| Common Name: | CHROMIUM TRIOXIDE, ACS |
| Manufacturer: | LABCHEM |
| SDS Revision Date: | 1/24/2020 |
| SDS Format: | GHS-US |
| Item Number(s): | 8FV43 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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LABCHEM
PERFORMANCE THROUGH CHEMISTRY
CHROMIUM TRIOXIDE, ACS
SAFETY DATA SHEET
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY,
MARCH 26, 2012 / RULES AND REGULATIONS
DATE OF ISSUE: 10/18/2013
REVISION DATE: 01/24/2020
SUPERSEDES: 03/12/2019
VERSION: 2.1
| SECTION 1: IDENTIFICATION |  |
1.1. IDENTIFICATION:
PRODUCT FORM: SUBSTANCE
SUBSTANCE NAME: CHROMIUM TRIOXIDE, ACS
CAS-NO.: 1333-82-0
PRODUCT CODE: LC13090
FORMULA: CrO3
SYNONYMS:
CHROMIA / CHROMIUM (VI) OXIDE / CHROMIC ANHYDRIDE / CHROMIC TRIOXIDE /
CHROMIC ACID / CHROMIUM ANHYDRIDE / CHROMIUM OXIDE,RED / MONOCHROMIUM
OXIDE / RED OXIDE OF CHROMIUM
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
USE OF THE SUBSTANCE/MIXTURE:
OXIDANT
REAGENT
RESTRICTIONS ON USE: NOT FOR FOOD, DRUG OR HOUSEHOLD USE
1.3. SUPPLIER:
LABCHEM, INC.
JACKSON'S POINTE COMMERCE PARK BUILDING 1000, 1010 JACKSON'S POINTE COURT
ZELIENOPLE, PA 16063
USA
T: 412-826-5230
F: 724-473-0647
INFO@LABCHEM.COM - WWW.LABCHEM.COM
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER:
CHEMTREC: 1-800-424-9300 OR +1-703-741-5970
| SECTION 2: HAZARD(S) IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS US CLASSIFICATION:
OXIDIZING SOLIDS CATEGORY 1:
H271: MAY CAUSE FIRE OR EXPLOSION; STRONG OXIDIZER
ACUTE TOXICITY (ORAL) CATEGORY 3:
H301: TOXIC IF SWALLOWED
ACUTE TOXICITY (DERMAL) CATEGORY 2:
H310: FATAL IN CONTACT WITH SKIN
ACUTE TOXICITY (INHALATION: DUST,MIST)
CATEGORY 2:
H330: FATAL IF INHALED
SKIN CORROSION/IRRITATION CATEGORY 1A:
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE
RESPIRATORY SENSITIZATION, CATEGORY 1:
H334:
MAY CAUSE AN ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF
INHALED
SKIN SENSITIZATION, CATEGORY 1:
H317: MAY CAUSE AN ALLERGIC SKIN REACTION
GERM CELL MUTAGENICITY CATEGORY 1B:
H340: MAY CAUSE GENETIC DEFECTS
CARCINOGENICITY CATEGORY 1A:
H350: MAY CAUSE CANCER (INHALATION)
REPRODUCTIVE TOXICITY CATEGORY 2:
H361: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) CATEGORY 1:
H372:
CAUSES DAMAGE TO ORGANS (KIDNEYS, LIVER, RESPIRATORY SYSTEM, SKIN, EYES)
THROUGH PROLONGED OR REPEATED EXPOSURE
HAZARDOUS TO THE AQUATIC ENVIRONMENT - ACUTE HAZARD CATEGORY 1:
H400: VERY TOXIC TO AQUATIC LIFE
HAZARDOUS TO THE AQUATIC ENVIRONMENT - CHRONIC HAZARD CATEGORY 1:
H410: VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS
FULL TEXT OF H STATEMENTS: SEE SECTION 16
2.2. GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENTS:
GHS US LABELING:
HAZARD PICTOGRAMS (GHS US):
FLAME OVER CIRCLE
CORROSION
SKULLS AND CROSSBONES
HEALTH HAZARD
ENVIRONMENT
SIGNAL WORD (GHS US): DANGER
HAZARD STATEMENTS (GHS US):
H271: MAY CAUSE FIRE OR EXPLOSION; STRONG OXIDIZER
H301: TOXIC IF SWALLOWED
H310+H330: FATAL IN CONTACT WITH SKIN OR IF INHALED
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE
H317: MAY CAUSE AN ALLERGIC SKIN REACTION
H334:
MAY CAUSE AN ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF
INHALED
H340: MAY CAUSE GENETIC DEFECTS
H350: MAY CAUSE CANCER (INHALATION)
H361: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD
H372:
CAUSES DAMAGE TO ORGANS (KIDNEYS, LIVER, RESPIRATORY SYSTEM, SKIN, EYES)
THROUGH PROLONGED OR REPEATED EXPOSURE
H410: VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS
PRECAUTIONARY STATEMENTS (GHS US):
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
P210: KEEP AWAY FROM HEAT, SPARKS, OPEN FLAMES. - NO SMOKING.
P220: KEEP/STORE AWAY FROM CLOTHING, COMBUSTIBLE MATERIALS
P221: TAKE ANY PRECAUTION TO AVOID MIXING WITH COMBUSTIBLES
P260: DO NOT BREATHE DUST.
P262: DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING.
P264: WASH EXPOSED SKIN THOROUGHLY AFTER HANDLING.
P270: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
P271:
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA. CONTAMINATED WORK CLOTHING
MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
P273: AVOID RELEASE TO THE ENVIRONMENT.
P280:
WEAR PROTECTIVE GLOVES, PROTECTIVE CLOTHING, EYE PROTECTION, FACE
PROTECTION.
P283: WEAR FIRE/FLAME RESISTANT/RETARDANT CLOTHING.
P284: WEAR RESPIRATORY PROTECTION.
P301+P330+P331:
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING.
P303+P361+P353:
IF ON SKIN (OR HAIR):
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
P304+P340:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
P306+P360:
IF ON CLOTHING:
RINSE IMMEDIATELY CONTAMINATED CLOTHING AND SKIN WITH PLENTY OF WATER
BEFORE REMOVING CLOTHES
P308+P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
P310: IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
P363: WASH CONTAMINATED CLOTHING BEFORE REUSE.
