| Common Name: | SODIUM HYDROXIDE, 1.00 N SOLUTION, APHA |
| Manufacturer: | SPECTRUM CHEMICALS & LABORATORY PRODUCTS |
| SDS Revision Date: | 11/18/2019 |
| SDS Format: | No Format Specified |
| Item Number(s): | 6PJR4 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SPECTRUM(R*)
S
ISO 9001-2015 REGISTERED
SAFETY DATA SHEET
PREPARATION DATE: 7/9/2014
REVISION DATE: 11/18/2019
REVISION NUMBER: G5
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER:
PRODUCT CODE: S-370
PRODUCT NAME: SODIUM HYDROXIDE, 1.00 N SOLUTION, APHA
OTHER MEANS OF IDENTIFICATION:
SYNONYMS: NO INFORMATION AVAILABLE
CAS #: MIXTURE
RTECS #: NOT AVAILABLE
CI#: NOT AVAILABLE
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE: NO INFORMATION AVAILABLE.
USES ADVISED AGAINST: NO INFORMATION AVAILABLE
SUPPLIER:
SPECTRUM CHEMICAL MFG. CORP
14422 SOUTH SAN PEDRO ST.
GARDENA, CA 90248
(310) 516-8000
ORDER ONLINE AT: HTTPS://WWW.SPECTRUMCHEMICAL.COM
EMERGENCY TELEPHONE NUMBER:
CHEMTREC: 1-800-424-9300
CONTACT PERSON: TOM TYNER (USA - WEST COAST)
CONTACT PERSON: IBAD TIRMIZ (USA - EAST COAST)
| 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION:
THIS CHEMICAL IS CONSIDERED HAZARDOUS BY THE 2012 OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200)
CONSIDERED A DANGEROUS SUBSTANCE OR MIXTURE ACCORDING TO THE GLOBALLY
HARMONIZED SYSTEM (GHS)
SKIN CORROSION/IRRITATION: CATEGORY 1 SUB-CATEGORY B
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 1
LABEL ELEMENTS:
DANGER:
HAZARD STATEMENTS: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE
CORROSION
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC): NOT APPLICABLE
OTHER HAZARDS: NOT AVAILABLE
PRECAUTIONARY STATEMENTS - PREVENTION:
DO NOT BREATHE MIST OR VAPORS
WASH FACE, HANDS AND ANY EXPOSED SKIN THOROUGHLY AFTER HANDLING
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION
PRECAUTIONARY STATEMENTS - RESPONSE:
IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN.
IF ON SKIN (OR HAIR):
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER
WASH CONTAMINATED CLOTHING BEFORE REUSE
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. IMMEDIATELY
CALL A POISON CENTER OR PHYSICIAN.
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING
PRECAUTIONARY STATEMENTS - STORAGE: STORE LOCKED UP
PRECAUTIONARY STATEMENTS - DISPOSAL:
DISPOSE OF CONTENTS AND CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT IN
ACCORDANCE WITH LOCAL, REGIONAL, NATIONAL AND INTERNATIONAL REGULATIONS
AS APPLICABLE
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
COMPONENT CAS NO WEIGHT-%
WATER 7732-18-5 96.16
SODIUM HYDROXIDE 1310-73-2 3.84
| 4. FIRST AID MEASURES | |
FIRST AID MEASURES:
GENERAL ADVICE:
NATIONAL CAPITAL POISON CENTER IN THE UNITED STATES CAN PROVIDE ASSISTANCE
IF YOU HAVE A POISON EMERGENCY AND NEED TO TALK TO A POISON SPECIALIST.
CALL 1-800-222-1222. ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE
MATERIAL(S) INVOLVED AND TAKE PRECAUTIONS TO PROTECT THEMSELVES. FIRST
AIDER NEEDS TO PROTECT HIMSELF.
SKIN CONTACT:
WASH OFF IMMEDIATELY WITH SOAP AND PLENTY OF WATER. CONTINUE FLUSHING
WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. REMOVE ALL CONTAMINATED
CLOTHES AND SHOES. IMMEDIATE MEDICAL ATTENTION IS REQUIRED. CALL A
PHYSICIAN IMMEDIATELY.
EYE CONTACT:
FLUSH EYES WITH WATER FOR 15 MINUTES. IMMEDIATE MEDICAL ATTENTION IS
REQUIRED. CALL A PHYSICIAN IMMEDIATELY.
INHALATION:
MOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION. WARNING! IT MAY BE HAZARDOUS TO
THE PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH RESUSCITATION WHEN THE
INHALED OR INGESTED MATERIAL IS TOXIC, INFECTIOUS OR CORROSIVE. DO NOT USE
MOUTH-TO-MOUTH RESUSCITATION IF VICTIM INGESTED OR INHALED THE SUBSTANCE;
INDUCE ARTIFICIAL RESPIRATION WITH THE AID OF A POCKET MASK EQUIPPED WITH
A ONE-WAY VALVE OR OTHER PROPER RESPIRATORY MEDICAL DEVICE. IMMEDIATE
MEDICAL ATTENTION IS REQUIRED. CALL A PHYSICIAN IMMEDIATELY.
