| Common Name: | CRYSTAL VIOLET, 1% W/V IN GLACIAL ACETIC ACID |
| Manufacturer: | LABCHEM |
| SDS Revision Date: | 5/3/2017 |
| SDS Format: | No Format Specified |
| Item Number(s): | 8G965 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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LC
LABCHEM
PERFORMANCE THROUGH CHEMISTRY
CRYSTAL VIOLET, 1% W/V IN GLACIAL ACETIC ACID
SAFETY DATA SHEET
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26, 2012 /
RULES AND REGULATIONS
DATE OF ISSUE: 12/30/2014
REVISION DATE: 05/03/2017
SUPERSEDES: 09/14/2015
VERSION: 1.2
| SECTION 1: IDENTIFICATION |  |
1.1. IDENTIFICATION
PRODUCT FORM: MIXTURES
PRODUCT NAME: CRYSTAL VIOLET, 1% W/V IN GLACIAL ACETIC ACID
PRODUCT CODE: LC13541
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE
USE OF THE SUBSTANCE/MIXTURE: FOR LABORATORY AND MANUFACTURING USE ONLY.
RECOMMENDED USE: LABORATORY CHEMICALS
RESTRICTIONS ON USE: NOT FOR FOOD, DRUG OR HOUSEHOLD USE
1.3. SUPPLIER
LABCHEM INC
JACKSON'S POINTE COMMERCE PARK BUILDING 1000, 1010 JACKSON'S POINTE COURT
ZELIENOPLE, PA 16063
USA
T: 412-826-5230
F: 724-473-0647
INFO@LABCHEM.COM
WWW.LABCHEM.COM
1.4. EMERGENCY TELEPHONE NUMBER
EMERGENCY NUMBER:
CHEMTREC: 1-800-424-9300 OR 011-703-527-3887
| SECTION 2: HAZARD(S) IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE
GHS-US CLASSIFICATION
FLAMMABLE LIQUIDS CATEGORY 3:
H226: FLAMMABLE LIQUID AND VAPOR
SERIOUS EYE DAMAGE/EYE IRRITATION CATEGORY 1:
H318: CAUSES SERIOUS EYE DAMAGE
CARCINOGENICITY CATEGORY 2:
H351: SUSPECTED OF CAUSING CANCER
HAZARDOUS TO THE AQUATIC ENVIRONMENT - ACUTE HAZARD CATEGORY 3:
H402: HARMFUL TO AQUATIC LIFE
HAZARDOUS TO THE AQUATIC ENVIRONMENT - CHRONIC HAZARD CATEGORY 3:
H412: HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS
FULL TEXT OF H STATEMENTS: SEE SECTION 16
2.2. GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENTS:
GHS-US LABELING:
HAZARD PICTOGRAMS (GHS-US):
GHS02: FLAME
GHS05: CORROSION
GHS08: HEALTH HAZARD
SIGNAL WORD (GHS-US): DANGER
HAZARD STATEMENTS (GHS-US):
H226: FLAMMABLE LIQUID AND VAPOR
H318: CAUSES SERIOUS EYE DAMAGE
H351: SUSPECTED OF CAUSING CANCER
H412: HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS
PRECAUTIONARY STATEMENTS (GHS-US):
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD
P210: KEEP AWAY FROM HEAT, SPARKS, OPEN FLAMES, HOT SURFACES. - NO SMOKING
P233: KEEP CONTAINER TIGHTLY CLOSED
P240: GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT
P241: USE EXPLOSION-PROOF ELECTRICAL, VENTILATING, LIGHTING EQUIPMENT
P242: USE ONLY NON-SPARKING TOOLS
P243: TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE
P273: AVOID RELEASE TO THE ENVIRONMENT
P280: WEAR PROTECTIVE GLOVES, EYE PROTECTION
P303+P361+P353:
IF ON SKIN (OR HAIR):
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING
P310: IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN
P370+P378:
IN CASE OF FIRE:
USE CARBON DIOXIDE (CO2), POWDER, ALCOHOL-RESISTANT FOAM TO EXTINGUISH
P403+P235: STORE IN A WELL-VENTILATED PLACE. KEEP COOL
P405: STORE LOCKED UP
P501:
DISPOSE OF CONTENTS/CONTAINER TO COMPLY WITH LOCAL, STATE AND FEDERAL
REGULATIONS
2.3. OTHER HAZARDS WHICH DO NOT RESULT IN CLASSIFICATION:
OTHER HAZARDS NOT CONTRIBUTING TO THE CLASSIFICATION:
NONE.
