| Common Name: | AUTOMATIC TOILET BOWL CLEANER |
| Manufacturer: | IRON OUT DBA SUMMIT BRANDS |
| SDS Revision Date: | 12/3/2018 |
| SDS Format: | GHS-US |
| Item Number(s): | 4YJW6, 60MM35, 60MM39, 6VME6 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
SUMMIT BRANDS
SAFETY DATA SHEET
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT IDENTIFIER: IRON OUT AUTOMATIC TOILET BOWL CLEANER
OTHER MEANS OF IDENTIFICATION: NOT AVAILABLE
RECOMMENDED USE: NOT AVAILABLE.
RECOMMENDED RESTRICTIONS: NONE KNOWN.
MANUFACTURER INFORMATION:
IRON OUT DBA SUMMIT BRANDS
6714 POINTE INVERNESS WAY
SUITE 200
FORT WAYNE, IN 46804-7935 US
PHONE: 260-483-2519
EMERGENCY PHONE: 1-800-424-9300 (CHEMTREC)
SUPPLIER: SEE ABOVE.
| 2. HAZARDS IDENTIFICATION | |
PHYSICAL HAZARDS: NOT CLASSIFIED.
HEALTH HAZARDS:
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 1
REPRODUCTIVE TOXICITY: CATEGORY 1B
ENVIRONMENTAL HAZARDS: NOT CLASSIFIED.
WHMIS 2015 DEFINED HAZARDS: NOT CLASSIFIED
LABEL ELEMENTS:
CORROSION
HEALTH HAZARD
SIGNAL WORD: DANGER
HAZARD STATEMENT:
CAUSES SKIN IRRITATION. CAUSES SERIOUS EYE DAMAGE. MAY DAMAGE FERTILITY OR
THE UNBORN CHILD.
PRECAUTIONARY STATEMENT:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. WASH THOROUGHLY AFTER HANDLING.
WEAR PROTECTIVE GLOVES, PROTECTIVE CLOTHING, EYE PROTECTION AND FACE
PROTECTION.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF SKIN IRRITATION OCCURS:
GET MEDICAL ATTENTION. TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE
REUSE. SPECIFIC TREATMENT (SEE INFORMATION ON THIS LABEL).
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING. IMMEDIATELY CALL A POISON CENTER
OR DOCTOR.
IF EXPOSED OR CONCERNED: GET MEDICAL ATTENTION.
STORAGE: STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTAINER IN ACCORDANCE WITH LOCAL, REGIONAL, NATIONAL AND
INTERNATIONAL REGULATIONS.
WHMIS 2015:
HEALTH HAZARD(S) NOT OTHERWISE CLASSIFIED (HHNOC): NONE KNOWN
WHMIS 2015:
PHYSICAL HAZARD(S) NOT OTHERWISE CLASSIFIED (PHNOC): NONE KNOWN
HAZARD(S) NOT OTHERWISE CLASSIFIED (HNOC): NONE KNOWN.
SUPPLEMENTAL INFORMATION: NONE.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
MIXTURE:
CHEMICAL NAME COMMON NAME CAS NUMBER %
AND SYNONYMS
BICYCLO[2.2.1]HEPTAN-2-OL, 125-12-2 1-5*
1,7,7-TRIMETHYL-, ACETATE, EXO-
DODECANAMIDE, N-(2-HYDROXYETHYL)- 142-78-9 10-30*
METHANOL 67-56-1 0.1-1*
MONOETHANOLAMINE 141-43-5 1-5*
N-(2-HYDROXYETHYL)MYRISTAMIDE 142-58-5 5-10*
N-(2-HYDROXYETHYL)OLEAMIDE 111-58-0 1-5*
OCTADECANAMIDE, 111-57-9 1-5*
N-(2-HYDROXYETHYL)-
PALMIDROL 544-31-0 1-5*
SODIUM CARBOXYMETHYL CELLULOSE 9004-32-4 1-5*
SODIUM HYDROSULFITE 7775-14-6 10-30*
SODIUM LAURYL SULFATE 151-21-3 5-10*
ALL CONCENTRATIONS ARE IN PERCENT BY WEIGHT UNLESS INGREDIENT IS A GAS. GAS
CONCENTRATIONS ARE IN PERCENT BY VOLUME.
COMPOSITION COMMENTS:
US GHS:
THE EXACT PERCENTAGE (CONCENTRATION) OF COMPOSITION HAS BEEN WITHHELD AS A
TRADE SECRET IN ACCORDANCE WITH PARAGRAPH (I) OF SUBSECTION 1910.1200.
*CANADA GHS:
THE EXACT PERCENTAGE (CONCENTRATION) OF COMPOSITION HAS BEEN WITHHELD AS A
TRADE SECRET.
| 4. FIRST AID MEASURES | |
INHALATION:
IF SYMPTOMS DEVELOP MOVE VICTIM TO FRESH AIR. IF SYMPTOMS PERSIST, OBTAIN
MEDICAL ATTENTION.
SKIN CONTACT:
IF ON SKIN:
WASH WITH PLENTY OF WATER. SPECIFIC TREATMENT (SEE INFORMATION ON THIS
LABEL). TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
IF SKIN IRRITATION OCCURS: GET MEDICAL ATTENTION.
EYE CONTACT:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING. IMMEDIATELY CALL A POISON CENTER
OR DOCTOR.