INGESTION:
DO NOT INDUCE VOMITING WITHOUT MEDICAL ADVICE. NEVER GIVE ANYTHING BY
MOUTH TO AN UNCONSCIOUS PERSON. IF VICTIM IS CONSCIOUS, GIVE WATER OR
MILK. IMMEDIATE MEDICAL ATTENTION IS REQUIRED. CALL A PHYSICIAN OR POISON
CONTROL CENTER IMMEDIATELY.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS:
SEVERE SKIN AND EYE IRRITATION OR BURNS
CAUSES DIGESTIVE (GASTROINTESTINAL) TRACT IRRITATION
MAY CAUSE GASTROINTESTINAL (DIGESTIVE) TRACT BURNS
MAY CAUSE ABDOMINAL PAIN, NAUSEA, VOMITING, DIARRHEA
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY.
PROTECTION OF FIRST-AIDERS:
FIRST-AID PROVIDERS:
AVOID EXPOSURE TO BLOOD OR BODY FLUIDS. WEAR GLOVES AND OTHER NECESSARY
PROTECTIVE CLOTHING. DISPOSE OF CONTAMINATED CLOTHING AND EQUIPMENT AS
BIO-HAZARDOUS WASTE.
| 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
THE PRODUCT IS NOT FLAMMABLE. IF IT IS INVOLVED IN A FIRE, EXTINGUISH
THE FIRE USING AN AGENT SUITABLE FOR THE TYPE OF SURROUNDING FIRE.
UNSUITABLE EXTINGUISHING MEDIA: NO INFORMATION AVAILABLE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
HAZARDOUS COMBUSTION PRODUCTS: NO INFORMATION AVAILABLE.
SPECIFIC HAZARDS: NO INFORMATION AVAILABLE.
SPECIAL PROTECTIVE ACTIONS FOR FIREFIGHTERS:
SPECIFIC METHODS: NO INFORMATION AVAILABLE
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND,
MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
KEEP PEOPLE AWAY FROM AND UPWIND OF SPILL/LEAK. ENSURE ADEQUATE
VENTILATION. DO NOT TOUCH DAMAGED CONTAINERS OR SPILLED MATERIAL UNLESS
WEARING APPROPRIATE PROTECTIVE CLOTHING. USE PERSONAL PROTECTIVE
EQUIPMENT. AVOID CONTACT WITH SKIN, EYES AND CLOTHING.
ENVIRONMENTAL PRECAUTIONS:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO. SHOULD NOT BE
RELEASED INTO THE ENVIRONMENT. DO NOT LET PRODUCT ENTER DRAINS. DO NOT
FLUSH INTO SURFACE WATER OR SANITARY SEWER SYSTEM. PREVENT ENTRY INTO
WATERWAYS, SEWERS, BASEMENTS OR CONFINED AREAS.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CONTAINMENT:
STOP LEAK IF YOU CAN DO IT WITHOUT RISK. IN CASE OF LARGE SPILL, DIKE IF
NEEDED. DIKE FAR AHEAD OF LIQUID SPILL FOR LATER DISPOSAL.
METHODS FOR CLEANING UP:
NEUTRALIZE WITH A DILUTE SOLUTION OF ACETIC ACID. DILUTE WITH WATER.
ABSORB SPILL WITH INERT MATERIAL (E.G. VERMICULITE, DRY SAND OR EARTH),
THEN PLACE IN A SUITABLE CHEMICAL WASTE CONTAINER. CLEAN CONTAMINATED
SURFACE THOROUGHLY.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
TECHNICAL MEASURES/PRECAUTIONS:
USE ONLY IN AREA PROVIDED WITH APPROPRIATE EXHAUST VENTILATION. KEEP AWAY
FROM INCOMPATIBLE MATERIALS.
SAFE HANDLING ADVICE:
WEAR PERSONAL PROTECTIVE EQUIPMENT. AVOID CONTACT WITH SKIN, EYES AND
CLOTHING. DO NOT INGEST. DO NOT BREATHE VAPORS OR SPRAY MIST. HANDLE IN
ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
TECHNICAL MEASURES/STORAGE CONDITIONS:
KEEP CONTAINER TIGHTLY CLOSED IN A DRY AND WELL-VENTILATED PLACE. STORE
AT ROOM TEMPERATURE IN THE ORIGINAL CONTAINER. STORE IN A SEGREGATED AND
APPROVED AREA. STORE AWAY FROM INCOMPATIBLE MATERIALS.
INCOMPATIBLE MATERIALS:
OXIDIZING AGENTS
REDUCING AGENTS
ACIDS
BASES
ALDEHYDES
METALS
POWDERED METALS
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
NATIONAL OCCUPATIONAL EXPOSURE LIMITS:
UNITED STATES:
COMPONENT CAS NO OSHA NIOSH ACGIH AIHA WEEL
WATER 7732-18-5 NONE NONE NONE NONE
SODIUM HYDROXIDE 1310-73-2 2 MG/M3 2 MG/M3 2 MG/M3 NONE
TWA CEILING CEILING
CANADA:
COMPONENT CAS NO CANADA - CANADA - CANADA - CANADA -
ALBERTA BRITISH ONTARIO QUEBEC
COLUMBIA
WATER 7732-18-5 NONE NONE NONE NONE
SODIUM HYDROXIDE 1310-73-2 2 MG/M3 2 MG/M3 2 MG/M3 2 MG/M3
CEILING CEILING CEILING CEILING
AUSTRALIA AND MEXICO:
COMPONENT CAS NO AUSTRALIA MEXICO
WATER 7732-18-5 NONE NONE
SODIUM HYDROXIDE 1310-73-2 NONE 2 MG/M3 CEILING
APPROPRIATE ENGINEERING CONTROLS:
ENGINEERING MEASURES TO REDUCE EXPOSURE:
ENSURE ADEQUATE VENTILATION. PROVIDE EXHAUST VENTILATION OR OTHER
ENGINEERING CONTROLS TO KEEP THE AIRBORNE CONCENTRATIONS OF VAPORS AND
MIST BELOW THEIR RESPECTIVE THRESHOLD LIMIT VALUE.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
PERSONAL PROTECTIVE EQUIPMENT:
EYE PROTECTION: FACE-SHIELD.
