| Common Name: | 5-100 PPM H2S, 1-999 PPM CO, 0.1-3.0% METHANE, 10-23.5% O2 IN N2 |
| Manufacturer: | NORLAB |
| SDS Revision Date: | 9/6/2019 |
| SDS Format: | No Format Specified |
| Item Number(s): | 8FWL5, 8FWL6 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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NORLAB
A DIVISION OF NORCO, INC.
SAFETY DATA SHEET
SDS
5-100 PPM H2S, 1-999 PPM CO, 0.1-3.0% METHANE, 10-23.5% O2 IN N2
| 1 PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT IDENTIFIER:
5-100 PPM H2S, 1-999 PPM CO, 0.1-3.0% METHANE, 10-23.5% O2 IN N2
SYNONYMS: QUAD MIX, BUMP GAS, CALIBRATION GAS MIXTURE
COMMON NAME: H2S QUAD MIX (METHANE)
SDS NUMBER: NLB 2310
REVISION DATE: 9/6/2019
VERSION: 4
CAS NUMBER: NOT AVAILABLE - GAS MIXTURE
CHEMICAL FORMULA: H2S+CH4+CO+O2+N2
PRODUCT USE: CALIBRATION OF ANALYITICAL INSTRUMENTATION
SUPPLIER DETAILS:
NORLAB A DIVISION OF NORCO
898 W. GOWEN RD.
BOISE, ID 83705
CONTACT: QUALITY DEPT.
PHONE: 208-336-1643
FAX: 208-433-6160
INTERNET: WWW.NORLAB-GAS.COM
FOR TRANSPORTATION EMERGENCY CONTACT CHEMTREC: 800-424-9300
| 2 HAZARDS IDENTIFICATION | |
CLASSIFICATION OF SUBSTANCE:
GHS CLASSIFICATION IN ACCORDANCE WITH 29 CFR 1910 (OSHA HCS):
PHYSICAL, GASES UNDER PRESSURE, COMPRESSED GAS
HEALTH, ACUTE TOXICITY, 5 INHALATION
GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENTS:
GHS SIGNAL WORD: WARNING
GHS HAZARD PICTOGRAMS: GAS CYLINDER
GHS HAZARD STATEMENTS:
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED
H333: MAY BE HARMFUL IF INHALED
OSHA-H01: MAY DISPLACE OXYGEN AND CAUSE RAPID SUFFOCATION.
GHS PRECAUTIONARY STATEMENTS:
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
P251:
PRESSURIZED CONTAINER: DO NOT PIERCE OR BURN, EVEN AFTER USE.
P260: DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P281: USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED.
P304+340:
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING.
P308+313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
P403+233: STORE IN A WELL VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
CGA-PG02:
PROTECT FROM SUNLIGHT WHEN AMBIENT TEMPERATURE EXCEEDS 52 DEG. C
(125 DEG. F).
CGA-PG05: USE A BACK FLOW PREVENTIVE DEVICE IN THE PIPING.
CGA-PG06: CLOSE VALVE AFTER EACH USE AND WHEN EMPTY.
CGA-PG10: USE ONLY WITH EQUIPMENT RATED FOR CYLINDER PRESSURE.
CGA-PG20: USE ONLY EQUIPMENT OF COMPATIBLE MATERIALS OF CONSTRUCTION.
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC) OR NOT COVERED BY GHS:
ROUTE OF ENTRY: INHALATION;
TARGET ORGANS:
CARDIOVASCULAR SYSTEM; LUNGS; BLOOD; CENTRAL NERVOUS SYSTEM;
INHALATION:
THIS MIX MAY OR MAY NOT CONTAIN SUFFECIENT OXYGEN TO SUSTAIN LIFE.
NITROGEN ACTS AS A SIMPLE ASPHYXIANT DISPLACING THE OXYGEN CONTENT IN THE
AIR NECESSARY FOR LIFE. THE FOLLOWING EFFECTS OF ASPHYXIATION ARE
REPRESENTATIVE AND IT IS POSSIBLE THAT NONE OF THESE SYMPTOMS MAY OCCUR:
LOSS OF BALANCE OR DIZZINESS; TIGHTNESS IN THE FRONTAL AREA OF THE
FOREHEAD; TINGLING OF THE TONGUE, FINGERTIPS OR TOES; WEAKENED SPEECH
LEADING TO THE INABILITY TO UTTER SOUNDS; RAPID REDUCTION IN THE ABILITY
TO PERFORM MOVEMENTS; REDUCED CONSCIOUSNESS OF SURROUNDINGS; LOSS OF
TACTILE SENSATIONS; AND HEIGHTENED MENTAL ACTIVITY.
CONCENTRATIONS OF 150 PPM HYDROGEN SULFIDE CAN CAUSE UPPER RESPIRATORY
TRACT IRRITATION, OLFACTORY NERVE PARALYSIS, AND PULMONARY EDEMA WITH
PROLONGED EXPOSURE. CONCENTRATIONS OF 200 PPM HYDROGEN SULFIDE MAY BE
LIFE THREATENING. EXPOSURE TO NON-FATAL LEVELS OF HYDROGEN SULFIDE MAY
RESULT IN COUGHING, LACRIMATION, MUCOUS NASAL DISCHARGE, DEPRESSION,
FLUID SOUNDS IN THE LUNGS, HEADACHE, SWEATING, VERTIGO, IRRITABILITY,
WEAKNESS CONFUSION, DELIRIUM, CONVULSIONS AND CYANOSIS. AT HIGHER
EXPOSURES HYDROGEN SULFIDE MAY CAUSE SUDDEN COLLAPSE, ANOXIC CONVULSIONS,
PULMONARY EDEMA, HEMORRHAGES IN VARIOUS ORGANS, DEGENERATIVE CHANGES IN
THE LIVER AND KIDNEY, EDEMA OF THE INTESTINES AND BRAIN AND/OR RAPID
DEATH.
INHALED CARBON MONOXIDE BINDS WITH BLOOD HEMOGLOBIN TO FORM
CARBOXYHEMOGLOBIN. CARBOXYHEMOGLOBIN CANNOT TAKE PART IN NORMAL
OXYGEN TRANSPORT, GREATLY REDUCING THE BLOOD'S ABILITY TO TRANSPORT
OXYGEN. DEPENDING ON LEVELS AND DURATION OF EXPOSURE, SYMPTOMS MAY INCLUDE
HEADACHE, DIZZINESS, HEART PALPITATIONS, WEAKNESS, CONFUSION, NAUSEA, AND
EVEN CONVULSIONS, EVENTUAL UNCONSCIOUSNESS AND DEATH. SOME EXPERIMENTAL
EVIDENCE INDICATES TERATOGENIC AND REPRODUCTIVE EFFECTS FOR CARBON
MONOXIDE.