INGESTION:
RINSE MOUTH. DO NOT INDUCE VOMITING. IF VOMITING OCCURS NATURALLY, HAVE
VICTIM LEAN FORWARD TO REDUCE RISK OF ASPIRATION. NEVER GIVE ANYTHING BY
MOUTH IF VICTIM IS UNCONSCIOUS OR IS CONVULSING. OBTAIN MEDICAL ATTENTION.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
SEVERE EYE IRRITATION. SYMPTOMS MAY INCLUDE STINGING, TEARING, REDNESS,
SWELLING, AND BLURRED VISION. PERMANENT EYE DAMAGE INCLUDING BLINDNESS
COULD RESULT. SKIN IRRITATION. MAY CAUSE REDNESS AND PAIN.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
PROVIDE GENERAL SUPPORTIVE MEASURES AND TREAT SYMPTOMATICALLY. SYMPTOMS MAY
BE DELAYED.
GENERAL INFORMATION:
IF EXPOSED OR CONCERNED:
GET MEDICAL ADVICE/ATTENTION. IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE (SHOW
THE LABEL WHERE POSSIBLE). ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE
MATERIAL(S) INVOLVED AND TAKE PRECAUTIONS TO PROTECT THEMSELVES. SHOW THIS
SAFETY DATA SHEET TO THE DOCTOR IN ATTENDANCE. AVOID CONTACT WITH EYES AND
SKIN. KEEP OUT OF REACH OF CHILDREN.
| 5. FIRE FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
WATER FOG. FOAM. DRY CHEMICAL POWDER. CARBON DIOXIDE.
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE WATER JET AS AN EXTINGUISHER, AS THIS WILL SPREAD THE FIRE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
DURING FIRE, GASES HAZARDOUS TO HEALTH MAY BE FORMED.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING MUST BE
WORN IN CASE OF FIRE.
FIRE-FIGHTING EQUIPMENT/INSTRUCTIONS:
USE WATER SPRAY TO COOL UNOPENED CONTAINERS.
SPECIFIC METHODS:
USE STANDARD FIREFIGHTING PROCEDURES AND CONSIDER THE HAZARDS OF OTHER
INVOLVED MATERIALS.
GENERAL FIRE HAZARDS: NO UNUSUAL FIRE OR EXPLOSION HAZARDS NOTED.
HAZARDOUS COMBUSTION PRODUCTS:
MAY INCLUDE AND ARE NOT LIMITED TO:
OXIDES OF CARBON. OXIDES OF SULFUR. HYDROGEN SULFIDE.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
KEEP UNNECESSARY PERSONNEL AWAY. KEEP PEOPLE AWAY FROM AND UPWIND OF
SPILL/LEAK. WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND CLOTHING DURING
CLEAN-UP. DO NOT TOUCH DAMAGED CONTAINERS OR SPILLED MATERIAL UNLESS
WEARING APPROPRIATE PROTECTIVE CLOTHING. ENSURE ADEQUATE VENTILATION. LOCAL
AUTHORITIES SHOULD BE ADVISED IF SIGNIFICANT SPILLAGES CANNOT BE CONTAINED.
FOR PERSONAL PROTECTION, SEE SECTION 8 OF THE SDS.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
LARGE SPILLS:
STOP THE FLOW OF MATERIAL, IF THIS IS WITHOUT RISK. DIKE THE SPILLED
MATERIAL, WHERE THIS IS POSSIBLE. COVER WITH PLASTIC SHEET TO PREVENT
SPREADING. ABSORB IN VERMICULITE, DRY SAND OR EARTH AND PLACE INTO
CONTAINERS. FOLLOWING PRODUCT RECOVERY, FLUSH AREA WITH WATER.
SMALL SPILLS:
WIPE UP WITH ABSORBENT MATERIAL (E.G. CLOTH, FLEECE). CLEAN SURFACE
THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION.
NEVER RETURN SPILLS TO ORIGINAL CONTAINERS FOR RE-USE. FOR WASTE DISPOSAL,
SEE SECTION 13 OF THE SDS.
