| Common Name: | GLYCERIN |
| Manufacturer: | LABCHEM |
| SDS Revision Date: | 12/17/2013 |
| SDS Format: | GHS-US |
| Item Number(s): | 8G476, 8G477 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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LC
LABCHEM
PERFORMANCE THROUGH CHEMISTRY
GLYCERIN
SAFETY DATA SHEET
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26, 2012 /
RULES AND REGULATIONS
DATE OF ISSUE: 12/17/2013
VERSION: 1.0
| SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE |  |
AND OF THE COMPANY/UNDERTAKING
1.1. PRODUCT IDENTIFIER:
PRODUCT FORM: SUBSTANCE
SUBSTANCE NAME: GLYCERIN
CHEMICAL NAME: 1,2,3-TRIHYDROXYPROPANE
CAS NO: 56-81-5
PRODUCT CODE: LC14850
FORMULA: HOCH2CH(OH)CH2OH
SYNONYMS: GLYCEROL
1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
USE OF THE SUBSTANCE/MIXTURE: FOR LABORATORY AND MANUFACTURING USE ONLY.
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
LABCHEM INC
JACKSON'S POINTE COMMERCE PARK BUILDING 1000, 1010 JACKSON'S POINTE COURT
ZELIENOPLE, PA 16063
USA
T: 412-826-5230
F: 724-473-0647
INFO@LABCHEM.COM - WWW.LABCHEM.COM
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER:
CHEMTREC: 1-800-424-9300 OR 011-703-527-3887
| SECTION 2: HAZARDS IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS-US CLASSIFICATION: NOT CLASSIFIED
2.2. LABEL ELEMENTS:
GHS-US LABELLING: NO LABELLING APPLICABLE
2.3. OTHER HAZARDS:
OTHER HAZARDS NOT CONTRIBUTING TO THE CLASSIFICATION: NONE.
2.4. UNKNOWN ACUTE TOXICITY (GHS-US): NO DATA AVAILABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCE:
SUBSTANCE TYPE: MONO-CONSTITUENT
NAME PRODUCT IDENTIFIER % GHS-US CLASSIFICATION
GLYCERIN
(MAIN CONSTITUENT) (CAS NO) 56-81-5 100 NOT CLASSIFIED
FULL TEXT OF H-PHRASES: SEE SECTION 16
3.2. MIXTURE: NOT APPLICABLE
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES GENERAL:
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE (SHOW THE LABEL WHERE POSSIBLE).
FIRST-AID MEASURES AFTER INHALATION:
ASSURE FRESH AIR BREATHING. ALLOW THE VICTIM TO REST.
FIRST-AID MEASURES AFTER SKIN CONTACT:
REMOVE AFFECTED CLOTHING AND WASH ALL EXPOSED SKIN AREA WITH MILD SOAP AND
WATER, FOLLOWED BY WARM WATER RINSE.
FIRST-AID MEASURES AFTER EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER. OBTAIN MEDICAL ATTENTION IF PAIN,
BLINKING OR REDNESS PERSIST.
FIRST-AID MEASURES AFTER INGESTION:
RINSE MOUTH. DO NOT INDUCE VOMITING. OBTAIN EMERGENCY MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS/INJURIES:
NOT EXPECTED TO PRESENT A SIGNIFICANT HAZARD UNDER ANTICIPATED CONDITIONS
OF NORMAL USE.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 5: FIREFIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
FOAM. DRY POWDER. CARBON DIOXIDE. WATER SPRAY. SAND.
UNSUITABLE EXTINGUISHING MEDIA: DO NOT USE A HEAVY WATER STREAM.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NO ADDITIONAL INFORMATION AVAILABLE
5.3. ADVICE FOR FIREFIGHTERS:
FIREFIGHTING INSTRUCTIONS:
USE WATER SPRAY OR FOG FOR COOLING EXPOSED CONTAINERS. EXERCISE CAUTION
WHEN FIGHTING ANY CHEMICAL FIRE. AVOID (REJECT) FIRE-FIGHTING WATER TO
ENTER ENVIRONMENT.
PROTECTION DURING FIREFIGHTING:
DO NOT ENTER FIRE AREA WITHOUT PROPER PROTECTIVE EQUIPMENT, INCLUDING
RESPIRATORY PROTECTION.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
6.1.1. FOR NON-EMERGENCY PERSONNEL:
PROTECTIVE EQUIPMENT: SAFETY GLASSES. GLOVES.
EMERGENCY PROCEDURES: EVACUATE UNNECESSARY PERSONNEL.