2.4. UNKNOWN ACUTE TOXICITY (GHS US): NOT APPLICABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCES: NOT APPLICABLE
3.2. MIXTURES:
NAME PRODUCT IDENTIFIER % GHS-US CLASSIFICATION
ACETIC ACID (CAS NO) 64-19-7 99 FLAM. LIQ. 3, H226
SKIN CORR. 1B, H314
EYE DAM. 1, H318
AQUATIC ACUTE 3, H402
GENTIAN VIOLET (CAS NO) 548-62-9 1 ACUTE TOX. 4 (ORAL), H302
EYE DAM. 1, H318
CARC. 2, H351
AQUATIC ACUTE 1, H400
AQUATIC CHRONIC 1, H410
FULL TEXT OF HAZARD CLASSES AND H-STATEMENTS: SEE SECTION 16
| SECTION 4: FIRST-AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES GENERAL:
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF YOU FEEL UNWELL,
SEEK MEDICAL ADVICE (SHOW THE LABEL WHERE POSSIBLE). SUSPECTED OF CAUSING
CANCER.
FIRST-AID MEASURES AFTER INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
FIRST-AID MEASURES AFTER SKIN CONTACT:
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
FIRST-AID MEASURES AFTER EYE CONTACT:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING. IMMEDIATELY CALL A POISON CENTER
OR DOCTOR/PHYSICIAN.
FIRST-AID MEASURES AFTER INGESTION:
RINSE MOUTH. DO NOT INDUCE VOMITING. IMMEDIATELY CALL A POISON CENTER OR
DOCTOR/PHYSICIAN.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS (ACUTE AND DELAYED):
SYMPTOMS/INJURIES: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
SYMPTOMS/INJURIES AFTER EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
4.3. IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT, IF NECESSARY:
OBTAIN MEDICAL ASSISTANCE.
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE (AND UNSUITABLE) EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
FOAM. DRY POWDER. CARBON DIOXIDE. WATER SPRAY. SAND.
UNSUITABLE EXTINGUISHING MEDIA: DO NOT USE A HEAVY WATER STREAM.
5.2. SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
FIRE HAZARD: FLAMMABLE LIQUID AND VAPOR.
EXPLOSION HAZARD: MAY FORM FLAMMABLE/EXPLOSIVE VAPOR-AIR MIXTURE.
REACTIVITY:
THERMAL DECOMPOSITION GENERATES: CORROSIVE VAPORS.
5.3. SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE-FIGHTERS:
FIREFIGHTING INSTRUCTIONS:
USE WATER SPRAY OR FOG FOR COOLING EXPOSED CONTAINERS. EXERCISE CAUTION
WHEN FIGHTING ANY CHEMICAL FIRE. PREVENT FIRE-FIGHTING WATER FROM ENTERING
ENVIRONMENT.
PROTECTION DURING FIREFIGHTING:
DO NOT ENTER FIRE AREA WITHOUT PROPER PROTECTIVE EQUIPMENT, INCLUDING
RESPIRATORY PROTECTION.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
GENERAL MEASURES:
REMOVE IGNITION SOURCES. USE SPECIAL CARE TO AVOID STATIC ELECTRIC
CHARGES. NO NAKED LIGHTS. NO SMOKING.
6.1.1. FOR NON-EMERGENCY PERSONNEL:
PROTECTIVE EQUIPMENT: SAFETY GLASSES. GLOVES. PROTECTIVE CLOTHING.
EMERGENCY PROCEDURES: EVACUATE UNNECESSARY PERSONNEL.
6.1.2. FOR EMERGENCY RESPONDERS:
PROTECTIVE EQUIPMENT: EQUIP CLEANUP CREW WITH PROPER PROTECTION.
EMERGENCY PROCEDURES: VENTILATE AREA.
