| Common Name: | AXXE BROAD SPECTRUM HERBICIDE |
| Manufacturer: | BIOSAFE SYSTEMS |
| SDS Revision Date: | 1/31/2019 |
| SDS Format: | GHS-US |
| Item Number(s): | 787KJ3 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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BIOSAFE SYSTEMS(R*) LLC
SIMPLY SUSTAINABLE. ALWAYS EFFECTIVE.
SAFETY DATA SHEET (SDS)
AXXE(R*) BROAD SPECTRUM HERBICIDE
FORM #: SDS-035
REVISION DATE: 01/31/2019
REVISION #: 03
SUPERSEDES DATE: 08/22/2018
| SECTION 1: IDENTIFICATION |  |
PRODUCT NAME: AXXE(R*) BROAD SPECTRUM HERBICIDE
RECOMMENDED USE: NON-SELECTIVE HERBICIDE FOR COMMERCIAL USE.
USE RESTRICTIONS:
IT IS A VIOLATION OF FEDERAL LAW TO USE THIS PRODUCT IN A
MANNER INCONSISTENT WITH ITS LABELING.
MANUFACTURER:
BIOSAFE SYSTEMS, LLC
22 MEADOW STREET
EAST HARTFORD, CT 06108
TELEPHONE NUMBER: 1-888-273-3088
PRODUCT TYPE / DESCRIPTION: HERBICIDE
OTHER MEANS OF IDENTIFICATION: AMMONIUM NONANOATE SOLUTION
EPA REGISTRATION #: 70299-23
CANADA PMRA REGISTRATION #: 32719
EMERGENCY NUMBER: 1-800-424-9300 (CHEMTREC)
| SECTION 2: HAZARD IDENTIFICATION | |
GHS CLASSIFICATION:
SERIOUS EYE DAMAGE / IRRITATION: CATEGORY 2A
HAZARD STATEMENTS:
H319: CAUSES SERIOUS EYE IRRITATION.
PICTOGRAMS: EXCLAMATION MARK
SIGNAL WORD: WARNING
PRECAUTIONARY STATEMENTS:
GENERAL:
P101: IF MEDICAL ADVICE IS NEEDED, HAVE PRODUCT CONTAINER OR LABEL AT HAND.
P102: KEEP OUT OF REACH OF CHILDREN.
P103: READ LABEL BEFORE USE.
RESPONSE:
P301+P330+P331:
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING.
P303+P361+P353:
IF ON SKIN:
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
P304+P340:
IF INHALED: MOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
PREVENTION:
P264: WASH THOROUGHLY AFTER HANDLING.
P280: WEAR PROTECTIVE GLOVES, CLOTHING, EYE PROTECTION, FACE PROTECTION.
STORAGE / DISPOSAL:
P405: STORE LOCKED UP.
P501:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
| SECTION 3: COMPOSITION / INFORMATION ON INGREDIENTS | |
COMPONENTS CAS-NO % COMPOSITION (W/W)
AMMONIUM NONANOATE 63718-65-0 36.0 - 41.0%
OTHER PROPRIETARY INGREDIENTS 59.0 - 64.0%
| SECTION 4: FIRST-AID MEASURES | |
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER, OCCASIONALLY LIFTING THE UPPER
AND LOWER EYELIDS. CHECK FOR AND REMOVE ANY CONTACT LENSES. CONTINUE TO
RINSE FOR AT LEAST 10 MINUTES. GET MEDICAL ATTENTION.
SKIN CONTACT:
FLUSH CONTAMINATED SKIN WITH PLENTY OF WATER. REMOVE CONTAMINATED CLOTHING
AND SHOES. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. WASH CLOTHING BEFORE
REUSE. CLEAN SHOES THOROUGHLY BEFORE REUSE.
