| Common Name: | CITRIC ACID, MONOHYDRATE, CRYSTAL, REAGENT, ACS |
| Manufacturer: | SPECTRUM CHEMICALS & LABORATORY PRODUCTS |
| SDS Revision Date: | 6/12/2018 |
| SDS Format: | No Format Specified |
| Item Number(s): | 6PKZ3, 6PKZ6 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
SPECTRUM(R*)
S
ISO 9001-2015 REGISTERED
SAFETY DATA SHEET
PREPARATION DATE: 2/12/2015
REVISION DATE: 6/12/2018
REVISION NUMBER: G3
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER:
PRODUCT CODE: C1285
PRODUCT NAME: CITRIC ACID, MONOHYDRATE, CRYSTAL, REAGENT, ACS
OTHER MEANS OF IDENTIFICATION:
SYNONYMS: 2-HYDROXY-1,2,3-PROPANETRICARBOXYLIC ACID MONOHYDRATE
CAS #: 5949-29-1
RTECS #: GE7810000
CI#: NOT AVAILABLE
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE: IN BEVERAGES. IN FOODS.
USES ADVISED AGAINST: NO INFORMATION AVAILABLE
SUPPLIER:
SPECTRUM CHEMICAL MFG. CORP
14422 SOUTH SAN PEDRO ST.
GARDENA, CA 90248
(310) 516-8000
ORDER ONLINE AT: HTTPS://WWW.SPECTRUMCHEMICAL.COM
EMERGENCY TELEPHONE NUMBER:
CHEMTREC: 1-800-424-9300
CONTACT PERSON: MARTIN LABENZ (WEST COAST)
CONTACT PERSON: IBAD TIRMIZ (EAST COAST)
| 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION:
THIS CHEMICAL IS CONSIDERED HAZARDOUS ACCORDING TO THE 2012 OSHA HAZARD
COMMUNICATION STANDARD (29 CFR 1910.1200)
CONSIDERED A DANGEROUS SUBSTANCE OR MIXTURE ACCORDING TO THE GLOBALLY
HARMONIZED SYSTEM (GHS)
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): CATEGORY 3
LABEL ELEMENTS:
WARNING:
HAZARD STATEMENTS:
CAUSES SERIOUS EYE IRRITATION
MAY CAUSE RESPIRATORY IRRITATION
EXCLAMATION MARK
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC): NOT APPLICABLE
OTHER HAZARDS: CAUSES MILD SKIN IRRITATION
PRECAUTIONARY STATEMENTS - PREVENTION:
WASH FACE, HANDS AND ANY EXPOSED SKIN THOROUGHLY AFTER HANDLING
WEAR EYE/FACE PROTECTION
AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
PRECAUTIONARY STATEMENTS - STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED
STORE LOCKED UP
PRECAUTIONARY STATEMENTS - DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
COMPONENTS CAS-NO. WEIGHT %
CITRIC ACID, MONOHYDRATE 5949-29-1 100
| 4. FIRST AID MEASURES | |
FIRST AID MEASURES:
GENERAL ADVICE:
NATIONAL CAPITAL POISON CENTER IN THE UNITED STATES CAN PROVIDE ASSISTANCE
IF YOU HAVE A POISON EMERGENCY AND NEED TO TALK TO A POISON SPECIALIST.
CALL 1-800-222-1222.
SKIN CONTACT:
WASH OFF IMMEDIATELY WITH SOAP AND PLENTY OF WATER REMOVING ALL
CONTAMINATED CLOTHING AND SHOES. GET MEDICAL ATTENTION. IF SKIN IRRITATION
PERSISTS, CALL A PHYSICIAN.
EYE CONTACT: FLUSH EYES WITH WATER FOR 15 MINUTES. GET MEDICAL ATTENTION.