6.2. ENVIRONMENTAL PRECAUTIONS:
PREVENT ENTRY TO SEWERS AND PUBLIC WATERS. NOTIFY AUTHORITIES IF LIQUID
ENTERS SEWERS OR PUBLIC WATERS. AVOID RELEASE TO THE ENVIRONMENT
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CLEANING UP:
SOAK UP SPILLS WITH INERT SOLIDS, SUCH AS CLAY OR DIATOMACEOUS EARTH AS
SOON AS POSSIBLE. COLLECT SPILLAGE. STORE AWAY FROM OTHER MATERIALS.
6.4. REFERENCE TO OTHER SECTIONS:
SEE HEADING 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
ADDITIONAL HAZARDS WHEN PROCESSED:
HANDLE EMPTY CONTAINERS WITH CARE BECAUSE RESIDUAL VAPORS ARE FLAMMABLE.
PRECAUTIONS FOR SAFE HANDLING:
WASH HANDS AND OTHER EXPOSED AREAS WITH MILD SOAP AND WATER BEFORE EATING,
DRINKING OR SMOKING AND WHEN LEAVING WORK. PROVIDE GOOD VENTILATION IN
PROCESS AREA TO PREVENT FORMATION OF VAPOR. NO NAKED LIGHTS. NO SMOKING.
TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE. USE ONLY
NON-SPARKING TOOLS. DO NOT BREATHE MIST, VAPORS, SPRAY. OBTAIN SPECIAL
INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE
BEEN READ AND UNDERSTOOD
HYGIENE MEASURES:
WASH EXPOSED SKIN THOROUGHLY AFTER HANDLING. WASH CONTAMINATED CLOTHING
BEFORE REUSE.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
TECHNICAL MEASURES:
PROPER GROUNDING PROCEDURES TO AVOID STATIC ELECTRICITY SHOULD BE
FOLLOWED. GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT. USE
EXPLOSION-PROOF ELECTRICAL/VENTILATING/LIGHTING/... EQUIPMENT.
COMPLY WITH APPLICABLE REGULATIONS.
STORAGE CONDITIONS:
KEEP ONLY IN THE ORIGINAL CONTAINER IN A COOL, WELL VENTILATED PLACE AWAY
FROM:
HEAT SOURCES, IGNITION SOURCES. KEEP CONTAINER TIGHTLY CLOSED.
INCOMPATIBLE PRODUCTS: STRONG OXIDIZERS. METALS. STRONG BASES.
INCOMPATIBLE MATERIALS:
SOURCES OF IGNITION. DIRECT SUNLIGHT. HEAT SOURCES.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS
ACETIC ACID (64-19-7):
ACGIH:
ACGIH TWA (PPM):
10 PPM (ACETIC ACID; USA; TIME-WEIGHTED AVERAGE EXPOSURE LIMIT 8 H;
TLV - ADOPTED VALUE)
ACGIH:
ACGIH STEL (PPM):
15 PPM (ACETIC ACID; USA; SHORT TIME VALUE; TLV - ADOPTED VALUE)
OSHA:
OSHA PEL (TWA) (MG/M3): 25 MG/M3
OSHA:
OSHA PEL (TWA) (PPM): 10 PPM
IDLH:
US IDLH (PPM): 50 PPM
NIOSH:
NIOSH REL (TWA) (MG/M3): 25 MG/M3
NIOSH:
NIOSH REL (TWA) (PPM): 10 PPM
NIOSH:
NIOSH REL (STEL) (MG/M3): 37 MG/M3
NIOSH:
NIOSH REL (STEL) (PPM): 15 PPM
GENTIAN VIOLET (548-62-9): NOT APPLICABLE
8.2. APPROPRIATE ENGINEERING CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
EMERGENCY EYE WASH FOUNTAINS SHOULD BE AVAILABLE IN THE IMMEDIATE VICINITY
OF ANY POTENTIAL EXPOSURE.
8.3. INDIVIDUAL PROTECTION MEASURES/PERSONAL PROTECTIVE EQUIPMENT:
PERSONAL PROTECTIVE EQUIPMENT:
GLOVES.
SAFETY GLASSES.