INGESTION:
WASH OUT MOUTH WITH WATER. REMOVE DENTURES IF ANY. REMOVE VICTIM TO FRESH
AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR BREATHING. IF MATERIAL
HAS BEEN SWALLOWED AND THE EXPOSED PERSON IS CONSCIOUS, GIVE SMALL
QUANTITIES OF WATER TO DRINK. STOP IF THE EXPOSED PERSON FEELS SICK AS
VOMITING MAY BE DANGEROUS. DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO
BY MEDICAL PERSONNEL. IF VOMITING OCCURS, THE HEAD SHOULD BE KEPT LOW SO
THAT VOMIT DOES NOT ENTER THE LUNGS. GET MEDICAL ATTENTION IF ADVERSE
HEALTH EFFECTS PERSIST OR ARE SEVERE. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON. IF UNCONSCIOUS, PLACE IN RECOVERY POSITION AND GET
MEDICAL ATTENTION IMMEDIATELY. MAINTAIN AN OPEN AIRWAY. LOOSEN TIGHT
CLOTHING SUCH AS A COLLAR, TIE, BELT OR WAISTBAND.
INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. IF NOT BREATHING, IF BREATHING IS IRREGULAR OR IF RESPIRATORY
ARREST OCCURS, PROVIDE ARTIFICIAL RESPIRATION OR OXYGEN BY TRAINED
PERSONNEL. IT MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE
MOUTH-TO-MOUTH RESUSCITATION. GET MEDICAL ATTENTION IF ADVERSE HEALTH
EFFECTS PERSIST OR ARE SEVERE. IF UNCONSCIOUS, PLACE IN RECOVERY POSITION
AND GET MEDICAL ATTENTION IMMEDIATELY. MAINTAIN AN OPEN AIRWAY. LOOSEN
TIGHT CLOTHING SUCH AS A COLLAR, TIE, BELT OR WAISTBAND. IN CASE OF
INHALATION OF DECOMPOSITION PRODUCTS IN A FIRE, SYMPTOMS MAY BE DELAYED.
THE EXPOSED PERSON MAY NEED TO BE KEPT UNDER MEDICAL SURVEILLANCE FOR 48
HOURS.
| SECTION 5: FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
USE ALCOHOL-RESISTANT FOAM, CARBON DIOXIDE, WATER OR DRY CHEMICAL SPRAY.
UNSUITABLE EXTINGUISHING MEDIA: NONE KNOWN.
COMBUSTION PRODUCTS: NONE KNOWN, NOT COMBUSTIBLE.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
IN A FIRE OR IF HEATED, A PRESSURE INCREASE WILL OCCUR AND THE CONTAINER
MAY BURST.
PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
DO NOT ENTER FIRE AREA WITHOUT PROPER PROTECTIVE EQUIPMENT, INCLUDING
RESPIRATORY PROTECTION.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS:
EVACUATE SURROUNDING AREAS. KEEP UNNECESSARY AND UNPROTECTED PERSONNEL FROM
ENTERING. DO NOT TOUCH OR WALK THROUGH SPILLED MATERIAL. AVOID BREATHING
VAPOR OR MIST. PROVIDE ADEQUATE VENTILATION.
EMERGENCY PROCEDURES:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. EVACUATE SURROUNDING AREAS. KEEP UNNECESSARY AND UNPROTECTED
PERSONNEL FROM ENTERING. DO NOT TOUCH OR WALK THROUGH SPILLED MATERIAL.
AVOID BREATHING VAPOR OR MIST. PROVIDE ADEQUATE VENTILATION. WEAR
APPROPRIATE RESPIRATOR WHEN VENTILATION IS INADEQUATE. PUT ON APPROPRIATE
PERSONAL PROTECTIVE EQUIPMENT.
ENVIRONMENTAL PRECAUTIONS:
AVOID DISPERSAL OF SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL,
WATERWAYS, DRAINS AND SEWERS. INFORM THE RELEVANT AUTHORITIES IF THE
PRODUCT HAS CAUSED ENVIRONMENTAL POLLUTION (SEWERS, WATERWAYS, SOIL OR
AIR).
METHODS AND MATERIAL FOR CONTAINMENT AND CLEAN-UP:
SMALL SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. DILUTE WITH
WATER AND MOP UP IF WATER-SOLUBLE. ALTERNATIVELY, OR IF WATER-INSOLUBLE,
ABSORB WITH AN INERT DRY MATERIAL AND PLACE IN AN APPROPRIATE WASTE
DISPOSAL CONTAINER. DISPOSE OF VIA A LICENSED WASTE DISPOSAL CONTRACTOR.