INHALATION:
MOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING WITHOUT MEDICAL ADVICE. NEVER GIVE ANYTHING BY
MOUTH TO AN UNCONSCIOUS PERSON. OBTAIN MEDICAL ATTENTION.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS:
CAUSES EYE IRRITATION
MILD SKIN IRRITATION
IRRITATING TO RESPIRATORY SYSTEM
MAY CAUSE IRRITATION OF RESPIRATORY TRACT
CENTRAL NERVOUS SYSTEM EFFECTS
MAY AFFECT THE CARDIOVASCULAR SYSTEM
MAY AFFECT RESPIRATION
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY.
PROTECTION OF FIRST-AIDERS:
FIRST-AID PROVIDERS:
AVOID EXPOSURE TO BLOOD OR BODY FLUIDS. WEAR GLOVES AND OTHER NECESSARY
PROTECTIVE CLOTHING. DISPOSE OF CONTAMINATED CLOTHING AND EQUIPMENT AS
BIO-HAZARDOUS WASTE.
| 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA: DRY CHEMICAL. WATER SPRAY MIST OR FOAM.
UNSUITABLE EXTINGUISHING MEDIA: NO INFORMATION AVAILABLE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
HAZARDOUS COMBUSTION PRODUCTS: CARBON MONOXIDE, CARBON DIOXIDE.
SPECIFIC HAZARDS:
MAY BE COMBUSTIBLE AT HIGH TEMPERATURES. FINE DUST DISPERSED IN AIR IN
SUFFICIENT CONCENTRATIONS, AND IN THE PRESENCE OF AN IGNITION SOURCE IS
A POTENTIAL DUST EXPLOSION HAZARD.
SPECIAL PROTECTIVE ACTIONS FOR FIREFIGHTERS:
SPECIFIC METHODS: NO INFORMATION AVAILABLE.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND,
MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
ENSURE ADEQUATE VENTILATION. USE PERSONAL PROTECTIVE EQUIPMENT. AVOID
CONTACT WITH SKIN, EYES AND CLOTHING. AVOID DUST FORMATION. KEEP PEOPLE
AWAY FROM AND UPWIND OF SPILL/LEAK. DO NOT TOUCH DAMAGED CONTAINERS OR
SPILLED MATERIAL UNLESS WEARING APPROPRIATE PROTECTIVE CLOTHING. REMOVE
ALL SOURCES OF IGNITION.
ENVIRONMENTAL PRECAUTIONS:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO. PREVENT PRODUCT
FROM ENTERING DRAINS. PREVENT ENTRY INTO WATERWAYS, SEWERS, BASEMENTS OR
CONFINED AREAS.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CONTAINMENT:
STOP LEAK IF YOU CAN DO IT WITHOUT RISK. COVER WITH PLASTIC SHEET TO
PREVENT SPREADING.
METHODS FOR CLEANING UP:
SWEEP UP AND SHOVEL INTO SUITABLE CONTAINERS FOR DISPOSAL. CLEAN
CONTAMINATED SURFACE THOROUGHLY.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
TECHNICAL MEASURES/PRECAUTIONS:
PROVIDE SUFFICIENT AIR EXCHANGE AND/OR EXHAUST IN WORK ROOMS. AVOID DUST
FORMATION. KEEP AWAY FROM INCOMPATIBLE MATERIALS.
SAFE HANDLING ADVICE:
WEAR PERSONAL PROTECTIVE EQUIPMENT. AVOID CONTACT WITH SKIN, EYES AND
CLOTHING. KEEP AWAY FROM HEAT AND SOURCES OF IGNITION. DO NOT INGEST. DO
NOT BREATHE DUST. HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND
SAFETY PRACTICE.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
TECHNICAL MEASURES/STORAGE CONDITIONS:
KEEP CONTAINER TIGHTLY CLOSED IN A DRY AND WELL-VENTILATED PLACE. STORE AT
ROOM TEMPERATURE IN THE ORIGINAL CONTAINER. STORE AWAY FROM INCOMPATIBLE
MATERIALS.