ENVIRONMENTAL PRECAUTIONS:
AVOID DISCHARGE INTO DRAINS, WATER COURSES OR ONTO THE GROUND. DO NOT
DISCHARGE INTO LAKES, STREAMS, PONDS OR PUBLIC WATERS.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. DO NOT GET THIS MATERIAL IN
CONTACT WITH EYES. AVOID CONTACT WITH EYES, SKIN, AND CLOTHING. PREGNANT OR
BREASTFEEDING WOMEN MUST NOT HANDLE THIS PRODUCT. PROVIDE ADEQUATE
VENTILATION. AVOID PROLONGED EXPOSURE. WEAR APPROPRIATE PERSONAL PROTECTIVE
EQUIPMENT. WASH THOROUGHLY AFTER HANDLING. USE GOOD INDUSTRIAL HYGIENE
PRACTICES IN HANDLING THIS MATERIAL. WHEN USING DO NOT EAT OR DRINK.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE LOCKED UP. STORE IN ORIGINAL TIGHTLY CLOSED CONTAINER. STORE AWAY
FROM INCOMPATIBLE MATERIALS (SEE SECTION 10 OF THE SDS). KEEP OUT OF REACH
OF CHILDREN.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE LIMITS:
CANADA. ALBERTA OELS (OCCUPATIONAL HEALTH & SAFETY CODE, SCHEDULE 1, TABLE
2):
COMPONENTS TYPE VALUE
METHANOL (CAS 67-56-1) STEL 328 MG/M3
250 PPM
TWA 262 MG/M3
200 PPM
MONOETHANOLAMINE (CAS STEL 15 MG/M3
141-43-5) 6 PPM
TWA 7.5 MG/M3
3 PPM
CANADA. BRITISH COLUMBIA OELS. (OCCUPATIONAL EXPOSURE LIMITS FOR CHEMICAL
SUBSTANCES, OCCUPATIONAL HEALTH AND SAFETY REGULATION 296/97, AS AMENDED):
COMPONENTS TYPE VALUE
METHANOL (CAS 67-56-1) STEL 250 PPM
TWA 200 PPM
MONOETHANOLAMINE (CAS STEL 6 PPM
141-43-5) TWA 3 PPM
CANADA. MANITOBA OELS (REG. 217/2006, THE WORKPLACE SAFETY AND HEALTH ACT):
COMPONENTS TYPE VALUE
METHANOL (CAS 67-56-1) STEL 250 PPM
TWA 200 PPM
MONOETHANOLAMINE (CAS STEL 6 PPM
141-43-5) TWA 3 PPM
CANADA. ONTARIO OELS. (CONTROL OF EXPOSURE TO BIOLOGICAL OR CHEMICAL
AGENTS):
COMPONENTS TYPE VALUE
METHANOL (CAS 67-56-1) STEL 250 PPM
TWA 200 PPM
MONOETHANOLAMINE (CAS STEL 6 PPM
141-43-5) TWA 3 PPM
CANADA. QUEBEC OELS. (MINISTRY OF LABOR - REGULATION RESPECTING THE QUALITY
OF THE WORK ENVIRONMENT):
COMPONENTS TYPE VALUE
METHANOL (CAS 67-56-1) STEL 328 MG/M3
250 PPM
TWA 262 MG/M3
200 PPM
MONOETHANOLAMINE (CAS STEL 15 MG/M3
141-43-5) 6 PPM
TWA 7.5 MG/M3
3 PPM
US. OSHA TABLE Z-1 LIMITS FOR AIR CONTAMINANTS (29 CFR 1910.1000):
COMPONENTS TYPE VALUE
METHANOL (CAS 67-56-1) PEL 260 MG/M3
200 PPM
MONOETHANOLAMINE (CAS PEL 6 MG/M3
141-43-5) 3 PPM
US. ACGIH THRESHOLD LIMIT VALUES:
COMPONENTS TYPE VALUE
METHANOL (CAS 67-56-1) STEL 250 PPM
TWA 200 PPM
MONOETHANOLAMINE (CAS STEL 6 PPM
141-43-5) TWA 3 PPM
US. NIOSH: POCKET GUIDE TO CHEMICAL HAZARDS
COMPONENTS TYPE VALUE
METHANOL (CAS 67-56-1) STEL 325 MG/M3
250 PPM
TWA 260 MG/M3
200 PPM
MONOETHANOLAMINE (CAS STEL 15 MG/M3
141-43-5) 6 PPM
TWA 8 MG/M3
3 PPM
BIOLOGICAL LIMIT VALUES:
ACGIH BIOLOGICAL EXPOSURE INDICES:
COMPONENTS VALUE DETERMINANT SPECIMEN SAMPLING TIME
METHANOL (CAS 67-56-1) 15 MG/L METHANOL URINE *
* - FOR SAMPLING DETAILS, PLEASE SEE THE SOURCE DOCUMENT.
EXPOSURE GUIDELINES:
CANADA - ALBERTA OELS: SKIN DESIGNATION
METHANOL (CAS 67-56-1): CAN BE ABSORBED THROUGH THE SKIN.
CANADA - BRITISH COLUMBIA OELS: SKIN DESIGNATION
METHANOL (CAS 67-56-1): CAN BE ABSORBED THROUGH THE SKIN.
CANADA - MANITOBA OELS: SKIN DESIGNATION
METHANOL (CAS 67-56-1): CAN BE ABSORBED THROUGH THE SKIN.
CANADA - ONTARIO OELS: SKIN DESIGNATION
METHANOL (CAS 67-56-1): CAN BE ABSORBED THROUGH THE SKIN.
CANADA - QUEBEC OELS: SKIN DESIGNATION
METHANOL (CAS 67-56-1): CAN BE ABSORBED THROUGH THE SKIN.
CANADA - SASKATCHEWAN OELS: SKIN DESIGNATION
METHANOL (CAS 67-56-1): CAN BE ABSORBED THROUGH THE SKIN.
US ACGIH THRESHOLD LIMIT VALUES: SKIN DESIGNATION
METHANOL (CAS 67-56-1): CAN BE ABSORBED THROUGH THE SKIN.
US. NIOSH:
POCKET GUIDE TO CHEMICAL HAZARDS:
METHANOL (CAS 67-56-1): CAN BE ABSORBED THROUGH THE SKIN.
APPROPRIATE ENGINEERING CONTROLS:
GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER HOUR) SHOULD BE
USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS. IF APPLICABLE, USE
PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO MAINTAIN AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. IF
EXPOSURE LIMITS HAVE NOT BEEN ESTABLISHED, MAINTAIN AIRBORNE LEVELS TO AN
ACCEPTABLE LEVEL.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION: WEAR SAFETY GLASSES WITH SIDE SHIELDS.
