| Common Name: | ROUNDUP QUIKPRO HERBICIDE |
| Manufacturer: | MONSANTO |
| SDS Revision Date: | 5/29/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 8DMY8, 8MJX9 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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MONSANTO COMPANY
ROUNDUP QUIKPRO(TM) HERBICIDE
VERSION: 1.0
EFFECTIVE DATE: 05/29/2015
MONSANTO COMPANY
SAFETY DATA SHEET
COMMERCIAL PRODUCT
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER: ROUNDUP QUIKPRO(TM) HERBICIDE
1.1.1. CHEMICAL NAME: NOT APPLICABLE.
1.1.2. SYNONYMS: NONE.
1.1.3. EPA REG. NO.: 524-535
1.2. COMPANY
MONSANTO COMPANY,
800 N. LINDBERGH BLVD.
ST. LOUIS, MO, 63167
TELEPHONE: 800-332-3111
FAX: 314-694-5557
E-MAIL: SAFETY.DATASHEET@MONSANTO.COM
1.3. EMERGENCY NUMBERS:
FOR CHEMICAL EMERGENCY, SPILL LEAK, FIRE, EXPOSURE, OR ACCIDENT CALL:
CHEMTREC - DAY OR NIGHT:
1-800-424-9300 TOLL FREE IN THE CONTINENTAL U.S., PUERTO RICO, CANADA, OR
VIRGIN ISLANDS.
FOR CALLS ORIGINATING ELSEWHERE: 703-527-3887 (COLLECT CALLS ACCEPTED).
FOR MEDICAL EMERGENCY - DAY OR NIGHT:
+1 (314) 694-4000 (COLLECT CALLS ACCEPTED).
| 2. HAZARDS IDENTIFICATION | |
2.1. CLASSIFICATION:
OSHA HAZARD COMMUNICATION STANDARD, 29 CFR 1910.1200 (2012)
STOT RE - CATEGORY 1
2.2. LABEL ELEMENTS:
2.2.1. SIGNAL WORD: DANGER!
2.2.2. HAZARD PICTOGRAM/PICTOGRAMS:
HEALTH HAZARD
EXCLAMATION MARK
2.2.3. HAZARD STATEMENT/STATEMENTS:
CAUSES DAMAGE TO KIDNEY, LIVER, ADRENAL, OVARY, THYROID, OR BLOOD THOUGH
PROLONGED OR REPEATED EXPOSURE.
2.2.4. PRECAUTIONARY STATEMENT/STATEMENTS:
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPOURS/SPRAY.
WASH THOROUGHLY AFTER HANDLING.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
GET MEDICAL ADVICE/ATTENTION IF YOU FEEL UNWELL.
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL, REGIONAL,
NATIONAL AND INTERNATIONAL REGULATIONS.
2.3. APPEARANCE AND ODOUR (COLOUR/FORM/ODOUR):
PALE YELLOW-BROWN /GRANULES / SLIGHT
2.4. OSHA STATUS:
THIS PRODUCT IS HAZARDOUS ACCORDING TO THE OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
REFER TO SECTION 11 FOR TOXICOLOGICAL AND SECTION 12 FOR ENVIRONMENTAL
INFORMATION.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
ACTIVE INGREDIENT:
AMMONIUM SALT OF N-(PHOSPHONOMETHYL)GLYCINE; {AMMONIUM SALT OF GLYPHOSATE}
6,7-DIHYDRODIPYRIDO(1,2-A:2',1'C) PYRAZINEDIUM DIBROMIDE; {DIQUAT
DIBROMIDE}
COMPOSITION:
COMPONENT CAS NO. % BY WEIGHT (APPROXIMATE)
AMMONIUM SALT OF GLYPHOSATE 40465-66-5 73.3
DIQUAT DIBROMIDE 85-00-7 2.9
OTHER INGREDIENTS 23.8
THE SPECIFIC CHEMICAL IDENTITY IS BEING WITHHELD BECAUSE IT IS TRADE
SECRET INFORMATION OF MONSANTO COMPANY.
| 4. FIRST AID MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8.
4.1. DESCRIPTION OF FIRST AID MEASURES:
4.1.1. EYE CONTACT:
IF IN EYES, HOLD EYE OPEN AND RINSE SLOWLY AND GENTLY FOR 15-20 MINUTES.