INCOMPATIBLE MATERIALS:
OXIDIZING AGENTS
REDUCING AGENTS
BASES
ACETATES
SULFIDES
BICARBONATES
POTASSIUM TARTRATE
METALS
ALUMINUM
ALUMINUM ALLOYS
ZINC
ZINC ALLOYS
COPPER
COPPER ALLOYS
METAL NITRATES
ALKALINE EARTH CARBONATES
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
NATIONAL OCCUPATIONAL EXPOSURE LIMITS:
UNITED STATES:
COMPONENTS CAS-NO. OSHA NIOSH ACGIH AIHA WEEL
CITRIC ACID, MONOHYDRATE 5949-29-1 NONE NONE NONE NONE
CANADA:
COMPONENT CAS NO CANADA - CANADA - CANADA - CANADA -
ALBERTA BRITISH ONTARIO QUEBEC
COLUMBIA
CITRIC ACID, 5949-29-1 NONE NONE NONE NONE
MONOHYDRATE
AUSTRALIA AND MEXICO:
COMPONENTS CAS-NO. AUSTRALIA MEXICO
CITRIC ACID, MONOHYDRATE 5949-29-1 NONE NONE
APPROPRIATE ENGINEERING CONTROLS:
ENGINEERING MEASURES TO REDUCE EXPOSURE:
ENSURE ADEQUATE VENTILATION. USE PROCESS ENCLOSURES, LOCAL EXHAUST
VENTILATION, OR OTHER ENGINEERING CONTROLS TO KEEP AIRBORNE LEVELS BELOW
RECOMMENDED EXPOSURE LIMITS. IF USER OPERATIONS GENERATE DUST, FUME OR
MIST, USE VENTILATION TO KEEP EXPOSURE TO AIRBORNE CONTAMINANTS BELOW THE
EXPOSURE LIMIT.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
PERSONAL PROTECTIVE EQUIPMENT:
EYE PROTECTION: GOGGLES
SKIN AND BODY PROTECTION:
CHEMICAL RESISTANT APRON
LONG SLEEVED CLOTHING
GLOVES
RESPIRATORY PROTECTION:
EFFECTIVE DUST MASK. USE A DUST RESPIRATOR UNDER CONDITIONS WHERE EXPOSURE
TO THE SUBSTANCE IS APPARENT (E.G. GENERATION OF HIGH CONCENTRATION OF
DUST (DUST CLOUDS), INADEQUATE VENTILATION, DEVELOPMENT OF RESPIRATORY
TRACT IRRITATION), AND ENGINEERING CONTROLS ARE NOT FEASIBLE. BE SURE TO
USE AN APPROVED/CERTIFIED RESPIRATOR OR EQUIVALENT.
HYGIENE MEASURES:
AVOID CONTACT WITH SKIN, EYES AND CLOTHING. WASH HANDS BEFORE BREAKS AND
IMMEDIATELY AFTER HANDLING THE PRODUCT. WHEN USING, DO NOT EAT, DRINK OR
SMOKE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: SOLID
APPEARANCE: CRYSTALLINE POWDER. GRANULAR. FINE CRYSTALS.
COLOR: COLORLESS. WHITE.
ODOR: ODORLESS.
TASTE: ACID. SOUR.
FORMULA: C6H8O7xH2O
MOLECULAR/FORMULA WEIGHT: 210.14
FLAMMABILITY: NO INFORMATION AVAILABLE
FLASHPOINT (DEG. C/DEG. F): NO INFORMATION AVAILABLE.