HAND PROTECTION: WEAR PROTECTIVE GLOVES
EYE PROTECTION: CHEMICAL GOGGLES OR FACE SHIELD
SKIN AND BODY PROTECTION: WEAR SUITABLE PROTECTIVE CLOTHING
RESPIRATORY PROTECTION:
RESPIRATORY PROTECTION NOT REQUIRED IN NORMAL CONDITIONS
OTHER INFORMATION: DO NOT EAT, DRINK OR SMOKE DURING USE.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
COLOR: PURPLE
ODOR: VINEGAR ODOUR
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
MELTING POINT: NO DATA AVAILABLE
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: 118 DEG. C
FLASH POINT: 40 DEG. C NOT APPLICABLE
RELATIVE EVAPORATION RATE (BUTYL ACETATE=1): NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): FLAMMABLE LIQUID AND VAPOR.
VAPOR PRESSURE: NO DATA AVAILABLE
RELATIVE VAPOR DENSITY AT 20 DEG. C: NO DATA AVAILABLE
RELATIVE DENSITY: NO DATA AVAILABLE
SPECIFIC GRAVITY / DENSITY: 1.06 G/ML
SOLUBILITY: SOLUBLE IN WATER.
LOG POW: NO DATA AVAILABLE
AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: 2.18 CST
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
EXPLOSION LIMITS: NO DATA AVAILABLE
EXPLOSIVE PROPERTIES: NO DATA AVAILABLE
OXIDIZING PROPERTIES: NO DATA AVAILABLE
9.2. OTHER INFORMATION: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THERMAL DECOMPOSITION GENERATES : CORROSIVE VAPORS.
10.2. CHEMICAL STABILITY:
FLAMMABLE LIQUID AND VAPOR. MAY FORM FLAMMABLE/EXPLOSIVE VAPOR-AIR
MIXTURE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
REACTS VIOLENTLY WITH (SOME) BASES: RELEASE OF HEAT.
10.4. CONDITIONS TO AVOID:
DIRECT SUNLIGHT. EXTREMELY HIGH OR LOW TEMPERATURES. OPEN FLAME.
OVERHEATING. HEAT. SPARKS.
10.5. INCOMPATIBLE MATERIALS: STRONG OXIDIZERS. METALS. STRONG BASES.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
CARBON MONOXIDE. CARBON DIOXIDE. MAY RELEASE FLAMMABLE GASES. THERMAL
DECOMPOSITION GENERATES:
CORROSIVE VAPORS
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
LIKELY ROUTES OF EXPOSURE: INHALATION; SKIN AND EYE CONTACT
ACUTE TOXICITY: NOT CLASSIFIED
CRYSTAL VIOLET, 1% W/V IN GLACIAL ACETIC ACID:
LD50 ORAL RAT: 3141 MG/KG
ATE US (ORAL): 3141.000 MG/KG BODY WEIGHT
ACETIC ACID (64-19-7):
LD50 ORAL RAT: 3310 MG/KG BODY WEIGHT (RAT; OTHER; READ-ACROSS)
ATE US (ORAL): 3310.000 MG/KG BODY WEIGHT
GENTIAN VIOLET (548-62-9):
ATE US (ORAL): 500.000 MG/KG BODY WEIGHT
SKIN CORROSION/IRRITATION: NOT CLASSIFIED
SERIOUS EYE DAMAGE/IRRITATION: CAUSES SERIOUS EYE DAMAGE.
RESPIRATORY OR SKIN SENSITIZATION: NOT CLASSIFIED
GERM CELL MUTAGENICITY: NOT CLASSIFIED
CARCINOGENICITY: SUSPECTED OF CAUSING CANCER.
REPRODUCTIVE TOXICITY: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NOT CLASSIFIED
ASPIRATION HAZARD: NOT CLASSIFIED
POTENTIAL ADVERSE HUMAN HEALTH EFFECTS AND SYMPTOMS:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
SYMPTOMS/INJURIES AFTER EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
ECOLOGY - WATER:
HARMFUL TO AQUATIC LIFE. HARMFUL TO AQUATIC LIFE WITH LONG LASTING
EFFECTS.