LARGE SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. APPROACH
RELEASE FROM UPWIND. PREVENT ENTRY INTO SEWERS, WATER COURSES, BASEMENTS OR
CONFINED AREAS. WASH SPILLAGES INTO AN EFFLUENT TREATMENT PLANT OR PROCEED
AS FOLLOWS. CONTAIN AND COLLECT SPILLAGE WITH NON-COMBUSTIBLE, ABSORBENT
MATERIAL E.G. SAND, EARTH, VERMICULITE OR DIATOMACEOUS EARTH AND PLACE IN
CONTAINER FOR DISPOSAL ACCORDING TO LOCAL REGULATIONS. DISPOSE OF VIA A
LICENSED WASTE DISPOSAL CONTRACTOR. CONTAMINATED ABSORBENT MATERIAL MAY
POSE THE SAME HAZARD AS THE SPILLED PRODUCT.
| SECTION 7: HANDLING AND STORAGE | |
HANDLING:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8). DO NOT
INGEST. AVOID CONTACT WITH EYES, SKIN AND CLOTHING. AVOID BREATHING VAPOR
OR MIST. KEEP IN THE ORIGINAL CONTAINER OR AN APPROVED ALTERNATIVE MADE
FROM A COMPATIBLE MATERIAL, KEPT TIGHTLY CLOSED WHEN NOT IN USE. EMPTY
CONTAINERS RETAIN PRODUCT RESIDUE AND CAN BE HAZARDOUS. DO NOT REUSE
CONTAINER.
STORAGE:
EATING, DRINKING AND SMOKING SHOULD BE PROHIBITED IN AREAS WHERE THIS
MATERIAL IS HANDLED, STORED AND PROCESSED. WORKERS SHOULD WASH HANDS AND
FACE BEFORE EATING, DRINKING AND SMOKING. REMOVE CONTAMINATED CLOTHING AND
PROTECTIVE EQUIPMENT BEFORE ENTERING EATING AREAS. SEE ALSO SECTION 8 FOR
ADDITIONAL INFORMATION ON HYGIENE MEASURES.
INCOMPATIBLE MATERIALS:
DO NOT STORE BELOW THE FOLLOWING TEMPERATURE:
0 DEG. C (32 DEG. F). STORE IN ACCORDANCE WITH LOCAL REGULATIONS. STORE IN
ORIGINAL CONTAINER PROTECTED FROM DIRECT SUNLIGHT IN A DRY, COOL AND
WELL-VENTILATED AREA, AWAY FROM INCOMPATIBLE MATERIALS (SEE SECTION 10) AND
FOOD AND DRINK. KEEP CONTAINER TIGHTLY CLOSED AND SEALED UNTIL READY FOR
USE. CONTAINERS THAT HAVE BEEN OPENED MUST BE CAREFULLY RESEALED AND KEPT
UPRIGHT TO PREVENT LEAKAGE. DO NOT STORE IN UNLABELED CONTAINERS. USE
APPROPRIATE CONTAINMENT TO AVOID ENVIRONMENTAL CONTAMINATION.
| SECTION 8: EXPOSURE CONTROLS / PERSONAL PROTECTION | |
COMPONENTS WITH WORKPLACE CONTROL PARAMETERS:
COMPONENT ACGIH NIOSH OSHA
AMMONIUM NONANOATE NOT APPLICABLE. NOT APPLICABLE. NOT APPLICABLE.
ENGINEERING CONTROLS:
GOOD GENERAL VENTILATION SHOULD BE SUFFICIENT TO CONTROL WORKER EXPOSURE TO
AIRBORNE CONTAMINANTS.
GENERAL HYGIENIC PRACTICES: DO NOT EAT, DRINK OR SMOKE DURING USE.
PERSONAL PROTECTIVE EQUIPMENT:
PROTECTIVE CLOTHING, PROTECTIVE GOGGLES, GLOVES, FACE SHIELD.