FLASH POINT TESTED ACCORDING TO: NOT AVAILABLE
AUTOIGNITION TEMPERATURE (DEG. C/DEG. F): NO INFORMATION AVAILABLE
LOWER EXPLOSION LIMIT (%): NO INFORMATION AVAILABLE
UPPER EXPLOSION LIMIT (%): NO INFORMATION AVAILABLE
MELTING POINT/RANGE (DEG. C/DEG. F): 100-153 DEG. C/212-307.4 DEG. F
DECOMPOSITION TEMPERATURE (DEG. C/DEG. F):
LOSES WATER OF CRYSTALLIZATION IN DRY AIR OR WHEN HEATED AT ABOUT
40-50 DEG. C/104-122 DEG. F
BOILING POINT/RANGE (DEG. C/DEG. F): NO INFORMATION AVAILABLE
BULK DENSITY: NO INFORMATION AVAILABLE
DENSITY (G/CM3): 1.542
SPECIFIC GRAVITY: 1.54
PH: NO INFORMATION AVAILABLE
VAPOR PRESSURE @ 20 DEG. C (KPA): NO INFORMATION AVAILABLE
EVAPORATION RATE: NO INFORMATION AVAILABLE
VAPOR DENSITY: NO INFORMATION AVAILABLE
VOC CONTENT (G/L): NO INFORMATION AVAILABLE
ODOR THRESHOLD (PPM): NO INFORMATION AVAILABLE
PARTITION COEFFICIENT (N-OCTANOL/WATER): NO INFORMATION AVAILABLE
VISCOSITY: NO INFORMATION AVAILABLE
MISCIBILITY: NO INFORMATION AVAILABLE
SOLUBILITY:
EASILY SOLUBLE IN COLD WATER
EASILY SOLUBLE IN HOT WATER
EASILY SOLUBLE IN METHANOL
SOLUBLE IN ETHER
SOLUBILITY IN ETHER: 2.17 G/100 G
SOLUBILITY IN METHANOL: 197 G/100 G @ 19 DEG. C
| 10. STABILITY AND REACTIVITY | |
REACTIVITY:
REACTIVE WITH OXIDIZING AGENTS
REACTS WITH REDUCING AGENTS
REACTS WITH STRONG BASES
POTENTIALLY EXPLOSIVE REACTION WITH METAL NITRATES
CHEMICAL STABILITY:
STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS: HAZARDOUS POLYMERIZATION DOES NOT OCCUR
CONDITIONS TO AVOID:
HEAT. IGNITION SOURCES. INCOMPATIBLE MATERIALS. AVOID DUST FORMATION.
DUST MAY FORM EXPLOSIVE MIXTURE IN AIR. FINE DUST DISPERSED IN AIR IN
SUFFICIENT CONCENTRATIONS, AND IN THE PRESENCE OF AN IGNITION SOURCE IS
A POTENTIAL DUST EXPLOSION HAZARD.
INCOMPATIBLE MATERIALS:
OXIDIZING AGENTS
REDUCING AGENTS
BASES
ACETATES
SULFIDES
BICARBONATES
POTASSIUM TARTRATE
METALS
ALUMINUM
ALUMINUM ALLOYS
ZINC
ZINC ALLOYS
COPPER
COPPER ALLOYS
METAL NITRATES
ALKALINE EARTH CARBONATES
HAZARDOUS DECOMPOSITION PRODUCTS: CARBON OXIDES.
OTHER INFORMATION:
CORROSIVITY:
CORROSIVE IN PRESENCE OF ALUMINUM, ZINC, COPPER AND THEIR ALLOYS
SPECIAL REMARKS ON CORROSIVITY: NO INFORMATION AVAILABLE
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
PRINCIPAL ROUTES OF EXPOSURE: INGESTION. INHALATION.
