| Common Name: | HYDROGEN PEROXIDE, 30 PERCENT SOLUTION, REAGENT, ACS |
| Manufacturer: | SPECTRUM CHEMICALS & LABORATORY PRODUCTS |
| SDS Revision Date: | 12/21/2015 |
| SDS Format: | No Format Specified |
| Item Number(s): | 6PMW5 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SPECTRUM(R*)
S
ISO 9001-2008 REGISTERED
SAFETY DATA SHEET
PREPARATION DATE: 12/21/2015
REVISION DATE: 12/21/2015
REVISION NUMBER: G1
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER:
PRODUCT CODE: H1065
PRODUCT NAME: HYDROGEN PEROXIDE, 30 PERCENT SOLUTION, REAGENT, ACS
OTHER MEANS OF IDENTIFICATION:
SYNONYMS: NO INFORMATION AVAILABLE
CAS #: MIXTURE
RTECS #: NOT AVAILABLE
CI #: NOT AVAILABLE
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE: NO INFORMATION AVAILABLE.
USES ADVISED AGAINST: NO INFORMATION AVAILABLE
SUPPLIER:
SPECTRUM CHEMICAL MFG. CORP
14422 SOUTH SAN PEDRO ST.
GARDENA, CA 90248
(310) 516-8000
ORDER ONLINE AT: HTTPS://WWW.SPECTRUMCHEMICAL.COM
EMERGENCY TELEPHONE NUMBER:
CHEMTREC: 1-800-424-9300
CONTACT PERSON: MARTIN LABENZ (WEST COAST)
CONTACT PERSON: IBAD TIRMIZ (EAST COAST)
| 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION:
THIS CHEMICAL IS CONSIDERED HAZARDOUS BY THE 2012 OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200)
ACUTE TOXICITY - ORAL: CATEGORY 4
SKIN CORROSION/IRRITATION: CATEGORY 1
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 1
OXIDIZING LIQUIDS: CATEGORY 2
LABEL ELEMENTS:
DANGER:
HAZARD STATEMENTS:
CAUSES SEVERE SKIN BURNS AND EYE DAMAGE
HARMFUL IF SWALLOWED
MAY INTENSIFY FIRE; OXIDIZER
CORROSION
EXCLAMATION MARK
FLAME OVER CIRCLE
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC): NOT APPLICABLE
OTHER HAZARDS:
MAY BE HARMFUL IN CONTACT WITH SKIN
MAY BE HARMFUL IF INHALED
MAY CONTAIN GAS UNDER PRESSURE
PRECAUTIONARY STATEMENTS - PREVENTION:
WASH FACE, HANDS AND ANY EXPOSED SKIN THOROUGHLY AFTER HANDLING
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING
KEEP/STORE AWAY FROM CLOTHING/.. /COMBUSTIBLE MATERIALS
TAKE ANY PRECAUTION TO AVOID MIXING WITH COMBUSTIBLES..
PRECAUTIONARY STATEMENTS - RESPONSE:
IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN
SPECIFIC TREATMENT (SEE.. ON THIS LABEL)
IN CASE OF FIRE:
USE WATER TO EXTINGUISH. DO NOT USE DRY CHEMICALS OR FOAMS. CO2OR HALON MAY
PROVIDE LIMITED CONTROL.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
IF ON SKIN (OR HAIR):
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER
WASH CONTAMINATED CLOTHING BEFORE REUSE
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
IF SWALLOWED: CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL
RINSE MOUTH
DO NOT INDUCE VOMITING
PRECAUTIONARY STATEMENTS - STORAGE: STORE LOCKED UP
PRECAUTIONARY STATEMENTS - DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
COMPONENTS CAS-NO. WEIGHT % TRADE SECRET
WATER 7732-18-5 68-71 *
7732-18-5
HYDROGEN PEROXIDE 7722-84-1 29-32 *
7722-84-1
| 4. FIRST AID MEASURES | |
FIRST AID MEASURES:
GENERAL ADVICE:
POISON INFORMATION CENTERS IN EACH STATE CAPITAL CITY CAN PROVIDE
ADDITIONAL ASSISTANCE FOR SCHEDULED POISONS (13 1126). ENSURE THAT MEDICAL
PERSONNEL ARE AWARE OF THE MATERIAL(S) INVOLVED AND TAKE PRECAUTIONS TO
PROTECT THEMSELVES. FIRST AIDER NEEDS TO PROTECT HIMSELF.
SKIN CONTACT:
WASH OFF IMMEDIATELY WITH SOAP AND PLENTY OF WATER. CONTINUE FLUSHING WITH
PLENTY OF WATER FOR AT LEAST 15 MINUTES. REMOVE ALL CONTAMINATED CLOTHES
AND SHOES. IMMEDIATE MEDICAL ATTENTION IS REQUIRED. CALL A PHYSICIAN OR
POISON CONTROL CENTRE IMMEDIATELY.
EYE CONTACT:
FLUSH EYES WITH WATER FOR 15 MINUTES. IMMEDIATE MEDICAL ATTENTION IS
REQUIRED. CALL A PHYSICIAN OR POISON CONTROL CENTRE IMMEDIATELY.
INHALATION:
MOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN.
WARNING!
IT MAY BE HAZARDOUS TO THE PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH
RESUSCITATION WHEN THE INHALED OR INGESTED MATERIAL IS TOXIC, INFECTIOUS OR
CORROSIVE. DO NOT USE MOUTH-TO-MOUTH RESUSCITATION IF VICTIM INGESTED OR
INHALED THE SUBSTANCE; INDUCE ARTIFICIAL RESPIRATION WITH THE AID OF A
POCKET MASK EQUIPPED WITH A ONE-WAY VALVE OR OTHER PROPER RESPIRATORY
MEDICAL DEVICE. IMMEDIATE MEDICAL ATTENTION IS REQUIRED.
