| Common Name: | 0.0002% TO 0.01% NITROGEN DIOXIDE IN NITROGEN |
| Manufacturer: | NORLAB |
| SDS Revision Date: | 6/1/2018 |
| SDS Format: | GHS-US |
| Item Number(s): | 8FZD7 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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NORLAB
A DIVISION OF NORCO, INC.
SDS
SAFETY DATA SHEET
0.0002% TO 0.01% NITROGEN DIOXIDE IN NITROGEN
| 1 PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT IDENTIFIER: 0.0002% TO 0.01% NITROGEN DIOXIDE IN NITROGEN
SYNONYMS: NITROGEN DIOXIDE IN NITROGEN, NOX GAS MIX, CALIBRATION GAS MIX
COMMON NAME: NITROGEN DIOXIDE IN NITROGEN
SDS NUMBER: NLB 2240
REVISION DATE: 6/1/2018
VERSION: 3
CAS NUMBER: NOT AVAILABLE - GAS MIXTURE
EPA NUMBER: NOT AVAILBLE
RCRA NUMBER: NOT APPLICABLE
CHEMICAL FAMILY: GAS MIXTURE
CHEMICAL FORMULA: NO2 IN AIR
PRODUCT USE: CALIBRATION OF ANALYITICAL INSTRUMENTATION
SUPPLIER DETAILS:
NORLAB A DIVISION OF NORCO
898 W. GOWEN RD.
BOISE, ID 83705
CONTACT: QUALITY DEPT.
PHONE: 208-336-1643
INTERNET: WWW.NORLAB-GAS.COM
FOR TRANSPORTATION EMERGENCY CONTACT CHEMTREC: 800-424-9300
| 2 HAZARDS IDENTIFICATION | |
CLASSIFICATION OF SUBSTANCE:
GHS CLASSIFICATION IN ACCORDANCE WITH 29 CFR 1910 (OSHA HCS):
PHYSICAL, GASES UNDER PRESSURE, COMPRESSED GAS:
HEALTH, ACUTE TOXICITY, 5 INHALATION:
GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENTS:
GHS SIGNAL WORD: WARNING
GHS HAZARD PICTOGRAMS: GAS CYLINDER
GHS HAZARD STATEMENTS:
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED
H333: MAY BE HARMFUL IF INHALED
OSHA-H01: MAY DISPLACE OXYGEN AND CAUSE RAPID SUFFOCATION.
GHS PRECAUTIONARY STATEMENTS:
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
P260: DO NOT BREATHE GAS.
P281: USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED.
P304+340:
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING.
P308+313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
P403: STORE AND USE IN A WELL VENTILATED PLACE.
P410+412:
PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING
50 DEG. C/122 DEG. F
CGA-PG05: USE A BACK FLOW PREVENTIVE DEVICE IN THE PIPING.
CGA-PG06: CLOSE VALVE AFTER EACH USE AND WHEN EMPTY.
CGA-PG10: USE ONLY WITH EQUIPMENT RATED FOR CYLINDER PRESSURE.
CGA-PG20: USE ONLY EQUIPMENT OF COMPATIBLE MATERIALS OF CONSTRUCTION.
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC) OR NOT COVERED BY GHS:
ROUTE OF ENTRY: EYES; INHALATION; SKIN
TARGET ORGANS: EYES; CARDIOVASCULAR SYSTEM; RESPIRATORY SYSTEM
INHALATION:
GAS MIXTURE CONTAINS LESS THAN 500 PPM NITROGEN DIOXIDE, WHICH CAN
IRRITATE THE PULMONARY TRACT. INITIAL SYMPTOMS MAY INCLUDE EYE AND
THROAT IRRITATION, CHEST TIGHTNESS, HEADACHE, AND NAUSEA. INHALATION
OF HIGH CONCENTRATIONS MAY CAUSE SWELLING AND FLUID RETENTION IN THE
LUNGS, WHICH CAN BE FATAL. SYMPTOMS MAY BE DELAYED FOR UP TO 72 HOURS
FOLLOWING EXPOSURE.