ACUTE TOXICITY:
COMPONENT INFORMATION:
CITRIC ACID, MONOHYDRATE:
CAS-NO.: 5949-29-1
LD50/ORAL/RAT: NO INFORMATION AVAILABLE
LD50/ORAL/MOUSE: 5790 MG/KG
LD50/DERMAL/RABBIT: NO INFORMATION AVAILABLE
LD50/DERMAL/RAT: NO INFORMATION AVAILABLE
LC50/INHALATION/RAT: NO INFORMATION AVAILABLE
LC50/INHALATION/MOUSE: NO INFORMATION AVAILABLE
OTHER LD50 OR LC50 INFORMATION:
375 MG/KG, INTRAPERITONEAL, RAT;
2700 MG/KG, SUBCUTANEOUS, MOUSE;
5500 MG/KG, SUBCUTANEOUS, RAT
PRODUCT INFORMATION:
LD50/ORAL/RAT:
VALUE - ACUTE TOX ORAL: NO INFORMATION AVAILABLE
LD50/ORAL/MOUSE:
VALUE - ACUTE TOX ORAL: 5790 MG/KG
LD50/DERMAL/RABBIT:
VALUE-ACUTE TOX DERMAL: NO INFORMATION AVAILABLE
LD50/DERMAL/RAT:
VALUE - ACUTE TOX DERMAL: NO INFORMATION AVAILABLE
LC50/INHALATION/RAT:
VALUE-VAPOR: NO INFORMATION AVAILABLE
VALUE-GAS: NO INFORMATION AVAILABLE
VALUE-DUST/MIST: NO INFORMATION AVAILABLE
LC50/INHALATION/MOUSE:
VALUE-VAPOR: NO INFORMATION AVAILABLE
VALUE - GAS: NO INFORMATION AVAILABLE
VALUE - DUST/MIST: NO INFORMATION AVAILABLE
SYMPTOMS:
SKIN CONTACT: MILD SKIN IRRITATION.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION. HIGHLY IRRITATING.
INHALATION:
IRRITATING TO RESPIRATORY SYSTEM. SYMPTOMS MAY INCLUDING COUGHING.
INGESTION:
CAUSES GASTROINTESTINAL (DIGESTIVE) TRACT IRRITATION WITH NAUSEA,
VOMITING, AND DIARRHEA. MAY AFFECT BEHAVIOR/CENTRAL NERVOUS SYSTEM
(CONVULSIONS, SOMNOLENCE), AND RESPIRATION. MAY AFFECT BEHAVIOR/CENTRAL
NERVOUS SYSTEM (ATAXIA). MAY AFFECT BEHAVIOR/CENTRAL NERVOUS SYSTEM
(TREMOR, CONVULSIONS). MAY AFFECT RESPIRATION (RESPIRATORY DEPRESSION).
MAY AFFECT THE CARDIOVASCULAR SYSTEM (CHANGE IN HEART RATE). MAY AFFECT
THE CARDIOVASCULAR SYSTEM (HYPOTENSION). MAY CAUSE METABOLIC ACIDOSIS. MAY
CAUSE HYPOCALCEMIA. MAY CAUSE LACTIC ACIDOSIS. MAY CAUSE HYPERKALEMIA.
ASPIRATION HAZARD: NO INFORMATION AVAILABLE.
DELAYED AND IMMEDIATE EFFECTS AS WELL AS CHRONIC EFFECTS FROM SHORT AND
LONG-TERM EXPOSURE:
CHRONIC TOXICITY:
FREQUENT INTAKE OF CITRATED BEVERAGES MAY CAUSE EROSION OF DENTAL ENAMEL
AND IRRITATION OF THE MUCOUS MEMBRANE LINING OF THE MOUTH (ORAL MUCOSA).
SENSITIZATION: NO INFORMATION AVAILABLE.
MUTAGENIC EFFECTS: NO INFORMATION AVAILABLE
CARCINOGENIC EFFECTS: NOT CONSIDERED CARCINOGENIC.