SKIN AND BODY PROTECTION:
CHEMICAL RESISTANT PROTECTIVE SUIT
GLOVES
BOOTS
RESPIRATORY PROTECTION:
VAPOR RESPIRATOR. BE SURE TO USE AN APPROVED/CERTIFIED RESPIRATOR OR
EQUIVALENT.
HYGIENE MEASURES:
AVOID CONTACT WITH SKIN, EYES AND CLOTHING. WHEN USING, DO NOT EAT, DRINK
OR SMOKE. WASH HANDS BEFORE BREAKS AND IMMEDIATELY AFTER HANDLING THE
PRODUCT
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
APPEARANCE: NO INFORMATION AVAILABLE.
COLOR: CLEAR. COLORLESS.
ODOR: ODORLESS.
TASTE: NO INFORMATION AVAILABLE.
FORMULA: NO INFORMATION AVAILABLE
MOLECULAR/FORMULA WEIGHT (G/MOLE): NO INFORMATION AVAILABLE
FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
FLASHPOINT (DEG. C/DEG. F): NO INFORMATION AVAILABLE
FLASH POINT TESTED ACCORDING TO: NOT AVAILABLE
AUTOIGNITION TEMPERATURE (DEG. C/DEG. F): NO INFORMATION AVAILABLE
LOWER EXPLOSION LIMIT (%): NO INFORMATION AVAILABLE
UPPER EXPLOSION LIMIT (%): NO INFORMATION AVAILABLE
MELTING POINT/RANGE (DEG. C/DEG. F): NO INFORMATION AVAILABLE
DECOMPOSITION TEMPERATURE (DEG. C/DEG. F): NO INFORMATION AVAILABLE
BOILING POINT/RANGE (DEG. C/DEG. F): NO INFORMATION AVAILABLE
BULK DENSITY: NO INFORMATION AVAILABLE
DENSITY (G/CM3): NO INFORMATION AVAILABLE
SPECIFIC GRAVITY: 1.04
PH: NO INFORMATION AVAILABLE
VAPOR PRESSURE @ 20 DEG. C (KPA): NO INFORMATION AVAILABLE
EVAPORATION RATE: NO INFORMATION AVAILABLE
VAPOR DENSITY: NO INFORMATION AVAILABLE
VOC CONTENT (G/L): NO INFORMATION AVAILABLE
ODOR THRESHOLD (PPM): NO INFORMATION AVAILABLE
PARTITION COEFFICIENT (N-OCTANOL/WATER): NO INFORMATION AVAILABLE
VISCOSITY: NO INFORMATION AVAILABLE
MISCIBILITY: NO INFORMATION AVAILABLE
SOLUBILITY: FREELY SOLUBLE IN WATER
| 10. STABILITY AND REACTIVITY | |
REACTIVITY:
FOR SODIUM HYDROXIDE:
SODIUM HYDROXIDE + ZINC METAL DUST CAUSES IGNITION OF THE LATTER.
UNDER PROPER CONDITIONS OF TEMPERATURE, PRESSURE AND STATE OF DIVISION,
IT CAN IGNITE OR REACT VIOLENTLY WITH ACETALDEHYDE, ALLY ALCOHOL, ALLYL
CHLORIDE, BENZENE-1,4-DIOL, CHLORINE TRIFLUORIDE, 1,2 DICHLORETHYLENE,
NITROETHANE, NITROMETHANE, NITROPARAFFINS, NITROPROPANE, CINNAMALDEHYDE,
2,2-DICHLORO-3,3-DIMETHYLBUTANE.
PHOSPHOROUS BOILED WITH NAOH YIELDS MIXED PHOSPHINES WHICH MAY IGNITE
SPONTANEOUSLY IN AIR.
SODIUM HYDROXIDE AND CINNAMALDEHYDE + HEAT MAY CAUSE IGNITION.
REACTION WITH CERTAIN METALS RELEASES FLAMMABLE AND EXPLOSIVE HYDROGEN GAS.