INGESTION:
DO NOT INDUCE VOMITING WITHOUT MEDICAL ADVICE. NEVER GIVE ANYTHING BY MOUTH
TO AN UNCONSCIOUS PERSON. IMMEDIATE MEDICAL ATTENTION IS REQUIRED. CALL A
PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS:
CAUSES SEVERE SKIN BURNS. SKIN CONTACT MAY RESULT IN REDNESS, PAIN,
INFLAMMATION, ITCHING, SCALING. CAUSES EYE DAMAGE. CAUSES EYE BURNS.
INFLAMMATION OF THE EYE IS CHARACTERIZED BY REDNESS, WATERING AND ITCHING.
MODERATE IRRITANT TO MUCOUS MEMBRANES ON INHALATION. MAY CAUSE IRRITATION
OF RESPIRATORY TRACT. COUGHING. CHOKING SENSATION. DYSPNEA (SHORTNESS OF
BREATH AND DIFFICULTY BREATHING).
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY
PROTECTION OF FIRST-AIDERS:
FIRST-AID PROVIDERS:
AVOID EXPOSURE TO BLOOD OR BODY FLUIDS. WEAR GLOVES AND OTHER NECESSARY
PROTECTIVE CLOTHING. DISPOSE OF CONTAMINATED CLOTHING AND EQUIPMENT AS
BIO-HAZARDOUS WASTE
| 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
WATER. CO2 MAY BE OF NO VALUE IN EXTINGUISHING FIRES INVOLVING OXIDIZERS
AND MAY ONLY PROVIDE LIMITED CONTROL.
UNSUITABLE EXTINGUISHING MEDIA: DRY CHEMICAL. FOAM. HALONS.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
HAZARDOUS COMBUSTION PRODUCTS: NO INFORMATION AVAILABLE.
SPECIFIC HAZARDS:
OXIDIZER. KEEP AWAY FROM COMBUSTIBLE MATERIALS (WOOD, PAPER, OIL,
CLOTHING, ETC.)
THE PRODUCT IS NOT FLAMMABLE, BUT IT MAY CAUSE FIRE WHEN IN CONTACT WITH
OTHER MATERIAL
CONTACT WITH COMBUSTIBLE OR ORGANIC MATERIALS MAY CAUSE FIRE
CONTAINER EXPLOSION MAY OCCUR UNDER FIRE CONDITIONS OR WHEN HEATED
HYDROGEN PEROXIDE MIXED WITH MAGNESIUM AND A TRACE OF MAGNESIUM DIOXIDE
WILL IGNITE IMMEDIATELY
SOLUBLE FUELS (ACETONE, ETHANOL, GLYCEROL) WILL DETONATE ON A MIXTURE WITH
PEROXIDE OVER 30% CONCENTRATION, THE VIOLENCE INCREASING WITH CONCENTRATION
EXPLOSIVE WITH ACETIC ACID, ACETIC ANHYDRIDE, ACETONE, ALCOHOLS, CARBOXYLIC
ACIDS, NITROGEN CONTAINING BASES, As2S3, Cl2 + KOH, FeS, FeSO4 + 2
METHYLPRYIDINE + H2SO4, NITRIC ACID, POTASSIUM PERMANGANATE, P2O5, H2Se,
ALCOHOLS + H2SO4, ALCOHOLS + TIN CHLORIDE, ANTIMOY TRISULFIDE,
CHLOROSULFONIC ACID, AROMATIC HYDROCARBONS + TRIFLUOROACETIC ACID, AZELIAC
ACID + SULFURIC ACID (ABOVE 45 C), BENZENESULFONIC ANHYDRIDE,
TERT-BUTANOL + SULFURIC ACID, HYDRAZINE, SULFURIC ACID, SODIUM IODATE,
TETRAHYDROTHIOPHENE, THIODIGLYCOL, MERCUROUS OXIDE, MERCURIC OXIDE, LEAD
DIOXIDE, LEAD OXIDE, MANGANESE DIOXIDE, LEAD SULFIDE, GALLIUM + HCl,
KETENES + NITRIC ACID, IRON (II) SULFATE + 2-METHYLPYRIDINE + SULFURIC
ACID, IRON (II) SULFATE + NITRIC ACID, + SODIUM CARBOXYMETHYLCELLULOSE
(WHEN EVAPORATED), VINYL ACETATE, TRIOXANE, WATER + OXYGENATED COMPOUNDS
(EG: ACETALDEHYDE, ACETIC ACID, ACETONE, ETHANOL, FORMALDEHYDE, FORMIC
ACID, METHANOL, 2-PROPANOL, PROPIONALDEHYDE), ORGANIC COMPOUNDS.
BEWARE:
MANY MIXITURES OF HYDROGEN PEROXIDE AND ORGANIC MATERIALS MAY NOT EXPLODE
UPON CONTACT. HOWEVER, THE RESULTING COMBINATION IS DETONATABLE EITHER UPON
CATCHING FIRE OR BY IMPACT.