PRODUCT IS AN ASPHYXIANT. THIS PRODUCT MAY DISPLACE OXYGEN IF RELEASED
IN A CONFINED SPACE. MAINTAIN OXYGEN LEVELS ABOVE 19.5% AT SEA LEVEL TO
PREVENT ASPHYXIATION. EFFECTS OF OXYGEN DEFICIENCY RESULTING FROM SIMPLE
ASPHYXIANTS MAY INCLUDE: RAPID BREATHING, DIMINISHED MENTAL ALERTNESS,
IMPAIRED MUSCULAR COORDINATION, FAULTY JUDGMENT, DEPRESSION OF ALL
SENSATIONS, EMOTIONAL INSTABILITY AND FATIGUE. AS ASPHYXIATION PROGRESSES,
NAUSEA, VOMITING, PROSTRATION AND LOSS OF CONSCIOUSNESS MAY RESULT,
EVENTUALLY LEADING TO CONVULSIONS, COMA AND DEATH.
OXYGEN DEFICIENCY DURING PREGNANCY HAS PRODUCED DEVELOPMENTAL
ABNORMALITIES IN HUMANS AND EXPERIMENTAL ANIMALS.
SKIN CONTACT:
MAY CAUSE IRRITATION. CONTACT WITH RAPIDLY EXPANDING GAS NEAR THE POINT
OF RELEASE MAY CAUSE FROSTBITE WITH REDNESS, SKIN COLOR CHANGE TO GRAY
OR WHITE, AND BLISTERING.
EYE CONTACT:
MAY CAUSE IRRITATION. CONTACT WITH RAPIDLY EXPANDING GAS NEAR THE POINT
OF RELEASE MAY CAUSE FROSTBITE.
INGESTION: NOT ANTICIPATED. PRODUCT IS A GAS AT NORMAL CONDITIONS.
| 3 COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL INGREDIENTS:
CAS# % CHEMICAL NAME
10102-44-0 0.0002-0.01% NITROGEN DIOXIDE
7727-37-9 99.99-99.9998% NITROGEN
| 4 FIRST AID MEASURES | |
INHALATION:
PROMPT REMOVAL FROM THE CONTAMINATED AREA AND IMMEDIATE MEDICAL ATTENTION
IS MANDATORY IN ALL CASES OF OVEREXPOSURE. RESCUE PERSONNEL SHOULD BE
EQUIPPED WITH SELFCONTAINED BREATHING APPARATUS.
DELAYED ONSET OF LIFE-THREATENING SYMPTOMS IS MAY OCCUR.
VICTIMS SHOULD BE CARRIED (NOT ASSISTED) TO AN UNCONTAMINATED AREA AND
INHALE FRESH AIR SUPPLEMENTED WITH OXYGEN. QUICK REMOVAL FROM THE
CONTAMINATED AREA IS MOST IMPORTANT. KEEP PATIENT WARM, QUIET AND UNDER
COMPETENT MEDICAL OBSERVATION UNTIL THE DANGER OF DELAYED PULMONARY EDEMA
HAS PASSED (AT LEAST 72 HOURS). ANY PHYSICAL EXERTION DURING THIS PERIOD
SHOULD BE DISCOURAGED AS IT MAY INCREASE THE SEVERITY OF THE PULMONARY
EDEMA OR CHEMICAL PNEUMONITIS. BED REST IS INDICATED. UNCONSCIOUS PERSONS
SHOULD BE MOVED TO AN UNCONTAMINATED AREA, GIVEN ARTIFICIAL RESUSCITATION
AND SUPPLEMENTAL OXYGEN. ONCE RESPIRATION HAS BEEN RESTORED, THEY SHOULD
BE TREATED AS ABOVE.
SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING AND FLUSH AFFECTED AREA WITH LARGE QUANTITIES
OF WATER. IF IRRITATION PERSISTS OR FROSTBITE IS SUSPECTED, SEEK MEDICAL
ATTENTION.