SKIN CONTACT:
CONTACT WITH HYDROGEN SULFIDE IN THIS PRODUCT MAY CAUSE SEVERE PAIN
ITCHING AND ERYTHEMA. CONTACT WITH RAPIDLY EXPANDING GAS NEAR THE POINT
OF RELEASE MAY CAUSE FROSTBITE WITH REDNESS, SKIN COLOR CHANGE TO GRAY
OR WHITE, AND BLISTERING.
EYE CONTACT:
EXPOSURE TO 20-50 PPM HYDROGEN SULFIDE WILL CAUSE EYE IRRITATION. LOW TO
MODERATELY HIGH CONCENTRATIONS MAY CAUSE PAINFUL CONJUNCTIVITIS,
PHOTOPHOBIA, LACRIMATION AND CORNEAL OPACITY. EXPOSURE TO 50-100 PPM
HYDROGEN SULFIDE HAS RESULTED IN TEMPORARY DAMAGE TO THE CORNEAL
EPITHELIUM IN DOGS, CATS, RABBITS, AND GUINEA PIGS. CONTACT WITH
RAPIDLY EXPANDING GAS NEAR THE POINT OF RELEASE MAY CAUSE FROSTBITE.
INGESTION:
INGESTION OF THIS PRODUCT IS UNLIKELY BUT CAN CAUSE IRRITATION OF THE
MUCOUS MEMBRANES AND GASTROINTESTINAL TRACT.
PRODUCT IS A COLORLESS NON-FLAMMABLE GAS WITH A DISTINCTIVE ROTTEN EGG
LIKE ODOR. DO NOT RELY ON SMELL TO DETECT HYDROGEN SULFIDE BECAUSE OF
OLFACTORY FATIGUE. EXPOSURE TO LOW LEVELS OF HYDROGEN SULFIDE CAUSES
IRRITATION OF MUCOUS MEMBRANES. INHALED CARBON MONOXIDE BINDS TO THE
BLOOD HEMOGLOBIN, GREATLY REDUCING THE RED BLOOD CELL'S ABILITY TO
TRANSPORT OXYGEN TO BODY TISSUES. EFFECTS MAY INCLUDE HEADACHES,
DIZZINESS, CONVULSIONS, LOSS OF CONSCIOUSNESS, AND DEATH. MIX MAY OR
MAY NOT HAVE SUFFICIENT OXYGEN CONTENT TO SUPPORT LIFE THEREFORE MIX
SHOULD BE TREATED AS A SIMPLE ASPHYXIATE. CONTENTS UNDER PRESSURE.
USE AND STORE BELOW 125 DEG. F (52 DEG. C).
| 3 COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL INGREDIENTS:
CAS# % CHEMICAL NAME
7783-06-4 0.0005-0.01% HYDROGEN SULFIDE
630-08-0 0.0001-0.0999% CARBON MONOXIDE
74-82-8 0.1-3.0% METHANE
7782-44-7 10.0-23.5% OXYGEN
7727-37-9 73.3901-89.8994% NITROGEN
| 4 FIRST AID MEASURES | |
INHALATION:
PROMPT REMOVAL FROM THE CONTAMINATED AREA AND IMMEDIATE MEDICAL ATTENTION
IS MANDATORY IN ALL CASES OF OVEREXPOSURE. RESCUE PERSONNEL SHOULD BE
EQUIPPED WITH SELFCONTAINED BREATHING APPARATUS. CONSCIOUS PERSONS SHOULD
BE ASSISTED TO AN UNCONTAMINATED AREA AND BE TREATED WITH SUPPLEMENTAL
OXYGEN. QUICK REMOVAL FROM THE CONTAMINATED AREA IS MOST IMPORTANT.
UNCONSCIOUS PERSONS SHOULD BE MOVED TO AN UNCONTAMINATED AREA AND BE GIVEN
ARTIFICIAL RESPIRATION AND OXYGEN AT THE SAME TIME. THE ADMINISTERING OF
THE OXYGEN AT AN ELEVATED PRESSURE (UP TO 2 TO 2.5 ATMOSPHERES) HAS SHOWN
TO BE BENEFICIAL AS HAS TREATMENT IN A HYPERBARIC CHAMBER. THE PHYSICIAN
SHOULD BE INFORMED THAT THE PATIENT HAS INHALED TOXIC QUANTITIES OF CARBON
MONOXIDE.
DEPENDING ON THE CONCENTRATION OF THE CARBON MONOXIDE PRESENT, THIS
PRODUCT MAY ACT AS A SIMPLE ASPHYXIATE OR A CHEMICAL ASPHYXIATE. THIS
MIXTURE CONTAINS SUFFICIENT OXYGEN TO SUPPORT LIFE.
INHALED CARBON MONOXIDE BINDS WITH BLOOD HEMOGLOBIN TO FORM
CARBOXYHEMOGLOBIN. CARBOXYHEMOGLOBIN CANNOT TAKE PART IN NORMAL
OXYGEN TRANSPORT, GREATLY REDUCING THE BLOOD'S ABILITY TO TRANSPORT
OXYGEN. DEPENDING ON LEVELS AND DURATION OF EXPOSURE, SYMPTOMS MAY
INCLUDE HEADACHE, DIZZINESS, HEART PALPITATIONS, WEAKNESS, CONFUSION,
NAUSEA, AND EVEN CONVULSIONS, EVENTUAL UNCONSCIOUSNESS AND DEATH.
SOME EXPERIMENTAL EVIDENCE INDICATES TERATOGENIC AND REPRODUCTIVE EFFECTS.
SKIN CONTACT:
IF IRRITATION OCCURS, FLUSH AFFECTED AREA WITH COPIOUS QUANTITIES OF
WATER. REMOVE CONTAMINATED CLOTHING. IF IRRITATION PERSISTS, SEEK MEDICAL
ATTENTION.
FOR FROSTBITE, IMMERSE SKIN IN LUKEWARM WATER. DO NOT USE HOT WATER.
EYE CONTACT:
PERSONS WITH POTENTIAL EXPOSURE TO HYDROGEN SULFIDE SHOULD NOT WEAR
CONTACT LENSES. FLUSH EYES WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15
MINUTES, HOLDING EYELIDS OPEN TO ENSURE ADEQUATE RINSING. IF IRRITATION
PERSISTS, SEEK IMMEDIATE MEDICAL ATTENTION. IF FROSTBITE IS SUSPECTED,
FLUSH EYES WITH COOL WATER FOR 15 MINUTES AND OBTAIN IMMEDIATE MEDICAL
ATTENTION.