ANOTHER SOURCE OF HYDROGEN PEROXIDE EXPLOSIONS IS FROM SEALING THE MATERIAL
IN STRONG CONTAINERS. UNDER SUCH CONDITIONS EVEN GRADUAL DECOMPOSITION OF
HYDROGEN PEROXIDE TO WATER + 1/2 OXYGEN CAN CAUSE LARGE PRESSURES TO BUILD
UP IN THE CONTAINERS WHICH MAY BURST EXPLOSIVELY
SPECIAL PROTECTIVE ACTIONS FOR FIREFIGHTERS:
SPECIFIC METHODS:
FOR LARGE FIRES, FLOOD FIRE AREA WITH WATER FROM A DISTANCE. DO NOT USE
COMBUSTIBLE MATERIALS SUCH AS SAWDUST.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND,
MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
KEEP PEOPLE AWAY FROM AND UPWIND OF SPILL/LEAK. ENSURE ADEQUATE
VENTILATION. USE PERSONAL PROTECTIVE EQUIPMENT. AVOID CONTACT WITH SKIN,
EYES AND CLOTHING. REMOVE ALL SOURCES OF IGNITION. KEEP COMBUSTIBLES (WOOD,
PAPER, OIL, CLOTHING, ETC.) AWAY FROM SPILLED MATERIAL. DO NOT TOUCH
DAMAGED CONTAINERS OR SPILLED MATERIAL UNLESS WEARING APPROPRIATE
PROTECTIVE CLOTHING.
ENVIRONMENTAL PRECAUTIONS:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO. DO NOT LET PRODUCT
ENTER DRAINS. PREVENT ENTRY INTO WATERWAYS, SEWERS, BASEMENTS OR CONFINED
AREAS.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CONTAINMENT:
STOP LEAK IF YOU CAN DO IT WITHOUT RISK. DILUTE WITH WATER. CONTAIN AND
COLLECT SPILLAGE WITH NON-COMBUSTIBLE ABSORBENT MATERIAL, (E.G. SAND,
EARTH, DIATOMACEOUS EARTH, VERMICULITE). IN CASE OF LARGE SPILL, DIKE IF
NEEDED. DIKE FAR AHEAD OF LIQUID SPILL FOR LATER DISPOSAL.
METHODS FOR CLEANING UP:
USE APPROPRIATE TOOLS TO PUT THE SPILLED MATERIAL IN A SUITABLE CHEMICAL
WASTE DISPOSAL CONTAINER. CLEAN CONTAMINATED SURFACE THOROUGHLY.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
TECHNICAL MEASURES/PRECAUTIONS:
PROVIDE SUFFICIENT AIR EXCHANGE AND/OR EXHAUST IN WORK ROOMS. KEEP AWAY
FROM INCOMPATIBLE MATERIALS.
SAFE HANDLING ADVICE:
WEAR PERSONAL PROTECTIVE EQUIPMENT. AVOID CONTACT WITH SKIN, EYES AND
CLOTHING. DO NOT BREATHE VAPORS OR SPRAY MIST. DO NOT INGEST. WHEN USING DO
NOT SMOKE. KEEP AWAY FROM COMBUSTIBLE MATERIAL. KEEP AWAY FROM HEAT AND
SOURCES OF IGNITION. HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND
SAFETY PRACTICE.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
TECHNICAL MEASURES/STORAGE CONDITIONS:
KEEP TIGHTLY CLOSED IN A DRY, COOL AND WELL-VENTILATED PLACE. KEEP
REFRIGERATED. KEEP AT TEMPERATURES BETWEEN 2 AND 8 DEG. C. DO NOT STORE
NEAR COMBUSTIBLE MATERIALS. STORE AWAY FROM INCOMPATIBLE MATERIALS. STORE
IN A SEGRATED AND APPROVED AREA.
INCOMPATIBLE MATERIALS:
INCOMPATIBLE WITH REDUCING MATERIALS, ALKALIES, ETHERS (DIOXANE, FURFURAN,
TETRAHYDROFURAN), METALS (EG. POTASSIUM, SODIUM LITHIUM, IRON, COPPER,
BRASS, BRONZE, CHROMIUM, ZINC, LEAD, SILVER, NICKEL, MANGANESE, PLATINUM,
COBALT, IRIDIUM, GOLD, TUNGSTEN, OSMIUM, PALLADIUM), METAL OXIDES (EG.
COBALT OXIDE, IRON OXIDE, LEAD OXIDE, LEAD HYDROXIDE, MANGANESE OXIDE),
METAL SALTS (EG. CALCIUM PERMANGANATE, SALTS OF IRON), ASBESTOS, VANADIUM,
MOLYBDEUM, TRIETHYLAMINE, PALLADIUM, SODIUM PYROPHOSPHATE, CARBOXYLIC
ACIDS, CYCLOPENTADIENE, FORMIC ACID, CHLOROSULFONIC ACID, CARBOXYLIC ACIDS,
ACETIC ACID, NITRIC ACID, RUST, KETONES, SODIUM CARBONATE, SODIUM BORATE,
ANILINE, MERCUROUS CHLORIDE, SODIUM PYROPHOSPHATE, HEXAVALENT CHROMIUM
COMPOUNDS, TETRAHYDROFURAN, SODIUM FLUORIDE, POTASSIUM PERMANGANATE, UREA,
MANGANESE DIOXIDE, HYDROGEN SELENIDE, CHARCOAL, COAL, SODIUM BORATE,
CYCLOPENTADIENE, GLYCERINE, CYANIDES (POTASSIUM, CYANIDE, SODIUM CYANIDE),
NITROGEN COMPOUNDS
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
NATIONAL OCCUPATIONAL EXPOSURE LIMITS:
UNITED STATES:
COMPONENTS OSHA NIOSH ACGIH AIHA WHEEL
WATER NONE NONE NONE NONE
7732-18-5
HYDROGEN PEROXIDE 1 PPM TWA =1 PPM TWA =1 PPM TWA NONE
7722-84-1 1.4 MG/M3 TWA
CANADA:
COMPONENTS ALBERTA BRITISH ONTARIO QUEBEC
COLUMBIA
WATER NONE NONE NONE NONE
7732-18-5
HYDROGEN PEROXIDE =1 PPM TWA =1 PPM TWA 1 PPM TWA 1 PPM TWAEV
7722-84-1 =1.4 MG/M3 TWA 1.4 MG/M3 TWAEV
AUSTRALIA AND MEXICO:
COMPONENTS AUSTRALIA MEXICO
WATER NONE NONE
7732-18-5
HYDROGEN PEROXIDE 1.4 MG/M3 TWA =1 PPM TWA
7722-84-1 =1.5 MG/M3 TWA
APPROPRIATE ENGINEERING CONTROLS:
ENGINEERING MEASURES TO REDUCE EXPOSURE:
ENSURE ADEQUATE VENTILATION. PROVIDE EXHAUST VENTILATION OR OTHER
ENGINEERING CONTROLS TO KEEP THE AIRBORNE CONCENTRATIONS OF VAPORS AND MIST
BELOW THEIR RESPECTIVE THRESHOLD LIMIT VALUE.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
PERSONAL PROTECTIVE EQUIPMENT:
EYE PROTECTION: FACE-SHIELD. OR. GOGGLES.
