| Common Name: | ORP STANDARD, 200MV |
| Manufacturer: | W.W. GRAINGER |
| SDS Revision Date: | 8/19/2013 |
| SDS Format: | GHS-US |
| Item Number(s): | 8ELA2 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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LSS
ORP STANDARD, 200MV
SAFETY DATA SHEET
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26, 2012 /
RULES AND REGULATIONS
DATE OF ISSUE: 08/30/2006
REVISION DATE: 08/19/2013
SUPERSEDES: 10/26/2009
VERSION: 1.0
| SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE |  |
AND OF THE COMPANY/UNDERTAKING
1.1. PRODUCT IDENTIFIER:
PRODUCT FORM: MIXTURE
PRODUCT NAME: ORP STANDARD, 200MV
PRODUCT CODE: 8ELA2
1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
USE OF THE SUBSTANCE/MIXTURE: FOR LABORATORY AND MANUFACTURING USE ONLY.
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
W. W. GRAINGER INC.
60045 LAKE FOREST
IL - U.S.A.
T: 1-800-356-0783
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER: 1-800-535-5053
| SECTION 2: HAZARDS IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS-US CLASSIFICATION: NOT CLASSIFIED
2.2. LABEL ELEMENTS:
GHS-US LABELLING: NO LABELLING APPLICABLE
2.3. OTHER HAZARDS:
OTHER HAZARDS NOT CONTRIBUTING TO THE CLASSIFICATION: NONE.
2.4. UNKNOWN ACUTE TOXICITY (GHS-US): NO DATA AVAILABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCE: NOT APPLICABLE
FULL TEXT OF H-PHRASES: SEE SECTION 16
3.2. MIXTURE
NAME PRODUCT IDENTIFIER % GHS-US CLASSIFICATION
WATER (CAS NO) 7732-18-5 98.64 NOT CLASSIFIED
POTASSIUM CHLORIDE (CAS NO) 7447-40-7 0.75 NOT CLASSIFIED
POTASSIUM FERROCYANIDE, (CAS NO) 14459-95-1 0.53 NOT CLASSIFIED
TRIHYDRATE
POTASSIUM FERRICYANIDE (CAS NO) 13746-66-2 0.08 NOT CLASSIFIED
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES GENERAL:
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF YOU FEEL UNWELL,
SEEK MEDICAL ADVICE (SHOW THE LABEL WHERE POSSIBLE).
FIRST-AID MEASURES AFTER INHALATION:
ASSURE FRESH AIR BREATHING. ALLOW THE VICTIM TO REST.
FIRST-AID MEASURES AFTER SKIN CONTACT:
REMOVE AFFECTED CLOTHING AND WASH ALL EXPOSED SKIN AREA WITH MILD SOAP AND
WATER, FOLLOWED BY WARM WATER RINSE.
FIRST-AID MEASURES AFTER EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER. OBTAIN MEDICAL ATTENTION IF PAIN,
BLINKING OR REDNESS PERSIST.
FIRST-AID MEASURES AFTER INGESTION:
RINSE MOUTH. DO NOT INDUCE VOMITING. OBTAIN EMERGENCY MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS/INJURIES:
NOT EXPECTED TO PRESENT A SIGNIFICANT HAZARD UNDER ANTICIPATED CONDITIONS
OF NORMAL USE.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 5: FIREFIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
FOAM. DRY POWDER. CARBON DIOXIDE. WATER SPRAY. SAND.
UNSUITABLE EXTINGUISHING MEDIA: DO NOT USE A HEAVY WATER STREAM.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NO ADDITIONAL INFORMATION AVAILABLE
5.3. ADVICE FOR FIREFIGHTERS:
FIREFIGHTING INSTRUCTIONS:
USE WATER SPRAY OR FOG FOR COOLING EXPOSED CONTAINERS. EXERCISE CAUTION
WHEN FIGHTING ANY CHEMICAL FIRE. PREVENT FIRE-FIGHTING WATER FROM ENTERING
ENVIRONMENT.
PROTECTION DURING FIREFIGHTING:
DO NOT ENTER FIRE AREA WITHOUT PROPER PROTECTIVE EQUIPMENT, INCLUDING
RESPIRATORY PROTECTION.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
6.1.1. FOR NON-EMERGENCY PERSONNEL:
PROTECTIVE EQUIPMENT: SAFETY GLASSES.
EMERGENCY PROCEDURES: EVACUATE UNNECESSARY PERSONNEL.
6.1.2. FOR EMERGENCY RESPONDERS:
PROTECTIVE EQUIPMENT: EQUIP CLEANUP CREW WITH PROPER PROTECTION.
EMERGENCY PROCEDURES: VENTILATE AREA.
6.2. ENVIRONMENTAL PRECAUTIONS:
PREVENT ENTRY TO SEWERS AND PUBLIC WATERS. NOTIFY AUTHORITIES IF LIQUID
ENTERS SEWERS OR PUBLIC WATERS.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CLEANING UP:
SOAK UP SPILLS WITH INERT SOLIDS, SUCH AS CLAY OR DIATOMACEOUS EARTH AS
SOON AS POSSIBLE. COLLECT SPILLAGE. STORE AWAY FROM OTHER MATERIALS.
6.4. REFERENCE TO OTHER SECTIONS:
SEE HEADING 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
PRECAUTIONS FOR SAFE HANDLING:
WASH HANDS AND OTHER EXPOSED AREAS WITH MILD SOAP AND WATER BEFORE EATING,
DRINKING OR SMOKING AND WHEN LEAVING WORK. PROVIDE GOOD VENTILATION IN
PROCESS AREA TO PREVENT FORMATION OF VAPOUR.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE CONDITIONS: KEEP CONTAINER CLOSED WHEN NOT IN USE.
INCOMPATIBLE PRODUCTS: STRONG OXIDIZERS. STRONG ACIDS.
INCOMPATIBLE MATERIALS: SOURCES OF IGNITION. DIRECT SUNLIGHT.
7.3. SPECIFIC END USE(S): NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
POTASSIUM FERRICYANIDE (13746-66-2):
USA ACGIH:
ACGIH TWA (MG/M3): 1 MG/M3 IRON SALTS, SOLUBLE, AS Fe
POTASSIUM FERROCYANIDE, TRIHYDRATE (14459-95-1):
USA ACGIH:
ACGIH TWA (MG/M3): 1 MG/M3 IRON SALTS, SOLUBLE, AS Fe
8.2. EXPOSURE CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
EMERGENCY EYE WASH FOUNTAINS AND SAFETY SHOWERS SHOULD BE AVAILABLE IN THE
IMMEDIATE VICINITY OF ANY POTENTIAL EXPOSURE. PROVIDE ADEQUATE GENERAL AND
LOCAL EXHAUST VENTILATION.
PERSONAL PROTECTIVE EQUIPMENT: AVOID ALL UNNECESSARY EXPOSURE.
HAND PROTECTION: WEAR PROTECTIVE GLOVES.
EYE PROTECTION: CHEMICAL GOGGLES OR SAFETY GLASSES.
RESPIRATORY PROTECTION: WEAR APPROPRIATE MASK.
OTHER INFORMATION: DO NOT EAT, DRINK OR SMOKE DURING USE.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
APPEARANCE: LIQUID.
COLOUR: YELLOW.
ODOUR: ODOURLESS.
ODOUR THRESHOLD: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
RELATIVE EVAPORATION RATE (BUTYLACETATE=1): NO DATA AVAILABLE
MELTING POINT: NO DATA AVAILABLE
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: NO DATA AVAILABLE
FLASH POINT: NO DATA AVAILABLE
SELF IGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
VAPOUR PRESSURE: NO DATA AVAILABLE
RELATIVE VAPOUR DENSITY AT 20 DEG. C: NO DATA AVAILABLE
RELATIVE DENSITY: NO DATA AVAILABLE
DENSITY: 1 G/ML
SOLUBILITY: SOLUBLE IN WATER.
LOG POW: NO DATA AVAILABLE
LOG KOW: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
EXPLOSIVE PROPERTIES: NO DATA AVAILABLE
OXIDISING PROPERTIES: NO DATA AVAILABLE
EXPLOSIVE LIMITS: NO DATA AVAILABLE
9.2. OTHER INFORMATION: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY: NO ADDITIONAL INFORMATION AVAILABLE
10.2. CHEMICAL STABILITY: NOT ESTABLISHED.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS: NOT ESTABLISHED.
10.4. CONDITIONS TO AVOID:
DIRECT SUNLIGHT. EXTREMELY HIGH OR LOW TEMPERATURES.