P370+P378:
IN CASE OF FIRE:
USE CARBON DIOXIDE (CO2), POWDER, ALCOHOL-RESISTANT FOAM TO EXTINGUISH
P371+P380+P375:
IN CASE OF MAJOR FIRE AND LARGE QUANTITIES:
EVACUATE AREA. FIGHT FIRE REMOTELY DUE TO THE RISK OF EXPLOSION.
P391: COLLECT SPILLAGE.
P403+P233: STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
P405: STORE LOCKED UP.
P501:
DISPOSE OF CONTENTS/CONTAINER TO COMPLY WITH LOCAL, STATE AND FEDERAL
REGULATIONS.
2.3. OTHER HAZARDS WHICH DO NOT RESULT IN CLASSIFICATION:
OTHER HAZARDS NOT CONTRIBUTING TO THE CLASSIFICATION: NONE.
2.4. UNKNOWN ACUTE TOXICITY (GHS US): NOT APPLICABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCES:
SUBSTANCE TYPE: MONO-CONSTITUENT
NAME PRODUCT IDENTIFIER % GHS US CLASSIFICATION
CHROMIUM TRIOXIDE, ACS (CAS-NO.) 1333-82-0 100 OX. SOL. 1, H271
(MAIN CONSTITUENT) ACUTE TOX. 3 (ORAL), H301
ACUTE TOX. 2 (DERMAL),
H310
ACUTE TOX. 2
(INHALATION: DUST,MIST),
H330
SKIN CORR. 1A, H314
RESP. SENS. 1, H334
SKIN SENS. 1, H317
MUTA. 1B, H340
CARC. 1A, H350
REPR. 2, H361
STOT RE 1, H372
AQUATIC ACUTE 1, H400
AQUATIC CHRONIC 1, H410
FULL TEXT OF HAZARD CLASSES AND H-STATEMENTS: SEE SECTION 16
3.2. MIXTURES: NOT APPLICABLE
| SECTION 4: FIRST-AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES GENERAL:
CHECK THE VITAL FUNCTIONS. UNCONSCIOUS:
MAINTAIN ADEQUATE AIRWAY AND RESPIRATION.
RESPIRATORY ARREST: ARTIFICIAL RESPIRATION OR OXYGEN.
CARDIAC ARREST: PERFORM RESUSCITATION.
VICTIM CONSCIOUS WITH LABORED BREATHING: HALF-SEATED.
VICTIM IN SHOCK: ON HIS BACK WITH LEGS SLIGHTLY RAISED.
VOMITING:
PREVENT ASPHYXIA/ASPIRATION PNEUMONIA. PREVENT COOLING BY COVERING THE
VICTIM (NO WARMING UP). KEEP WATCHING THE VICTIM. GIVE PSYCHOLOGICAL AID.
KEEP THE VICTIM CALM, AVOID PHYSICAL STRAIN.
DEPENDING ON THE VICTIM'S CONDITION: DOCTOR/HOSPITAL.
FIRST-AID MEASURES AFTER INHALATION:
REMOVE THE VICTIM INTO FRESH AIR. IMMEDIATELY CONSULT A DOCTOR/MEDICAL
SERVICE.
FIRST-AID MEASURES AFTER SKIN CONTACT:
WASH IMMEDIATELY WITH LOTS OF WATER (15 MINUTES)/SHOWER. DO NOT APPLY
(CHEMICAL) NEUTRALIZING AGENTS. REMOVE CLOTHING WHILE WASHING. DO NOT
REMOVE CLOTHING IF IT STICKS TO THE SKIN. COVER WOUNDS WITH STERILE
BANDAGE. CONSULT A DOCTOR/MEDICAL SERVICE. IF BURNED SURFACE >10%:
TAKE VICTIM TO HOSPITAL.
FIRST-AID MEASURES AFTER EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER FOR 15 MINUTES. REMOVE CONTACT
LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING. DO NOT APPLY
NEUTRALIZING AGENTS. TAKE VICTIM TO AN OPHTHALMOLOGIST.
FIRST-AID MEASURES AFTER INGESTION:
RINSE MOUTH WITH WATER. IMMEDIATELY AFTER INGESTION:
GIVE LOTS OF WATER TO DRINK. DO NOT INDUCE VOMITING. IMMEDIATELY CONSULT A
DOCTOR/MEDICAL SERVICE. CALL POISON INFORMATION CENTRE
(WWW.BIG.BE/ANTIGIF.HTM).
INGESTION OF LARGE QUANTITIES:
IMMEDIATELY TO HOSPITAL. TAKE THE CONTAINER/VOMIT TO THE DOCTOR/HOSPITAL.
DO NOT GIVE CHEMICAL ANTIDOTE.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS (ACUTE AND DELAYED):
POTENTIAL ADVERSE HUMAN HEALTH EFFECTS AND SYMPTOMS:
TOXIC IF SWALLOWED. FATAL IN CONTACT WITH SKIN. CAUSES SEVERE SKIN BURNS.
FATAL IF INHALED. CAUSES SERIOUS EYE DAMAGE. CAUTION!
SUBSTANCE IS ABSORBED THROUGH THE SKIN.
SYMPTOMS/EFFECTS AFTER INHALATION:
DRY/SORE THROAT. COUGHING. CORROSION OF THE UPPER RESPIRATORY TRACT.
RUNNY NOSE. RESPIRATORY DIFFICULTIES.
FOLLOWING SYMPTOMS MAY APPEAR LATER:
POSSIBLE LARYNGEAL SPASM/OEDEMA. RISK OF LUNG EDEMA.
SYMPTOMS/EFFECTS AFTER SKIN CONTACT: CAUSTIC BURNS/CORROSION OF THE SKIN.
SYMPTOMS/EFFECTS AFTER EYE CONTACT:
CORROSION OF THE EYE TISSUE. INFLAMMATION/DAMAGE OF THE EYE TISSUE.