SKIN PROTECTION:
HAND PROTECTION:
IMPERVIOUS GLOVES. CONFIRM WITH REPUTABLE SUPPLIER FIRST.
OTHER:
WEAR APPROPRIATE CHEMICAL RESISTANT CLOTHING. USE OF AN IMPERVIOUS APRON IS
RECOMMENDED. AS REQUIRED BY EMPLOYER CODE.
RESPIRATORY PROTECTION:
WHERE EXPOSURE GUIDELINE LEVELS MAY BE EXCEEDED, USE AN APPROVED NIOSH
RESPIRATOR. RESPIRATOR SHOULD BE SELECTED BY AND USED UNDER THE DIRECTION
OF A TRAINED HEALTH AND SAFETY PROFESSIONAL FOLLOWING REQUIREMENTS FOUND IN
OSHA'S RESPIRATOR STANDARD (29 CFR 1910.134), CAN/CSA-Z94.4 AND ANSI'S
STANDARD FOR RESPIRATORY PROTECTION (Z88.2).
THERMAL HAZARDS: NOT APPLICABLE.
GENERAL HYGIENE CONSIDERATIONS:
ALWAYS OBSERVE GOOD PERSONAL HYGIENE MEASURES, SUCH AS WASHING AFTER
HANDLING THE MATERIAL AND BEFORE EATING, DRINKING, AND/OR SMOKING.
ROUTINELY WASH WORK CLOTHING AND PROTECTIVE EQUIPMENT TO REMOVE
CONTAMINANTS. WHEN USING DO NOT EAT OR DRINK.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
TABLET.
CIRCULAR, WRAPPED IN A CLEAR FILM
PHYSICAL STATE: SOLID.
FORM: SOLID.
COLOR: NOT AVAILABLE.
ODOR: NOT AVAILABLE.
ODOR THRESHOLD: NOT AVAILABLE.
PH: 3 - 7 (1% SOLUTION)
MELTING POINT/FREEZING POINT: NOT AVAILABLE.
INITIAL BOILING POINT AND BOILING RANGE: NOT AVAILABLE.
POUR POINT: NOT AVAILABLE.
SPECIFIC GRAVITY: NOT AVAILABLE.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
FLASH POINT: NOT AVAILABLE.
EVAPORATION RATE: NOT AVAILABLE.
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE.
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS:
FLAMMABILITY LIMIT - LOWER (%): NOT AVAILABLE.
FLAMMABILITY LIMIT - UPPER (%): NOT AVAILABLE.
EXPLOSIVE LIMIT - LOWER (%): NOT AVAILABLE.
EXPLOSIVE LIMIT - UPPER (%): NOT AVAILABLE.
VAPOR PRESSURE: NOT AVAILABLE.
VAPOR DENSITY: NOT AVAILABLE.
RELATIVE DENSITY: NOT AVAILABLE.
SOLUBILITY(IES): NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY: NOT AVAILABLE.
OTHER INFORMATION:
EXPLOSIVE PROPERTIES: NOT EXPLOSIVE.
OXIDIZING PROPERTIES: NOT OXIDIZING.
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: THIS PRODUCT MAY REACT WITH STRONG OXIDIZING AGENTS.
POSSIBILITY OF HAZARDOUS REACTIONS:
NO DANGEROUS REACTION KNOWN UNDER CONDITIONS OF NORMAL USE.
CHEMICAL STABILITY: MATERIAL IS STABLE UNDER NORMAL CONDITIONS.
CONDITIONS TO AVOID: DO NOT MIX WITH OTHER CHEMICALS.
INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS.
HAZARDOUS DECOMPOSITION PRODUCTS:
MAY INCLUDE AND ARE NOT LIMITED TO:
OXIDES OF CARBON. OXIDES OF SULFUR. HYDROGEN SULPHIDE.
| 11. TOXICOLOGICAL INFORMATION | |
ROUTES OF EXPOSURE: EYE, SKIN CONTACT, INHALATION, INGESTION.
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INGESTION: MAY CAUSE STOMACH DISTRESS, NAUSEA OR VOMITING.
INHALATION: PROLONGED INHALATION MAY BE HARMFUL.
SKIN CONTACT: CAUSES SKIN IRRITATION.
EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
SEVERE EYE IRRITATION. SYMPTOMS MAY INCLUDE STINGING, TEARING, REDNESS,
SWELLING, AND BLURRED VISION. PERMANENT EYE DAMAGE INCLUDING BLINDNESS
COULD RESULT. SKIN IRRITATION. MAY CAUSE REDNESS AND PAIN.