6.1.2. FOR EMERGENCY RESPONDERS:
PROTECTIVE EQUIPMENT: EQUIP CLEANUP CREW WITH PROPER PROTECTION.
EMERGENCY PROCEDURES: VENTILATE AREA.
6.2. ENVIRONMENTAL PRECAUTIONS:
PREVENT ENTRY TO SEWERS AND PUBLIC WATERS. NOTIFY AUTHORITIES IF LIQUID
ENTERS SEWERS OR PUBLIC WATERS.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CLEANING UP:
SOAK UP SPILLS WITH INERT SOLIDS, SUCH AS CLAY OR DIATOMACEOUS EARTH AS
SOON AS POSSIBLE. COLLECT SPILLAGE. STORE AWAY FROM OTHER MATERIALS.
6.4. REFERENCE TO OTHER SECTIONS:
SEE HEADING 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
PRECAUTIONS FOR SAFE HANDLING:
WASH HANDS AND OTHER EXPOSED AREAS WITH MILD SOAP AND WATER BEFORE EATING,
DRINKING OR SMOKING AND WHEN LEAVING WORK. PROVIDE GOOD VENTILATION IN
PROCESS AREA TO PREVENT FORMATION OF VAPOUR.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE CONDITIONS: KEEP CONTAINER CLOSED WHEN NOT IN USE.
INCOMPATIBLE PRODUCTS: STRONG BASES. STRONG ACIDS. STRONG OXIDIZERS.
INCOMPATIBLE PRODUCTS: SOURCES OF IGNITION. DIRECT SUNLIGHT.
7.3. SPECIFIC END USE(S): NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
GLYCERIN (56-81-5):
USA ACGIH:
ACGIH TWA (MG/M3): 10 MG/M3 MIST
USA OSHA:
OSHA PEL (TWA) (MG/M3): 5 MG/M3 RESPIRABLE
8.2. EXPOSURE CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
EMERGENCY EYE WASH FOUNTAINS AND SAFETY SHOWERS SHOULD BE AVAILABLE IN
THE IMMEDIATE VICINITY OF ANY POTENTIAL EXPOSURE. PROVIDE ADEQUATE GENERAL
AND LOCAL EXHAUST VENTILATION.
PERSONAL PROTECTIVE EQUIPMENT: AVOID ALL UNNECESSARY EXPOSURE.
HAND PROTECTION: WEAR PROTECTIVE GLOVES.
EYE PROTECTION: CHEMICAL GOGGLES OR SAFETY GLASSES.
RESPIRATORY PROTECTION: WEAR APPROPRIATE MASK.
OTHER INFORMATION: DO NOT EAT, DRINK OR SMOKE DURING USE.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
MOLECULAR MASS: 92.11 G/MOL
COLOUR: COLOURLESS.
ODOUR: CHARACTERISTIC.
ODOUR THRESHOLD: NO DATA AVAILABLE
PH: 5 10% SOLUTION
RELATIVE EVAPORATION RATE (BUTYLACETATE=1): NO DATA AVAILABLE
MELTING POINT: 20 DEG. C
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: 182 DEG. C
FLASH POINT: 160 DEG. C
SELF IGNITION TEMPERATURE: 400 DEG. C
DECOMPOSITION TEMPERATURE: 290 DEG. C
FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
VAPOUR PRESSURE: NO DATA AVAILABLE
VAPOUR PRESSURE AT 50 DEG. C: 0.003 HPA
RELATIVE VAPOUR DENSITY AT 20 DEG. C: 3.18
RELATIVE DENSITY: NO DATA AVAILABLE
DENSITY: 1.2613 G/ML
SOLUBILITY: SOLUBLE IN WATER. SOLUBLE IN ETHANOL.
LOG POW: 0
LOG KOW: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: 1181.3 CST
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
EXPLOSIVE PROPERTIES: NO DATA AVAILABLE
OXIDISING PROPERTIES: NO DATA AVAILABLE
EXPLOSIVE LIMITS: >/= 1.1 VOL %
9.2. OTHER INFORMATION: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY: NO ADDITIONAL INFORMATION AVAILABLE
10.2. CHEMICAL STABILITY: STABLE UNDER NORMAL CONDITIONS.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS: NOT ESTABLISHED.
10.4. CONDITIONS TO AVOID:
DIRECT SUNLIGHT. EXTREMELY HIGH OR LOW TEMPERATURES.