10.5. INCOMPATIBLE MATERIALS: STRONG ACIDS. STRONG OXIDIZERS.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
POTASSIUM OXIDE. CARBON MONOXIDE. CARBON DIOXIDE.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY: NOT CLASSIFIED
POTASSIUM FERRICYANIDE (13746-66-2):
LDS50 ORAL RAT: 2970 MG/KG
POTASSIUM FERROCYANIDE, TRIHYDRATE (14459-95-1):
LDS50 ORAL RAT: 3613 MG/KG
WATER (7732-18-5):
LDS50 ORAL RAT: >/=90000 MG/KG
POTASSIUM CHLORIDE (7447-40-7):
LDS50 ORAL RAT: 2600 MG/KG
SKIN CORROSION/IRRITATION: NOT CLASSIFIED
SERIOUS EYE DAMAGE/IRITATION: NOT CLASSIFIED
RESPIRATORY OR SKIN SENSITISATION: NOT CLASSIFIED
GEM CELL MUTAGENICITY: NOT CLASSIFIED
CARCINOGENICITY: NOT CLASSIFIED
REPRODUCTIVE TOXICITY: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): NOT CLASSIFIED
ASPIRATION HAZARD: NOT CLASSIFIED
POTENTIAL ADVERSE HUMAN HEALTH EFFECTS AND SYMPTOMS:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
POTASSIUM FERRICYANIDE (13746-66-2):
LC50 FISHES 1: 869 MG/L
EC50 DAPHNIA 1: 549 MG/L
POTASSIUM CHLORIDE (7447-40-7):
ECS50 DAPHNIA 1: 825 MG/L
12.2. PERSISTENCE AND DEGRADABILITY
ORP STANDARD, 200MV:
PERSISTENCE AND DEGRADABILITY: NOT ESTABLISHED.
POTASSIUM FERRICYANIDE (13746-66-2):
PERSISTENCE AND DEGRADABILITY: NOT ESTABLISHED.
POTASSIUM FERROCYANIDE, TRIHYDRATE (14459-95-1):
PERSISTENCE AND DEGRADABILITY: NOT ESTABLISHED.
WATER (7732-18-5):
PERSISTENCE AND DEGRADABILITY: NOT ESTABLISHED.
POTASSIUM CHLORIDE (7447-40-7):
PERSISTENCE AND DEGRADABILITY: NOT ESTABLISHED.
12.3. BIOACCUMULATIVE POTENTIAL:
ORP STANDARD, 200MV:
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
POTASSIUM FERRICYANIDE (13746-66-2):
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
POTASSIUM FERROCYANIDE, TRIHYDRATE (14459-95-1):
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
WATER (7732-18-5):
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
POTASSIUM CHLORIDE (7447-40-7):
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
12.4. MOBILITY IN SOIL: NO ADDITIONAL INFORMATION AVAILABLE
12.5. OTHER ADVERSE EFFECTS:
OTHER INFORMATION: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. WASTE TREATMENT METHODS:
WASTE DISPOSAL RECOMMENDATIONS:
DISPOSE IN A SAFE MANNER IN ACCORDANCE WITH LOCAL/NATIONAL REGULATIONS.
ECOLOGY - WASTE MATERIALS: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 14: TRANSPORT INFORMATION | |
IN ACCORDANCE WITH ADR / RID / IMDG / IATA / ADN:
14.1. UN NUMBER: NOT APPLICABLE
14.2. UN PROPER SHIPPING NAME: NOT APPLICABLE
14.3. ADDITIONAL INFORMATION:
OTHER INFORMATION: NO SUPPLEMENTARY INFORMATION AVAILABLE.
OVERLAND TRANSPORT: NO ADDITIONAL INFORMATION AVAILABLE
TRANSPORT BY SEA: NO ADDITIONAL INFORMATION AVAILABLE
AIR TRANSPORT: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
POTASSIUM FERRICYANIDE (13746-66-2):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
POTASSIUM FERROCYANIDE, TRIHYDRATE (14459-95-1):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
WATER (7732-18-5):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
POTASSIUM CHLORIDE (7447-40-7):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
15.2. INTERNATIONAL REGULATIONS:
CANADA:
ORP STANDARD, 200MV:
WHMIS CLASSIFICATION:
UNCONTROLLED PRODUCT ACCORDING TO WHMIS CLASSIFICATION CRITERIA
POTASSIUM FERRICYANIDE (13746-66-2):
LISTED ON THE CANADIAN DSL (DOMESTIC SUSTANCES LIST) INVENTORY.
WHMIS CLASSIFICATION:
UNCONTROLLED PRODUCT ACCORDING TO WHMIS CLASSIFICATION CRITERIA
POTASSIUM FERROCYANIDE, TRIHYDRATE (14459-95-1):
NOT LISTED ON THE CANADIAN DSL (DOMESTIC SUSTANCES LIST) INVENTORY.
WHMIS CLASSIFICATION:
UNCONTROLLED PRODUCT ACCORDING TO WHMIS CLASSIFICATION CRITERIA
WATER (7732-18-5):
LISTED ON THE CANADIAN DSL (DOMESTIC SUSTANCES LIST) INVENTORY.
WHMIS CLASSIFICATION:
UNCONTROLLED PRODUCT ACCORDING TO WHMIS CLASSIFICATION CRITERIA
POTASSIUM CHLORIDE (7447-40-7):
LISTED ON THE CANADIAN DSL (DOMESTIC SUSTANCES LIST) INVENTORY.
WHMIS CLASSIFICATION:
UNCONTROLLED PRODUCT ACCORDING TO WHMIS CLASSIFICATION CRITERIA
EU-REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
CLASSIFICATION ACCORDING TO REGULATION (EC) NO. 1272/2008 [CLP]:
CLASSIFICATION ACCORDING TO DIRECTIVE 67/548/EEC OR 1999/45/EC:
NOT CLASSIFIED
15.2.2. NATIONAL REGULATIONS:
POTASSIUM FERRICYANIDE (13746-66-2):
NOT LISTED ON THE CANADIAN INGREDIENT DISCLOSURE LIST
POTASSIUM FERROCYANIDE, TRIHYDRATE (14459-95-1):
NOT LISTED ON THE CANADIAN INGREDIENT DISCLOSURE LIST
WATER (7732-18-5):
NOT LISTED ON THE CANADIAN INGREDIENT DISCLOSURE LIST
POTASSIUM CHLORIDE (7447-40-7):
NOT LISTED ON THE CANADIAN INGREDIENT DISCLOSURE LIST
15.3. US STATE REGULATIONS:
NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 16: OTHER INFORMATION | |
OTHER INFORMATION: NONE.
NFPA HEALTH HAZARD 1 - EXPOSURE COULD CAUSE IRRITATION BUT ONLY MINOR
RESIDUAL INJURY EVEN IF NO TREATMENT IS GIVEN.
NFPA FIRE HAZARD 0 - MATERIALS THAT WILL NOT BURN.
NFPA REACTIVITY 0 - NORMALLY STABLE, EVEN UNDER FIRE EXPOSURE
CONDITIONS, AND ARE NOT REACTIVE WITH WATER.
NFPA:
1
0
0
HMIS III RATING:
HEALTH 1 SLIGHT HAZARD - IRRITATION OR MINOR REVERSIBLE
INJURY POSSIBLE
FLAMMABILITY 0 MINIMAL HAZARD
PHYSICAL 0 MINIMAL HAZARD
PERSONAL PROTECTION B
SDS US GRAINGER:
THIS INFORMATION IS BASED ON OUR CURRENT KNOWLEDGE AND IS INTENDED TO
DESCRIBE THE PRODUCT FOR THE PURPOSES OF HEAITH, SAFETY AND ENVIRONMENTAL
REQUIREMENTS ONLY. IT SHOUID NOT THEREFORE BE CONSTRUED AS GUARANTEEING
ANY SPECIFIC PROPERTY OF THE PRODUCT
04/09/2014
EN (ENGLISH)