INGESTION: INGESTION UNLIKELY. PRODUCT IS A GAS UNDER NORMAL CONDITIONS
| 5 FIRE FIGHTING MEASURES | |
FLAMMABILITY: NOT FLAMMABLE
FLASH POINT: NOT AVAILABLE
FLASH POINT METHOD: NOT APPLICABLE
BURNING RATE: NOT AVAILABLE
AUTOIGNITION TEMPERATURE: NOT AVAILABLE
LOWER EXPLOSIVE LIMIT: NONE
UPPER EXPLOSIVE LIMIT: NONE
FIRE AND EXPLOSION HAZARDS:
NONFLAMMABLE. CYLINDERS MAY RUPTURE VIOLENTLY OR VENT RAPIDLY FROM
PRESSURE WHEN INVOLVED IN A FIRE SITUATION.
EXTINGUISHING MEDIA:
NONE REQUIRED. USE AS APPROPRIATE FOR SURROUNDING MATERIALS
FIRE FIGHTING INSTRUCTIONS:
USE WATER SPRAY TO COOL ADJACENT CYLINDERS AND AREAS. FIREFIGHTERS SHOULD
WEAR RESPIRATORY PROTECTION (SCBA) AND FULL TURNOUT OR BUNKER GEAR.
CONTINUE TO COOL FIRE-EXPOSED CYLINDERS UNTIL WELL AFTER FLAMES ARE
EXTINGUISHED.
| 6 ACCIDENTAL RELEASE MEASURES | |
ISOLATE HAZARD AREA, EVACUATE PERSONNEL AND DENY ENTRY TO
UNAUTHORIZED/UNPROTECTED INDIVIDUALS. EXTINGUISH ALL IGNITION SOURCES AND
VENTILATE CLOSED SPACES AND LOW AREAS. HYDROGEN SULFIDE IS SOLUBLE, USE
WATER SPRAY TO KNOCK DOWN VAPORS AND PROTECT PERSONNEL. DIKE RUNOFF WATERS
FOR LATER DISPOSAL. PERSONNEL ENTERING AREA SHOULD WEAR APPROPRIATE
PROTECTIVE EQUIPMENT, INCLUDING RESPIRATORY PROTECTION SUITABLE FOR
UNKNOWN CONCENTRATIONS. PERSONNEL SHOULD NOT RE-ENTER AN AREA UNTIL
HYDROGEN SULFIDE HAS SUFFICIENTLY DISPERSED AND ADEQUATE OXYGEN
RE-ESTABLISHED. IF A LEAK IS IN USER'S EQUIPMENT, BE CERTAIN TO PURGE
PIPING WITH AN INERT GAS PRIOR TO ATTEMPTING REPAIRS. IF LEAK IS IN
CONTAINER VALVE, CONTACT THE APPROPRIATE EMERGENCY TELEPHONE NUMBER
LISTED IN SECTION 1 OR CALL YOUR CLOSEST NORCO/NORLAB LOCATION.
| 7 HANDLING AND STORAGE | |
HANDLING PRECAUTIONS:
USE ONLY IN WELL-VENTILATED AREAS. VALVE PROTECTION CAPS MUST REMAIN IN
PLACE UNLESS THE CYLINDER IS SECURED WITH VALVE OUTLET PIPED TO USE POINT.
DO NOT DRAG, SLIDE OR ROLL CYLINDERS. USE A SUITABLE HAND TRUCK FOR
CYLINDER MOVEMENT. USE A PRESSURE REGULATOR WHEN CONNECTING CYLINDER TO
LOWER PRESSURE (<3000 PSIG) PIPING OR SYSTEMS. DO NOT HEAT CYLINDER BY
ANY MEANS TO INCREASE THE DISCHARGE RATE OF PRODUCT FROM THE CYLINDER.
USE A CHECK VALVE OR TRAP IN THE DISCHARGE LINE TO PREVENT HAZARDOUS
BACKFLOW INTO THE CYLINDER.
DO NOT RELY ON THE OLFACTORY SENSE TO DETECT THE PRESENCE OF HYDROGEN
SULFIDE. ANALYTICAL DEVICES AND INSTRUMENTATION ARE READILY AVAILABLE FOR
THIS PURPOSE. PERFORM FREQUENT ANALYTICAL TESTS TO BE CERTAIN THAT THE TWA
IS NOT EXCEEDED. MANY METALS CORRODE RAPIDLY WITH WET HYDROGEN SULFIDE.
ANHYDROUS HYDROGEN SULFIDE CAN BE HANDLED IN CARBON STEEL, ALUMINUM,
INCONEL(R*), STELITE(R*), 304 AND 316 STAINLESS STEELS. AVOID HARD STEELS,
WHICH ARE HIGHLY STRESSED SINCE THEY MAY BE SUSCEPTIBLE TO HYDROGEN
EMBRITTLEMENT FROM HYDROGEN SULFIDE. MULTIPOINT AIR SAMPLERS WITH ALARMS
FOR PLANT PRODUCTION UNITS SHOULD BE PROVIDED TO CONSTANTLY MONITOR THE
AIR IN AND AROUND THE UNITS.
FOR ADDITIONAL RECOMMENDATIONS, CONSULT COMPRESSED GAS ASSOCIATION
PAMPHLETS P-1.
NEVER CARRY A COMPRESSED GAS CYLINDER OR A CONTAINER OF A GAS IN
CRYOGENIC LIQUID FORM IN AN ENCLOSED SPACE SUCH AS A CAR TRUNK, VAN OR
STATION WAGON. A LEAK CAN RESULT IN A FIRE, EXPLOSION, ASPHYXIATION OR A
TOXIC EXPOSURE.
STORAGE REQUIREMENTS:
PROTECT CYLINDERS FROM PHYSICAL DAMAGE. STORE IN COOL, DRY,
WELL-VENTILATED AREA AWAY FROM HEAVY TRAFFIC AREAS AND EMERGENCY EXITS.