SKIN AND BODY PROTECTION:
CHEMICAL RESISTANT PROTECTIVE SUIT. GLOVES. BOOTS.
RESPIRATORY PROTECTION:
VAPOR RESPIRATOR. BE SURE TO USE AN APPROVED/CERTIFIED RESPIRATOR OR
EQUIVALENT.
HYGIENE MEASURES:
AVOID CONTACT WITH SKIN, EYES AND CLOTHING. WHEN USING, DO NOT EAT, DRINK
OR SMOKE. WASH HANDS BEFORE BREAKS AND IMMEDIATELY AFTER HANDLING THE
PRODUCT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
APPEARANCE: NO INFORMATION AVAILABLE
COLOR: CLEAR. COLORLESS.
ODOR: ODORLESS.
TASTE: BITTER. ACID.
FORMULA: H2O2
MOLECULAR/FORMULA WEIGHT: 34.01 G/MOL
FLAMMABILITY: NO INFORMATION AVAILABLE
FLASH POINT (DEG. C): NO DATA AVAILABLE
FLASHPOINT (DEG. C/DEG. F): NO INFORMATION AVAILABLE.
FLASH POINT TESTED ACCORDING TO: NOT AVAILABLE
AUTOIGNITION TEMPERATURE (DEG. C/DEG. F): NO INFORMATION AVAILABLE
LOWER EXPLOSION LIMIT (%): NO INFORMATION AVAILABLE
UPPER EXPLOSION LIMIT (%): NO INFORMATION AVAILABLE
PH: NO INFORMATION AVAILABLE
MELTING POINT/RANGE (DEG. C/DEG. F): -33 DEG. C/ -27.4 DEG. F
BOILING POINT/RANGE (DEG. C/DEG. F): 108 DEG. C/ 226.4D EG. F
DECOMPOSITION TEMPERATURE (DEG. C/DEG. F): NO INFORMATION AVAILABLE
BULK DENSITY: NO INFORMATION AVAILABLE
DENSITY (G/CM3): NO INFORMATION AVAILABLE
SPECIFIC GRAVITY: 1.1
VAPOR PRESSURE @ 20 DEG. C (KPA): 3.1
EVAPORATION RATE: NO INFORMATION AVAILABLE
VAPOR DENSITY: 1.1
VOC CONTENT (G/L): NO INFORMATION AVAILABLE
ODOR THRESHOLD (PPM): NO INFORMATION AVAILABLE
PARTITION COEFFICIENT (N-OCTANOL/WATER): NO INFORMATION AVAILABLE
VISCOSITY: NO INFORMATION AVAILABLE
MISCIBILITY: NO INFORMATION AVAILABLE
SOLUBILITY:
EASILY SOLUBLE IN COLD WATER
SOLUBLE IN DIETHYL ETHER
| 10. STABILITY AND REACTIVITY | |
REACTIVITY:
STRONG OXIDIZER. REACTIVE WITH REDUCING AGENT, COMBUSTIBLE MATERIALS,
ORGANIC MATERIALS, METALS, ACIDS, ALKALIS
CHEMICAL STABILITY:
STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS: HAZARDOUS POLYMERIZATION DOES NOT OCCUR
CONDITIONS TO AVOID: HEAT. INCOMPATIBLE MATERIALS.
INCOMPATIBLE MATERIALS:
INCOMPATIBLE WITH REDUCING MATERIALS, ALKALIES, ETHERS (DIOXANE, FURFURAN,
TETRAHYDROFURAN), METALS (EG. POTASSIUM, SODIUM LITHIUM, IRON, COPPER,
BRASS, BRONZE, CHROMIUM, ZINC, LEAD, SILVER, NICKEL, MANGANESE, PLATINUM,
COBALT, IRIDIUM, GOLD, TUNGSTEN, OSMIUM, PALLADIUM), METAL OXIDES (EG.
COBALT OXIDE, IRON OXIDE, LEAD OXIDE, LEAD HYDROXIDE, MANGANESE OXIDE),
METAL SALTS (EG. CALCIUM PERMANGANATE, SALTS OF IRON), ASBESTOS, VANADIUM,
MOLYBDEUM, TRIETHYLAMINE, PALLADIUM, SODIUM PYROPHOSPHATE, CARBOXYLIC
ACIDS, CYCLOPENTADIENE, FORMIC ACID, CHLOROSULFONIC ACID, CARBOXYLIC ACIDS,
ACETIC ACID, NITRIC ACID, RUST, KETONES, SODIUM CARBONATE, SODIUM BORATE,
ANILINE, MERCUROUS CHLORIDE, SODIUM PYROPHOSPHATE, HEXAVALENT CHROMIUM
COMPOUNDS, TETRAHYDROFURAN, SODIUM FLUORIDE, POTASSIUM PERMANGANATE, UREA,
MANGANESE DIOXIDE, HYDROGEN SELENIDE, CHARCOAL, COAL, SODIUM BORATE,
CYCLOPENTADIENE, GLYCERINE, CYANIDES (POTASSIUM, CYANIDE, SODIUM CYANIDE),
NITROGEN COMPOUNDS
HAZARDOUS DECOMPOSITION PRODUCTS: OXYGEN.