RESPIRATORY PROTECTION:
USE NIOSH-APPROVED RESPIRATOR WHERE AIRBORNE CONCENTRATIONS OF VAPOR ARE
EXPECTED TO EXCEED EXPOSURE LIMITS.
EYE / FACE PROTECTION: CHEMICAL GOGGLES OR FACE SHIELD.
HANDS: CHEMICAL RESISTANT GLOVES.
SKIN / BODY: WEAR SUITABLE PROTECTIVE CLOTHING.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: CLEAR, PALE LIQUID.
ODOR: SLIGHT AMMONIA.
ODOR THRESHOLD: NOT AVAILABLE.
PH: 8.0 - 9.0
SPECIFIC GRAVITY: 1.00 G/CM3
VISCOSITY: 0.61 CM2/S (61 CST)
MELTING POINT: NOT AVAILABLE.
FREEZING POINT: NOT AVAILABLE.
BOILING POINT: 104.4 DEG. C (219.9 DEG. F)
FLASH POINT: NOT AVAILABLE.
FLAMMABILITY: NOT AVAILABLE.
FLAMMABILITY LIMITS: NOT AVAILABLE.
VAPOR PRESSURE: NOT AVAILABLE.
VAPOR DENSITY: NOT AVAILABLE.
SOLUBILITY: COMPLETE.
EVAPORATION RATE: NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
RELATIVE DENSITY: NOT AVAILABLE.
PARTITION COEFFICIENT N-OCTANOL / WATER: NOT AVAILABLE.
| SECTION 10: STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER NORMAL CONDITIONS.
CONDITIONS TO AVOID: NO SPECIFIC DATA.
INCOMPATIBLE MATERIALS: NO SPECIFIC DATA.
HAZARDOUS DECOMPOSITION PRODUCTS:
CARBON DIOXIDE, CARBON MONOXIDE, NITROGEN OXIDES.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
ACUTE TOXICOLOGICAL DATA:
ORAL LD50: >5000 MG/KG (RAT)
DERMAL LD50: >2000 MG/KG (RABBIT)
INHALATION LC50: NOT AVAILABLE.
LIKELY ROUTES OF EXPOSURE: EYE CONTACT, SKIN CONTACT.
SYMPTOMS AND EFFECTS:
CONDITION ACUTE EFFECTS CHRONIC (DELAYED) EFFECTS
EYE CONTACT CAUSES SERIOUS EYE IRRITATION. PERSISTENT IRRITATION.
SKIN CONTACT NO SPECIFIC DATA. NO SPECIFIC DATA.
INHALATION NO SPECIFIC DATA. NO SPECIFIC DATA.
INGESTION NO SPECIFIC DATA. NO SPECIFIC DATA.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICITY: NOT AVAILABLE.
PERSISTENCE AND DEGRADABILITY: NOT AVAILABLE.
BIOACCUMULATION POTENTIAL: NOT AVAILABLE.
MOBILITY IN SOIL: NOT AVAILABLE.
OTHER ADVERSE EFFECTS: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
WASTE FROM RESIDUES AND UNUSED PRODUCT:
DISPOSE OF WASTE MATERIAL IN ACCORDANCE WITH ALL LOCAL, REGIONAL, NATIONAL,
PROVINCIAL, TERRITORIAL AND INTERNATIONAL REGULATIONS.
CONTAMINATED CONTAINER DISPOSAL:
DO NOT REUSE OR REFILL THIS CONTAINER. TRIPLE RINSE EMPTY CONTAINERS WITH
CLEAN WATER. CLEAN AND EMPTY CONTAINERS ARE TO BE RECYCLED OR PLACED IN THE
TRASH.
| SECTION 14: TRANSPORT INFORMATION | |
UN UN PROPER SHIPPING HAZARD CLASS LABEL PACKING MARINE
NUMBER NAME (SUBSIDIARY) (SUBSIDIARY) GROUP POLLUTANT
NOT REGULATED.
| SECTION 15: REGULATORY INFORMATION | |
TSCA INVENTORY LIST: YES
US EPA CERCLA HAZARDOUS SUBSTANCES: NOT APPLICABLE.