EYE CONTACT:
PERSONS WITH POTENTIAL EXPOSURE TO NITROGEN DIOXIDE SHOULD NOT WEAR
CONTACT LENSES. FLUSH EYES WITH LARGE AMOUNTS OF WATER FOR AT LEAST
15 MINUTES, HOLDING EYELIDS OPEN TO ENSURE ADEQUATE RINSING. IF IRRITATION
PERSISTS, SEEK IMMEDIATE MEDICAL ATTENTION. IF FROSTBITE IS SUSPECTED,
FLUSH EYES WITH COOL WATER FOR 15 MINUTES AND OBTAIN IMMEDIATE MEDICAL
ATTENTION.
INGESTION: NOT A DIRECT HAZARD.
| 5 FIRE FIGHTING MEASURES | |
FLAMMABILITY: NOT FLAMMABLE
FLASH POINT: NONE
FLASH POINT METHOD: NOT APPLICABLE
BURNING RATE: NOT APPLICABLE
AUTOIGNITION TEMPERATURE: NONE
LOWER EXPLOSIVE LIMIT: NONE
UPPER EXPLOSIVE LIMIT: NONE
FIRE AND EXPLOSION HAZARDS:
NONFLAMMABLE. CYLINDERS MAY VENT RAPIDLY OR RUPTURE VIOLENTLY FROM
PRESSURE WHEN INVOLVED IN A FIRE SITUATION.
EXTINGUISHING MEDIA:
USE MEDIA SUITABLE FOR SURROUNDING COMBUSTIBLE OR FLAMMABLE MATERIALS.
NITROGEN DIOXIDE CAN SLOWLY REACT WITH WATER TO FORM A CORROSIVE SOLUTION
OF NITRIC ACID. NITRIC ACID IS CORROSIVE TO SKIN AND METAL. SMALL AMOUNTS
OF NITROGEN DIOXIDE PRESENT ARE INCOMPATIBLE WITH HALOGENATED EXTINGUISHING
MEDIA.
FIRE FIGHTING INSTRUCTIONS:
STOP THE FLOW OF GAS IF IT CAN BE DONE WITHOUT RISK. USE WATER SPRAY TO
COOL SURROUNDING CONTAINERS. CONTINUE TO COOL SURROUNDING CONTAINERS UNTIL
WELL AFTER FLAMES ARE EXTINGUISHED. FIREFIGHTERS SHOULD WEAR A FULL-FACE
PIECE, NIOSH/MSHA-APPROVED SELFCONTAINED BREATHING APPARATUS (SCBA)
OPERATED IN POSITIVE PRESSURE MODE AND FULL TURNOUT GEAR.
| 6 ACCIDENTAL RELEASE MEASURES | |
ISOLATE HAZARD AREA, EVACUATE PERSONNEL AND DENY ENTRY TO UNAUTHORIZED/
UNPROTECTED INDIVIDUALS. EXTINGUISH ALL IGNITION SOURCES AND VENTILATE
CLOSED SPACES AND LOW AREAS. PERSONNEL ENTERING AREA SHOULD WEAR
APPROPRIATE PROTECTIVE EQUIPMENT INCLUDING RESPIRATORY PROTECTION
SUITABLE FOR UNKNOWN CONCENTRATIONS. PERSONNEL SHOULD NOT REENTER
HAZARD AREA UNTIL NITROGEN DIOXIDE HAS SUFFICIENTLY DISPERSED AND
ADEQUATE OXYGEN RE-ESTABLISHED. IF A LEAK IS IN USER'S EQUIPMENT,
BE CERTAIN TO PURGE PIPING WITH AN INERT GAS PRIOR TO ATTEMPTING
REPAIRS. IF LEAK IS IN CONTAINER OF CONTAINER VALVE, CONTACT THE
APPROPRIATE EMERGENCY TELEPHONE NUMBER LISTED IN SECTION1OR CALL
YOUR CLOSEST NORCO/NORLAB LOCATION.
| 7 HANDLING AND STORAGE | |
HANDLING PRECAUTIONS:
THIS GAS MIXTURE IS NON-CORROSIVE. NITROGEN DIOXIDE CONTENT MAY CAUSE
SOME CORROSION OF COPPER AND COPPER ALLOYS. TEFLON IS THE PREFERRED
GASKET MATERIAL FOR PURE NITROGEN DIOXIDE.