SYMPTOMS/EFFECTS AFTER INGESTION:
NAUSEA. BURNS TO THE GASTRIC/INTESTINAL MUCOSA. ABDOMINAL PAIN. BLOOD IN
VOMIT. BLOOD IN STOOL. SHOCK. DISTURBANCES OF CONSCIOUSNESS.
FOLLOWING SYMPTOMS MAY APPEAR LATER:
CHANGE IN URINE OUTPUT. RENAL DISEASE. ENLARGEMENT/DISEASE OF THE LIVER.
CHANGE IN THE BLOOD COMPOSITION.
CHRONIC SYMPTOMS:
SKIN RASH/INFLAMMATION. AFFECTION OF THE NASAL SEPTUM. NOSEBLEEDING.
RESPIRATORY DIFFICULTIES. POSSIBLE INFLAMMATION OF THE RESPIRATORY TRACT.
RISK OF PNEUMONIA. LUNG TISSUE AFFECTION/DEGENERATION. INFLAMMATION/DAMAGE
OF THE EYE TISSUE. ENLARGEMENT/AFFECTION OF THE LIVER.
4.3. IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT, IF NECESSARY:
NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE (AND UNSUITABLE) EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
WATER. QUICK-ACTING ABC POWDER EXTINGUISHER. QUICK-ACTING CO2 EXTINGUISHER.
QUANTITIES OF WATER.
UNSUITABLE EXTINGUISHING MEDIA: FOAM. FOAM.
5.2. SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
FIRE HAZARD:
DIRECT FIRE HAZARD. NON COMBUSTIBLE. INDIRECT FIRE HAZARD. MAY CAUSE FIRE
OR EXPLOSION; STRONG OXIDISER. REACTIONS INVOLVING A FIRE HAZARD:
SEE "REACTIVITY HAZARD".
EXPLOSION HAZARD:
INDIRECT EXPLOSION HAZARD. REACTIONS WITH EXPLOSION HAZARDS:
SEE "REACTIVITY HAZARD".
5.3. SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE-FIGHTERS:
PRECAUTIONARY MEASURES FIRE:
EXPOSURE TO FIRE/HEAT: KEEP UPWIND.
EXPOSURE TO FIRE/HEAT: CONSIDER EVACUATION.
EXPOSURE TO FIRE/HEAT: HAVE NEIGHBOURHOOD CLOSE DOORS AND WINDOWS.
FIREFIGHTING INSTRUCTIONS:
COOL TANKS/DRUMS WITH WATER SPRAY/REMOVE THEM INTO SAFETY. DO NOT MOVE
THE LOAD IF EXPOSED TO HEAT. TAKE ACCOUNT OF TOXIC FIRE-FIGHTING WATER.
USE WATER MODERATELY AND IF POSSIBLE COLLECT OR CONTAIN IT.
PROTECTION DURING FIREFIGHTING:
HEAT/FIRE EXPOSURE: COMPRESSED AIR/OXYGEN APPARATUS.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
6.1.1. FOR NON-EMERGENCY PERSONNEL:
PROTECTIVE EQUIPMENT:
GLOVES. FACE-SHIELD. CORROSION-PROOF SUIT. DUST CLOUD PRODUCTION:
COMPRESSED AIR/OXYGEN APPARATUS.
DUST CLOUD PRODUCTION: DUST-TIGHT SUIT.
EMERGENCY PROCEDURES:
MARK THE DANGER AREA. PREVENT DUST CLOUD FORMATION. NO NAKED FLAMES.
CORROSION-PROOF APPLIANCES. KEEP CONTAINERS CLOSED. WASH CONTAMINATED
CLOTHES. IN CASE OF REACTIVITY HAZARD: CONSIDER EVACUATION.
MEASURES IN CASE OF DUST RELEASE:
IN CASE OF DUST PRODUCTION: KEEP UPWIND.
IN CASE OF DUST PRODUCTION: CONSIDER EVACUATION.
DUST PRODUCTION: HAVE NEIGHBOURHOOD CLOSE DOORS AND WINDOWS.
6.1.2. FOR EMERGENCY RESPONDERS:
PROTECTIVE EQUIPMENT:
DO NOT BREATHE DUST. EQUIP CLEANUP CREW WITH PROPER PROTECTION.
EMERGENCY PROCEDURES:
IF A MAJOR SPILL OCCURS, ALL PERSONNEL SHOULD BE IMMEDIATELY EVACUATED
AND THE AREA VENTILATED. STOP LEAK IF SAFE TO DO SO. VENTILATE AREA.
6.2. ENVIRONMENTAL PRECAUTIONS:
PREVENT SOIL AND WATER POLLUTION. PREVENT SPREADING IN SEWERS.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
FOR CONTAINMENT:
CONTAIN RELEASED SUBSTANCE, PUMP INTO SUITABLE CONTAINERS. PLUG THE LEAK,
CUT OFF THE SUPPLY. DAM UP THE SOLID SPILL. KNOCK DOWN/DILUTE DUST CLOUD
WITH WATER SPRAY. TAKE ACCOUNT OF TOXIC/CORROSIVE PRECIPITATION WATER.
METHODS FOR CLEANING UP:
SPILL MUST NOT RETURN IN ITS ORIGINAL CONTAINER. PREVENT DISPERSION BY
COVERING WITH DRY SAND/EARTH.
DO NOT TAKE UP IN COMBUSTIBLE MATERIAL SUCH AS: SAW DUST.
WETTED SUBSTANCE:
MIX WITH DRY SAND OR POWDERED LIMESTONE. SCOOP SOLID SPILL INTO CLOSING
CONTAINERS. CAREFULLY COLLECT THE SPILL/LEFTOVERS. CLEAN CONTAMINATED
SURFACES WITH AN EXCESS OF WATER. TAKE COLLECTED SPILL TO
MANUFACTURER/COMPETENT AUTHORITY. WASH CLOTHING AND EQUIPMENT AFTER
HANDLING.
6.4. REFERENCE TO OTHER SECTIONS: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
ADDITIONAL HAZARDS WHEN PROCESSED:
PULVERIZATION RAPIDLY INCREASES TOXIC CONCENTRATION.