OTHER INFORMATION:
CORROSIVITY: NON-CORROSIVE IN PRESENCE OF GLASS.
SPECIAL REMARKS ON CORROSIVITY: NO INFORMATION AVAILABLE
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
PRINCIPAL ROUTES OF EXPOSURE: SKIN. INGESTION. EYES.
ACUTE TOXICITY:
COMPONENT INFORMATION:
WATER - 7732-18-5:
LD50/ORAL/RAT: >90 ML/KG ORAL LD50 RAT
LD50/ORAL/MOUSE: NO INFORMATION AVAILABLE
LD50/DERMAL/RAT: NO INFORMATION AVAILABLE
LD50/DERMAL/RABBIT: NO INFORMATION AVAILABLE
LC50/INHALATION/RAT: NO INFORMATION AVAILABLE
LC50/INHALATION/MOUSE: NO INFORMATION AVAILABLE
OTHER LD50 OR LC50 INFORMATION: NO INFORMATION AVAILABLE
HYDROGEN PEROXIDE - 7722-84-1:
LD50/ORAL/RAT: 1518 MG/KG ORAL LD50 RAT
LD50/ORAL/MOUSE: NO INFORMATION AVAILABLE
LD50/DERMAL/RAT: 4060 MG/KG DERMAL LD50 RAT
LD50/DERMAL/RABBIT: 2000 MG/KG DERMAL LD50 RABBIT
LC50/INHALATION/RAT: 2 G/M3 INHALATION LC50 RAT 4 H
LC50/INHALATION/MOUSE: NO INFORMATION AVAILABLE
OTHER LD50 OR LC50 INFORMATION: NO INFORMATION AVAILABLE
PRODUCT INFORMATION:
LD50/ORAL/RAT:
VALUE - ACUTE TOX ORAL: NO INFORMATION AVAILABLE
LD50/ORAL/MOUSE:
VALUE - ACUTE TOX ORAL: NO INFORMATION AVAILABLE
LD50/DERMAL/RABBIT:
VALUE-ACUTE TOX DERMAL: NO INFORMATION AVAILABLE
LD50/DERMAL/RAT:
VALUE - ACUTE TOX DERMAL: NO INFORMATION AVAILABLE
LC50/INHALATION/RAT:
VALUE-VAPOR: NO INFORMATION AVAILABLE
VALUE-GAS: NO INFORMATION AVAILABLE
VALUE-DUST/MIST: NO INFORMATION AVAILABLE
LC50/INHALATION/MOUSE:
VALUE-VAPOR: NO INFORMATION AVAILABLE
VALUE - GAS: NO INFORMATION AVAILABLE
VALUE - DUST/MIST: NO INFORMATION AVAILABLE
SYMPTOMS:
SKIN CONTACT:
CORROSIVE. CONTACT CAUSES SEVERE SKIN IRRITATION AND POSSIBLE BURNS.
ABSORPTION INTO SKIN MAY AFFECT BEHAVIOR/CENTRAL NERVOUS SYSTEM (TREMOR,
ATAXIA, CONVULSIONS), RESPIRATION (DYSPNEA, PULMONARY EMBOLI), BRAIN.
EYE CONTACT:
CORROSIVE. CAUSES SEVERE EYE IRRITATION, SUPERFICIAL CLOUDING, CORNEAL
EDEMA AND MAY CAUSE BURNS.
INHALATION:
MAY BE HARMFUL IF INHALED. CAUSES RESPIRATORY TRACT (NOSE, THROAT, LUNG)
IRRITATION WITH COUGHING AND WHEEZING. MAY CAUSE ULCERATION AND PERFORATION
OF THE NASAL SEPTUM IF INHALED IN EXCESSIVE QUANTITIES. BURNING COPPER
SULFATE MAY RESULT IN IRRITATING AND POISONOUS GASES WHICH MAY IRRITATE THE
RESPIRATORY TRACT AND LUNGS, AND MAY CAUSE FUME METAL FEVER WHICH IS
CHARACTERIZED BY FLU-LIKE SYMPTOMS SUCH AS FEVER, CHILLS, MUSCLE ACHES.
CAUSES LACRIMATION. MAY CAUSE CHEMICAL BURNS TO THE RESPIRATORY TRACT. MAY
AFFECT BEHAVIOR/CENTRAL NERVOUS SYSTEM (INSOMNIA, HEADACHE, ATAXIA, NERVOUS
TREMORS WITH NUMB EXTREMITIES) AND MAY CAUSE ULCERATION OF NASAL TISSUE,
AND, CHEMICAL PNEUMONIA, UNCONCIOUSNESS, AND POSSIBLE DEATH. AT HIGH
CONCENTRATIONS, RESPIRATORY EFFECTS MAY INCLUDE ACUTE LUNG DAMAGE, AND
DELAYED PULMONARY EDEMA. MAY AFFECT BLOOD.
INGESTION:
HARMFUL IF SWALLOWED. CAUSES GASTROINTESTIONAL TRACT IRRITATION WITH
NAUSEA, VOMITING, HYPERMOTILITY, AND DIARRHEA. CAUSES GASTROINTESTIONAL
TRACT BURNS. MAY AFFECT CARDIOVASCULAR SYSTEM AND CAUSE VASCULAR COLLAPSE
AND DAMAGE. MAY AFFECT BLOOD (CHANGE IN LEUKOCYTE COUNT, PIGMENTED OR
NUCLEATED RED BLOOD CELLS). MAY CAUSE DIFFICULTY IN SWALLOWING, STOMACH
DISTENSION AND POSSIBLE CEREBAL SWELLING. MAY AFFECT BEHAVIOR/CENTRAL
NERVOUS SYSTEM (TETANY, EXCITEMENT)., AND BRAIN.