USE ONLY IN WELL-VENTILATED AREAS. VALVE PROTECTION CAPS MUST REMAIN IN
PLACE UNLESS THE CYLINDER IS SECURED WITH VALVE OUTLET PIPED TO USE POINT.
DO NOT DRAG, SLIDE OR ROLL CYLINDERS. USE A SUITABLE HAND TRUCK FOR
CYLINDER MOVEMENT. USE A PRESSURE REGULATOR WHEN CONNECTING CYLINDER
TO LOWER PRESSURE (<3000 PSIG) PIPING OR SYSTEMS. DO NOT HEAT CYLINDER
BY ANY MEANS TO INCREASE THE DISCHARGE RATE OF PRODUCT FROM THE CYLINDER.
USE A CHECK VALVE OR TRAP IN THE DISCHARGE LINE TO PREVENT HAZARDOUS
BACKFLOW INTO THE CYLINDER.
FOR ADDITIONAL RECOMMENDATIONS, CONSULT COMPRESSED GAS ASSOCIATION
PAMPHLETS P-1.
NEVER CARRY A COMPRESSED GAS CYLINDER OR A CONTAINER OF A GAS IN
CRYOGENIC LIQUID FROM IN AN ENCLOSED SPACE SUCH AS A CAR TRUNK,
VAN OR STATION WAGON. A LEAK CAN RESULT IN ASPHYXIATION OR TOXIC
EXPOSURE.
STORAGE REQUIREMENTS:
PROTECT CYLINDERS FROM PHYSICAL DAMAGE. STORE IN COOL, DRY,
WELL-VENTILATED AREA AWAY FROM HEAVY TRAFFIC AREAS AND EMERGENCY
EXITS. DO NOT ALLOW THE TEMPERATURE WHERE CYLINDERS ARE STORED TO
EXCEED 125 DEGREES F (52 DEGREES C). CYLINDERS SHOULD BE STORED
UPRIGHT AND FIRMLY SECURED TO PREVENT FALLING OR BEING KNOCKED
OVER. FULL AND EMPTY CYLINDERS SHOULD BE SEGREGATED. USE A "FIRST
IN-FIRST OUT" INVENTORY SYSTEM TO PREVENT FULL CYLINDERS FROM BEING
STORED FOR EXCESSIVE PERIODS OF TIME.
| 8 EXPOSURE CONTROLS/PERSONAL PROTECTION | |
ENGINEERING CONTROLS:
ALL VENTILATION SHOULD BE DESIGNED IN ACCORDANCE WITH OSHA STANDARD
(29 CFR 1910.94). USE LOCAL EXHAUST AT FILLING ZONES AND WHERE LEAKAGE
AND DUST FORMATION IS PROBABLE. USE MECHANICAL (GENERAL) VENTILATION FOR
STORAGE AREAS. USE APPROPRIATE VENTILATION AS REQUIRED TO KEEP EXPOSURE
LIMITS IN AIR BELOW TLV & PEL LIMITS. MAINTAIN ATMOSPHERIC OXYGEN CONTENT
AT OR ABOVE 19.5%
PERSONAL PROTECTIVE EQUIPMENT:
NITROGEN DIOXIDE CAS#: (10102-44-0) [0.0002-0.01%]
NITROGEN CAS#: (7727-37-9) [99.99-99.9998%]
PERSONAL PROTECTIVE EQUIPMENT:
RESPIRATORY PROTECTION:
WHERE RISK ASSESSMENT SHOWS AIR-PURIFYING RESPIRATORS ARE APPROPRIATE USE
A FULL-FACE RESPIRATOR WITH MULTI-PURPOSE COMBINATION (US) OR TYPE AXBEK
(EN 14387) RESPIRATOR CARTRIDGES AS A BACKUP TO ENGINEERING CONTROLS. IF
THE RESPIRATOR IS THE SOLE MEANS OF PROTECTION, USE A FULL-FACE SUPPLIED
AIR RESPIRATOR. USE RESPIRATORS AND COMPONENTS TESTED AND APPROVED UNDER
APPROPRIATE GOVERNMENT STANDARDS SUCH AS NIOSH (US) OR CEN (EU).
HAND PROTECTION:
HANDLE WITH GLOVES. GLOVES MUST BE INSPECTED PRIOR TO USE. USE PROPER
GLOVE REMOVAL TECHNIQUE (WITHOUT TOUCHING GLOVES OUTER SURFACE) TO AVOID
SKIN CONTACT WITH THIS PRODUCT. DISPOSE OF CONTAMINATED GLOVES AFTER USE
IN ACCORDANCE WITH APPLICABLE LAWS AND GOOD LABORATORY PRACTICES. WASH AND
DRY HANDS. FULL CONTACT MATERIAL: BUTYL-RUBBER MINIMUM LAYER THICKNESS:
0.3 MM BREAK THROUGH TIME: 480 MIN MATERIAL TESTED: BUTOJECT
(KCL 897 / ALDRICH Z677647, SIZE M)
SPLASH PROTECTION:
MATERIAL: CHLOROPRENE MINIMUM LAYER THICKNESS: 0.6 MM BREAK THROUGH TIME:
30 MIN MATERIAL TESTED: CAMAPREN (KCL 722 / ALDRICH Z677493, SIZE M) DATA
SOURCE: KCL GMBH, D-36124 EICHENZELL, PHONE +49 (0)6659 87300, E-MAIL
SALES@KCL.DE, TEST METHOD: EN374 IF USED IN SOLUTION, OR MIXED WITH OTHER
SUBSTANCES, AND UNDER CONDITIONS WHICH DIFFER FROM EN 374, CONTACT THE
SUPPLIER OF THE CE APPROVED GLOVES. THIS RECOMMENDATION IS ADVISORY ONLY
AND MUST BE EVALUATED BY AN INDUSTRIAL HYGIENIST FAMILIAR WITH THE
SPECIFIC SITUATION OF ANTICIPATED USE BY OUR CUSTOMERS. IT SHOULD NOT BE
CONSTRUED AS OFFERING AN APPROVAL FOR ANY SPECIFIC USE SCENARIO.
EYE PROTECTION:
TIGHTLY FITTING SAFETY GOGGLES. FACESHIELD (8-INCH MINIMUM). USE
EQUIPMENT FOR EYE PROTECTION TESTED AND APPROVED UNDER APPROPRIATE
GOVERNMENT STANDARDS SUCH AS NIOSH (US) OR EN 166(EU).
SKIN AND BODY PROTECTION:
COMPLETE SUIT PROTECTING AGAINST CHEMICALS, THE TYPE OF PROTECTIVE
EQUIPMENT MUST BE SELECTED ACCORDING TO THE CONCENTRATION AND AMOUNT
OF THE DANGEROUS SUBSTANCE AT THE SPECIFIC WORKPLACE.
HYGIENE MEASURES:
AVOID CONTACT WITH SKIN, EYES AND CLOTHING. WASH HANDS BEFORE BREAKS AND
IMMEDIATELY AFTER HANDLING THE PRODUCT.
NITROGEN DIOXIDE CAS#: (10102-44-0) [0.0002-0.01%]
COMPONENTS WITH WORKPLACE CONTROL PARAMETERS:
TWA 3 PPM USA. ACGIH THRESHOLD LIMIT VALUES (TLV)
UPPER RESPIRATORY TRACT & LOWER RESPIRATORY TRACT IRRITATION NOT
CLASSIFIABLE AS A HUMAN CARCINOGEN
STEL 5 PPM USA. ACGIH THRESHOLD LIMIT VALUES (TLV)
UPPER RESPIRATORY TRACT & LOWER RESPIRATORY TRACT IRRITATION NOT
CLASSIFIABLE AS A HUMAN CARCINOGEN
CEIL 5 PPM USA. OCCUPATIONAL EXPOSURE LIMITS
9 MG/M3 (OSHA) - TABLE Z- 1 - LIMITS FOR AIR
CONTAMINANTS
THE VALUE IN MG/M3 IS APPROXIMATE. CEILING LIMIT IS TO BE DETERMINED FROM
BREATHING-ZONE AIR SAMPLES.