PRECAUTIONS FOR SAFE HANDLING:
AVOID RAISING DUST. KEEP AWAY FROM NAKED FLAMES/HEAT. MEASURE THE
CONCENTRATION IN THE AIR REGULARLY. CARRY OPERATIONS IN THE OPEN/UNDER
LOCAL EXHAUST/VENTILATION OR WITH RESPIRATORY PROTECTION. COMPLY WITH
THE LEGAL REQUIREMENTS. REMOVE CONTAMINATED CLOTHING IMMEDIATELY. CLEAN
CONTAMINATED CLOTHING. KEEP THE SUBSTANCE FREE FROM CONTAMINATION. USE
CORROSIONPROOF EQUIPMENT. THOROUGHLY CLEAN/DRY THE INSTALLATION BEFORE
USE. DO NOT DISCHARGE THE WASTE INTO THE DRAIN. KEEP CONTAINER TIGHTLY
CLOSED.
HYGIENE MEASURES:
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH CONTAMINATED
CLOTHING BEFORE REUSE.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
INCOMPATIBLE PRODUCTS:
ALUMINUM. COMBUSTIBLE MATERIALS. METALS. STRONG OXIDIZERS. STRONG
REDUCING AGENTS.
INCOMPATIBLE MATERIALS: MOISTURE.
HEAT-IGNITION:
KEEP SUBSTANCE AWAY FROM: HEAT SOURCES.
PROHIBITIONS ON MIXED STORAGE:
KEEP SUBSTANCE AWAY FROM:
COMBUSTIBLE MATERIALS. REDUCING AGENTS. (STRONG) BASES. OILS-FATS.
METALS. HALOGENS. ORGANIC MATERIALS. ALCOHOLS. STRONG ACIDS.
STORAGE AREA:
STORE IN A DRY AREA. STORE IN A DARK AREA. KEEP CONTAINER IN A
WELL-VENTILATED PLACE. FIREPROOF STOREROOM. KEEP LOCKED UP. UNAUTHORIZED
PERSONS ARE NOT ADMITTED. DETACHED BUILDING. KEEP ONLY IN THE ORIGINAL
CONTAINER. MEET THE LEGAL REQUIREMENTS.
SPECIAL RULES ON PACKAGING:
SPECIAL REQUIREMENTS:
HERMETICAL. WATERTIGHT. CORROSION-PROOF. DRY. CLEAN. SHOCK-ABSORBING.
CORRECTLY LABELLED. MEET THE LEGAL REQUIREMENTS. SECURE FRAGILE
PACKAGINGS IN SOLID CONTAINERS.
PACKAGING MATERIALS:
MATERIAL TO AVOID:
PAPER. WOOD. STEEL. ALUMINIUM. IRON. COPPER. NICKEL. BRONZE. PLASTICS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
CHROMIUM TRIOXIDE, ACS (1333-82-0):
ACGIH:
ACGIH TWA (MG/M3): 0.0002 MG/M3 (INHALABLE FRACTION)
ACGIH:
ACGIH STEL (MG/M3): 0.0005 MG/M3 (INHALABLE FRACTION)
CHROMIUM TRIOXIDE, ACS (1333-82-0):
OSHA:
OSHA PEL (TWA) (MG/M3): 0.005 MG/M3
IDLH:
US IDLH (MG/M3): 15 MG/M3
NIOSH:
NIOSH REL (TWA) (MG/M3): 0.001 MG/M3
8.2. APPROPRIATE ENGINEERING CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
EMERGENCY EYE WASH FOUNTAINS AND SAFETY SHOWERS SHOULD BE AVAILABLE IN THE
IMMEDIATE VICINITY OF ANY POTENTIAL EXPOSURE. PROVIDE ADEQUATE GENERAL AND
LOCAL EXHAUST VENTILATION.
8.3. INDIVIDUAL PROTECTION MEASURES/PERSONAL PROTECTIVE EQUIPMENT:
PERSONAL PROTECTIVE EQUIPMENT:
SAFETY GLASSES. GLOVES. PROTECTIVE CLOTHING. HIGH DUST PRODUCTION:
SELF-CONTAINED BREATHING APPARATUS. COMBINED GAS/DUST MASK WITH FILTER
TYPE E/P2.
MATERIALS FOR PROTECTIVE CLOTHING:
GIVE GOOD RESISTANCE: BUTYL RUBBER. PVC
HAND PROTECTION: GLOVES
EYE PROTECTION:
FACE SHIELD. IN CASE OF DUST PRODUCTION: PROTECTIVE GOGGLES
SKIN AND BODY PROTECTION:
CORROSION-PROOF CLOTHING. IN CASE OF DUST PRODUCTION: HEAD/NECK PROTECTION
RESPIRATORY PROTECTION:
DUST PRODUCTION: DUST MASK WITH FILTER TYPE P3.
HIGH DUST PRODUCTION: SELF-CONTAINED BREATHING APPARATUS
PERSONAL PROTECTIVE EQUIPMENT SYMBOL(S):
CHEMICAL GOGGLES
GLOVES
FULL SUIT
FACE SHIELD
FULL-FACE RESPIRATOR
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: SOLID
APPEARANCE: CRYSTALLINE SOLID. CRYSTALLINE POWDER. NEEDLES. FLAKES.
COLOR: DARK RED TO RED-VIOLET
ODOR: ODORLESS
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
MELTING POINT:
196 DEG. C (EU METHOD A.1: MELTING/FREEZING POINT)
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: NOT APPLICABLE (DECOMPOSES)
FLASH POINT: NOT APPLICABLE
RELATIVE EVAPORATION RATE (BUTYL ACETATE=1): NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
VAPOR PRESSURE: NOT APPLICABLE
RELATIVE VAPOR DENSITY AT 20 DEG. C: NOT APPLICABLE
RELATIVE DENSITY:
2.7 (OECD 109: DENSITY OF LIQUIDS AND SOLIDS)
SPECIFIC GRAVITY / DENSITY: 2700 KG/M3
MOLECULAR MASS: 99.99 G/MOL
SOLUBILITY:
EXOTHERMICALLY SOLUBLE IN WATER. SOLUBLE IN ETHANOL. SOLUBLE IN ETHER.
SOLUBLE IN ACIDS. SOLUBLE IN NITRIC ACID. SOLUBLE IN SULFURIC ACID.
WATER:
166.7 G/100ML (EU METHOD A.6: WATER SOLUBILITY)
LOG POW: NO DATA AVAILABLE
AUTO-IGNITION TEMPERATURE: NOT APPLICABLE
DECOMPOSITION TEMPERATURE: 250 DEG. C
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
EXPLOSION LIMITS: NO DATA AVAILABLE
EXPLOSIVE PROPERTIES: NOT EXPLOSIVE.
OXIDIZING PROPERTIES: MAY CAUSE FIRE OR EXPLOSION; STRONG OXIDISER.
9.2. OTHER INFORMATION:
SADT: NOT APPLICABLE
VOC CONTENT: 0 %
OTHER PROPERTIES: HYGROSCOPIC. SUBSTANCE HAS ACID REACTION.
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
RISK OF EXPLOSION WITH COMBUSTIBLE MATERIALS. REACTS WITH ORGANIC MATERIAL:
RISK OF SPONTANEOUS IGNITION.
REACTS VIOLENTLY WITH MANY COMPOUNDS E.G.:
WITH (STRONG) REDUCERS, WITH (SOME) ACIDS AND WITH OILS/FATS:
(INCREASED) RISK OF FIRE/EXPLOSION. WHEN DECOMPOSING ON EXPOSURE TO
TEMPERATURE RISE:
OXIDATION WHICH INCREASES FIRE HAZARD. REACTS VIOLENTLY ON EXPOSURE TO
WATER (MOISTURE) WITH (SOME) BASES. REACTS ON EXPOSURE TO WATER (MOISTURE)
WITH (SOME) METALS.
10.2. CHEMICAL STABILITY: UNSTABLE ON EXPOSURE TO MOISTURE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
MAY REACT VIOLENTLY WITH REDUCING AGENTS.
10.4. CONDITIONS TO AVOID:
AVOID DUST FORMATION. FINELY DIVIDED METALS. INCOMPATIBLE MATERIALS.
MOISTURE.
10.5. INCOMPATIBLE MATERIALS:
ALCOHOLS. ALDEHYDES. ALUMINUM. COMBUSTIBLE MATERIALS. METALS. STRONG
REDUCING AGENTS. STRONG BASES.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY (ORAL): TOXIC IF SWALLOWED.
ACUTE TOXICITY (DERMAL): FATAL IN CONTACT WITH SKIN.
ACUTE TOXICITY (INHALATION): FATAL IF INHALED.
CHROMIUM TRIOXIDE, ACS (1333-82-0):
LD50 ORAL RAT:
52 MG/KG BODY WEIGHT (EQUIVALENT OR SIMILAR TO OECD 401, RAT,
MALE / FEMALE, EXPERIMENTAL VALUE, ORAL, 14 DAY(S))
LD50 DERMAL RABBIT:
57 MG/KG (EQUIVALENT OR SIMILAR TO OECD 402, 24 H, RABBIT,
MALE / FEMALE, EXPERIMENTAL VALUE, DERMAL, 14 DAY(S))
LC50 INHALATION RAT (MG/L):
0.217 MG/L (EPA OTS 798.1150:
ACUTE INHALATION TOXICITY, 4 H, RAT, MALE / FEMALE,
EXPERIMENTAL VALUE, INHALATION (AEROSOL), 14 DAY(S))
ATE US (ORAL): 52 MG/KG BODY WEIGHT
ATE US (DERMAL): 57 MG/KG BODY WEIGHT
ATE US (VAPORS): 0.217 MG/L/4H
ATE US (DUST, MIST): 0.217 MG/L/4H
ADDITIONAL INFORMATION:
AN ORAL TOXICITY STUDY OF CHROMIUM TRIOXIDE CONDUCTED ON RATS IN
1989 FOUND THE AVERAGE LD50 TO BE 51.9 MG/KG.
SKIN CORROSION/IRRITATION: CAUSES SEVERE SKIN BURNS.
SERIOUS EYE DAMAGE/IRRITATION: ASSUMED TO CAUSE SERIOUS EYE DAMAGE
RESPIRATORY OR SKIN SENSITIZATION:
MAY CAUSE AN ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF
INHALED. MAY CAUSE AN ALLERGIC SKIN REACTION.
GERM CELL MUTAGENICITY: MAY CAUSE GENETIC DEFECTS.
CARCINOGENICITY: MAY CAUSE CANCER (INHALATION).
CHROMIUM TRIOXIDE, ACS (1333-82-0):
IARC GROUP: 1 - CARCINOGENIC TO HUMANS
NATIONAL TOXICOLOGY PROGRAM (NTP) STATUS: KNOWN HUMAN CARCINOGENS
REPRODUCTIVE TOXICITY: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
STOT-SINGLE EXPOSURE: NOT CLASSIFIED
STOT-REPEATED EXPOSURE:
CAUSES DAMAGE TO ORGANS (KIDNEYS, LIVER, RESPIRATORY SYSTEM, SKIN, EYES)
THROUGH PROLONGED OR REPEATED EXPOSURE.
ASPIRATION HAZARD: NOT CLASSIFIED
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
LIKELY ROUTES OF EXPOSURE: INHALATION. SKIN AND EYE CONTACT.
POTENTIAL ADVERSE HUMAN HEALTH EFFECTS AND SYMPTOMS:
TOXIC IF SWALLOWED. FATAL IN CONTACT WITH SKIN. CAUSES SEVERE SKIN BURNS.
FATAL IF INHALED. CAUSES SERIOUS EYE DAMAGE. CAUTION!
SUBSTANCE IS ABSORBED THROUGH THE SKIN.
SYMPTOMS/EFFECTS AFTER INHALATION:
DRY/SORE THROAT. COUGHING. CORROSION OF THE UPPER RESPIRATORY TRACT. RUNNY
NOSE. RESPIRATORY DIFFICULTIES.
FOLLOWING SYMPTOMS MAY APPEAR LATER:
POSSIBLE LARYNGEAL SPASM/OEDEMA. RISK OF LUNG EDEMA.
SYMPTOMS/EFFECTS AFTER SKIN CONTACT: CAUSTIC BURNS/CORROSION OF THE SKIN.
SYMPTOMS/EFFECTS AFTER EYE CONTACT:
CORROSION OF THE EYE TISSUE. INFLAMMATION/DAMAGE OF THE EYE TISSUE.
SYMPTOMS/EFFECTS AFTER INGESTION:
NAUSEA. BURNS TO THE GASTRIC/INTESTINAL MUCOSA. ABDOMINAL PAIN. BLOOD
IN VOMIT. BLOOD IN STOOL. SHOCK. DISTURBANCES OF CONSCIOUSNESS.
FOLLOWING SYMPTOMS MAY APPEAR LATER:
CHANGE IN URINE OUTPUT. RENAL DISEASE. ENLARGEMENT/DISEASE OF THE LIVER.
CHANGE IN THE BLOOD COMPOSITION.
CHRONIC SYMPTOMS:
SKIN RASH/INFLAMMATION. AFFECTION OF THE NASAL SEPTUM. NOSEBLEEDING.
RESPIRATORY DIFFICULTIES. POSSIBLE INFLAMMATION OF THE RESPIRATORY TRACT.
RISK OF PNEUMONIA. LUNG TISSUE AFFECTION/DEGENERATION. INFLAMMATION/DAMAGE
OF THE EYE TISSUE. ENLARGEMENT/AFFECTION OF THE LIVER.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
ECOLOGY - GENERAL: DANGEROUS FOR THE ENVIRONMENT.
ECOLOGY - AIR:
NOT INCLUDED IN THE LIST OF SUBSTANCES WHICH MAY CONTRIBUTE TO THE
GREENHOUSE EFFECT (IPCC). NOT INCLUDED IN THE LIST OF FLUORINATED
GREENHOUSE GASES (REGULATION (EU) NO 517/2014). NOT CLASSIFIED AS
DANGEROUS FOR THE OZONE LAYER (REGULATION (EC) NO 1005/2009).
ECOLOGY - WATER:
VERY TOXIC TO CRUSTACEA. HARMFUL TO FISHES. SEVERE WATER POLLUTANT
(SURFACE WATER). VERY TOXIC TO ALGAE. PH SHIFT.
CHROMIUM TRIOXIDE, ACS (1333-82-0):
LC50 FISH 1: 58.5 MG/L (96 H, BRACHYDANIO RERIO, FRESH WATER, READ-ACROSS)
EC50 DAPHNIA 1: 0.063 MG/L (48 H, DAPHNIA MAGNA, FRESH WATER, READ-ACROSS)
12.2. PERSISTENCE AND DEGRADABILITY:
CHROMIUM TRIOXIDE, ACS (1333-82-0):
CHEMICAL OXYGEN DEMAND (COD): NOT APPLICABLE
THOD: NOT APPLICABLE
BOD (% OF THOD): NOT APPLICABLE
12.3. BIOACCUMULATIVE POTENTIAL:
CHROMIUM TRIOXIDE, ACS (1333-82-0):
BCF FISH 1:
4.6 - 72 (CYPRINUS CARPIO, TEST DURATION: 6 WEEKS)
BCF FISH 2: 16 (PISCES)
BCF OTHER AQUATIC ORGANISMS 1: 192 (MYTILIDAE, CHROME)
BCF OTHER AQUATIC ORGANISMS 2: 125 (OSTREIDAE, CHROME)
BIOACCUMULATIVE POTENTIAL: NOT BIOACCUMULATIVE.
12.4. MOBILITY IN SOIL: NO ADDITIONAL INFORMATION AVAILABLE
12.5. OTHER ADVERSE EFFECTS: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
WASTE DISPOSAL RECOMMENDATIONS:
TREAT USING THE BEST AVAILABLE TECHNIQUES BEFORE DISCHARGE INTO DRAINS
OR THE AQUATIC ENVIRONMENT. REMOVE WASTE IN ACCORDANCE WITH LOCAL AND/OR
NATIONAL REGULATIONS. HAZARDOUS WASTE SHALL NOT BE MIXED TOGETHER WITH
OTHER WASTE. DIFFERENT TYPES OF HAZARDOUS WASTE SHALL NOT BE MIXED
TOGETHER IF THIS MAY ENTAIL A RISK OF POLLUTION OR CREATE PROBLEMS FOR
THE FURTHER MANAGEMENT OF THE WASTE. HAZARDOUS WASTE SHALL BE MANAGED
RESPONSIBLY. ALL ENTITIES THAT STORE, TRANSPORT OR HANDLE HAZARDOUS WASTE
SHALL TAKE THE NECESSARY MEASURES TO PREVENT RISKS OF POLLUTION OR DAMAGE
TO PEOPLE OR ANIMALS. RECYCLE/REUSE. REMOVE TO AN AUTHORIZED DUMP
(CLASS I). REMOVE FOR PHYSICO-CHEMICAL/BIOLOGICAL TREATMENT.
ADDITIONAL INFORMATION:
HAZARDOUS WASTE ACCORDING TO DIRECTIVE 2008/98/EC, AS AMENDED BY
REGULATION (EU) NO 1357/2014 AND REGULATION (EU) NO 2017/997.