GENTIAN VIOLET (548-62-9):
EC50 DAPHNIA 1: 0.24 - 5 MG/L 48 HR.
EC50 OTHER AQUATIC ORGANISMS 1:
0.025 - 0.8 72 HR., PSUEDOKIRCHNERIELLA SUBCAPITATA
12.2. PERSISTENCE AND DEGRADABILITY
CRYSTAL VIOLET, 1% W/V IN GLACIAL ACETIC ACID:
PERSISTENCE AND DEGRADABILITY:
MAY CAUSE LONG-TERM ADVERSE EFFECTS IN THE ENVIRONMENT.
ACETIC ACID (64-19-7):
PERSISTENCE AND DEGRADABILITY:
READILY BIODEGRADABLE IN WATER. BIODEGRADABLE IN THE SOIL.
HIGHLY MOBILE IN SOIL.
BIOCHEMICAL OXYGEN DEMAND (BOD): 0.6 - 0.74 G O2/G SUBSTANCE
CHEMICAL OXYGEN DEMAND (COD): 1.03 G O2/G SUBSTANCE
THOD: 1.07 G O2/G SUBSTANCE
GENTIAN VIOLET (548-62-9):
PERSISTENCE AND DEGRADABILITY: NOT ESTABLISHED.
12.3. BIOACCUMULATIVE POTENTIAL:
CRYSTAL VIOLET, 1% W/V IN GLACIAL ACETIC ACID:
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
ACETIC ACID (64-19-7):
BCF FISH 1: 3.16 (BCF; PISCES)
LOG POW: -0.17 (EXPERIMENTAL VALUE; 25 DEG. C)
BIOACCUMULATIVE POTENTIAL:
LOW POTENTIAL FOR BIOACCUMULATION (LOG KOW < 4).
GENTIAN VIOLET (548-62-9):
LOG POW: 1.172
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
12.4. MOBILITY IN SOIL:
ACETIC ACID (64-19-7):
SURFACE TENSION: 0.028 N/M (20 DEG. C)
LOG KOC: LOG KOC,0.06; QSAR
ECOLOGY - SOIL:
MAY BE HARMFUL TO PLANT GROWTH, BLOOMING AND FRUIT FORMATION.
12.5. OTHER ADVERSE EFFECTS:
EFFECT ON THE GLOBAL WARMING: NO KNOWN EFFECTS FROM THIS PRODUCT.
GWPMIX COMMENT: NO KNOWN EFFECTS FROM THIS PRODUCT.
OTHER INFORMATION: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
WASTE DISPOSAL RECOMMENDATIONS:
DISPOSE IN A SAFE MANNER IN ACCORDANCE WITH LOCAL/NATIONAL REGULATIONS.
DISPOSE OF CONTENTS/CONTAINER TO COMPLY WITH LOCAL, STATE AND FEDERAL
REGULATIONS.
ADDITIONAL INFORMATION:
HANDLE EMPTY CONTAINERS WITH CARE BECAUSE RESIDUAL VAPORS ARE FLAMMABLE.
ECOLOGY - WASTE MATERIALS: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 14: TRANSPORT INFORMATION | |
DEPARTMENT OF TRANSPORTATION (DOT):
IN ACCORDANCE WITH DOT TRANSPORT DOCUMENT DESCRIPTION:
UN2789 ACETIC ACID SOLUTION, 8, II
UN-NO.(DOT): UN2789
PROPER SHIPPING NAME (DOT): ACETIC ACID SOLUTION
TRANSPORT HAZARD CLASS(ES) (DOT):
8 - CLASS 8 - CORROSIVE MATERIAL 49 CFR 173.136
PACKING GROUP (DOT): II - MEDIUM DANGER
HAZARD LABELS (DOT):
8 - CORROSIVE
3 - FLAMMABLE LIQUID
CORROSIVE, CLASS/DIVISION 8
FLAMMABLE LIQUID, CLASS/DIVISION 3.1, 3.2, 3.3
DOT PACKAGING NON BULK (49 CFR 173.XXX): 202
DOT PACKAGING BULK (49 CFR 173.XXX): 243
DOT SPECIAL PROVISIONS (49 CFR 172.102):
A3:
FOR COMBINATION PACKAGING, IF GLASS INNER PACKAGING (INCLUDING AMPOULES)
ARE USED, THEY MUST BE PACKED WITH ABSORBENT MATERIAL IN TIGHTLY CLOSED
METAL RECEPTACLES BEFORE PACKING IN OUTER PACKAGING.