SARA TITLE III SEC. 302/303: NOT APPLICABLE.
SEC. 302 TPQ: NOT APPLICABLE.
SARA TITLE III SEC. 311/312: NOT APPLICABLE.
HAZARD CATEGORY: NOT APPLICABLE.
SEC. 304 EHS RQ: NOT APPLICABLE.
US EPA EPCRA SEC. 313: NOT APPLICABLE.
CAA THRESHOLD QTY: NOT APPLICABLE.
NFPA RATING:
HEALTH 2
FLAMMABILITY 0
REACTIVITY 0
SPECIAL NONE
HMIS RATING:
HEALTH 2
FLAMMABILITY 0
PHYSICAL 0
PPE RECOMMENDED.
CAN WHMIS CLASSIFICATION:
CLASS D-2B: MATERIAL CAUSING OTHER TOXIC EFFECTS
CALIFORNIA PROP 65:
THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER, DEVELOPMENTAL AND/OR REPRODUCTIVE HARM.
| SECTION 16: OTHER INFORMATION | |
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26, 2012 /
RULES AND REGULATIONS
TO THE EXTENT OF OUR KNOWLEDGE, THE INFORMATION HEREIN IS ACCURATE AS OF
THE DATE OF THIS DOCUMENT. HOWEVER, NEITHER BIOSAFE SYSTEMS NOR ANY OF ITS
AFFILIATES MAKE ANY WARRANTY, EXPRESSED OR IMPLIED, OR ACCEPT ANY LIABILITY
RELATING TO THE INFORMATION OR ITS USE. THE INFORMATION IS FOR USE BY
TECHNICALLY SKILLED PERSONS AT THEIR OWN DISCRETION AND RISK. THIS IS NOT A
LICENSE OR A PATENT. THE USER ALONE MUST FINALLY DETERMINE SUITABILITY OF
ANY INFORMATION OR MATERIAL FOR ANY CONTEMPLATED USE, THE MANNER OR USE AND
WHETHER ANY PATENTS ARE INFRINGED. ALWAYS READ AND FOLLOW LABEL DIRECTIONS.
AXXE(R*) BROAD SPECTRUM HERBICIDE IS A REGISTERED TRADEMARK OF BIOSAFE
SYSTEMS, LLC.
FOR ADDITIONAL INFORMATION, CALL US TOLL-FREE AT 1.888.273.3088 OR VISIT
WWW.BIOSAFESYSTEMS.COM
(C) 2018 BIOSAFE SYSTEMS, LLC.
REVISION DATE: 01/31/2019
CURRENT REVISION NUMBER: 03
BIOSAFE SYSTEMS
KEY TO ABBREVIATIONS:
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENE
TWA: TIME-WEIGHTED AVERAGES ARE BASED ON 8H/DAY, 40H/WEEK EXPOSURES
NIOSH: NATIONAL INSTITUTE OF OCCUPATIONAL SAFETY AND HEALTH
STEL: SHORT TERM EXPOSURE LIMITS ARE BASED ON 15-MINUTE EXPOSURES
OSHA: OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION
STEV: SHORT TERM EXPOSURE VALUE
EHS: ENVIRONMENTAL HEALTH AND SAFETY
PEL: PERMISSIBLE EXPOSURE LIMIT
DOT: DEPARTMENT OF TRANSPORTATION CAN
TDG: CANADIAN TRANSPORTATION OF DANGEROUS GOODS
EPA: ENVIRONMENTAL PROTECTION AGENCY
TSCA: TOXIC SUBSTANCES CONTROL ACT
TPQ: THRESHOLD PLANNING QUANTITY
RQ: REPORTABLE QUANTITY
CERCLA:
COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION, AND LIABILITY ACT
SARA: SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT
NFPA: NATIONAL FIRE PROTECTION ASSOCIATION
HMIS: HAZARDOUS MATERIALS IDENTIFICATION SYSTEM
WHMIS: WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (CANADA)
EPCRA: EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT