| Common Name: | BROMOCRESOL GREEN-METHYL RED, ALCOHOLIC |
| Manufacturer: | LABCHEM |
| SDS Revision Date: | 12/19/2016 |
| SDS Format: | No Format Specified |
| Item Number(s): | 8EJ38 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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LC
LABCHEM
PERFORMANCE THROUGH CHEMISTRY
BROMOCRESOL GREEN-METHYL RED, ALCOHOLIC
SAFETY DATA SHEET
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26, 2012 /
RULES AND REGULATIONS
DATE OF ISSUE: 10/01/1998
REVISION DATE: 12/19/2016
SUPERSEDES: 08/03/2015
VERSION: 2.2
| SECTION 1: IDENTIFICATION |  |
1.1. IDENTIFICATION:
PRODUCT FORM: MIXTURE
PRODUCT NAME: BROMOCRESOL GREEN-METHYL RED, ALCOHOLIC
PRODUCT CODE: LC11880
1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
USE OF THE SUBSTANCE/MIXTURE: FOR LABORATORY AND MANUFACTURING USE ONLY.
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
LABCHEM INC
JACKSON'S POINTE COMMERCE PARK BUILDING 1000
1010 JACKSON'S POINTE COURT
ZELIENOPLE, PA 16063
USA
T: 412-826-5230
F: 724-473-0647
INFO@LABCHEM.COM - WWW.LABCHEM.COM
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER:
CHEMTREC: 1-800-424-9300 OR 011-703-527-3887
| SECTION 2: HAZARD(S) IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS-US CLASSIFICATION:
FLAMMABLE LIQUIDS CATEGORY 2: H225
CARCINOGENICITY CATEGORY 1A: H350
REPRODUCTIVE TOXICITY CATEGORY 2: H361
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) CATEGORY 1: H370
FULL TEXT OF H STATEMENTS: SEE SECTION 16
2.2. LABEL ELEMENTS:
GHS-US LABELING:
HAZARD PICTOGRAMS (GHS-US):
GHS02: FLAME
GHS08: HEALTH HAZARD
SIGNAL WORD (GHS-US): DANGER
HAZARD STATEMENTS (GHS-US):
H225: HIGHLY FLAMMABLE LIQUID AND VAPOR
H350: MAY CAUSE CANCER (ORAL)
H361: SUSPECTED OF DAMAGING THE UNBORN CHILD (ORAL)
H370:
CAUSES DAMAGE TO ORGANS (CENTRAL NERVOUS SYSTEM, OPTIC NERVE) (ORAL,
DERMAL)
PRECAUTIONARY STATEMENTS (GHS-US):
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD
P210: KEEP AWAY FROM HEAT, HOT SURFACES, OPEN FLAMES, SPARKS. - NO SMOKING
P233: KEEP CONTAINER TIGHTLY CLOSED
P240: GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT
P241: USE EXPLOSION-PROOF ELECTRICAL, LIGHTING, VENTILATING EQUIPMENT
P242: USE ONLY NON-SPARKING TOOLS
P243: TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE
P260: DO NOT BREATHE MIST, SPRAY, VAPORS
P264: WASH EXPOSED SKIN THOROUGHLY AFTER HANDLING
P270: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT
P280:
WEAR EYE PROTECTION, FACE PROTECTION, PROTECTIVE CLOTHING, PROTECTIVE
GLOVES
P303+P361+P353:
IF ON SKIN (OR HAIR):
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER
P308+P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION
P370+P378:
IN CASE OF FIRE:
USE CARBON DIOXIDE (CO2), POWDER, ALCOHOL-RESISTANT FOAM TO EXTINGUISH
P403+P235: STORE IN A WELL-VENTILATED PLACE. KEEP COOL
P405: STORE LOCKED UP
P501:
DISPOSE OF CONTENTS/CONTAINER TO COMPLY WITH LOCAL, STATE AND FEDERAL
REGULATIONS
2.3. OTHER HAZARDS:
OTHER HAZARDS NOT CONTRIBUTING TO THE CLASSIFICATION: NONE.
2.4. UNKNOWN ACUTE TOXICITY (GHS US): NOT APPLICABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCE: NOT APPLICABLE
3.2. MIXTURE:
NAME PRODUCT IDENTIFIER % GHS-US CLASSIFICATION
ETHANOL (CAS NO) 64-17-5 90.36 FLAM. LIQ. 2, H225
CARC. 1A, H350
REPR. 2, H361
ISOPROPYL ALCOHOL (CAS NO) 67-63-0 5 FLAM. LIQ. 2, H225
(2-PROPANOL) EYE IRRIT. 2A, H319
STOT SE 3, H335
METHANOL (CAS NO) 67-56-1 4.5 FLAM. LIQ. 2, H225
ACUTE TOX. 3 (ORAL), H301
ACUTE TOX. 3 (DERMAL),
H311
ACUTE TOX. 3 (INHALATION),
H331
STOT SE 1, H370
BROMOCRESOL GREEN, (CAS NO) 62625-32-5 0.1 NOT CLASSIFIED
SODIUM SALT, ACS
METHYL RED, (CAS NO) 845-10-3 0.04 NOT CLASSIFIED
SODIUM SALT, ACS
FULL TEXT OF HAZARD CLASSES AND H-STATEMENTS: SEE SECTION 16
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES GENERAL:
CHECK THE VITAL FUNCTIONS. UNCONSCIOUS: MAINTAIN ADEQUATE AIRWAY AND
RESPIRATION. RESPIRATORY ARREST: ARTIFICIAL RESPIRATION OR OXYGEN. CARDIAC
ARREST: PERFORM RESUSCITATION. VICTIM CONSCIOUS WITH LABORED BREATHING:
HALF-SEATED. VICTIM IN SHOCK: ON HIS BACK WITH LEGS SLIGHTLY RAISED.
VOMITING: PREVENT ASPHYXIA/ASPIRATION PNEUMONIA. PREVENT COOLING BY
COVERING THE VICTIM (NO WARMING UP). KEEP WATCHING THE VICTIM. GIVE
PSYCHOLOGICAL AID. KEEP THE VICTIM CALM, AVOID PHYSICAL STRAIN. DEPENDING
ON THE VICTIM'S CONDITION: DOCTOR/HOSPITAL. NEVER GIVE ALCOHOL TO DRINK.
FIRST-AID MEASURES AFTER INHALATION:
REMOVE THE VICTIM INTO FRESH AIR. RESPIRATORY PROBLEMS: CONSULT A
DOCTOR/MEDICAL SERVICE.
FIRST-AID MEASURES AFTER SKIN CONTACT:
RINSE WITH WATER. TAKE VICTIM TO A DOCTOR IF IRRITATION PERSISTS.
FIRST-AID MEASURES AFTER EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER. DO NOT APPLY NEUTRALIZING AGENTS.
TAKE VICTIM TO AN OPHTHALMOLOGIST IF IRRITATION PERSISTS.
FIRST-AID MEASURES AFTER INGESTION:
RINSE MOUTH WITH WATER. DO NOT INDUCE VOMITING. CALL POISON INFORMATION
CENTRE (WWW.BIG.BE/ANTIGIF.HTM). CONSULT A DOCTOR/MEDICAL SERVICE IF YOU
FEEL UNWELL. INGESTION OF LARGE QUANTITIES: IMMEDIATELY TO HOSPITAL.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS/INJURIES AFTER INHALATION:
EXPOSURE TO HIGH CONCENTRATIONS:
DRY/SORE THROAT. COUGHING. IRRITATION OF THE RESPIRATORY TRACT. IRRITATION
OF THE NASAL MUCOUS MEMBRANES. RESPIRATORY DIFFICULTIES. CENTRAL NERVOUS
SYSTEM DEPRESSION. SYMPTOMS SIMILAR TO THOSE LISTED UNDER INGESTION.
SYMPTOMS/INJURIES AFTER SKIN CONTACT: SLIGHT IRRITATION.
SYMPTOMS/INJURIES AFTER EYE CONTACT:
REDNESS OF THE EYE TISSUE. LACRIMATION. ON CONTINUOUS EXPOSURE/CONTACT:
IRRITATION OF THE EYE TISSUE.
SYMPTOMS/INJURIES AFTER INGESTION:
AFTER ABSORPTION OF LARGE QUANTITIES:
RISK OF ASPIRATION PNEUMONIA. RED SKIN. BODY TEMPERATURE RISE. DAMP/CLAMMY
SKIN. EXCITED/RESTLESS. ACCELERATED HEART ACTION. CENTRAL NERVOUS SYSTEM
DEPRESSION. DIZZINESS. NARCOSIS. HEADACHE. DRUNKENNESS. NAUSEA. VOMITING.
DISTURBED MOTOR RESPONSE. COORDINATION DISORDERS. VISUAL DISTURBANCES.
IMPAIRED CONCENTRATION. DELUSIONS. DISTURBED SENSATION OF PAIN.
DISTURBANCES OF HEART RATE. DISTURBANCES OF CONSCIOUSNESS. TREMOR.
CRAMPS/UNCONTROLLED MUSCULAR CONTRACTIONS. DILATED PUPILS.
CHRONIC SYMPTOMS:
ON CONTINUOUS/REPEATED EXPOSURE/CONTACT:
DRY SKIN. GASTROINTESTINAL COMPLAINTS. ENLARGEMENT/AFFECTION OF THE LIVER.
CHANGE IN THE HAEMOGRAMME/BLOOD COMPOSITION. CARDIAC AND BLOOD CIRCULATION
EFFECTS. HIGH ARTERIAL PRESSURE. IMPAIRMENT OF THE NERVOUS SYSTEM.
BEHAVIORAL DISTURBANCES. MENTAL CONFUSION. DISTURBED TACTILE SENSIBILITY.
TREMOR. AFFECTION OF THE BONE MARROW. AFFECTION OF THE ENDOCRINE SYSTEM.
WEAKENING OF THE IMMUNE SYSTEM.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 5: FIREFIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
WATER SPRAY. ALCOHOL-RESISTANT FOAM. BC POWDER. CARBON DIOXIDE.
UNSUITABLE EXTINGUISHING MEDIA:
SOLID WATER JET INEFFECTIVE AS EXTINGUISHING MEDIUM.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
FIRE HAZARD:
DIRECT FIRE HAZARD. HIGHLY FLAMMABLE. GAS/VAPOR FLAMMABLE WITH AIR WITHIN
EXPLOSION LIMITS. INDIRECT FIRE HAZARD. MAY BE IGNITED BY SPARKS. GAS/VAPOR
SPREADS AT FLOOR LEVEL: IGNITION HAZARD. REACTIONS INVOLVING A FIRE HAZARD:
SEE "REACTIVITY HAZARD". EXPLOSION HAZARD: DIRECT EXPLOSION HAZARD.
GAS/VAPOUR EXPLOSIVE WITH AIR WITHIN EXPLOSION LIMITS. INDIRECT EXPLOSION
HAZARD. MAY BE IGNITED BY SPARKS. REACTIONS WITH EXPLOSION HAZARDS: SEE
"REACTIVITY HAZARD".
REACTIVITY:
UPON COMBUSTION:
CO AND CO2 ARE FORMED. REACTS VIOLENTLY WITH MANY COMPOUNDS E.G.: WITH
(STRONG) OXIDIZERS: (INCREASED) RISK OF FIRE/EXPLOSION. VIOLENT TO
EXPLOSIVE REACTION WITH (SOME) ACIDS.
5.3. ADVICE FOR FIREFIGHTERS:
FIREFIGHTING INSTRUCTIONS:
COOL TANKS/DRUMS WITH WATER SPRAY/REMOVE THEM INTO SAFETY. DO NOT MOVE THE
LOAD IF EXPOSED TO HEAT.
PROTECTION DURING FIREFIGHTING:
HEAT/FIRE EXPOSURE: COMPRESSED AIR/OXYGEN APPARATUS.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
GENERAL MEASURES:
REMOVE IGNITION SOURCES. USE SPECIAL CARE TO AVOID STATIC ELECTRIC CHARGES.
NO NAKED LIGHTS. NO SMOKING.
6.1.1. FOR NON-EMERGENCY PERSONNEL:
PROTECTIVE EQUIPMENT:
GLOVES. PROTECTIVE GOGGLES. PROTECTIVE CLOTHING. LARGE SPILLS/IN ENCLOSED
SPACES: COMPRESSED AIR APPARATUS. SEE "MATERIAL-HANDLING" TO SELECT
PROTECTIVE CLOTHING.
EMERGENCY PROCEDURES:
KEEP UPWIND. MARK THE DANGER AREA. CONSIDER EVACUATION. SEAL OFF LOW-LYING
AREAS. CLOSE DOORS AND WINDOWS OF ADJACENT PREMISES. STOP ENGINES AND NO
SMOKING. NO NAKED FLAMES OR SPARKS. SPARK- AND EXPLOSION-PROOF APPLIANCES
AND LIGHTING EQUIPMENT. KEEP CONTAINERS CLOSED. WASH CONTAMINATED CLOTHES.
6.1.2. FOR EMERGENCY RESPONDERS:
PROTECTIVE EQUIPMENT:
EQUIP CLEANUP CREW WITH PROPER PROTECTION. AVOID BREATHING
DUST/FUME/GAS/MIST/VAPORS/SPRAY.
EMERGENCY PROCEDURES: VENTILATE AREA.
6.2. ENVIRONMENTAL PRECAUTIONS: PREVENT SPREADING IN SEWERS.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
FOR CONTAINMENT:
CONTAIN RELEASED SUBSTANCE, PUMP INTO SUITABLE CONTAINERS. CONSULT
"MATERIAL-HANDLING" TO SELECT MATERIAL OF CONTAINERS. PLUG THE LEAK, CUT
OFF THE SUPPLY. DAM UP THE LIQUID SPILL. TRY TO REDUCE EVAPORATION. MEASURE
THE CONCENTRATION OF THE EXPLOSIVE GAS-AIR MIXTURE. DILUTE/DISPERSE
COMBUSTIBLE GAS/VAPOUR WITH WATER CURTAIN. PROVIDE EQUIPMENT/RECEPTACLES
WITH EARTHING. DO NOT USE COMPRESSED AIR FOR PUMPING OVER SPILLS.
METHODS FOR CLEANING UP:
TAKE UP LIQUID SPILL INTO A NON COMBUSTIBLE MATERIAL E.G.: SAND, EARTH,
VERMICULITE OR KIESELGUHR, POWDERED LIMESTONE. SCOOP ABSORBED SUBSTANCE
INTO CLOSING CONTAINERS. SEE "MATERIAL-HANDLING" FOR SUITABLE CONTAINER
MATERIALS. CAREFULLY COLLECT THE SPILL/LEFTOVERS. DAMAGED/COOLED TANKS MUST
BE EMPTIED. DO NOT USE COMPRESSED AIR FOR PUMPING OVER SPILLS. CLEAN
CONTAMINATED SURFACES WITH AN EXCESS OF WATER. TAKE COLLECTED SPILL TO
MANUFACTURER/COMPETENT AUTHORITY. WASH CLOTHING AND EQUIPMENT AFTER
HANDLING.
6.4. REFERENCE TO OTHER SECTIONS:
SEE HEADING 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
PRECAUTIONS FOR SAFE HANDLING:
COMPLY WITH THE LEGAL REQUIREMENTS. REMOVE CONTAMINATED CLOTHING
IMMEDIATELY. CLEAN CONTAMINATED CLOTHING. HANDLE UNCLEANED EMPTY CONTAINERS
AS FULL ONES. THOROUGHLY CLEAN/DRY THE INSTALLATION BEFORE USE. DO NOT
DISCHARGE THE WASTE INTO THE DRAIN. DO NOT USE COMPRESSED AIR FOR PUMPING
OVER. USE SPARK-/EXPLOSION PROOF APPLIANCES AND LIGHTING SYSTEM. TAKE
PRECAUTIONS AGAINST ELECTROSTATIC CHARGES. KEEP AWAY FROM NAKED
FLAMES/HEAT. KEEP AWAY FROM IGNITION SOURCES/SPARKS. OBSERVE NORMAL HYGIENE
STANDARDS. KEEP CONTAINER TIGHTLY CLOSED. MEASURE THE CONCENTRATION IN THE
AIR REGULARLY. WORK UNDER LOCAL EXHAUST/VENTILATION. HYGIENE MEASURES:
WASH HANDS, FOREARMS AND FACE THOROUGHLY AFTER HANDLING.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
TECHNICAL MEASURES:
PROPER GROUNDING PROCEDURES TO AVOID STATIC ELECTRICITY SHOULD BE FOLLOWED.
GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT. USE EXPLOSION-PROOF
ELECTRICAL/VENTILATING/LIGHTING/... EQUIPMENT.
STORAGE CONDITIONS:
KEEP CONTAINER TIGHTLY CLOSED. KEEP ONLY IN THE ORIGINAL CONTAINER IN A
COOL, WELL VENTILATED PLACE AWAY FROM: KEEP IN FIREPROOF PLACE.
INCOMPATIBLE PRODUCTS: STRONG BASES. STRONG ACIDS.
INCOMPATIBLE MATERIALS:
SOURCES OF IGNITION. DIRECT SUNLIGHT. HEAT SOURCES.
HEAT-IGNITION:
KEEP SUBSTANCE AWAY FROM: HEAT SOURCES. IGNITION SOURCES.
PROHIBITIONS ON MIXED STORAGE:
KEEP SUBSTANCE AWAY FROM:
OXIDIZING AGENTS. STRONG ACIDS. WATER/MOISTURE. STORAGE AREA: KEEP OUT OF
DIRECT SUNLIGHT. STORE IN A DRY AREA. VENTILATION AT FLOOR LEVEL. FIREPROOF
STOREROOM. PROVIDE FOR AN AUTOMATIC SPRINKLER SYSTEM. PROVIDE FOR A TUB TO
COLLECT SPILLS. PROVIDE THE TANK WITH EARTHING. MEET THE LEGAL
REQUIREMENTS.
SPECIAL RULES ON PACKAGING:
SPECIAL REQUIREMENTS:
CLOSING. DRY. CLEAN. CORRECTLY LABELED. MEET THE LEGAL REQUIREMENTS.
SECURE FRAGILE PACKAGINGS IN SOLID CONTAINERS.
PACKAGING MATERIALS:
SUITABLE MATERIAL:
STAINLESS STEEL. ALUMINIUM. IRON. COPPER. NICKEL. SYNTHETIC MATERIAL.
GLASS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
BROMOCRESOL GREEN-METHYL RED, ALCOHOLIC:
ACGIH:
ACGIH STEL (PPM):
1000 PPM (ETHANOL; USA; SHORT TIME VALUE; TLV - ADOPTED VALUE)
OSHA:
OSHA PEL (TWA) (MG/M3): 1900 MG/M3
OSHA:
OSHA PEL (TWA) (PPM): 1000 PPM
IDLH:
US IDLH (PPM): 3300 PPM
NIOSH:
NIOSH REL (TWA) (MG/M3): 1900 MG/M3
NIOSH:
NIOSH REL (TWA) (PPM): 1000 PPM
ETHANOL (64-17-5):
ACGIH:
ACGIH STEL (PPM):
1000 PPM (ETHANOL; USA; SHORT TIME VALUE; TLV - ADOPTED VALUE)
OSHA:
OSHA PEL (TWA) (MG/M3): 1900 MG/M3
OSHA:
OSHA PEL (TWA) (PPM): 1000 PPM
IDLH:
US IDLH (PPM): 3300 PPM
NIOSH:
NIOSH REL (TWA) (MG/M3): 1900 MG/M3
NIOSH:
NIOSH REL (TWA) (PPM): 1000 PPM
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
ACGIH:
ACGIH TWA (PPM):
200 PPM (2-PROPANOL; USA; TIME-WEIGHTED AVERAGE EXPOSURE LIMIT 8 H; TLV -
ADOPTED VALUE)
ACGIH:
ACGIH STEL (PPM):
400 PPM (2-PROPANOL; USA; SHORT TIME VALUE; TLV - ADOPTED VALUE)
OSHA:
OSHA PEL (TWA) (MG/M3): 980 MG/M3
OSHA:
OSHA PEL (TWA) (PPM): 400 PPM
IDLH:
US IDLH (PPM): 2000 PPM
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
NIOSH:
NIOSH REL (TWA) (MG/M3): 980 MG/M3
NIOSH:
NIOSH REL (TWA) (PPM): 400 PPM
NIOSH:
NIOSH REL (STEL) (MG/M3): 1225 MG/M3
NIOSH:
NIOSH REL (STEL) (PPM): 500 PPM
METHANOL (67-56-1):
ACGIH:
ACGIH TWA (PPM):
200 PPM (METHANOL; USA; TIME-WEIGHTED AVERAGE EXPOSURE LIMIT 8 H; TLV -
ADOPTED VALUE)
ACGIH:
ACGIH STEL (PPM):
250 PPM (METHANOL; USA; SHORT TIME VALUE; TLV - ADOPTED VALUE)
OSHA:
OSHA PEL (TWA) (MG/M3): 260 MG/M3
OSHA:
OSHA PEL (TWA) (PPM): 200 PPM
IDLH:
US IDLH (PPM): 6000 PPM
NIOSH:
NIOSH REL (TWA) (MG/M3): 250 MG/M3
NIOSH:
NIOSH REL (TWA) (PPM): 200 PPM
NIOSH:
NIOSH REL (STEL) (MG/M3): 325 MG/M3
NIOSH:
NIOSH REL (STEL) (PPM): 250 PPM
NIOSH:
REMARK (NIOSH): SKIN
BROMOCRESOL GREEN, SODIUM SALT, ACS (62625-32-5): NOT APPLICABLE
METHYL RED, SODIUM SALT, ACS (845-10-3): NOT APPLICABLE
8.2. EXPOSURE CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
EMERGENCY EYE WASH FOUNTAINS AND SAFETY SHOWERS SHOULD BE AVAILABLE IN THE
IMMEDIATE VICINITY OF ANY POTENTIAL EXPOSURE. ENSURE ADEQUATE VENTILATION.
PERSONAL PROTECTIVE EQUIPMENT:
SAFETY GLASSES. GLOVES. HIGH GAS/VAPOR CONCENTRATION:
GAS MASK WITH FILTER TYPE B.
MATERIALS FOR PROTECTIVE CLOTHING:
GIVE EXCELLENT RESISTANCE: BUTYL RUBBER. VITON.
GIVE GOOD RESISTANCE: NEOPRENE. TETRAFLUOROETHYLENE.
GIVE LESS RESISTANCE: NITRILE RUBBER. POLYETHYLENE.
GIVE POOR RESISTANCE: NATURAL RUBBER. PVA. PVC.
HAND PROTECTION: GLOVES.
EYE PROTECTION: SAFETY GLASSES.
SKIN AND BODY PROTECTION: PROTECTIVE CLOTHING.
RESPIRATORY PROTECTION:
WEAR GAS MASK WITH FILTER TYPE A IF CONC. IN AIR > EXPOSURE LIMIT.
OTHER INFORMATION: DO NOT EAT, DRINK OR SMOKE DURING USE.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
APPEARANCE: LIQUID.
COLOR: GREEN
ODOR: ALCOHOL ODOR PLEASANT ODOR
ODOR THRESHOLD:
100 PPM
188 MG/M3
PH: NO DATA AVAILABLE
MELTING POINT: -115 DEG. C
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: 78 DEG. C
CRITICAL TEMPERATURE: 243 DEG. C
CRITICAL PRESSURE: 63840 HPA
FLASH POINT: 13 DEG. C
RELATIVE EVAPORATION RATE (BUTYL ACETATE=1): 2.4
RELATIVE EVAPORATION RATE (ETHER=1): 8.3
FLAMMABILITY (SOLID, GAS): HIGHLY FLAMMABLE LIQUID AND VAPOR.
VAPOR PRESSURE: 59 HPA
VAPOR PRESSURE AT 50 DEG. C: 300 HPA
RELATIVE VAPOR DENSITY AT 20 DEG. C: 1.6
RELATIVE DENSITY: 0.79
RELATIVE DENSITY OF SATURATED GAS/AIR MIXTURE: 1.04
SPECIFIC GRAVITY / DENSITY: 790 KG/M3
MOLECULAR MASS: 46.07 G/MOL
SOLUBILITY:
SOLUBLE IN WATER. SOLUBLE IN ETHER. SOLUBLE IN ACETONE. SOLUBLE IN
CHLOROFORM. SOLUBLE IN OILS/FATS. SOLUBLE IN METHANOL. SOLUBLE IN ACIDS.
ETHANOL: NOT APPLICABLE
ETHER: COMPLETE
ACETONE: COMPLETE
LOG POW: -0.31 (EXPERIMENTAL VALUE)
AUTO-IGNITION TEMPERATURE: 363 DEG. C
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
VISCOSITY, DYNAMIC: 0.0012 PA.S (20 DEG. C)
EXPLOSION LIMITS:
3.3 - 19.0 VOL %
67 - 290 G/M3
EXPLOSIVE PROPERTIES: NO DATA AVAILABLE
OXIDIZING PROPERTIES: NO DATA AVAILABLE
9.2. OTHER INFORMATION:
SPECIFIC CONDUCTIVITY: 130000 PS/M
SATURATION CONCENTRATION: 112 G/M3
VOC CONTENT: 100%
OTHER PROPERTIES:
GAS/VAPOUR HEAVIER THAN AIR AT 20 DEG. C. CLEAR. HYGROSCOPIC. VOLATILE.
SUBSTANCE HAS NEUTRAL REACTION.
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
UPON COMBUSTION:
CO AND CO2 ARE FORMED. REACTS VIOLENTLY WITH MANY COMPOUNDS E.G.: WITH
(STRONG) OXIDIZERS: (INCREASED) RISK OF FIRE/EXPLOSION. VIOLENT TO
EXPLOSIVE REACTION WITH (SOME) ACIDS.
10.2. CHEMICAL STABILITY: HYGROSCOPIC.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS: NOT ESTABLISHED.
10.4. CONDITIONS TO AVOID:
DIRECT SUNLIGHT. EXTREMELY HIGH OR LOW TEMPERATURES. OPEN FLAME.