| SECTION 14: TRANSPORT INFORMATION | |
DEPARTMENT OF TRANSPORTATION (DOT): IN ACCORDANCE WITH DOT
TRANSPORT DOCUMENT DESCRIPTION:
UN1463 CHROMIUM TRIOXIDE, ANHYDROUS, 5.1, II
UN-NO.(DOT): UN1463
PROPER SHIPPING NAME (DOT): CHROMIUM TRIOXIDE, ANHYDROUS
PACKING GROUP (DOT): II - MEDIUM DANGER
HAZARD LABELS (DOT):
5.1 - OXIDIZER
6.1 - POISON
8 - CORROSIVE
DANGEROUS FOR THE ENVIRONMENT: YES
MARINE POLLUTANT: YES
ENVIRONMENT
DOT PACKAGING NON BULK (49 CFR 173.XXX): 212
DOT PACKAGING BULK (49 CFR 173.XXX): 242
DOT SPECIAL PROVISIONS (49 CFR 172.102):
IB8 - AUTHORIZED IBCS:
METAL (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B AND 31N); RIGID PLASTICS
(11H1, 11H2, 21H1, 21H2, 31H1 AND 31H2); COMPOSITE (11HZ1, 11HZ2, 21HZ1,
21HZ2, 31HZ1 AND 31HZ2); FIBERBOARD (11G); WOODEN (11C, 11D AND 11F);
FLEXIBLE (13H1, 13H2, 13H3, 13H4, 13H5, 13L1, 13L2, 13L3, 13L4, 13M1 OR
13M2). IP2 -WHEN IBCS OTHER THAN METAL OR RIGID PLASTICS IBCS ARE USED,
THEY MUST BE OFFERED FOR TRANSPORTATION IN A CLOSED FREIGHT CONTAINER OR
A CLOSED TRANSPORT VEHICLE. IP4 - FLEXIBLE, FIBERBOARD OR WOODEN IBCS MUST
BE SIFT-PROOF AND WATER-RESISTANT OR BE FITTED WITH A SIFT-PROOF AND
WATER-RESISTANT LINER.
T3 - 2.65 178.274(D)(2) NORMAL............. 178.275(D)(2)
TP33 - THE PORTABLE TANK INSTRUCTION ASSIGNED FOR THIS SUBSTANCE APPLIES
FOR GRANULAR AND POWDERED SOLIDS AND FOR SOLIDS WHICH ARE FILLED AND
DISCHARGED AT TEMPERATURES ABOVE THEIR MELTING POINT WHICH ARE COOLED
AND TRANSPORTED AS A SOLID MASS. SOLID SUBSTANCES TRANSPORTED OR OFFERED
FOR TRANSPORT ABOVE THEIR MELTING POINT ARE AUTHORIZED FOR TRANSPORTATION
IN PORTABLE TANKS CONFORMING TO THE PROVISIONS OF PORTABLE TANK INSTRUCTION
T4 FOR SOLID SUBSTANCES OF PACKING GROUP III OR T7 FOR SOLID SUBSTANCES OF
PACKING GROUP II, UNLESS A TANK WITH MORE STRINGENT REQUIREMENTS FOR
MINIMUM SHELL THICKNESS, MAXIMUM ALLOWABLE WORKING PRESSURE,
PRESSURE-RELIEF DEVICES OR BOTTOM OUTLETS ARE ASSIGNED IN WHICH CASE THE
MORE STRINGENT TANK INSTRUCTION AND SPECIAL PROVISIONS SHALL APPLY.
FILLING LIMITS MUST BE IN ACCORDANCE WITH PORTABLE TANK SPECIAL PROVISION
TP3. SOLIDS MEETING THE DEFINITION OF AN ELEVATED TEMPERATURE MATERIAL
MUST BE TRANSPORTED IN ACCORDANCE WITH THE APPLICABLE REQUIREMENTS OF THIS
SUBCHAPTER.
DOT PACKAGING EXCEPTIONS (49 CFR 173.XXX): NONE
DOT QUANTITY LIMITATIONS PASSENGER AIRCRAFT/RAIL (49 CFR 173.27): 5 KG
DOT QUANTITY LIMITATIONS CARGO AIRCRAFT ONLY (49 CFR 175.75): 25 KG
DOT VESSEL STOWAGE LOCATION:
A - THE MATERIAL MAY BE STOWED "ON DECK" OR "UNDER DECK" ON A CARGO
VESSEL AND ON A PASSENGER VESSEL.
DOT VESSEL STOWAGE OTHER:
66 - STOW "SEPARATED FROM" FLAMMABLE SOLIDS,90 - STOW "SEPARATED FROM"
RADIOACTIVE MATERIALS
OTHER INFORMATION: NO SUPPLEMENTARY INFORMATION AVAILABLE.
TRANSPORTATION OF DANGEROUS GOODS:
TRANSPORT DOCUMENT DESCRIPTION:
UN1463 CHROMIUM TRIOXIDE, ANHYDROUS, 5.1 (6.1;8), II
UN-NO. (TDG): UN1463
PROPER SHIPPING NAME (TRANSPORTATION OF DANGEROUS GOODS):
CHROMIUM TRIOXIDE, ANHYDROUS
TDG PRIMARY HAZARD CLASSES: 5.1 - CLASS 5.1 - OXIDIZING SUBSTANCES
PACKING GROUP: II - MEDIUM DANGER
TDG SUBSIDIARY CLASSES: 6.1;8
EXPLOSIVE LIMIT AND LIMITED QUANTITY INDEX: 1 KG
PASSENGER CARRYING ROAD VEHICLE OR PASSENGER CARRYING RAILWAY VEHICLE
INDEX:
5 KG
TRANSPORT BY SEA:
TRANSPORT DOCUMENT DESCRIPTION (IMDG):
UN 1463 CHROMIUM TRIOXIDE, ANHYDROUS, 5.1 (6.1+8), II, MARINE
POLLUTANT/ENVIRONMENTALLY HAZARDOUS
UN-NO. (IMDG): 1463
PROPER SHIPPING NAME (IMDG): CHROMIUM TRIOXIDE, ANHYDROUS
CLASS (IMDG): 5.1 - OXIDIZING SUBSTANCES
PACKING GROUP (IMDG): II - SUBSTANCES PRESENTING MEDIUM DANGER
SUBSIDIARY RISKS (IMDG):
6.1 - TOXIC SUBSTANCES
8 - CORROSIVE SUBSTANCES
EMS-NO. (1): F-A
EMS-NO. (2): S-Q
MARINE POLLUTANT: YES
ENVIRONMENT
AIR TRANSPORT:
TRANSPORT DOCUMENT DESCRIPTION (IATA):
UN 1463 CHROMIUM TRIOXIDE, ANHYDROUS, 5.1, II, ENVIRONMENTALLY HAZARDOUS
UN-NO. (IATA): 1463
PROPER SHIPPING NAME (IATA): CHROMIUM TRIOXIDE, ANHYDROUS
CLASS (IATA): 5.1 - OXIDIZING SUBSTANCES
PACKING GROUP (IATA): II - MEDIUM DANGER
SUBSIDIARY HAZARDS (IATA):
6.1 - TOXIC SUBSTANCES, 8 - CORROSIVE SUBSTANCES
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
CHROMIUM TRIOXIDE, ACS (1333-82-0):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT)
INVENTORY SUBJECT TO REPORTING REQUIREMENTS OF UNITED STATES SARA
SECTION 313
EPA TSCA REGULATORY FLAG:
R - R - INDICATES A SUBSTANCE THAT IS THE SUBJECT OF A TSCA SECTION 6
RISK MANAGEMENT RULE.