DO NOT ALLOW THE TEMPERATURE WHERE CYLINDERS ARE STORED TO EXCEED 125
DEGREES F (52 DEGREES C). CYLINDERS SHOULD BE STORED UPRIGHT AND FIRMLY
SECURED TO PREVENT FALLING OR BEING KNOCKED OVER. FULL AND EMPTY CYLINDERS
SHOULD BE SEGREGATED. USE A "FIRST IN-FIRST OUT" INVENTORY SYSTEM TO
PREVENT FULL CYLINDERS FROM BEING STORED FOR EXCESSIVE PERIODS OF TIME.
| 8 EXPOSURE CONTROLS/PERSONAL PROTECTION | |
ENGINEERING CONTROLS:
ALL VENTILATION SHOULD BE DESIGNED IN ACCORDANCE WITH OSHA STANDARD
(29 CFR 1910.94). USE LOCAL EXHAUST AT FILLING ZONES AND WHERE LEAKAGE
AND DUST FORMATION IS PROBABLE. USE MECHANICAL (GENERAL) VENTILATION FOR
STORAGE AREAS. USE APPROPRIATE VENTILATION AS REQUIRED TO KEEP EXPOSURE
LIMITS IN AIR BELOW TLV & PEL LIMITS. MAINTAIN ATMOSPHERIC OXYGEN CONTENT
AT OR ABOVE 19.5%
PERSONAL PROTECTIVE EQUIPMENT:
HYDROGEN SULFIDE CAS#: (7783-06-4) [0.0005-0.01%]
CARBON MONOXIDE CAS#: (630-08-0) [0.0001-0.0999%]
METHANE CAS#: (74-82-8) [0.1-3.0%]
OXYGEN CAS#: (7782-44-7) [10.0-23.5%]
NITROGEN CAS#: (7727-37-9) [73.3901-89.8994%]
PERSONAL PROTECTIVE EQUIPMENT:
RESPIRATORY PROTECTION:
WHERE RISK ASSESSMENT SHOWS AIR-PURIFYING RESPIRATORS ARE APPROPRIATE
USE A FULL-FACE RESPIRATOR WITH MULTI-PURPOSE COMBINATION (US) OR TYPE
AXBEK (EN 14387) RESPIRATOR CARTRIDGES AS A BACKUP TO ENGINEERING
CONTROLS. IF THE RESPIRATOR IS THE SOLE MEANS OF PROTECTION, USE A
FULL-FACE SUPPLIED AIR RESPIRATOR. USE RESPIRATORS AND COMPONENTS
TESTED AND APPROVED UNDER APPROPRIATE GOVERNMENT STANDARDS SUCH AS
NIOSH (US) OR CEN (EU).
HAND PROTECTION:
HANDLE WITH GLOVES. GLOVES MUST BE INSPECTED PRIOR TO USE. USE PROPER
GLOVE REMOVAL TECHNIQUE (WITHOUT TOUCHING GLOVES OUTER SURFACE) TO AVOID
SKIN CONTACT WITH THIS PRODUCT. DISPOSE OF CONTAMINATED GLOVES AFTER USE
IN ACCORDANCE WITH APPLICABLE LAWS AND GOOD LABORATORY PRACTICES. WASH AND
DRY HANDS.
FULL CONTACT MATERIAL:
BUTYL-RUBBER MINIMUM LAYER THICKNESS:
0.3 MM BREAK THROUGH TIME:
480 MIN MATERIAL TESTED: BUTOJECT (KCL 897 / ALDRICH Z677647, SIZE M)
SPLASH PROTECTION:
MATERIAL:
BUTYL-RUBBER MINIMUM LAYER THICKNESS:
0.3 MM BREAK THROUGH TIME:
480 MIN MATERIAL TESTED:
BUTOJECT (KCL 897 / ALDRICH Z677647, SIZE M) DATA SOURCE:
KCL GMBH, D-36124 EICHENZELL, PHONE +49 (0)6659 87300, E-MAIL
SALES@KCL.DE, TEST METHOD:
EN374 IF USED IN SOLUTION, OR MIXED WITH OTHER SUBSTANCES, AND UNDER
CONDITIONS WHICH DIFFER FROM EN 374, CONTACT THE SUPPLIER OF THE CE
APPROVED GLOVES. THIS RECOMMENDATION IS ADVISORY ONLY AND MUST BE
EVALUATED BY AN INDUSTRIAL HYGIENIST FAMILIAR WITH THE SPECIFIC
SITUATION OF ANTICIPATED USE BY OUR CUSTOMERS. IT SHOULD NOT BE
CONSTRUED AS OFFERING AN APPROVAL FOR ANY SPECIFIC USE SCENARIO.
EYE PROTECTION:
FACE SHIELD AND SAFETY GLASSES USE EQUIPMENT FOR EYE PROTECTION TESTED AND
APPROVED UNDER APPROPRIATE GOVERNMENT STANDARDS SUCH AS NIOSH (US) OR EN
166(EU).
SKIN AND BODY PROTECTION:
COMPLETE SUIT PROTECTING AGAINST CHEMICALS, FLAME RETARDANT ANTISTATIC
PROTECTIVE CLOTHING, THE TYPE OF PROTECTIVE EQUIPMENT MUST BE SELECTED
ACCORDING TO THE CONCENTRATION AND AMOUNT OF THE DANGEROUS SUBSTANCE AT
THE SPECIFIC WORKPLACE.
HYGIENE MEASURES:
AVOID CONTACT WITH SKIN, EYES AND CLOTHING. WASH HANDS BEFORE BREAKS AND
IMMEDIATELY AFTER HANDLING THE PRODUCT.
HYDROGEN SULFIDE CAS#: (7783-06-4) [0.0005-0.01%]
TWA: 10 PPM
USA. ACGIH THRESHOLD LIMIT VALUES (TLV)
STEL:
15 PPM
21 MG/M3
USA. ACGIH THRESHOLD LIMIT VALUES (TLV)
TWA:
10 PPM
14 MG/M3
USA. OSHA - TABLE Z-1 LIMITS FOR AIR CONTAMINANTS - 1910.1000
STEL:
15 PPM
21 MG/M3
USA. OSHA - TABLE Z-1 LIMITS FOR AIR CONTAMINANTS - 1910.1000
CEIL: 20 PPM
USA. OCCUPATIONAL EXPOSURE LIMITS (OSHA) - TABLE Z2
PEAK: 50 PPM
USA. OCCUPATIONAL EXPOSURE LIMITS (OSHA) - TABLE Z2 -Z37.2-1966
TWA: 1 PPM
USA. ACGIH THRESHOLD LIMIT VALUES (TLV)
CENTRAL NERVOUS SYSTEM IMPAIRMENT UPPER RESPIRATORY TRACT IRRITATION 2010
ADOPTION
STEL: 5 PPM
USA. ACGIH THRESHOLD LIMIT VALUES (TLV)
CENTRAL NERVOUS SYSTEM IMPAIRMENT UPPER RESPIRATORY TRACT IRRITATION 2010
ADOPTION
CEIL:
10 PPM
15 MG/M3
USA. NIOSH RECOMMENDED EXPOSURE LIMITS
10 MINUTE CEILING VALUE
CARBON MONOXIDE CAS#: (630-08-0) [0.0001-0.0999%]
CEIL:
200 PPM
229 MG/M3
USA. OSHA - TABLE Z-1 LIMITS FOR AIR CONTAMINANTS - 1910.1000
SAMPLING FOR THE CARBON MONOXIDE CEILING SHALL BE AVERAGED OVER 5 MINUTES
BUT AN INSTANTANEOUS READING OVER 1500 PPM SHALL NOT BE EXCEEDED.