10.5. INCOMPATIBLE MATERIALS: STRONG ACIDS. STRONG BASES.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
CARBON MONOXIDE. CARBON DIOXIDE. NITROGEN OXIDES.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
LIKELY ROUTES OF EXPOSURE: INHALATION; SKIN AND EYE CONTACT
ACUTE TOXICITY: NOT CLASSIFIED
BROMOCRESOL GREEN-METHYL RED, ALCOHOLIC:
LD50 ORAL RAT:
10740 MG/KG BODY WEIGHT (RAT; OECD 401: ACUTE ORAL TOXICITY; EXPERIMENTAL
VALUE)
LD50 DERMAL RABBIT: >16000 MG/KG (RABBIT; LITERATURE STUDY)
ATE US (ORAL): 10740.000 MG/KG BODY WEIGHT
ETHANOL (64-17-5):
LD50 ORAL RAT:
10740 MG/KG (RAT; EXPERIMENTAL VALUE, RAT; EXPERIMENTAL VALUE)
LD50 DERMAL RABBIT: >16000 MG/KG (RABBIT; LITERATURE STUDY)
ATE US (ORAL): 10740.000 MG/KG BODY WEIGHT
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
LD50 DERMAL RABBIT:
12870 MG/KG (RABBIT; EXPERIMENTAL VALUE; EQUIVALENT OR SIMILAR TO OECD 402;
16.4; RABBIT)
LC50 INHALATION RAT (MG/L): 73 MG/L/4H (RAT)
ATE US (ORAL): 5045.000 MG/KG BODY WEIGHT
ATE US (DERMAL): 12870.000 MG/KG BODY WEIGHT
ATE US (VAPORS): 73.000 MG/L/4H
ATE US (DUST, MIST): 73.000 MG/L/4H
METHANOL (67-56-1):
LD50 ORAL RAT:
>5000 MG/KG (RAT; BASF TEST; LITERATURE STUDY; 1187-2769 MG/KG BODYWEIGHT;
RAT; WEIGHT OF EVIDENCE)
LD50 DERMAL RABBIT: 15800 MG/KG (RABBIT; LITERATURE STUDY)
LC50 INHALATION RAT (MG/L): 85 MG/L/4H (RAT; LITERATURE STUDY)
LC50 INHALATION RAT (PPM): 64000 PPM/4H (RAT; LITERATURE STUDY)
SKIN CORROSION/IRRITATION: NOT CLASSIFIED
SERIOUS EYE DAMAGE/IRRITATION: NOT CLASSIFIED
RESPIRATORY OR SKIN SENSITIZATION: NOT CLASSIFIED
GERM CELL MUTAGENICITY: NOT CLASSIFIED
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET
CARCINOGENICITY: MAY CAUSE CANCER (ORAL).
BROMOCRESOL GREEN-METHYL RED, ALCOHOLIC:
IARC GROUP: 1 - CARCINOGENIC TO HUMANS
ETHANOL (64-17-5):
IARC GROUP: 1 - CARCINOGENIC TO HUMANS
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
IARC GROUP: 3 - NOT CLASSIFIABLE
REPRODUCTIVE TOXICITY: SUSPECTED OF DAMAGING THE UNBORN CHILD (ORAL).
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE):
CAUSES DAMAGE TO ORGANS (CENTRAL NERVOUS SYSTEM, OPTIC NERVE) (ORAL,
DERMAL).
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): NOT CLASSIFIED
ASPIRATION HAZARD: NOT CLASSIFIED
POTENTIAL ADVERSE HUMAN HEALTH EFFECTS AND SYMPTOMS:
HARMFUL IF SWALLOWED. BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA
ARE NOT MET.
SYMPTOMS/INJURIES AFTER INHALATION:
EXPOSURE TO HIGH CONCENTRATIONS:
DRY/SORE THROAT. COUGHING. IRRITATION OF THE RESPIRATORY TRACT. IRRITATION
OF THE NASAL MUCOUS MEMBRANES. RESPIRATORY DIFFICULTIES. CENTRAL NERVOUS
SYSTEM DEPRESSION. SYMPTOMS SIMILAR TO THOSE LISTED UNDER INGESTION.
SYMPTOMS/INJURIES AFTER SKIN CONTACT: SLIGHT IRRITATION.
SYMPTOMS/INJURIES AFTER EYE CONTACT:
REDNESS OF THE EYE TISSUE. LACRIMATION. ON CONTINUOUS EXPOSURE/CONTACT:
IRRITATION OF THE EYE TISSUE.
SYMPTOMS/INJURIES AFTER INGESTION:
AFTER ABSORPTION OF LARGE QUANTITIES:
RISK OF ASPIRATION PNEUMONIA. RED SKIN. BODY TEMPERATURE RISE. DAMP/CLAMMY
SKIN. EXCITED/RESTLESS. ACCELERATED HEART ACTION. CENTRAL NERVOUS SYSTEM
DEPRESSION. DIZZINESS. NARCOSIS. HEADACHE. DRUNKENNESS. NAUSEA. VOMITING.
DISTURBED MOTOR RESPONSE. COORDINATION DISORDERS. VISUAL DISTURBANCES.
IMPAIRED CONCENTRATION. DELUSIONS. DISTURBED SENSATION OF PAIN.
DISTURBANCES OF HEART RATE. DISTURBANCES OF CONSCIOUSNESS. TREMOR.
CRAMPS/UNCONTROLLED MUSCULAR CONTRACTIONS. DILATED PUPILS.
CHRONIC SYMPTOMS:
ON CONTINUOUS/REPEATED EXPOSURE/CONTACT:
DRY SKIN. GASTROINTESTINAL COMPLAINTS. ENLARGEMENT/AFFECTION OF THE LIVER.
CHANGE IN THE HAEMOGRAMME/BLOOD COMPOSITION. CARDIAC AND BLOOD CIRCULATION
EFFECTS. HIGH ARTERIAL PRESSURE. IMPAIRMENT OF THE NERVOUS SYSTEM.
BEHAVIORAL DISTURBANCES. MENTAL CONFUSION. DISTURBED TACTILE SENSIBILITY.
TREMOR. AFFECTION OF THE BONE MARROW. AFFECTION OF THE ENDOCRINE SYSTEM.
WEAKENING OF THE IMMUNE SYSTEM.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
ECOLOGY - GENERAL:
CLASSIFICATION CONCERNING THE ENVIRONMENT: NOT APPLICABLE.