REMOVE CONTACT LENSES, IF PRESENT, AFTER FIRST 5 MINUTES, THEN CONTINUE
RINSING. CALL A POISON CONTROL CENTER OR DOCTOR FOR TREATMENT ADVICE.
4.1.2. SKIN CONTACT:
TAKE OFF CONTAMINATED CLOTHING. RINSE SKIN IMMEDIATELY WITH PLENTY OF
WATER FOR 15-20 MINUTES. CALL A POISON CONTROL CENTER OR DOCTOR FOR
TREATMENT ADVICE.
4.1.3. INHALATION:
IF INHALED, MOVE PERSON TO FRESH AIR. IF PERSON IS NOT BREATHING, CALL
EMERGENCY NUMBER OR AMBULANCE, THEN GIVE ARTIFICIAL RESPIRATION,
PREFERABLY MOUTH-TO-MOUTH, IF POSSIBLE. CALL A POISON CONTROL CENTER
OR DOCTOR FOR TREATMENT ADVICE.
4.1.4. INGESTION:
CALL POISON CONTROL CENTER OR DOCTOR IMMEDIATELY FOR TREATMENT ADVICE.
HAVE PERSON SIP A GLASS OF WATER IF ABLE TO SWALLOW. DO NOT INDUCE
VOMITING UNLESS TOLD TO DO SO BY THE POISON CENTER OR DOCTOR. DO NOT
GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. QUICK TREATMENT IS
ESSENTIAL TO COUNTERACT POISONING AND SHOULD BE INITIATED BEFORE SIGNS
AND SYMPTOMS OF INJURY APPEAR.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
4.2.1. EYE CONTACT, SHORT TERM: MAY CAUSE TEMPORARY EYE IRRITATION.
4.2.2. SKIN CONTACT, SHORT TERM:
NOT EXPECTED TO PRODUCE SIGNIFICANT ADVERSE EFFECTS WHEN RECOMMENDED
USE INSTRUCTIONS ARE FOLLOWED.
4.2.3. INHALATION, SHORT TERM: HARMFUL BY INHALATION.
4.2.4. SINGLE INGESTION: HARMFUL IF SWALLOWED.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED:
4.3.1. ADVICE TO DOCTORS:
THIS PRODUCT IS NOT AN INHIBITOR OF CHOLINESTERASE.
4.3.2. ANTIDOTE:
TREATMENT WITH ATROPINE AND OXIMES IS NOT INDICATED.
| 5. FIRE-FIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
5.1.1. RECOMMENDED: WATER, DRY CHEMICAL, FOAM, CARBON DIOXIDE (CO2)
5.2. SPECIAL HAZARDS:
5.2.1. UNUSUAL FIRE AND EXPLOSION HAZARDS:
NONE.
ENVIRONMENTAL PRECAUTIONS: SEE SECTION 6.
5.2.2. HAZARDOUS PRODUCTS OF COMBUSTION:
CARBON MONOXIDE (CO), NITROGEN OXIDES (NOx), PHOSPHORUS OXIDES (PxOy),
HYDROGEN BROMIDE (HBr)
5.3. FIRE FIGHTING EQUIPMENT:
SELF-CONTAINED BREATHING APPARATUS. EQUIPMENT SHOULD BE THOROUGHLY
DECONTAMINATED AFTER USE.
5.4. FLASH POINT: DOES NOT FLASH.
| 6. ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS:
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8.
6.2. ENVIRONMENTAL PRECAUTIONS:
SMALL QUANTITIES: LOW ENVIRONMENTAL HAZARD.
LARGE QUANTITIES:
MINIMISE SPREAD.
KEEP OUT OF DRAINS, SEWERS, DITCHES AND WATER WAYS.
6.3. METHODS FOR CLEANING UP:
SMALL QUANTITIES: FLUSH SPILL AREA WITH WATER.
LARGE QUANTITIES:
ABSORB IN EARTH, SAND OR ABSORBENT MATERIAL.
DIG UP HEAVILY CONTAMINATED SOIL.
COLLECT IN CONTAINERS FOR DISPOSAL.
REFER TO SECTION 7 FOR TYPES OF CONTAINERS.
FLUSH RESIDUES WITH SMALL QUANTITIES OF WATER.
MINIMISE USE OF WATER TO PREVENT ENVIRONMENTAL CONTAMINATION.