TWA:
50 PPM
55 MG/M3 S
USA. OCCUPATIONAL EXPOSURE LIMITS (OSHA) - TABLE Z- 1 - LIMITS FOR AIR
CONTAMINANT
THE VALUE IN MG/M3 IS APPROXIMATE.
TWA: 25 PPM
USA. ACGIH THRESHOLD LIMIT VALUES (TLV)
CARBOXYHEMOGLOBINEMIA SUBSTANCES FOR WHICH THERE IS A BIOLOGICAL EXPOSURE
INDEX OR INDICES.
TWA:
35 PPM
40 MG/M3
USA. OSHA - TABLE Z-1 LIMITS FOR AIR CONTAMINANTS - 1910.1000
TWA:
35 PPM
40 MG/M3
USA. NIOSH RECOMMENDED EXPOSURE LIMITS
CEIL:
200 PPM
229 MG/M3
USA. NIOSH RECOMMENDED EXPOSURE LIMITS
METHANE CAS#: (74-82-8) [0.1-3.0%]
TWA: 1,000 PPM
USA. ACGIH THRESHOLD LIMIT VALUES (TLV)
CENTRAL NERVOUS SYSTEM IMPAIRMENT CARDIAC SENSITIZATION
| 9 PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: COLORLESS GAS
PHYSICAL STATE: GAS
ODOR: CHARACTERISTIC ROTTEN EGG ODOR
ODOR THRESHOLD:
FAINT BUT READILLY PERCEPTABLE AT 0.77 PPM. DO NOT RELY ON SMELL TO DETECT
HYDROGEN SULFIDE BECAUSE OF OLFACTORY FATIGUE.
MOLECULAR FORMULA: MIXTURE
PARTICLE SIZE: NOT DETERMINED
SOLUBILITY: VERY SLIGHTLY SOLUBLE
SOFTENING POINT: NOT DETERMINED
VISCOSITY: NOT DETERMINED
PERCENT VOLATILE: 100%
HEAT VALUE: NOT DETERMINED
BOILING POINT: NOT DETERMINED
FREEZING OR MELTING POINT: NOT DETERMINED
FLAMMABILITY: NOT FLAMMABLE
FLASH POINT: NOT DETERMINED
PARTITION COEFFICIENT: NOT DETERMINED
VAPOR PRESSURE: NOT DETERMINED
VAPOR DENSITY: NOT DETERMINED
POTENTIA HYDROGENII: NOT DETERMINED
EVAPORATION RATE: NOT DETERMINED
BULK DENSITY: NOT DETERMINED
UPPER FLAMMABILITY LIMIT AND LOWER FLAMMABILITY LIMIT: NONE
| 10 STABILITY AND REACTIVITY | |
CHEMICAL STABILITY: PRODUCT IS STABLE UNDER NORMAL CONDITIONS.
CONDITIONS TO AVOIDENTIFICATION: AVOID OPEN FLAMES AND HIGH TEMPERATURES.
MATERIALS TO AVOIDENTIFICATION:
ALL FLAMMABLE MATERIALS. HYDROGEN SULFIDE WILL REACT WITH BRASS MATERIALS
WITH COPPER SULFIDE AS A REACTION PRODUCT.
HAZARDOUS DECOMPOSITION:
CARBON OXIDES, NITROGEN OXIDES (NOX) AND SULFUR OXIDES.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR.
| 11 TOXICOLOGICAL INFORMATION | |
HYDROGEN SULFIDE CAS#: (7783-06-4) [0.0005-0.01%]
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
ORAL LD50: NO DATA AVAILABLE
INHALATION LC50 LC50 INHALATION: MOUSE - 1 H - 634 PPM
LC50 INHALATION - RAT - 444 PPM REMARKS:
LUNGS, THORAX, OR RESPIRATION:
OTHER CHANGES. DIARRHOEA KIDNEY, URETER, BLADDER: URINE VOLUME INCREASED.
DERMAL LD50:
OTHER INFORMATION ON ACUTE TOXICITY:
SKIN CORROSION/IRRITATION: NO DATA AVAILABLE
SERIOUS EYE DAMAGE/EYE IRRITATION: NO DATA AVAILABLE
RESPIRATORY OR SKIN SENSITIZATION: NO DATA AVAILABLE
GERM CELL MUTAGENICITY: NO DATA AVAILABLE
CARCINOGENICITY:
IARC:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS PROBABLE, POSSIBLE OR CONFIRMED HUMAN CARCINOGEN
BY IARC.
ACGIH:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A CARCINOGEN OR POTENTIAL CARCINOGEN BY ACGIH.
NTP:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A KNOWN OR ANTICIPATED CARCINOGEN BY NTP.
OSHA:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A CARCINOGEN OR POTENTIAL CARCINOGEN BY OSHA.
REPRODUCTIVE TOXICITY:
REPRODUCTIVE TOXICITY - RAT - INHALATION:
EFFECTS ON NEWBORN: PHYSICAL.NO DATA AVAILABLE
TERATOGENICITY: NO DATA AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE (GLOBALLY HARMONIZED
SYSTEM): NO DATA AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE (GLOBALLY HARMONIZED
SYSTEM): NO DATA AVAILABLE
ASPIRATION HAZARD: NO DATA AVAILABLE
POTENTIAL HEALTH EFFECTS:
INHALATION TOXIC IF INHALED. MAY CAUSE RESPIRATORY TRACT IRRITATION.
INGESTION MAY BE HARMFUL IF SWALLOWED. SKIN MAY BE HARMFUL IF ABSORBED
THROUGH SKIN. MAY CAUSE SKIN IRRITATION. EYES MAY CAUSE EYE IRRITATION.
