLD HEALTH ORGANIZATION
REVISION DATE: 31-MARCH-2021
REVISION NOTE: NO INFORMATION AVAILABLE.
DISCLAIMER:
THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT TO THE BEST
OF OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS PUBLICATION.
THE INFORMATION GIVEN IS DESIGNED ONLY AS A GUIDANCE FOR SAFE HANDLING,
USE, PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE AND IS NOT
TO BE CONSIDERED A WARRANTY OR QUALITY SPECIFICATION. THE INFORMATION
RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR
SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY
PROCESS, UNLESS SPECIFIED IN THE TEXT.