REFER TO SECTION 13 FOR DISPOSAL OF SPILLED MATERIAL.
USE HANDLING RECOMMENDATIONS IN SECTION 7 AND PERSONAL PROTECTION
RECOMMENDATIONS IN SECTION 8.
| 7. HANDLING AND STORAGE | |
GOOD INDUSTRIAL PRACTICE IN HOUSEKEEPING AND PERSONAL HYGIENE SHOULD
BE FOLLOWED.
7.1. PRECAUTIONS FOR SAFE HANDLING:
AVOID BREATHING DUST. AVOID CONTACT WITH EYES, SKIN AND CLOTHING. WASH
CONTAMINATED CLOTHING BEFORE RE-USE. WASH HANDS THOROUGHLY AFTER HANDLING
OR CONTACT.
7.2. CONDITIONS FOR SAFE STORAGE:
COMPATIBLE MATERIALS FOR STORAGE:
STAINLESS STEEL, FIBREGLASS, PLASTIC, GLASS LINING
INCOMPATIBLE MATERIALS FOR STORAGE:
GALVANISED STEEL, UNLINED MILD STEEL, SEE SECTION 10.
KEEP OUT OF REACH OF CHILDREN.
KEEP AWAY FROM FOOD, DRINK AND ANIMAL FEED.
KEEP ONLY IN THE ORIGINAL CONTAINER.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. AIRBORNE EXPOSURE LIMITS:
COMPONENTS EXPOSURE GUIDELINES
AMMONIUM SALT OF GLYPHOSATE NO SPECIFIC OCCUPATIONAL EXPOSURE LIMIT HAS
BEEN ESTABLISHED.
DIQUAT DIBROMIDE TLV (ACGIH):
0.5 MG/M3: INHALABLE FRACTION, SKIN, THE
EXPOSURE LIMIT INDICATED IS FOR THE DIQUAT
CATION.
TLV (ACGIH):
0.1 MG/M3: RESPIRABLE FRACTION, SKIN, THE
EXPOSURE LIMIT INDICATED IS FOR THE DIQUAT
CATION.
PEL (OSHA):
NO SPECIFIC OCCUPATIONAL EXPOSURE LIMIT HAS
BEEN ESTABLISHED.
OTHER INGREDIENTS NO SPECIFIC OCCUPATIONAL EXPOSURE LIMIT HAS
BEEN ESTABLISHED.
8.2. ENGINEERING CONTROLS: PROVIDE LOCAL EXHAUST VENTILATION.
8.3. RECOMMENDATIONS FOR PERSONAL PROTECTIVE EQUIPMENT:
8.3.1. EYE PROTECTION:
IF THERE IS SIGNIFICANT POTENTIAL FOR CONTACT: WEAR DUST GOGGLES.
8.3.2. SKIN PROTECTION:
NO SPECIAL REQUIREMENT WHEN USED AS RECOMMENDED.
IF REPEATED OR PROLONGED CONTACT: WEAR CHEMICAL RESISTANT GLOVES.
8.3.3. RESPIRATORY PROTECTION:
IF AIRBORNE EXPOSURE IS EXCESSIVE:
WEAR RESPIRATOR.
FULL FACEPIECE/HOOD/HELMET RESPIRATOR REPLACES NEED FOR CHEMICAL GOGGLES.
WHEN RECOMMENDED, CONSULT MANUFACTURER OF PERSONAL PROTECTIVE EQUIPMENT
FOR THE APPROPRIATE TYPE OF EQUIPMENT FOR A GIVEN APPLICATION.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
THESE PHYSICAL DATA ARE TYPICAL VALUES BASED ON MATERIAL TESTED BUT MAY
VARY FROM SAMPLE TO SAMPLE. TYPICAL VALUES SHOULD NOT BE CONSTRUED AS A
GUARANTEED ANALYSIS OF ANY SPECIFIC LOT OR AS SPECIFICATIONS FOR THE
PRODUCT.
COLOUR/COLOUR RANGE: PALE YELLOW - BROWN
ODOUR: SLIGHT
FORM: GRANULES
PHYSICAL FORM CHANGES (MELTING, BOILING, ETC.):
MELTING POINT: NO DATA.
FLASH POINT: DOES NOT FLASH.
EXPLOSIVE PROPERTIES: NO EXPLOSIVE PROPERTIES
AUTO IGNITION TEMPERATURE: NO DATA.