10.5. INCOMPATIBLE MATERIALS:
STRONG ACIDS. STRONG BASES. STRONG OXIDIZERS.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
FUME. CARBON MONOXIDE. CARBON DIOXIDE.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY: NOT CLASSIFIED
GLYCERIN (\F) 56-81-5:
LD50 ORAL RAT: 12600 MG/KG
LD50 DERMAL RAT: 21900 MG/KG
SKIN CORROSION/IRRITATION: NOT CLASSIFIED
PH: 5 10% SOLUTION
SERIOUS EYE DAMAGE/IRRITATION: NOT CLASSIFIED
PH: 5 10% SOLUTION
RESPIRATORY OR SKIN SENSITISATION: NOT CLASSIFIED
GERM CELL MUTAGENICITY: NOT CLASSIFIED
CARCINOGENICITY: NOT CLASSIFIED
REPRODUCTIVE TOXICITY: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): NOT CLASSIFIED
ASPIRATION HAZARD: NOT CLASSIFIED
POTENTIAL ADVERSE HUMAN HEALTH EFFECTS AND SYMPTOMS:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
GLYCERIN (56-81-5):
LC50 FISHES 1: 64 - 72 G/L
12.2. PERSISTENCE AND DEGRADABILITY:
GLYCERIN (56-81-5):
PERSISTENCE AND DEGRADABILITY: NOT ESTABLISHED.
12.3. BIOACCUMULATIVE POTENTIAL:
GLYCERIN (56-81-5):
LOG POW: 0
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
12.4. MOBILITY IN SOIL: NO ADDITIONAL INFORMATION AVAILABLE
12.5. OTHER ADVERSE EFFECTS:
OTHER INFORMATION: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. WASTE TREATMENT METHODS:
WASTE DISPOSAL RECOMMENDATIONS:
DISPOSE IN A SAFE MANNER IN ACCORDANCE WITH LOCAL/NATIONAL REGULATIONS.
ECOLOGY - WASTE MATERIALS: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 14: TRANSPORT INFORMATION | |
IN ACCORDANCE WITH DOT:
NO DANGEROUS GOOD IN SENSE OF TRANSPORT REGULATIONS
ADDITIONAL INFORMATION:
OTHER INFORMATION: NO SUPPLEMENTARY INFORMATION AVAILABLE.
ADR: TRANSPORT DOCUMENT DESCRIPTION
TRANSPORT BY SEA: NO ADDITIONAL INFORMATION AVAILABLE
AIR TRANSPORT: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
GLYCERIN (56-81-5):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
15.2. INTERNATIONAL REGULATIONS:
CANADA:
GLYCERIN (56-81-5):
LISTED ON THE CANADIAN DSL (DOMESTIC SUSTANCES LIST) INVENTORY.
WHMIS CLASSIFICATION:
UNCONTROLLED PRODUCT ACCORDING TO WHMIS CLASSIFICATION CRITERIA
EU-REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
CLASSIFICATION ACCORDING TO REGULATION (EC) NO. 1272/2008 [CLP]:
NOT CLASSIFIED
CLASSIFICATION ACCORDING TO DIRECTIVE 67/548/EEC OR 1999/45/EC:
NOT CLASSIFIED
15.2.2. NATIONAL REGULATIONS:
GLYCERIN (56-81-5): NOT LISTED ON THE CANADIAN INGREDIENT DISCLOSURE LIST
15.3. US STATE REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 16: OTHER INFORMATION | |
OTHER INFORMATION: NONE.
NFPA HEALTH HAZARD 1 - EXPOSURE COULD CAUSE IRRITATION BUT ONLY MINOR
RESIDUAL INJURY EVEN IF NO TREATMENT IS GIVEN.
NFPA FIRE HAZARD 0 - MATERIALS THAT WILL NOT BURN.
NFPA REACTIVITY 0 - NORMALLY STABLE, EVEN UNDER FIRE EXPOSURE
CONDITIONS, AND ARE NOT REACTIVE WITH WATER.
HMIS III RATING:
HEALTH 1 SLIGHT HAZARD - IRRITATION OR MINOR REVERSIBLE INJURY
POSSIBLE
FLAMMABILITY 0 MINIMAL HAZARD
PHYSICAL 0 MINIMAL HAZARD
PERSONAL PROTECTION E
SDS US (GHS HAZCOM 2012)
INFORMATION IN THIS SDS IS FROM AVAILABLE PUBLISHED SOURCES AND IS BELIEVED
TO BE ACCURATE. NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AND LABCHEM INC
ASSUMES NO LIABILITY RESULTING FROM THE USE OF THIS SDS. THE USER MUST
DETERMINE SUITABILITY OF THIS INFORMATION FOR HIS APPLICATION.
EN (ENGLISH)