ECOLOGY - AIR:
NOT CLASSIFIED AS DANGEROUS FOR THE OZONE LAYER (REGULATION (EC) NO
1005/2009). NOT INCLUDED IN THE LIST OF SUBSTANCES WHICH MAY CONTRIBUTE TO
THE GREENHOUSE EFFECT (REGULATION (EC) NO 842/2006). TA-LUFT KLASSE 5.2.5.
ECOLOGY - WATER:
NOT HARMFUL TO FISHES (LC50(96H) >1000 MG/L). NOT HARMFUL TO INVERTEBRATES
(DAPHNIA). SLIGHTLY HARMFUL TO ALGAE (EC50 (72H): 100 - 1000 MG/L). HARMFUL
TO PLANKTON. NOT HARMFUL TO BACTERIA (EC50 >1000 MG/L). NO INHIBITION OF
ACTIVATED SLUDGE.
BROMOCRESOL GREEN-METHYL RED, ALCOHOLIC:
LC50 FISH 1: 14200 MG/L (96 H; PIMEPHALES PROMELAS; NOMINAL CONCENTRATION)
EC50 DAPHNIA 1: 9300 MG/L (48 H; DAPHNIA MAGNA)
LC50 FISH 2: 13000 MG/L 96 H; SALMO GAIRDNERI (ONCORHYNCHUS MYKISS)
EC50 DAPHNIA 2: 10800 MG/L (24 H; DAPHNIA MAGNA)
ETHANOL (64-17-5):
LC50 FISH 1:
14200 MG/L (LC50; US EPA; 96 H; PIMEPHALES PROMELAS; FLOW-THROUGH SYSTEM;
FRESH WATER; EXPERIMENTAL VALUE)
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
LC50 FISH 2:
9640 MG/L (LC50; OECD 203: FISH, ACUTE TOXICITY TEST; 96 H; PIMEPHALES
PROMELAS; FLOW-THROUGH SYSTEM; FRESH WATER; EXPERIMENTAL VALUE)
EC50 DAPHNIA 2: 13299 MG/L (EC50; OTHER; 48 H; DAPHNIA MAGNA)
THRESHOLD LIMIT ALGAE 1:
>1000 MG/L (EC50; UBA; 72 H; SCENEDESMUS SUBSPICATUS)
METHANOL (67-56-1):
LC50 FISH 1:
15400 MG/L (LC50; EPA 660/3 - 75/009; 96 H; LEPOMIS MACROCHIRUS;
FLOW-THROUGH SYSTEM; FRESH WATER; EXPERIMENTAL VALUE)
EC50 DAPHNIA 1:
>10000 MG/L (EC50; DIN 38412-11; 48 H; DAPHNIA MAGNA; STATIC SYSTEM; FRESH
WATER; EXPERIMENTAL VALUE)
LC50 FISH 2: 10800 MG/L (LC50; 96 H; SALMO GAIRDNERI)
12.2. PERSISTENCE AND DEGRADABILITY:
BROMOCRESOL GREEN-METHYL RED, ALCOHOLIC:
PERSISTENCE AND DEGRADABILITY:
READILY BIODEGRADABLE IN WATER. BIODEGRADABLE IN THE SOIL. NO TEST DATA ON
MOBILITY OF THE SUBSTANCE AVAILABLE.
BIOCHEMICAL OXYGEN DEMAND (BOD): 0.8 - 0.967 G O2/G SUBSTANCE
CHEMICAL OXYGEN DEMAND (COD): 1.7 G O2/G SUBSTANCE
THOD: 2.1 G O2/G SUBSTANCE
BOD (% OF THOD): 0.43% THOD
ETHANOL (64-17-5):
PERSISTENCE AND DEGRADABILITY:
READILY BIODEGRADABLE IN WATER. BIODEGRADABLE IN THE SOIL. HIGHLY MOBILE IN
SOIL.
BIOCHEMICAL OXYGEN DEMAND (BOD): 0.8 - 0.967 G O2/G SUBSTANCE
CHEMICAL OXYGEN DEMAND (COD): 1.7 G O2/G SUBSTANCE
THOD: 2.1 G O2/G SUBSTANCE
BOD (% OF THOD): 0.43
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
PERSISTENCE AND DEGRADABILITY:
READILY BIODEGRADABLE IN WATER. BIODEGRADABLE IN THE SOIL. BIODEGRADABLE IN
THE SOIL UNDER ANAEROBIC CONDITIONS. NO TEST DATA ON MOBILITY OF THE
SUBSTANCE AVAILABLE.
BIOCHEMICAL OXYGEN DEMAND (BOD): 1.19 G O2/G SUBSTANCE
CHEMICAL OXYGEN DEMAND (COD): 2.23 G O2/G SUBSTANCE
THOD: 2.4 G O2/G SUBSTANCE
METHANOL (67-56-1):
PERSISTENCE AND DEGRADABILITY:
READILY BIODEGRADABLE IN WATER. BIODEGRADABLE IN THE SOIL. HIGHLY MOBILE IN
SOIL.
BIOCHEMICAL OXYGEN DEMAND (BOD): 0.6 - 1.12 G O2/G SUBSTANCE
CHEMICAL OXYGEN DEMAND (COD): 1.42 G O2/G SUBSTANCE
THOD: 1.5 G O2/G SUBSTANCE
BOD (% OF THOD): 0.8 (LITERATURE STUDY)
BROMOCRESOL GREEN, SODIUM SALT, ACS (62625-32-5):
PERSISTENCE AND DEGRADABILITY: NOT ESTABLISHED.
METHYL RED, SODIUM SALT, ACS (845-10-3):
PERSISTENCE AND DEGRADABILITY: NOT ESTABLISHED.
12.3. BIOACCUMULATIVE POTENTIAL:
BROMOCRESOL GREEN-METHYL RED, ALCOHOLIC:
BCF FISH 1:
1 (BCF; OTHER; 72 H; CYPRINUS CARPIO; STATIC SYSTEM; FRESH WATER;
READ-ACROSS)
LOG POW: -0.31 (EXPERIMENTAL VALUE)
BIOACCUMULATIVE POTENTIAL: LOW POTENTIAL FOR BIOACCUMULATION (LOG KOW <4).
ETHANOL (64-17-5):
BCF FISH 1:
1 (BCF; OTHER; 72 H; CYPRINUS CARPIO; STATIC SYSTEM; FRESH WATER;
READ-ACROSS)
LOG POW: -0.31 (EXPERIMENTAL VALUE)
BIOACCUMULATIVE POTENTIAL: LOW POTENTIAL FOR BIOACCUMULATION (LOG KOW <4).
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
LOG POW: 0.05 (WEIGHT OF EVIDENCE APPROACH; OTHER; 25 DEG. C)
BIOACCUMULATIVE POTENTIAL:
LOW POTENTIAL FOR BIOACCUMULATION (LOG KOW <4).