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
COMPONENTS SPECIES TEST RESULTS
BICYCLO[2.2.1]HEPTAN-2-OL, 1,7,7-TRIMETHYL-, ACETATE, EXO- (CAS 125-12-2):
ACUTE:
DERMAL:
LD50 RABBIT 20000 MG/KG, ECHA
INHALATION:
LC50 NOT AVAILABLE
ORAL:
LD50 MOUSE 9000 MG/KG
RAT >10000 MG/KG, ECHA
DODECANAMIDE, N-(2-HYDROXYETHYL)- (CAS 142-78-9):
ACUTE:
DERMAL:
LD50 NOT AVAILABLE
INHALATION:
LC50 NOT AVAILABLE
ORAL:
LD50 NOT AVAILABLE
METHANOL (CAS 67-56-1):
ACUTE:
DERMAL:
LD50 RABBIT 15800 - 20000 MG/KG, SIDS
REPORT/HSDB
RAT >450000 MG/KG, SIDS REPORT/HSDB
INHALATION:
LC50 CAT 85.4 MG/L/4H, HSDB
85.4 MG/L, 4.5 HOURS, ECHA/HSDB
43.7 MG/L, 6 HOURS, ECHA
MOUSE 79.4 MG/L, 134 MINUTES, ECHA
RAT >115.9 MG/L, 4 HOURS, ECHA
64000 PPM, 4 HOURS, HSDB
130.7 MG/L, 4 HOURS, ECHA
128.2 MG/L, 4 HOURS, ECHA
92.6 MG/L, 6 HOURS, ECHA
87.5 MG/L, 6 HOURS, ECHA
83.2 - 128.8 MG/L/4H, SIDS
REPORT/HSDB
82.1 MG/L, 6 HOURS, ECHA
ORAL:
LD50 DOG 8000 MG/KG, HSDB
HUMAN 143 - 300 MG/KG, HSNO
CCID/SIGMA-ALDRICH
MONKEY 7000 - 9000 MG/KG, ECHA
6000 MG/KG, ECHA
3000 MG/KG, RTECS
2000 MG/KG, HSDB
MOUSE 7300 MG/KG, HSDB
PIG >5000 MG/KG, ECHA
RABBIT 14200 - 14400 MG/KG, RTECS
14.4 G/KG, HSDB
RAT 1187 - 2769 MG/KG
790 - 13000 MG/KG, SIDS REPORT/HSDB
5628 MG/KG, HSDB
MONOETHANOLAMINE (CAS 141-43-5):
ACUTE:
DERMAL:
LD50 RABBIT 2881 MG/KG, 24 HOURS, ECHA
2504 MG/KG, 24 HOURS
1018 MG/KG, HMIRA
1000 MG/KG, CCOHS
2.5 - 2.8 ML/KG, 24 HOURS
INHALATION:
LC50 MOUSE 1210 MG/M3, 4 HOURS, CCOHS
484 PPM, 4 HOURS, CCOHS
1.2 MG/L, 4 HOURS, CCOHS
RAT >1.3 MG/L, 6 HOURS, ECHA
ORAL:
LD50 GUINEA PIG 620 MG/KG, HSDB, CCOHS
MOUSE 1475 MG/KG, CCOHS
700 MG/KG, SAX, CCOHS
RAT 1970 MG/KG, CCOHS
1720 MG/KG, CCOHS, SIGMA
1515 MG/KG, ECHA
1089 MG/KG, ECHA
1.2 ML/KG, ECHA
1.1 ML/KG, ECHA
N-(2-HYDROXYETHYL)MYRISTAMIDE (CAS 142-58-5):
ACUTE:
DERMAL:
LD50 NOT AVAILABLE
INHALATION:
LC50 NOT AVAILABLE
ORAL:
LD50 NOT AVAILABLE
N-(2-HYDROXYETHYL)OLEAMIDE (CAS 111-58-0):
ACUTE:
DERMAL:
LD50 NOT AVAILABLE
INHALATION:
LC50 NOT AVAILABLE
ORAL:
LD50 NOT AVAILABLE
OCTADECANAMIDE, N-(2-HYDROXYETHYL)- (CAS 111-57-9):
ACUTE:
DERMAL:
LD50 RABBIT >2000 MG/KG, 24 HOURS, ECHA
ORAL:
LD50 RAT >3000 MG/KG, ECHA
>2000 MG/KG, ECHA
PALMIDROL (CAS 544-31-0):
ACUTE:
DERMAL:
LD50 NOT AVAILABLE
INHALATION:
LC50 NOT AVAILABLE
ORAL:
LD50 NOT AVAILABLE
SODIUM CARBOXYMETHYL CELLULOSE (CAS 9004-32-4):
ACUTE:
DERMAL:
LD50 RABBIT >2000 MG/KG, SIGMA ALDRICH
INHALATION:
LC50 NOT AVAILABLE
ORAL:
LD50 GUINEA PIG 16000 MG/KG, FOOD RESEARCH. VOL.
13, PG. 29, 1948.
RAT 27000 MG/KG, SIGMA ALDRICH
SODIUM HYDROSULFITE (CAS 7775-14-6):
ACUTE:
DERMAL:
LD50 RAT >2000 MG/KG, 24 HOURS, ECHA
INHALATION:
LC50 RAT >22 MG/L, 4 HOURS, ECHA
>5.5 MG/L, 4 HOURS, ECHA
ORAL:
LD50 RAT 2500 MG/KG, ECHA
SODIUM LAURYL SULFATE (CAS 151-21-3):
ACUTE:
DERMAL:
LD50 RABBIT >2000 MG/KG, 24 HOURS, ECHA
>500 MG/KG, 24 HOURS, ECHA
RAT >2000 MG/KG, 24 HOURS, ECHA
INHALATION:
LC50 NOT AVAILABLE
ORAL:
LD50 RAT >5000 MG/KG, ECHA
>1500 MG/KG, ECHA
1427 MG/KG, ECHA
1288 MG/KG, HSDB
1200 MG/KG, ECHA
977 MG/KG, ECHA
SKIN CORROSION/IRRITATION: CAUSES SKIN IRRITATION.