A6:
FOR COMBINATION PACKAGING, IF PLASTIC INNER PACKAGING ARE USED, THEY
MUST BE PACKED IN TIGHTLY CLOSED METAL RECEPTACLES BEFORE PACKING IN OUTER
PACKAGING.
A7:
STEEL PACKAGING MUST BE CORROSION-RESISTANT OR HAVE PROTECTION AGAINST
CORROSION.
A10:
WHEN ALUMINUM OR ALUMINUM ALLOY CONSTRUCTION MATERIALS ARE USED, THEY MUST
BE RESISTANT TO CORROSION.
B2:
MC 300, MC 301, MC 302, MC 303, MC 305, AND MC 306 AND DOT 406 CARGO TANKS
ARE NOT AUTHORIZED.
IB2:
AUTHORIZED IBCS:
METAL (31A, 31B AND 31N); RIGID PLASTICS (31H1 AND 31H2); COMPOSITE
(31HZ1).
ADDITIONAL REQUIREMENT:
ONLY LIQUIDS WITH A VAPOR PRESSURE LESS THAN OR EQUAL TO 110 KPA AT 50 C
(1.1 BAR AT 122 F), OR 130 KPA AT 55 C (1.3 BAR AT 131 F) ARE AUTHORIZED.
T7: 4 178.274(D)(2) NORMAL............. 178.275(D)(3)
TP2:
A. THE MAXIMUM DEGREE OF FILLING MUST NOT EXCEED THE DEGREE OF FILLING
DETERMINED BY THE FOLLOWING:
(IMAGE) WHERE:
TR IS THE MAXIMUM MEAN BULK TEMPERATURE DURING TRANSPORT, TF IS THE
TEMPERATURE IN DEGREES CELSIUS OF THE LIQUID DURING FILLING, AND A IS THE
MEAN COEFFICIENT OF CUBICAL EXPANSION OF THE LIQUID BETWEEN THE MEAN
TEMPERATURE OF THE LIQUID DURING FILLING (TF) AND THE MAXIMUM MEAN BULK
TEMPERATURE DURING TRANSPORTATION (TR) BOTH IN DEGREES CELSIUS.
B. FOR LIQUIDS TRANSPORTED UNDER AMBIENT CONDITIONS MAY BE CALCULATED
USING THE FORMULA:
(IMAGE) WHERE:
D15 AND D50 ARE THE DENSITIES (IN UNITS OF MASS PER UNIT VOLUME) OF THE
LIQUID AT 15 C (59 F) AND 50 C (122 F), RESPECTIVELY.
DOT PACKAGING EXCEPTIONS (49 CFR 173.XXX): 154
DOT QUANTITY LIMITATIONS PASSENGER AIRCRAFT/RAIL (49 CFR 173.27): 1 L
DOT QUANTITY LIMITATIONS CARGO AIRCRAFT ONLY (49 CFR 175.75): 30 L
DOT VESSEL STOWAGE LOCATION:
A:
THE MATERIAL MAY BE STOWED "ON DECK" OR "UNDER DECK" ON A CARGO
VESSEL AND ON A PASSENGER VESSEL.
OTHER INFORMATION: NO SUPPLEMENTARY INFORMATION AVAILABLE.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
CRYSTAL VIOLET, 1% W/V IN GLACIAL ACETIC ACID:
SARA SECTION 311/312 HAZARD CLASSES:
IMMEDIATE (ACUTE) HEALTH HAZARD FIRE HAZARD
ALL COMPONENTS OF THIS PRODUCT ARE LISTED, OR EXCLUDED FROM LISTING, ON
THE UNITED STATES ENVIRONMENTAL PROTECTION AGENCY TOXIC SUBSTANCES
CONTROL ACT (TSCA) INVENTORY
THIS PRODUCT OR MIXTURE DOES NOT CONTAIN A TOXIC CHEMICAL OR CHEMICALS IN
EXCESS OF THE APPLICABLE DE MINIMIS CONCENTRATION AS SPECIFIED IN 40 CFR
SUBSECTION372.38(A) SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313
OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986
AND 40 CFR PART 372.