STEL 1 PPM USA. OSHA - TABLE Z-1 LIMITS FOR AIR
1.8 MG/M3 CONTAMINANTS - 1910.1000
STEL 1 PPM USA. NIOSH RECOMMENDED EXPOSURE LIMITS
1.8 MG/M3
| 9 PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: COLORLESS GAS
PHYSICAL STATE: GAS
ODOR: ACIDIC ODOR
ODOR THRESHOLD: 0.1 TO 0.4 PPM FOR NITROGEN DIOXIDE
MOLECULAR FORMULA: NO2 IN NITROGEN
PARTICLE SIZE: NOT APPLICABLE
SOLUBILITY: VERY SLIGHTLY SOLUBLE
SPECIFIC GRAVITY OR DENSITY: NOT NETERMINED
SOFTENING POINT: NOT APPLICABLE
VISCOSITY: NOT APPLICABLE
PERCENT VOLATILE: 100%
BOILING POINT: NOT DETERMINED
FREEZING OR MELTING POINT: NOT DETERMINED
FLAMMABILITY: NOT FLAMMABLE
FLASH POINT: NOT DETERMINED
| 10 STABILITY AND REACTIVITY | |
CHEMICAL STABILITY: PRODUCT IS STABLE UNDER NORMAL CONDITIONS.
CONDITIONS TO AVOIDENTIFICATION:
NITROGEN DIOXIDE REACTS WITH WATER TO FORM NITRIC ACID.
MATERIALS TO AVOIDENTIFICATION:
NITROGEN DIOXIDE IS NOT COMPATIBLE WITH STRONG BASES, STRONG OXIDIZERS,
ALKALI METALS, ALKALI EARTH METALS AND POWDERED METALS. AVOID COMBUSTIBLE
MATERIALS, WATER, CHLORINATED HYDROCARBONS, CARBON DISULFIDE, AND AMMONIA.
HAZARDOUS DECOMPOSITION: TOXIC FUMES OF NITROXIDES.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR.
| 11 TOXICOLOGICAL INFORMATION | |
NITROGEN DIOXIDE CAS#: (10102-44-0) [0.0002-0.01%]
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
ORAL LD50: NO DATA AVAILABLE
INHALATION LC50:
DERMAL LD50:
OTHER INFORMATION ON ACUTE TOXICITY:
SKIN CORROSION/IRRITATION: NO DATA AVAILABLE
SERIOUS EYE DAMAGE/EYE IRRITATION: NO DATA AVAILABLE
RESPIRATORY OR SKIN SENSITIZATION: NO DATA AVAILABLE
GERM CELL MUTAGENICITY: NO DATA AVAILABLE
CARCINOGENICITY:
IARC:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS PROBABLE, POSSIBLE OR CONFIRMED HUMAN CARCINOGEN
BY IARC.
NTP:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A KNOWN OR ANTICIPATED CARCINOGEN BY NTP.
OSHA:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A CARCINOGEN OR POTENTIAL CARCINOGEN BY OSHA.
REPRODUCTIVE TOXICITY: NO DATA AVAILABLE
TERATOGENICITY: NO DATA AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE
(GLOBALLY HARMONIZED SYSTEM):
NO DATA AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE
(GLOBALLY HARMONIZED SYSTEM):
NO DATA AVAILABLE
ASPIRATION HAZARD: NO DATA AVAILABLE
POTENTIAL HEALTH EFFECTS:
INHALATION MAY BE FATAL IF INHALED. MATERIAL IS EXTREMELY DESTRUCTIVE TO
THE TISSUE OF THE MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT. INGESTION
MAY BE HARMFUL IF SWALLOWED. SKIN MAY BE HARMFUL IF ABSORBED THROUGH SKIN.
CAUSES SKIN BURNS. EYES CAUSES EYE BURNS.
SIGNS AND SYMPTOMS OF EXPOSURE:
INHALATION OF VAPORS MAY CAUSE:, RHINITIS, PHARYNGITIS, CYANOSIS,
RESPIRATORY FAILURE, COMA., UNCONSCIOUSNESS, DEATH, WEIGHT LOSS,
DROP IN BLOOD PRESSURE, LOSS OF SENSE OF SMELL, AMNESIA.