SELF-ACCELERATING DECOMPOSITION TEMPERATURE (SADT): NO DATA.
OXIDIZING PROPERTIES: NONE
SPECIFIC GRAVITY: NO DATA.
VAPOUR PRESSURE: NO SIGNIFICANT VOLATILITY; AQUEOUS SOLUTION.
VAPOUR DENSITY: NOT APPLICABLE.
EVAPORATION RATE: NO DATA.
DYNAMIC VISCOSITY: NOT APPLICABLE.
DENSITY:
36 LB/FT3; (LOOSE BULK DENSITY)
42.6 LB/FT3; (TAPPED BULK DENSITY)
SOLUBILITY:
WATER: SOLUBLE
PH: 3.7 10 G/L
PARTITION COEFFICIENT:
LOG POW: -3.2 @ 25 DEG. C (GLYPHOSATE)
| 10. STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
REACTS WITH GALVANISED STEEL OR UNLINED MILD STEEL TO PRODUCE HYDROGEN,
A HIGHLY FLAMMABLE GAS THAT COULD EXPLODE.
10.2. STABILITY: STABLE UNDER NORMAL CONDITIONS OF HANDLING AND STORAGE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
REACTS WITH GALVANISED STEEL OR UNLINED MILD STEEL TO PRODUCE HYDROGEN,
A HIGHLY FLAMMABLE GAS THAT COULD EXPLODE.
10.4. INCOMPATIBLE MATERIALS:
GALVANISED STEEL; UNLINED MILD STEEL;SEE SECTION 10.;
COMPATIBLE MATERIALS FOR STORAGE: SEE SECTION 7.2.
10.5. HAZARDOUS DECOMPOSITION:
THERMAL DECOMPOSITION:
HAZARDOUS PRODUCTS OF COMBUSTION: SEE SECTION 5.
| 11. TOXICOLOGICAL INFORMATION | |
THIS SECTION IS INTENDED FOR USE BY TOXICOLOGISTS AND OTHER HEALTH
PROFESSIONALS.
LIKELY ROUTES OF EXPOSURE: SKIN CONTACT, EYE CONTACT, INHALATION
POTENTIAL HEALTH EFFECTS:
EYE CONTACT, SHORT TERM: MAY CAUSE TEMPORARY EYE IRRITATION.
SKIN CONTACT, SHORT TERM:
NOT EXPECTED TO PRODUCE SIGNIFICANT ADVERSE EFFECTS WHEN RECOMMENDED
USE INSTRUCTIONS ARE FOLLOWED.
INHALATION, SHORT TERM: HARMFUL BY INHALATION.
SINGLE INGESTION: HARMFUL IF SWALLOWED.
DATA OBTAINED ON PRODUCT AND COMPONENTS ARE SUMMARIZED BELOW.
ACUTE ORAL TOXICITY:
RAT, LD50:
4,443 MG/KG BODY WEIGHT
SLIGHTLY TOXIC.
ACUTE DERMAL TOXICITY:
RAT, LD50:
> 5,000 MG/KG BODY WEIGHT
PRACTICALLY NON-TOXIC.
ACUTE INHALATION TOXICITY:
RAT, LC50, 4 HOURS, AEROSOL:
SLIGHTLY TOXIC. NO 4-HR LC50 AT THE MAXIMUM ACHIEVABLE CONCENTRATION.
SKIN IRRITATION:
RABBIT, 3 ANIMALS, OECD 404 TEST:
DAYS TO HEAL: 2
PRIMARY IRRITATION INDEX (PII): 0.5/8.0
SLIGHT IRRITATION.
EYE IRRITATION:
RABBIT, 3 ANIMALS, OECD 405 TEST:
DAYS TO HEAL: 3
MODERATE IRRITATION.
SKIN SENSITIZATION:
GUINEA PIG, 3-INDUCTION BUEHLER TEST:
POSITIVE INCIDENCE: 0 %
NEGATIVE.
N-(PHOSPHONOMETHYL)GLYCINE; {GLYPHOSATE ACID}:
GENOTOXICITY: NOT GENOTOXIC.
CARCINOGENICITY: NOT CARCINOGENIC IN RATS OR MICE.