SIGNS AND SYMPTOMS OF EXPOSURE:
HYDROGEN SULFIDE IS STRONGLY BOUND TO METHEMOGLOBIN IN A MANNER SIMILAR
TO CYANIDE. TOXICOLOGICALLY, ITS REACTION WITH ENZYMES IN THE BLOOD
STREAM INHIBITS CELL RESPIRATION RESULTING IN PULMONARY PARALYSIS, SUDDEN
COLLAPSE, AND DEATH. IT IS RECOGNIZED BY ITS CHARACTERISTIC ODOR OF
"ROTTEN EGGS". THE DETECTABLE, MINIMUM PERCEPTIBLE ODOR OCCURS AT 0.13PPM,
RAPID OLFACTORY FATIGUE CAN OCCUR AT HIGH CONCENTRATIONS (>100 PPM). AT
CONCENTRATIONS OF 20PPM HYDROGEN SULFIDE BEGINS ACTING AS AN IRRITANT ON
THE MUCOUS MEMBRANES OF THE EYES AND RESPIRATORY TRACT AND INCREASES WITH
CONCENTRATION AND EXPOSURE TIME. EYE IRRITATION IS CHARACTERIZED BY
IRRITATION OF THE CONJUNCTIVA WITH PHOTOPHOBIA TO KERATOCONJUNCTIVITIS
AND VESICULAT ION OF THE CORNEA EPITHELIUM. PROLONGED EXPOSURE TO MODERATE
CONCENTRATIONS (250PPM) MAY CAUSE PULMONARY EDEMA. AT CONCENTRATIONS OVER
500PPM, DROWSINESS, DIZZINESS, EXCITEMENT, HEADACHE, UNSTABLE GAIT, AND
OTHER SYSTEMIC SYMPTOMS OCCUR WITHIN A FEW MINUTES. SUDDEN LOSS OF
CONSCIOUSNESS WITHOUT PREMONITION, ANXIETY, OR SENSE OF STRUGGLE ARE
CHARACTERISTIC OF ACUTE EXPOSURE AT CONCENTRATIONS ABOVE 700PPM. AT
CONCENTRATIONS OF 1000-2000PPM HYDROGEN SULFIDE IS RAPIDLY ABSORBED
THROUGH THE LUNG INTO THE BLOOD. IN THIS RANGE A SINGLE INHALATION
MAY CAUSE COMA AND MAY BE RAPIDLY FATAL. INITIALLY HYPERPNEA OCCURS,
FOLLOWED BY RAPID COLLAPSE AND RESPIRATORY INHIBITION. AT HIGHER
CONCENTRATIONS, HYDROGEN SULFIDE EXERTS AN IMMEDIATE PARALYZING EFFECT
ON THE RESPIRATORY CENTERS. WHEN CONCENTRATION REACHES 5000PPM, IMMINENT
DEATH ALMOST ALWAYS RESULTS., EXPOSURE TO AND/OR CONSUMPTION OF ALCOHOL
MAY INCREASE TOXIC EFFECTS.
SYNERGISTIC EFFECTS: NO DATA AVAILABLE
ADDITIONAL INFORMATION:
RTECS: MX1225000
CARBON MONOXIDE CAS#: (630-08-0) [0.0001-0.0999%]
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
ORAL LD50 INHALATION LC50: LC50 INHALATION - RAT - 4 H - 1807 PPM
DERMAL LD50: NO DATA AVAILABLE
OTHER INFORMATION ON ACUTE TOXICITY:
SKIN CORROSION/IRRITATION: NO DATA AVAILABLE
SERIOUS EYE DAMAGE/EYE IRRITATION: NO DATA AVAILABLE
RESPIRATORY OR SKIN SENSITIZATION: NO DATA AVAILABLE
GERM CELL MUTAGENICITY: NO DATA AVAILABLE
CARCINOGENICITY:
IARC:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS PROBABLE, POSSIBLE OR CONFIRMED HUMAN CARCINOGEN
BY IARC.
ACGIH:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A CARCINOGEN OR POTENTIAL CARCINOGEN BY ACGIH.
NTP:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A KNOWN OR ANTICIPATED CARCINOGEN BY NTP.
OSHA:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A CARCINOGEN OR POTENTIAL CARCINOGEN BY OSHA.
REPRODUCTIVE TOXICITY: NO DATA AVAILABLE
TERATOGENICITY: KNOWN HUMAN REPRODUCTIVE TOXICANT
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE (GLOBALLY HARMONIZED
SYSTEM): NO DATA AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE (GLOBALLY HARMONIZED
SYSTEM):
INHALATION - CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED
EXPOSURE.
ASPIRATION HAZARD: NO DATA AVAILABLE
POTENTIAL HEALTH EFFECTS:
INHALATION MAY BE HARMFUL IF INHALED. MAY CAUSE RESPIRATORY TRACT
IRRITATION. INGESTION MAY BE HARMFUL IF SWALLOWED. SKIN MAY BE
HARMFUL IF ABSORBED THROUGH SKIN. MAY CAUSE SKIN IRRITATION. EYES
MAY CAUSE EYE IRRITATION.
SIGNS AND SYMPTOMS OF EXPOSURE: BLOOD DISORDERS
SYNERGISTIC EFFECTS: NO DATA AVAILABLE
ADDITIONAL INFORMATION:
RTECS: FG3500000
METHANE CAS#: (74-82-8) [0.1-3.0%]
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
ORAL LD50: NO DATA AVAILABLE
INHALATION LC50:
DERMAL LD50:
OTHER INFORMATION ON ACUTE TOXICITY:
SKIN CORROSION/IRRITATION: NO DATA AVAILABLE
SERIOUS EYE DAMAGE/EYE IRRITATION: NO DATA AVAILABLE
RESPIRATORY OR SKIN SENSITIZATION: NO DATA AVAILABLE
GERM CELL MUTAGENICITY: NO DATA AVAILABLE
CARCINOGENICITY:
IARC:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS PROBABLE, POSSIBLE OR CONFIRMED HUMAN CARCINOGEN
BY IARC.
ACGIH:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A CARCINOGEN OR POTENTIAL CARCINOGEN BY ACGIH.
NTP:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A KNOWN OR ANTICIPATED CARCINOGEN BY NTP.
OSHA:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A CARCINOGEN OR POTENTIAL CARCINOGEN BY OSHA.
REPRODUCTIVE TOXICITY: NO DATA AVAILABLE
TERATOGENICITY: NO DATA AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE (GLOBALLY HARMONIZED
SYSTEM): NO DATA AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE (GLOBALLY HARMONIZED
SYSTEM): NO DATA AVAILABLE
ASPIRATION HAZARD: NO DATA AVAILABLE
POTENTIAL HEALTH EFFECTS:
INHALATION MAY BE HARMFUL IF INHALED. MAY CAUSE RESPIRATORY TRACT
IRRITATION. INGESTION MAY BE HARMFUL IF SWALLOWED. SKIN MAY BE
HARMFUL IF ABSORBED THROUGH SKIN. MAY CAUSE SKIN IRRITATION. EYES
MAY CAUSE EYE IRRITATION.