COMPONENTS CAS-NO. IARC ACGIH - NTP
CARCINOGENS
CITRIC ACID, 5949-29-1 NOT LISTED NOT LISTED NOT LISTED
MONOHYDRATE
COMPONENTS OSHA HCS - AUSTRALIA - AUSTRALIA -
CARCINOGENS NOTIFIABLE PROHIBITED
CARCINOGENIC CARCINOGENIC
SUBSTANCES SUBSTANCES
CITRIC ACID, MONOHYDRATE NOT LISTED NOT LISTED NOT LISTED
ACGIH (AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS)
IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER)
NTP (NATIONAL TOXICOLOGY PROGRAM)
OSHA (OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION OF THE US DEPARTMENT
OF LABOR)
REPRODUCTIVE TOXICITY: NO DATA IS AVAILABLE
REPRODUCTIVE EFFECTS: NO INFORMATION AVAILABLE
DEVELOPMENTAL EFFECTS: NO INFORMATION AVAILABLE
TERATOGENIC EFFECTS: NO INFORMATION AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY:
STOT - SINGLE EXPOSURE: RESPIRATORY SYSTEM.
STOT - REPEATED EXPOSURE: NO INFORMATION AVAILABLE.
TARGET ORGANS: RESPIRATORY SYSTEM.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
ECOTOXICITY EFFECTS: NO DATA AVAILABLE.
PERSISTENCE AND DEGRADABILITY: NO INFORMATION AVAILABLE
BIOACCUMULATIVE POTENTIAL: NO INFORMATION AVAILABLE.
MOBILITY: NO INFORMATION AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
WASTE FROM RESIDUES / UNUSED PRODUCTS:
WASTE MUST BE DISPOSED OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL
REGULATION.
CONTAMINATED PACKAGING:
EMPTY CONTAINERS SHOULD BE TAKEN FOR LOCAL RECYCLING, RECOVERY OR WASTE
DISPOSAL
COMPONENTS CAS-NO. RCRA - F RCRA - K RCRA - P RCRA - U
SERIES SERIES SERIES SERIES
WASTES WASTES WASTES WASTES
CITRIC ACID, 5949-29-1 NONE NONE NONE NONE
MONOHYDRATE
| 14. TRANSPORT INFORMATION | |
DOT:
UN-NO: NOT REGULATED
PROPER SHIPPING NAME: NO INFORMATION AVAILABLE
HAZARD CLASS: NO INFORMATION AVAILABLE
SUBSIDIARY CLASS: NO INFORMATION AVAILABLE
PACKING GROUP: NO INFORMATION AVAILABLE
EMERGENCY RESPONSE GUIDE NUMBER: NO INFORMATION AVAILABLE
MARINE POLLUTANT: NO DATA AVAILABLE
DOT RQ (LBS): NO INFORMATION AVAILABLE
SPECIAL PROVISIONS: NO INFORMATION AVAILABLE
SYMBOL(S): NO INFORMATION AVAILABLE
DESCRIPTION: NO INFORMATION AVAILABLE
TDG (CANADA):
UN-NO: NOT REGULATED
PROPER SHIPPING NAME: NO INFORMATION AVAILABLE
HAZARD CLASS: NO INFORMATION AVAILABLE
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: NO INFORMATION AVAILABLE
MARINE POLLUTANT: NO INFORMATION AVAILABLE
DESCRIPTION: NO INFORMATION AVAILABLE
ADR:
UN-NO: NOT REGULATED
PROPER SHIPPING NAME: NO INFORMATION AVAILABLE
HAZARD CLASS: NO INFORMATION AVAILABLE
PACKING GROUP: NO INFORMATION AVAILABLE
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
IMO / IMDG:
UN-NO: NOT REGULATED