GENERATES CONSIDERABLE HEAT WHEN A SODIUM HYDROXIDE SOLUTION IS MIXED WITH
AN ACID.SODIUM HYDROXIDE SOLUTION AND OCTANOL + DIBORANE DURING A WORK-UP
OF A REACTION MIXTURE OF OXIME AND DIBORANE IN TETRAHYROFURAN IS VERY
EXOTHERMIC, A MILD EXPLOSION BEING NOTED ON ONE OCCASSION.REACTIVE WITH
WATER, ACIDS (MINERAL, NON-OXIDIZING, E.G. HYDROCHLORIC, HYDROFLUORIC ACID,
MURIATIC ACID, PHOSPHORIC), ACIDS (MINERAL, OXIDIZING E.G. CHROMIC ACID,
HYPOCHLOROUS ACID, NITRIC ACID, SULFURIC ACID), ACIDS (ORGANIC E.G. ACETIC
ACID, BENZOIC ACID, FORMIC ACID, METHANOIC ACID, OXALIC ACID), ALDEHYDES
(E.G. ACETALDEHYDE, ACROLEIN, CHLORAL HYDRATE, FORMALDEHYDE), CARBAMATES
(E.G. CARBANOLATE, CARBOFURAN), ESTERS (E.G. BUTYL ACETATE, ETHYL ACETATE,
PROPYL FORMATE), HALOGENATED ORGANICS (DIBROMOETHANE, HEXACHLOROBENZENE,
METHYL CHLORIDE, TRICHLOROETHYLENE), ISOCYANATES (E.G. METHYL ISOCYANATE),
KETONES (ACETONE, ACETOPHENONE, MEK, MIBK), ACID CHLORIDES, STRONG BASES,
STRONG OXIDIZING AGENTS, STRONG REDUCING AGENTS, FLAMMABLE LIQUIDS,
POWDERED METALS AND METALS (I.E ALUMINUM, TIN, ZINC, HAFNIUM, RANEY
NICKEL), METALS (ALKALI AND ALKALINE E.G. CESIUM, POTASSIUM, SODIUM),
METAL COMPOUNDS (TOXIC E.G. BERYLIUM, LEAD ACETATE, NICKEL CARBONYL,
TETRAETHYL LEAD), NITRIDES (E.G. POTASSIUM NITRIDE, SODIUM NITRIDE),
NITRILES (E.G. ACETONITRILE, METHYL CYANIDE), NITRO COMPOUNDS (ORGANIC E.G.
NITROBENZENE, NITROMETHANE), ACETIC ANHYDRIDE, HYDROQUINONE, CHLOROHYDRIN,
CHLOROSULFONIC ACID, ETHYLENE CYANOHYDRIN, GLYOXAL, HYDROSULFURIC ACID,
OLEUM, PROPIOLACTONE, ACYLONITRILE, PHOROSOUS PENTOXIDE, CHLOROETHANOL,
CHLOROFORM-METHANOL, TETRAHYDROBORATE, CYANOGEN AZIDE, 1,2,4,5
TETRACHLOROBENZENE, CINNAMALDEHYDE.REACTS WITH FORMALDEHYDE HYDROXIDE
TO YIELD FORMIC ACID, AND HYDROGEN.
SODIUM HYDROXIDE REACTS TO FORM EXPLOSIVE PRODUCTS WITH AMMONIA + SILVER
NITRATE.BENZENE EXTRACT OF ALLYL BENZENESULFONATE PREPARED FROM ALLYL
ALCOHOL, AND BENZENE SULFONYL CHLORIDE IN PRESENCE OF AQUEOUS SODIUM
HYDROXIDE, UNDER VACUUM DISTILLATION, RESIDUE DARKENED AND EXPLODED. SODIUM
HYDROXDE + IMPURE TETRAHYDROFURAN, WHICH CAN CONTAIN PEROXIDES, CAN CAUSE
SERIOUS EXPLOSIONS. SODIUM HYDROXIDE REACTS WITH SODIUM SALT OF
TRICHLOROPHENOL + METHYL ALCOHOL + TRICHLOROBENZENE + HEAT TO CAUSE AN
EXPLOSION.
CHEMICAL STABILITY:
STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS: HAZARDOUS POLYMERIZATION DOES NOT OCCUR
CONDITIONS TO AVOID: INCOMPATIBLE MATERIALS.
INCOMPATIBLE MATERIALS:
OXIDIZING AGENTS
REDUCING AGENTS
ACIDS
BASES
ALDEHYDES
METALS
POWDERED METALS
HAZARDOUS DECOMPOSITION PRODUCTS: NO INFORMATION AVAILABLE.
OTHER INFORMATION:
CORROSIVITY: NO INFORMATION AVAILABLE
SPECIAL REMARKS ON CORROSIVITY:
VERY CAUSTIC TO ALUMINUM AND OTHER METALS IN THE PRESENCE OF MOISTURE
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
PRINCIPAL ROUTES OF EXPOSURE: SKIN. INHALATION. INGESTION.
