| Common Name: | HYDROGEN PEROXIDE, 3% W/W |
| Manufacturer: | LABCHEM |
| SDS Revision Date: | 10/31/2017 |
| SDS Format: | GHS-US |
| Item Number(s): | 8FZH0 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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LC
LABCHEM
PERFORMANCE THROUGH CHEMISTRY
HYDROGEN PEROXIDE, 3% W/W
SAFETY DATA SHEET
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26, 2012 /
RULES AND REGULATIONS
DATE OF ISSUE: 02/17/2014
REVISION DATE: 10/31/2017
SUPERSEDES: 01/06/2016
VERSION: 1.3
| SECTION 1: IDENTIFICATION |  |
1.1. IDENTIFICATION:
PRODUCT FORM: MIXTURES
PRODUCT NAME: HYDROGEN PEROXIDE, 3% W/W
PRODUCT CODE: LC15450
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
USE OF THE SUBSTANCE/MIXTURE: FOR LABORATORY AND MANUFACTURING USE ONLY.
RECOMMENDED USE: LABORATORY CHEMICALS
RESTRICTIONS ON USE: NOT FOR FOOD, DRUG OR HOUSEHOLD USE
1.3. SUPPLIER:
LABCHEM INC
JACKSON'S POINTE COMMERCE PARK BUILDING 1000
1010 JACKSON'S POINTE COURT
ZELIENOPLE, PA 16063
USA
T: 412-826-5230
F: 724-473-0647
INFO@LABCHEM.COM
WWW.LABCHEM.COM
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER:
CHEMTREC: 1-800-424-9300 OR 011-703-527-3887
| SECTION 2: HAZARD(S) IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS-US CLASSIFICATION:
SKIN CORROSION/IRRITATION: CATEGORY 2
H315: CAUSES SKIN IRRITATION
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 1
H318: CAUSES SERIOUS EYE DAMAGE
FULL TEXT OF H STATEMENTS: SEE SECTION 16
2.2. GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENTS:
GHS-US LABELING
HAZARD PICTOGRAMS (GHS-US):
GHS05: CORROSION
SIGNAL WORD (GHS-US): DANGER
HAZARD STATEMENTS (GHS-US):
H315: CAUSES SKIN IRRITATION
H318: CAUSES SERIOUS EYE DAMAGE
PRECAUTIONARY STATEMENTS (GHS-US):
P264: WASH EXPOSED SKIN THOROUGHLY AFTER HANDLING
P280: WEAR PROTECTIVE GLOVES, EYE PROTECTION
P302+P352:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING
P310: IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN
P321: SPECIFIC TREATMENT (SEE ... ON THIS LABEL)
P332+P313:
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION
P362+P364: TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE
2.3. OTHER HAZARDS WHICH DO NOT RESULT IN CLASSIFICATION:
OTHER HAZARDS NOT CONTRIBUTING TO THE CLASSIFICATION:
NONE UNDER NORMAL CONDITIONS.
2.4. UNKNOWN ACUTE TOXICITY (GHS US): NOT APPLICABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCES: NOT APPLICABLE
3.2. MIXTURES:
NAME PRODUCT IDENTIFIER % GHS-US CLASSIFICATION
WATER (CAS-NO.) 7732-18-5 97 NOT CLASSIFIED
HYDROGEN PEROXIDE, 30% W/W (CAS-NO.) 7722-84-1 3 OX. LIQ. 1, H271
ACUTE TOX. 4 (ORAL),
H302
ACUTE TOX. 4
(INHALATION), H332
SKIN CORR. 1A, H314
FULL TEXT OF HAZARD CLASSES AND H-STATEMENTS: SEE SECTION 16
| SECTION 4: FIRST-AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES GENERAL:
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF YOU FEEL UNWELL,
SEEK MEDICAL ADVICE (SHOW THE LABEL WHERE POSSIBLE).
FIRST-AID MEASURES AFTER INHALATION:
ALLOW VICTIM TO BREATHE FRESH AIR. ALLOW THE VICTIM TO REST.
FIRST-AID MEASURES AFTER SKIN CONTACT:
WASH WITH PLENTY OF SOAP AND WATER. WASH CONTAMINATED CLOTHING BEFORE
REUSE.
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
FIRST-AID MEASURES AFTER EYE CONTACT:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING. IMMEDIATELY CALL A POISON CENTER
OR DOCTOR/PHYSICIAN.