EXPOSURE MINUTES: NOT AVAILABLE.
ERYTHEMA VALUE: NOT AVAILABLE.
OEDEMA VALUE: NOT AVAILABLE.
SERIOUS EYE DAMAGE/EYE IRRITATION: CAUSES SERIOUS EYE DAMAGE.
CORNEAL OPACITY VALUE: NOT AVAILABLE.
IRIS LESION VALUE: NOT AVAILABLE.
CONJUNCTIVAL REDDENING VALUE: NOT AVAILABLE.
CONJUNCTIVAL OEDEMA VALUE: NOT AVAILABLE.
RECOVER DAYS: NOT AVAILABLE.
RESPIRATORY OR SKIN SENSITIZATION:
CANADA - ALBERTA OELS: IRRITANT
MONOETHANOLAMINE (CAS 141-43-5): IRRITANT
RESPIRATORY SENSITIZATION: NOT A RESPIRATORY SENSITIZER.
SKIN SENSITIZATION:
THIS PRODUCT IS NOT EXPECTED TO CAUSE SKIN SENSITIZATION.
MUTAGENICITY:
NO DATA AVAILABLE TO INDICATE PRODUCT OR ANY COMPONENTS PRESENT AT GREATER
THAN 0.1% ARE MUTAGENIC OR GENOTOXIC.
CARCINOGENICITY: SEE BELOW.
US. OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1050):
NOT LISTED.
REPRODUCTIVE TOXICITY: MAY DAMAGE FERTILITY OR THE UNBORN CHILD.
TERATOGENICITY:
METHANOL HAS PRODUCED TERATOGENIC EFFECTS IN MICE EXPOSED BY INHALATION TO
HIGH CONCENTRATIONS THAT DID NOT PRODUCE SIGNIFICANT MATERNAL TOXICITY.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: NOT CLASSIFIED.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NOT CLASSIFIED.
ASPIRATION HAZARD: NOT AN ASPIRATION HAZARD.
CHRONIC EFFECTS: PROLONGED INHALATION MAY BE HARMFUL.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY: SEE BELOW
ECOTOXICOLOGICAL DATA:
COMPONENTS SPECIES TEST RESULTS
METHANOL (CAS 67-56-1):
AQUATIC:
CRUSTACEA EC50 WATER FLEA (DAPHNIA MAGNA) >10000 MG/L, 48
HOURS
FISH LC50 FATHEAD MINNOW (PIMEPHALES PROMELAS) >100 MG/L, 96 HOURS
MONOETHANOLAMINE (CAS 141-43-5):
ALGAE IC50 ALGAE 15 MG/L, 72 HOURS
CRUSTACEA EC50 DAPHNIA 65 MG/L, 48 HOURS
AQUATIC:
FISH LC50 RAINBOW TROUT, DONALDSON TROUT 114 - 196 MG/L, 96
(ONCORHYNCHUS MYKISS) HOURS
SODIUM CARBOXYMETHYL CELLULOSE (CAS 9004-32-4):
AQUATIC:
CRUSTACEA EC50 WATER FLEA (CERIODAPHNIA DUBIA) 46.04 - 165.37
MG/L, 48 HOURS
FISH LC50 CRUCIAN CARP (CARASSIUS CARASSIUS) >20000 MG/L, 96
HOURS
SODIUM HYDROSULFITE (CAS 7775-14-6):
ALGAE IC50 ALGAE 120 MG/L, 72 HOURS
CRUSTACEA EC50 DAPHNIA 98 MG/L, 48 HOURS
SODIUM LAURYL SULFATE (CAS 151-21-3):
ALGAE IC50 ALGAE 53 MG/L, 72 HOURS
CRUSTACEA EC50 DAPHNIA 1.8 MG/L, 48 HOURS
AQUATIC:
FISH LC50 CARP, HAWK FISH (CIRRHINUS MRIGALA) 1.36 MG/L, 96 HOURS
PERSISTENCE AND DEGRADABILITY:
NO DATA IS AVAILABLE ON THE DEGRADABILITY OF THIS PRODUCT.
BIOACCUMULATIVE POTENTIAL:
MOBILITY IN SOIL: NO DATA AVAILABLE.
MOBILITY IN GENERAL: NOT AVAILABLE.
OTHER ADVERSE EFFECTS:
NO OTHER ADVERSE ENVIRONMENTAL EFFECTS (E.G. OZONE DEPLETION, PHOTOCHEMICAL
OZONE CREATION POTENTIAL, ENDOCRINE DISRUPTION, GLOBAL WARMING POTENTIAL)
ARE EXPECTED FROM THIS COMPONENT.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL INSTRUCTIONS:
COLLECT AND RECLAIM OR DISPOSE IN SEALED CONTAINERS AT LICENSED WASTE
DISPOSAL SITE. DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
LOCAL DISPOSAL REGULATIONS:
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS.
HAZARDOUS WASTE CODE:
THE WASTE CODE SHOULD BE ASSIGNED IN DISCUSSION BETWEEN THE USER, THE
PRODUCER AND THE WASTE DISPOSAL COMPANY.