ACUTE TOXICITY:
THE FOLLOWING VALUES ARE CALCULATED BASED ON CHAPTER 3.1 OF THE GHS
DOCUMENT:
ATEMIX (DERMAL): 35162 MG/KG
COMPONENT INFORMATION:
WATER:
CAS NO: 7732-18-5
LD50/ORAL/RAT: >90 ML/KG ORAL LD50 RAT
LD50/ORAL/MOUSE: NO INFORMATION AVAILABLE
LD50/DERMAL/RABBIT: NO INFORMATION AVAILABLE
LD50/DERMAL/RAT: NO INFORMATION AVAILABLE
LC50/INHALATION/RAT: NO INFORMATION AVAILABLE
LC50/INHALATION/MOUSE: NO INFORMATION AVAILABLE
OTHER LD50 OR LC50 INFORMATION: NO INFORMATION AVAILABLE
SODIUM HYDROXIDE:
CAS NO: 1310-73-2
LD50/ORAL/RAT: 325 MG/KG ORAL LD50 RAT; 140-340 MG/KG
LD50/ORAL/MOUSE: NO INFORMATION AVAILABLE
LD50/DERMAL/RABBIT: 1350 MG/KG DERMAL LD50 RABBIT
LD50/DERMAL/RAT: NO INFORMATION AVAILABLE
LC50/INHALATION/RAT: NO INFORMATION AVAILABLE
LC50/INHALATION/MOUSE: NO INFORMATION AVAILABLE
OTHER LD50 OR LC50 INFORMATION:
500 MG/KG ORAL LDL(LOWEST LETHAL DOSE) RABBIT
PRODUCT INFORMATION:
LD50/ORAL/RAT:
VALUE - ACUTE TOXICITY: NO INFORMATION AVAILABLE
LD50/ORAL/MOUSE:
VALUE - ACUTE TOX: NO INFORMATION AVAILABLE
LD50/DERMAL/RABBIT:
VALUE - ACUTE TOXICITY: NO INFORMATION AVAILABLE
LD50/DERMAL/RAT:
VALUE - ACUTE TOX: NO INFORMATION AVAILABLE
LC50/INHALATION/RAT:
VALUE-VAPOR: NO INFORMATION AVAILABLE
VALUE-GAS: NO INFORMATION AVAILABLE
VALUE-DUST/MIST: NO INFORMATION AVAILABLE
LC50/INHALATION/MOUSE:
VALUE - VAPOR: NO INFORMATION AVAILABLE
VALUE - GAS: NO INFORMATION AVAILABLE
VALUE - DUST/MIST: NO INFORMATION AVAILABLE
SYMPTOMS:
SKIN CONTACT:
SEVERE SKIN IRRITATION. CAUSES SKIN BURNS. MAY CAUSE DEEP PENETRATING
ULCERS OF THE SKIN.
EYE CONTACT:
SEVERE EYE IRRITATION. CAUSES EYE BURNS. MAY CAUSE CORNEAL DAMAGE.
INHALATION:
SEVERELY IRRITATING TO THE UPPER RESPIRATORY TRACT. MAY CAUSE CHEMICAL
BURNS TO THE RESPIRATORY TRACT. IT MAY CAUSE PULMONARY EDEMA. MAY CAUSE
CHEMICAL PNEUMONITIS.
INGESTION:
CAUSES SEVERE GASTROINTESTINAL TRACT IRRITATION AND BURNS. CAUSES SEVERE
PAIN, NAUSEA, VOMITING, DIARRHEA, AND SHOCK. MAY CAUSE SEVERE AND
PERMANENT DAMAGE TO THE DIGESTIVE TRACT. MAY CAUSE PERFORATION OF THE
DIGESTIVE TRACT. MAY CAUSE CORROSION AND PERMANENT DESTRUCTION OF THE
ESOPHAGUS.
ASPIRATION HAZARD: NO INFORMATION AVAILABLE.
DELAYED AND IMMEDIATE EFFECTS AS WELL AS CHRONIC EFFECTS FROM SHORT
AND LONG-TERM EXPOSURE:
CHRONIC TOXICITY: NO INFORMATION AVAILABLE.
SENSITIZATION: NO INFORMATION AVAILABLE.
MUTAGENIC EFFECTS: NO INFORMATION AVAILABLE
CARCINOGENIC EFFECTS: NOT CONSIDERED CARCINOGENIC.
COMPONENT CAS NO IARC ACGIH - NTP
CARCINOGENS
WATER 7732-18-5 NOT LISTED NOT LISTED NOT LISTED
SODIUM HYDROXIDE 1310-73-2 NOT LISTED NOT LISTED NOT LISTED
COMPONENT OSHA HCS - AUSTRALIA - AUSTRALIA -
CARCINOGENS NOTIFIABLE PROHIBITED
CARCINOGENIC CARCINOGENIC
SUBSTANCES SUBSTANCES
WATER NOT LISTED NOT LISTED NOT LISTED
SODIUM HYDROXIDE NOT LISTED NOT LISTED NOT LISTED
ACGIH (AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS)
IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER)
NTP (NATIONAL TOXICOLOGY PROGRAM)
OSHA (OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION OF THE US DEPARTMENT
OF LABOR)
REPRODUCTIVE TOXICITY: NO DATA IS AVAILABLE
REPRODUCTIVE EFFECTS: NO INFORMATION AVAILABLE
DEVELOPMENTAL EFFECTS: NO INFORMATION AVAILABLE
TERATOGENIC EFFECTS: NO INFORMATION AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY:
STOT - SINGLE EXPOSURE: NO INFORMATION AVAILABLE.
STOT - REPEATED EXPOSURE: NO INFORMATION AVAILABLE.
TARGET ORGANS: SKIN. EYES. RESPIRATORY SYSTEM.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
ECOTOXICITY EFFECTS: AQUATIC ENVIRONMENT.