ASPIRATION HAZARD: NO INFORMATION AVAILABLE
DELAYED AND IMMEDIATE EFFECTS AS WELL AS CHRONIC EFFECTS FROM SHORT AND
LONG-TERM EXPOSURE:
CHRONIC TOXICITY:
PROLONGED OR REPEATED SKIN CONTACT MAY CAUSE DERMATITIS
PROLONGED OR REPEATED EXPOSURE OF EYES TO VAPOR OR MIST MAY CAUSE CORNEAL
DAMAGE
PROLONGED OR REPEATED INHALATION MAY AFFECT METABOLISM (WEIGHT LOSS)
PROLONGED OR REPEATED INGESTION MAY AFFECT THE LIVER
PROLONGED OR REPEATED INHALATION MAY AFFECT THE BLOOD (CHANGES IN SERUM
COMPOSITION)
SENSITIZATION: NO INFORMATION AVAILABLE
MUTAGENIC EFFECTS:
MUTATIONS IN MICROORGANISMS
EXPERIMENTS WITH BACTERIA AND/OR YEAST HAVE SHOWN MUTAGENIC EFFECTS
CARCINOGENIC EFFECTS:
NOT CLASSIFIABLE AS A HUMAN CARCINOGEN. NOT CLASSIFIABLE AS TO ITS
CARCINOGENICITY TO HUMANS.
COMPONENTS IARC ACGIH - NTP
CARCINOGENS
WATER NOT LISTED NOT LISTED NOT LISTED
HYDROGEN PEROXIDE GROUP 3 - A3 CONFIRMED NOT LISTED
MONOGRAPH 71 ANIMAL
[1999] CARCINOGEN
SUPPLEMENT 7 [1987] WITH UNKNOWN
MONOGRAPH 36 RELEVANCE TO
[1985] HUMANS
COMPONENTS OSHA HCS - AUSTRALIA - AUSTRALIA -
CARCINOGENS NOTIFIABLE PROHIBITED
CARCINOGENIC CARCINOGENIC
SUBSTANCES SUBSTANCES
WATER NOT LISTED NOT LISTED NOT LISTED
HYDROGEN PEROXIDE NOT LISTED NOT LISTED NOT LISTED
ACGIH (AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS)
IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER):
GROUP 3 - NOT CLASSIFIABLE AS TO ITS CARCINOGENICITY TO HUMANS
REPRODUCTIVE TOXICITY: NO DATA IS AVAILABLE
REPRODUCTIVE EFFECTS: NO INFORMATION AVAILABLE
DEVELOPMENTAL EFFECTS: NO INFORMATION AVAILABLE
TERATOGENIC EFFECTS: NO INFORMATION AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY:
STOT - SINGLE EXPOSURE: NO INFORMATION AVAILABLE
STOT - REPEATED EXPOSURE: NO INFORMATION AVAILABLE
TARGET ORGANS:
BLOOD. RESPIRATORY SYSTEM. SKIN. EYES. CENTRAL NERVOUS SYSTEM.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
ECOTOXICITY EFFECTS: AQUATIC ENVIRONMENT.
HYDROGEN PEROXIDE - 7722-84-1:
FRESHWATER ALGAE DATA: 2.5 MG/L EC50 CHLORELLA VULGARIS 72 H
FRESHWATER FISH SPECIES DATA:
18-56 MG/L LC50 LEPOMIS MACROCHIRUS 96 H STATIC 1
10.0-32.0 MG/L LC50 ONCORHYNCHUS MYKISS 96 H STATIC 1
16.4 MG/L LC50 PIMEPHALES PROMELAS 96 H 1
WATER FLEA DATA:
18 - 32 MG/L EC50 DAPHNIA MAGNA 48 H
7.7 MG/L EC50 DAPHNIA MAGNA 24 H
PERSISTENCE AND DEGRADABILITY: NO INFORMATION AVAILABLE
BIOACCUMULATIVE POTENTIAL: NO INFORMATION AVAILABLE
MOBILITY: NO INFORMATION AVAILABLE
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
WASTE FROM RESIDUES / UNUSED PRODUCTS:
WASTE MUST BE DISPOSED OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL
REGULATION.