ACETIC ACID (64-19-7):
RQ (REPORTABLE QUANTITY, SECTION 304 OF EPA'S LIST OF LISTS): 5000 LB
GENTIAN VIOLET (548-62-9):
SARA SECTION 311/312 HAZARD CLASSES:
IMMEDIATE (ACUTE) HEALTH HAZARD
DELAYED (CHRONIC) HEALTH HAZARD
15.2. INTERNATIONAL REGULATIONS:
CANADA:
ACETIC ACID (64-19-7):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
GENTIAN VIOLET (548-62-9):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
EU-REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
NATIONAL REGULATIONS:
ACETIC ACID (64-19-7):
LISTED ON THE CANADIAN IDL (INGREDIENT DISCLOSURE LIST)
GENTIAN VIOLET (548-62-9):
LISTED ON THE CANADIAN IDL (INGREDIENT DISCLOSURE LIST)
15.3. US STATE REGULATIONS:
CALIFORNIA PROPOSITION 65 - THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES
KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER, DEVELOPMENTAL AND/OR
REPRODUCTIVE HARM
| SECTION 16: OTHER INFORMATION | |
REVISION DATE: 05/03/2017
OTHER INFORMATION: NONE.
FULL TEXT OF H-PHRASES: SEE SECTION 16
H226: FLAMMABLE LIQUID AND VAPOR
H302: HARMFUL IF SWALLOWED
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE
H318: CAUSES SERIOUS EYE DAMAGE
H351: SUSPECTED OF CAUSING CANCER
H400: VERY TOXIC TO AQUATIC LIFE
H402: HARMFUL TO AQUATIC LIFE
H410: VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS
H412: HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS
NFPA HEALTH HAZARD 3 - MATERIALS THAT, UNDER EMERGENCY CONDITIONS, CAN
CAUSE SERIOUS OR PERMANENT INJURY.
NFPA FIRE HAZARD 2 - MATERIALS THAT MUST BE MODERATELY HEATED OR EXPOSED
TO RELATIVELY HIGH AMBIENT TEMPERATURES BEFORE
IGNITION CAN OCCUR.
NFPA REACTIVITY 0 - MATERIAL THAT IN THEMSELVES ARE NORMALLY STABLE,
EVEN UNDER FIRE CONDITIONS.
HMIS III RATING:
HEALTH 3 SERIOUS HAZARD - MAJOR INJURY LIKELY UNLESS PROMPT
ACTION IS TAKEN AND MEDICAL TREATMENT IS GIVEN
FLAMMABILITY 2 MODERATE HAZARD - MATERIALS WHICH MUST BE MODERATELY
HEATED OR EXPOSED TO HIGH AMBIENT TEMPERATURES BEFORE
IGNITION WILL OCCUR. INCLUDES LIQUIDS HAVING A FLASH
POINT AT OR ABOVE 100 F BUT BELOW 200 F.
(CLASSES II & IIIA)
PHYSICAL 0 MINIMAL HAZARD - MATERIALS THAT ARE NORMALLY STABLE,
EVEN UNDER FIRE CONDITIONS, AND WILL NOT REACT WITH
WATER, POLYMERIZE, DECOMPOSE, CONDENSE, OR SELF-REACT.
NON-EXPLOSIVES.
PERSONAL PROTECTION H
H - SPLASH GOGGLES, GLOVES, SYNTHETIC APRON, VAPOR
RESPIRATOR
SDS US LABCHEM
INFORMATION IN THIS SDS IS FROM AVAILABLE PUBLISHED SOURCES AND IS
BELIEVED TO BE ACCURATE. NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AND
LABCHEM INC ASSUMES NO LIABILITY RESULTING FROM THE USE OF THIS SDS. THE
USER MUST DETERMINE SUITABILITY OF THIS INFORMATION FOR HIS APPLICATION.
EN (ENGLISH US)