REPRODUCTIVE/DEVELOPMENTAL TOXICITY:
DEVELOPMENTAL EFFECTS IN RATS AND RABBITS ONLY IN THE PRESENCE OF
SIGNIFICANT MATERNAL TOXICITY. REPRODUCTIVE EFFECTS IN RATS ONLY
IN THE PRESENCE OF SIGNIFICANT MATERNAL TOXICITY.
DIQUAT DIBROMIDE:
GENOTOXICITY: NOT GENOTOXIC IN VIVO.
CARCINOGENICITY: NOT CARCINOGENIC IN RATS OR MICE.
REPRODUCTIVE/DEVELOPMENTAL TOXICITY:
REPRODUCTIVE EFFECTS IN RATS ONLY IN THE PRESENCE OF MATERNAL TOXICITY.
DEVELOPMENTAL EFFECTS IN RATS, RABBITS, AND MICE ONLY IN THE PRESENCE
OF MATERNAL TOXICITY.
SURFACTANT:
GENOTOXICITY: NOT GENOTOXIC.
| 12. ECOLOGICAL INFORMATION | |
THIS SECTION IS INTENDED FOR USE BY ECOTOXICOLOGISTS AND OTHER
ENVIRONMENTAL SPECIALISTS.
DATA OBTAINED ON SIMILAR PRODUCTS AND ON COMPONENTS ARE SUMMARIZED BELOW.
SIMILAR GLYPHOSATE FORMULATION:
AQUATIC TOXICITY, FISH:
RAINBOW TROUT (ONCORHYNCHUS MYKISS):
ACUTE TOXICITY, 96 HOURS, STATIC, LC50: 5.4 MG/L
MODERATELY TOXIC.
BLUEGILL SUNFISH (LEPOMIS MACROCHIRUS):
ACUTE TOXICITY, 96 HOURS, STATIC, LC50: 7.3 MG/L
MODERATELY TOXIC.
AQUATIC TOXICITY, INVERTEBRATES:
WATER FLEA (DAPHNIA MAGNA):
ACUTE TOXICITY, 48 HOURS, STATIC, EC50: 11 MG/L
SLIGHTLY TOXIC.
AVIAN TOXICITY:
MALLARD DUCK (ANAS PLATYRHYNCHOS):
DIETARY TOXICITY, 5 DAYS, LC50: > 5,620 MG/KG DIET
PRACTICALLY NON-TOXIC.
BOBWHITE QUAIL (COLINUS VIRGINIANUS):
DIETARY TOXICITY, 5 DAYS, LC50: > 5,620 MG/KG DIET
PRACTICALLY NON-TOXIC.
ARTHROPOD TOXICITY:
HONEY BEE (APIS MELLIFERA):
ORAL/CONTACT, 48 HOURS, LD50: > 100 (MICRO)G/BEE
PRACTICALLY NON-TOXIC.
SOIL ORGANISM TOXICITY, INVERTEBRATES:
EARTHWORM (EISENIA FOETIDA):
ACUTE TOXICITY, 14 DAYS, LC50: > 1,250 MG/KG SOIL
PRACTICALLY NON-TOXIC.
ISOPROPYLAMINE SALT OF GLYPHOSATE (62%):
DATA OBTAINED ON PRODUCT AND COMPONENTS ARE SUMMARIZED BELOW.
AQUATIC TOXICITY, ALGAE/AQUATIC PLANTS:
GREEN ALGAE (SCENEDESMUS SUBSPICATUS):
ACUTE TOXICITY, 72 HOURS, STATIC, EBC50 (BIOMASS): 72.9 MG/L
SLIGHTLY TOXIC.
GREEN ALGAE (SCENEDESMUS SUBSPICATUS):
ACUTE TOXICITY, 72 HOURS, STATIC, NOEC (GROWTH RATE): 26.4 MG/L
DIQUAT DIBROMIDE:
AQUATIC TOXICITY, FISH:
BLUEGILL SUNFISH (LEPOMIS MACROCHIRUS):
ACUTE TOXICITY, 72 HOURS, STATIC, LC50: 12.1 - 21.5 MG/L
RAINBOW TROUT (ONCORHYNCHUS MYKISS):
ACUTE TOXICITY, 96 HOURS, STATIC, LC50: 14.8 MG/L
SLIGHTLY TOXIC.
AQUATIC TOXICITY, INVERTEBRATES:
WATER FLEA (DAPHNIA MAGNA):
ACUTE TOXICITY, 48 HOURS, STATIC, EC50: 0.77 - 1.19 MG/L
HIGHLY TOXIC.