WASTE FROM RESIDUES / UNUSED PRODUCTS:
DISPOSE OF IN ACCORDANCE WITH LOCAL REGULATIONS. EMPTY CONTAINERS OR LINERS
MAY RETAIN SOME PRODUCT RESIDUES. THIS MATERIAL AND ITS CONTAINER MUST BE
DISPOSED OF IN A SAFE MANNER (SEE: DISPOSAL INSTRUCTIONS).
CONTAMINATED PACKAGING:
SINCE EMPTIED CONTAINERS MAY RETAIN PRODUCT RESIDUE, FOLLOW LABEL WARNINGS
EVEN AFTER CONTAINER IS EMPTIED. EMPTY CONTAINERS SHOULD BE TAKEN TO AN
APPROVED WASTE HANDLING SITE FOR RECYCLING OR DISPOSAL.
| 14. TRANSPORT INFORMATION | |
TRANSPORT OF DANGEROUS GOODS (TDG) PROOF OF CLASSIFICATION:
CLASSIFICATION METHOD:
CLASSIFIED AS PER PART 2, SECTIONS 2.1 - 2.8 OF THE TRANSPORTATION OF
DANGEROUS GOODS REGULATIONS. IF APPLICABLE, THE TECHNICAL NAME AND THE
CLASSIFICATION OF THE PRODUCT WILL APPEAR BELOW.
GENERAL:
CANADA:
MARINE POLLUTANTS EXEMPTION. 1.45.1. : PART 3, DOCUMENTATION, AND PART 4,
DANGEROUS GOODS SAFETY MARKS, DO NOT APPLY TO SUBSTANCES THAT ARE
CLASSIFIED AS MARINE POLLUTANTS IN ACCORDANCE WITH SECTION 2.43 OF PART 2,
CLASSIFICATION, IF THEY ARE IN TRANSPORT SOLELY ON LAND BY ROAD VEHICLE OR
RAILWAY VEHICLE. HOWEVER, SUBSTANCES MAY BE IDENTIFIED AS MARINE POLLUTANTS
ON A SHIPPING DOCUMENT AND THE REQUIRED DANGEROUS GOODS SAFETY MARKS MAY BE
DISPLAYED WHEN THEY ARE IN TRANSPORT BY ROAD OR RAILWAY VEHICLE.
(SOR/2008-34, S. 23)
US:
CFR 171.4: THE REQUIREMENTS OF THIS SUBCHAPTER SPECIFIC TO MARINE
POLLUTANTS DOES NOT APPLY TO NON-BULK PACKAGINGS TRANSPORTED BY MOTOR
VEHICLE, RAIL CAR OR AIRCRAFT, EXCEPT WHEN ALL OR PART OF THE
TRANSPORTATION IS BY VESSEL.
U.S. DEPARTMENT OF TRANSPORTATION (DOT): NOT REGULATED AS DANGEROUS GOODS.
TRANSPORTATION OF DANGEROUS GOODS (TDG - CANADA):
NOT REGULATED AS DANGEROUS GOODS.
| 15. REGULATORY INFORMATION | |
CANADIAN FEDERAL REGULATIONS:
THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF
THE HPR AND THE SDS CONTAINS ALL THE INFORMATION REQUIRED BY THE HPR.
CANADA NPRI VOCS WITH ADDITIONAL REPORTING REQUIREMENTS: MASS REPORTING
THRESHOLD/IDENTIFICATION NUMBER
METHANOL (CAS 67-56-1): 1 TONNES
EXPORT CONTROL LIST (CEPA 1999, SCHEDULE 3): NOT LISTED.
GREENHOUSE GASES: NOT LISTED.
PRECURSOR CONTROL REGULATIONS: NOT REGULATED.
WHMIS 2015 EXEMPTIONS: NOT APPLICABLE
US FEDERAL REGULATIONS:
THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.
TSCA SECTION 12(B) EXPORT NOTIFICATION (40 CFR 707, SUBPT. D):
NOT REGULATED.
CERCLA HAZARDOUS SUBSTANCE LIST (40 CFR 302.4):
METHANOL (CAS 67-56-1): LISTED.
US. OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1050):
NOT LISTED.
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA):
HAZARD CATEGORIES:
IMMEDIATE HAZARD: YES
DELAYED HAZARD: YES
FIRE HAZARD: NO
PRESSURE HAZARD: NO
REACTIVITY HAZARD: NO
SARA 302 EXTREMELY HAZARDOUS SUBSTANCE: NO
SARA 311/312 HAZARDOUS CHEMICAL: NO
SARA 313 (TRI REPORTING):
CHEMICAL NAME CAS NUMBER % BY WT.
METHANOL 67-56-1 0.1-1*
OTHER FEDERAL REGULATIONS:
CLEAN AIR ACT (CAA) SECTION 112 HAZARDOUS AIR POLLUTANTS (HAPS) LIST:
METHANOL (CAS 67-56-1)
CLEAN AIR ACT (CAA) SECTION 112(R) ACCIDENTAL RELEASE PREVENTION (40 CFR
68.130): NOT REGULATED.
US STATE REGULATIONS: SEE BELOW
US - CALIFORNIA HAZARDOUS SUBSTANCES (DIRECTOR'S): LISTED SUBSTANCE
METHANOL (CAS 67-56-1): LISTED.
MONOETHANOLAMINE (CAS 141-43-5): LISTED.