FIRST-AID MEASURES AFTER INGESTION:
RINSE MOUTH. DO NOT INDUCE VOMITING. OBTAIN EMERGENCY MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS (ACUTE AND DELAYED):
SYMPTOMS/EFFECTS AFTER SKIN CONTACT: CAUSES SKIN IRRITATION.
SYMPTOMS/EFFECTS AFTER EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
4.3. IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT, IF NECESSARY:
NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE (AND UNSUITABLE) EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
FOAM. DRY POWDER. CARBON DIOXIDE. WATER SPRAY. SAND.
UNSUITABLE EXTINGUISHING MEDIA: DO NOT USE A HEAVY WATER STREAM.
5.2. SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
NO ADDITIONAL INFORMATION AVAILABLE
5.3. SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE-FIGHTERS:
FIREFIGHTING INSTRUCTIONS:
USE WATER SPRAY OR FOG FOR COOLING EXPOSED CONTAINERS. EXERCISE CAUTION
WHEN FIGHTING ANY CHEMICAL FIRE. PREVENT FIRE-FIGHTING WATER FROM ENTERING
ENVIRONMENT.
PROTECTION DURING FIREFIGHTING:
DO NOT ENTER FIRE AREA WITHOUT PROPER PROTECTIVE EQUIPMENT, INCLUDING
RESPIRATORY PROTECTION.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
6.1.1. FOR NON-EMERGENCY PERSONNEL:
PROTECTIVE EQUIPMENT: SAFETY GLASSES. GLOVES.
EMERGENCY PROCEDURES: EVACUATE UNNECESSARY PERSONNEL.
6.1.2. FOR EMERGENCY RESPONDERS:
PROTECTIVE EQUIPMENT: EQUIP CLEANUP CREW WITH PROPER PROTECTION.
EMERGENCY PROCEDURES: VENTILATE AREA.
6.2. ENVIRONMENTAL PRECAUTIONS:
PREVENT ENTRY TO SEWERS AND PUBLIC WATERS. NOTIFY AUTHORITIES IF LIQUID
ENTERS SEWERS OR PUBLIC WATERS.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CLEANING UP:
SOAK UP SPILLS WITH INERT SOLIDS, SUCH AS CLAY OR DIATOMACEOUS EARTH AS
SOON AS POSSIBLE. COLLECT SPILLAGE. STORE AWAY FROM OTHER MATERIALS.
6.4. REFERENCE TO OTHER SECTIONS:
SEE HEADING 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
PRECAUTIONS FOR SAFE HANDLING:
WASH HANDS AND OTHER EXPOSED AREAS WITH MILD SOAP AND WATER BEFORE EATING,
DRINKING OR SMOKING AND WHEN LEAVING WORK. PROVIDE GOOD VENTILATION IN
PROCESS AREA TO PREVENT FORMATION OF VAPOR.
HYGIENE MEASURES: WASH EXPOSED SKIN THOROUGHLY AFTER HANDLING.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE CONDITIONS:
KEEP ONLY IN THE ORIGINAL CONTAINER IN A COOL, WELL VENTILATED PLACE AWAY
FROM: INCOMPATIBLE MATERIALS, COMBUSTIBLE MATERIALS. KEEP CONTAINER CLOSED
WHEN NOT IN USE.
INCOMPATIBLE PRODUCTS:
STRONG BASES. STRONG REDUCING AGENTS. METALS. COMBUSTIBLE MATERIALS.
INCOMPATIBLE MATERIALS: SOURCES OF IGNITION. DIRECT SUNLIGHT.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
HYDROGEN PEROXIDE, 30% W/W (7722-84-1):
ACGIH:
ACGIH TWA (MG/M3): 1.4 MG/M3
ACGIH:
ACGIH TWA (PPM): 1 PPM
OSHA:
OSHA PEL (TWA) (MG/M3): 1.4 MG/M3
OSHA:
OSHA PEL (TWA) (PPM): 1 PPM
IDLH:
US IDLH (PPM): 75 PPM
NIOSH:
NIOSH REL (TWA) (MG/M3): 1.4 MG/M3
NIOSH:
NIOSH REL (TWA) (PPM): 1 PPM
WATER (7732-18-5): NOT APPLICABLE
8.2. APPROPRIATE ENGINEERING CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
EMERGENCY EYE WASH FOUNTAINS SHOULD BE AVAILABLE IN THE IMMEDIATE VICINITY
OF ANY POTENTIAL EXPOSURE.
8.3. INDIVIDUAL PROTECTION MEASURES/PERSONAL PROTECTIVE EQUIPMENT:
PERSONAL PROTECTIVE EQUIPMENT: FACE SHIELD. GLOVES. SAFETY GLASSES.