SYNERGISTIC EFFECTS: NO DATA AVAILABLE
ADDITIONAL INFORMATION:
RTECS: QW9800000
NITROGEN CAS#: (7727-37-9) [99.99-99.9998%]
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
ORAL LD50: NO DATA AVAILABLE
INHALATION LC50:
DERMAL LD50:
OTHER INFORMATION ON ACUTE TOXICITY:
SKIN CORROSION/IRRITATION: NO DATA AVAILABLE
SERIOUS EYE DAMAGE/EYE IRRITATION: NO DATA AVAILABLE
RESPIRATORY OR SKIN SENSITIZATION: NO DATA AVAILABLE
GERM CELL MUTAGENICITY: NO DATA AVAILABLE
CARCINOGENICITY:
IARC:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS PROBABLE, POSSIBLE OR CONFIRMED HUMAN CARCINOGEN
BY IARC.
ACGIH:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A CARCINOGEN OR POTENTIAL CARCINOGEN BY ACGIH.
NTP:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A KNOWN OR ANTICIPATED CARCINOGEN BY NTP.
OSHA:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A CARCINOGEN OR POTENTIAL CARCINOGEN BY OSHA.
REPRODUCTIVE TOXICITY: NO DATA AVAILABLE
TERATOGENICITY: NO DATA AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE
(GLOBALLY HARMONIZED SYSTEM):
NO DATA AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE
(GLOBALLY HARMONIZED SYSTEM):
NO DATA AVAILABLE
ASPIRATION HAZARD: NO DATA AVAILABLE
POTENTIAL HEALTH EFFECTS:
INHALATION MAY BE HARMFUL IF INHALED. MAY CAUSE RESPIRATORY TRACT
IRRITATION. INGESTION MAY BE HARMFUL IF SWALLOWED. SKIN MAY BE
HARMFUL IF ABSORBED THROUGH SKIN. MAY CAUSE SKIN IRRITATION. EYES
MAY CAUSE EYE IRRITATION.
SIGNS AND SYMPTOMS OF EXPOSURE:
MAY BE HARMFUL., NAUSEA, HEADACHE, VOMITING
SYNERGISTIC EFFECTS: NO DATA AVAILABLE
ADDITIONAL INFORMATION:
RTECS: QW9700000
| 12 ECOLOGICAL INFORMATION | |
NITROGEN DIOXIDE CAS#: (10102-44-0) [0.0002-0.01%]
INFORMATION ON ECOLOGICAL EFFECTS:
TOXICITY:
TOXICITY TO FISH LC50 - TINCA TINCA - 19.6 MG/L - 96 H.
PERSISTENCE AND DEGRADABILITY: NO DATA AVAILABLE
BIOACCUMULATIVE POTENTIAL: NO DATA AVAILABLE
MOBILITY IN SOIL: NO DATA AVAILABLE
PBT AND VPVB ASSESSMENT: NO DATA AVAILABLE
OTHER ADVERSE EFFECTS:
AN ENVIRONMENTAL HAZARD CANNOT BE EXCLUDED IN THE EVENT OF UNPROFESSIONAL
HANDLING OR DISPOSAL.
HARMFUL TO AQUATIC LIFE.
NITROGEN CAS#: (7727-37-9) [99.99-99.9998%]
INFORMATION ON ECOLOGICAL EFFECTS:
TOXICITY: NO DATA AVAILABLE
PERSISTENCE AND DEGRADABILITY: NO DATA AVAILABLE
BIOACCUMULATIVE POTENTIAL: NO DATA AVAILABLE
MOBILITY IN SOIL: NO DATA AVAILABLE
PBT AND VPVB ASSESSMENT: NO DATA AVAILABLE
OTHER ADVERSE EFFECTS: NO DATA AVAILABLE
| 13 DISPOSAL CONSIDERATIONS | |
DISPOSE OF IN ACCORDANCE WITH LOCAL REGULATIONS. DO NOT ATTEMPT TO DISPOSE
OF WASTE OR UNUSED QUANTITIES IN RETURNABLE CYLINDERS. RETURN IN THE
SHIPPING CONTAINER, PROPERLY LABELED, WITH ANY VALVE OUTLET PLUGS OR
CAPS SECURE AND VALVE PROTECTION CAP IN PLACE TO NORLAB FOR PROPER
DISPOSAL. NON-REFILLABLE CONTAINERS SHOULD BE VENTED IN A WELL-VENTILATED
AREA THEN DISPOSED OF IN COMPLIANCE WITH LOCAL REGULATIONS, OR RETURNED
TO NORLAB.