METHANOL (67-56-1):
BCF FISH 1: <10 (BCF; 72 H; LEUCISCUS IDUS)
LOG POW: -0.77 (EXPERIMENTAL VALUE; OTHER)
BIOACCUMULATIVE POTENTIAL: LOW POTENTIAL FOR BIOACCUMULATION (BCF <500).
BROMOCRESOL GREEN, SODIUM SALT, ACS (62625-32-5):
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
METHYL RED, SODIUM SALT, ACS (845-10-3):
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
12.4. MOBILITY IN SOIL:
BROMOCRESOL GREEN-METHYL RED, ALCOHOLIC:
SURFACE TENSION: 0.022 N/M (20 DEG. C)
LOG KOC: KOC, PCKOCWIN V1.66; 1; READ-ACROSS
ETHANOL (64-17-5):
SURFACE TENSION: 0.022 N/M (20 DEG. C)
LOG KOC: KOC, PCKOCWIN V1.66; 1; READ-ACROSS
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
SURFACE TENSION: 0.021 N/M (25 DEG. C)
METHANOL (67-56-1):
SURFACE TENSION: 0.023 N/M (20 DEG. C)
LOG KOC: KOC, PCKOCWIN V1.66; 1; CALCULATED VALUE
12.5. OTHER ADVERSE EFFECTS:
EFFECT ON THE GLOBAL WARMING: NO KNOWN EFFECTS FROM THIS PRODUCT.
GWPMIX COMMENT: NO KNOWN EFFECTS FROM THIS PRODUCT.
OTHER INFORMATION: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. WASTE TREATMENT METHODS:
WASTE DISPOSAL RECOMMENDATIONS:
REMOVE WASTE IN ACCORDANCE WITH LOCAL AND/OR NATIONAL REGULATIONS.
HAZARDOUS WASTE SHALL NOT BE MIXED TOGETHER WITH OTHER WASTE. DIFFERENT
TYPES OF HAZARDOUS WASTE SHALL NOT BE MIXED TOGETHER IF THIS MAY ENTAIL A
RISK OF POLLUTION OR CREATE PROBLEMS FOR THE FURTHER MANAGEMENT OF THE
WASTE. HAZARDOUS WASTE SHALL BE MANAGED RESPONSIBLY. ALL ENTITIES THAT
STORE, TRANSPORT OR HANDLE HAZARDOUS WASTE SHALL TAKE THE NECESSARY
MEASURES TO PREVENT RISKS OF POLLUTION OR DAMAGE TO PEOPLE OR ANIMALS.
RECYCLE BY DISTILLATION. REMOVE TO AN AUTHORIZED WASTE INCINERATOR FOR
SOLVENTS WITH ENERGY RECOVERY. DO NOT DISCHARGE INTO SURFACE WATER. MAY BE
DISCHARGED TO WASTEWATER TREATMENT INSTALLATION.
ADDITIONAL INFORMATION:
LWCA (THE NETHERLANDS):
KGA CATEGORY 03. HAZARDOUS WASTE ACCORDING TO DIRECTIVE 2008/98/EC.
ECOLOGY - WASTE MATERIALS: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 14: TRANSPORT INFORMATION | |
DEPARTMENT OF TRANSPORTATION (DOT):
IN ACCORDANCE WITH DOT:
TRANSPORT DOCUMENT DESCRIPTION: UN1170 ETHANOL SOLUTIONS, 3, II
UN-NO.(DOT): UN1170
PROPER SHIPPING NAME (DOT): ETHANOL SOLUTIONS
TRANSPORT HAZARD CLASS(ES) (DOT):
3 - CLASS 3 - FLAMMABLE AND COMBUSTIBLE LIQUID 49 CFR 173.120
PACKING GROUP (DOT): II - MEDIUM DANGER
HAZARD LABELS (DOT): 3 - FLAMMABLE LIQUID
DOT PACKAGING NON BULK (49 CFR 173.XXX): 202
DOT PACKAGING BULK (49 CFR 173.XXX): 242
DOT SPECIAL PROVISIONS (49 CFR 172.102):
24 - ALCOHOLIC BEVERAGES CONTAINING MORE THAN 70 PERCENT ALCOHOL BY VOLUME
MUST BE TRANSPORTED AS MATERIALS IN PACKING GROUP II. ALCOHOLIC BEVERAGES
CONTAINING MORE THAN 24 PERCENT BUT NOT MORE THAN 70 PERCENT ALCOHOL BY
VOLUME MUST BE TRANSPORTED AS MATERIALS IN PACKING GROUP III.
IB2 - AUTHORIZED IBCS: METAL (31A, 31B AND 31N); RIGID PLASTICS (31H1 AND
31H2); COMPOSITE (31HZ1). ADDITIONAL REQUIREMENT: ONLY LIQUIDS WITH A VAPOR
PRESSURE LESS THAN OR EQUAL TO 110 KPA AT 50 C (1.1 BAR AT 122 F), OR 130
KPA AT 55 C (1.3 BAR AT 131 F) ARE AUTHORIZED.
T4 - 2.65 178.274(D)(2) NORMAL............. 178.275(D)(3)
TP1 - THE MAXIMUM DEGREE OF FILLING MUST NOT EXCEED THE DEGREE OF FILLING
DETERMINED BY THE FOLLOWING: DEGREE OF FILLING = 97 / 1 + A (TR - TF)
WHERE: TR IS THE MAXIMUM MEAN BULK TEMPERATURE DURING TRANSPORT, AND TF IS
THE TEMPERATURE IN DEGREES CELSIUS OF THE LIQUID DURING FILLING.
DOT PACKAGING EXCEPTIONS (49 CFR 173.XXX): 4B;150
DOT QUANTITY LIMITATIONS PASSENGER AIRCRAFT/RAIL (49 CFR 173.27): 5 L
DOT QUANTITY LIMITATIONS CARGO AIRCRAFT ONLY (49 CFR 175.75): 60 L
DOT VESSEL STOWAGE LOCATION:
A - THE MATERIAL MAY BE STOWED "ON DECK" OR "UNDER DECK" ON A CARGO VESSEL
AND ON A PASSENGER VESSEL.