HAND PROTECTION: WEAR PROTECTIVE GLOVES
EYE PROTECTION: CHEMICAL GOGGLES OR SAFETY GLASSES
SKIN AND BODY PROTECTION: WEAR SUITABLE PROTECTIVE CLOTHING
RESPIRATORY PROTECTION:
RESPIRATORY PROTECTION NOT REQUIRED IN NORMAL CONDITIONS
OTHER INFORMATION: DO NOT EAT, DRINK OR SMOKE DURING USE.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
COLOR: COLORLESS
ODOR: NONE.
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
MELTING POINT: NO DATA AVAILABLE
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: NO DATA AVAILABLE
FLASH POINT: NO DATA AVAILABLE
RELATIVE EVAPORATION RATE (BUTYL ACETATE=1): NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NON FLAMMABLE.
VAPOR PRESSURE: NO DATA AVAILABLE
RELATIVE VAPOR DENSITY AT 20 DEG. C: NO DATA AVAILABLE
RELATIVE DENSITY: NO DATA AVAILABLE
SPECIFIC GRAVITY / DENSITY: 1
SOLUBILITY: SOLUBLE IN WATER.
LOG POW: NO DATA AVAILABLE
AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
EXPLOSION LIMITS: NO DATA AVAILABLE
EXPLOSIVE PROPERTIES: NO DATA AVAILABLE
OXIDIZING PROPERTIES: NO DATA AVAILABLE
9.2. OTHER INFORMATION: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY: NO ADDITIONAL INFORMATION AVAILABLE
10.2. CHEMICAL STABILITY: UNSTABLE ON EXPOSURE TO LIGHT.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS: NOT ESTABLISHED.
10.4. CONDITIONS TO AVOID:
DIRECT SUNLIGHT. EXTREMELY HIGH OR LOW TEMPERATURES.
10.5. INCOMPATIBLE MATERIALS:
STRONG REDUCING AGENTS. STRONG BASES. METALS. COMBUSTIBLE MATERIALS.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS: OXYGEN.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
LIKELY ROUTES OF EXPOSURE: INHALATION; SKIN AND EYE CONTACT
ACUTE TOXICITY: NOT CLASSIFIED
HYDROGEN PEROXIDE, 30% W/W (7722-84-1):
ATE US (ORAL): 500 MG/KG BODY WEIGHT
ATE US (GASES): 4500 PPMV/4H
HYDROGEN PEROXIDE, 30% W/W (7722-84-1):
ATE US (VAPORS): 11 MG/L/4H
ATE US (DUST, MIST): 1.5 MG/L/4H
WATER (7732-18-5):
LD50 ORAL RAT: >/=90000 MG/KG
ATE US (ORAL): 90000 MG/KG BODY WEIGHT
SKIN CORROSION/IRRITATION: CAUSES SKIN IRRITATION.
SERIOUS EYE DAMAGE/IRRITATION: CAUSES SERIOUS EYE DAMAGE.
RESPIRATORY OR SKIN SENSITIZATION: NOT CLASSIFIED
GERM CELL MUTAGENICITY: NOT CLASSIFIED
CARCINOGENICITY: NOT CLASSIFIED
HYDROGEN PEROXIDE, 30% W/W (7722-84-1):
IARC GROUP: 3 - NOT CLASSIFIABLE
REPRODUCTIVE TOXICITY: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NOT CLASSIFIED
ASPIRATION HAZARD: NOT CLASSIFIED
POTENTIAL ADVERSE HUMAN HEALTH EFFECTS AND SYMPTOMS:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
SYMPTOMS/EFFECTS AFTER SKIN CONTACT: CAUSES SKIN IRRITATION.
SYMPTOMS/EFFECTS AFTER EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY: NO ADDITIONAL INFORMATION AVAILABLE
12.2. PERSISTENCE AND DEGRADABILITY:
HYDROGEN PEROXIDE, 3% W/W:
PERSISTENCE AND DEGRADABILITY: NOT ESTABLISHED.
HYDROGEN PEROXIDE, 30% W/W (7722-84-1):
PERSISTENCE AND DEGRADABILITY: NOT ESTABLISHED.
WATER (7732-18-5):
PERSISTENCE AND DEGRADABILITY: NOT ESTABLISHED.