| 14 TRANSPORT INFORMATION | |
UN1956, COMPRESSED GAS, N.O.S., 2.2:
PROPER SHIPPING NAME US:
UN 1956, COMPRESSED GAS N.O.S., (NITROGEN DIOXIDE, NITROGEN), 2.2
PROPER SHIPPING NAME CANADA:
UN1956, COMPRESSED GAS, N.O.S., (NITROGEN DIOXIDE, NITROGEN), 2.2
CLASS 2.2, NON-FLAMMABLE AND NON-TOXIC GASES
| 15 REGULATORY INFORMATION | |
COMPONENT (CAS#) [%] CODES
RQ(10LBS), (10102-44-0) [0.0002-0.01%] ACUTERCRA, CERCLA,
NITROGEN DIOXIDE CSWHS, EHS302,
MASS, NJEHS, NJHS,
OSHAPSM, OSHAWAC,
PA, TSCA, TXAIR,
TXHWL
NITROGEN (7727-37-9) [99.99-99.9998%] MASS, PA, TSCA
REGULATORY CODE DESCRIPTIONS:
RQ = REPORTABLE QUANTITY
ACUTERCRA = RCRA ACUTE HAZARDOUS WASTES (P-LIST)
CERCLA = SUPERFUND CLEAN UP SUBSTANCE
CSWHS = CLEAN WATER ACT HAZARDOUS SUBSTANCES
EHS 302 = EXTREMELY HAZARDOUS SUBSTANCE
MASS = MA MASSACHUSETTS HAZARDOUS SUBSTANCES LIST
NJEHS = NJ EXTRAORDINARILY HAZARDOUS SUBSTANCES
NJHS = NJ RIGHT-TO-KNOW HAZARDOUS SUBSTANCES
OSHAPSM = OSHA CHEMICALS REQUIRING PROCESS SAFETY MANAGEMENT
OSHAWAC = OSHA WORKPLACE AIR CONTAMINANTS
PA = PA RIGHT-TO-KNOW LIST OF HAZARDOUS SUBSTANCES
TSCA = TOXIC SUBSTANCES CONTROL ACT
TXAIR = TX AIR CONTAMINANTS WITH HEALTH EFFECTS SCREENING LEVEL
TXHWL = TX HAZARDOUS WASTE LIST
| 16 OTHER INFORMATION | |
NFPA:
HEALTH 1
FIRE 0
REACTIVITY 0
SPECIFIC HAZARD N/A
HMIS III:
HEALTH 1
FIRE 0
PHYSICAL HAZARD 3
HMIS PPE: B - SAFETY GLASSES, GLOVES
NFPA:
HEALTH 1
FIRE HAZARD 0
REACTIVITY 0
SPECIFIC HAZARD
HMIS:
HEALTH 1
FLAMMABILITY 0
PHYSICAL HAZARD 3
PERSONAL PROTECTION B
PPE:
CHEMICAL GOGGLES
GLOVES
DISCLAIMER:
ALTHOUGH REASONABLE CARE HAS BEEN TAKEN IN THE PREPARATION OF THIS
DOCUMENT, WE EXTEND NO WARRANTIES AND MAKE NO REPRESENTATIONS AS TO
THE ACCURACY OR COMPLETENESS OF THE INFORMATION CONTAINED HEREIN,
AND ASSUME NO RESPONSIBILITY REGARDING THE SUITABILITY OF THIS
INFORMATION FOR THE USER'S INTENDED PURPOSES OR FOR THE CONSEQUENCES
OF ITS USE. EACH INDIVIDUAL SHOULD MAKE A DETERMINATION AS TO THE
SUITABILITY OF THE INFORMATION FOR THEIR PARTICULAR PURPOSE(S).
REVISION DATE: 6/1/2018