AQUATIC TOXICITY, ALGAE/AQUATIC PLANTS:
GREEN ALGAE (SELENASTRUM CAPRICORNUTUM):
ACUTE TOXICITY, 96 HOURS, STATIC, EC50: 0.0094 MG/L
VERY HIGHLY TOXIC.
AVIAN TOXICITY:
BOBWHITE QUAIL (COLINUS VIRGINIANUS):
DIETARY TOXICITY, 5 DAYS, LC50: 575 MG/KG DIET
MODERATELY TOXIC.
MALLARD DUCK (ANAS PLATYRHYNCHOS):
DIETARY TOXICITY, 5 DAYS, LC50: > 980 MG/KG DIET
MALLARD DUCK (ANAS PLATYRHYNCHOS):
ACUTE ORAL TOXICITY, SINGLE DOSE, LD50: 60.6 - 89.6 MG/KG BODY WEIGHT
MODERATELY TOXIC.
BIOACCUMULATION:
BLUEGILL SUNFISH (LEPOMIS MACROCHIRUS):
EDIBLE PORTION: BCF: < 1
NO SIGNIFICANT BIOACCUMULATION. RAPID DEPURATION AFTER END OF EXPOSURE.
DISSIPATION:
WATER/SEDIMENT, FIELD:
HALF LIFE: 1 - 2 DAYS
RAPID REMOVAL BY ADSORPTION TO SEDIMENTS.
N-(PHOSPHONOMETHYL)GLYCINE {GLYPHOSATE}:
BIOACCUMULATION:
BLUEGILL SUNFISH (LEPOMIS MACROCHIRUS):
WHOLE FISH: BCF: < 1
NO SIGNIFICANT BIOACCUMULATION IS EXPECTED.
DISSIPATION:
SOIL, FIELD:
HALF LIFE: 2 - 174 DAYS
KOC: 884 - 60,000 L/KG
ADSORBS STRONGLY TO SOIL.
WATER, AEROBIC:
HALF LIFE: < 7 DAYS
| 13. DISPOSAL CONSIDERATIONS | |
13.1.WASTE TREATMENT METHODS:
13.1.1. PRODUCT:
KEEP OUT OF DRAINS, SEWERS, DITCHES AND WATER WAYS. RECYCLE IF APPROPRIATE
FACILITIES/EQUIPMENT AVAILABLE. BURN IN PROPER INCINERATOR. FOLLOW ALL
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
13.1.2. CONTAINER:
SEE THE INDIVIDUAL CONTAINER LABEL FOR DISPOSAL INFORMATION. EMPTIED
PACKAGES RETAIN PRODUCT RESIDUE AND DUST. OBSERVE ALL LABELED SAFEGUARDS
UNTIL CONTAINER IS CLEANED, RECONDITIONED OR DESTROYED. EMPTY PACKAGING
COMPLETELY. STORE FOR COLLECTION BY APPROVED WASTE DISPOSAL SERVICE.
ENSURE PACKAGING CANNOT BE REUSED. DO NOT RE-USE CONTAINERS. RECYCLE IF
APPROPRIATE FACILITIES/EQUIPMENT AVAILABLE. BURY IN APPROVED LANDFILL.
FOLLOW ALL LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
USE HANDLING RECOMMENDATIONS IN SECTION 7 AND PERSONAL PROTECTION
RECOMMENDATIONS IN SECTION 8.
| 14. TRANSPORT INFORMATION | |
THE DATA PROVIDED IN THIS SECTION IS FOR INFORMATION ONLY. PLEASE APPLY
THE APPROPRIATE REGULATIONS TO PROPERLY CLASSIFY YOUR SHIPMENT FOR
TRANSPORTATION.