SODIUM HYDROXIDE - 1310-73-2:
FISH:
LC50: =45.4 MG/L (96H, ONCORHYNCHUS MYKISS)
CRUSTACEA: 40.4 MG/L EC50 CERIODAPHNIA SP. 48H
PERSISTENCE AND DEGRADABILITY: NO INFORMATION AVAILABLE
BIOACCUMULATIVE POTENTIAL: NO INFORMATION AVAILABLE.
MOBILITY IN SOIL: NO INFORMATION AVAILABLE
OTHER ADVERSE EFFECTS: NO INFORMATION AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
WASTE FROM RESIDUES / UNUSED PRODUCTS:
WASTE MUST BE DISPOSED OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL
REGULATION.
CONTAMINATED PACKAGING:
EMPTY CONTAINERS SHOULD BE TAKEN FOR LOCAL RECYCLING, RECOVERY OR WASTE
DISPOSAL
COMPONENT CAS NO RCRA - F RCRA - K RCRA - P RCRA - U
SERIES SERIES SERIES SERIES
WASTES WASTES WASTES WASTES
WATER 7732-18-5 NONE NONE NONE NONE
SODIUM HYDROXIDE 1310-73-2 NONE NONE NONE NONE
| 14. TRANSPORT INFORMATION | |
DOT:
UN-NO: UN1824
PROPER SHIPPING NAME: SODIUM HYDROXIDE SOLUTION
HAZARD CLASS: 8
SUBSIDIARY CLASS: NO INFORMATION AVAILABLE
PACKING GROUP: II
EMERGENCY RESPONSE GUIDE NUMBER: NO INFORMATION AVAILABLE
MARINE POLLUTANT: NO DATA AVAILABLE
DOT RQ (LBS): NO INFORMATION AVAILABLE
SPECIAL PROVISIONS: NO INFORMATION AVAILABLE
SYMBOL(S):
[DOT]:
(R4) - IDENTIFIES A MATERIAL THAT IS A HAZARDOUS SUBSTANCE THAT HAS A
REPORTABLE QUANTITY (RQ) OF 1000 POUNDS (454 KILOGRAMS).
DESCRIPTION: UN1824, SODIUM HYDROXIDE SOLUTION, 8,, PG II
TDG (CANADA):
UN-NO: UN1824
PROPER SHIPPING NAME: SODIUM HYDROXIDE SOLUTION
HAZARD CLASS: 8
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: II
MARINE POLLUTANT: NO INFORMATION AVAILABLE
DESCRIPTION: SODIUM HYDROXIDE SOLUTION, 8, UN1824, PG II
ADR:
UN NUMBER: UN1824
PROPER SHIPPING NAME: SODIUM HYDROXIDE SOLUTION
TRANSPORT HAZARD CLASS(ES): 8
PACKING GROUP: II
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
DESCRIPTION: UN1824 SODIUM HYDROXIDE SOLUTION, 8, II
IMDG:
UN-NO: UN1824
PROPER SHIPPING NAME: SODIUM HYDROXIDE SOLUTION
HAZARD CLASS: 8
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: II
MARINE POLLUTANT: NO INFORMATION AVAILABLE
EMS: F-A
RID:
UN NUMBER: UN1824
PROPER SHIPPING NAME: SODIUM HYDROXIDE SOLUTION
TRANSPORT HAZARD CLASS(ES): 8
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: II
DESCRIPTION: UN1824 SODIUM HYDROXIDE SOLUTION, 8, II, RID
ICAO (AIR):
UN-NO: UN1824
PROPER SHIPPING NAME: SODIUM HYDROXIDE SOLUTION
HAZARD CLASS: 8
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: II
DESCRIPTION: SODIUM HYDROXIDE SOLUTION, 8, UN1824, PG II
IATA:
UN NUMBER: UN1824
PROPER SHIPPING NAME: SODIUM HYDROXIDE SOLUTION
TRANSPORT HAZARD CLASS(ES): 8
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: II
PRECAUTIONARY STATEMENTS - RESPONSE: 8L
SPECIAL PROVISIONS: NO INFORMATION AVAILABLE
DESCRIPTION: UN1824, SODIUM HYDROXIDE SOLUTION, 8, PG II
| 15. REGULATORY INFORMATION | |
INTERNATIONAL INVENTORIES:
COMPONENTS CAS-NO. U.S. TSCA KOREA KECL PHILIPPINES
(PICCS)
WATER 7732-18-5 PRESENT PRESENT PRESENT
ACTIVE KE-35400
SODIUM HYDROXIDE 1310-73-2 PRESENT PRESENT PRESENT
(ACTIVE) KE-31487
COMPONENT JAPAN ENCS CHINA IECSC AUSTRALIA (AICS) EINECS-NO.