PROPER SHIPPING NAME: NO INFORMATION AVAILABLE
HAZARD CLASS: NO INFORMATION AVAILABLE
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: NO INFORMATION AVAILABLE
MARINE POLLUTANT: NO INFORMATION AVAILABLE
RID:
UN-NO: NOT REGULATED
PROPER SHIPPING NAME: NO INFORMATION AVAILABLE
HAZARD CLASS: NO INFORMATION AVAILABLE
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: NO INFORMATION AVAILABLE
ICAO:
UN-NO: NOT REGULATED
PROPER SHIPPING NAME: NO INFORMATION AVAILABLE
HAZARD CLASS: NO INFORMATION AVAILABLE
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: NO INFORMATION AVAILABLE
IATA:
UN-NO: NOT REGULATED
PROPER SHIPPING NAME: NO INFORMATION AVAILABLE
HAZARD CLASS: NO INFORMATION AVAILABLE
SUBSIDIARY RISK: NO INFORMATION AVAILABLE
PACKING GROUP: NO INFORMATION AVAILABLE
ERG CODE: NO INFORMATION AVAILABLE
SPECIAL PROVISIONS: NO INFORMATION AVAILABLE
| 15. REGULATORY INFORMATION | |
INTERNATIONAL INVENTORIES:
COMPONENTS CAS-NO. U.S. TSCA KOREA KECL PHILIPPINES
(PICCS)
CITRIC ACID, 5949-29-1 NOT LISTED; NOT PRESENT PRESENT
MONOHYDRATE CITRIC ACID,
MONOHYDRATE
(CAS NO. 5949-29-1)
IS EXEMPT FROM
TSCA 8(B)
INVENTORY LISTING
SINCE IT IS A
HYDRATE. HOWEVER,
THE ANHYDROUS FORM
(CAS NO. 77-92-9)
IS LISTED AS
ACTIVE ON THE TSCA
8(B) INVENTORY
COMPONENTS JAPAN ENCS CHINA AUSTRALIA (AICS) EINECS-NO.
CITRIC ACID, PRESENT PRESENT PRESENT NOT PRESENT
MONOHYDRATE (2)-1318 [38022]
U.S. REGULATIONS:
CALIFORNIA PROP. 65: SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986.
CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER:
THIS PRODUCT DOES NOT CONTAIN A CHEMICAL REQUIRING A WARNING UNDER
CALIFORNIA PROP. 65. (SEE TABLE BELOW)
CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE REPRODUCTIVE TOXICITY:
THIS PRODUCT DOES NOT CONTAIN A CHEMICAL REQUIRING A WARNING UNDER
CALIFORNIA PROP. 65. (SEE TABLE BELOW)
COMPONENTS CAS-NO.
CITRIC ACID, MONOHYDRATE 5949-29-1
COMPONENTS CARCINOGEN DEVELOPMENTAL MALE FEMALE
TOXICITY REPRODUCTIVE REPRODUCTIVE
TOXICITY TOXICITY
CITRIC ACID, NOT LISTED NOT LISTED NOT LISTED NOT LISTED
MONOHYDRATE
CERCLA/SARA:
COMPONENTS CAS-NO. CERCLA - SECTION 302 SECTION 302
HAZARDOUS EXTREMELY EXTREMELY
SUBSTANCES HAZARDOUS HAZARDOUS
AND THEIR SUBSTANCES SUBSTANCES
REPORTABLE AND TPQS AND RQS
QUANTITIES
CITRIC ACID, 5949-29-1 NONE NONE NONE
MONOHYDRATE
COMPONENTS SECTION 313 - CHEMICAL SECTION 313 - REPORTING
CATEGORY DE MINIMIS
CITRIC ACID, NONE NONE
MONOHYDRATE
U.S. TSCA:
COMPONENTS CAS-NO. TSCA SECTION TSCA 8(D) - HEALTH
5(A)2 - CHEMICALS AND SAFETY REPORTING
WITH SIGNIFICANT NEW
USE RULES (SNURS)
CITRIC ACID, 5949-29-1 NOT APPLICABLE NOT APPLICABLE
MONOHYDRATE
CANADA:
WHIMIS 2015 - GHS CLASSIFICATIONS:
WHMIS 2015 HAZARD CLASSIFICATION INFORMATION:
COMPONENT WHMIS 2015 HAZARD CLASSIFICATION
CITRIC ACID, MONOHYDRATE SERIOUS EYE DAMAGE/EYE IRRITATION - CATEGORY 2:
5949-29-1 (100) H319:
CAUSES SERIOUS EYE IRRITATION. (DUE TO LACK OF
DATA, THIS CLASSIFICATION WAS ESTABLISHED BY
ANALOGY TO ANHYDROUS CITRIC ACID)
COMBUSTIBLE DUST - CATEGORY 1:
MAY FORM COMBUSTIBLE DUST CONCENTRATIONS IN
AIR (FACTORS SUCH AS COMBUSTIBILITY AND
EXPLOSIVENESS OF DUSTS INCLUDING COMPOSITION
AND SHAPE AND SIZE OF PARTICLES COULD CAUSE
SUBSTANCE TO BELONG TO 'COMBUSTIBLE DUST'
HAZARD CLASS)
CANADA HAZARDOUS PRODUCTS REGULATION:
THIS PRODUCT HAS BEEN CLASSIFIED ACCORDING TO THE HAZARD CRITERIA OF THE
HPR (HAZARDOUS PRODUCTS REGULATION) AND THE SDS CONTAINS ALL OF THE
INFORMATION REQUIRED BY THE HPR
WHMIS 1988 HAZARD CLASS:
E: CORROSIVE MATERIAL
COMPONENTS WHMIS 1988
CITRIC ACID, MONOHYDRATE E
CANADA CONTROLLED PRODUCTS REGULATION:
THIS PRODUCT HAS BEEN CLASSIFIED ACCORDING TO THE HAZARD CRITERIA OF THE
CPR (CONTROLLED PRODUCTS REGULATION) AND THE MSDS CONTAINS ALL OF THE
INFORMATION REQUIRED BY THE CPR.
INVENTORY:
COMPONENTS CAS-NO. CANADA (DSL) CANADA (NDSL)
CITRIC ACID, MONOHYDRATE 5949-29-1 PRESENT NOT LISTED
COMPONENTS CAS-NO. CEPA SCHEDULE I - TOXIC SUBSTANCES
CITRIC ACID, MONOHYDRATE 5949-29-1 NOT LISTED
COMPONENTS CAS-NO. CEPA - 2010 GREENHOUSE GASES
SUBJECT TO MANDATORY REPORTING
CITRIC ACID, MONOHYDRATE 5949-29-1 NOT LISTED
EU CLASSIFICATION:
EU GHS - SV - CLP 1272/2008:
COMPONENTS CAS-NO. EU GHS - SV - CLP (1272/2008)
CITRIC ACID, MONOHYDRATE 5949-29-1 NO INFORMATION
EU - CLP (1272/2008):
R-PHRASE(S):
R36: IRRITATING TO EYES.
S-PHRASE(S):
S26:
IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF WATER AND
SEEK MEDICAL ADVICE.
COMPONENTS CAS-NO. CLASSIFICATION CONCENTRATION SAFETY PHRASES
LIMITS
CITRIC ACID, 5949-29-1 NO INFORMATION
MONOHYDRATE
THE PRODUCT IS CLASSIFIED IN ACCORDANCE WITH ANNEX VI TO DIRECTIVE
67/548/EEC:
INDICATION OF DANGER:
XI: IRRITANT.
| 16. OTHER INFORMATION | |
PREPARATION DATE: 2/12/2015
REVISION DATE: 6/12/2018
PREPARED BY: SONIA OWEN
DISCLAIMER:
ALL CHEMICALS MAY POSE UNKNOWN HAZARDS AND SHOULD BE USED WITH CAUTION.
THIS SAFETY DATA SHEET (SDS) APPLIES ONLY TO THE MATERIAL AS PACKAGED. IF
THIS PRODUCT IS COMBINED WITH OTHER MATERIALS, DETERIORATES, OR BECOMES
CONTAMINATED, IT MAY POSE HAZARDS NOT MENTIONED IN THIS SDS. THE PHYSICAL
PROPERTIES REPORTED IN THIS SDS ARE OBTAINED FROM THE LITERATURE AND DO
NOT CONSTITUTE PRODUCT SPECIFICATIONS. INFORMATION CONTAINED HEREIN DOES
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