US - ILLINOIS CHEMICAL SAFETY ACT: LISTED SUBSTANCE
METHANOL (CAS 67-56-1)
US - LOUISIANA SPILL REPORTING: LISTED SUBSTANCE
METHANOL (CAS 67-56-1): LISTED.
US - MINNESOTA HAZ SUBS: LISTED SUBSTANCE
METHANOL (CAS 67-56-1): LISTED.
MONOETHANOLAMINE (CAS 141-43-5): LISTED.
US - NEW JERSEY RTK - SUBSTANCES: LISTED SUBSTANCE
METHANOL (CAS 67-56-1)
MONOETHANOLAMINE (CAS 141-43-5)
SODIUM HYDROSULFITE (CAS 7775-14-6)
US - TEXAS EFFECTS SCREENING LEVELS: LISTED SUBSTANCE
BICYCLO[2.2.1]HEPTAN-2-OL, 1,7,7-TRIMETHYL-, ACETATE, EXO-
(CAS 125-12-2): LISTED.
DODECANAMIDE, N-(2-HYDROXYETHYL)- (CAS 142-78-9): LISTED.
METHANOL (CAS 67-56-1): LISTED.
MONOETHANOLAMINE (CAS 141-43-5): LISTED.
OCTADECANAMIDE, N-(2-HYDROXYETHYL)- (CAS 111-57-9): LISTED.
PALMIDROL (CAS 544-31-0): LISTED.
SODIUM CARBOXYMETHYL CELLULOSE (CAS 9004-32-4): LISTED.
SODIUM HYDROSULFITE (CAS 7775-14-6): LISTED.
SODIUM LAURYL SULFATE (CAS 151-21-3): LISTED.
US. MASSACHUSETTS RTK - SUBSTANCE LIST:
METHANOL (CAS 67-56-1)
MONOETHANOLAMINE (CAS 141-43-5)
SODIUM HYDROSULFITE (CAS 7775-14-6)
US. NEW JERSEY WORKER AND COMMUNITY RIGHT-TO-KNOW ACT:
METHANOL (CAS 67-56-1)
US. PENNSYLVANIA WORKER AND COMMUNITY RIGHT-TO-KNOW LAW:
METHANOL (CAS 67-56-1)
MONOETHANOLAMINE (CAS 141-43-5)
SODIUM HYDROSULFITE (CAS 7775-14-6)
US. RHODE ISLAND RTK:
METHANOL (CAS 67-56-1)
MONOETHANOLAMINE (CAS 141-43-5)
SODIUM HYDROSULFITE (CAS 7775-14-6)
US. CALIFORNIA PROPOSITION 65:
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986
(PROPOSITION 65):
THIS MATERIAL IS NOT KNOWN TO CONTAIN ANY CHEMICALS CURRENTLY LISTED AS
CARCINOGENS OR REPRODUCTIVE TOXINS.
INVENTORY STATUS:
COUNTRY(S) OR REGION INVENTORY NAME ON INVENTORY
(YES/NO)*
CANADA DOMESTIC SUBSTANCES LIST (DSL) NO
CANADA NON-DOMESTIC SUBSTANCES LIST (NDSL) YES
UNITED STATES & TOXIC SUBSTANCES CONTROL ACT (TSCA) YES
PUERTO RICO INVENTORY
*A "YES" INDICATES THAT ALL COMPONENTS OF THIS PRODUCT COMPLY WITH THE
INVENTORY REQUIREMENTS ADMINISTERED BY THE GOVERNING COUNTRY(S)
| 16. OTHER INFORMATION | |
HEALTH 2*
FLAMMABILITY 1
PHYSICAL HAZARD 1
PERSONAL PROTECTION X
NFPA:
2
1
1
LEGEND:
SEVERE 4
SERIOUS 3
MODERATE 2
SLIGHT 1
MINIMAL 0
DISCLAIMER:
THE DATA CONTAINED IN THIS MATERIAL SAFETY DATA SHEET WAS OBTAINED FROM
SOURCES THAT WERE TECHNICALLY ACCURATE, RELIABLE, AND STATE OF THE ART WHEN
THIS DOCUMENT WAS PREPARED. IF DATA WAS UNAVAILABLE TO COMPLETE CERTAIN
SECTIONS, THE ABSENCE OF THAT DATA IS IDENTIFIED IN THIS DOCUMENT. BECAUSE
THE SUPPLIER CANNOT KNOW THE EXACT CIRCUMSTANCES DURING ACTUAL USE OF THIS
PRODUCT, OTHER HAZARDS, EXPOSURE SCENARIOS, DISPOSAL CONSIDERATIONS, AND
REGULATIONS MAY APPLY AND IT IS THE RESPONSIBILITY OF THE USER TO READ AND
UNDERSTAND THE PRODUCT LABEL AND THIS DOCUMENT BEFORE USE. DO NOT USE THE
PRODUCT FOR PURPOSES OTHER THAN THOSE STATED IN SECTION 1.
ISSUE DATE: 03-DECEMBER-2018
VERSION #: 03
EFFECTIVE DATE: 29-MARCH-2018
PREPARED BY: DELL TECH LABORATORIES, LTD.
PHONE: (519) 858-5021
OTHER INFORMATION:
FOR AN UPDATED SDS, PLEASE CONTACT THE SUPPLIER/MANUFACTURER LISTED IN
SECTION 1 OF THIS DOCUMENT.
REDBOOK REVISION # 15, 3/13/18
#15661