WATER NOT PRESENT PRESENT PRESENT PRESENT
231-791-2
SODIUM HYDROXIDE PRESENT PRESENT PRESENT PRESENT
(1)-410 215-185-5
U.S. REGULATIONS:
SODIUM HYDROXIDE:
MASSACHUSETTS RTK: PRESENT
NEW JERSEY RTK HAZARDOUS SUBSTANCE LIST: 1706
NEW JERSEY - DISCHARGE PREVENTION - LIST OF HAZARDOUS SUBSTANCES: PRESENT
PENNSYLVANIA RTK: ENVIRONMENTAL HAZARD
PENNSYLVANIA RTK - ENVIRONMENTAL HAZARD LIST: PRESENT
MINNESOTA - HAZARDOUS SUBSTANCE LIST: PRESENT
NEW YORK RELEASE REPORTING - LIST OF HAZARDOUS SUBSTANCES:
1000 LB RQ
100 LB RQ
LOUISANA REPORTABLE QUANTITY LIST FOR POLLUTANTS:
1000 LB FINAL RQ
454 KG FINAL RQ
CALIFORNIA DIRECTORS LIST OF HAZARDOUS SUBSTANCES: PRESENT
FDA - FOOD ADDITIVES GENERALLY RECOGNIZED AS SAFE (GRAS): 21 CFR 184.1763
FDA - DIRECT FOOD ADDITIVES: 21 CFR 173.310
FDA - 21 CFR - TOTAL FOOD ADDITIVES - LIST SOURCED FROM EAFUS:
155.191, 155.194, 163.110, 163.111, 163.112, 172.560, 172.814, 172.892,
173.310, 176.170, 176.180, 176.210, 177.1600, 177.2800, 184.1763, 73.85
CALIFORNIA PROP. 65: SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986.
CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER:
THIS PRODUCT DOES NOT CONTAIN A CHEMICAL REQUIRING A WARNING UNDER
CALIFORNIA PROP. 65. (SEE TABLE BELOW)
CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE REPRODUCTIVE TOXICITY:
THIS PRODUCT DOES NOT CONTAIN A CHEMICAL REQUIRING A WARNING UNDER
CALIFORNIA PROP. 65. (SEE TABLE BELOW)
COMPONENT CAS NO
WATER 7732-18-5
SODIUM HYDROXIDE 1310-73-2
COMPONENT CARCINOGEN DEVELOPMENTAL MALE FEMALE
TOXICITY REPRODUCTIVE REPRODUCTIVE
TOXICITY TOXICITY
WATER NOT LISTED NOT LISTED NOT LISTED NOT LISTED
SODIUM HYDROXIDE NOT LISTED NOT LISTED NOT LISTED NOT LISTED
CERCLA/SARA:
COMPONENT CAS NO CERCLA - SECTION 302 SECTION 302
HAZARDOUS EXTREMELY EXTREMELY
SUBSTANCES HAZARDOUS HAZARDOUS
AND THEIR SUBSTANCES SUBSTANCES
REPORTABLE AND TPQS AND RQS
QUANTITIES
WATER 7732-18-5 NONE NONE NONE
SODIUM HYDROXIDE 1310-73-2 1000 LB FINAL RQ NONE NONE
454 KG FINAL RQ
COMPONENT SECTION 313 - CHEMICAL SECTION 313 - REPORTING
CATEGORY DE MINIMIS
WATER NONE NONE
SODIUM HYDROXIDE NONE NONE
U.S. TSCA:
COMPONENT CAS NO TSCA SECTION TSCA 8(D) - HEALTH
5(A)2 - CHEMICALS AND SAFETY REPORTING
WITH SIGNIFICANT NEW
USE RULES (SNURS)
WATER 7732-18-5 NOT APPLICABLE NOT APPLICABLE
SODIUM HYDROXIDE 1310-73-2 NOT APPLICABLE NOT APPLICABLE
CANADA:
WHIMIS 2015 - GHS CLASSIFICATIONS:
WHMIS 2015 HAZARD CLASSIFICATION INFORMATION: CORROSIVE.
COMPONENT WHMIS 2015 HAZARD CLASSIFICATION
WATER NOT A DANGEROUS PRODUCT ACCORDING TO HPR
7732-18-5 (96.16) CLASSIFICATION CRITERIA
SODIUM HYDROXIDE CORROSIVE TO METALS - CATEGORY 1:
1310-73-2 (3.84) H290:
MAY BE CORROSIVE TO METALS. (POTENTIALLY CORROSIVE
TO METALS; THE SUPPLIER SHOULD BE CONTACTED FOR MORE
INFORMATION)
HEALTH HAZARD NOT OTHERWISE CLASSIFIED - CATEGORY 1:
CAUSES SEVERE DAMAGE TO THE RESPIRATORY TRACT
(73% IN AQUEOUS SOLUTION)
SKIN CORROSION/IRRITATION -CATEGORY 1:
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
SKIN CORROSION/IRRITATION - CATEGORY 2:
H315:
CAUSES SKIN IRRITATION. (0.4% IN AQUEOUS SOLUTION)
SERIOUS EYE DAMAGE/EYE IRRITATION - CATEGORY 1:
H318: CAUSES SERIOUS EYE DAMAGE.