OTHER INFORMATION: NO SUPPLEMENTARY INFORMATION AVAILABLE.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
ALL COMPONENTS OF THIS PRODUCT ARE LISTED, OR EXCLUDED FROM LISTING, ON THE
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY TOXIC SUBSTANCES CONTROL ACT
(TSCA) INVENTORY
CHEMICAL(S) SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OR TITLE
III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND
40 CFR PART 372.
ISOPROPYL ALCOHOL (2-PROPANOL) CAS NO 67-63-0 5%
METHANOL CAS NO 67-56-1 4.5%
METHANOL (67-56-1):
RQ (REPORTABLE QUANTITY, SECTION 304 OF EPA'S LIST OF LISTS): 5000 LB
SARA SECTION 311/312 HAZARD CLASSES:
IMMEDIATE (ACUTE) HEALTH HAZARD
FIRE HAZARD
15.2. INTERNATIONAL REGULATIONS:
CANADA:
BROMOCRESOL GREEN-METHYL RED, ALCOHOLIC:
WHMIS CLASSIFICATION:
CLASS B DIVISION 2 - FLAMMABLE LIQUID
CLASS D DIVISION 1 SUBDIVISION B - TOXIC MATERIAL CAUSING IMMEDIATE AND
SERIOUS TOXIC EFFECTS
CLASS D DIVISION 2 SUBDIVISION A - VERY TOXIC MATERIAL CAUSING OTHER TOXIC
EFFECTS
CLASS D DIVISION 2 SUBDIVISION B - TOXIC MATERIAL CAUSING OTHER TOXIC
EFFECTS
ISOPROPYL ALCOHOL (2-PROPANOL) (67-63-0):
WHMIS CLASSIFICATION:
CLASS B DIVISION 2 - FLAMMABLE LIQUID
CLASS D DIVISION 2 SUBDIVISION B - TOXIC MATERIAL CAUSING OTHER TOXIC
EFFECTS
METHANOL (67-56-1):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
WHMIS CLASSIFICATION:
CLASS B DIVISION 2 - FLAMMABLE LIQUID
CLASS D DIVISION 2 SUBDIVISION A - VERY TOXIC MATERIAL CAUSING OTHER TOXIC
EFFECTS
CLASS D DIVISION 2 SUBDIVISION B - TOXIC MATERIAL CAUSING OTHER TOXIC
EFFECTS
BROMOCRESOL GREEN, SODIUM SALT, ACS (62625-32-5):
WHMIS CLASSIFICATION:
UNCONTROLLED PRODUCT ACCORDING TO WHMIS CLASSIFICATION CRITERIA
METHYL RED, SODIUM SALT, ACS (845-10-3):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
WHMIS CLASSIFICATION:
UNCONTROLLED PRODUCT ACCORDING TO WHMIS CLASSIFICATION CRITERIA
EU-REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
NATIONAL REGULATIONS:
ETHANOL (64-17-5):
LISTED ON IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER)
BROMOCRESOL GREEN, SODIUM SALT, ACS (62625-32-5):
NOT LISTED ON THE CANADIAN IDL (INGREDIENT DISCLOSURE LIST)
METHYL RED, SODIUM SALT, ACS (845-10-3):
NOT LISTED ON THE CANADIAN IDL (INGREDIENT DISCLOSURE LIST)
15.3. US STATE REGULATIONS:
BROMOCRESOL GREEN-METHYL RED, ALCOHOLIC:
U.S. - CALIFORNIA - PROPOSITION 65 - CARCINOGENS LIST: NO
U.S. - CALIFORNIA - PROPOSITION 65 - DEVELOPMENTAL TOXICITY: YES
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - FEMALE: NO
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - MALE: NO
CALIFORNIA PROPOSITION 65 - THIS PRODUCT CONTAINS, OR MAY CONTAIN, TRACE
QUANTITIES OF A SUBSTANCE(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER, DEVELOPMENTAL AND/OR REPRODUCTIVE HARM
METHANOL (67-56-1):
U.S. - CALIFORNIA - PROPOSITION 65 - CARCINOGENS LIST: NO
U.S. - CALIFORNIA - PROPOSITION 65 - DEVELOPMENTAL TOXICITY: YES
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - FEMALE: NO
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - MALE: NO
NON-SIGNIFICANT RISK LEVEL (NSRL)
| SECTION 16: OTHER INFORMATION | |
REVISION DATE: 12/19/2016
OTHER INFORMATION: NONE.
FULL TEXT OF H-PHRASES: SEE SECTION 16
H225: HIGHLY FLAMMABLE LIQUID AND VAPOR
H301: TOXIC IF SWALLOWED
H311: TOXIC IN CONTACT WITH SKIN
H319: CAUSES SERIOUS EYE IRRITATION
H331: TOXIC IF INHALED
H335: MAY CAUSE RESPIRATORY IRRITATION
H350: MAY CAUSE CANCER
H361: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD
H370: CAUSES DAMAGE TO ORGANS
NFPA HEALTH HAZARD 2 - INTENSE OR CONTINUED EXPOSURE COULD CAUSE TEMPORARY
INCAPACITATION OR POSSIBLE RESIDUAL INJURY UNLESS
PROMPT MEDICAL ATTENTION IS GIVEN.
NFPA FIRE HAZARD 3 - LIQUIDS AND SOLIDS THAT CAN BE IGNITED UNDER ALMOST
ALL AMBIENT CONDITIONS.
NFPA REACTIVITY 0 - NORMALLY STABLE, EVEN UNDER FIRE EXPOSURE
CONDITIONS, AND ARE NOT REACTIVE WITH WATER.
HMIS III RATING:
HEALTH 2 MODERATE HAZARD - TEMPORARY OR MINOR INJURY MAY OCCUR
FLAMMABILITY 3 SERIOUS HAZARD - MATERIALS CAPABLE OF IGNITION UNDER
ALMOST ALL NORMAL TEMPERATURE CONDITIONS. INCLUDES
FLAMMABLE LIQUIDS WITH FLASH POINTS BELOW 73 F AND
BOILING POINTS ABOVE 100 F. AS WELL AS LIQUIDS WITH
FLASH POINTS BETWEEN 73 F AND 100 F. (CLASSES IB &
IC)
PHYSICAL 0 MINIMAL HAZARD - MATERIALS THAT ARE NORMALLY STABLE,
EVEN UNDER FIRE CONDITIONS, AND WILL NOT REACT WITH
WATER, POLYMERIZE, DECOMPOSE, CONDENSE, OR
SELF-REACT. NON-EXPLOSIVES.
PERSONAL PROTECTION B
B - SAFETY GLASSES, GLOVES
SDS US LABCHEM
INFORMATION IN THIS SDS IS FROM AVAILABLE PUBLISHED SOURCES AND IS BELIEVED
TO BE ACCURATE. NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AND LABCHEM INC
ASSUMES NO LIABILITY RESULTING FROM THE USE OF THIS SDS. THE USER MUST
DETERMINE SUITABILITY OF THIS INFORMATION FOR HIS APPLICATION.
EN (ENGLISH US)