14.1. US DEPT. OF TRANSPORTATION (DOT) HAZARDOUS MATERIALS REGULATIONS
(49 CFR PARTS 105-180):
UN NO.: UN3077
PROPER SHIPPING NAME (TECHNICAL NAME IF REQUIRED):
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (DIQUAT DIBROMIDE)
CLASS: 9
PACKING GROUP: III
14.1.1. NOTE: APPLIES ONLY TO PACKAGES WHICH CONTAIN AN RQ.
14.1.2. US DOT REPORTABLE QUANTITY:
RQ COMPONENT RQ MINIMUM PACKAGE SIZE CONTAINING RQ
DIQUAT 1,000 LB 34,483 LB
14.2. IMDG CODE:
UN NO.: UN3077
PROPER SHIPPING NAME (TECHNICAL NAME IF REQUIRED):
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., LIMITED QUANTITY
(DIQUAT DIBROMIDE)
CLASS: 9
PACKING GROUP: III
14.3. IATA/ICAO:
UN NO.: UN3077
PROPER SHIPPING NAME (TECHNICAL NAME IF REQUIRED):
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., LIMITED QUANTITY ()
CLASS: 9
PACKING GROUP: III
| 15. REGULATORY INFORMATION | |
15.1. ENVIRONMENTAL PROTECTION AGENCY:
15.1.1. TSCA INVENTORY: EXEMPT
15.1.2. SARA TITLE III RULES:
SECTION 311/312 HAZARD CATEGORIES: IMMEDIATE
SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES: NOT APPLICABLE.
SECTION 313 TOXIC CHEMICAL(S): NOT APPLICABLE.
15.1.3. CERCLA REPORTABLE QUANTITY:
RQ COMPONENT RQ MINIMUM PACKAGE SIZE CONTAINING RQ
DIQUAT 1,000 LB 34,483 LB
RELEASE OF MORE THAN ANY REPORTABLE QUANTITY TO THE ENVIRONMENT IN A
24 HOUR PERIOD REQUIRES NOTIFICATION TO THE NATIONAL RESPONSE CENTER
(800-424-8802 OR 202-426-2675).
15.1.4. FEDERAL INSECTICIDE, FUNGICIDE, RODENTICIDE ACT (FIFRA):
THIS CHEMICAL IS A PESTICIDE PRODUCT REGISTERED BY THE UNITED STATES
ENVIRONMENTAL PROTECTION AGENCY AND IS SUBJECT TO CERTAIN LABELING
REQUIREMENTS UNDER FEDERAL PESTICIDE LAW. THESE REQUIREMENTS DIFFER
FROM THE CLASSIFICATION CRITERIA AND HAZARD INFORMATION REQUIRED FOR
SAFETY DATA SHEETS (SDS), AND FOR WORKPLACE LABELS OF NON-PESTICIDE
CHEMICALS. THE HAZARD INFORMATION REQUIRED ON THE PESTICIDE LABEL IS
REPRODUCED BELOW. THE PESTICIDE LABEL ALSO INCLUDES OTHER IMPORTANT
INFORMATION, INCLUDING DIRECTIONS FOR USE.
CAUTION!
HARMFUL IF SWALLOWED, HARMFUL IF INHALED, CAUSES MODERATE EYE
IRRITATION
ACUTE ORAL TOXICITY: FIFRA CATEGORY III.
ACUTE DERMAL TOXICITY: FIFRA CATEGORY IV.
ACUTE INHALATION TOXICITY: FIFRA CATEGORY III.
SKIN IRRITATION: FIFRA CATEGORY IV.
EYE IRRITATION: FIFRA CATEGORY III.
| 16. OTHER INFORMATION | |
THE INFORMATION GIVEN HERE IS NOT NECESSARILY EXHAUSTIVE BUT IS
REPRESENTATIVE OF RELEVANT, RELIABLE DATA.
FOLLOW ALL LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
PLEASE CONSULT SUPPLIER IF FURTHER INFORMATION IS NEEDED.
IN THIS DOCUMENT THE BRITISH SPELLING WAS APPLIED.
NFPA:
HEALTH 2
FLAMMABILITY 1
INSTABILITY 2
ADDITIONAL MARKINGS
0 = MINIMAL HAZARD
1 = SLIGHT HAZARD
2 = MODERATE HAZARD
3 = SEVERE HAZARD
4 = EXTREME HAZARD
FULL DENOMINATION OF MOST FREQUENTLY USED ACRONYMS. BCF (BIOCONCENTRATION
FACTOR), BOD (BIOCHEMICAL OXYGEN DEMAND), COD (CHEMICAL OXYGEN DEMAND),
EC50 (50% EFFECT CONCENTRATION), ED50 (50% EFFECT DOSE), I.M.