SERIOUS EYE DAMAGE/EYE IRRITATION - CATEGORY 2:
H319:
CAUSES SERIOUS EYE IRRITATION. (0.4% IN AQUEOUS
SOLUTION)
SPECIFIC TARGET ORGAN TOXICITY - SINGLE
EXPOSURE - CATEGORY 3:
H335:
MAY CAUSE RESPIRATORY IRRITATION. (0.4% IN AQUEOUS
SOLUTION)
CANADA HAZARDOUS PRODUCTS REGULATION:
THIS PRODUCT HAS BEEN CLASSIFIED ACCORDING TO THE HAZARD CRITERIA OF THE
HPR (HAZARDOUS PRODUCTS REGULATION) AND THE SDS CONTAINS ALL OF THE
INFORMATION REQUIRED BY THE HPR
DSL/NDSL:
COMPONENT CAS NO CANADA (DSL) CANADA (NDSL)
WATER 7732-18-5 PRESENT NOT LISTED
SODIUM HYDROXIDE 1310-73-2 PRESENT NOT LISTED
COMPONENT CAS NO CEPA SCHEDULE I - TOXIC SUBSTANCES
WATER 7732-18-5 NOT LISTED
SODIUM HYDROXIDE 1310-73-2 NOT LISTED
COMPONENT CAS NO CEPA - 2010 GREENHOUSE GASES SUBJECT
TO MANDATORY REPORTING
WATER 7732-18-5 NOT LISTED
SODIUM HYDROXIDE 1310-73-2 NOT LISTED
EU CLASSIFICATION:
EU GHS - SV - CLP 1272/2008:
COMPONENT CAS NO EU GHS - SV - CLP (1272/2008)
WATER 7732-18-5
SODIUM HYDROXIDE 1310-73-2 SKIN CORROSION/IRRITATION - SKIN
CORR. 1A:
H314:
CAUSES SEVERE SKIN BURNS AND EYE
DAMAGE. 011-002-00-6
SKIN CORROSION/IRRITATION - SKIN
CORR. 1A:
H314:
CAUSES SEVERE SKIN BURNS AND EYE
DAMAGE. (C >=5%)
SKIN CORROSION/IRRITATION - SKIN
CORR. 1B:
H314:
CAUSES SEVERE SKIN BURNS AND EYE
DAMAGE. (2% <=C <5%)
SKIN CORROSION/IRRITATION - SKIN
IRRIT. 2:
H315:
CAUSES SKIN IRRITATION.
(0.5% <=C <2%)
SERIOUS EYE DAMAGE/EYE
IRRITATION - EYE IRRIT. 2:
H319:
CAUSES SERIOUS EYE IRRITATION.
(0.5% <=C <2%)
EU - CLP (1272/2008):
R-PHRASE(S):
R34: CAUSES BURNS
S-PHRASE(S):
S26:
IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF WATER AND
SEEK MEDICAL ADVICE
S45:
IN CASE OF ACCIDENT OR IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE IMMEDIATELY
(SHOW THE LABEL WHERE POSSIBLE)
S 1/2: KEEP LOCKED UP AND OUT OF THE REACH OF CHILDREN.
S37/39: WEAR SUITABLE GLOVES AND EYE/FACE PROTECTION
COMPONENT CAS NO CLASSIFICATION CONCENTRATION SAFETY PHRASES
LIMITS
WATER 7732-18-5 NO INFORMATION
SODIUM 1310-73-2 C; R35 5%<=C C; R35 S1/2 S26
HYDROXIDE 2%<=C<5% C; R34 S37/39 S45
0.5%<=C<2% XI;
R36/38
THE PRODUCT IS CLASSIFIED IN ACCORDANCE WITH ANNEX VI TO DIRECTIVE
67/548/EEC:
INDICATION OF DANGER:
C: CORROSIVE
| 16. OTHER INFORMATION | |
PREPARATION DATE: 7/9/2014
REVISION DATE 11/18/2019
PREPARED BY: SONIA OWEN
DISCLAIMER:
ALL CHEMICALS MAY POSE UNKNOWN HAZARDS AND SHOULD BE USED WITH CAUTION.
THIS SAFETY DATA SHEET (SDS) APPLIES ONLY TO THE MATERIAL AS PACKAGED. IF
THIS PRODUCT IS COMBINED WITH OTHER MATERIALS, DETERIORATES, OR BECOMES
CONTAMINATED, IT MAY POSE HAZARDS NOT MENTIONED IN THIS SDS. THE PHYSICAL
PROPERTIES REPORTED IN THIS SDS ARE OBTAINED FROM THE LITERATURE AND DO
NOT CONSTITUTE PRODUCT SPECIFICATIONS. INFORMATION CONTAINED HEREIN DOES
NOT CONSTITUTE A WARRANTY, WHETHER EXPRESSED OR IMPLIED, AS TO THE SAFETY,
MERCHANTABILITY OR FITNESS OF THE GOODS FOR A PARTICULAR PURPOSE.
SPECTRUM CHEMICALS & LABORATORY PRODUCTS, INC. ASSUMES NO RESPONSIBILITY
FOR RESULTS OBTAINED OR FOR INCIDENTAL OR CONSEQUENTIAL DAMAGES, INCLUDING
LOST PROFITS, ARISING FROM THE USE OF THESE DATA. NO WARRANTY AGAINST
INFRINGEMENT OF ANY PATENT, COPYRIGHT OR TRADEMARK IS MADE OR IMPLIED. IT
SHALL BE THE USER'S RESPONSIBILITY TO DEVELOP PROPER METHODS OF HANDLING
AND PERSONAL PROTECTION BASED ON THE ACTUAL CONDITIONS OF USE. WHILE THIS
SDS IS BASED ON TECHNICAL DATA JUDGED TO BE RELIABLE, SPECTRUM ASSUMES
NO RESPONSIBILITY FOR THE COMPLETENESS OR ACCURACY OF THE INFORMATION
CONTAINED HEREIN.