12.3. BIOACCUMULATIVE POTENTIAL:
HYDROGEN PEROXIDE, 3% W/W:
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
HYDROGEN PEROXIDE, 30% W/W (7722-84-1):
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
WATER (7732-18-5):
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
12.4. MOBILITY IN SOIL: NO ADDITIONAL INFORMATION AVAILABLE
12.5. OTHER ADVERSE EFFECTS:
EFFECT ON THE GLOBAL WARMING: NO KNOWN EFFECTS FROM THIS PRODUCT.
GWPMIX COMMENT: NO KNOWN EFFECTS FROM THIS PRODUCT.
OTHER INFORMATION: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
WASTE DISPOSAL RECOMMENDATIONS:
DISPOSE IN A SAFE MANNER IN ACCORDANCE WITH LOCAL/NATIONAL REGULATIONS.
ECOLOGY - WASTE MATERIALS: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 14: TRANSPORT INFORMATION | |
DEPARTMENT OF TRANSPORTATION (DOT):
IN ACCORDANCE WITH DOT
NOT REGULATED
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
HYDROGEN PEROXIDE, 3% W/W:
SARA SECTION 311/312 HAZARD CLASSES: IMMEDIATE (ACUTE) HEALTH HAZARD
ALL COMPONENTS OF THIS PRODUCT ARE LISTED, OR EXCLUDED FROM LISTING, ON THE
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY TOXIC SUBSTANCES CONTROL ACT
(TSCA) INVENTORY
HYDROGEN PEROXIDE, 30% W/W (7722-84-1):
SARA SECTION 311/312 HAZARD CLASSES:
REACTIVE HAZARD
IMMEDIATE (ACUTE) HEALTH HAZARD
15.2. INTERNATIONAL REGULATIONS:
CANADA: NO ADDITIONAL INFORMATION AVAILABLE
EU-REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
NATIONAL REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
15.3. US STATE REGULATIONS:
CALIFORNIA PROPOSITION 65:
THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER, DEVELOPMENTAL AND/OR REPRODUCTIVE HARM
| SECTION 16: OTHER INFORMATION | |
REVISION DATE: 10/31/2017
OTHER INFORMATION: NONE.
FULL TEXT OF H-PHRASES: SEE SECTION 16
H271: MAY CAUSE FIRE OR EXPLOSION; STRONG OXIDIZER
H302: HARMFUL IF SWALLOWED
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE
H315: CAUSES SKIN IRRITATION
H318: CAUSES SERIOUS EYE DAMAGE
H332: HARMFUL IF INHALED
NFPA HEALTH HAZARD 2 - MATERIALS THAT, UNDER EMERGENCY CONDITIONS, CAN
CAUSE TEMPORARY INCAPACITATION OR RESIDUAL INJURY.
NFPA FIRE HAZARD 0 - MATERIALS THAT WILL NOT BURN UNDER TYPICAL DIRE
CONDITIONS, INCLUDING INTRINSICALLY NONCOMBUSTIBLE
MATERIALS SUCH AS CONCRETE, STONE, AND SAND.
NFPA REACTIVITY 1 - MATERIALS THAT IN THEMSELVES ARE NORMALLY STABLE BUT
CAN BECOME UNSTABLE AT ELEVATED TEMPERATURES AND
PRESSURES.
NFPA SPECIFIC OX - MATERIALS THAT POSSES OXIDIZING PROPERTIES.
HAZARD
HAZARD RATING:
HEALTH 2 MODERATE HAZARD - TEMPORARY OR MINOR INJURY MAY OCCUR
FLAMMABILITY 0 MINIMAL HAZARD - MATERIALS THAT WILL NOT BURN
PHYSICAL 1 SLIGHT HAZARD - MATERIALS THAT ARE NORMALLY STABLE
BUT CAN BECOME UNSTABLE (SELF-REACT) AT HIGH
TEMPERATURES AND PRESSURES. MATERIALS MAY REACT
NON-VIOLENTLY WITH WATER OR UNDERGO HAZARDOUS
POLYMERIZATION IN THE ABSENCE OF INHIBITORS.
PERSONAL PROTECTION B
B - SAFETY GLASSES, GLOVES
SDS US LABCHEM
INFORMATION IN THIS SDS IS FROM AVAILABLE PUBLISHED SOURCES AND IS BELIEVED
TO BE ACCURATE. NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AND LABCHEM INC
ASSUMES NO LIABILITY RESULTING FROM THE USE OF THIS SDS. THE USER MUST
DETERMINE SUITABILITY OF THIS INFORMATION FOR HIS APPLICATION.
EN (ENGLISH US)