SIGNS AND SYMPTOMS OF EXPOSURE:
TO THE BEST OF OUR KNOWLEDGE, THE CHEMICAL, PHYSICAL, AND TOXICOLOGICAL
PROPERTIES HAVE NOT BEEN THOROUGHLY INVESTIGATED.
SYNERGISTIC EFFECTS: NO DATA AVAILABLE
ADDITIONAL INFORMATION:
RTECS: PA1490000
OXYGEN CAS#: (7782-44-7) [10.0-23.5%]
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
ORAL LD50: NO DATA AVAILABLE
INHALATION LC50:
DERMAL LD50:
OTHER INFORMATION ON ACUTE TOXICITY:
SKIN CORROSION/IRRITATION: NO DATA AVAILABLE
SERIOUS EYE DAMAGE/EYE IRRITATION: NO DATA AVAILABLE
RESPIRATORY OR SKIN SENSITIZATION: NO DATA AVAILABLE
GERM CELL MUTAGENICITY: NO DATA AVAILABLE
CARCINOGENICITY:
IARC:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS PROBABLE, POSSIBLE OR CONFIRMED HUMAN CARCINOGEN
BY IARC.
ACGIH:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A CARCINOGEN OR POTENTIAL CARCINOGEN BY ACGIH.
NTP:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A KNOWN OR ANTICIPATED CARCINOGEN BY NTP.
OSHA:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A CARCINOGEN OR POTENTIAL CARCINOGEN BY OSHA.
REPRODUCTIVE TOXICITY: NO DATA AVAILABLE
TERATOGENICITY: NO DATA AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE (GLOBALLY HARMONIZED
SYSTEM): NO DATA AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE (GLOBALLY HARMONIZED
SYSTEM): NO DATA AVAILABLE
ASPIRATION HAZARD: NO DATA AVAILABLE
POTENTIAL HEALTH EFFECTS:
INHALATION MAY BE HARMFUL IF INHALED. MAY CAUSE RESPIRATORY TRACT
IRRITATION. INGESTION MAY BE HARMFUL IF SWALLOWED. SKIN MAY BE HARMFUL
IF ABSORBED THROUGH SKIN. MAY CAUSE SKIN IRRITATION. EYES MAY CAUSE EYE
IRRITATION.
SIGNS AND SYMPTOMS OF EXPOSURE:
NAUSEA, DIZZINESS, UNCONSCIOUSNESS, MAY BE HARMFUL.
SYNERGISTIC EFFECTS: NO DATA AVAILABLE
ADDITIONAL INFORMATION:
RTECS: RS2060000
NITROGEN CAS#: (7727-37-9) [73.3901-89.8994%]
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
ORAL LD50: NO DATA AVAILABLE
INHALATION LC50:
DERMAL LD50:
OTHER INFORMATION ON ACUTE TOXICITY:
SKIN CORROSION/IRRITATION: NO DATA AVAILABLE
SERIOUS EYE DAMAGE/EYE IRRITATION: NO DATA AVAILABLE
RESPIRATORY OR SKIN SENSITIZATION: NO DATA AVAILABLE
GERM CELL MUTAGENICITY: NO DATA AVAILABLE
CARCINOGENICITY:
IARC:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS PROBABLE, POSSIBLE OR CONFIRMED HUMAN CARCINOGEN
BY IARC.
ACGIH:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A CARCINOGEN OR POTENTIAL CARCINOGEN BY ACGIH.
NTP:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A KNOWN OR ANTICIPATED CARCINOGEN BY NTP.
OSHA:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A CARCINOGEN OR POTENTIAL CARCINOGEN BY OSHA.
REPRODUCTIVE TOXICITY: NO DATA AVAILABLE
TERATOGENICITY: NO DATA AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE (GLOBALLY HARMONIZED
SYSTEM): NO DATA AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE (GLOBALLY HARMONIZED
SYSTEM): NO DATA AVAILABLE
ASPIRATION HAZARD: NO DATA AVAILABLE
POTENTIAL HEALTH EFFECTS:
INHALATION MAY BE HARMFUL IF INHALED. MAY CAUSE RESPIRATORY TRACT
IRRITATION. INGESTION MAY BE HARMFUL IF SWALLOWED. SKIN MAY BE HARMFUL
IF ABSORBED THROUGH SKIN. MAY CAUSE SKIN IRRITATION. EYES MAY CAUSE EYE
IRRITATION.
SIGNS AND SYMPTOMS OF EXPOSURE:
MAY BE HARMFUL., NAUSEA, HEADACHE, VOMITING
SYNERGISTIC EFFECTS: NO DATA AVAILABLE
ADDITIONAL INFORMATION:
RTECS: QW9700000
| 12 ECOLOGICAL INFORMATION | |
HYDROGEN SULFIDE CAS#: (7783-06-4) [0.0005-0.01%]
INFORMATION ON ECOLOGICAL EFFECTS:
TOXICITY:
TOXICITY TO FISH LC50:
PIMEPHALES PROMELAS (FATHEAD MINNOW) - 0.016 MG/L - 96.0 H.
PERSISTENCE AND DEGRADABILITY: NO DATA AVAILABLE
BIOACCUMULATIVE POTENTIAL: NO DATA AVAILABLE
MOBILITY IN SOIL: NO DATA AVAILABLE
PBT AND VPVB ASSESSMENT: NO DATA AVAILABLE
OTHER ADVERSE EFFECTS:
AN ENVIRONMENTAL HAZARD CANNOT BE EXCLUDED IN THE EVENT OF UNPROFESSIONAL
HANDLING OR DISPOSAL.