RQ (REPORTABLE QUANTITY, SECTION 304 OF EPA'S LIST OF LISTS): 10 LB
SARA SECTION 311/312 HAZARD CLASSES:
PHYSICAL HAZARD: OXIDIZER (LIQUID, SOLID OR GAS)
HEALTH HAZARD: ACUTE TOXICITY (ANY ROUTE OF EXPOSURE)
HEALTH HAZARD: CARCINOGENICITY
HEALTH HAZARD: RESPIRATORY OR SKIN SENSITIZATION
HEALTH HAZARD: GERM CELL MUTAGENICITY
HEALTH HAZARD: REPRODUCTIVE TOXICITY
HEALTH HAZARD: SERIOUS EYE DAMAGE OR EYE IRRITATION
HEALTH HAZARD: SKIN CORROSION OR IRRITATION
HEALTH HAZARD: SPECIFIC TARGET ORGAN TOXICITY (SINGLE OR REPEATED EXPOSURE)
ALL COMPONENTS OF THIS PRODUCT ARE LISTED, OR EXCLUDED FROM LISTING, ON
THE UNITED STATES ENVIRONMENTAL PROTECTION AGENCY TOXIC SUBSTANCES CONTROL
ACT (TSCA) INVENTORY
CHEMICAL(S) SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OR TITLE
III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND
40 CFR PART 372.
CHROMIUM TRIOXIDE, ACS CAS-NO. 1333-82-0 100%
15.2. INTERNATIONAL REGULATIONS:
CANADA: NO ADDITIONAL INFORMATION AVAILABLE
EU-REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
NATIONAL REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
15.3. US STATE REGULATIONS:
CHROMIUM TRIOXIDE, ACS (1333-82-0):
U.S. - CALIFORNIA - PROPOSITION 65 - CARCINOGENS LIST: YES
U.S. - CALIFORNIA - PROPOSITION 65 - DEVELOPMENTAL TOXICITY: YES
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - FEMALE: YES
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - MALE: YES
NO SIGNIFICANT RISK LEVEL (NSRL): 0.001 (MICRO)G/DAY - INHALATION
WARNING:
THIS PRODUCT CAN EXPOSE YOU TO CHROMIUM TRIOXIDE, ACS, WHICH IS KNOWN TO
THE STATE OF CALIFORNIA TO CAUSE CANCER AND BIRTH DEFECTS OR OTHER
REPRODUCTIVE HARM. FOR MORE INFORMATION GO TO WWW.P65WARNINGS.CA.GOV.
| SECTION 16: OTHER INFORMATION | |
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26,
2012 / RULES AND REGULATIONS:
REVISION DATE: 01/24/2020
FULL TEXT OF H-PHRASES:
SEE SECTION 16:
H271: MAY CAUSE FIRE OR EXPLOSION; STRONG OXIDIZER
H301: TOXIC IF SWALLOWED
H310: FATAL IN CONTACT WITH SKIN
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE
H317: MAY CAUSE AN ALLERGIC SKIN REACTION
H330: FATAL IF INHALED
H334:
MAY CAUSE AN ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF
INHALED
H340: MAY CAUSE GENETIC DEFECTS
H350: MAY CAUSE CANCER
H361: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD
H372: CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE
H400: VERY TOXIC TO AQUATIC LIFE
H410: VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS
NFPA:
3
0
1
OX
NFPA HEALTH HAZARD:
3:
MATERIALS THAT, UNDER EMERGENCY CONDITIONS, CAN CAUSE SERIOUS OR PERMANENT
INJURY.
NFPA FIRE HAZARD:
0:
MATERIALS THAT WILL NOT BURN UNDER TYPICAL FIRE CONDITIONS, INCLUDING
INTRINSICALLY NONCOMBUSTIBLE MATERIALS SUCH AS CONCRETE, STONE, AND SAND.
NFPA REACTIVITY:
1:
MATERIALS THAT IN THEMSELVES ARE NORMALLY STABLE BUT CAN BECOME UNSTABLE
AT ELEVATED TEMPERATURES AND PRESSURES.
NFPA SPECIFIC HAZARD:
OX: MATERIALS THAT POSSES OXIDIZING PROPERTIES.
HAZARD RATING:
HEALTH:
3 SERIOUS HAZARD:
MAJOR INJURY LIKELY UNLESS PROMPT ACTION IS TAKEN AND MEDICAL TREATMENT IS
GIVEN
FLAMMABILITY:
0 MINIMAL HAZARD: MATERIALS THAT WILL NOT BURN
PHYSICAL:
1 SLIGHT HAZARD:
MATERIALS THAT ARE NORMALLY STABLE BUT CAN BECOME UNSTABLE (SELF-REACT) AT
HIGH TEMPERATURES AND PRESSURES. MATERIALS MAY REACT NON-VIOLENTLY WITH
WATER OR UNDERGO HAZARDOUS POLYMERIZATION IN THE ABSENCE OF INHIBITORS.
PERSONAL PROTECTION: J
J: SPLASH GOGGLES, GLOVES, SYNTHETIC APRON, DUST & VAPOR RESPIRATOR
SDS US LABCHEM:
INFORMATION IN THIS SDS IS FROM AVAILABLE PUBLISHED SOURCES AND IS
BELIEVED TO BE ACCURATE. NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AND
LABCHEM INC ASSUMES NO LIABILITY RESULTING FROM THE USE OF THIS SDS.
THE USER MUST DETERMINE SUITABILITY OF THIS INFORMATION FOR HIS
APPLICATION.
EN (ENGLISH US)