(INTRAMUSCULAR), I.P. (INTRAPERITONEAL), I.V. (INTRAVENOUS), KOC (SOIL
ADSORPTION COEFFICIENT), LC50 (50% LETHALITY CONCENTRATION), LD50 (50%
LETHALITY DOSE), LDLO (LOWER LIMIT OF LETHAL DOSAGE), LEL (LOWER EXPLOSION
LIMIT), LOAEC (LOWEST OBSERVED ADVERSE EFFECT CONCENTRATION), LOAEL
(LOWEST OBSERVED ADVERSE EFFECT LEVEL), LOEC (LOWEST OBSERVED EFFECT
CONCENTRATION), LOEL (LOWEST OBSERVED EFFECT LEVEL), MEL (MAXIMUM EXPOSURE
LIMIT), MTD (MAXIMUM TOLERATED DOSE), NOAEC (NO OBSERVED ADVERSE EFFECT
CONCENTRATION), NOAEL (NO OBSERVED ADVERSE EFFECT LEVEL), NOEC (NO
OBSERVED EFFECT CONCENTRATION), NOEL (NO OBSERVED EFFECT LEVEL), OEL
(OCCUPATIONAL EXPOSURE LIMIT), PEL (PERMISSIBLE EXPOSURE LIMIT), PII
(PRIMARY IRRITATION INDEX), POW (PARTITION COEFFICIENT N-OCTANOL/WATER),
S.C. (SUBCUTANEOUS), STEL (SHORT-TERM EXPOSURE LIMIT), TLV-C (THRESHOLD
LIMIT VALUE-CEILING), TLV-TWA (THRESHOLD LIMIT VALUE - TIME WEIGHTED
AVERAGE), UEL (UPPER EXPLOSION LIMIT)
THIS MATERIAL SAFETY DATA SHEET (MSDS) SERVES DIFFERENT PURPOSES THAN AND
DOES NOT REPLACE OR MODIFY THE EPA-APPROVED PRODUCT LABELING (ATTACHED TO
AND ACCOMPANYING THE PRODUCT CONTAINER). THIS MSDS PROVIDES IMPORTANT
HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION FOR EMPLOYERS, EMPLOYEES,
EMERGENCY RESPONDERS AND OTHERS HANDLING LARGE QUANTITIES OF THE PRODUCT
IN ACTIVITIES GENERALLY OTHER THAN PRODUCT USE, WHILE THE LABELING
PROVIDES THAT INFORMATION SPECIFICALLY FOR PRODUCT USE IN THE ORDINARY
COURSE. USE, STORAGE AND DISPOSAL OF PESTICIDE PRODUCTS ARE REGULATED BY
THE EPA UNDER THE AUTHORITY OF THE FEDERAL INSECTICIDE, FUNGICIDE, AND
RODENTICIDE ACT (FIFRA) THROUGH THE PRODUCT LABELING, AND ALL NECESSARY
AND APPROPRIATE PRECAUTIONARY, USE, STORAGE, AND DISPOSAL INFORMATION IS
SET FORTH ON THAT LABELING. IT IS A VIOLATION OF FEDERAL LAW TO USE A
PESTICIDE PRODUCT IN ANY MANNER NOT PRESCRIBED ON THE EPA-APPROVED LABEL.
ALTHOUGH THE INFORMATION AND RECOMMENDATIONS SET FORTH HEREIN (HEREINAFTER
"INFORMATION") ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE CORRECT AS
OF THE DATE HEREOF, MONSANTO COMPANY OR ANY OF ITS SUBSIDIARIES MAKES NO
REPRESENTATIONS AS TO THE COMPLETENESS OR ACCURACY THEREOF. INFORMATION IS
SUPPLIED UPON THE CONDITION THAT THE PERSONS RECEIVING SAME WILL MAKE
THEIR OWN DETERMINATION AS TO ITS SUITABILITY FOR THE PURPOSES PRIOR TO
USE. IN NO EVENT WILL MONSANTO COMPANY OR ANY OF ITS SUBSIDIARIES BE
RESPONSIBLE FOR DAMAGES OF ANY NATURE WHATSOEVER RESULTING FROM THE USE
OF OR RELIANCE UPON INFORMATION. NO REPRESENTATIONS OR WARRANTIES, EITHER
EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE
OR OF ANY OTHER NATURE ARE MADE HEREUNDER WITH RESPECT TO INFORMATION OR
TO THE PRODUCT TO WHICH INFORMATION REFERS.
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