CARBON MONOXIDE CAS#: (630-08-0) [0.0001-0.0999%]
INFORMATION ON ECOLOGICAL EFFECTS:
TOXICITY: NO DATA AVAILABLE
PERSISTENCE AND DEGRADABILITY: NO DATA AVAILABLE
BIOACCUMULATIVE POTENTIAL: NO DATA AVAILABLE
MOBILITY IN SOIL: NO DATA AVAILABLE
PBT AND VPVB ASSESSMENT: NO DATA AVAILABLE
OTHER ADVERSE EFFECTS: NO DATA AVAILABLE
METHANE CAS#: (74-82-8) [0.1-3.0%]
INFORMATION ON ECOLOGICAL EFFECTS:
TOXICITY: NO DATA AVAILABLE
PERSISTENCE AND DEGRADABILITY: NO DATA AVAILABLE
BIOACCUMULATIVE POTENTIAL: NO DATA AVAILABLE
MOBILITY IN SOIL: NO DATA AVAILABLE
PBT AND VPVB ASSESSMENT: NO DATA AVAILABLE
OTHER ADVERSE EFFECTS: NO DATA AVAILABLE
OXYGEN CAS#: (7782-44-7) [10.0-23.5%]
INFORMATION ON ECOLOGICAL EFFECTS:
TOXICITY: NO DATA AVAILABLE
PERSISTENCE AND DEGRADABILITY: NO DATA AVAILABLE
BIOACCUMULATIVE POTENTIAL: NO DATA AVAILABLE
MOBILITY IN SOIL: NO DATA AVAILABLE
PBT AND VPVB ASSESSMENT: NO DATA AVAILABLE
OTHER ADVERSE EFFECTS: NO DATA AVAILABLE
NITROGEN CAS#: (7727-37-9) [73.3901-89.8994%]
INFORMATION ON ECOLOGICAL EFFECTS:
TOXICITY: NO DATA AVAILABLE
PERSISTENCE AND DEGRADABILITY: NO DATA AVAILABLE
BIOACCUMULATIVE POTENTIAL: NO DATA AVAILABLE
MOBILITY IN SOIL: NO DATA AVAILABLE
PBT AND VPVB ASSESSMENT: NO DATA AVAILABLE
OTHER ADVERSE EFFECTS: NO DATA AVAILABLE
| 13 DISPOSAL CONSIDERATIONS | |
DISPOSE OF IN ACCORDANCE WITH LOCAL REGULATIONS. DO NOT ATTEMPT TO DISPOSE
OF WASTE OR UNUSED QUANTITIES IN RETURNABLE CYLINDERS. RETURN IN THE
SHIPPING CONTAINER, PROPERLY LABELED, WITH ANY VALVE OUTLET PLUGS OR CAPS
SECURE AND VALVE PROTECTION CAP IN PLACE TO NORLAB FOR PROPER DISPOSAL.
NON-REFILLABLE CONTAINERS SHOULD BE VENTED IN A WELL-VENTILATED AREA THEN
DISPOSED OF IN COMPLIANCE WITH LOCAL REGULATIONS, OR RETURNED TO NORLAB.
| 14 TRANSPORT INFORMATION | |
UN1956, COMPRESSED GAS, N.O.S., 2.2:
PROPER SHIPPING NAME US:
UN 1956, COMPRESSED GAS N.O.S., (HYDROGEN SULFIDE, NITROGEN), 2.2
PROPER SHIPPING NAME CANADA:
UN1956, COMPRESSED GAS, N.O.S., (HYDROGEN SULFIDE, NITROGEN), 2.2
NON-FLAMMABLE GAS, CLASS/DIVISION 2.2
| 15 REGULATORY INFORMATION | |
COMPONENT (CAS#) [%] - CODES:
RQ(100LBS), HYDROGEN SULFIDE (7783-06-4) [0.0005-0.01%] CERCLA, CSWHS,
DSL, EHS302, HAP, MASS, NJEHS, NJHS, OSHAPSM, OSHAWAC, PA, SARA313,
TOXICRCRA, TSCA, TXAIR, TXHWL
CARBON MONOXIDE (630-08-0) [0.0001-0.0999%] DSL, MASS, NJEHS, OSHAWAC,
PA, PROP65, TSCA, TXAIR
METHANE (74-82-8) [0.1-3.0%] DSL, MASS, NJHS, PA, TSCA, TXAIR
OXYGEN (7782-44-7) [10.0-23.5%] MASS, PA, TSCA
NITROGEN (7727-37-9) [73.3901-89.8994%] MASS, PA, TSCA
WARNING:
THIS PRODUCT CAN EXPOSE YOU TO CHEMICALS INCLUDING CARBON MONOXIDE, WHICH
IS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE BIRTH DEFECTS OR OTHER
REPRODUCTIVE HARM. FOR MORE INFORMATION GO TO WWW.P65WARNINGS.CA.GOV.
REGULATORY CODE DESCRIPTIONS:
RQ = REPORTABLE QUANTITY
CERCLA = SUPERFUND CLEAN UP SUBSTANCE
CSWHS = CLEAN WATER ACT HAZARDOUS SUBSTANCES
DSL = CANADIAN DOMESTIC SUBSTANCES LIST
EHS302 = EXTREMELY HAZARDOUS SUBSTANCE
HAP = HAZARDOUS AIR POLLUTANTS
MASS = MA MASSACHUSETTS HAZARDOUS SUBSTANCES LIST
NJEHS = NJ EXTRAORDINARILY HAZARDOUS SUBSTANCES
NJHS = NJ RIGHT-TO-KNOW HAZARDOUS SUBSTANCES
OSHAPSM = OSHA CHEMICALS REQUIRING PROCESS SAFETY MANAGEMENT
OSHAWAC = OSHA WORKPLACE AIR CONTAMINANTS
PA = PA RIGHT-TO-KNOW LIST OF HAZARDOUS SUBSTANCES
SARA313 = SARA 313 TITLE III TOXIC CHEMICALS
TOXICRCRA = RCRA TOXIC HAZARDOUS WASTES (U-LIST)
TSCA = TOXIC SUBSTANCES CONTROL ACT
TXAIR = TX AIR CONTAMINANTS WITH HEALTH EFFECTS SCREENING LEVEL
TXHWL = TX HAZARDOUS WASTE LIST
PROP65 = CA PROP 65
| 16 OTHER INFORMATION | |
NFPA:
HEALTH 1
FIRE 0
REACTIVITY 0
SPECIFIC HAZARD N/A
HMIS III:
HEALTH 1
FIRE 0
PHYSICAL HAZARD 3
HMIS PPE: B - SAFETY GLASSES, GLOVES
NFPA:
HEALTH 1
FIRE HAZARD 0
REACTIVITY 0
SPECIFIC HAZARD
HMIS:
HEALTH 1
FLAMMABILITY 0
PHYSICAL HAZARD 3
PERSONAL PROTECTION B
PPE:
SAFETY GLASSES
GLOVES
DISCLAIMER:
ALTHOUGH REASONABLE CARE HAS BEEN TAKEN IN THE PREPARATION OF THIS
DOCUMENT, WE EXTEND NO WARRANTIES AND MAKE NO REPRESENTATIONS AS TO
THE ACCURACY OR COMPLETENESS OF THE INFORMATION CONTAINED HEREIN, AND
ASSUME NO RESPONSIBILITY REGARDING THE SUITABILITY OF THIS INFORMATION
FOR THE USER'S INTENDED PURPOSES OR FOR THE CONSEQUENCES OF ITS USE.
EACH INDIVIDUAL SHOULD MAKE A DETERMINATION AS TO THE SUITABILITY OF
THE INFORMATION FOR THEIR PARTICULAR PURPOSE(S).
REVISION DATE: 9/6/2019