CONTAMINATED PACKAGING:
EMPTY CONTAINERS SHOULD BE TAKEN FOR LOCAL RECYCLING, RECOVERY OR WASTE
DISPOSAL
COMPONENTS RCRA - F RCRA - K RCRA - P RCRA - U
SERIES SERIES SERIES SERIES
WASTES WASTES WASTES WASTES
WATER NONE NONE NONE NONE
HYDROGEN PEROXIDE NONE NONE NONE NONE
| 14. TRANSPORT INFORMATION | |
DOT:
UN-NO: UN2014
PROPER SHIPPING NAME: HYDROGEN PEROXIDE, AQUEOUS SOLUTIONS
HAZARD CLASS: 5.1
SUBSIDIARY RISK: 8
PACKING GROUP: NONE
ERG NO: 140
MARINE POLLUTANT: NO DATA AVAILABLE
DOT RQ (LBS): NO INFORMATION AVAILABLE
TDG (CANADA):
UN-NO: UN2014
PROPER SHIPPING NAME: HYDROGEN PEROXIDE, AQUEOUS SOLUTION
HAZARD CLASS: 5.1
SUBSIDIARY RISK: (8)
PACKING GROUP: II
DESCRIPTION: NO INFORMATION AVAILABLE
ADR:
UN-NO: UN2014
PROPER SHIPPING NAME: HYDROGEN PEROXIDE, AQUEOUS SOLUTION
HAZARD CLASS: 5.1
PACKING GROUP: II
SUBSIDIARY RISK: 8
CLASSIFICATION CODE: NO INFORMATION AVAILABLE
DESCRIPTION: NO INFORMATION AVAILABLE
CEFIC TREMCARD NO: NO INFORMATION AVAILABLE
IMO / IMDG:
UN-NO: UN2014
PROPER SHIPPING NAME: HYDROGEN PEROXIDE, AQUEOUS SOLUTION
HAZARD CLASS: 5.1
SUBSIDIARY RISK: 8
PACKING GROUP: II
DESCRIPTION: NO INFORMATION AVAILABLE
IMDG PAGE: NO INFORMATION AVAILABLE
MARINE POLLUTANT: NO INFORMATION AVAILABLE
EMS: F-H
MFAG: NO INFORMATION AVAILABLE
MAXIMUM QUANTITY: NO INFORMATION AVAILABLE
RID:
UN-NO: UN2014
PROPER SHIPPING NAME: HYDROGEN PEROXIDE, AQUEOUS SOLUTION
HAZARD CLASS: 5.1
SUBSIDIARY RISK: 8
PACKING GROUP: II
CLASSIFICATION CODE: NO INFORMATION AVAILABLE
DESCRIPTION: NO INFORMATION AVAILABLE
ICAO:
UN-NO: UN2014
PROPER SHIPPING NAME: HYDROGEN PEROXIDE, AQUEOUS SOLUTION
HAZARD CLASS: 5.1
SUBSIDIARY RISK: 8
PACKING GROUP: II
DESCRIPTION: NO INFORMATION AVAILABLE
IATA:
UN-NO: UN2014
PROPER SHIPPING NAME: HYDROGEN PEROXIDE, AQUEOUS SOLUTION
HAZARD CLASS: 5.1
SUBSIDIARY RISK: 8
PACKING GROUP: II
ERG CODE: 5C
DESCRIPTION: NO INFORMATION AVAILABLE
| 15. REGULATORY INFORMATION | |
INTERNATIONAL INVENTORIES:
COMPONENTS U.S. TSCA KOREA KECL PHILIPPINES (PICCS)
WATER PRESENT PRESENT PRESENT
KE-35400
HYDROGEN PEROXIDE PRESENT PRESENT PRESENT
KE-20204
COMPONENTS JAPAN ENCS CHINA AUSTRALIA EINECS-NO.
(AICS)
WATER NOT PRESENT PRESENT PRESENT PRESENT 231-791-2
HYDROGEN PEROXIDE PRESENT PRESENT PRESENT PRESENT 231-765-0
(1)-419
U.S. REGULATIONS:
HYDROGEN PEROXIDE:
MASSACHUSETTS RTK: PRESENT
MASSACHUSETTS EHS: EXTRAORDINARILY HAZARDOUS
NEW JERSEY RTK HAZARDOUS SUBSTANCE LIST: 1015
NEW JERSEY (EHS) LIST: 1015 500 LB TPQ
NEW JERSEY - DISCHARGE PREVENTION - LIST OF HAZARDOUS SUBSTANCES: PRESENT
PENNSYLVANIA RTK: ENVIRONMENTAL HAZARD
PENNSYLVANIA RTK - ENVIRONMENTAL HAZARD LIST: PRESENT
PENNSYLVANIA RTK - SPECIAL HAZARDOUS SUBSTANCES: PRESENT
MICHIGAN PSM HHC: =7500 LB TQ 52% BY WEIGHT OR GREATER
MINNESOTA - HAZARDOUS SUBSTANCE LIST: PRESENT
NEW YORK RELEASE REPORTING - LIST OF HAZARDOUS SUBSTANCES: =1 LB RQ
CALIFORNIA DIRECTORS LIST OF HAZARDOUS SUBSTANCES: PRESENT
FDA - FOOD ADDITIVES GENERALLY RECOGNIZED AS SAFE (GRAS): 21 CFR 184.1366
FDA - DIRECT FOOD ADDITIVES:
21 CFR 173.315
21 CFR 173.356
FDA - 21 CFR - TOTAL FOOD ADDITIVES:
133.113 133.118 133.136 133.144 133.195 160.105 160.145 160.185 172.167
172.723 172.814 172.892 173.315 173.356 173.370 175.105 178.1005 178.1010
184.1366
CALIFORNIA PROP. 65: SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986.
CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER:
THIS PRODUCT DOES NOT CONTAIN A CHEMICAL REQUIRING A WARNING UNDER
CALIFORNIA PROP. 65. (SEE TABLE BELOW)
CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE REPRODUCTIVE TOXICITY:
THIS PRODUCT DOES NOT CONTAIN A CHEMICAL REQUIRING A WARNING UNDER
CALIFORNIA PROP. 65. (SEE TABLE BELOW)
COMPONENTS CARCINOGEN DEVELOPMENTAL MALE FEMALE
TOXICITY REPRODUCTIVE REPRODUCTIVE
TOXICITY TOXICITY
WATER NOT LISTED NOT LISTED NOT LISTED NOT LISTED
HYDROGEN PEROXIDE NOT LISTED NOT LISTED NOT LISTED NOT LISTED
CERCLA/SARA:
COMPONENTS CERCLA - HAZARDOUS SECTION 302 SECTION 302
SUBSTANCES AND EXTREMELY EXTREMELY
THEIR REPORTABLE HAZARDOUS HAZARDOUS
QUANTITIES SUBSTANCES AND SUBSTANCES AND
TPQS RQS
WATER NONE NONE NONE
HYDROGEN PEROXIDE NONE 1000 LB TPQ NONE
1000
COMPONENTS SECTION 313 - SECTION 313 - REPORTING
CHEMICAL CATEGORY DE MINIMIS
WATER NONE NONE
HYDROGEN PEROXIDE NONE NONE
U.S. TSCA:
COMPONENTS TSCA SECTION 5(A)2 - TSCA 8(D) - HEALTH AND
CHEMICALS WITH SAFETY REPORTING
SIGNIFICANT NEW USE
RULES (SNURS)
WATER NOT APPLICABLE NOT APPLICABLE
HYDROGEN PEROXIDE NOT APPLICABLE NOT APPLICABLE
CANADA:
WHMIS HAZARD CLASS:
C: OXIDIZING MATERIALS
E: CORROSIVE MATERIAL
F: DANGEROUSLY REACTIVE MATERIAL
WATER: UNCONTROLLED PRODUCT ACCORDING TO WHMIS CLASSIFICATION CRITERIA
HYDROGEN PEROXIDE:
C E F
C D2B INCLUDING 9%, 10%, 15%
C E INCLUDING 20%, 25%, 27%
C E F INCLUDING 30%, 35%, 40%, 50%, 65%, 70%, 75%, 80%, 85%, 90%, 95%
CANADA CONTROLLED PRODUCTS REGULATION:
THIS PRODUCT HAS BEEN CLASSIFIED ACCORDING TO THE HAZARD CRITERIA OF THE
CPR (CONTROLLED PRODUCTS REGULATION) AND THE MSDS CONTAINS ALL OF THE
INFORMATION REQUIRED BY THE CPR.
COMPONENTS WHMIS INGREDIENT DISCLOSURE LIST
HYDROGEN PEROXIDE 1 %
INVENTORY:
COMPONENTS CANADA (DSL) CANADA (NDSL)
WATER PRESENT NOT LISTED
HYDROGEN PEROXIDE PRESENT NOT LISTED
COMPONENTS CEPA SCHEDULE I - CEPA - 2010 GREENHOUSE
TOXIC SUBSTANCES GASES SUBJECT TO MANDITORY
REPORTING
WATER NOT LISTED NOT LISTED
HYDROGEN PEROXIDE NOT LISTED NOT LISTED
EU CLASSIFICATION:
R-PHRASE(S):
R8: CONTACT WITH COMBUSTIBLE MATERIAL MAY CAUSE FIRE.
R34: CAUSES BURNS.
S-PHRASE(S):
S28: AFTER CONTACT WITH SKIN, WASH IMMEDIATELY WITH PLENTY OF WATER
S45:
IN CASE OF ACCIDENT OR IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE IMMEDIATELY
(SHOW THE LABEL WHERE POSSIBLE).
S1/2: KEEP LOCKED UP AND OUT OF THE REACH OF CHILDREN.
S36/39: WEAR SUITABLE PROTECTIVE CLOTHING AND EYE/FACE PROTECTION.
COMPONENTS CLASSIFICATION CONCENTRATION LIMITS SAFETY PHRASES
WATER NO INFORMATION
HYDROGEN PEROXIDE C; R34 20% <=C C; R34 S(1/2)-S28-S36/
O; R8 5% <=C<20% XI; R36/38 39-S45
THE PRODUCT IS CLASSIFIED IN ACCORDANCE WITH ANNEX VI TO DIRECTIVE
67/548/EEC:
INDICATION OF DANGER:
C: CORROSIVE.
O: OXIDISING.
| 16. OTHER INFORMATION | |
PREPARATION DATE: 12/21/2015
REVISION DATE: 12/21/2015
PREPARED BY: SONIA OWEN
DISCLAIMER:
ALL CHEMICALS MAY POSE UNKNOWN HAZARDS AND SHOULD BE USED WITH CAUTION.
THIS SAFETY DATA SHEET (SDS) APPLIES ONLY TO THE MATERIAL AS PACKAGED. IF
THIS PRODUCT IS COMBINED WITH OTHER MATERIALS, DETERIORATES, OR BECOMES
CONTAMINATED, IT MAY POSE HAZARDS NOT MENTIONED IN THIS SDS. THE PHYSICAL
PROPERTIES REPORTED IN THIS SDS ARE OBTAINED FROM THE LITERATURE AND DO NOT
CONSTITUTE PRODUCT SPECIFICATIONS. INFORMATION CONTAINED HEREIN DOES NOT
CONSTITUTE A WARRANTY, WHETHER EXPRESSED OR IMPLIED, AS TO THE SAFETY,
MERCHANTABILITY OR FITNESS OF THE GOODS FOR A PARTICULAR PURPOSE. SPECTRUM
CHEMICALS & LABORATORY PRODUCTS, INC. ASSUMES NO RESPONSIBILITY FOR RESULTS
OBTAINED OR FOR INCIDENTAL OR CONSEQUENTIAL DAMAGES, INCLUDING LOST
PROFITS, ARISING FROM THE USE OF THESE DATA. NO WARRANTY AGAINST
INFRINGEMENT OF ANY PATENT, COPYRIGHT OR TRADEMARK IS MADE OR IMPLIED. IT
SHALL BE THE USER'S RESPONSIBILITY TO DEVELOP PROPER METHODS OF HANDLING
AND PERSONAL PROTECTION BASED ON THE ACTUAL CONDITIONS OF USE. WHILE THIS
SDS IS BASED ON TECHNICAL DATA JUDGED TO BE RELIABLE, SPECTRUM ASSUMES NO
RESPONSIBILITY FOR THE COMPLETENESS OR ACCURACY OF THE INFORMATION
CONTAIN.ED HEREIN.